Polyolefin formulations containing clotophenone compounds

Abstract

A polyolefin blend comprising (A) a polyolefin polymer and (B) a crotophenone compound of formula (I) as described herein, as well as crosslinked products made therefrom, methods of making and using same, and articles containing same.

Description

[Technical field]

[0001] The technical field involves polyolefin formulations for wire and cable. [Background technology]

[0002] Introduction Patents in this field include U.S. Patent Nos. 3,413,263, 6,696,154 (B2), 8,680,399 (B2), 9,133,320 (B2), and 9,343,198 (B2). Published patent applications in this field include EP 0,111,043 (A1), EP 2,886,595, GB 1,461,331 (A), U.S. Patent Application Publication Nos. 2016 / 0304699 (A1), 2016 / 0312007 (A1), WO 2010 / 028721 (A1), WO 2012 / 044521, WO 2014 / 209661 (A1), and WO 2014 / 172107 (A1). Publications include H. Wagner and J. Wartusch, About The Significance Of Peroxide Decomposition Products In XLPE Cable Insulations, IEEE Trans. Electr. Insul, vol. EI-12, no. 6, December 1977.

[0003] Insulated conductors typically comprise a conductive core coated with an insulating layer. The conductive core may be solid or stranded (e.g., a bundle of wires). Some insulated conductors may also contain one or more additional elements, such as semiconductive layers and / or protective jackets (e.g., windings, tapes, or sheaths). Examples are coated metal wires and power cables, including low voltage ("LV", >0 to <5 kilovolts (kV)), medium voltage ("MV", 5 to <69 kV), high voltage ("HV", 69 to 230 kV), and extra high voltage ("EHV", >230 kV) power cables and their transmission / distribution applications. AEIC / ICEA specifications and / or IEC test methods can be used to evaluate power cables.

[0004] The majority of high voltage and extra high voltage power cables contain an insulation layer composed of an insulating material that includes a host polymer and one or more additives. The additives may include antioxidants, colorants, and / or hindered amine stabilizers. The dielectric breakdown strength (also known as dielectric strength) of the insulating material determines how thick the insulation layer needs to be to meet industry standards for power cable performance at a particular voltage.

[0005] All other things being equal, a higher dielectric breakdown strength of the insulating material allows for a thinner insulating layer with the same dielectric breakdown strength as a relatively thicker layer. All other things being equal, a thinner insulating layer means a thinner cable. A thinner cable advantageously allows for a smaller amount of cable mass to be used per unit cable length to achieve a given dielectric breakdown strength. This in turn usefully increases the length of cable that can be wound onto a standard size cable roll. A longer cable then reduces the number of joints or splices required to connect two or more thinner cables together. Alternatively, a higher dielectric breakdown strength of the insulating material allows for a higher dielectric breakdown strength for an insulating layer with the same thickness, and therefore for a cable of the same size. A higher dielectric breakdown strength for a cable of the same size advantageously allows for a higher voltage to be transmitted in that cable configuration. Transmitting power at a higher voltage reduces energy losses.

[0006] The clotophenone compound itself has this structure:

[0007] [ka] Summary of the Invention

[0008] The inventors have discovered clotophenone compounds that have beneficial voltage stabilizing efficacy. When a host polyolefin polymer is blended with one or more of these clotophenone compounds, the resulting polyolefin blend has increased dielectric breakdown strength compared to a host polyolefin that does not contain (B) a clotophenone compound. In some embodiments, the dielectric breakdown strength of the blends of the present invention is advantageously greater than a comparative blend containing benzyl and / or benzyl derivatives. The inventors contemplate the following embodiments:

[0009] A polyolefin blend comprising: (A) a polyolefin polymer; and (B) a polyolefin polymer of formula (I):

[0010] [ka] [In the formula, Ar is phenyl, alkylphenyl, 1-naphthyl, or 2-naphthyl, and R is (C1-C5) alkyl, (C6-C 10 ) alkyl, (C 11 ~C 20 ) alkyl, or (C 21 ~C 40 ) alkyl] and a crotophenone compound.

[0011] 1. A method of making a polyolefin blend comprising contacting (A) a polyolefin polymer with (B) a crotophenone compound of formula (I) to make the blend.

[0012] 1. A method of making a crosslinked polyolefin product, comprising: (A) subjecting a formulation to curing conditions to crosslink a polyolefin polymer, thereby making a crosslinked polyolefin product.

[0013] A crosslinked polyolefin product made by the above process.

[0014] Articles comprising polyolefin blends and / or crosslinked polymer products. [Brief description of the drawings]

[0015] [Figure 1] FIG. 2 is a diagram showing the shape of a test sample for measuring dielectric breakdown strength. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0016] The Summary and Abstract are incorporated herein by reference. Embodiments are described below, some of which are described as numbered aspects for ease of reference.

[0017] Aspect 1. A polyolefin blend comprising: (A) a polyolefin polymer; and (B) a copolymer of formula (I):

[0018] [ka] [In the formula, Ar is phenyl, alkylphenyl, 1-naphthyl, or 2-naphthyl, and R is (C1-C5) alkyl, (C6-C 10 ) alkyl, (C 11 ~C 20 ) alkyl, or (C 21 ~C 40 and a crotophenone compound of formula (A), (B), wherein the total weight of the polyolefin compound, including components (A), (B), and any optional additives, is 100.0 wt.%. The polyolefin compound has increased dielectric breakdown strength compared to crosslinked (A) polyolefin polymer not including the (B) crotophenone compound.

[0019] Aspect 2. The polyolefin blend of aspect 1, wherein Ar is selected from the group consisting of: (i) phenyl, (ii) alkylphenyl, (iii) 1-naphthyl, (iv) 2-naphthyl, (v) both (i) and (ii), (vi) both (i) and (iii), (vii) both (i) and (iv), (viii) both (ii) and (iii), (ix) both (ii) and (iv), (x) both (iii) and (iv), and (xi) a combination of any three of (i), (ii), (iii), and (iv).

[0020] Aspect 3. The polyolefin blend of aspect 1 or 2, wherein R is methyl or (C2-C5) alkyl.

[0021] Aspect 4. (A) The polyolefin polymer is a low density polyethylene polymer, an ethylene / (C4-C 20 4. The polyolefin blend of any one of aspects 1-3, wherein the polyolefin blend is selected from the group consisting of alpha-olefin copolymers, ethylene / (unsaturated carboxylic acid ester) copolymers, ethylene / (monocyclic organosiloxane) copolymers, ethylene / propylene copolymers, ethylene / propylene / (diene monomer) terpolymers, and propylene homopolymers.

[0022] Aspect 5. The polyolefin formulation of any one of Aspects 1-4, comprising: 0.0-99.8 weight percent (wt%) of (A) a polyolefin polymer; 0.1-10.0 wt% of a (B) a crotophenone compound; and 0.1-40 wt% total of at least one additive, each of the at least one additive being different from components (A) and (B) and independently selected from the group consisting of (C) an organic peroxide, (D) a scorch inhibitor, (E) an antioxidant, (F) a filler, (G) a flame retardant, (H) a hindered amine stabilizer, (I) a tree inhibitor, (J) a methyl radical scavenger, (K) a crosslinking coagent, (L) a processing aid, (M) a colorant, and a combination of any two or more of additives (C)-(M).

[0023] Aspect 6. A polyolefin formulation according to aspect 5, comprising: 85 to 99.5 weight percent (wt%) of an (A) polyolefin polymer that is a low density polyethylene polymer; 0.5 to 1.4 wt% of a (B) crotophenone compound that is a compound of formula (I) where Ar is phenyl and R is methyl; and 0.1 to 1.5 wt% of at least one (E) antioxidant.

[0024] Aspect 7. A method of making a polyolefin blend according to any one of aspects 1-6, comprising blending (A) a polyolefin polymer with (B) a crotophenone compound and optionally at least one additive to make a blend. The blend made may be a heterogeneous or homogeneous blend of components (A) and (B). The contacting step comprises contacting components (A) and (B) with one another (from a previously uncontacted state). The contacting step may further comprise blending the contacted (A) and (B) together to form a homogeneous mixture thereof. In some embodiments, the method further comprises blending at least one of optional additives (C)-(M) with (A) and (B). The blending may comprise melt blending component (B) and optionally one or more of additives (C)-(M) into a melt of component (A). The melt blending may be carried out in an extruder configured to melt blend the polyolefin and additives. The resulting molten blend can be extruded through a die to form strands and then pelletized to provide the polyolefin blend in pellet form, or the molten blend can be extruded through a die designed to form an article of manufacture that includes the polyolefin blend.

[0025] Aspect 8. A method of making a crosslinked polyolefin product, comprising subjecting a polyolefin formulation according to any one of aspects 1-6 to curing conditions to crosslink the (A) polyolefin polymer, thereby making a crosslinked polyolefin product. The curing conditions may include exposing the formulation to ultraviolet light or heating the formulation with (C) an organic peroxide and, optionally, (K) a crosslinking coagent. An embodiment of the method may include heating an embodiment of a polyolefin formulation according to any one of aspects 1-7 comprising (C) an organic peroxide and, optionally, (K) a crosslinking coagent to crosslink the (A) polyethylene polymer, thereby making a crosslinked polyolefin product. When no (K) crosslinking coagent is used, crosslinking comprises forming covalent carbon-carbon bonds between molecules of the (A) polyolefin polymer. When a (K) crosslinking coagent is included, crosslinking comprises forming covalent carbon-carbon bonds between molecules of the (A) polyolefin polymer and forming covalent carbon-carbon bonds between molecules of the (K) crosslinking coagent and molecules of the (A) polyolefin polymer.

