Package and packaging body

A package with a bag containing a triazine-skeleton compound, made from synthetic resin or paper, addresses the need for effective containment of triazine compounds, providing mechanical strength and handling ease with optional additives for enhanced properties.

JP2025157472APending Publication Date: 2025-10-15ADEKA CORP
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Patent Information

Application Number
JP2025122193
Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Filing Date
2025-07-22
Publication Date
2025-10-15

AI Technical Summary

Technical Problem

There is a need for a package and packaging material that can effectively contain compounds with a triazine skeleton, which are not adequately addressed by existing synthetic resin additives.

Method used

A package comprising a bag containing a compound with a group represented by a specific general formula (1), sealed inside, which can be made into a heavy-duty or flexible container bag, using materials like synthetic resin, paper, or metal foil, with specific dimensions and thickness for mechanical strength and handling ease, and containing additional additives for enhanced properties.

Benefits of technology

The package provides a secure and efficient means to contain compounds with a triazine skeleton, offering mechanical strength, ease of handling, and transportability while allowing for customization with various additives for additional functionalities.

✦ Generated by Eureka AI based on patent content.

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    Figure 2025157472000003
Patent Text Reader

Abstract

To provide a package and a packaging body of a composition containing a compound having a triazine skeleton.SOLUTION: A package comprises a bag and a composition containing a compound having a group represented by the general formula (1) in the figure, where the composition is sealed inside the bag. (In general formula (1), X1, X2 and X3 each independently represent an unsubstituted or substituted phenylene group, and *, **, and *** each represent a bonding site to another atom.)SELECTED DRAWING: None
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Description

[Technical Field]

[0001] The present invention relates to a package and a wrapping. [Background technology]

[0002] Various compounds have been investigated as additives for synthetic resins. For example, Patent Document 1 below discloses a compound having a triazine skeleton as an additive for synthetic resins. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Unexamined Patent Publication No. 54-4950 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present invention is to provide a package and a packaging material for a composition containing a compound having a triazine skeleton. [Means for solving the problem]

[0005] The package of the present invention comprises a bag and a composition containing a compound having a group represented by the following general formula (1), and the composition is sealed inside the bag.

[0006] [ka] (In general formula (1), X 1 , X 2 and X 3 each independently represents an unsubstituted or substituted phenylene group, and *, **, and *** represent a bonding site to another atom.

[0007] Furthermore, a package of the present invention includes a packaging container and the above-described packaging body, and the packaging body is contained in the packaging container. [Effects of the Invention]

[0008] According to the present invention, a package and a packaging material for a composition containing a compound having a triazine skeleton can be provided. DETAILED DESCRIPTION OF THE INVENTION

[0009] Hereinafter, embodiments of the present invention will be described in detail.

[0010] <Package> The package of this embodiment includes a bag and a composition containing a compound including a group represented by the following general formula (1), with the composition sealed inside the bag.

[0011] [ka]

[0012] Here, in the general formula (1), X 1 , X 2 and X 3 each independently represents an unsubstituted or substituted phenylene group, and *, **, and *** represent a bonding site with another atom.

[0013] Examples of the bag include a heavy-duty bag and a flexible container bag. In the package of this embodiment, the bag is preferably a heavy-duty bag. However, in the package of this embodiment, the bag may also be a flexible container bag.

[0014] First, as a first embodiment of the packaging body of the present invention, a packaging body in which the bag is a heavy-duty bag will be described.

[0015] The first embodiment of the package includes a bag and a composition containing a compound having a group represented by the general formula (1), the composition being sealed inside the bag, and the bag being a heavy-duty bag.

[0016] In the package of the first embodiment, the composition is sealed inside a bag. The ratio V1 / V2 of the volume V1 of the sealed composition to the volume V2 of the internal space of the bag can be, for example, 0.4 to 1, and preferably 0.5 to 0.9.

[0017] The weight of the composition enclosed inside the bag is not particularly limited, but can be, for example, 1 to 50 kg. From the viewpoint of achieving both transport efficiency and ease of handling of the package, it is preferably 2 to 40 kg, and more preferably 5 to 30 kg.

[0018] In the packaging body of the first embodiment, the opening of the bag may be sealed by, for example, rubber band fastening, heat sealing, kraft band binding, resin rope binding, double-sided tape fastening, adhesive bonding, over-taping, sewing by machine, or the like.

[0019] Examples of the bag shape include bottom-sealed bags, side-sealed bags, three-side-sealed bags, pillow bags, gusseted bags, square-bottomed bags, stand-up bags, etc. Among these, bottom-sealed bags are preferred because they are inexpensive and easily available.

[0020] The dimensions of the bag are not particularly limited, and for example, in the case of a rectangular bottom-sealed bag, the length of each side can be 200 to 1200 mm, and the ratio L / W of the length of the vertical side L to the length of the horizontal side W can be 0.5 to 2. Here, the vertical side refers to the side perpendicular to the opening of the bottom-sealed bag, and the horizontal side refers to the side parallel to the opening of the bottom-sealed bag.

[0021] The thickness of the bag is not particularly limited and can be, for example, 10 to 5,000 μm, and from the viewpoint of achieving both mechanical strength and ease of handling, it is preferably 20 to 1,000 μm.

[0022] Examples of materials for the bag include synthetic resin, paper, metal foil, etc. Among these, synthetic resin is preferred from the viewpoint of ease of handling and transportability. That is, the bag is preferably made of synthetic resin.

[0023] When the bag is made of synthetic resin, examples of the synthetic resin include polyethylene resin, polypropylene resin, polyester resin, polyamide resin, polyvinyl chloride resin, etc. From the viewpoint of ease of handling and transportability, among these, polyethylene resin is preferred, low-density polyethylene (LDPE) or linear low-density polyethylene (LLDPE) is more preferred, and linear low-density polyethylene (LLDPE) is even more preferred.

[0024] When the bag is made of synthetic resin, examples of the bag include a film bag made of a synthetic resin film, a woven fabric bag made of a synthetic resin woven fabric, a nonwoven fabric bag made of a synthetic resin nonwoven fabric, etc. Among these, a film bag is preferred from the viewpoint of airtightness.

