Composite structures for MEMS applications including deformable layers and piezoelectric layers, and associated manufacturing methods.

Abstract

The present invention provides a novel composite structure, a method for manufacturing the same, and a device formed from the composite structure. [Solution] A composite structure (100) comprising: a receiver substrate (3) including a cavity (31), wherein the cavity (31) is defined within the substrate and does not contain solid material or is filled with sacrificial solid material; a single crystal semiconductor layer (1) disposed on the receiver substrate (3), having a free surface over the entire extent of the structure and having a thickness ranging from 0.1 microns to 100 microns; and a piezoelectric layer (2) disposed between the single crystal semiconductor layer (1) and the receiver substrate (3), which is firmly fixed to the single crystal semiconductor layer (1).

Description

Technical Field

[0001] The present invention relates to the field of microelectronics and microsystems. More particularly, the present invention relates to a composite structure including a piezoelectric layer and a single-crystal semiconductor layer having elastic properties that can be deformed above at least one cavity. The present invention also relates to a method of manufacturing the composite structure.

Background Art

[0002] In the field of microelectromechanical systems (MEMS) and actuators, substrates and components typically include a thin piezoelectric layer disposed on a deformable layer, which in the form of a movable membrane above a cavity has elastic properties that allow it to move or deform. Note that the term membrane is used herein in a broad sense and encompasses a sealed membrane or apertured membrane, a beam, or any other form of membrane that can curve and / or deform. The deformable layer provides mechanical strength to the membrane, while the piezoelectric layer induces or detects deformation of the membrane. This concept also extends to the field of acoustic wave filters.

[0003] Thin film piezoelectrics, particularly PZT (lead zirconate titanate), are often sensitive to aggressive external environments and thus tend to degrade when exposed to the external environment for long periods. This may be the case for sensors or actuators such as, for example, microphones, loudspeakers, or piezoelectric micromachine ultrasonic transducers (pMUT). Therefore, in the manufacturing process, it is necessary to provide an additional step of depositing a protective film on the piezoelectric layer in order to isolate the piezoelectric layer from the external environment without affecting performance.

[0004] Furthermore, considering the example of a piezoelectric layer made of PZT, this material, which is easy to deposit, requires a recrystallization step at a temperature of approximately 700°C to achieve a good quality level. In certain applications, substrates containing a deformable layer on which the piezoelectric layer must be deposited may prove unsuitable for such temperatures, for example, if the substrate contains glass or plastic carriers, or even if the substrate contains components such as transistors. [Overview of the Initiative] [Problems that the invention aims to solve]

[0005] The present invention relates to an alternative solution to a prior art solution and aims to improve all or some of the aforementioned shortcomings. In particular, the present invention relates to a composite structure comprising a piezoelectric layer and a single-crystal semiconductor layer having elastic properties that allow deformation above at least one cavity. The present invention also relates to a method for manufacturing the composite structure. [Means for solving the problem]

[0006] The present invention A receiver substrate comprising at least one cavity, wherein at least one cavity is defined within the substrate and is free of solid material or filled with sacrificial solid material, A single-crystal semiconductor layer disposed on a receiver substrate, having a free surface over the entire extent of the structure and having a thickness ranging from 0.1 microns to 100 microns, A piezoelectric layer is firmly fixed to the single-crystal semiconductor layer and is placed between the single-crystal semiconductor layer and the receiver substrate. This relates to composite structures, including those mentioned above.

[0007] In the composite structure according to the present invention, at least one segment of the single-crystal semiconductor layer is intended to form a movable film above the cavity when the cavity does not contain solid material or after the sacrificial solid material has been removed, and the piezoelectric layer is intended to induce or detect deformation of the film.

[0008] According to other advantageous and non-limiting features of the present invention, these features can be implemented individually or in any technically feasible combination.

[0009] The piezoelectric layer comprises a material selected from lithium niobate (LiNbO3), lithium tantalate (LiTaO3), potassium-sodium niobate (KxNa1-xNbO3 or KNN), barium titanate (BaTiO3), quartz, lead zirconate titanate (PZT), a compound of lead-magnesium niobate and lead titanate (PMN-PT), zinc oxide (ZnO), aluminum nitride (AlN), and aluminum nitride-scandium (AlScN). The piezoelectric layer has a thickness of less than 10 microns, preferably less than 5 microns. The single-crystal semiconductor layer is made of silicon or silicon carbide. The piezoelectric layer is positioned to face exclusively one cavity of the receiver substrate. The piezoelectric layer is positioned to face at least one cavity of the receiver substrate and is firmly fixed to the receiver substrate in all other locations except for at least one cavity.

[0010] The present invention also relates to a device based on a movable membrane above a cavity, the device being formed from the aforementioned composite structure and comprising at least two electrodes in contact with a piezoelectric layer, The cavity does not contain any solid material. At least one segment of the single-crystal semiconductor layer forms a movable film above the cavity.