[0026] Aspect 9. A crosslinked polyolefin product produced by the method of aspect 8. The crosslinked polyolefin product has increased dielectric breakdown strength compared to the crosslinked (A) polyolefin polymer without the (B) crotophenone compound. The crosslinked polyolefin product may comprise (A) polyolefin polymer or (A') crosslinked (networked) polyethylene polymer produced by crosslinking (A) polyolefin polymer with (K) crosslinking coagent and (B) crotophenone compound of formula (I). The crosslinked polyolefin product may further comprise at least one additive selected from (E) antioxidant, (F) filler, (G) flame retardant, (H) hindered amine stabilizer, (I) tree inhibitor, (J) methyl radical scavenger, (L) nucleating agent, and (M) colorant (e.g., carbon black or titanium dioxide). The crosslinked polyolefin product has increased dielectric breakdown strength compared to the crosslinked (A) polyolefin polymer without the (B) crotophenone compound.

[0027] Aspect 10. An article comprising the polyolefin formulation according to any one of aspects 1-6 or the crosslinked polyolefin product according to aspect 9. The article has increased dielectric breakdown strength compared to an article not containing (B) the crotophenone compound. In some aspects, the article of manufacture is selected from coatings, films, sheets, extruded articles (not pellets), and injection molded articles. For example, coated conductors, insulation layers for wires and cables for power transmission or communication, agricultural films, automotive parts, containers, food packaging, garment bags, grocery bags, heavy duty bags, industrial sheets, pallets and shrink wrap, bags, buckets, freezer containers, lids, toys. The article of manufacture has increased dielectric breakdown strength compared to a crosslinked host polyolefin not containing (B) the crotophenone compound.

[0028] Aspect 11. A coated conductor comprising a conductive core and an insulating layer at least partially covering the conductive core, wherein at least a portion of the insulating layer comprises the crosslinked polyolefin product of aspect 9. The coated conductor and its insulating layer have increased dielectric breakdown strength relative to a coated conductor and its insulating layer formed from (A) a polyolefin polymer that does not contain (B) a crotophenone compound. The conductive core may be a wire having a proximal end and a distal end, at least one of which may not include an insulating layer.

[0029] A method of transmitting electricity comprising applying a voltage across the conductive core of the coated conductor of Aspect 10 to cause a flow of electricity through the conductive core. Also contemplated is a method of transmitting data using the coated conductors of the present invention comprising insulated conductors.

[0030] Aspect 13. The invention of any one of aspects 1-12, wherein the polyolefin blend has an improvement (increase) in dielectric breakdown strength value eta, η of at least +10.0 percent (%) compared to the (A) polyolefin polymer not containing a voltage stabilizer, the dielectric breakdown strength value eta, η at a failure probability value of 63.2% being determined using Weibull statistics according to the dielectric breakdown strength test method described herein. In some embodiments, the improvement (increase) in dielectric breakdown strength value eta, η (at a failure probability value of 63.2%) of the invention compared to the (A) polyolefin polymer not containing a voltage stabilizer (e.g., compared to Comparative Example 0 (CE0) described in the Examples below) is at least +15%, alternatively at least +21%, alternatively at least +25%, alternatively at least +31%, alternatively at least +35%, alternatively at least +41%, alternatively at least +45%. In some embodiments, the improvement in the dielectric breakdown strength value eta, η (at a failure probability value of 63.2%) of the present invention compared to the (A) polyolefin polymer not containing a voltage stabilizer (e.g., compared to CE0) is further characterized as being up to 75%, alternatively up to +65%, alternatively up to +59%, alternatively up to 55%. In some embodiments, the improvement in the dielectric breakdown strength value eta, η (at a failure probability value of 63.2%) of the present invention compared to the (A) polyolefin polymer not containing a voltage stabilizer (e.g., compared to CE0) is +10.0% to +54.0%, alternatively +21% to +52, alternatively +23% to +51%. In some embodiments, the improvement in the dielectric breakdown strength value eta, η (at a failure probability value of 63.2%) of the present invention compared to the (A) polyolefin polymer not containing a voltage stabilizer (e.g., compared to CE0) is +24%±5%, alternatively +50%±9%. Alternatively, the improvement in dielectric breakdown strength of the present invention may be any one of the aforementioned percentage values ​​compared to an eta, η, of 18.49 (18.5) kV / mm (at a failure probability value of 63.2%). In some embodiments, the crosslinked polyolefin product made from the polyolefin blend has any one of the aforementioned improvements in dielectric breakdown strength value, eta, η, (at a failure probability value of 63.2%) of the present invention.The aforementioned dielectric strength improvement values ​​eta, η (for a failure probability value of 63.2%) are all determined according to the dielectric strength test method described below. In some embodiments, the values ​​eta, η (for a failure probability value of 63.2%) are further characterized by a 90% confidence level beta, β, determined according to the dielectric strength test method and Weibull statistical method described below.

[0031] The coated conductor may be a power cable having a proximal end and a distal end, and electricity may flow from the proximal end to the distal end through a conductive core, or vice versa. The conductive core may be a wire. The power cable may be a medium-voltage (MV), high-voltage (HV), or extra-high-voltage (EHV) power cable. The power cable is useful in power transmission applications.

[0032] (A) Polyolefin polymers. They are composed of polyethylene macromolecules containing, independently, at least 5, or alternatively 10 to 200,000 constitutional units derived from the polymerization of ethylene and zero, one, or more other olefin-functional monomers. (A) Polyolefin polymers have a molecular weight of 0.870 to 0.975 grams per cubic centimeter (g / cm 3 ), or 0.890 to 0.930 g / cm 3 (e.g. LDPE or LLDPE), or 0.910-0.930 g / cm 3 (e.g., LDPE or LLDPE), or 0.931 to 0.945 g / cm 3 (e.g. MDPE), or 0.945-0.970g / cm 3 (e.g., HDPE), all measured in accordance with ASTM D792-13, Method B.

[0033] Polyethylene may be a homopolymer or a copolymer. A homopolymer is made by polymerizing only ethylene. A copolymer is made by polymerizing at least two different olefin monomers, one of which is ethylene. A copolymer may be a bipolymer made by polymerizing ethylene and one olefin monomer, a terpolymer made by polymerizing ethylene and two different olefin monomers, or a tetrapolymer made by polymerizing ethylene and three different olefin monomers. Polyolefins that are copolymers may be block copolymers or random copolymers.

[0034] (A) Examples of olefin-functional monomers used to make polyolefin polymers are ethylene, propene, (C4-C 20 ) alpha-olefins, cyclic alkenes (e.g., norbornene), dienes (e.g., 1,3-butadiene), unsaturated carboxylic acid esters, and olefin-functional hydrolyzable silanes. (C4-C 20 Examples of alpha-olefins include (C4-C8) alpha-olefins such as 1-butene, 1-hexene, or 1-octene, and (C 10 ~C 20 ) alpha-olefins. An example of a diene is 1,3-butadiene. Examples of unsaturated carboxylic acid esters are alkyl acrylates, alkyl methacrylates, and vinyl carboxylates (e.g., vinyl acetate). Examples of olefin-functional hydrolyzable silanes are vinyltrialkoxysilanes, vinyltris(dialkylamino)silanes, and vinyl(trioximo)silanes.

[0035] In some embodiments, (A) the polyolefin polymer is an ethylene-based polymer. The ethylene-based polymer comprises 51 to 100 weight percent ethylene units derived from the polymerization of ethylene and 49 to 0 weight percent comonomer units derived from the polymerization of one or two olefin-functional monomers (comonomers). The comonomers include propylene, (C4 to C6 20) alpha-olefins, and 1,3-butadiene. (C4-C 20 The alpha-olefin may be a (C4-C8) alpha-olefin such as 1-butene, 1-hexene, or 1-octene.

[0036] Examples of suitable ethylene-based polymers include polyethylene homopolymers, ethylene / (C4-C 20 ) alpha-olefin copolymers, ethylene / propylene copolymers, ethylene / propylene / diene monomer (EPDM) copolymers, such as ethylene / propylene / 1,3-butadiene terpolymers, and ethylene / 1-butene / styrene copolymers. 20Examples of alpha-olefin copolymers are ethylene / 1-butene copolymer, ethylene / 1-hexene copolymer, and ethylene / 1-octene copolymer. The ethylene-based polymer can be ultra-low-density polyethylene (ULDPE), very low-density polyethylene (VLDPE), linear low-density polyethylene (LLDPE), low-density polyethylene (LDPE), medium-density polyethylene (MDPE), high-density polyethylene (HDPE), or ultra-high-density polyethylene (UHDPE). Many of the ethylene-based polymers are sold by The Dow Chemical Company under trade names such as AFFINITY, ATTANE, DOWLEX, ENGAGE, FLEXOMER, or INFUSE. Other ethylene-based polymers are sold by other suppliers under trade names such as TAFMER, EXCEED, and EXACT. LDPE and LLDPE are compositionally different due to how they are made under different polymerization conditions: LDPE is made in a high pressure polymerization reactor in the presence of a free radical initiator (peroxide or O2) and without an olefin polymerization catalyst, whereas LLDPE is made in a standard pressure polymerization reactor in the presence of an olefin polymerization catalyst and in the absence of a free radical initiator.

