Laminated magnet and motor

Abstract

To reduce variations in a coercive force (Hcj) caused by positions of a laminated magnet.SOLUTION: A laminated magnet 10 includes a plurality of plate magnets 11 laminated via an insulation bonding layer 13 containing inorganic crystals. Heavy rare earth elements do not exist in the central part 20C of a particle 20 existing 200 μm from a surface S of each of the plate magnets 11 and exist in the range of 10 nm of a surface layer 20A of the particle 20. In a laminated magnet cross section, when a line analysis is performed at 0.1 μm intervals on a straight line L2 extending in a lamination direction, peaks of the heavy rare earth elements appear so as to repeat changes in concentration of the heavy rare earth elements.SELECTED DRAWING: Figure 5

Description

[Technical Field]

[0001] The present disclosure relates to laminated magnets and motors. [Background technology]

[0002] Patent Document 1 discloses a rare earth magnet having a resistive layer formed on the surface of a magnet body, and also shows a laminated magnet in which a plurality of rare earth magnets are stacked and molded with resin. Furthermore, various magnets have been proposed with the aim of reducing eddy current loss (for example, Patent Documents 2-4). [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 2017-174962 [Patent Document 2] Japanese Patent Application Laid-Open No. 2013-219911 [Patent Document 3] Japanese Patent Application Laid-Open No. 2007-157903 [Patent Document 4] Japanese Patent Application Laid-Open No. 2003-164083 Summary of the Invention [Problem to be solved by the invention]

[0004] In recent years, there have been various demands for laminated magnets. For example, there are cases where the coercive force (Hcj) of a laminated magnet varies greatly depending on the part of the magnet, and there is a demand to reduce this variation. The present disclosure has been made in consideration of the above-mentioned circumstances, and aims to reduce variations in coercive force (Hcj) depending on the location of a laminated magnet. The present disclosure can be realized in the following forms. [Means for solving the problem]

[0005] [1] A laminated magnet in which a plurality of plate magnets are stacked via an insulating bonding layer containing inorganic crystals, The two adjacent plate magnets are separated by the insulating bonding layer, and are therefore not in contact with each other; the plate magnet contains a rare earth element; The heavy rare earth element is not present in the center of the particle located 200 μm from the surface of the plate magnet, but is present within a 10 nm range of the surface layer of the particle, A laminated magnet in which, when an imaginary line passing through the center of gravity of the laminated magnet and extending in the stacking direction is taken, and the laminated magnet is cut on an imaginary plane containing the imaginary line so that the cross-sectional area of ​​the laminated magnet is maximized, line analysis is performed at 0.1 μm intervals on the line extending in the stacking direction, and peaks of the heavy rare earth element appear, with repeated light and dark concentrations of the heavy rare earth element. [Effects of the Invention]

[0006] According to the present disclosure, it is possible to reduce variations in coercive force (Hcj) depending on the location of the laminated magnet. [Brief explanation of the drawings]

[0007] [Figure 1] FIG. 1 is a perspective view schematically illustrating an example of a laminated magnet. [Figure 2] FIG. 2 is a top view of a laminated magnet. [Figure 3] FIG. 3 is a cross-sectional view of the magnet laminate of FIG. 2 cut along an imaginary plane. [Figure 4] FIG. 2 is an explanatory diagram showing a cross section of a plate magnet 200 μm from its surface. [Figure 5] FIG. 1 is an explanatory diagram showing the cross section of a particle located 200 μm from the surface of a plate magnet. [Figure 6] FIG. 1 is an explanatory diagram illustrating the concept of parallelism. [Figure 7] FIG. 1 is an explanatory diagram illustrating the concept of parallelism. [Figure 8] FIG. 2 is a cross-sectional view illustrating an insulating bonding layer whose thickness is to be measured. [Figure 9] FIG. 10 is a perspective view schematically showing another example 2 of the magnet laminate. [Figure 10] FIG. 10 is a top view of another example 2 of the laminated magnet. [Figure 11] FIG. 11 is a cross-sectional view of the magnet laminate of FIG. 10 cut along an imaginary plane. [Figure 12] FIG. 2 is a cross-sectional view schematically illustrating a part of a motor. [Figure 13] FIG. DETAILED DESCRIPTION OF THE INVENTION

[0008] [2] The magnet laminate according to [1], wherein the inorganic crystal is at least one selected from the group consisting of fluorides of Group 2A of the periodic table and light rare earth oxides. [3] The laminated magnet according to [1] or [2], wherein the concentration of light rare earth elements in the range from the interface between the plate magnet and the insulating bonding layer to a depth of 10 μm on the plate magnet side is 10% or more higher than that in the center of the plate magnet. [4] When the cross section of the laminated magnet is observed, A laminated magnet according to any one of [1] to [3], wherein, when the parallelism of each of the plurality of plate magnets is calculated, which is the angle between a first line connecting both ends of the surface on one end side in the stacking direction and a second line connecting both ends of the surface on the other end side, the parallelism of at least one-third of the plurality of plate magnets is 3° or less. [5] A motor having the laminated magnet according to any one of [1] to [4]. The present disclosure will be described in detail below. In this specification, when a numerical range is indicated using "-", it is assumed that both the lower and upper limits are included unless otherwise specified. For example, the expression "10-20" includes both the lower limit "10" and the upper limit "20". In other words, "10-20" has the same meaning as "10 or more and 20 or less". Furthermore, in this specification, the upper and lower limits of each numerical range can be arbitrarily combined. Hereinafter, the Z-axis direction in each figure is the arrangement direction (stacking direction) of the multiple plate magnets 11. The direction perpendicular to the Z-axis direction is the X-axis direction (also referred to as the horizontal direction), and the direction perpendicular to the Z-axis direction and the X-axis direction is the Y-axis direction (also referred to as the vertical direction). It should be noted that all of the drawings are conceptual diagrams for explaining the disclosed contents and do not accurately depict actual dimensions.

[0009] 1.Laminated magnet 10 The laminated magnet 10 is formed by stacking a plurality of plate magnets 11 via insulating bonding layers 13 containing inorganic crystals. Two adjacent plate magnets 11, 11 are separated by the insulating bonding layers 13 and are therefore not in contact with each other.