[0011] Finally, the present invention relates to a method for manufacturing a composite structure, the method comprising the following steps, namely: a) A step of preparing a donor substrate including a single-crystal semiconductor layer, wherein the single-crystal semiconductor layer has a defined range between the front surface of the donor substrate and the embedded weak surface within the donor substrate, and has a thickness ranging from 0.1 microns to 100 microns. b) A step of preparing a receiver substrate including at least one cavity, wherein at least one cavity is defined within the substrate, opens onto the front surface of the receiver substrate, and the cavity is free of solid material or filled with sacrificial solid material, c) The step of forming a piezoelectric layer such that the piezoelectric layer is positioned on the front surface of the donor substrate and / or the front surface of the receiver substrate, d) The step of joining the donor board and the receiver board via their respective front surfaces, e) The step of cleaving a single-crystal semiconductor layer from the rest of the donor substrate along the embedded weak surface to form a composite structure including a single-crystal semiconductor layer, a piezoelectric layer, and a receiver substrate, Includes.

[0012] According to other advantageous and non-limiting features of the present invention, these features can be implemented individually or in any technically feasible combination.

[0013] • The embedded weak surface is formed by injecting a light nuclide into the donor substrate, and cleavage along the embedded weak surface is obtained via heat treatment and / or the application of mechanical stress. • The embedded vulnerable surface has a load capacity of 0.7 J / m². 2 Formed by interfaces having a binding energy of less than, The manufacturing method includes the step of forming a metal electrode before and / or after step c) so that the electrode comes into contact with the piezoelectric layer, Step c) includes local etching of the piezoelectric layer when it is formed on the front surface of the donor substrate such that the piezoelectric layer remains exclusively facing at least one cavity at the end of step d), which is a bonding step. [Brief explanation of the drawing]

[0014] Other features and advantages of the present invention will become apparent from the following detailed description of the invention, which is given with reference to the accompanying drawings. [Figure 1a] This is a diagram showing a composite structure according to the present invention. [Figure 1b] It is a figure showing a composite structure according to the present invention. [Figure 1c] It is a figure showing a composite structure according to the present invention. [Figure 2] It is a figure showing a device based on a movable film above the cavity, and the device is formed from the composite structure according to the present invention. [Figure 3a] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 3b] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 3c] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 3d] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 3e] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 3f] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. [Figure 4a] It is a figure showing a donor substrate according to a first modification of an embodiment of a manufacturing method according to the present invention. [Figure 4b] It is a figure showing a donor substrate according to a first modification of an embodiment of a manufacturing method according to the present invention. [Figure 5a] It is a figure showing a donor substrate according to a second modification of an embodiment of a manufacturing method according to the present invention. [Figure 5b] It is a figure showing a donor substrate according to a second modification of an embodiment of a manufacturing method according to the present invention. [Figure 6] It is a figure showing steps of a method for manufacturing a composite structure according to the present invention. In the figure, the same reference numerals may be used for the same type of elements. The figure is a schematic representation and not to scale for ease of reading. In particular, the thickness of the layers along the z-axis is not to scale with respect to the lateral dimensions along the x-axis and y-axis, and the relative thicknesses of the layers with respect to each other are not necessarily considered in the figure.

Mode for Carrying Out the Invention

[0015] The composite structure 100 according to the present invention includes a receiver substrate 3 having at least one cavity 31 which is free of solid material or filled with sacrificial solid material (Figures 1a and 1b). The receiver substrate 3 is advantageously in the form of a wafer having a diameter greater than 100 mm, for example, 150 mm, 200 mm, or 300 mm. Its thickness is typically in the range of 200 to 900 microns. The receiver substrate is preferably composed of a low-cost material (silicon, glass, plastic) if its function is essentially mechanical, or it is formed from a functionalized substrate (for example, including components such as transistors) if it is intended that more complex integrated devices will be formed on the composite structure 100.

[0016] The composite structure 100 also includes a single-crystal semiconductor layer 1 disposed on the piezoelectric layer 2. This layer 1 has mechanical properties that allow it to deform over the cavity in a highly controlled manner. The single-crystal properties of layer 1 guarantee the stability and reproducibility of its properties, in contrast to the case of polycrystalline materials, for example, in which the mechanical properties depend heavily on the deposition conditions (size and shape of crystal grains, properties of grain boundaries, stress, etc.). Thus, in the case of single-crystal materials, the mechanical properties of layer 1 can be controlled, simulated, and predicted in a direct manner by knowing only a few basic parameters such as the modulus of elasticity (Young's modulus) or Poisson's ratio. This semiconductor layer 1 will be equivalently referred to as the single-crystal layer 1 or elastic layer 1 for the remainder of this description.

[0017] The semiconductor layer is preferably formed from silicon or silicon carbide, without limitation. The semiconductor layer is advantageously thicker, ranging from 0.1 microns to 100 microns.

[0018] The composite structure 100 also includes a piezoelectric layer 2, which is firmly fixed to the single-crystal semiconductor layer 1 and disposed between the single-crystal semiconductor layer 1 and the receiver substrate 3.

[0019] According to the first modified example shown in Figure 1a, the piezoelectric layer 2 is in contact with the single-crystal semiconductor layer 1 via one of its sides (directly or indirectly, i.e., through another layer) and with the receiver substrate 3 via the other side (directly or indirectly). If the receiver substrate 3 is semiconductive or conductive, an intermediate insulating layer 43 can be provided between the substrate 3 and the piezoelectric layer 2 (Figure 1b). If the receiver substrate 3 is insulating, this insulating layer 43 is not necessary for electrical reasons, but may be useful for improving interlayer adhesion and / or the structural quality of the piezoelectric layer 2.