[0037] In some embodiments, the (A) polyolefin polymer is a polyethylene homopolymer, e.g., low density polyethylene (LDPE). All of its constituent units are ethylenic repeat units. LDPE can be produced by polymerizing ethylene in a high pressure reactor in the absence of a metal-based polymerization catalyst and in the presence of a small amount (e.g., 0.3-0.4 wt%) of a free radical initiator (e.g., a peroxide or mixture of peroxides or O2) and 1 wt% of a chain transfer agent, which is propylene.

[0038] In some embodiments, the (A) polyolefin polymer consists of only one ethylene-based polymer (e.g., only LLDPE, or only LDPE, or only MDPE, or only HDPE). In some embodiments, the (A) polyolefin polymer consists of LDPE. When the (A) polyolefin polymer consists of LDPE, in some such embodiments, the polyolefin blend may not include any organic polymers other than LDPE.

[0039] Alternatively, the (A) polyolefin polymer may be an ethylene / alpha-olefin copolymer. The ethylene / alpha-olefin copolymer may be an ethylene / 1-butene copolymer, an ethylene / 1-hexene copolymer, an ethylene / 1-octene copolymer, or a blend of any two thereof. Ethylene / (C4-C 20 The constituent units of the alpha-olefin copolymer are composed of 51 to 99.9% by weight of constituent units derived from ethylene and 49 to 0.1% by weight of constituent units derived from an alpha-olefin.

[0040] The (A) polyolefin polymer may be an ethylene / propylene copolymer, the constituent units of which are composed of ethylene monomer units, propylene comonomer units, and, optionally, diene comonomer units.

[0041] The (A) polyolefin polymer may be an ethylene / (unsaturated carboxylic acid ester) copolymer. The unsaturated carboxylic acid ester is vinyl acetate, an alkyl acrylate, or an alkyl methacrylate.

[0042] The (A) polyolefin polymer may be an ethylene / (monocyclic organosiloxane) copolymer. The monocyclic organosiloxane is represented by the formula (II): [R 1 ,R 2 SiO 2 / 2 ] n (II), wherein the subscript n is an integer equal to or greater than 3, and each R 1 are independently (C2-C4) alkenyl or H2C=C(R 1a )-C(=O)-O-(CH2) m -, wherein R 1a is H or methyl, the subscript m is an integer from 1 to 4, and each R 2 are independently H, (C1-C4) alkyl, phenyl, or R 1 It is.

[0043] The (A) polyolefin polymer may comprise a blend of two or more different ethylene-based polymers. In some embodiments, the two or more different ethylene-based polymers of the blend comprise at least one LDPE.

[0044] In some embodiments, the (A) polyolefin polymer comprises a low density polyethylene (LDPE) polymer. The LDPE polymer is made by polymerizing ethylene in a high pressure reactor in the absence of a metal-based polymerization catalyst and in the presence of small amounts of a free radical initiator (e.g., peroxide or O2) and a chain transfer agent (CTA). The CTA may be propylene, which may be used at 1 wt. % based on the total weight of ethylene and propylene in the high pressure reactor. The LDPE polymer has a viscosity of 0.910-0.930 g / cm. 3 and a melt index (I2) of 1.0 to 5 g / 10 min. The LDPE polymer may be LDPE-1 as described in the examples.

[0045] The polyolefin blend may comprise 60.0 to 99.9 wt.% of the (A) polyolefin polymer, alternatively 70.0 to 99.9 wt.% of the (A) polyolefin polymer, alternatively 85.0 to 99.9 wt.% of the (A) polyolefin polymer, alternatively 90.0 to 99.9 wt.% of the (A) polyolefin polymer, all based on the total weight of the polyolefin blend.

[0046] (B) Clotophenone Compound. (B) Clotophenone compound has the formula (I):

[0047] [ka] wherein Ar is phenyl, alkylphenyl, 1-naphthyl, or 2-naphthyl, and R is (C1-C5) alkyl, (C6-C 10 ) alkyl, (C 11 ~C 20 ) alkyl, or (C 21 ~C 40 In some embodiments, R is (C1-C 40 ) alkyl. The structure of formula (I) is drawn to show opposite (E) double bond configurations, but also includes same-side (Z) double bond configurations. Thus, formula (I) can be conveniently written as Ar-C(=O)-CH=CHR(I). In some embodiments, the geometry is (E), alternatively (Z), or a mixture of (E) and (Z).

[0048] Alkylphenyl is a group consisting of 1 to 5 (C1 to C 20 ) alkyl groups. Alkylphenyl is a phenyl group independently substituted with an alkyl group. Alkylphenyl is an alkylphenyl group independently substituted with an alkyl group. 20) alkylphenyl, or a combination thereof. (C1) Examples of alkylphenyl (i.e., methylphenyl) include 4-methylphenyl, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,4,5-trimethylphenyl, and 2,3,4,t-tetramethylphenyl. (C2-C 20 Examples of alkylphenyl include 4-ethylphenyl, 4-hexylphenyl, 4-decylphenyl, and 4-nonadecylphenyl. An example of a combination is 2-methyl-4-hexylphenyl.

[0049] (B) In another embodiment of the clotophenone compounds of formula (I), Ar is 1-naphthyl and R is (C1-C5) alkyl or (C2-C5) alkyl. In another embodiment, Ar is 1-naphthyl and R is (C6-C 10 In another embodiment, Ar is 1-naphthyl and R is (C1-C 20 In other embodiments, Ar is 1-naphthyl and R is (C 21 ~C 40 ) alkyl.

[0050] (B) In another embodiment of the clotophenone compounds of formula (I), Ar is 2-naphthyl and R is (C1-C5) alkyl or (C2-C5) alkyl. In another embodiment, Ar is 2-naphthyl and R is (C6-C 10 In another embodiment, Ar is 2-naphthyl and R is (C1-C 20 In other embodiments, Ar is 2-naphthyl and R is (C 21 ~C 40 ) alkyl.

[0051] (B) In another embodiment of the clotophenone compounds of formula (I), Ar is phenyl and R is (C1-C5) alkyl or (C2-C5) alkyl. In another embodiment, Ar is phenyl and R is (C6-C 10In another embodiment, Ar is phenyl and R is (C1-C 20 In other embodiments, Ar is phenyl and R is (C 21 ~C 40 ) alkyl.

[0052] (B) The crotophenone compound may be a compound of formula (1), wherein Ar is phenyl and R is (C 40 ) alkyl.

[0053] The (B) clotophenone compound may itself be clotophenone, a compound of formula (I) where Ar is phenyl and R is methyl, referred to herein as (B)-1 clotophenone 1.

[0054] A representative comparative compound (CE1), compounds of the present invention ((B)-1 to (B)-11), and their Ar and R groups, ALogP values, and electron affinities ("EA") and HOMO-LUMO gaps ("HL"), both in electron volts (eV), are shown below in Table A. HOMO means highest occupied molecular orbital and LUMO means lowest unoccupied molecular orbital.

[0055] [Table 1-1]

[0056] [Table 1-2] (1) Expected value based on (B)-1 to (B)-8.

[0057] As shown in Table A, clotophenone itself is used in the examples of the present invention and is believed to be representative of the compounds of formula (I). This belief is based on (1) the structural similarity of the Ar groups in formula (I) - all Ar groups are phenyl or (C4-C9) hydrocarbyl substituted phenyl, (2) the similarity of the effect of the R groups on (A) the compatibility of the compounds of formula (I) for absorption into polyolefin polymers, as characterized by their atom-based logP octanol / water partition coefficient ("ALogP") values ​​- all compounds of formula (I) have an ALogP of 2.6 or greater, and (3) the similarity of their electronic properties, electron affinities, and HOMO-LUMO gaps - all compounds of formula (I) have an electron affinity of 1.57 electron volts (eV) or slightly higher and a HOMO-LUMO gap of 4.8 eV or slightly higher. Atom-based logP (ALogP) values ​​can be determined according to the method of Ghose, A. K., Viswanadhann V. N., and Wendoloski, J. J., Prediction of Hydrophobic (Lipophilic) Properties of Small Organic Molecules Using Fragment Methods: An Analysis of AlogP and CLogP Methods. J. Phys. Chem. A, 1998, 102, 3762-3772.

[0058] Based on Table A, the Ar groups based on phenyl or substituted phenyl and unsubstituted (C1-C 40Compounds of formula (I) having an R group that is alkyl have an ALogP of greater than 2.6, an electron affinity of about 1.6 electron volts, e.g., 1.57-1.59 electron volts, and a HOMO-LUMO gap of about 4.8 electron volts, and therefore (B) crotophenone compounds are believed to effectively bind with (A) polyolefin polymers and the resulting polyolefin blends have a voltage stabilizing effect. In contrast, if a compound has an ALogP of less than 2.3, an electron affinity significantly different from about 1.6 electron volts (e.g., if such a compound has an electron affinity of about 1.3 electron volts), and / or a HOMO-LUMO gap significantly different from about 4.8 electron volts (e.g., if such a compound has a HOMO-LUMO gap of about 4.6 electron volts), such a compound will not effectively bind within or with (A) polyolefin polymers and / or the resulting polyolefin blends will not have a voltage stabilizing effect.

[0059] In contrast, the comparative compound 2',4'-dihydroxycrotophenone has an ALogP of 2.19, which is too low for compatibility with (A) polyolefin polymers, and an electron affinity of 1.25 eV and a HOMO-LUMO gap of 4.51 eV, which is considered too low for voltage stabilization effects. For 2',4'-dihydroxycrotophenone (compound "C1"), there is a significant change in the electronic properties (electron affinity and HOMO-LUMO gap), which indicates that the dielectric strength may not be the same as crotophenone. And it is likely to be worse. Other experimental data shows that adding one -OH group to benzophenone worsens the dielectric strength.