[0010] (1) Plate magnet 11 The plate magnet 11 contains a rare earth element, and when the entire plate magnet 11 is taken as 100 mass %, The total amount of rare earth elements is 28.50 mass% or more and 31.75 mass% or less, The Co (cobalt) content is 0.80 mass% or more and 1.00 mass% or less, The Cu (copper) content is 0.02 mass% or more and 0.18 mass% or less, The content of Al (aluminum) is 0.12 mass% or more and 0.28 mass% or less. The total content of Ga (gallium) is 0.15 mass% or more and 0.25 mass% or less, The content of B (boron) is 0.92% by mass or more and 1.02% by mass or less, The balance is made up of Fe (iron) and unavoidable impurities. When the entire plate magnet 11 is taken as 100% by mass, the amount of the heavy rare earth element is preferably 0.5% by mass or less.

[0011] The heavy rare earth element is not present in the central portion 20C of the particle 20 located 200 μm from the surface S of the plate magnet 11, but is present in a range of 10 nm in the surface layer 20A of the particle 20. Furthermore, if a virtual line L1 that passes through the center of gravity G1 of the magnet laminate 10 and extends in the stacking direction is taken, and the cross section of the magnet laminate 10 is cut along a virtual plane VP that includes the virtual line L1 so that the cross-sectional area of ​​the magnet laminate 10 is maximized, line analysis is performed at 0.1 μm intervals on a line L2 that extends in the stacking direction. Peaks of heavy rare earth element concentration appear, with repeated variations in the heavy rare earth element concentration. Line analysis can be performed using a field emission scanning electron microscope (e.g., JSM-7001F manufactured by JEOL Ltd.).

[0012] Examples of rare earth elements include one or more selected from the group consisting of neodymium (Nd), praseodymium (Pr), terbium (Tb), dysprosium (Dy), samarium (Sm), yttrium (Y), scandium (Sc), lanthanum (La), cerium (Ce), europium (Eu), gadolinium (Gd), holmium (Ho), ytterbium (Yb), and lutetium (Lu). Among these, it is preferable to include one or more of Nd, Pr, Dy, and Tb as the rare earth element, and it is more preferable to include Nd as the main component. Note that "containing Nd as the main component" means that the content (mass %) of Nd is the highest among the rare earth elements.

[0013] The composition of the plate magnet 11 is NdFe 14 It is preferable that the permanent magnet has a main phase of B. From the viewpoint of having good magnetic properties, the plate magnet 11 is preferably a rare earth sintered magnet. From the viewpoint of increasing the magnetic flux density, the total amount of rare earth elements is preferably 28.50% by mass or more and 31.75% by mass or less, more preferably 28.50% by mass or more and 30.90% by mass or less, and even more preferably 28.50% by mass or more and 30.10% by mass or less. The total amount of rare earth elements in plate magnet 11 can be measured by fluorescent X-ray analysis. The total amount of rare earth elements can be adjusted by changing the content of rare earth elements in the raw materials of plate magnet 11 and insulating bonding layer 13.

[0014] The Co (cobalt) content is preferably 0.80 mass % or more and 1.00 mass % or less, preferably 0.82 mass % or more and 0.98 mass % or less, and more preferably 0.84 mass % or more and 0.96 mass % or less. The Cu (copper) content is preferably 0.02 mass % or more and 0.18 mass % or less, preferably 0.04 mass % or more and 0.16 mass % or less, and more preferably 0.06 mass % or more and 0.14 mass % or less. The Al (aluminum) content is preferably 0.12 mass % or more and 0.28 mass % or less, preferably 0.14 mass % or more and 0.26 mass % or less, and more preferably 0.16 mass % or more and 0.24 mass % or less. The total content of Ga (gallium) is preferably 0.15 mass % or more and 0.25 mass % or less, preferably 0.17 mass % or more and 0.23 mass % or less, and more preferably 0.19 mass % or more and 0.21 mass % or less. The content of B (boron) is preferably 0.92 mass % or more and 1.02 mass % or less, preferably 0.94 mass % or more and 1.00 mass % or less, and more preferably 0.96 mass % or more and 0.98 mass % or less. The amounts of Co (cobalt), Cu (copper), Al (aluminum), Ga (gallium), and B (boron) can be measured by X-ray fluorescence analysis. The amounts of Co (cobalt), Cu (copper), Al (aluminum), Ga (gallium), and B (boron) can be adjusted by changing the content of each element in the raw materials of plate magnet 11 and insulating bonding layer 13.

[0015] The plate magnet 11 is made of Nd2Fe 14 It is preferable that B is the main phase. It is preferable that the plate magnet 11 has an Nd-rich phase that has a higher Nd content than the main phase. 14 B has a tetragonal crystal structure. The main phase of the plate magnet 11 can be identified as the component with the greatest peak intensity by XRD (X-ray diffraction) analysis of the plate magnet 11. 14 When the peak intensity of B is the largest, the plate magnet 11 is NdFe 14 It can be determined that the main phase is B.

[0016] The heavy rare earth element may be at least one selected from the group consisting of terbium (Tb), dysprosium (Dy), gadolinium (Gd), holmium (Ho), europium (Eu), thulium (Tm), ytterbium (Yb), and lutetium (Lu). Among these, the heavy rare earth element is preferably at least one of Dy and Tb.

[0017] Heavy rare earth elements satisfy the following requirements for heavy rare earth elements [1] and [2]. First, we will explain requirement [1] for heavy rare earth elements. As shown in Figures 4 and 5, heavy rare earth elements are not present in the central portion 20C of particles 20 located 200 μm from the surface of plate magnet 11, but are present within a 10 nm range of the surface layer 20A of particles 20. Figure 4 conceptually shows the location of particles 20 in plate magnet 11. Figure 5 schematically shows an EPMA analysis image using an SEM of a cross section of particle 20 located 200 μm from the surface of plate magnet 11 shown in Figure 4. The dotted lines in Figure 5 indicate heavy rare earth elements. Requirement [1] can be confirmed by EPMA image analysis of the cross section of the laminate magnet, as described below. Note that requirement [1] for heavy rare earth elements only needs to be satisfied in at least one of the particles 20 located within 200 μm from the surface S of plate magnet 11.

[0018] Next, we will explain requirement [2] for the heavy rare earth element. Requirement [2] is that when a virtual line L1 that passes through the center of gravity G1 of the magnet laminate 10 and extends in the stacking direction is taken, and the cross-section of the magnet laminate 10 is cut so that its cross-sectional area is maximized on a virtual plane VP that includes the virtual line L1, line analysis is performed at 0.1 μm intervals on a line L2 that extends in the stacking direction, and peaks of the heavy rare earth element concentration appear, with repeated variations in the concentration of the heavy rare earth element. The line L2 that extends in the stacking direction may be the same line as the virtual line L1, as shown in Figure 3. The dotted lines in Figure 3 schematically show heavy rare earth elements. Heavy rare earth elements are concentrated near the surface of plate magnet 11, with a lower abundance in the center (away from the surface) of plate magnet 11 compared to near the surface. Therefore, when a line analysis is performed on line L2 extending in the stacking direction, the surface, center, and surface regions of multiple plate magnets 10 are repeated, resulting in a peak of heavy rare earth element concentration that appears as if the heavy rare earth element concentration is repeatedly increased or decreased. In manufacturing the magnet laminate 10, compound powder containing a heavy rare earth element is added to the raw material of the insulating bonding layer 13 and hot pressed, thereby satisfying the requirements for the heavy rare earth element [1][2].