[0025] When the bag is a film bag made of a synthetic resin film, the film may be a single layer film made of one type of synthetic resin material, or a laminate film made of two or more types of synthetic resin materials laminated together.

[0026] The method for manufacturing the bag is not particularly limited, and any known method can be used. For example, when the bag is a film bag made of a synthetic resin film, the bag can be manufactured by a method such as extrusion molding or blow molding.

[0027] As described above, in the package of the first embodiment, the composition contains a compound containing a group represented by the general formula (1). Specific examples of the compound containing a group represented by the general formula (1) include the following compounds No. 1 to No. 42, but the compound containing a group represented by the general formula (1) is not limited to the following compounds.

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[0040] Compounds containing a group represented by general formula (1) can be produced by known methods such as those described in WO 2020 / 067144 and WO 2022 / 039244.

[0041] The composition may contain only one type of compound containing a group represented by general formula (1), or may contain two or more types.

[0042] The composition may further contain one or more additives other than the compound containing a group represented by general formula (1) above (hereinafter referred to as "other additives"), such as nucleating agents, phenolic antioxidants, phosphorus-based antioxidants, sulfur-based antioxidants, other antioxidants, hindered amine compounds, ultraviolet absorbers, fatty acid metal salts, flame retardants, flame retardant aids, fillers, lubricants, hydrotalcites, antistatic agents, fluorescent brighteners, colorants, and neutralizing agents.

[0043] Examples of nucleating agents include aromatic phosphate metal salts such as sodium 2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate, lithium 2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate, dihydroxyaluminum 2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate, and hydroxyaluminum bis[2,2'-methylenebis(4,6-di-tert-butylphenyl)phosphate], sodium benzoate, aluminum 4-tert-butylbenzoate, sodium adipate, disodium bicyclo[2.2.1]heptane-2,3-dicarboxylate, and calcium Examples of the compound include metal salts of carboxylic acids such as cyclohexane-1,2-dicarboxylate, amide compounds such as N,N',N"-tris[2-methylcyclohexyl]-1,2,3-propanetricarboxamide, N,N',N"-tricyclohexyl-1,3,5-benzenetricarboxamide, N,N'-dicyclohexylnaphthalenedicarboxamide, and 1,3,5-tris[(2,2-dimethylpropanoylamino)]benzene, and diacetal compounds such as dibenzylidene sorbitol, bis(p-methylbenzylidene)sorbitol, bis(p-ethylbenzylidene)sorbitol, bis(3,4-dimethylbenzylidene)sorbitol, and 1,2,3-trideoxy-4,6:5,7-o-bis(4-propylbenzylidene)nonitol.

[0044] Examples of phenolic antioxidants include 2,6-di-tert-butyl-4-ethylphenol, 2-tert-butyl-4,6-dimethylphenol, styrenated phenol, 2,2'-methylenebis(4-ethyl-6-tert-butylphenol), 2,2'-thiobis-(6-tert-butyl-4-methylphenol), 2,2'-thiodiethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 2-methyl-4,6-bis(octylsulfanylmethyl)phenol, 2,2'-isobutylidenebis(4,6-dimethylphenol), isooctyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, and 2,2'-isobutylidenebis(4,6-dimethylphenol). Nyl)propionate, N,N'-hexane-1,6-diylbis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionamide], 2,2'-oxamido-bis[ethyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 2-ethylhexyl-3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate, 2,2'-ethylenebis(4,6-di-tert-butylphenol), 3,5-di-tert-butyl-4-hydroxybenzenepropanoic acid and C13-15 alkyl ester, 2,5-di-tert-amylhydroquinone, hindered phenol polymer (ADEKA POLYMER ADDITIVES EUROPE SAS) Trade name "AO.OH.98"), 2,2'-methylenebis[6-(1-methylcyclohexyl)-p-cresol], 2-tert-butyl-6-(3-tert-butyl-2-hydroxy5-methylbenzyl)-4-methylphenyl acrylate, 2-[1-(2-hydroxy-3,5-di-tert-pentylphenyl)ethyl]-4,6-di-tert-pentylphenyl acrylate, 6-[3-(3-tert-butyl-4-hydroxy-5-methyl)propoxy]-2,4,8,10-tetra-tert-butylbenz[d,f][1,3,2]-dioxaphophobin, hexamethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], bis[monoethyl(3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate]calcium salt, 5,Reaction products of 7-bis(1,1-dimethylethyl)-3-hydroxy-2(3H)-benzofuranone with o-xylene, 2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol, DL-α-tocophenol (vitamin E), 2,6-bis(α-methylbenzyl)-4-methylphenol, bis[3,3-bis-(4'-hydroxy-3'-tert-butyl-phenyl)butanoic acid] glycol ester, 2,6-di-tert-butyl-p-cresol, 2,6-diphenyl Nyl-4-octadecyloxyphenol, stearyl (3,5-di-tert-butyl-4-hydroxyphenyl)propionate, distearyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonate, tridecyl-3,5-tert-butyl-4-hydroxybenzylthioacetate, thiodiethylenebis[(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], 4,4'-thiobis(6-tert-butyl-m-cresol), 2-octylthio-4,6-di(3,5-di-tert-butyl) (4-hydroxyphenoxy)-s-triazine, 2,2'-methylenebis(4-methyl-6-tert-butylphenol), bis[3,3-bis(4-hydroxy-3-tert-butylphenyl)butylic acid] glycol ester, 4,4'-butylidenebis(2,6-di-tert-butylphenol), 4,4'-butylidenebis(6-tert-butyl-3-methylphenol), 2,2'-ethylidenebis(4,6-di-tert-butylphenol), 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenol), rt-butylphenyl)butane, bis[2-tert-butyl-4-methyl-6-(2-hydroxy-3-tert-butyl-5-methylbenzyl)phenyl]terephthalate, 1,3,5-tris(2,6-dimethyl-3-hydroxy-4-tert-butylbenzyl)isocyanurate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, 1,3,5-tris[(3,5-di-tert-butyl-4-hydroxyphenyl)propionyloxyethyl]isocyanurate, tetrakis[methylene-3-(3',5'-tert-butyl-4'-hydroxyphenyl)propionate]methane, 2-tert-butyl-4-methyl-6-(2-acryloyloxy-3-tert-butyl-5-methylbenzyl)phenol, 3,9-bis[2-(3-tert-butyl-4-hydroxy-5-methylhydrocinnamoyloxy)-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, triethylene glycol bis[β 3-(3,5-dialkyl-4-hydroxyphenyl)propionic acid derivatives such as 3-(3,5-di-tert-butyl-4-hydroxy-5-methylphenyl)propionate, stearyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid amide, palmityl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid amide, myristyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid amide, and lauryl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid amide, etc.