[0060] Without wishing to be bound by theory, the inclusion of any of the heteroatom substituents such as O, N, P, or S on the Ar or R groups of crotophenone, particularly proton heteroatom substituents such as -OH, -NH, -NH2, -POH, or -SH, or the replacement of a carbon atom of crotophenone with a heteroatom such as O, N, P, or S, is expected to result in a comparative heteroatom-containing crotophenone which is expected to have poor or no voltage stabilizing effect, which may be due directly to its structure and / or indirectly to its lower affinity for the (A) polyolefin polymer.

[0061] The polyolefin formulations and crosslinked polyolefin products made therefrom may be free of any voltage stabilizer compound other than the (B) crotophenone compound of formula (I), or alternatively, the polyolefin formulations and crosslinked polyolefin products made therefrom may contain a second voltage stabilizer compound different from the (B) crotophenone compound of formula (I).

[0062] The polyolefin blends and crosslinked polyolefin products made therefrom may contain from 0.1 to 10.0 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 0.2 to 5.0 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 0.3 to 2.0 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 0.4 to 1.4 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 0.45 to 1.04 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 0.5±0.1 wt. % of the crotophenone compounds of formula (I) (B), alternatively from 1.0±0.2 wt. % of the crotophenone compounds of formula (I) (B), all based on the total weight of the polyolefin blend or the total weight of the crosslinked polyolefin product, respectively.

[0063] Component (C) organic peroxide: a molecule or collection of such molecules that contains carbon, hydrogen, and two or more oxygen atoms and has at least one -OO- group, with the proviso that when there is more than one -OO- group, each -OO- group is indirectly bonded to another -OO- group through one or more carbon atoms. The (C) organic peroxide may be added to the polyolefin formulation for curing, which comprises heating the polyolefin formulation containing components (A), (B), and (C) to a temperature at or above the decomposition temperature of the (C) organic peroxide. The (C) organic peroxide is represented by the formula R O -OOR O where each R O are independently 20 ) alkyl group, or (C6-C 20 ) an aryl group. 20 ) alkyl groups are independently unsubstituted or have one or two (C6-C 12 ) substituted with an aryl group. 20 The aryl group is unsubstituted or has 1 to 4 (C 10 ) alkyl group. Alternatively, (C) is a group of formula R O -OOROOR O [In the formula, R is (C2 to C 10 ) alkylene, (C3-C 10 ) a divalent hydrocarbon group such as cycloalkylene or phenylene, and each R O(C) The organic peroxide may be a diperoxide of bis(1,1-dimethylethyl)peroxide, bis(1,1-dimethylpropyl)peroxide, 2,5-dimethyl-2,5-bis(1,1-dimethylethylperoxy)hexane, 2,5-dimethyl-2,5-bis(1,1-dimethylethylperoxy)hexyne, 4,4-bis(1,1-dimethylethylperoxy)valeric acid, butyl ester, 1,1-bis(1,1-dimethylethylperoxy)-3,3,5-trimethylcyclohexane, benzoyl peroxide, tert-butyl peroxybenzoate, di-tert-amyl peroxide ("DTAP"), bis(alanine), ... (C) The organic peroxide may be di-t-butyl-peroxyisopropyl)benzene ("BIPB"), isopropyl cumyl t-butyl peroxide, t-butyl cumyl peroxide, di-t-butyl peroxide, 2,5-bis(t-butylperoxy)-2,5-dimethylhexane, 2,5-bis(t-butylperoxy)-2,5-dimethylhexyne-3,1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, isopropyl cumyl cumyl peroxide, butyl 4,4-di(tert-butylperoxy)valerate, or di(isopropyl cumyl)peroxide, or dicumyl peroxide. (D) The organic peroxide may be dicumyl peroxide. In some embodiments, only a blend of two or more (C) organic peroxides is used, such as a 20:80 (w / w) blend of t-butylcumyl peroxide and bis(t-butylperoxyisopropyl)benzene (e.g., LUPEROX D446B available from Arkema). In some embodiments, at least one, or each (C) organic peroxide contains one -OO- group. The (C) organic peroxide can be 0.29-0.44 wt. %, alternatively 0.30-39 wt. %, alternatively 0.30-0.37 wt. % of the carrier mixture, or alternatively of the polyolefin formulation.

[0064] Optional Component (D) Scorch Inhibitor: A molecule or collection of such molecules that inhibits premature curing. Examples of scorch inhibitors are hindered phenols, semi-hindered phenols, TEMPO, TEMPO derivatives, 1,1-diphenylethylene, 2,4-diphenyl-4-methyl-1-pentene (also known as alpha-methylstyrene dimer or AMSD), and allyl-containing compounds as described in U.S. Pat. No. 6,277,925 B1, column 2, line 62 to column 3, line 46. In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not include (D). When present, (D) scorch inhibitor can be 0.01 to 1.5 wt. % of the polyolefin formulation, alternatively 0.05 to 1.2 wt. %, alternatively 0.1 to 1.0 wt. %.

[0065] Optional Component (E) Antioxidant: An organic molecule, or collection of such molecules, that inhibits oxidation. (E) Antioxidants function to provide antioxidant properties to the polyolefin formulation and / or crosslinked polyolefin product. Examples of suitable (E) are bis(4-(1-methyl-1-phenylethyl)phenyl)amine (e.g., NAUGARD 445), 2,2'-methylene-bis(4-methyl-6-t-butylphenol) (e.g., VANOX MBPC), 2,2'-thiobis(2-t-butyl-5-methylphenol) (CAS number 90-66-4, 4,4'-thiobis(2-t-butyl-5-methylphenol) (also known as 4,4'-thiobis(6-tert-butyl-m-cresol)), CAS number 96-69-5, commercially available LOWINOX TBM-6), 2,2'-thiobis(6-t-butyl-4-methylphenol) (CAS number 90-66-4, commercially available LOWINOX TBM-6), TBP-6), tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazine-2,4,6-trione) (e.g., CYANOX 1790), pentaerythritol tetrakis(3-(3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl)propionate (e.g., IRGANOX 1010, CAS number 6683-19-8), 3,5-bis(1,1-dimethylethyl)-4-hydroxybenzenepropanoic acid 2,2'-thiodiethanediyl ester (e.g., IRGANOX 1035, CAS number 41484-35-9), distearyl thiodipropionate ("DSTDP"), dilauryl thiodipropionate (e.g., IRGANOX PS800), stearyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (e.g., IRGANOX 1076), 2,4-bis(dodecylthiomethyl)-6-methylphenol (IRGANOX 1726), 4,6-bis(octylthiomethyl)-o-cresol (e.g., IRGANOX 1520), and 2',3-bis[[3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl]]propionohydrazide (IRGANOX 1024).In some embodiments, (E) is 4,4'-thiobis(2-t-butyl-5-methylphenol) (also known as 4,4'-thiobis(6-tert-butyl-m-cresol)), 2,2'-thiobis(6-t-butyl-4-methylphenol, tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazine-2,4,6-trione, distearyl thiodipropionate, or dilauryl thiodipropionate, or any two thereof. The above combinations. The combination can be tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazine-2,4,6-trione and distearyl thiodipropionate. In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not include (E). When present, the (E) antioxidant can be 0.01 to 1.5 wt. %, alternatively 0.05 to 1.2 wt. %, alternatively 0.1 to 1.0 wt. % of the polyolefin formulation.

[0066] Optional Component (F) Filler: A finely divided particulate solid or gel that occupies space in the host material and optionally affects the function of the host material. The (F) filler may be a calcined clay, an organoclay, or a hydrophobized fumed silica, such as that available from Cabot Corporation under the trade name CAB-O-SIL. The (F) filler may have a flame retardant effect. In some embodiments, the polyolefin formulation and the crosslinked polyolefin product do not include (F). When present, the (F) filler may be 1 to 40% by weight, alternatively 2 to 30% by weight, alternatively 5 to 20% by weight of the polyolefin formulation.

[0067] Optional Component (G) Flame Retardant: A molecule or substance that inhibits combustion, or an aggregate of such molecules. (G) may be a halogenated or halogen-free compound. (G) Examples of halogenated (G) flame retardants are organic chlorides and organic bromides, and examples of organic chlorides are chlorendic acid derivatives and chlorinated paraffins. Examples of organic bromides are polymeric brominated compounds such as decabromodiphenyl ether, decabromodiphenyl ethane, brominated polystyrene, brominated carbonate oligomers, brominated epoxy oligomers, tetrabromophthalic anhydride, tetrabromobisphenol A, and hexabromocyclododecane. Typically, halogenated (G) flame retardants are used in combination with a synergist to improve their efficiency. The synergist may be antimony trioxide. Examples of halogen-free (G) flame retardants are inorganic minerals, organic nitrogen intumescent compounds, and phosphorus-based intumescent compounds. Examples of inorganic minerals are aluminum hydroxide and magnesium hydroxide. Examples of phosphorus-based expanding compounds are organic phosphonic acids, phosphonates, phosphinates, phosphonites, phosphinites, phosphine oxides, phosphines, phosphites, phosphates, phosphorus nitrile chlorides, phosphoramidates, phosphoric acid amides, phosphonic acid amides, phosphinic acid amides, melamine and their melamine derivatives including melamine polyphosphate, melamine pyrophosphate and melamine cyanurate, and mixtures of two or more of these materials.Examples include phenyl bis dodecyl phosphate, phenyl bis neopentyl phosphate, phenyl ethylene hydrogen phosphate, phenyl bis-3,5,5' trimethylhexyl phosphate), ethyl diphenyl phosphate, 2 ethylhexyl di(p-tolyl) phosphate, diphenyl hydrogen phosphate, bis(2-ethyl-hexyl) para-tolyl phosphate, tritolyl phosphate, bis(2-ethylhexyl)-phenyl phosphate, tri(nonylphenyl) phosphate, phenylmethyl hydrogen phosphate, di(dodecyl) p-tolyl phosphate, tricresyl phosphate, triphenyl phosphate, triphenyl phosphate, dibutylphenyl phosphate, 2-chloroethyl diphenyl phosphate, p-tolyl bis(2,5,5'-trimethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, and diphenyl hydrogen phosphate. The types of phosphate esters described in U.S. Patent No. 6,404,971 are examples of phosphorus-based flame retardants. Additional examples include liquid phosphates such as bisphenol A diphosphate (BAPP) (Adeka Palmarole) and / or resorcinol bis(diphenyl phosphate) (Fyroflex RDP) (Supresta, ICI), solid phosphorus such as ammonium polyphosphate (APP), piperazine pyrophosphate, and piperazine polyphosphate. Ammonium polyphosphate is often used with flame retardant co-additives such as melamine derivatives. Melafine (DSM) (2,4,6-triamino-1,3,5-triazine, finely divided melamine) is also useful. In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not include (G). When present, (G) can be at a concentration of 0.01 to 70% by weight of the polyolefin formulation, alternatively 0.05 to 40% by weight, alternatively 1 to 20% by weight.