[0019] By satisfying the requirements [1] and [2] for the heavy rare earth elements, the concentration of heavy rare earth elements will be finely repeated in each plate magnet when viewed as a whole magnet laminate 10, and it is presumed that this will reduce the variation in coercivity (Hcj) depending on the part of the magnet laminate 10. In manufacturing the magnet laminate 10, compound powder containing a heavy rare earth element is added to the raw material of the insulating bonding layer 13 and hot pressed, thereby satisfying the requirements for the heavy rare earth element [1][2].

[0020] The average thickness of each plate magnet 11 is preferably 1.5 mm or more and 4.0 mm or less, more preferably 2.0 mm or more and 3.0 mm or less, and even more preferably 2.0 mm or more and 2.8 mm or less. If the average thickness of the plate magnets 11 is 1.5 mm or more, it is easy to form the plate magnets 11 while ensuring an average degree of orientation. If the average thickness of the plate magnets 11 is 4.0 mm or less, it is easy to diffuse the heavy rare earth elements to the interior. Furthermore, if the average thickness is 4.0 mm or less, eddy current loss inside the magnet stack 10 can be suitably reduced. The dimensions of the plate magnets 11 in the direction perpendicular to the thickness are not particularly limited. For example, the plate magnets 11 can be 4 mm or more and 10 mm or less in length and 10 mm or more and 30 mm or less in width.

[0021] Next, the parallelism requirement will be explained with reference to Figures 6 and 7. In the present disclosure, this parallelism requirement is not a mandatory requirement, but an optional requirement that is desirably met. This requirement is that when observing the cross section of the magnet stack 10, the parallelism, which is the angle θ formed by a first line LA connecting both ends E1, E2 on the surface at one end in the stacking direction and a second line LB connecting both ends E3, E4 on the surface at the other end, is calculated for at least one-third of the plate magnets 11, and the average parallelism must be 3° or less. This requirement is confirmed by observing the cross section of the laminated magnet described above. First, for each of the multiple plate magnets 11 constituting the magnet stack 10, the parallelism is determined, which is the angle θ formed by a first line LA connecting both ends E1, E2 on the surface at one end in the stacking direction and a second line LB connecting both ends E3, E4 on the surface at the other end, as shown schematically in Figures 6 and 7. Then, it is confirmed whether the parallelism of at least one-third of the multiple plate magnets 11 is 3° or less. In the present disclosure, from the viewpoint of suppressing a decrease in the degree of orientation while realizing high durability in vibration and impact tests, the parallelism of at least one-third of the multiple plate magnets 11 is 3° or less, preferably 2° or less, and more preferably 1° or less. The average parallelism may be 0°. The parallelism can be adjusted by correcting warpage of the plate magnet 11 or by adjusting the parallelism through processing. It can also be adjusted by reducing the deviation in parallelism between the upper and lower punches of the pressure press used for lamination and pressure bonding.

[0022] When a virtual line L1 passing through the center of gravity G1 of the magnet laminate 10 and extending in the stacking direction is taken and a cross section of the magnet laminate 10 cut along a virtual plane VP including the virtual line L1 so as to maximize the cross-sectional area, it is preferable that a light rare earth-rich phase (e.g., a Nd-rich phase (hereinafter simply referred to as the "Nd-rich phase")) having a light rare earth (e.g., Nd) concentration 10% or more higher than that of the center of the magnet laminate 11 is present in the area from the interface I between the magnet laminate 11 and the insulating bonding layer 13 to a depth of 10 μm on the magnet laminate 11 side. The center of the magnet laminate 11 refers to the location of the center of gravity G2 of the magnet laminate 11. Note that inorganic crystals (e.g., fluoride particles of a metal of Group 2A of the periodic table), which will be described later, may be present in the area from the interface I between the magnet laminate 11 and the insulating bonding layer 13 to a depth of 10 μm on the magnet laminate 11 side.

[0023] 3, a cross section cut by the imaginary plane VP shows a plurality of cut surfaces of the plate magnet 11. Each cut surface of the plate magnet 11 forms a rectangular planar figure. 9 to 11, the imaginary line L1 also extends in the Z-axis direction. The imaginary plane VP is a plane that includes the imaginary line L1.

[0024] (2) Insulating bonding layer 13 The main component of the insulating bonding layer 13 is not particularly limited. The main component of insulating bonding layer 13 is preferably one or more selected from glass, polyimide, epoxy resin, Al2O3, and the following inorganic crystals. Here, the main component refers to a substance whose content (mass %) is 50 mass % or more. The insulating bonding layer 13 contains inorganic crystals. The insulating bonding layer 13 preferably contains inorganic crystals as a main component. Incidentally, "containing inorganic crystals as a main component" means that the content of inorganic crystals in the insulating bonding layer 13 is 50% by mass or more. The content of inorganic crystals in the insulating bonding layer 13 is preferably 80% by mass or more, more preferably 90% by mass or more, and may be 100% by mass. The composition of insulating bonding layer 13 can be analyzed by the following method: The presence of inorganic crystals is determined by X-ray microanalysis or XRD analysis, and the content of inorganic crystals is calculated in combination with composition analysis by EPMA (Electron Probe Micro Analyser).

[0025] From the viewpoint of reducing eddy current loss, the inorganic crystal is preferably one or more selected from the group consisting of Group 2A fluorides of the periodic table and light rare earth oxides. The Group 2A fluorides of the periodic table are preferably one or more selected from the group consisting of CaF2, BaF2, SrF2, and MgF2. Among these, CaF2 is particularly preferred. The light rare earth oxide is preferably one or more selected from the group consisting of Nd2O3, Sm2O3, Pr2O3, and La2O3. When the entire inorganic crystal is taken as 100 mass %, insulating bonding layer 13 preferably contains 80 mass % or more, more preferably 90 mass % or more, and even more preferably 95 mass % or more of a fluoride of Group 2A of the periodic table as the inorganic crystal. The upper limit of the content of the fluoride of Group 2A of the periodic table is not particularly limited, and may be, for example, 100 mass %.