[0045] Examples of phosphorus-based antioxidants include triphenyl phosphite, diisooctyl phosphite, heptakis(dipropylene glycol)triphosphite, triisodecyl phosphite, diphenyl isooctyl phosphite, diisooctylphenyl phosphite, diphenyl tridecyl phosphite, triisooctyl phosphite, trilauryl phosphite, diphenyl phosphite, tris(dipropylene glycol)phosphite, dioleylhydrogen phosphite, trilauryl trithiophosphite, and bis(tridecyl)phosphite. phosphite, tris(isodecyl)phosphite, tris(tridecyl)phosphite, diphenyldecylphosphite, dinonylphenylbis(nonylphenyl)phosphite, poly(dipropylene glycol)phenylphosphite, tetraphenyldipropylene glycol diphosphite, trisnonylphenylphosphite, tris(2,4-di-tert-butylphenyl)phosphite, tris(2,4-di-tert-butyl-5-methylphenyl)phosphite, tris[2-tert-butyl-4-(3-tert-butyl-4-hydrochloride] (tridecyl) bisphenol A phosphite, octyl diphenyl phosphite, di(decyl) monophenyl phosphite, mixture of distearyl pentaerythritol and calcium stearate, alkyl (C10) bisphenol A phosphite, tetraphenyl-tetra(tridecyl) pentaerythritol tetraphosphite, bis(2,4-di-tert-butyl-6-methylphenyl)ethyl phosphite, tetra(tridecyl) isopropylidenediphenol diphosphite tetra(tridecyl)-4,4'-n-butylidenebis(2-tert-butyl-5-methylphenol)diphosphite, hexa(tridecyl)-1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butanetriphosphite, tetrakis(2,4-di-tert-butylphenyl)biphenylene diphosphonite, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, (1-methyl-1-propenyl-3-ylidene)tris(1,1-dimethylethyl)-5-methyl-4,1-phenylene)hexatridecyl phosphite, 2,2'-methylenebis(4,6-di-tert-butylphenyl)-2-ethylhexyl phosphite, 2,2'-methylenebis(4,6-di-tert-butylphenyl)-octadecyl phosphite, 2,2'-ethylidenebis(4,6-di-tert-butylphenyl)fluorophosphite, 4,4'-butylidenebis(3-methyl- 6-tert-butylphenylditridecyl)phosphite, tris(2-[(2,4,8,10-tetrakis-tert-butyldibenzo[d,f][1,3,2]dioxaphosphepin-6-yl)oxy]ethyl)amine, 3,9-bis(4-nonylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphespiro[5,5]undecane, 2,4,6-tri-tert-butyl Examples of suitable phosphates include phenyl-2-butyl-2-ethyl-1,3-propanediol phosphite, poly4,4'-isopropylidenediphenol C12-15 alcohol phosphite, bis(diisodecyl)pentaerythritol diphosphite, bis(tridecyl)pentaerythritol diphosphite, bis(octadecyl)pentaerythritol diphosphite, bis(nonylphenyl)pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,4,6-tri-tert-butylphenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, and bis(2,4-dicumylphenyl)pentaerythritol diphosphite.

[0046] Examples of sulfur-based antioxidants include tetrakis[methylene-3-(laurylthio)propionate]methane, bis(methyl-4-[3-n-alkyl(C12 / C14)thiopropionyloxy]5-tert-butylphenyl)sulfide, ditridecyl-3,3'-thiodipropionate, dilauryl-3,3'-thiodipropionate, dimyristyl-3,3'-thiodipropionate, distearyl-3,3'-thiodipropionate, lauryl / stearyl thiodipropionate, 4,4'-thiobis(6-tert-butyl-m-cresol), 2,2'-thiobis(6-tert-butyl-p-cresol), and distearyl disulfide.

[0047] Other antioxidants include nitrone compounds such as N-benzyl-α-phenyl nitrone, N-ethyl-α-methyl nitrone, N-octyl-α-heptyl nitrone, N-lauryl-α-undecyl nitrone, N-tetradecyl-α-tridecyl nitrone, N-hexadecyl-α-pentadecyl nitrone, N-octyl-α-heptadecyl nitrone, N-hexadecyl-α-heptadecyl nitrone, N-octadecyl-α-pentadecyl nitrone, N-heptadecyl-α-heptadecyl nitrone, and N-octadecyl-α-heptadecyl nitrone; 3-arylbenzofuran-2(3H)-one, 3-(alkoxyphenyl)benzofuran-2-one, 3-(acyloxyphenyl)benzofuran-2(3H)-one; Examples of the benzofuran compounds include t-butyl-3-(3,4-dimethylphenyl)-benzofuran-2(3H)-one, 5,7-di-tert-butyl-3-(4-hydroxyphenyl)-benzofuran-2(3H)-one, 5,7-di-tert-butyl-3-{4-(2-hydroxyethoxy)phenyl}-benzofuran-2(3H)-one, 6-(2-(4-(5,7-di-tert-2-oxo-2,3-dihydrobenzofuran-3-yl)phenoxy)ethoxy)-6-oxohexyl-6-((6-hydroxyhexanoyl)oxy)hexanoate, and 5-di-tert-butyl-3-(4-((15-hydroxy-3,6,9,13-tetraoxapentadecyl)oxy)phenyl)benzofuran-2(3H)-one.

