Manufacturing method of electrode body

Abstract

To provide a manufacturing method of an electrode body, capable of suppressing the generation of cracking of the electrode body.SOLUTION: A manufacturing method of an electrode body of a bipolar structure having a collector, a positive electrode layer arranged on a first surface of the collector, and a negative electrode layer arranged on a second surface of the collector, includes: a preparation step of applying a positive electrode mixture to the first surface of the collector, applying a negative electrode mixture to the second surface of the collector, to prepare a workpiece having the collector, the positive electrode mixture, and the negative electrode mixture; and a drying step of drying the workpiece while transporting it. In the drying step, one surface of the workpiece is heated by a radiation heat, and the other surface of the workpiece is heated by a heat air, and thereby the workpiece is dried.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a method for manufacturing an electrode assembly. [Background technology]

[0002] Various techniques have been proposed for producing an electrode assembly such as that disclosed in Patent Document 1. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2020-145034 A Summary of the Invention [Problem to be solved by the invention]

[0004] When drying an electrode body for a bipolar battery in which a positive electrode composite and a negative electrode composite are applied to both sides of a current collector, the heating conditions required for the top and bottom surfaces of the electrode composite may differ. For example, if the electrode body is dried under conditions where the positive electrode composite is completely dry, the negative electrode composite on the back side may become brittle and crack. A drying method suitable for such cases is required.

[0005] The present disclosure has been made in consideration of the above-mentioned circumstances, and has as its main object to provide a manufacturing method for an electrode assembly that can suppress the occurrence of cracks in the electrode assembly. [Means for solving the problem]

[0006] That is, the present disclosure includes the following aspects. <1> A method for manufacturing a bipolar electrode assembly including a current collector, a positive electrode layer disposed on a first surface of the current collector, and a negative electrode layer disposed on a second surface of the current collector, comprising: a preparation step of applying a positive electrode composite material to the first surface of the current collector and applying a negative electrode composite material to the second surface of the current collector to prepare a workpiece including the current collector, the positive electrode composite material, and the negative electrode composite material; A drying process for drying the workpiece while transporting it, In the drying step, one surface of the workpiece is heated by radiant heat and the other surface of the workpiece is heated by hot air, thereby drying the workpiece.

[0007] <2> The temperature of the hot air is lower than the temperature of the radiant heat. <1> A method for producing the electrode assembly according to claim 1.

[0008] <3> In the drying step, one surface of the workpiece is heated by the radiant heat and the hot air, and the other surface of the workpiece is heated by the hot air. <1> A method for producing the electrode assembly according to claim 1.

[0009] <4> In the drying step, the temperature of the hot air for heating one side of the workpiece is higher than the temperature of the hot air for heating the other side of the workpiece. <3> A method for producing the electrode assembly according to claim 1.

[0010] <5> In the drying step, the dew point of the hot air that heats one side of the workpiece is lower than the dew point of the hot air that heats the other side of the workpiece. <3> A method for producing the electrode assembly according to claim 1. Effect of the Invention

[0011] The manufacturing method of the electrode assembly according to the present disclosure can suppress the occurrence of cracks in the electrode assembly. [Brief description of the drawings]

[0012] [Figure 1] FIG. 2 is a schematic diagram showing an example of a drying step according to the present disclosure. [Diagram 2] FIG. 2 is a schematic diagram showing an example of a workpiece, a laser, and hot air in the drying furnace shown in FIG. [Diagram 3] FIG. 4 is a schematic diagram showing another example of the drying step of the present disclosure. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] Hereinafter, the embodiments of the present disclosure will be described. Note that matters other than those specifically mentioned in this specification and necessary for implementing the present disclosure (for example, the general configuration and manufacturing process of the electrode body that do not characterize the present disclosure) can be understood as design matters of a person skilled in the art based on the prior art in the field. The present disclosure can be implemented based on the contents disclosed in this specification and the technical common sense in the field. Furthermore, the dimensional relationships (length, width, thickness, etc.) in the drawings do not reflect the actual dimensional relationships.

[0014] The present disclosure provides a method for manufacturing a bipolar electrode assembly including a current collector, a positive electrode layer disposed on a first surface of the current collector, and a negative electrode layer disposed on a second surface of the current collector, the method comprising the steps of: a preparation step of applying a positive electrode composite material to the first surface of the current collector and applying a negative electrode composite material to the second surface of the current collector to prepare a workpiece including the current collector, the positive electrode composite material, and the negative electrode composite material; A drying process for drying the workpiece while transporting it, In the drying step, one surface of the workpiece is heated by radiant heat and the other surface of the workpiece is heated by hot air, thereby drying the workpiece.