[0068] Optional component (H) hindered amine stabilizer: a molecule or collection of such molecules containing a basic nitrogen atom that is bonded to at least one sterically bulky organic group and functions as an inhibitor of degradation or decomposition. (H) is a compound that has a sterically hindered amino functional group and can inhibit oxidative degradation and increase the shelf life of the polyolefin formulation embodiment containing (C) organic peroxide. Examples of suitable (H) are butanedioic acid dimethyl ester, polymer with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidine-ethanol (CAS number 65447-77-0, commercially available LOWILITE62), and N,N'-bisformyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-hexamethylenediamine (CAS number 124172-53-8, commercially available Uvinul 4050H). In some aspects, the polyolefin formulation and crosslinked polyolefin product do not contain (H). When present, the (H) hindered amine stabilizer may be from 0.001 to 1.5 wt %, alternatively from 0.002 to 1.2 wt %, alternatively from 0.002 to 1.0 wt %, alternatively from 0.005 to 0.5 wt %, alternatively from 0.01 to 0.2 wt %, alternatively from 0.05 to 0.1 wt % of the polyolefin formulation.

[0069] Optional Component (I) Tree Suppressant: A molecule or collection of such molecules that inhibits water and / or electrical treeing. The tree suppressant may be a water tree suppressant or an electrical tree suppressant. Water tree suppressants are compounds that inhibit water treeing, a process that degrades polyolefins when exposed to the combined effects of an electric field and moisture or water. Electrical tree suppressants, also called voltage stabilizers, are compounds that inhibit electrical treeing, an electrical pre-breakdown process in solid electrical insulation resulting from partial discharge. Electrical treeing can occur in the absence of water. Water treeing and electrical treeing are problems for electrical cables containing coated conductors, where the coating contains a polyolefin. (I) may be poly(ethylene glycol) (PEG). In some embodiments, the polyolefin formulation and crosslinked polyolefin products do not include (I). When present, (I) tree suppressant may be 0.01 to 1.5 wt. % of the polyolefin formulation, alternatively 0.05 to 1.2 wt. %, alternatively 0.1 to 1.0 wt. %.

[0070] Optional Component (J) Methyl Radical Scavenger: A molecule or aggregate of such molecules that reacts with methyl radicals. (J) reacts with methyl radicals in the polyolefin blend or crosslinked polyolefin product. (J) can be 2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl or a "TEMPO" derivative of 1,1-diarylethylene. Examples of TEMPO derivatives are 4-acryloxy-2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl (CAS number 21270-85-9, "acrylate TEMPO"), 4-allyloxy-2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl (CAS number 217496-13-4, "allyl TEMPO"), bis(2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl)sebacate ... Examples of 1,1-diarylethylenes are 1,1-diphenylethylene and alpha-methylstyrene. In some embodiments, the polyolefin formulation and crosslinked polyolefin product are free of (J). When present, the (J) methyl radical scavenger can be 0.01 to 1.5 wt. % of the polyolefin formulation, alternatively 0.05 to 1.2 wt. %, alternatively 0.1 to 1.0 wt. %.

[0071] Optional Component (K) Crosslinking Coagent: A molecule containing a backbone or ring substructure and one or more propenyl, acrylate, and / or vinyl groups attached thereto, the substructure being composed of carbon atoms and optionally nitrogen atoms, or an aggregate of such molecules. The (K) crosslinking coagent does not contain silicon atoms. The (K) crosslinking coagent may be a conventional coagent of propenyl functionality as described by any one of the following constraints (i)-(v): (i) (K) is 2-allylphenyl allyl ether, 4-isopropenyl-2,6-dimethylphenyl allyl ether, 2,6-dimethyl-4-allylphenyl allyl ether, 2-methoxy-4-allylphenyl allyl ether, 2,2'-diallyl bisphenol A, O,O'-diallyl bisphenol A, or tetraaryl ether. (ii) (K) is 2,4-diphenyl-4-methyl-1-pentene or 1,3-diisopropenylbenzene; (iii) (K) is triallyl isocyanurate ("TAIC"), triallyl cyanurate ("TAC"), triallyl trimellitate ("TATM"), N,N,N',N',N",N"-hexaallyl-1,3,5-triazine-2,4,6-triamine ("HATATA", N 2 ,N 2 ,N 4 ,N 4 ,N 6 ,N 6(iv) (K) is a mixture of any two of the propenyl-functional coagents in (i). Alternatively, (K) may be an acrylate-functional coagent selected from trimethylolpropane triacrylate ("TMPTA"), trimethylolpropane trimethylacrylate ("TMPTMA"), ethoxylated bisphenol A dimethacrylate, 1,6-hexanediol diacrylate, pentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, tris(2-hydroxyethyl)isocyanurate triacrylate, and propoxylated glyceryl triacrylate. Alternatively, (K) may be a vinyl-functional coagent selected from polybutadiene having a 1,2-vinyl content of at least 50% by weight, and trivinylcyclohexane ("TVCH"). Alternatively, (K) may be a coagent described in U.S. Pat. No. 5,346,961 or U.S. Pat. No. 4,018,852. Alternatively, (K) may be a combination of the aforementioned coagents or any two or more thereof. In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not include (K). When present, the (K) coagent may be 0.01 to 4.5% by weight of the polyolefin formulation, alternatively 0.05 to 2% by weight, alternatively 0.1 to 1% by weight, alternatively 0.2 to 0.5% by weight.

[0072] Optional Component (L) Processing Aid: (A) An organic or organosiloxane additive that enhances the flowability of the melt of the polyolefin polymer during its extrusion. Examples of (L) are poly(fluoroethylene) polymers and polydimethylsiloxane. In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not contain (L). When present, (L) can be at a concentration of 0.01 to 1.5 wt. % of the polyolefin formulation, alternatively 0.05 to 1.2 wt. %, alternatively 0.1 to 1.0 wt. %.

[0073] Optional Component (M) Colorant (e.g., carbon black or TiO2). Carbon black: A microcrystalline form of quasicrystalline carbon with a high surface area to volume ratio, but lower than that of activated carbon. Examples of carbon black are furnace carbon black, acetylene carbon black, conductive carbon (e.g., carbon fiber, carbon nanotubes, graphene, graphite, and expanded graphite platelets). In some embodiments, the polyolefin formulation and crosslinked polyolefin product do not include (M). When present, (M) can be 0.01 to 40% by weight of the polyolefin formulation, alternatively 0.05 to 35% by weight, alternatively 0.1 to 20% by weight, alternatively 0.5 to 10% by weight, alternatively 1 to 5% by weight.

[0074] For the avoidance of doubt, (F) filler and (M) colorant are different.

[0075] In addition, the polyolefin formulation may further comprise one or more other optional additives independently selected from carrier resins, lubricants, slip agents, plasticizers, surfactants, extender oils, acid scavengers, and metal deactivators.

[0076] The crosslinked polyolefin product may also contain a curing by-product, such as (C) a by-product of the reaction of an organic peroxide with an alcohol and a ketone. If the polyolefin formulation further contains one or more of any optional additives or components, such as (E) an antioxidant, the crosslinked polyolefin product may also contain any one or more of the optional additives or components, such as (E), or one or more reaction products formed therefrom during the curing of the polyolefin formulation.

[0077] The crosslinked polyolefin product may be in a divided solid form or a continuous form. The divided solid form may include granules, pellets, powders, or a combination of any two or more thereof. The continuous form may be an article of manufacture, such as a molded part (e.g., an injection molded part) or an extruded part (e.g., a coated conductor or cable).

[0078] Coated conductor. A coated conductor may be an insulated conductor. An insulated conductor may be a coated metal wire or electric cable, including power cables for use in low voltage ("LV", >0 to <5 kilovolts (kV)), medium voltage ("MV", 5 to <69 kV), high voltage ("HV", 69 to 230 kV), or extra high voltage ("EHV", >230 kV) data transmission and electricity transmission / distribution applications. "Wire" means a single strand or filament of conductive material, e.g., a conductive metal such as copper or aluminum. "Cable" and "power cable" are synonymous and refer to an insulated conductor including at least one wire disposed within a covering, which may be referred to as a sheath, jacket (protective outer jacket), or coating. Insulated conductors may be designed and configured for use in medium voltage, high voltage, or extra high voltage applications. Examples of suitable cable designs are shown in US Pat. Nos. 5,246,783, 6,496,629, and 6,714,707.