[0026] Furthermore, from the viewpoint of reducing eddy current loss due to the increased resistance of insulating bonding layer 13, it is preferable that the Group 2A elements of the periodic table are not diffused into sheet magnet 11. Here, "not diffused" means that the abundance of the Group 2A elements of the periodic table is 3 mass % or less in the range from the interface between sheet magnet 11 and insulating bonding layer 13 to a depth of 10 μm on the sheet magnet 11 side. The abundance of the Group 2A elements of the periodic table can be calculated using an EPMA composition analysis of a cross section of the laminated magnet.

[0027] When insulating bonding layer 13 is primarily composed of a Group 2A fluoride of the periodic table, the raw material for insulating bonding layer 13 preferably contains a compound of the above-mentioned heavy rare earth element in addition to the Group 2A fluoride of the periodic table. If the raw material for insulating bonding layer 13 contains a compound of the above-mentioned heavy rare earth element, the heavy rare earth element can be favorably diffused into plate magnet 11. The heavy rare earth element contained in the raw material for insulating bonding layer 13 diffuses into plate magnet 11 after heat treatment. Therefore, insulating bonding layer 13 of the obtained magnet laminate 10 contains almost no heavy rare earth element. There is no particular limitation on the mass ratio of the Group 2A fluoride of the periodic table to the compound of the heavy rare earth element in the raw materials of insulating bonding layer 13. The mass ratio of the Group 2A fluoride of the periodic table to the compound of the heavy rare earth element in the raw materials of insulating bonding layer 13 can be, for example, 20:80 to 40:60.

[0028] The average thickness of each insulating bonding layer 13 is not particularly limited. From the viewpoint of ensuring sufficient insulation, the average thickness of each insulating bonding layer 13 is preferably 5 μm or more, more preferably 9 μm or more, and even more preferably 12 μm or more. From the viewpoint of further suppressing a decrease in the degree of orientation and achieving a high level of high durability in a vibration impact test, the average thickness of each insulating bonding layer 13 is preferably 20 μm or less, more preferably 18 μm or less, and even more preferably 15 μm or less. From these viewpoints, the average thickness of the insulating bonding layer 13 is preferably 5 μm or more and 20 μm or less, more preferably 8 μm or more and 18 μm or less, and even more preferably 10 μm or more and 15 μm or less. The thickness of each insulating bonding layer 13 is measured as the distance between the plate magnets 11 located on both sides of the insulating bonding layer 13 by observing the cross section of the laminated magnet 10 with an SEM (scanning electron microscope).

[0029] The insulating bonding layer 13 is a layer that bonds the multiple plate magnets 11, 11 together in a stacked state. The insulating bonding layer 13 keeps two adjacent plate magnets 11, 11 from contacting each other. Therefore, even if layers with the same composition as the insulating bonding layer 13 are formed on the top, bottom, and side surfaces of the magnet stack 10, these layers do not keep the plate magnets 11, 11 from contacting each other, and therefore are not treated as "insulating bonding layers 13" for measuring the thickness T in this disclosure. For example, in Figure 8, the cross-hatched layers have the same composition as the insulating bonding layer 13, but are not treated as "insulating bonding layers 13" for measuring the thickness T.

[0030] The insulating bonding layer 13 is provided so as to be in direct contact with the plate magnet 11. The insulating bonding layer 13 also bonds (adheses) the plate magnets 11, 11 located on both sides. Such a laminated magnet 10 can be suitably formed by hot pressing.

[0031] The insulating bonding layers 13 may be provided along the orientation direction of the magnetic field of each plate magnet 11 (for example, the direction of the white arrow in FIG. 2), or along a direction intersecting the orientation direction (for example, the direction of the white arrow in FIG. 2). Note that, as shown in FIG. 12, when the magnet stack 10 is used as a motor magnet or the like, the insulating bonding layers 13 are preferably provided along the orientation direction of the plate magnets 11 (the X-axis direction in FIG. 12) from the perspective of efficiently reducing eddy current loss. With this configuration, the insulating bonding layers 13 are arranged approximately parallel to the direction in which the magnetic flux generated in the stator 31 passes through the magnet stack 10 (the X-axis direction in FIG. 12), thereby effectively reducing eddy current loss.

[0032] (3) Configuration of the magnet stack 10 From the viewpoint of reducing eddy current loss, it is preferable that 10 or more plate magnets 11 are used per 50 mm of dimension of the magnet stack 10 in the stacking direction, preferably 20 or more, and preferably 25 or more. There is no particular upper limit on the number of magnets, and it may be, for example, 42 or less.

[0033] 2. Manufacturing method of laminated magnet 10 There are no particular limitations on the method for manufacturing the magnet laminate 10. An example of a method for manufacturing the magnet laminate 10, in which plate magnets 11 and insulating bonding layers 13 are alternately stacked, will be described below.

[0034] (1) SC alloy preparation process A raw alloy (strip cast alloy (SC alloy)) containing rare earth elements, transition metal elements, boron, and the like is prepared.

[0035] (2) Hydrocracking process In a hydrogen atmosphere, the SC alloy is allowed to absorb hydrogen at a specified temperature (e.g., 200°C-300°C) for a specified time (e.g., 1 hour-5 hours), embrittling the grain boundaries (Nd-rich phase) of the SC alloy.

[0036] (3) Coarse grinding step, first lubricant addition step The SC alloy powder that has undergone the hydrogen cracking process is coarsely crushed (coarse crushing process). At this time, a lubricant may be added to the SC alloy powder (first lubricant addition process). This process may be carried out, for example, in an inert atmosphere (nitrogen atmosphere, argon atmosphere, etc.).

[0037] (4) Fine pulverization process, second lubricant addition process The SC alloy powder after the coarse pulverization step is then pulverized to a predetermined average particle size D50 (fine pulverization step). The average particle size D50 can be, for example, 2.0 μm-3.5 μm. At this time, to improve the flowability of the pulverized powder, a lubricant may be added to the pulverized SC alloy powder (second lubricant addition step). This step is preferably carried out in an inert atmosphere (such as a nitrogen atmosphere or an argon atmosphere).

[0038] (5) Powder filling process, orientation process, molding process The SC alloy powder after the pulverization process is filled into a mold. This process is preferably carried out in an inert atmosphere (such as a nitrogen atmosphere or an argon atmosphere). The mold has multiple molding spaces of a predetermined thickness. Each molding space is separated, for example, by multiple partition plates. A magnetic field is applied in a predetermined direction to the mold after the powder has been filled to align the orientation of the SC alloy powder. The SC alloy powder filled into the mold is then compressed to form an SC alloy compact. In this way, an SC alloy compact with a predetermined degree of orientation (for example, an average orientation of 90% or more) and a predetermined thickness (for example, a thickness of 0.5 mm to 4.0 mm) can be obtained without a cutting process.