[0048] Examples of the hindered amine compound include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2,6,6-tetramethyl-4-piperidyl benzoate, bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, tetrakis(1,2,2,6,6-pentamethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, biphenylsulfonyl ether ... Bis(2,2,6,6-tetramethyl-4-piperidyl)di(tridecyl)-1,2,3,4-butanetetracarboxylate, bis(1,2,2,6,6-pentamethyl-4-piperidyl)di(tridecyl)-1,2,3,4-butanetetracarboxylate, bis(1,2,2,4,4-pentamethyl-4-piperidyl)-2-butyl-2-(3,5-di-tert-butyl-4-hydroxybenzyl)malonate, 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-piperidinol / diethyl succinate polycondensate, 1,6-bis( 2,2,6,6-tetramethyl-4-piperidylamino)hexane / 2,4-dichloro-6-morpholino-s-triazine polycondensate, 1,6-bis(2,2,6,6-tetramethyl-4-piperidylamino)hexane / 2,4-dichloro-6-tert-octylamino-s-triazine polycondensate, 1,5,8,12-tetrakis[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino)-s-triazine-6-yl]-1,5,8,12-tetraazadodecane, 1,5,8,12-tetrakis[2,4-bis(N- butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino)-s-triazin-6-yl]-1,5,8-12-tetraazadodecane, 1,6,11-tris[2,4-bis(N-butyl-N-(2,2,6,6-tetramethyl-4-piperidyl)amino-s-triazin-6-ylamino]undecane, 1,6,11-tris[2,4-bis(N-butyl-N-(1,2,2,6,6-pentamethyl-4-piperidyl)amino-s-triazin-6-ylamino]undecane, 3,9-bis[1,1-dimethyl-2-{tris(2,2,Examples of the bis(1-undecyloxy-2,2,6,6-tetramethyl-4-piperidyloxycarbonyl)butylcarbonyloxy}ethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane include 3,9-bis[1,1-dimethyl-2-{tris(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)butylcarbonyloxy}ethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, bis(1-undecyloxy-2,2,6,6-tetramethylpiperidin-4-yl)carbonate, 2,2,6,6-tetramethyl-4-piperidyl hexadecanoate, and 2,2,6,6-tetramethyl-4-piperidyl octadecanoate.

[0049] Examples of the ultraviolet absorber include 2-hydroxybenzophenones such as 2,4-dihydroxybenzophenone and 5,5'-methylenebis(2-hydroxy-4-methoxybenzophenone); 2-(2-hydroxy-5-methylphenyl)benzotriazole, 2-(2-hydroxy-5-tert-octylphenyl)benzotriazole, 2-(2-hydroxy-3,5-di-tert-butylphenyl)-5-chlorobenzotriazole, 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole, 2-( 2-Hydroxy-3,5-dicumylphenyl)benzotriazole, 2,2'-methylenebis(4-tert-octyl-6-benzotriazolylphenol), polyethylene glycol esters of 2-(2-hydroxy-3-tert-butyl-5-carboxyphenyl)benzotriazole, 2-[2-hydroxy-3-(2-acryloyloxyethyl)-5-methylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]benzotriazole, 2-[2-hydroxy- 3-(2-Methacryloyloxyethyl)-5-tert-octylphenyl]benzotriazole, 2-[2-hydroxy-3-(2-methacryloyloxyethyl)-5-tert-butylphenyl]-5-chlorobenzotriazole, 2-[2-hydroxy-5-(2-methacryloyloxyethyl)phenyl]benzotriazole, 2-[2-hydroxy-3-tert-butyl-5-(2-methacryloyloxyethyl)phenyl]benzotriazole, 2-[2-hydroxy-3-tert-amyl-5-(2-methacryloyloxyethyl) 2-(2-hydroxyphenyl)benzotriazoles such as 2-[2-hydroxy-3-tert-butyl-5-(3-methacryloyloxypropyl)phenyl]benzotriazole, 2-[2-hydroxy-4-(2-methacryloyloxymethyl)phenyl]benzotriazole, 2-[2-hydroxy-4-(3-methacryloyloxy-2-hydroxypropyl)phenyl]benzotriazole, and 2-[2-hydroxy-4-(3-methacryloyloxypropyl)phenyl]benzotriazole;Phenyl salicylate, resorcinol monobenzoate, 2,4-di-tert-butylphenyl-3,5-di-tert-butyl-4-hydroxybenzoate, octyl (3,5-di-tert-butyl-4-hydroxy)benzoate, dodecyl (3,5-di-tert-butyl-4-hydroxy)benzoate, tetradecyl (3,5-di-tert-butyl-4-hydroxy)benzoate, hexadecyl (3,5-di-tert-butyl-4-hydroxy)benzoate ) benzoates such as octadecyl (3,5-di-tert-butyl-4-hydroxy) benzoate, behenyl (3,5-di-tert-butyl-4-hydroxy) benzoate; substituted oxanilides such as 2-ethyl-2'-ethoxyoxanilide, 2-ethoxy-4'-dodecyloxanilide; cyanoacrylates such as ethyl-α-cyano-β,β-diphenylacrylate, methyl-2-cyano-3-methyl-3-(p-methoxyphenyl)acrylate Acetates; 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexyloxyphenol, 2-(2-hydroxy-4-octoxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, trioctyl-2,2',2"-((1,3,5-triazine-2,4,6-triyl)tris(3-hydroxybenzene-4-,1-diyl)tripropionate), 2-(4,6-diphenyl-1,3,5-triazine-2- triazines such as 2-[4-(4,6-diphenyl-1,3,5-triazin-2-yl)-3-hydroxyphenoxy]ethyl]dodecanedioate; various metal salts or metal chelates, particularly nickel and chromium salts or chelates;

[0050] Examples of fatty acid metal salts include metal salts of fatty acids having 12 to 30 carbon atoms and containing linear or branched fatty acid residues. Examples of metal ions constituting fatty acid metal salts include sodium ions, potassium ions, lithium ions, dihydroxyaluminum ions, calcium ions, zinc ions, barium ions, magnesium ions, and hydroxyaluminum ions, with sodium ions, potassium ions, lithium ions, and calcium ions being preferred. Examples of fatty acids constituting fatty acid metal salts include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, arachidonic acid, behenic acid, lignoceric acid, cerotic acid, montanic acid, and melissic acid, with myristic acid and stearic acid being preferred. The fatty acids constituting fatty acid metal salts may be those in which one or more hydrogen atoms of the fatty acid residue have been substituted with hydroxyl groups. Examples of such fatty acids include 12-hydroxystearic acid and 12-hydroxyoleic acid.