[0015] In the present disclosure, in the drying process, the side of the workpiece where it is desired to remove more moisture is heated intensively using radiant heat from a laser or the like, while the side where it is desired to heat under gentler conditions is heated using hot air, thereby making it possible to change the heating conditions for the front and back sides of the workpiece and suppressing the occurrence of cracks in the electrode body.

[0016] The manufacturing method of the electrode assembly of the present disclosure includes (1) a preparation step and (2) a drying step.

[0017] (1) Preparation process The preparation process is a process of applying a positive electrode composite material to the first surface of the current collector and applying a negative electrode composite material to the second surface of the current collector to prepare a workpiece including the current collector, the positive electrode composite material, and the negative electrode composite material.

[0018] Examples of materials for the current collector include metals such as aluminum, copper, SUS, nickel, etc. The thickness of the current collector is, for example, 0.1 μm or more and 100 μm or less. The shape of the current collector may be a sheet or the like.

[0019] The positive electrode mixture can be prepared by applying it to a first surface of a current collector. The positive electrode mixture may be a positive electrode paste prepared by mixing positive electrode materials including a positive electrode active material, a binder, a conductive material, an electrolyte, a thickener, and the like, together with a solvent such as water. The negative electrode mixture can be prepared by applying it to the second surface, which is the surface opposite to the first surface, of a current collector. The negative electrode mixture may be a negative electrode paste prepared by mixing a negative electrode material including a negative electrode active material, a binder, a conductive material, an electrolyte, a thickener, and the like, together with a solvent such as water. The amount of the positive electrode paste and the negative electrode paste applied to the current collector is, for example, 30 to 80 mg / cm. 2 may be also possible. The viscosity of the positive electrode paste and the negative electrode paste may be, for example, 5000 to 50000 mPa·S. The positive electrode paste and the negative electrode paste may contain moisture of about 10,000 ppm or less.

[0020] The positive electrode active material may be, for example, an oxide active material. Examples of the oxide active material include LiCoO2, LiMnO2, LiNiO2, LiVO2, and LiNi 1 / 3 Co 1 / 3 Mn 1 / 3 O2, etc., rock salt layered active materials, LiMn2O4, Li(Ni 0.5 Mn 1.5 )O4 and the like; and olivine type active materials such as LiFePO4, LiMnPO4, LiNiPO4, and LiCuPO4.

[0021] Examples of the negative electrode active material include carbon active material, oxide active material, and metal active material. Examples of the carbon active material include mesocarbon microbeads (MCMB), highly oriented graphite (HOPG), hard carbon, and soft carbon. Examples of the oxide active material include Nb2O5, Li4Ti5O 12 and SiO. Examples of the metal active material include In, Al, Si, Sn, and the like.

[0022] Examples of the binder include fluorine-containing binders such as polyvinylidene fluoride (PVDF) and polytetrafluoroethylene (PTFE), rubber-based binders such as butadiene rubber, and acrylic-based binders.

[0023] Examples of conductive materials include carbon materials, metal particles, conductive polymers, etc. Examples of carbon materials include particulate carbon materials such as acetylene black (AB) and ketjen black (KB), and fibrous carbon materials such as carbon fibers, carbon nanotubes (CNT), and carbon nanofibers (CNF).

[0024] Examples of thickeners include polysaccharides such as carboxymethylcellulose and methylcellulose.

[0025] Examples of the electrolyte include inorganic solid electrolytes such as sulfide solid electrolytes and oxide solid electrolytes. Examples of the sulfide solid electrolyte include solid electrolytes containing Li, X (X is at least one of P, As, Sb, Si, Ge, Sn, B, Al, Ga, and In), and S. The sulfide solid electrolyte may further contain at least one of O and halogen elements. Examples of the halogen elements include F, Cl, Br, and I.

[0026] Examples of oxide solid electrolytes include Li2O-B2O3-P2O5, Li2O-SiO2, Li2O-B2O3, Li1.3 Al 0.3 Ti 0.7 (PO4)3, Li5La3Ta2O 12 , Li7La3Zr2O 12 , Li6BaLa2Ta2O 12 , Li 3.6 S 0.6 P 0.4 O4, Li4SiO4, Li3PO4, Li3PO 4-3 / 2x N x (x≦1).