[0039] (6) Mold removal process, first firing process The compact is removed from the mold (molding removal step). The compact is then fired at a predetermined firing temperature (e.g., 900°C-1200°C) for a predetermined time (e.g., 2 hours-5 hours) (first firing step). This firing is preferably carried out in a vacuum. Prior to this firing, heating at a temperature lower than the firing temperature may be carried out for dehydrogenation.

[0040] (7) Insulating bonding layer coating process The raw material for the insulating bonding layer 13 is applied to the surface of the sintered compact. The raw material for the insulating bonding layer 13 can be, for example, a mixture of raw material powder of inorganic crystal components, compound powder containing a heavy rare earth element, and a solvent. The raw material for the insulating bonding layer 13 may be applied to at least one main surface of the compact, or may be applied to both main surfaces. The main surface of the compact is the surface corresponding to the main surface 11A of the plate magnet 11. The raw material for the insulating bonding layer 13 may be applied to the entire surface of the compact, i.e., both main surfaces and side surfaces if the compact is plate-shaped.

[0041] (8) Laminate temporary fixing process A predetermined number of compacts coated with the raw material of the insulating bonding layer 13 are stacked and temporarily fixed. Hereinafter, the stack of temporarily fixed compacts will also be referred to as a laminate. This method makes it possible to manufacture plate magnet 11 without the need for a cutting process or other process to cut out plate-shaped magnets from a larger magnet.

[0042] (9) Hot pressing process The temporarily fixed laminate is placed in a hot press mold and subjected to uniaxial hot pressing. This process is carried out, for example, under a vacuum atmosphere (for example, 10 -3 Pa-10 -4 The hot pressing may be carried out under a pressure of 1000 psi (1000 Pa) or in an inert atmosphere (such as a nitrogen atmosphere or an argon atmosphere). The hot pressing temperature may be, for example, 700°C to 1100°C. The hot pressing time may be, for example, 1 second to 1 hour. The hot pressing pressure is preferably 3 MPa or more, more preferably 5 MPa or more, and even more preferably 8 MPa or more. The upper limit of the hot pressing pressure is not particularly limited, and is, for example, 100 MPa or less. The heat treatment time for the hot pressing may be, for example, 10 minutes to 20 hours. Through the above series of steps, a magnet stack 10 is manufactured, which includes plate magnets 11 and insulating bonding layers 13. The magnet stack 10 is formed by bonding a plurality of plate magnets 11 together with the insulating bonding layers 13, forming an integrated unit.

[0043] The hot pressing process allows the heavy rare earth elements (Tb, Dy, etc.) contained in the raw material of the applied insulating bonding layer 13 to diffuse into the inside of the plate magnet 11. The hot pressing process also allows the plate magnet 11 (for example, NdFe 14 The rare earth component (Nd component) in B) flows out to the surface of plate magnet 11, forming a Nd-rich surface layer near the interface with insulating bonding layer 13 (e.g., a layer containing CaF2) in plate magnet 11. Furthermore, this hot pressing process can sufficiently thin insulating bonding layer 13, and can also make the thickness of insulating bonding layer 13 uniform.

[0044] The laminated magnet 10 obtained in the above manner can be regarded as a laminated magnet manufactured by hot pressing (hot uniaxial pressing) a laminate in which the raw material of the insulating bonding layer 13 is sandwiched between at least a pair of plate magnets 11, 11 (sintered bodies of SC alloy), so that pressure is applied in a direction that crushes the raw material of the insulating bonding layer 13. Furthermore, the laminated magnet 10 can be understood as a laminated magnet manufactured by arranging a first plate magnet 11 (sintered body of SC alloy), the raw material of the insulating bonding layer 13, and a second plate magnet 11 (sintered body of SC alloy) in this order to form a laminate, and then heating the laminate while applying pressure to the first plate magnet 11 and the second plate magnet 11 from both sides. The raw material of insulating bonding layer 13 preferably contains inorganic crystals. The raw material of insulating bonding layer 13 may further contain a component containing a heavy rare earth element. For example, the raw material of insulating bonding layer 13 preferably contains 20% by mass to 40% by mass of CaF2 and 60% by mass to 80% by mass of TbF3, where the total of CaF2 and TbF3 is 100% by mass.

[0045] 3. Uses of laminated magnet 10 The uses of the magnet laminate 10 are not particularly limited. The magnet laminate 10 is suitable as a magnet for motors. The magnet laminate 10 has low eddy current loss generated internally and is resistant to deterioration over time, which can contribute to one or more of the following effects: motor miniaturization, suppression of heat generation, improved heat resistance, and improved heat dissipation. Furthermore, when the insulating bonding layer 13 of the magnet laminate 10 is primarily composed of inorganic crystals, its insulating performance is less susceptible to changes due to the effects of humidity, temperature, and deterioration over time than insulating bonding layers made of resin or the like. Therefore, the magnet laminate 10 is useful in a variety of applications where resistance to changes in insulating performance is desired.

[0046] An example of a motor 30 equipped with a magnet laminate 10 will be described below with reference to FIGS. 12 and 13. The motor 30 includes a stator 31 and a rotor 33 arranged inside the stator 31. The magnet laminate 10 is arranged in the rotor 33, and a winding (not shown) is arranged in the stator 31. The motor 30 in FIG. 12 is an inner rotor type in which the magnets are arranged on the inside (rotating shaft side) and the windings are arranged on the outside. The motor is not limited to the inner rotor type. For example, the motor may be an outer rotor type in which the windings are arranged on the inside (rotating shaft side) and the magnets are arranged on the outside.

[0047] The rotor 33 includes a rotating shaft 34, a rotating core 35, and a plurality of laminated magnets 10. The rotating core 35 is formed by laminating electromagnetic steel sheets. A shaft hole 37 is formed in the center of the rotating core 35. The rotating shaft 34 is inserted into the shaft hole 37. A plurality of magnet holes 39 are formed in the rotating core 35 at intervals in the circumferential direction. A laminated magnet 10 is inserted into each magnet hole 39.