[0051] Examples of flame retardants include triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, cresyl diphenyl phosphate, cresyl-2,6-dixylenyl phosphate, resorcinol bis(diphenyl phosphate), (1-methylethylidene)-4,1-phenylenetetraphenyl diphosphate, 1,3-phenylenetetrakis(2,6-dimethylphenyl)phosphate, and products under the trade names "ADEKA STAB FP-500," "ADEKA STAB FP-600," and "ADEKA STAB FP-600" manufactured by ADEKA Corporation. Aromatic phosphate esters such as "Stab FP-800", phosphonate esters such as divinyl phenylphosphonate, diallyl phenylphosphonate, and 1-butenyl phenylphosphonate, phosphinate esters such as phenyl diphenylphosphinate, methyl diphenylphosphinate, and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derivatives, phosphazene compounds such as bis(2-allylphenoxy)phosphazene and dicresylphosphazene, melamine phosphate, melamine pyrophosphate, and melamine polyphosphate amine, melam polyphosphate, ammonium polyphosphate, piperazine phosphate, piperazine pyrophosphate, piperazine polyphosphate, phosphorus-containing vinylbenzyl compounds, red phosphorus and other phosphorus-based flame retardants, magnesium hydroxide, aluminum hydroxide and other metal hydroxides, brominated bisphenol A type epoxy resin, brominated phenol novolac type epoxy resin, hexabromobenzene, pentabromotoluene, ethylene bis(pentabromophenyl), ethylene bistetrabromophthalimide, 1,2-dibromo-4-(1,2-dibromoethylene) Examples of suitable flame retardants include brominated flame retardants such as 2,4,6-tris(tribromophenoxy)-1,3,5-triazine, tribromophenylmaleimide, tribromophenyl acrylate, tribromophenyl methacrylate, tetrabromobisphenol A dimethacrylate, pentabromobenzyl acrylate, and brominated styrene. These flame retardants are preferably used in combination with anti-drip agents such as fluororesins, and flame retardant assistants such as polyhydric alcohols and hydrotalcite.

[0052] Examples of fillers include talc, mica, calcium carbonate, calcium oxide, calcium hydroxide, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, aluminum hydroxide, barium sulfate, glass powder, glass fiber, clay, dolomite, silica, alumina, potassium titanate whiskers, wollastonite, and fibrous magnesium oxysulfate. The particle size (fiber diameter, fiber length, and aspect ratio for fibrous fillers) can be appropriately selected. Among these fillers, talc is particularly preferred because of its excellent rigidity-imparting effect and easy availability. Furthermore, the filler may be surface-treated as needed.

[0053] Examples of lubricants include fatty acid esters such as fatty acid methyl, fatty acid ethyl, ethylene glycol fatty acid monoesters, propylene glycol fatty acid monoesters, ethylene glycol fatty acid diesters, propylene glycol fatty acid diesters, glycerol fatty acid monoesters, glycerol fatty acid diesters, glycerol fatty acid triesters, pentaerythritol fatty acid monoesters, pentaerythritol fatty acid diesters, pentaerythritol fatty acid triesters, and pentaerythritol fatty acid tetraesters; fatty acid monoamides such as stearic acid amide and oleic acid amide; alkylene bisfatty acid amides such as ethylene bisstearic acid amide; fatty acid amides such as alkylol fatty acid amides and N-alkyl fatty acid amides; fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, arachidonic acid, behenic acid, erucic acid, lignoceric acid, cerotic acid, montanic acid, melissic acid, 12-hydroxystearic acid, and ricinoleic acid; higher alcohols such as stearyl alcohol; and sugar alcohols such as mannitol.

[0054] Examples of hydrotalcites include complex salt compounds containing magnesium, aluminum, hydroxyl groups, carbonate groups, and optional crystal water, and they may be natural or synthetic. The crystal structure, particle shape, and particle size of the hydrotalcites are not particularly limited. Furthermore, the hydrotalcites may be those in which at least a portion of the magnesium or aluminum has been substituted with another metal such as an alkali metal or zinc, or those in which at least a portion of the hydroxyl groups or carbonate groups has been substituted with another anion group. Furthermore, the hydrotalcites may be those in which the crystal water has been dehydrated, and the surface may be coated with a higher fatty acid such as stearic acid, a higher fatty acid metal salt such as an alkali metal oleate, an organic sulfonic acid metal salt such as an alkali metal dodecylbenzenesulfonate, a higher fatty acid amide, a higher fatty acid ester, or a wax.

[0055] Examples of antistatic agents include low-molecular-weight antistatic agents such as nonionic, anionic, cationic, or amphoteric surfactants, and polymeric antistatic agents such as polymeric compounds. Nonionic surfactants include polyethylene glycol-based nonionic surfactants such as higher alcohol ethylene oxide adducts, fatty acid ethylene oxide adducts, higher alkylamine ethylene oxide adducts, and polyolefin glycol ethylene oxide adducts; polyhydric alcohol-based nonionic surfactants such as polyethylene oxide, glycerin fatty acid esters, pentaerythritol fatty acid esters, sorbitol or sorbitan fatty acid esters, polyhydric alcohol alkyl ethers, and alkanolamine fatty amides. Examples of anionic surfactants include carboxylates such as alkali metal salts of higher fatty acids; sulfate ester salts such as higher alcohol sulfate ester salts and higher alkyl ether sulfate ester salts; sulfonates such as alkylbenzene sulfonates, alkyl sulfonates, and paraffin sulfonates; and phosphate ester salts such as higher alcohol phosphate ester salts. Examples of cationic surfactants include quaternary ammonium salts such as alkyltrimethylammonium salts. Examples of amphoteric surfactants include amino acid-type amphoteric surfactants such as higher alkylaminopropionates, and betaine-type amphoteric surfactants such as higher alkyldimethylbetaine and higher alkyldihydroxyethylbetaine. Among these, anionic surfactants are preferred, and sulfonates such as alkylbenzenesulfonates, alkylsulfonates, and paraffin sulfonates are particularly preferred.

[0056] Examples of polymeric antistatic agents include ionomers and block polymers having polyethylene glycol as a hydrophilic moiety. Examples of ionomers include the ionomer described in JP 2010-132927 A. Examples of polymers having polyethylene glycol as a hydrophilic moiety include polyether ester amide described in JP 7-10989 A, polymers composed of polyolefin and polyethylene glycol described in U.S. Pat. No. 6,552,131 A, and polymers composed of polyester and polyethylene glycol described in JP 2016-023254 A.