[0079] An insulated conductor may include a conductor / transmission core and an outer single layer or multi-layer coating disposed therearound to protect and insulate the conductor / transmission core from the external environment. The conductor / transmission core may be comprised of one or more metal wires. When the conductor / transmission core houses two or more metal wires, the metal wires may be subdivided into individual wire bundles. Each wire in the conductor / transmission core, whether bundled or unbundled, may be individually coated with an insulating layer and / or the individual bundles may be coated with an insulating layer. The single layer or multi-layer coating (e.g., single or multi-layer coating, or sheath) functions primarily to protect or insulate the conductor / transmission core from the external environment, such as sunlight, water, heat, oxygen, other conductive materials (e.g., to prevent short circuits), and / or other corrosive substances (e.g., chemical gases).

[0080] The single or multi-layer coating from one insulated conductor to the next may be constructed differently depending on the intended use of each. For example, when viewed in cross-section, a multi-layer coating of an insulated conductor may be constructed sequentially to have the following components from its innermost layer to its outermost layer: an inner semiconducting layer, a cross-linked polyolefin insulating layer comprising a cross-linked polyolefin product (the cross-linked product of the present invention), an outer semiconducting layer, a metallic shield, and a protective sheath. The layers and sheath are circumferentially and coaxially (longitudinally) continuous. The metallic shield (ground) is coaxially continuous and either circumferentially continuous (layer) or discontinuous (tape or wire). Depending on the intended application, a multi-layer coating for an insulated optical fiber may omit the semiconducting layer and / or the metallic shield. The outer semiconducting layer, if present, may be constructed of a peroxide cross-linked semiconducting product bonded to or peelable from the cross-linked polyolefin layer.

[0081] In some embodiments, a method of making a coated conductor includes extruding a coating comprising a layer of a polyolefin formulation on a conductor / transmission core to obtain a coated core, and passing the coated core through a continuous vulcanization (CV) device configured with suitable CV conditions to cure the polyolefin formulation to obtain a coated conductor. The CV conditions include temperature, atmosphere (e.g., nitrogen gas), and line speed or duration of passage through the CV device. Suitable CV conditions can provide a coated conductor exiting the CV device, the coated conductor containing a crosslinked polyolefin layer formed by curing a layer of crosslinked polyolefin layer.

[0082] Dielectric Breakdown Strength (Dielectric Strength): The maximum electric field (applied voltage divided by electrode separation) that an electrically insulating material can withstand without experiencing a breakdown event, i.e., becoming conductive. Expressed in volts using standard electrode separations.

[0083] Any compound, composition, formulation, material, mixture, or reaction product herein may be free of any one of the chemical elements selected from the group consisting of H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Br, Rb, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, I, Cs, Ba, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, Bi, lanthanides, and actinides, provided that the compound, composition, formulation, material, mixture, or reaction product does not exclude any one of the chemical elements that are essentially required by the compound, composition, formulation, material, mixture, or reaction product (e.g., C and H required for polyethylene, or C, H, and O required for alcohol).

[0084] or precedes different embodiments. ANSI is the American National Standards Institute organization, headquartered in Washington, DC, USA. ASME is the American Society of Mechanical Engineers, headquartered in New York City, New York, USA. ASTM is the standards organization ASTM International, West Conshohocken, Pennsylvania, USA. Any comparative examples are used for illustrative purposes only and are not prior art. "Free of" or "lacking" means complete absence or undetectable. IEC is the International Electrotechnical Commission, 3 rue de Varemb, Case postale 131, CH-1211, Geneva 20, Switzerland, http: / / www.iec.ch. IUPAC is the International Union of Pure and Applied Chemistry, IUPAC Secretariat, Research Triangle Park, North Carolina, USA. The Periodic Table of the Elements is the IUPAC version of May 1, 2018. "May" gives permitted options, not required. "Operative" means functionally possible or effective. "Optional" means absent (or excluded) or present (or included). Properties can be measured using standard test methods and conditions. Ranges include endpoints, subranges, and integer and / or fractional values ​​subsumed therein, but integer ranges do not include fractional values. Room temperature: 23°C ± 1°C.

[0085] Unless otherwise stated, definitions of terms used herein are taken from the IUPAC Compendium of Chemical Technology ("Gold Book"), 2.3.3 edition, dated February 24, 2014.

[0086] In some embodiments, any one of the terms "comprising" or "comprises" may be replaced by the phrase "consisting essentially of" or "consists essentially of". The phrases "consisting essentially of" and "consists essentially of" are partially closed and mean that the polyolefin blend and crosslinked polyolefin products made therefrom do not include excluded materials. For example, the excluded materials may include any clotophenone compound that is not of formula (I). The use of the terms "comprises" or "comprising" when referring to the following materials or features does not negate the partially closed nature of "consisting essentially of" or "consists essentially of", but simply allows for any additional materials or features that are not expressly excluded by "consisting essentially of" or "consists essentially of". In some embodiments, any one of the terms "comprising" or "comprises" may be replaced by the phrase "consisting of" or "consists of." The phrases "consisting of" and "consists of" are closed ended and exclude any element or feature not expressly recited thereafter.

[0087] For the sake of brevity, only certain ranges are expressly disclosed herein. However, a range from any lower limit may be combined with any upper limit to describe a range not expressly described. A range from any lower limit may also be combined with any other lower limit to describe a range not expressly described, and similarly, a range from any upper limit may be combined with any other upper limit to describe a range not expressly described.

[0088] Density Test Method: Measured according to ASTM D792-13, Standard Test Method for Density and Specific Gravity (Relative Density) of Plastics by Displacement, Method B (for testing solid plastics in liquids other than water, e.g., liquid 2-propanol). Results are expressed in grams per cubic centimeter (g / cm 3 ) units.

[0089] Melt index (I2) is measured according to ASTM D1238-04 (190°C, 2.16 kg), Standard Test Method for Melt Flow Rate of Thermoplastics by Extrusion Plateometer, using the condition 190°C / 2.16 kilograms (kg), formerly known as "Condition E", also known as I2. Results are reported in grams dissolved per 10 minutes (g / 10 min) or the equivalent in decigrams per 1.0 minute (dg / 1 min). 10.0 dg = 1.00 g.

[0090] Embodiments of the invention may be tested according to the following dielectric breakdown strength test method. For clarity, the method description is divided into sections 1-3. Section 1 addresses materials used to prepare the test assembly. Section 2 addresses procedures for preparing a test plaque representing the insulating layer and preparing the test assembly. The test assembly includes a sandwich of a test plate representing the insulating layer and two conductor disks, with the test plate (insulating layer) disposed between the conductor disks. Section 3 addresses procedures for applying increasing test voltages to the test assembly and detecting a dielectric breakdown event in the insulating layer.

[0091] Section 1: Dielectric Breakdown Strength Test Method (Materials): The conductors are multiple 40 millimeter (mm) diameter aluminum disks and multiple 29 mm diameter aluminum disks, each disk 75 micrometers thick. A test insulation layer is sandwiched between the conductors such that the total thickness of the sandwich is 350-500 micrometers. After breakdown, the Al disks are removed and the thickness of the insulation layer is measured at the location of the breakdown.

[0092] Section 2: Dielectric Breakdown Strength Test Method (Procedure for Assembling Electrodes and Test Plaques into a Test Assembly). Prepare a sample of the test insulation layer in a two-step thermoforming process. Step 1: Weigh the polymer pellets. Place the weighed pellets in a compression mold (8 inch x 8 inch square compression molding frame, thickness about 150 to about 900 micrometers). Preheat the polymer pellets to 140°C under about 7 pounds per square inch (psi) for 3 minutes. At the same temperature, switch to high pressure of about 382 psi and hold for 3 minutes. Under the same pressure, cool the resulting polymer plaque to room temperature within about 15 minutes. Step 2: Cut out multiple conductive aluminum (Al) disks of 29 mm and 40 mm diameter from a 75 micrometer thick aluminum sheet. Place the conductive Al disks above and below the plaque (prepared in step 1), with the 29 mm diameter disk on one side and the 40 mm diameter disk on the other side. The two conductive Al disks face each other and are arranged approximately concentrically with each other. A 3x3 array of nine pairs of such conductive Al disks are spaced on each side of an 8"x8" polymer plaque. The resulting assembly is hot compressed in the same compression mold and under the same protocol as in step 1. The assembly is then placed between two brass electrodes to obtain a test assembly. Each test assembly has nine pairs of upper and lower brass electrodes, nine pairs of upper and lower conductive Al disks, and a single plaque sandwiched between the nine pairs of upper and lower conductive Al disks.