[0048] 4. Actions and Effects of the Present Embodiment The magnet laminate 10 of this embodiment can reduce variations in coercive force (Hcj) depending on the location of the magnet laminate. When the inorganic crystal of insulating bonding layer 13 is one or more selected from the group consisting of fluorides of Group 2A of the periodic table and light rare earth oxides, eddy current loss can be reduced after being held at a high temperature of 100°C or higher for 200 hours. In each plate magnet 11, the depth 1 If the light rare earth rich phase is provided in the range of 0 μm, the stress difference between the plate magnet 11 and the insulating bonding layer 13 is alleviated, resulting in high durability in vibration and impact tests. If the magnet laminate 10 of this embodiment satisfies the requirement for parallelism, it is possible to more effectively suppress a decrease in the degree of orientation (variation in the residual magnetic flux density Br). [Example]

[0049] The present disclosure will be described in more detail below with reference to examples. In Table 1 below, "LRE" represents the "amount of light rare earth elements," "HRE" represents the "amount of heavy rare earth elements," and "TRE" represents the "amount of total rare earth elements."

[0050] 1. Fabrication of laminated magnets Example 1 Process (1): SC alloy preparation process Nd / Pr alloy, alloy containing Co, Cu, Al, Ga, and metal single material are mixed to produce strip cast alloy (SC alloy) (for example, composition: NdFe 14 B) was prepared under an argon atmosphere. The SC alloy was a plate-shaped powder with the main surface dimensions of 10 mm × 10 mm to 20 mm × 20 mm.

[0051] Step (2): Hydro-crushing step The SC alloy was allowed to absorb hydrogen in a hydrogen furnace (hydrogen atmosphere, 200°C, 2 hours), embrittling the grain boundaries (neodymium-rich phase) of the SC alloy.

[0052] Step (3): Coarse grinding step, first lubricant addition step A lubricant was added to the SC alloy powder that had undergone the hydrogen crushing process. Methyl caprylate was used as the lubricant. The lubricant was mixed at a ratio of 0.03% to 0.07% by mass relative to the amount of SC alloy. While adding the lubricant to the SC alloy powder, the powder was coarsely crushed using a stirrer in a nitrogen or argon atmosphere. The average particle size of the SC alloy after coarse crushing was 50 μm to 500 μm.

[0053] Step (4): Fine pulverization step, second lubricant addition step The SC alloy powder after adding the lubricant was finely pulverized in a nitrogen atmosphere using a jet mill. The average particle size D50 after fine pulverization was 2.0 μm-3.5 μm. A lubricant (methyl laurate) was added to the finely pulverized SC alloy powder at a mixing ratio of 0.05% to 0.1% by mass relative to the amount of SC alloy.

[0054] Step (5): Powder filling step, orientation step, molding step The SC alloy powder after the pulverization and second lubricant addition processes was filled into each molding space of a mold equipped with multiple partition plates in a nitrogen atmosphere. Each compact formed in each molding space corresponds to each plate magnet to be stacked in a subsequent process. In the samples of the examples and comparative examples, each plate magnet was 2 mm thick and had a rectangular shape with dimensions of 5 mm x 16 mm. After the powder was filled into the mold, a magnetic field (e.g., 4 T) was applied in the planar direction of each compact (perpendicular to the thickness direction) to align the orientation of the SC alloy powder. The SC alloy powder filled into the mold was pressed to form an SC alloy compact. The pressure molding conditions were: pressure: 5 MPa - 20 MPa, packing density: 3.0 g / cm 3 -4.0g / cm3 , relative density: 40%-52%.

[0055] Step (6): Mold removal step, first firing step The outer frame was removed from the mold, and a series of alternating compacts and partition plates (the material to be fired) was prepared. To dehydrogenate and remove organic matter, the material to be fired (with the partition plates) was heated at 500°C for 3-4 hours in an Ar atmosphere. The material to be fired (with the partition plates) was then fired in a vacuum atmosphere at 930-1050°C for 3 hours.

[0056] Step (7): Insulating adhesive layer coating step After the first firing step, the firing mold was removed from the object to be fired, and Tb2O3 (terbium oxide) was applied to six surfaces of the magnet before lamination.

[0057] Step (8): Laminate temporary fixing step Twenty-five Tb2O3-coated magnets were stacked in air and temporarily fixed. The number of layers was adjusted so that the dimension of the laminated magnet in the stacking direction was 50 mm. This method makes it possible to manufacture plate-shaped magnets without the need for a cutting process or other process to cut out plate-shaped magnets from a larger magnet. After that, Tb was diffused from Tb2O3 by heat treatment at 800℃-870℃ without pressure.

[0058] Step (9): Hot pressing step The temporarily fixed laminate was placed in a hot press mold and subjected to uniaxial hot pressing. This process was carried out under a vacuum atmosphere (10 -3 The hot pressing conditions were as follows: <Hot pressing conditions> Example 1: 800°C, 3 MPa, 10 min The porous Tb2O3 was then impregnated with epoxy resin and heat-treated at 180°C to form an insulating bonding layer. In this way, the sample of Example 1 was prepared.

[0059] <Example 2-8> First, after carrying out steps (1) to (6) of Example 1, the following steps were carried out to prepare samples of Examples 2 to 9.

[0060] Step (7): Insulating adhesive layer coating step After the first firing step, the firing mold was removed from the object to be fired, and the raw material for the insulating bonding layer was applied to six surfaces of the magnet before lamination. The raw material for the insulating bonding layer was a mixture of the compound powder of the main components listed in Table 1, Tb compound powder, and a solvent. The proportion of Tb compound powder in the raw material for the insulating bonding layer was 10-20% by mass. The thickness of the insulating bonding layer was controlled by adjusting the thickness of the applied raw material for the insulating bonding layer. The raw material for the insulating bonding layer was applied in the air using a spray method.

[0061] Step (8): Laminate temporary fixing step Twenty-five magnets coated with the raw material for the insulating bonding layer were stacked in air and temporarily fixed. The number of layers was adjusted so that the dimension of the laminated magnet in the stacking direction was 50 mm. This method makes it possible to manufacture plate-shaped magnets without the need for a cutting process or other process to cut out plate-shaped magnets from a larger magnet. Thereafter, a pressureless heat treatment was carried out at 875°C to first diffuse the heavy rare earth (Tb) contained in the insulating bonding layer.

[0062] Step (9): Hot pressing step The temporarily fixed laminate was placed in a hot press mold and subjected to uniaxial hot pressing. This process was carried out under a vacuum atmosphere (10 -3 The hot pressing conditions were as follows: <Hot pressing conditions> Example 2: 800°C, 3 MPa, 10 min Example 3: 700°C, 50 MPa, 15 min Example 4 1100°C - 10 MPa - 10 min Example 5: 880°C, 30 MPa, 12 min Example 6 820°C-50 MPa-10 min Example 7 825°C-50 MPa-15 min Example 8 975°C-50 MPa-60 min In this manner, a sample of Example 2-8 was prepared.