[0057] Fluorescent brighteners are compounds that absorb ultraviolet light from sunlight or artificial light, convert it into violet-blue visible light, and radiate it to enhance the whiteness and blueness of molded articles through their fluorescent effect. Examples of fluorescent brighteners include the benzoxazole-based compound CI Fluorescent Brightener 184, the coumarin-based compound CI Fluorescent Brightener 52, and the diaminostilbene disulfonic acid-based compounds CI Fluorescent Brighteners 24, 85, and 71.

[0058] Examples of colorants include pigment red 1, 2, 3, 9, 10, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 228, 229, 230, 231, 232, 233, 234, 235, 236, 237, 238, 239, 240, 241, 242, 243, 244, 245, 246, 247, 248, 249, 250, 251, 252, 253, 254, 255, 256, 257, 258, 259, 260, 261, 262, 263, 264, 265, 266, 267, 268, 269, 270, 271, 272, 273, 274, 275, 276, 277, 278, 279, 280, 281, 282, 283, 284, 285, 286, 287, 288 27, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71; Pigment Yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 1 25, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180, 185; Pigment Green 7, 10, 36; Pigment Blue 15, 15:1, 15:2, 15:3, 15:4, 15:5, 15:6, 22, 24, 29, 56, 60, 61, 62, 64; Pigment Violet 1, 15, Examples of dyes include pigments such as 19, 23, 27, 29, 30, 32, 37, 40, and 50, azo dyes, anthraquinone dyes, indigoid dyes, triarylmethane dyes, xanthene dyes, alizarin dyes, acridine dyes, stilbene dyes, thiazole dyes, naphthol dyes, quinoline dyes, nitro dyes, indamine dyes, oxazine dyes, phthalocyanine dyes, and cyanine dyes.

[0059] Examples of the neutralizing agent include the above-mentioned fatty acid metal salts and hydrotalcites.

[0060] In the first embodiment, the composition may be in the form of powder or granules, or may be a masterbatch further containing a synthetic resin.

[0061] Powder properties of the composition, such as the average particle size, angle of repose, loose bulk density, packed bulk density, and compressibility, are not particularly limited and can be determined appropriately. Specifically, the average particle size can be, for example, 0.1 to 100 μm, the angle of repose can be, for example, 20 to 70°, the loose bulk density can be, for example, 0.1 to 0.8 g / cm, the packed bulk density can be, for example, 0.2 to 1 g / cm, and the compression ratio can be, for example, 1 to 10. Here, the average particle size is the average particle size calculated from the particle size distribution measured by laser diffraction in accordance with JIS Z 8825, the angle of repose is the angle of repose measured by a cylindrical rotation method, the loose bulk density is the bulk density measured in accordance with JIS K 5101-12-1, and the packed bulk density is the bulk density measured in accordance with JIS K 5101-12-2, and the compression ratio is a value calculated by the following formula: (Compression ratio) = (tight bulk density) / (loose bulk density)

[0062] When the composition of the first embodiment is in powder form, examples of methods for producing the composition include, for example, a method of mixing a compound containing a group represented by the general formula (1) described above and, if necessary, other additives using a mixing device such as an FM mixer, mill roll, Banbury mixer, or super mixer to obtain a mixture. When the composition of the first embodiment is in granular form, examples of methods for producing the composition include, for example, a method of granulating the mixture obtained as described above using a tumbling granulation method, fluidized bed granulation method, agitation granulation method, crushing granulation method, compression granulation method, extrusion granulation method, or dissolution granulation method. When the composition of the first embodiment is a masterbatch containing a synthetic resin, examples of methods for producing the composition include, for example, a method of mixing a compound containing a group represented by the general formula (1) and, if necessary, other additives with the synthetic resin using the mixing device described above, followed by melt-kneading using a melt-kneading device such as a single-screw extruder or a twin-screw extruder.

[0063] Examples of methods for producing the package include filling a bag with the composition and then sealing the opening of the bag. When filling the bag with the composition, the air inside the bag may be suctioned to degas it, or the bag may be filled with an inert gas such as nitrogen gas or argon gas, or dry air. The temperature when filling the bag with the composition is not particularly limited and can be, for example, 10 to 50°C, preferably 15 to 30°C. The humidity when filling the bag with the composition is also not particularly limited and can be, for example, 10 to 90% RH, preferably 30 to 70% RH.

[0064] Next, as a second embodiment of the package of the present invention, a package in which the bag is a flexible container bag will be described.

[0065] A second embodiment of the package includes a bag and a composition containing a compound having a group represented by the general formula (1), the composition being sealed inside the bag, and the bag being a flexible container bag.

[0066] In the package of the second embodiment, the composition is sealed inside a bag. The ratio V1 / V2 of the volume V1 of the sealed composition to the volume V2 of the internal space of the bag can be, for example, 0.4 to 1, and preferably 0.5 to 0.9.

[0067] The weight of the composition enclosed inside the bag is not particularly limited, but can be, for example, 100 to 2,000 kg. From the viewpoint of achieving both efficient transport and ease of handling of the package, it is preferably 200 to 1,000 kg, and more preferably 500 to 800 kg.

[0068] In the second embodiment of the packaging body, the opening of the bag may be sealed by, for example, rubber band fastening, heat sealing, kraft band binding, resin rope binding, double-sided tape fastening, adhesive bonding, over-taping, sewing, or other methods.

[0069] Examples of the bag shape include a rectangular parallelepiped (including a cube), a cylindrical shape, a prism shape, a cone shape, a pyramid shape, a sphere shape, an ellipsoid shape, a pillow shape, a drum shape, etc. Among these, a cylindrical shape is preferred because it has excellent mechanical strength and high content discharge efficiency, and a rectangular parallelepiped shape is also preferred because it has high stability during loading and excellent loading efficiency.

[0070] The dimensions of the bag are not particularly limited. For example, if the bag is cylindrical, the diameter of the bottom surface can be 500 to 2,000 mm and the height can be 500 to 2,000 mm. If the bag is rectangular, the length of one side of the bottom surface can be 500 to 2,000 mm, and the ratio L' / W' of the length of the vertical side of the bottom surface L' to the length of the horizontal side W' can be 0.5 to 2.