[0020] According to the second modification shown in Figure 1c, the piezoelectric layer 2 is in local contact (direct contact or indirect contact, i.e., contact via another layer) with the single-crystal semiconductor layer 1 via one of its sides, while the other side is positioned to face (at least one) cavity 31 of the receiver substrate 3.

[0021] In any of the above-described modifications, an intermediate insulating layer 41 can be provided between the elastic layer 1 and the piezoelectric layer 2 (Figure 1b).

[0022] The intermediate insulating layers 41 and 43 are typically composed of silicon oxide (SiO2) or silicon nitride (SiN).

[0023] The piezoelectric layer 2 consists of lithium niobate (LiNbO3), lithium tantalate (LiTaO3), and potassium-sodium niobate (K x Na 1-x The piezoelectric layer 2 may include materials selected from NbO3 or KNN, barium titanate (BaTiO3), quartz, lead zirconate titanate (PZT), lead-magnesium niobate and lead titanate compounds (PMN-PT) in various proportions (e.g., 70 / 30 or 90 / 10) depending on the desired properties, zinc oxide (ZnO), aluminum nitride (AlN), aluminum nitride-scandium (AlScN), etc. The thickness of the piezoelectric layer 2 can typically vary from 0.5 microns to 10 microns, preferably from 1 micron to 5 microns.

[0024] In the composite structure 100, the piezoelectric layer 2 is protected by the elastic layer 1. Therefore, in some cases, it is possible to omit an additional protective layer to protect the piezoelectric layer 2 from the external environment and / or to confine the piezoelectric layer 2 (the lead-based piezoelectric material must be embedded to suit the specific application). Alternatively, a protective layer may be provided, but this protective layer can be simplified compared to a standard prior art layer. According to yet another option, it may be desirable to retain a standard protective layer, but its effectiveness is enhanced by the protection already provided by the present invention.

[0025] The composite structure 1 includes at least one segment of a single crystal layer 1 and provides a film 50 that extends over a cavity 31 formed within the receiver substrate 3. As mentioned in the introduction, the piezoelectric layer 2 is provided to induce or detect deformation of the film 50 above the cavity 31.

[0026] Therefore, the device 150 based on the movable film 50 above the cavity 31 can be formed from the composite structure 100 (Figure 2) described above. The device 150 comprises at least two electrodes 21, 22 in contact with the piezoelectric layer 2, which are intended to transmit and / or collect electrical signals associated with the deformation of the film 50. The electrodes 21, 22 may be formed from platinum, aluminum, titanium, or molybdenum, in particular. In the example of Figure 2, the electrodes 21, 22 are located on the side of the piezoelectric layer 2 facing the elastic layer 1. Alternatively, these electrodes may be located on the other side (facing the receiver substrate 3), or on both sides of the piezoelectric layer 2, respectively. When these electrodes are located on the same side of the piezoelectric layer 2, the electrodes 21, 22 advantageously take the form of interdigitated combs. In all cases, one (or more) insulating layers 41, 43 are provided at intermediate positions to insulate the electrodes 21, 22 from the single crystal layer 1 and / or the receiver substrate 3.

[0027] In device 150, the (at least one) cavity 31 does not contain any solid material to allow deformation of the membrane 50. Therefore, in one desired application, the cavity 31 may be openable and closable, and its closure can achieve an impermeable seal. In the case of closure, a controlled atmosphere can be confined within the cavity 31. The controlled atmosphere is a relatively high vacuum (e.g., 10°C). -2 It can handle pressures from mbar to atmospheric pressure, and / or specific gas mixtures (e.g., a neutral atmosphere, nitrogen or argon, or ambient air).

[0028] In the case of an open cavity, the cavity can be opened in several ways. The cavity can be opened from the back through the receiver substrate 3. It is also possible to open the cavity through a lateral channel created within the receiver substrate 3. The cavity can also be opened through one or more through-holes formed by penetrating the film 50. An embedded flexible beam is an example of a design commonly associated with open cavity type composite structures.

[0029] At least one segment of the elastic layer 1 forms a movable film 50 above the cavity 31. Furthermore, the functional element 51 may be formed on or within the elastic layer 1 so as to interact overall with the electrodes and / or film of the piezoelectric layer 2. Optionally, the functional element 51 may include a transistor, a diode, or other microelectronic component.

[0030] Since the piezoelectric layer 2 is embedded beneath the elastic layer 1, it is desirable to form conductive vias 52 that penetrate through the layer 1 and, if present, through the intermediate insulating layer 41, thereby enabling electrical connection to the electrodes 21 and 22 from the front surface of the composite structure 100. Alternatively, the electrical connection may be achieved from the back surface of the composite structure by conductive vias that penetrate all or part of the receiver substrate 3 and the intermediate insulating layer 43 (if present).