[0093] The test assembly parts 1 are shown in FIG. 1. Each test assembly has nine parts 1. Each test assembly part 1 includes one of nine pairs of upper brass electrodes 11 and lower brass electrodes 15, one of nine pairs of upper conductive Al disks 21 and lower conductive Al disks 25, and a portion of a single plaque 30 (FIG. 1). Each pair of brass electrodes 11 and 15 is in electrical communication with a device (not shown) configured to provide electrical current, detect dielectric breakdown, and measure voltage therethrough. Such devices are well known, see, for example, ASTM D149-20, Standard Test Method for Dielectric Breakdown Voltage and Dielectric Strength of Solid Electrical Insulating Materials at Commercial Power Frequencies; and IEC 243-1, Methods of Test for Electrical Strength of Solid Insulating Materials Part 1: Tests at Power Frequencies. The brass electrodes 11 and 15 are used to apply electrical current to their pairs of conductive Al disks 21 and 25, respectively. The upper conductive Al disk 21 has an independent lower surface 22 and an independent upper surface 23, and the disk thickness is the distance between them (i.e., from 22 to 23). The lower conductive Al disk 25 has an independent lower surface 27 and an independent upper surface 26, and the disk thickness is the distance between them (i.e., from 26 to 27). Different portions of the plaque 30 are sandwiched between different pairs of spaced apart conductive Al disks 21 and 25, respectively. The thickness of the plaque 30 between the conductive Al disks 21 and 25 is the distance between the lower surface 22 of the upper conductive Al disk 21 and the upper surface 26 of the lower conductive Al disk 25. Each portion of the plaque 30 has an independent upper surface 31. The thickness T of the portion of the plaque 30 used to determine the dielectric breakdown strength in Section 3 below is the distance between the upper surface 26 of the lower conductive Al disk 25 and the upper surface 31 of the plaque 30.This thickness T is indicated by “}T” in FIG. 1 and is measured at the location of the channel formed by the breakdown event referenced in Section 3.

[0094] Section 3: Dielectric Breakdown Strength Test Method: A procedure in which an alternating current (AC) is applied to a test assembly with increasing test voltage to detect a dielectric breakdown event. The assembly prepared above is immersed in insulating oil and it is contacted with brass electrodes at the top and bottom. A voltage is applied. The voltage is gradually increased at a rate of 500 V / S (volts per second, 50 Hz) until a breakdown event occurs, forming a channel through the polymer. The breakdown event is detected as a sudden increase in current. The kilovolts (V) applied when this jump in current event occurs is recorded. Such a breakdown event is due to the formation of a channel by the voltage applied to the insulating layer. The thickness of the insulating layer at the location of the channel is measured and used as the insulation thickness in the following calculation of the actual dielectric breakdown strength: E act = V / T, where V is the breakdown voltage in kilovolts (kV), T is the insulation thickness in millimeters (mm) measured at the channel, and E act is the actual breakdown strength in kilovolts per millimeter (kV / mm). For reporting purposes, in the following tables, the actual breakdown strength E act is normalized to a thickness of 1.016 millimeters (mm, equal to 40 mils) and reported as normalized breakdown strength E in kV / mm. Normalized dielectric breakdown strength E is calculated according to Equation 1: E=(V / T) * (T / T0)^(1 / 2) (Equation 1) where ^(1 / 2) denotes the square root, V is the kilovolts applied when the breakdown event occurs, each T is a measurement of the thickness of the insulating layer (plaque, location of breakdown), and T0 is 1.016 mm thick (equivalent to 40 mils) so that T / T0 normalizes the breakdown strength values ​​to 1.016 mm thickness. The voltage at which the breakdown event occurs is recorded. The effectiveness of the voltage stabilizer is evaluated by comparing the breakdown field strength of the same polymer with and without the additive.

[0095] In the dielectric breakdown strength test method of the present invention, the voltage at which a dielectric breakdown event occurs varies depending on the thickness of the insulating layer. The normalized dielectric breakdown strength E, which has units of kV / mm, is analyzed using well-known two-parameter Weibull statistics according to the Weibull statistical method described below.

[0096] Weibull statistical method. Equation 2 (Equation 2):

[0097]

number

[0098] The dielectric breakdown strength values ​​used to determine the improvement or reduction over the baseline value of CE0 are the predicted values ​​eta, η, for a failure probability value of 63.2%, determined from the normalized field strength E values ​​using the Weibull statistics described above. Also reported are the 90% confidence level (upper and lower bounds) beta, β, values, b, obtained using the Weibull statistics described above. All other things being equal, the higher the β value, the narrower the range of field strengths at which test sample N will fail, and therefore the narrower the range of E at the 90% confidence level.

[0099] All other conditions being equal, including the thickness of the insulating layer, the higher the voltage at which the breakdown strength occurs, the greater the breakdown strength of the insulating material. Determine the percent increase (improvement) or percent decrease (deterioration) of the voltage of the test plaques (N=8 or 9) at which the breakdown event occurs compared to the voltage of 17 control plaques (N=153 or 155) at which the breakdown event occurs. The greater the percent increase, the greater the improvement in breakdown strength. The greater the percent decrease, the greater the deterioration in breakdown strength. EXAMPLES

[0100] Polyethylene polymer (A)-1: Low density polyethylene (LDPE-1). LDPE-1 has a density of 0.920 g / cm 3 and a melt index of 2.0 g / 10 min. Available from The Dow Chemical Company as DFDK-7423NT.

[0101] The present invention's crotophenone compound (B)-1: crotophenone, which is a compound of formula (I) (wherein Ar is phenyl and R is methyl).

[0102] The present invention's crotophenone compound (B)-2: crotophenone, which is a compound of formula (I) (wherein Ar is phenyl and R is decyl).

[0103] The present invention's crotophenone compound (B)-3: clotophenone, which is a compound of formula (I) (wherein Ar is 2,4-dimethylphenyl and R is methyl).

[0104] Clotophenone compound (B)-4 of the present invention: Clotophenone, which is a compound of formula (I) (wherein Ar is 1-naphthyl and R is methyl).

[0105] Clotophenone compound (B)-5 of the present invention: Clotophenone, which is a compound of formula (I) (wherein Ar is 2-naphthyl and R is methyl).

[0106] 2',4'-dihydroxycrotopheonone ("Di(HO)CROT") Compound C1.

[0107] The effect on the dielectric breakdown strength of the polyolefin formulation is evaluated using test compounds including (B) a crotophenone compound of formula (I) and a comparative (non-invention) compound. A test embodiment of the polyolefin formulation of the invention includes a test compound that is a crotophenone compound of formula (I) (B) and a polyethylene polymer (A)-1. A comparative polyolefin formulation includes a test compound that is a comparative (non-invention) compound not of formula (I), such as 2',4'-dihydroxycrotopheonone ("Di(HO)CROT"), and a polyethylene polymer (A)-1. A test formulation is prepared by melt blending a known amount of the test compound into the polyethylene polymer (A)-1 such that the concentration of the test compound in the test formulation is 0.1-10.0 wt% based on the total weight of the formulation. Concentrations of 0.5 wt% and 1.0 wt% of the test compound are convenient amounts to use for testing purposes, although higher concentrations may be used if desired. Separately, the formulations are fabricated into test plaques according to the procedure described above for the dielectric breakdown strength test method, and the voltage at which a dielectric breakdown event occurs is determined. Results are reported as eta values ​​where the probability of failure, as determined according to the Weibull statistics above, is 63.2%.

[0108] Comparative Example 0 ("CE0"). A single batch of stabilizer-free comparative formulation consisting of 100.00 wt. % polyethylene polymer (A)-1 is prepared. The stabilizer-free comparative formulation batch does not contain any voltage stabilizers or any additives. In a separate experiment, different samples of the stabilizer-free comparative formulation are melt compounded into 17 test plaques. The dielectric breakdown strength of each test plaque is measured using a 3 x 3 array of 9 pairs of electrodes to obtain 153 actual dielectric breakdown strength values. The dielectric breakdown strength values ​​are normalized to a plaque thickness of 40 mm according to Equation 1 above. The normalized dielectric breakdown strength value for CE0 has an eta, η, value of 18.49 kV / mm (for a failure probability value of 63.2%) with a 90% confidence level, beta of 18.18 to 18.81 kV / mm (lower to upper limit). All comparisons of percent improvement and eta, η, values ​​of the present invention at a failure probability value of 63.2% are compared to the baseline (unimproved or reduced) normalized breakdown strength value of 18.5 kV / mm at a failure probability value of 63.2%.

[0109] The procedure used to conduct the experiments of the comparative examples and inventive examples described below includes the following steps: (1) turn on the Brabender mixer and heat while the bowl is empty until the recorded temperature is about 140°C. (2) charge the Brabender bowl with about 260 grams of (A) polyethylene polymer resin and mix at 40 rpm until it melts. (3) reduce the mixing speed (rpm) and reverse the twin screw rotation to allow some samples to be removed for further testing. (4) add additional amounts of (A) polyethylene polymer and compounds (B) and (C) such that the bowl volume is refilled to 260 g with the target additive load and the rpm is increased back to 40 rpm. (5) mix the resulting sample for up to 5 minutes. (6) reduce the mixing speed (rpm) and reverse the twin screw rotation to allow some samples to be removed for further testing. (7) repeat steps 4-6 to create a series of additive concentrations up to 2% by weight in polyethylene. Typically blends are done at 0.5%, 1%, and 2% by weight. (8) The mixing speed (rpm) is reduced and the twin screw rotation is reversed to allow some samples to be removed for further testing. (9) Step 9 marks the end of the experiment. (10) The samples are pressed into thin plaques approximately 15 mils thick. (11) Aluminum disks are embedded into the top and bottom of the samples and taken for electrical testing (see the Measurement section below for an outline of the process). Blend Mix Additive Preparation Notes: The blend mix is ​​prepared by adding equal weight proportions of the two additives onto a weighing bowl and then mixing with a spatula.