[0063] <Examples 9 to 15> First, after carrying out steps (1) to (8) of Example 2, the following steps were carried out to prepare samples of Examples 9 to 15.

[0064] Step (9): Hot pressing step The temporarily fixed laminate was placed in a hot press mold and subjected to uniaxial hot pressing. This process was carried out under a vacuum atmosphere (10 -3 The hot pressing conditions were as follows: Thereafter, each specimen was subjected to annealing treatment for 5 hours at a pressure 5-10 MPa lower than that during hot pressing and at a temperature 30-50°C higher. <Hot pressing conditions> Example 9 850°C-20 MPa-15 min Example 10: 875°C, 60 MPa, 15 min Example 11 900°C-75 MPa-15 min Example 12 925°C-60 MPa-20 min Example 13 850°C-50 MPa-20 min Example 14: 850°C, 40 MPa, 30 min Example 15 850°C-55 MPa-25 min In this manner, samples of Examples 9 to 15 were prepared.

[0065] <Comparative Example 1> A sample of Comparative Example 1 was produced in the same manner as in Example 1, except that step (7) of applying the insulating adhesive layer was performed as follows. Step (7): Insulating adhesive layer coating step After the first firing step, the firing mold was removed from the fired object, and the raw material for the insulating bonding layer was applied to six surfaces of the magnet before lamination. The raw material for the insulating bonding layer was a mixture of a compound powder (epoxy resin) with the main components listed in Table 1 and a solvent. The thickness of the insulating bonding layer was controlled by adjusting the thickness of the applied raw material. The raw material for the insulating bonding layer was applied in the air using a spray method.

[0066] <Comparative Example 2> A sample of Comparative Example 2 was produced in the same manner as in Example 1, except that step (7) of applying the insulating adhesive layer was performed as follows. Step (7): Insulating adhesive layer coating step After the first firing step, the firing mold was removed from the fired object, and the raw material for the insulating bonding layer was applied to six surfaces of the magnet before lamination. The raw material for the insulating bonding layer was a mixture of a compound powder (polyimide resin) with the main components listed in Table 1 and a solvent. The thickness of the insulating bonding layer was controlled by adjusting the thickness of the applied raw material. The raw material for the insulating bonding layer was applied in the air using a spray method.

[0067] <Comparative Example 3> In step (1) of preparing an SC alloy, the main raw materials of an Nd / Pr alloy, an alloy containing Co, Cu, Al, Ga, and Tb, and a metal element are mixed to produce a strip cast alloy (SC alloy) (for example, composition: NdFe 14 B) was prepared under an argon atmosphere. A sample of Comparative Example 3 was prepared in the same manner as in Example 2, except that step (7) of applying the insulating bonding layer was performed as follows. Step (7): Insulating adhesive layer coating step After the first firing step, the firing mold was removed from the sintered object, and the raw material for the insulating bonding layer was applied to six surfaces of the magnet before lamination. The raw material for the insulating bonding layer was a mixture of a compound powder (Al2O3) with the main component listed in Table 1 and a solvent. The thickness of the insulating bonding layer was controlled by adjusting the thickness of the applied raw material. The raw material for the insulating bonding layer was applied in the air using a spray method.

[0068] <Comparative Example 4> In Comparative Example 5, a single block-shaped magnet was produced instead of a laminated magnet. Specifically, in Comparative Example 5, the SC alloy powder after the fine pulverization step and the second lubricant addition step was filled into a molding die that was not provided with multiple partition plates. In Comparative Example 5, a block-shaped magnet was obtained in the same manner as in Example 1, except that (7) the insulating layer application step, (8) the laminate temporary fixing step, and (9) the hot pressing step were not performed.

[0069] 2. Characteristics of Examples and Comparative Examples Tables 1 and 2 summarize the properties of the magnets and insulating bonding layers of each example and comparative example. The "Main Component" column of the "Insulating Bonding Layer" in Table 1 indicates the compound with the largest amount (mass %) contained in the insulating bonding layer. Regarding the components of the insulating bonding layer, inorganic substances were identified using EPMA and XRD, and organic substances were identified using NMR and IR analysis. In both the examples and comparative examples, the content (mass %) of the main component was 65% or more when the entire insulating bonding layer was taken as 100% by mass.

[0070] We confirmed whether the requirements for heavy rare earth elements [1] were met as follows: An imaginary line was drawn that passes through the center of gravity of the laminated magnet and extends in the stacking direction, and the laminated magnet was cut in an imaginary plane that includes the imaginary line so that the cross-sectional area of ​​the laminated magnet is maximized. Images were analyzed using an EPMA.

[0071] Whether or not the heavy rare earth element requirement [2] was met was confirmed as follows: An imaginary line was drawn that passed through the center of gravity of the laminated magnet and extended in the lamination direction, and a line analysis was performed at 0.1 μm intervals on the line extending in the lamination direction on the cross section of the laminated magnet that was cut so that the cross-sectional area of ​​the laminated magnet was maximized on an imaginary plane that included the imaginary line. The line analysis was performed using a field emission scanning electron microscope (e.g., JEOL Ltd. JSM-7001F). In the "Specific structure of heavy rare earth elements" column in Table 2, if both the requirements for heavy rare earth elements [1] and [2] are met, it is judged as "Yes," and in other cases it is judged as "No."

[0072] The "Light rare earth rich phase" column in Table 2 shows whether or not a light rare earth rich phase (Nd rich phase) with a light rare earth (Nd) concentration 10% or more higher than that at the center of the plate magnet was present in the range from the interface between the plate magnet and the insulating bonding layer to a depth of 10 μm on the plate magnet side, as determined by EPMA observation.

[0073] The parallelism was determined by observing the cross section of the laminated magnet. First, the parallelism of each of the plate magnets was determined. Then, it was confirmed whether the parallelism of at least one-third of the plate magnets was 3° or less.

[0074] [Table 1]

[0075] [Table 2]

[0076] 3.Performance evaluation (1) Hcj (coercive force) measurement Each sample (laminated magnet) was divided into three equal parts in the stacking direction, and measurement specimens measuring 2mm-7mm square were prepared from each of the three parts (upper, middle, and lower). Hcj was measured using a BH pulse tracer or VSM.

[0077] The evaluation was as follows: "A": The variation in the measurement values ​​for each measurement sample made from the three parts is 2% or more and less than 3%. "B": The variation in the measurement values ​​for each measurement sample made from the three parts is 3% or more and less than 5%. "C": The variation in the measurement values ​​for each of the measurement samples made from the three parts is 5% or more.