[0031] The present invention also relates to a method for manufacturing the aforementioned composite structure 100. The method first involves preparing a donor substrate 10 having a front surface 10a and a back surface 10b. The donor substrate 10 is advantageously in the form of a wafer having a diameter larger than 100 mm, for example, 150 mm, 200 mm, or 300 mm. Its thickness is typically in the range of 200 to 900 microns.

[0032] The donor substrate 10 includes a single-crystal semiconductor layer 1, and a range is defined between its front surface 10a and the embedded fragile surface 11 formed within the donor substrate 10 (Figure 3a).

[0033] According to the first embodiment, the embedded fragile surface 11 is formed by injecting a light nuclide into the donor substrate 10 according to the principle of the Smart Cut® method, which is particularly suitable for transferring a thin single crystal layer (Figure 4a). The donor substrate 10 may be a blank single crystal substrate having the target elastic properties relative to the single crystal layer 1. The donor substrate may be, for example, a single crystal silicon wafer. Alternatively, the donor substrate may have a donor layer 12 on its front surface 10a that can define the elastic layer 1 (Figure 4b). The donor layer 12 may be placed on any carrier 13 that can provide strength to the donor substrate 10, but of course the carrier must be suitable for the remaining steps of the method. This may be, for example, a donor layer 12 made of silicon produced by epitaxy on a carrier wafer 13 made of lower quality single crystal silicon.

[0034] This first embodiment is particularly suitable for single-crystal layers with a thickness of less than 2 microns.

[0035] According to the second embodiment, the embedded weak surface 11 is typically 0.7 J / m 2The interface is formed by an interface having a low binding energy of less than 1, which allows for cleavage at the interface in a subsequent process. The donor substrate 10 is, in this case, a separable substrate, two examples of which are shown in Figures 5a and 5b. The donor substrate is formed from a surface layer 12 bonded to a carrier 13 via a separable bonding interface 11. Such an interface 11 can be obtained, for example, by roughening the surface of the surface layer 12 and / or the surface of the carrier 13 before direct bonding by molecular adhesion. The fact that the bonded surface typically has a roughness of 0.5 nm to 1 nm RMS (measured by AFM with a 20 micron × 20 micron scan) reduces the binding energy of the interface 11 and gives the interface 11 its separable properties.

[0036] In the first example shown in Figure 5a, the surface layer 12 of the separable donor substrate 10 is a single crystal layer 1.

[0037] In the second example of Figure 5b, the surface layer 12 includes, on the one hand, a layer 12a that forms the crystalline layer 1, and on the other hand, a first bonding layer 12b, which is advantageously made of silicon oxide. Thus, the bonding surface of this first bonding layer 12b is treated to be roughened so that the future crystalline layer 1 does not need to undergo this treatment. Optionally, a second bonding layer 13b may be placed on the base 13a of the carrier 13. This second bonding layer is advantageously of the same properties as the first bonding layer 12b, facilitating the reuse of the base 13a after the surface layer 12 has been cleaved from the second bonding layer. In both examples described, the surface layer 12, which is intended to form all or part of the single-crystal layer 1, is obtained from a single-crystal initial substrate, bonded to the carrier 13 by a separable interface 11, and then thinned mechanically, chemomechanically, and / or chemically to a thickness of several to tens of microns. If the thickness of the surface layer 12 is thinner, for example, the Smart Cut® method can be used to transfer the surface layer 12 from the initial substrate to the carrier 13 via a separable interface 11.

[0038] According to the third embodiment, the embedded fragile surface 11 can be formed by a porous layer, for example, a porous layer made of porous silicon, or by any other fragile layer, film, or interface that can subsequently be cleaved along the layer.

[0039] In any of these embodiments, the features of the single-crystal semiconductor layer 1 are selected to impart to the layer the elastic properties targeted for the application. The thickness of the crystal layer 1 may be 0.1 microns to 100 microns. The material is selected from, for example, silicon, silicon carbide, etc.

[0040] Next, the manufacturing method includes preparing a receiver substrate 3 having a front surface 3a and a back surface 3b (Figure 3b). The receiver substrate 3 is advantageously in the form of a wafer having a diameter larger than 100 mm, for example, 150 mm, 200 mm, or 300 mm. Its thickness is typically in the range of 200 to 900 microns. The receiver substrate is preferably formed from a low-cost material (silicon, glass, plastic) if its function is essentially mechanical, or from a functionalized substrate (including components such as transistors) if it is intended to form an integrated device.

[0041] In all cases, the receiver substrate 3 includes at least one cavity 31 opening on its front surface 3a. While one or more cavities 31 are mentioned below, the receiver substrate 3 advantageously includes multiple cavities 31 distributed across its entire front surface 3a. Each cavity 31 may have dimensions of several tens to several hundreds of microns in the (x,y) plane of the front surface 3a and a height (or depth) of approximately one-tenth of a micron to several tens of microns along the z-axis perpendicular to the front surface 3a.

[0042] The cavity 31 may be empty, i.e., it may not contain any solid material, or it may be filled with sacrificial solid material that will be removed later in the method for manufacturing the composite structure 100 or during the manufacturing of the components on the composite structure 100.