[0110] Comparative Example 1 (CE1, hypothetical): Polyethylene polymer (A)-1 is melt blended with a known amount of 2',4'-dihydroxycrotopheonone C1 ("Di(HO)CROT") as shown in Table 1 below to obtain comparative polyolefin formulation CE1. The formulation is tested according to the Dielectric Breakdown Strength Test Method. Expected test results are shown in Table 2.

[0111] [Table 2]

[0112] [Table 3]

[0113] N / r not reported. As shown by the data in Table 2, 2',4'-dihydroxycrotopheonone ("Di(HO)CROT") (CE1) compared to CE0, which does not contain the voltage stabilizer additive, is not expected to change the electrical breakdown strength.

[0114] Inventive Examples 1-2 (IE1-IE2): In separate experiments, polyethylene polymer (A)-1 is melt blended with known amounts of crotophenone compound (B)-1 according to Table 3 below to obtain inventive crosslinked polyolefin blends IE1-IE2. The blends are tested according to the dielectric breakdown strength test method. The test results are shown in Table 4.

[0115] [Table 4]

[0116] The data in Table 3 show that polyolefin blends IE1-IE2 are examples of polyolefin blends of the present invention.

[0117] [Table 5]

[0118] As shown by the data in Table 4, the inventive crotophenone compound (B)-1 of formula (I) improved the electrical breakdown strength (increased the voltage) compared to CE0 without the voltage stabilizer additive. Furthermore, the improvement in electrical breakdown strength positively correlates with the concentration of the (B)-1 crotophenone compound in the formulation.

[0119] Inventive Examples 3a-3c (IE3a-IE3c, hypothetical): A polyethylene polymer (A)-1 is melt mixed with 1.0 wt% of a crotophenone compound (B)-1 to obtain a first inventive polyolefin blend IE3a. 1.0 wt% of dicumyl peroxide is immersed therein to obtain a second inventive polyolefin blend IE3b. The weight % is based on the total weight of the blend IE3b. The obtained inventive blend IE3b is heated at 120°C for 1 hour, thereby producing an inventive crosslinked polyolefin product IE3c.

[0120] Inventive Examples 4a-4c, 5a-5c, 6a-6c, and 7a-7c (IE4a-IE4c, IE5a-IE5c, IE6a-IE6c, and IE7a-IE7c, all hypothetical): In separate experiments, high density polyethylene polymer (HDPE, IE4a-IE4c), ethylene / vinyl acetate copolymer (EVA, IE5a-IE5c), ethylene / methyl acrylate copolymer (EMA, IE6a-IE6c), or ethylene / (monocyclic (tetravinyl, tetramethyl)tetrasiloxane) copolymer) (IE7a-IE7c) are melted with 9.8 wt. % of crotophenone compound (B)-1 to obtain the first inventive polyolefin blend IE4a, IE5a, IE6a, or IE7a, respectively. In a separate experiment, 1.0 wt. % of dicumyl peroxide is immersed therein to obtain a second inventive polyolefin formulation of IE4b, IE5b, IE6b, or IE7b, respectively. The wt. % is based on the total weight of each second formulation. In a separate experiment, the obtained inventive formulation IE4b, IE5b, IE6b, or IE7b is heated at 120° C. for 1 hour, thereby producing an inventive crosslinked polyolefin product of IE4c, IE5c, IE6c, or IE7c, respectively.

[0121] Inventive Examples 8a-8c, 9a-9c, 10a-10c, 11a-1c (all hypothetical): In a separate experiment, the procedure of IE3a is repeated except that the same amount of any one of the crotophenone compounds (B)-2, (B)-3, (B)-4, or (B)-5 is used instead of the crotophenone compound (B)-1 to obtain the first polyolefin blends IE8a, IE9a, IE10a, and IE11a of the invention, respectively. In a separate experiment, the procedure of IE3b is repeated except that the first polyolefin blends IE8a, IE9a, IE10a, or IE11a are used instead of the first polyolefin blends IE3a, respectively, to obtain the second polyolefin blends IE8b, IE9b, IE10b, and IE11b, respectively. In separate experiments, the resulting inventive blends IE8b, IE9b, IE10b, or IE11b are heated at 120° C. for 1 hour, thereby producing inventive crosslinked polyolefin products IE8c, IE9c, IE10c, or IE11c, respectively.

[0122] Inventive Example 12 (hypothetical): Preparation of a coated conductor. The inventive polyolefin formulation of any one of the preceding inventive examples is introduced into a wire coating extrusion line to produce a coated wire having a coating consisting essentially of the formulation as a wire structure on a 14 AWG solid copper wire. The wire coating extrusion line is comprised of a BRABENDER 1.9 cm extruder with variable speed drive, a 25:1 standard PE screw, a BRABENDER crosshead wire die, a lab water cooled trough with air wipe, a laser micrometer, and a variable speed wire puller. The sample is extruded to a wall thickness of 0.76 millimeters (mm, 30 mils) at a screw speed of 40 rpm. The wire is produced using a set temperature profile of 160° / 170°C / 180°C / 190°C across zone 1, zone 2, zone 3, and head / die, respectively, with a take-up speed of 3.1 meters per minute (10 feet per minute). The coating on the wire consists essentially of one of the inventive polyolefin formulations. The wire can be passed through a vulcanizing tube set at a cure temperature of 220°C to sufficiently cure the compound to obtain a wire having a coating thereon, where the coating consists essentially of the crosslinked product of the present invention.

[0123] Inventive Example 13 (hypothetical): Conducting electricity. Strip the ends of the coating from each end of the coated wire prepared above to expose the wire. Apply a voltage across the wire (e.g., conductive core) of the coated wire (coated conductor), thereby generating a flow of electricity through the wire. The applied voltage may be provided by a battery, a power grid, or an inverter-containing solar panel.

Claims

1. A polyolefin composition comprising (A) a polyolefin polymer and (B) a compound of formula (I): 【Chemical 1】 [wherein, Ar is phenyl, alkylphenyl, 1-naphthyl, or 2-naphthyl; and R is (C １ ~C ５ )alkyl, (C ６ ~C １０ )alkyl, (C １１ ~C ２０ )alkyl, or (C ２１ ~C ４０ )alkyl] and a crotofenone compound, containing A polyolefin composition.

2. The polyolefin composition according to claim 1, wherein said Ar is selected from the group consisting of (i) phenyl, (ii) alkylphenyl, (iii) 1-naphthyl, (iv) 2-naphthyl, (v) both (i) and (ii), (vi) both (i) and (iii), (vii) both (i) and (iv), (viii) both (ii) and (iii), (ix) both (ii) and (iv), (x) both (iii) and (iv), and (xi) any combination of three of (i), (ii), (iii), and (iv).

3. wherein R is methyl or (C ２ ~C ５ ) alkyl, the polyolefin composition according to claim 1 or 2.

4. The above-mentioned (A) polyolefin polymer is selected from the group consisting of a low-density polyethylene polymer, an ethylene / (C ４ -C ２０ ) alpha-olefin copolymer, an ethylene / (unsaturated carboxylic acid ester) copolymer, an ethylene / (monocyclic organosiloxane) copolymer, an ethylene / propylene copolymer, an ethylene / propylene / (diene monomer) terpolymer, and a propylene homopolymer, the polyolefin blend according to claim 1 or 2.

5. 50.0 to 99.8 weight percent (wt%) of said (A) polyolefin polymer, 0.1 to 10.0 weight percent of said (B) crotofenone compound, and at least one additive in a total amount of 0.1 to 40 weight percent, wherein each of said at least one additive is different from components (A) and (B) and is independently selected from the group consisting of (C) an organic peroxide, (D) a scorch inhibitor, (E) an antioxidant, (F) a filler, (G) a flame retardant, (H) a hindered amine stabilizer, (I) a tree inhibitor, (J) a methyl radical scavenger, (K) a crosslinking aid, (L) a processing aid, (M) a colorant, and any combination of two or more of additives (C) to (M), the polyolefin composition according to claim 1 or 2.

6. 85 to 99.5 weight percent (wt%) of said (A) polyolefin polymer, which is a low density polyethylene polymer, 0.5 to 1.4 weight percent of said (B) crotofenone compound which is a compound of formula (I) wherein Ar is phenyl and R is methyl, and 0.1 to 1.5 weight percent of at least one (E) antioxidant, the polyolefin composition according to claim 5.

7. A method for preparing the polyolefin composition according to claim 1 or 2, comprising mixing said (A) polyolefin polymer with said (B) crotofenone compound and optionally at least one additive so as to prepare said composition.

8. A method for producing a crosslinked polyolefin product, comprising subjecting the polyolefin blend according to claim 1 or 2 to curing conditions so as to crosslink the (A) polyolefin polymer, thereby producing the crosslinked polyolefin product.

9. A crosslinked polyolefin product produced by the method according to claim 8.

10. An article comprising the polyolefin blend according to claim 1 or 2, the crosslinked polyolefin product according to claim 9, or a combination thereof.

11. A coated conductor comprising a conductive core and an insulating layer at least partially covering the conductive core, wherein the insulating layer comprises the crosslinked polyolefin product according to claim 9.

12. A method for transmitting electricity, comprising applying a voltage across the entire conductive core of the coated conductor according to claim 10 so as to generate an electric current flow through the conductive core.

13. The invention according to claim 1 or 2, wherein the polyolefin blend has an improvement (increase) in the dielectric breakdown strength value eta, η of at least +10.0 percent (%) compared to a comparative blend not containing the (B) crotofenone compound, and the dielectric breakdown strength value eta, η is determined using Weibull statistics according to the dielectric breakdown strength test method and Weibull statistics described herein for a failure probability value of 63.2%.

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