[0078] (2) Vibration and impact test The vibration and impact test was carried out in accordance with ISO-16750-3 (random wave vibration test) at a test temperature of 180°C.

[0079] The evaluation was as follows: "A": No peeling occurred even when tested for more than 30 hours. "B": No peeling occurred at 30 hours. "C": Peeled off in less than 30 hours.

[0080] (3) Evaluation method for high-temperature eddy current loss (150°C, 1kHz) The samples were measured after the vibration and impact test (2) above. Specifically, each sample of the example and comparative example was sandwiched between the magnetic poles of a C-shaped core, and the loss at a frequency of 1 kHz and a magnetic flux density of 0.01 T was measured using a wattmeter.

[0081] Each sample was compared with a block-shaped magnet (Comparative Example 4) and evaluated as follows. Eddy current loss (150℃, 1kHz) "A": Performance improved by more than 5% but less than 10% compared to block magnets (eddy current loss reduced). "B"...Performance improved by more than 0% but less than 5% compared to block magnets (eddy current loss reduced). "C": Performance was equivalent to that of a block magnet.

[0082] (4) Evaluation method for residual magnetic flux density Br Each sample (laminated magnet) was divided into three equal parts in the stacking direction, and measurement specimens measuring 2mm-7mm square were prepared from each of the three parts (upper, middle, and lower). The residual magnetic flux density (Br(T)) was measured using a pulsed BH tracer.

[0083] The evaluation was as follows: "A": The variation in the measurement values ​​for each measurement sample made from the three parts is 2% or more and less than 3%. "B": The variation in the measurement values ​​for each measurement sample made from the three parts is 3% or more and less than 5%. "C": The variation in the measurement values ​​for each of the measurement samples made from the three parts is 5% or more.

[0084] 4. Evaluation Results The evaluation results are shown in Table 2. Examples 1-15 satisfy both requirements [1] and [2] for heavy rare earth elements (in Table 2, "specific structure of heavy rare earth" is "present"). In contrast, Comparative Examples 1-4 do not satisfy at least one of the requirements [1] and [2] for heavy rare earth elements (in Table 2, "specific heavy rare earth structure" is "absent"). Note that Comparative Example 5 is not a laminated magnet, but a single block magnet. In Example 1-15, the Hcj (coercive force) was evaluated as "B." Therefore, in Example 1-15, the variation in coercive force (Hcj) depending on the part of the laminated magnet was reduced. In contrast, in Comparative Example 1-5, the Hcj (coercive force) was evaluated as "C." Therefore, in Comparative Example 1-5, the variation in Hcj (coercive force) was large.

[0085] Furthermore, among Examples 1 to 15, Examples 5 to 15, which further satisfied the following requirement (a), were evaluated as "A" for high-temperature eddy current loss. This suggests that satisfying requirement (a) reduces eddy current loss after being held in a high-temperature range. Requirement (a): The inorganic crystal is one or more selected from the group consisting of fluorides of Group 2A of the periodic table and light rare earth oxides.

[0086] Furthermore, among Examples 1-15, Examples 9-15, which further satisfied the following requirement (b), were rated as "A" for vibration durability. It was suggested that by satisfying requirement (b), the stress difference between the plate magnet and the insulating adhesive layer was alleviated, resulting in high durability in vibration impact tests. Requirement (b): In the range from the interface between the plate magnet and the insulating bonding layer to a depth of 10 μm on the plate magnet side, the concentration of light rare earth elements is 10% or more higher than in the center of the plate magnet.

[0087] Furthermore, among Examples 1-15, Examples 12-15, which further satisfied the following requirement (c), were evaluated as having a residual magnetic flux density Br of "A." By satisfying requirement (c), the variation in residual magnetic flux density Br was further suppressed, and the variation in magnetic performance depending on the location of the laminated magnet was further reduced. Requirement (c): For each of the multiple plate magnets, when the parallelism, which is the angle between a first line connecting both ends of the surface on one end side in the stacking direction and a second line connecting both ends of the surface on the other end side, is calculated, the parallelism of more than one-third of the multiple plate magnets is 3° or less.

[0088] 5. Effects of the Example In this example, within the general composition range of magnets, it was possible to reduce variations in coercive force (Hcj) depending on the location of the laminated magnet.

[0089] The present invention is not limited to the above-described embodiments, and various modifications and variations are possible within the scope of the claims of the present invention. [Explanation of symbols]

[0090] 10...Laminated magnet 11...plate magnet 11A…Main surface 13...insulating bonding layer 20...particles 20A…Surface layer 20C…Central part 30...Motor 31... Stator 33...Rotor 34...rotation axis 35...Rotating core 37... Shaft hole 39...Magnetic hole E1...end E2...end E3...end E4...end G1...center of gravity G2 …center of gravity L1 ... virtual line LA…first straight line LB...Second straight line VP...Virtual plane θ...Angle

Claims

1. A laminated magnet in which a plurality of plate magnets are stacked via an insulating bonding layer containing inorganic crystals, The two adjacent plate magnets are separated by the insulating bonding layer, and are therefore not in contact with each other; the plate magnet contains a rare earth element; the heavy rare earth element is not present in the center of the particle located 200 μm from the surface of the plate magnet, but is present within a 10 nm range of the surface layer of the particle, A laminated magnet in which, when an imaginary line passing through the center of gravity of the laminated magnet and extending in the stacking direction is taken, and the laminated magnet is cut on an imaginary plane containing the imaginary line so that the cross-sectional area of ​​the laminated magnet is maximized, line analysis is performed at 0.1 μm intervals on the line extending in the stacking direction, and peaks of the heavy rare earth element appear, with repeated light and dark concentrations of the heavy rare earth element.

2. 2. The magnet laminate according to claim 1, wherein the inorganic crystal is at least one selected from the group consisting of fluorides of Group 2A of the periodic table and light rare earth oxides.

3. 3. The laminated magnet according to claim 1, wherein the concentration of light rare earth elements in the range from the interface between the plate magnet and the insulating bonding layer to a depth of 10 μm on the plate magnet side is 10% or more higher than in the center of the plate magnet.

4. When the cross section of the laminated magnet is observed, 3. The laminated magnet according to claim 1 or 2, wherein when the parallelism, which is the angle between a first line connecting both ends of the surface on one end side in the stacking direction and a second line connecting both ends of the surface on the other end side, is calculated for each of the plurality of plate magnets, the parallelism of more than one-third of the plurality of plate magnets is 3° or less.

5. A motor comprising the laminated magnet according to claim 1 or 2.

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