[0043] It should be noted that having a filled cavity 31 at this stage may be advantageous in order to facilitate subsequent steps in the manufacturing process. The sacrificial material placed in the cavity 31 may be silicon oxide, silicon nitride, amorphous silicon, or polycrystalline silicon, etc. The sacrificial material is selected according to the properties of the receiver substrate 3. Specifically, this material is intended to be removed after the composite structure 100 is formed, and therefore must be chemically etchable with good selectivity for the receiver substrate 3 as well as the elastic layer 1 and piezoelectric layer 2 (placed above the cavity).

[0044] Next, the manufacturing method includes step c) forming a piezoelectric layer 2. This layer 2 is formed directly on the single crystal layer 1 of the donor substrate 10 and / or on the receiver substrate 3, or via intermediate insulating layers 41, 43.

[0045] In the example shown in Figure 3c, the piezoelectric layer 2 is located on the receiver substrate 3. Alternatively, the piezoelectric layer may be located on the donor substrate 10. In the latter case, step c) may include local etching of the piezoelectric layer 2 to generate a pattern ("patterning") in the (x,y) plane of the layer 2. This makes it possible to define one or more slabs of the piezoelectric layer 2 that are intended to be positioned facing one or more cavities of the receiver substrate 3 at the end of the next step, step d). Thus, the patterned piezoelectric layer 2 does not come into contact with the receiver substrate 3, even though it is located between the elastic layer 1 and the receiver substrate 3. At the end of the manufacturing process, a composite structure 100 as shown in Figure 1c can be obtained.

[0046] The piezoelectric layer 2 can be formed by deposition using deposition techniques such as physical vapor deposition (PVD), pulsed laser deposition (PLD), sol-gel method, or epitaxial method, and examples of deposition materials include PZT, AlN, KNN, BaTiO3, PMN-PT, ZnO, and AlScN. Alternatively, the piezoelectric layer 2 may be formed by transferring the layer from a source substrate to a destination substrate (donor substrate 10 and / or receiver substrate 3). The source substrate may be made of LiNbO3, LiTaO3, etc., in particular. The piezoelectric layer 2 may be single-crystal or polycrystalline, depending on the technique used and the material selected.

[0047] Depending on the properties of the piezoelectric layer 2, its formation may require relatively high temperatures. If the receiver substrate 3 is based on a functionalized substrate (including its components), the piezoelectric layer 2 is advantageously formed on the donor substrate 10. If the receiver substrate 3 is suitable for the temperature at which the piezoelectric layer 2 is formed, the piezoelectric layer 2 can be formed on either or both the donor substrate 10 and the receiver substrate 3.

[0048] The donor substrate 10 is, of course, selected from the embodiments described above so as to be suitable for the temperature required to form the piezoelectric layer 2 when the piezoelectric layer 2 is formed on the substrate 10. This selection is also made considering any technical operations that are desirable to perform on the piezoelectric layer 2 and / or elastic layer 1 before the donor substrate 10 and the receiver substrate 3 are joined.

[0049] For example, as is known, PZT can be deposited at room temperature using the sol-gel method, with a typical thickness of several microns. To obtain a piezoelectric layer 2 made of good quality PZT, crystallization annealing at a temperature of approximately 700°C is required. Therefore, when the piezoelectric layer 2 is formed on the donor substrate 10, it is preferable to select a separable substrate that can withstand temperatures of 700°C or higher, as described in the second embodiment above. Here, "suitability" means that the separable substrate retains its separable properties even after the aforementioned temperature is applied.

[0050] In another example, a polycrystalline AlN layer can be deposited at 250°C to 500°C using conventional cathode sputtering techniques. Crystallization annealing is not required. The donor substrate 10 of the three embodiments described above, even if functionalized, is suitable for such deposition, as is most receiver substrate 3.

[0051] The manufacturing method according to the present invention advantageously includes the step of forming metal electrodes 21, 22 that come into contact with the piezoelectric layer 2 before and / or after the deposition of the piezoelectric layer 2. The electrodes 21, 22 are formed on one side of the piezoelectric layer 2 and advantageously take the form of interlocking combs or are formed in the form of two metal films on both sides of the layer 2. The material used to form the electrodes 21, 22 may be platinum, aluminum, titanium, or even molybdenum.

[0052] The electrodes 21 and 22 must not be in direct contact with the crystal layer 1; therefore, it is necessary to provide an intermediate insulating layer 41 (Figure 3c). It should also be noted that the electrodes 21 and 22 must not be in direct contact with the receiver substrate 3 if the receiver substrate 3 is semiconducting or conductive. In this case, an intermediate insulating layer 43 is provided between the piezoelectric layer 2 and the receiver substrate 3.

[0053] Following the formation of the piezoelectric layer 2, the manufacturing method includes the step of joining the donor substrate 10 and the receiver substrate 3 via their respective front surfaces 10a and 3a (Figure 3d). Various joining techniques are possible. In particular, direct bonding by molecular adhesion, thermocompression bonding, and even polymer bonding can be performed with insulating or metallic bonded surfaces. Thus, the bonding interface 6 is defined between the two substrates 10 and 3 that form the bonded structure at this stage of the method.