[0027] Examples of the solvent include aqueous solvents and organic solvents. The aqueous solvent means water or a mixed solvent containing water and a polar organic solvent. For example, an appropriate dispersion medium can be selected depending on the types of active material, binder, etc. As the aqueous solvent, water is preferably used because of its ease of handling. Examples of polar organic solvents that can be used in the mixed solvent include alcohols such as methanol, ethanol, and isopropyl alcohol, ketones such as acetone, and ethers such as tetrahydrofuran. An example of the organic solvent is N-methyl-2-pyrrolidone (NMP).

[0028] (2) Drying process The drying step is a step in which the workpiece is dried while being transported. In the drying step, one surface of the workpiece is heated by radiant heat and the other surface of the workpiece is heated by hot air, thereby drying the workpiece. In the drying step, for example, the positive electrode mixture, which needs to have more moisture removed than the negative electrode mixture, may be dried by radiant heating, and the negative electrode mixture, which is easily embrittled by heating, may be dried by hot air. Regarding drying conditions, the temperature of the hot air may be lower than the temperature of the radiant heat. By creating a temperature gradient in the thickness direction of the workpiece by radiant heat heating from one side (front side) of the workpiece and hot air from the other side (back side) of the workpiece, it is possible to perform drying suitable for bipolar structure electrodes in which the desired heating conditions differ between the front and back of the workpiece.

[0029] In the drying process, one side of the workpiece may be heated by the radiant heat and the hot air, and the other side of the workpiece may be heated by the hot air, which makes it easy to control the temperature and the dew point in the drying process, and allows the workpiece to be dried efficiently. In the drying step, the temperature of the hot air that heats one side of the workpiece may be higher than the temperature of the hot air that heats the other side of the workpiece. In the drying process, the dew point of the hot air that heats one side of the workpiece may be lower than the dew point of the hot air that heats the other side of the workpiece.

[0030] In the drying step, the positive electrode mixture and the negative electrode mixture may be completely dried until the moisture content is reduced to several hundred ppm or less, for example, 500 ppm or less. The positive electrode mixture becomes a positive electrode layer through a drying process, and the negative electrode mixture becomes a negative electrode layer through a drying process. A drying device that uses radiant heat for heating can be a laser device, an IR (infrared) device, or the like. As a drying device that heats with hot air, a hot air device such as an air nozzle can be used.

[0031] In the drying step, the workpiece may be dried in a drying furnace while being transported on a transport body. The transport speed may be, for example, 30 m / min or more. The shape of the carrier may be a roll or a plate. In the drying furnace, a laser device or an IR device may be installed above the workpiece, and an air nozzle may be installed below the workpiece. In the drying furnace, an air nozzle may also be installed above the workpiece. The hot air from the air nozzle above the workpiece may have a higher temperature and a lower dew point than the hot air from the air nozzle below the workpiece. In order to facilitate temperature control and dew point control, exhaust holes may be provided corresponding to the air nozzle above the workpiece and the air nozzle below the workpiece. In the drying furnace, a partition may be provided to separate the spaces above and below the workpiece. In the coating and drying process in the preparation step (1) above, if it is desired to create a temperature gradient above and below the workpiece or a humidity gradient above and below the workpiece, a similar drying furnace may be provided. In the drying step, the workpiece may be heated to a temperature of 100°C to 200°C. In the drying step, the drying time of the workpiece can be appropriately set depending on the dew point and temperature in the drying furnace, the heating temperature of the workpiece, etc.

[0032] FIG. 1 is a schematic diagram showing an example of the drying step of the present disclosure. FIG. 2 is a schematic diagram showing an example of the workpiece, the laser, and the hot air in the drying furnace shown in FIG. In the drying process shown in FIG. 1, a workpiece 1 is transported in a transport direction. As shown in FIG. 2, the workpiece 1 includes a current collector 2, a positive electrode composite material 3, and a negative electrode composite material 4, with the positive electrode composite material 3 being applied to a first surface, which is the upper surface, of the current collector 2, and the negative electrode composite material 4 being applied to a second surface, which is the lower surface, of the current collector 2. As shown in FIG. 1, the upper surface of the workpiece 1 is heated by a laser 12 irradiated by a laser device 11 in a drying furnace 10, and the lower surface of the workpiece 1 is heated by hot air 22 supplied into the drying furnace 10 by a hot air device 21 (air nozzle). For the drying process, the temperature of the hot air 22 may be lower than the temperature of the laser 12 . In the drying step, instead of the laser device 11, an IR device or the like may be used. In the drying step, a partition may be provided to separate the work 1 from above and below.