[0071] The thickness of the bag is not particularly limited and can be, for example, 10 to 5,000 μm. From the viewpoint of achieving both mechanical strength and ease of handling, it is preferably 50 to 3,000 μm, and more preferably 100 to 1,500 μm.

[0072] Examples of the material for the bag include synthetic resin, paper, metal foil, etc. Among these, synthetic resin is preferred from the viewpoint of ease of handling and transportability. That is, the bag is preferably made of synthetic resin.

[0073] When the bag is made of a synthetic resin, examples of the synthetic resin include polyethylene-based resin, polypropylene-based resin, polyester-based resin, polyamide-based resin, polyvinyl chloride-based resin, etc. From the viewpoint of handling and transportability, polypropylene-based resin and polyethylene-based resin are preferred, polypropylene-based resin is more preferred, and homopolypropylene is even more preferred.

[0074] When the bag is made of synthetic resin, examples of the bag include a film bag made of a synthetic resin film, a woven fabric bag made of a synthetic resin woven fabric, a nonwoven fabric bag made of a synthetic resin nonwoven fabric, etc. Among these, a woven fabric bag is preferred from the viewpoint of making the bag excellent in mechanical strength.

[0075] When the bag is a woven fabric bag made of synthetic resin woven fabric, the woven fabric constituting the bag may be, for example, a plain weave fabric or a circular weave fabric, and among these, a circular weave fabric is preferred from the viewpoint of increasing the productivity of the bag and making the bag have excellent mechanical strength.

[0076] The method for producing the bag is not particularly limited, and any known method can be used. For example, when the bag is a woven fabric bag made of a synthetic resin woven fabric, the bag can be produced by weaving a flat yarn of synthetic resin produced by stretch extrusion molding.

[0077] In the package of the second embodiment, the composition may be sealed in the bag via an inner liner (inner bag). That is, the composition may be sealed in an inner liner, and the inner liner containing the composition may be sealed in the bag. Examples of the inner liner include a film bag made of a synthetic resin film such as low-density polyethylene (LDPE) or linear low-density polyethylene (LLDPE), and a film bag made of a metal foil film such as aluminum.

[0078] The composition in the package of the second embodiment may be the same as the composition described above as the composition included in the package of the first embodiment. In addition, the method for producing the package of the second embodiment may be the same as the method for producing the package of the first embodiment.

[0079] <Packaging> The package of this embodiment includes a packaging container and the above-described packaging body, and the packaging body is contained in the packaging container.

[0080] Since the package is housed in the packaging container, the package of this embodiment has excellent transportability.

[0081] Only one package may be contained in the packaging container, or two or more packages may be contained in the packaging container.

[0082] The packaging container is not particularly limited, and examples thereof include cardboard boxes and drums.

[0083] The shape and dimensions of the packaging container are not particularly limited and can be selected appropriately depending on the dimensions of the package.

[0084] In the package of this embodiment, the packaging container may further contain a cushioning material that fills at least a part of the space inside the packaging container.

[0085] Further embodiments of the present invention include, for example, the following. [1] Bag and a composition containing a compound containing a group represented by the following general formula (1); Equipped with A package in which the composition is sealed inside a bag. [ka] (In general formula (1), X 1 , X 2 and X 3 each independently represents an unsubstituted or substituted phenylene group, and *, **, and *** represent a bonding site to another atom. [2] The package described in [1], wherein the bag is made of synthetic resin. [3] The package according to [2], wherein the synthetic resin is a polyethylene-based resin. [4] The package according to any one of [1] to [3], wherein the bag is a heavy-duty bag. [5] The package according to any one of [1] to [3], wherein the bag is a flexible container bag. [6] A packaging container; [1] to [5], and a package according to any one of the items. Equipped with A package in which a package is contained in the packaging container. [7] [6] The package according to [6], wherein the packaging container is a cardboard box or a drum.

[0086] The present invention is not limited to the above-described embodiments. The above-described embodiments are merely examples, and anything that has substantially the same configuration as the technical idea described in the claims of the present invention and that exhibits similar effects is included within the technical scope of the present invention. [Example]

[0087] The present invention will be explained in more detail below by way of examples, but the present invention is not limited to the following examples in any way.