[0054] According to the first option shown in Figures 3c and 3d, the piezoelectric layer 2 includes two alternating mating electrodes 21 and 22 and an insulating layer 41 on its free surface before bonding. The insulating layer 41 electrically insulates the electrodes 21 and 22 from the donor substrate 10, facilitating bond formation.

[0055] According to the second option, the piezoelectric layer 2 includes a first electrode 21 and a second electrode 22 formed by metal films arranged on both sides of the layer 2 (as shown in Figure 6). Therefore, metal bonding can be advantageously implemented by taking advantage of the presence of the electrode 22 on one side of the piezoelectric layer 2. The donor substrate 10 can then include a metal bonding layer 61 that comes into contact with the electrode 22. An intermediate insulating layer 41 may be provided between the bonding layer 61 and the single crystal layer 1.

[0056] The first and second options are shown with respect to the piezoelectric layer 2 deposited on the receiver substrate 3, but it should be noted that these options also apply when the layer is deposited on the donor substrate 10.

[0057] The manufacturing method according to the present invention finally includes the step of cleaving the single crystal layer 1 from the remaining portion 10' of the donor substrate 10 along the embedded weak surface 11 (Figure 3e). In this way, a composite structure 100 is obtained which includes the single crystal semiconductor layer 1 disposed on the piezoelectric layer 2, and the piezoelectric layer 2 itself is disposed on the receiver substrate 3.

[0058] The cleavage step can be performed in various ways depending on the selected embodiment of the donor substrate 10.

[0059] In particular, according to the first embodiment, cleavage along the embedded weak surface is achieved by applying heat treatment and / or mechanical stress, which causes separation in the microcrack region under the gas pressure generated by the injected nuclide.

[0060] According to the second embodiment, splitting along the embedded weak surface 11 is preferably achieved by applying mechanical stress to the separable interface.

[0061] In the third embodiment, the application of mechanical stress is also preferable.

[0062] Mechanical stress may also be applied by inserting a chamfered tool, such as a Teflon blade, between the edges of the joined substrates, thereby transmitting tensile force to the embedded weak surface 11, where splitting or delamination waves are initiated. Of course, tensile force is also applied to the joining interface 6 of the structures being joined. Therefore, it is important to sufficiently strengthen this interface 6 so that cleavage occurs at the embedded weak surface 11 rather than at this interface 6.

[0063] The step of finishing the front surface 100a of the composite structure 100, which corresponds to the free surface of the single crystal layer 1 after cleavage, may be performed to restore a good quality level with respect to material roughness, defects, or properties. This finishing may include smoothing by chemical mechanical polishing, cleaning, and / or chemical etching.

[0064] From the obtained composite structure 100, a device 150 based on a movable film 50 above the cavity 31 can be fabricated. For this purpose, openings created through the single crystal layer 1, the piezoelectric layer 2, and optionally the electrodes 21, 22, and the intermediate insulating layers 41, 43, 61 allow for selective etching of the material filling the cavity 31 (if the cavity 31 is actually filled at this stage of the method).

[0065] Functional elements 51, intended to be connected to or interact with the film 50, may be formed on or within the elastic layer 1 (Figure 3f). These functional elements 51 may include transistors, diodes, or other microelectronic components. The composite structure 100 is advantageous in that it results in a single-crystal layer 1 having a blank, flat free surface 100a, which is robust and further facilitates the potential fabrication of surface components.

[0066] The conductive vias 52 that penetrate the elastic layer 1 allow electrodes 21 and 22 to be electrically connected to the functional element 51 as needed.

[0067] Examples According to the first embodiment, the donor substrate 10 is a separable substrate, and the embedded fragile surface 11 corresponds to a roughened or low-temperature stable bonding interface. The donor substrate 10 is a thick SOI type having a surface layer 12a made of 20 microns single-crystal silicon on embedded silicon oxide layers 12b and 13b, with a separable interface 11 at the center of the embedded silicon oxide layers 12b and 13b (Figure 5b). The silicon oxide layers 12b and 13b are themselves placed on a carrier substrate 13a made of silicon.

[0068] A nucleation layer made of silicon oxide is formed on the front surface 10a of the donor substrate 10 to promote satisfactory texture growth, thus ensuring that the layers to be deposited thereafter (metal electrodes 21, 22 and piezoelectric layer 2) are of good quality. A metal film intended to form the first electrodes 21, 22 made of platinum is deposited on the nucleation layer. To improve the adhesion of this metal film to silicon oxide, an intermediate adhesion-promoting layer made of titanium is pre-deposited beneath the platinum. Then, conventional sol-gel deposition of the piezoelectric layer 2 made of PZT is performed to form a layer with a thickness of several microns, for example, 1 to 5 microns. Subsequently, the donor substrate 10 with the piezoelectric layer 2 is subjected to crystallization annealing at a temperature of approximately 650°C to 750°C. The second electrodes 21, 22 made of platinum are deposited in the form of metal films on the free surface of the PZT layer 2.

[0069] The receiver substrate 3 is a blank silicon substrate in which a square cavity 31 having, for example, a lateral dimension of 50 microns and a depth of 5 microns is etched. The cavity 31 does not contain any solid material. A 0.5 micron silicon oxide layer is deposited on the receiver substrate 3, including the bottom and side walls of the cavity 31.