[0033] FIG. 3 is a schematic diagram showing another example of the drying step of the present disclosure. In the drying process shown in Figure 3, the inside of the drying furnace 10 is divided by an upper and lower partition 50 that separates the workpiece 1 from the top and bottom, and a laser device 11, an upper hot air device 41, and an upper exhaust hole 43 are provided in the space on the top side of the workpiece 1, and a lower hot air device 31 (air nozzle) and a lower exhaust hole 33 are provided in the space on the bottom side of the workpiece 1. The upper surface of the workpiece 1 is heated by a laser 12 irradiated by a laser device 11 in the drying furnace 10 and by upper hot air 42 supplied into the drying furnace 10 by an upper hot air device 41 (air nozzle), and the lower surface of the workpiece 1 is heated by lower hot air 32 supplied into the drying furnace 10 by a lower hot air device 31 in the drying furnace 10. In the drying process, the temperature of the upper hot air 42 may be higher than the temperature of the lower hot air 32 . In the drying process, the dew point of the upper hot air 42 may be lower than the dew point of the lower hot air 32.

[0034] The electrode body obtained by the manufacturing method of the present disclosure has a bipolar structure including a current collector, a positive electrode layer disposed on a first surface of the current collector, and a negative electrode layer disposed on a second surface of the current collector. The positive electrode layer is disposed on a first surface of the current collector. The positive electrode layer contains the above-mentioned positive electrode active material, a binder, a conductive material, an electrolyte, a thickener, and the like. The negative electrode layer is disposed on a second surface of the current collector that is opposite to the first surface. The negative electrode layer contains the above-mentioned negative electrode active material, a binder, a conductive material, an electrolyte, a thickener, and the like.

[0035] The electrode assemblies of the present disclosure are typically used in the manufacture of batteries. The type of battery in which the electrode body is used is not particularly limited, and may be, for example, a lithium ion secondary battery. The battery may be a liquid battery using an electrolytic solution as an electrolyte, or a solid battery using a solid electrolyte as an electrolyte. Applications of the battery include, for example, power sources for vehicles such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), electric vehicles (BEVs), gasoline automobiles, and diesel automobiles. In particular, the battery may be used as a driving power source for hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), or electric vehicles (BEVs). The battery may also be used as a power source for moving objects other than vehicles (for example, railways, ships, and aircraft), and may also be used as a power source for electrical appliances such as information processing devices. [Explanation of symbols]

[0036] 1. Work 2. Current collector 3. Cathode mixture 4.Negative electrode composite material 10.Drying oven 11. Laser equipment 12. Laser 21. Hot air device (air nozzle) 22. Hot air 31.Lower hot air device (air nozzle) 32.Lower hot air 33.Lower heat exhaust vent 41.Upper hot air device (air nozzle) 42.Upper hot air 43.Upper heat exhaust vent 50. Top and bottom partitions

Claims

1. A method for manufacturing a bipolar electrode assembly including a current collector, a positive electrode layer disposed on a first surface of the current collector, and a negative electrode layer disposed on a second surface of the current collector, the method comprising the steps of: a preparation step of applying a positive electrode composite material to the first surface of the current collector and applying a negative electrode composite material to the second surface of the current collector to prepare a workpiece including the current collector, the positive electrode composite material, and the negative electrode composite material; A drying process for drying the workpiece while transporting it, In the drying step, one surface of the workpiece is heated by radiant heat and the other surface of the workpiece is heated by hot air, thereby drying the workpiece.

2. The method for manufacturing an electrode assembly according to claim 1 , wherein the temperature of the hot air is lower than the temperature of the radiant heat.

3. The method for manufacturing an electrode body according to claim 1 , wherein in the drying step, one surface of the workpiece is heated by the radiant heat and the hot air, and the other surface of the workpiece is heated by the hot air.

4. The method for manufacturing an electrode body according to claim 3 , wherein in the drying step, a temperature of the hot air for heating one side of the workpiece is higher than a temperature of the hot air for heating the other side of the workpiece.

5. The method for manufacturing an electrode body according to claim 3 , wherein in the drying step, a dew point of the hot air for heating one side of the workpiece is lower than a dew point of the hot air for heating the other side of the workpiece.

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