[0088] The compounds containing a group represented by general formula (1), antioxidants, lubricants, neutralizing agents, synthetic resins, bags and packaging containers used in the examples are as follows: [Compound containing a group represented by general formula (1)] Compound 1: Compound No. 19 (4'',4''''-bis[4',6'-bis(4-cyclohexylphenoxy)-1',3',5'-triazine-2'-oxy]biphenyl (CAS Registry Number 2761026-52-0)) [Antioxidants] Antioxidant-1: Tetrakis[methylene-3-(3',5'-tert-butyl-4'-hydroxyphenyl)propionate]methane Antioxidant-2: Tris(2,4-di-tert-butylphenyl)phosphite [Lubricant] Lubricant-1: Glycerol fatty acid monoester Lubricant-2: Stearic acid amide [Neutralizer] Neutralizer-1: Calcium stearate Neutralizer-2: Hydrotalcite (DHT-4A manufactured by Kyowa Chemical Industry Co., Ltd.) [Synthetic resin] Synthetic resin-1: Homopolypropylene (MFR = 8g / 10min at 230℃ and 2.16kg load) [bag] Bag-1: Rectangular bottom-sealed heavy-duty bag made of linear low-density polyethylene film, length 70 cm, width 54 cm, thickness 500 μm Bag-2: Rectangular bottom-sealed heavy-duty bag made of linear low-density polyethylene film, length 110 cm, width 80 cm, thickness 800 μm Bag-3: Cylindrical flexible container bag made of homopolypropylene flat yarn circular woven fabric, Type C as specified in JIS C61340-4-4:2015, base diameter 90 cm, height 80 cm Bag-4: Cylindrical flexible container bag made of homopolypropylene flat yarn circular woven fabric, Type C as specified in JIS C61340-4-4:2015, base diameter 110 cm, height 106 cm Bag-5: Cylindrical flexible container bag made of homopolypropylene flat yarn circular woven fabric, Type C as specified in JIS C61340-4-4:2015, base diameter 115 cm, height 120 cm Bag-6: Cylindrical flexible container bag made of homopolypropylene flat yarn circular woven fabric, Type C as specified in JIS C61340-4-4:2015, base diameter 125 cm, height 130 cm Bag-7: Cylindrical flexible container bag made of homopolypropylene flat yarn circular woven fabric, Type C as specified in JIS C61340-4-4:2015, base diameter 140cm, height 130cm Bag-8: A cubic flexible container bag made of a circular woven fabric of homopolypropylene flat yarn, Type C as specified in JIS C61340-4-4:2015, with a side length of 100 cm. Bag-9: A cube-shaped flexible container bag made of a circular woven fabric of homopolypropylene flat yarn, Type C as specified in JIS C61340-4-4:2015, with a side length of 110 cm. Bag-10: A cube-shaped flexible container bag made of a circular woven fabric of homopolypropylene flat yarn, Type C as specified in JIS C61340-4-4:2015, with a side length of 120 cm. [Packaging container] Packaging container-1: rectangular cardboard box, length 34.5cm, width 14cm, depth 27cm Packaging container-2: rectangular cardboard box, length 31.5cm, width 20cm, depth 30cm Packaging container-3: rectangular cardboard box, length 36.5cm, width 22cm, depth 33cm Packaging container-4: rectangular cardboard box, length 37.5cm, width 29.5cm, depth 28cm Packaging container-5: rectangular cardboard box, length 34.5cm, width 29.5cm, depth 38cm Packaging container-6: rectangular cardboard box, length 34.5cm, width 29.5cm, depth 43cm Packaging container-7: Cylindrical steel drum, bottom diameter 28.8cm, height 35.3cm Packaging container-8: Cylindrical steel drum, base diameter 39.5cm, height 58cm Packaging container-9: Cylindrical steel drum, base diameter 45cm, height 71.5cm

[0089] <Preparation of the composition> (Composition-1) The powder consisting of Compound-1 was designated as Composition-1. (Composition-2) Compound-1, lubricant-1 and neutralizer-1 were mixed in a mass ratio of 1:1:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.). The resulting powder was designated Composition-2. (Composition-3) Compound-1, lubricant-1 and neutralizer-2 were mixed in a mass ratio of 1:1:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.). The resulting powder was designated as composition-3. (Composition-4) Compound-1, lubricant-2 and neutralizer-1 were mixed in a mass ratio of 1:1:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.). The resulting powder was designated Composition-4. (Composition-5) Compound-1, lubricant-2 and neutralizer-2 were blended in a mass ratio of 1:1:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.). The resulting powder was designated Composition-5. (Composition-6) Compound-1, antioxidant-1, antioxidant-2, and neutralizer-1 were blended in a mass ratio of 1:1:2:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.), and the resulting powder was granulated at a granulation temperature of 90°C using a disc pelletizer (F-5 / 11-175D manufactured by Dalton Co., Ltd.) to obtain cylindrical granules with a diameter of 3 mm and a height of 5 to 9 mm. This was designated Composition-6. (Composition-7) Compound-1, antioxidant-1, antioxidant-2, and neutralizer-1 were blended in a mass ratio of 2:1:2:1 and mixed at 1000 rpm for 1 minute using an FM mixer (FM200 manufactured by Mitsui Mining Co., Ltd.), and the resulting powder was granulated at a granulation temperature of 90°C using a disc pelletizer (F-5 / 11-175D manufactured by Dalton Co., Ltd.) to obtain cylindrical granules with a diameter of 3 mm and a height of 5 to 9 mm. This was designated Composition-7. (Composition-8) Synthetic resin-1, compound-1, antioxidant-1, antioxidant-2, and neutralizer-1 were blended in a mass ratio of 75:5:5:10:5 and mixed for 30 minutes using a rocking mixer (Aichi Electric Co., Ltd. RM-150). The resulting mixture was melt-kneaded using a twin-screw extruder (The Japan Steel Works, Ltd. TEX-28V) under processing conditions of a resin temperature of 230 ° C and a screw speed of 150 rpm, and then granulated to obtain a pellet-shaped polypropylene masterbatch. This was designated Composition-8. <Manufacturing of packaging and packaging>

[0090] (Examples 1 to 104) Under an environment of a temperature of 25°C and a humidity of 50% RH, the compositions shown in Tables 1 to 3 were filled into bags shown in the following Tables 1 to 3 in the amounts shown in Tables 1 to 3, and the openings of the bags were sealed with rubber bands. In this way, the packages of Examples 1 to 104 were obtained. The packages thus obtained were placed in the packaging containers shown in Tables 1 to 3, and the openings of the packaging containers were then sealed, to obtain the packages of Examples 1 to 104.

[0091] (Examples 105 to 232) Under an environment of a temperature of 25°C and a humidity of 50% RH, the compositions shown in Tables 4 to 6 were filled into bags shown in the following Tables 4 to 6 in the amounts shown in Tables 4 to 6, and the openings of the bags were tied and sealed with a rope made of polypropylene resin, thereby obtaining the packages of Examples 105 to 232.

[0092] [Table 1]

[0093] [Table 2]

[0094] [Table 3]

[0095] [Table 4]

[0096] [Table 5]

[0097] [Table 6]

Claims

1. Bag and a composition containing a compound containing a group represented by the following general formula (1); Equipped with A package in which the composition is sealed inside the bag. 【Chemical 1】 (In general formula (1), X 1 , X 2 and X 3 each independently represents an unsubstituted or substituted phenylene group, and *, **, and *** represent a bonding site to another atom.

2. 2. The package according to claim 1, wherein the bag is made of synthetic resin.

3. 3. The package according to claim 2, wherein the synthetic resin is a polyethylene-based resin.

4. The package according to any one of claims 1 to 3, wherein the bag is a heavy-duty bag.

5. The package according to any one of claims 1 to 3, wherein the bag is a flexible container bag.

6. A packaging container; A packaging body according to any one of claims 1 to 3; Equipped with A package in which the packaging body is contained in the packaging container.

7. 7. The package according to claim 6, wherein the packaging container is a cardboard box or a drum.