[0070] The donor substrate 10 and the receiver substrate 3 are joined outside the cavity 31 by a metal bond via thermocompression bonding between the electrode film on the front surface 10a of the donor substrate 10 and a metal layer pre-deposited on the front surface 3a of the receiver substrate 3. The thermocompression bonding conditions depend particularly on the selection of the metals to be bonded. If gold is selected as the metal layer to be deposited on the front surface 3a of the receiver substrate 3, for example, a temperature of 300°C to 500°C is used.

[0071] By inserting a Teflon blade between the edges of the two joined substrates, mechanical stress is applied to the separable interface 11. Since the separable interface is the weakest region of the joined structure, cleavage occurs along the interface 11, forming a composite structure 100 on one side and the remaining portion 10' of the donor substrate 10 on the other.

[0072] In this way, a film 50 is obtained that extends over each cavity 31. The film 50 includes a 20-micron elastic layer 1 made of single-crystal silicon and a piezoelectric layer 2 having electrodes 21 and 22 with a thickness of several microns.

[0073] Next, additional steps may be taken to electrically isolate multiple devices of the composite structure 10 and form functional elements.

[0074] In the second embodiment, the initial donor substrate 10 and receiver substrate 3 are the same as those in the first embodiment. The receiver substrate 3 includes a silicon oxide layer on its front surface 3a. In this case, the cavity 31 is filled with silicon oxide, which is a sacrificial material intended to be etched after the fabrication of the composite structure 100.

[0075] Next, a piezoelectric layer 2 made of PZT is deposited using a conventional sol-gel method to form a layer of several microns on the receiver substrate 3. The receiver substrate 3 with the piezoelectric layer 2 is then subjected to crystallization annealing at 700°C. Subsequently, alternating mating electrodes 21 and 22 made of platinum are formed on the free surface of the PZT layer 2.

[0076] An insulating layer 41 made of silicon oxide is deposited on electrodes 21, 22 and piezoelectric layer 2, and then planarized (for example by chemical mechanical polishing) to promote adhesion to the donor substrate 10.

[0077] The front surfaces of the donor substrate 10 and the receiver substrate 3 are joined by direct oxide / silicon bonding via molecular adhesion. Heat treatment to strengthen the bonding interface 6 is performed at a temperature within 600°C to 700°C.

[0078] By inserting a Teflon blade between the edges of the two joined substrates, mechanical stress is applied to the separable interface 11. Since the separable interface is the weakest region of the joined structure, cleavage occurs along the interface 11, forming a composite structure 100 on one side and the remaining portion 10' of the donor substrate 10 on the other.

[0079] The sacrificial material filling the cavity 31 may be etched at this stage, or it may be etched later after the components or other functional elements 51 have been fabricated on the single crystal layer 1. This results in a film 50 extending over each cavity 31. The film 50 includes an elastic layer 1 of 20 microns of single crystal silicon and a piezoelectric layer 2 having alternating mating electrodes with a thickness of several microns.

[0080] According to the third embodiment, the donor substrate 10 is a substrate made of single-crystal silicon, and the embedded fragile surface 11 has an energy of 210 keV and approximately 7 × 10⁻¹⁰ 16 / cm 2 This corresponds to the region where hydrogen ions are implanted with this dose amount. In this way, a single crystal layer 1 of approximately 1.5 microns is defined in area between the front surface 10a of the donor substrate 10 and the implantation region 11.

[0081] Next, a piezoelectric layer 2 made of polycrystalline AlN is deposited by conventional cathode sputtering to form a layer with a thickness of 0.5 to 1 micron on the front surface of the donor substrate 10, which already has an insulating layer. Then, electrodes 21 and 22 made of molybdenum are created on both sides of the AlN layer 2.

[0082] The receiver substrate 3 is a blank silicon substrate in which a square cavity 31 having, for example, a lateral dimension of 25 microns and a depth of 0.3 microns is etched. The cavity 31 is filled with silicon oxide, which is a sacrificial material intended to be etched after the fabrication of the composite structure 100.

[0083] An insulating layer made of silicon oxide is deposited on electrodes 21, 22 and piezoelectric layer 2, and then planarized (for example by chemical mechanical polishing) to promote adhesion to the receiver substrate 3.

[0084] The front surfaces of the donor substrate 10 and the receiver substrate 3 are joined by direct oxide / silicon bonding via molecular adhesion. Heat treatment to strengthen the bonding interface 6 is performed at a temperature of 350°C.

[0085] Cleavage along the embedded weak surface 11 is obtained by heat-treating the bonded structure at a temperature of approximately 500°C, resulting in microcracks that grow under pressure in the injection region until the splitting wave propagates through the region. This cleavage forms the composite structure 100 on one side and the remaining portion 10' of the donor substrate 10 on the other.

[0086] The composite structure 100 is subjected to finishing steps involving chemical mechanical polishing and standard cleaning to provide the free surface of the single-crystal silicon layer 1 with a good quality level and low roughness.

[0087] The sacrificial material filling the cavity 31 may be etched at this stage, or it may be etched later after the components or other functional elements 51 have been manufactured on the single crystal layer 1.

[0088] A film 50 is obtained that extends over each cavity 31. The film 50 includes an elastic layer 1 of single-crystal silicon with a thickness of 1.2 microns and an AlN piezoelectric layer 2 having electrodes with a thickness of less than 1 micron.

[0089] Of course, the present invention is not limited to the embodiments and examples described, and can be modified without departing from the scope of the invention as defined by the claims. [Explanation of symbols]

[0090] 1...Single-crystal semiconductor layer, 2...Piezoelectric layer, 3...Receiver substrate, 31...Cavity, 50...Movable film, 100...Composite structure.

Claims

1. A composite structure (100), A receiver substrate (3) comprising at least one cavity (31), wherein the at least one cavity (31) is defined within the substrate and is free of solid material or filled with sacrificial solid material, A single-crystal semiconductor layer (1) disposed on the receiver substrate (3), having a free surface over the entire extent of the structure and having a thickness ranging from 0.1 microns to 100 microns, A piezoelectric layer (2) is firmly fixed to the single-crystal semiconductor layer (1) and is disposed between the single-crystal semiconductor layer (1) and the receiver substrate (3), Includes, At least one segment of the single-crystal semiconductor layer (1) is intended to form a movable film (50) above the cavity (31) when the cavity (31) does not contain solid material, or after the sacrificial solid material has been removed. The piezoelectric layer (2) is intended to induce or detect deformation of the film (50). Composite structure (100).

2. The piezoelectric layer (2) comprises lithium niobate (LiNbO3), lithium tantalate (LiTaO3), potassium sodium niobate (K ｘ Na １－ｘ NboO ３ The composite structure (100) according to claim 1, comprising a material selected from (or KNN), barium titanate (BaTiO3), quartz, lead zirconate titanate (PZT), lead-magnesium niobate and lead titanate compound (PMN-PT), zinc oxide (ZnO), aluminum nitride (AlN), and aluminum nitride-scandium (AlScN).

3. The composite structure (100) according to claim 1 or 2, wherein the piezoelectric layer (2) has a thickness of less than 10 microns, preferably less than 5 microns.

4. The composite structure (100) according to any one of claims 1 to 3, wherein the single-crystal semiconductor layer (1) is made of silicon or silicon carbide.

5. The composite structure (100) according to any one of claims 1 to 4, wherein the piezoelectric layer (2) is arranged to face exclusively the at least one cavity (31) of the receiver substrate (3).

6. The composite structure (100) according to any one of claims 1 to 4, wherein the piezoelectric layer (2) is arranged to face the at least one cavity (31) of the receiver substrate (3) and is firmly fixed to the receiver substrate (3) other than the at least one cavity (31).

7. A device (150) based on a movable membrane (50) above a cavity (31), formed from a composite structure (100) according to any one of claims 1 to 6, comprising at least two electrodes (21, 22) in contact with the piezoelectric layer (2), The cavity (31) does not contain a solid material. At least one segment of the single-crystal semiconductor layer (1) forms the movable film (50) above the cavity (31). Device (150).

8. a) A step of preparing a donor substrate (10) including a single crystal semiconductor layer (1), wherein the single crystal semiconductor layer (1) has a defined range between the front surface (10a) of the donor substrate (10) and the embedded fragile surface (11) within the donor substrate (10), and has a thickness that falls within 0.1 microns to 100 microns, b) A step of preparing a receiver substrate (3) including at least one cavity (31), wherein the at least one cavity (31) is defined within the substrate, opens onto the front surface (3a) of the receiver substrate (3), and the cavity (31) is free of solid material or filled with sacrificial solid material, c) The step of forming the piezoelectric layer (2) such that the piezoelectric layer (2) is positioned on the front surface (10a) of the donor substrate (10) and / or the front surface (3a) of the receiver substrate (3), d) The step of joining the donor substrate (10) and the receiver substrate (3) via their respective front surfaces, e) Cleaving the single-crystal semiconductor layer (1) from the remaining portion (11') of the donor substrate along the embedded weak surface (11) to form the composite structure (100) including the single-crystal semiconductor layer (1), the piezoelectric layer (2), and the receiver substrate (3), including, A method for manufacturing a composite structure (100) according to any one of claims 1 to 6.

9. The manufacturing method according to claim 8, wherein the embedded weak surface (11) is formed by injecting a light nuclide into the donor substrate (10), and the cleavage along the embedded weak surface (11) is obtained by applying heat treatment and / or mechanical stress.

10. The aforementioned embedded weak surface (11) has a load of 0.7 J / m ２ The manufacturing method according to claim 8, formed by an interface having a binding energy of less than 1.

11. The manufacturing method according to any one of claims 8 to 10, comprising the step of forming metal electrodes (21, 22) before and / or after step c) so that the electrodes come into contact with the piezoelectric layer (2).

12. The manufacturing method according to any one of claims 8 to 11, wherein step c) includes local etching of the piezoelectric layer (2) when the piezoelectric layer (2) is formed on the front surface (10a) of the donor substrate (10) such that the piezoelectric layer (2) remains exclusively facing the at least one cavity (31) at the end of the bonding step (step d).

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