Hair cosmetics

Abstract

This product provides a hair cosmetic that offers smoothness during rinsing, smoothness after finishing, good manageability after finishing, and no stickiness after finishing. [Solution] A hair cosmetic containing (A) one or more selected from dimethyldiallylammonium chloride / acrylamide copolymer, polydimethyldimethylene pyrrolidinium chloride, dimethyldiallylammonium chloride / acrylic acid copolymer, or acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, (B) one or more selected from O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride or O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride, (C) one or more selected from aminopropyl dimethicone, amodimethicone, or biscetearyl amodimethicone, and (D) linoleamidopropyl PG-dimonium chloride phosphate dimethicone.

Description

Technical Field

[0001] The present invention relates to hair cosmetics, and particularly to hair cosmetics that can impart smoothness during rinsing, smoothness during styling, a good sense of cohesion during styling, and no stickiness during styling.

Background Art

[0002] It is known that hair is damaged by chemical treatments such as hair coloring, bleaching, and permanent waving, and the good texture that healthy hair originally has is impaired. In addition to feeling poor finger combability due to hair squeaking and catching during rinsing, or feeling poor cohesion due to hair spreading during styling after drying, problems such as feeling poor finger combability due to hair frizz and catching are known.

[0003] In order to reduce the influence of the above-mentioned damage, the hair cosmetic of Patent Document 1 discloses that by containing a cationic surfactant, a higher alcohol, a silicone compound containing a phosphate group, and an amino-modified silicone, it can improve the persistence of slipperiness, the persistence of cohesion, and the lack of stickiness in the hair during styling.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0005] However, while Patent Document 1 examines the persistence of smoothness, manageability, and lack of stickiness in the finished hair, it was not entirely satisfactory. Furthermore, it did not examine how easily the fingers can comb through the hair during rinsing, and therefore did not simultaneously satisfy the requirements of smoothness during rinsing, smoothness of the fingers during the finished hair, good manageability, and lack of stickiness during the finished hair, leaving room for further research.

[0006] Therefore, the object of the present invention is to provide a hair cosmetic that can provide smoothness to the fingers during rinsing, smoothness to the fingers during the finished hair, good manageability during the finished hair, and no stickiness during the finished hair. [Means for solving the problem]

[0007] The inventors have selected (A) one or more selected from dimethyldiallylammonium chloride / acrylamide copolymer, polydimethylmethylenepyrrolidinium chloride, dimethyldiallylammonium chloride / acrylic acid copolymer, or acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, (B) one or more selected from O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride or O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride, and (C) aminopropyldimethicone, amodimethicone, or bis-methyldimethicone. We have discovered that a hair cosmetic can be obtained that provides smoothness when rinsing, smoothness when finished, manageability when finished, and lack of stickiness when finished, by providing a hair cosmetic that contains one or more selected from tearyl amodimethicone and (D) linoleamidopropyl PG-dimonium chloride phosphate dimethicone, wherein the content of component (A) is 0.04 to 1.7% by mass, the content of component (B) is 0.05 to 2% by mass, the content of component (C) is 0.05 to 10% by mass, and the content of component (D) is 0.06 to 2.5% by mass, and thus the present invention has been completed. [Effects of the Invention]

[0008] The present invention provides a hair cosmetic that can provide smoothness to the fingers during rinsing, smoothness to the fingers during the finished hair, good manageability during the finished hair, and no stickiness during the finished hair. [Modes for carrying out the invention]

[0009] The present invention will be described in detail below. Unless otherwise specified, all units indicating content are in mass percent.

[0010] The present invention relates to (A) one or more selected from dimethyldiallylammonium chloride / acrylamide copolymer, polydimethylmethylenepyrrolidinium chloride, dimethyldiallylammonium chloride / acrylic acid copolymer, or acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer, and (B) O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride or O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethyl chloride This invention relates to a hair cosmetic containing one or more selected from lurose, (C) one or more selected from aminopropyl dimethicone, amodimethicone, or biscetearyl amodimethicone, and (D) linoleamidopropyl PG-dimonium chloride phosphate dimethicone, wherein the content of component (A) is 0.04 to 1.7%, the content of component (B) is 0.05 to 2%, the content of component (C) is 0.05 to 10%, and the content of component (D) is 0.06 to 2.5%.

[0011] From the viewpoint of smoothness of the fingers during rinsing, the present invention contains one or more selected from (A) dimethyldiallylammonium chloride / acrylamide copolymer, polydimethylmethylenepyrrolidinium chloride, dimethyldiallylammonium chloride / acrylic acid copolymer, or acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer.

[0012] Of the components (A) used in the present invention, from the viewpoint of smoothness during rinsing, dimethyldiallylammonium chloride / acrylamide copolymer, polydimethylmethylenepyrrolidinium chloride, and dimethyldiallylammonium chloride / acrylic acid copolymer are preferred, and dimethyldiallylammonium chloride / acrylamide copolymer is more preferred.

[0013] The content of component (A) used in the present invention is preferably 0.04 to 1.7%, more preferably 0.08 to 1%, and even more preferably 0.12 to 0.6%. If the content of component (A) is less than 0.04%, the smoothness of the hair during rinsing and the manageability of the finished product will be poor. If the content of component (A) exceeds 1.7%, the smoothness of the hair during rinsing and the lack of stickiness of the finished product will be poor.

[0014] Of the components (B) used in the present invention, one or more are selected from O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride or O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride, from the viewpoint of how easily the hair can be run through after finishing.

[0015] Of the components (B) used in the present invention, O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride is preferred from the viewpoint of improving the smoothness of the finished product.

[0016] The content of component (B) used in the present invention is preferably 0.05 to 2%, more preferably 0.1 to 1.5%, and even more preferably 0.15 to 1%. If the content of component (B) is less than 0.05%, the finished product will have poor manageability. If the content of component (B) exceeds 2%, the finished product will have poor manageability and a lack of stickiness.

[0017] Of the components (C) used in the present invention, one or more selected from aminopropyl dimethicone, amodimethicone, or biscetearyl amodimethicone are included, from the viewpoint of achieving a cohesive finish.

[0018] Among the components (C) used in the present invention, aminopropyl dimethicone is preferred from the viewpoint of improving the cohesiveness of the finished product.

[0019] The aminopropyl dimethicone used in the present invention is commercially available and can be used as is. Examples of such commercially available products include KF-8015 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-8017 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-8018 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-8020 (manufactured by Shin-Etsu Chemical Co., Ltd.), and X-52-2328 (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0020] The amodimethicone used in this invention is commercially available and can be used as is. Examples of such commercially available products include KF-8004 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-867S (manufactured by Shin-Etsu Chemical Co., Ltd.), X-52-2265 (manufactured by Shin-Etsu Chemical Co., Ltd.), DOWSIL SF 8452 C (manufactured by Dow-Toray Industries, Inc.), DOWSIL SM 8904 Cosmetic Emulsion (manufactured by Dow-Toray Industries, Inc.), XF42-B1989 (manufactured by Momentive Performance Materials Japan LLC), XF42-B8922 (manufactured by Momentive Performance Materials Japan LLC), BELSIL ADM 1650 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.), BELSIL ADM 9101 E (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.), and Emacole HO-1400 (manufactured by Yamaei Chemical Co., Ltd.).

[0021] The biscetearyl amodimethicone used in this invention is commercially available and can be used as is. Examples of such commercially available products include SILSOFT AX-E PE EMULSION (manufactured by Momentive Performance Materials Japan LLC) and SILSOFT AX-LC fluid (manufactured by Momentive Performance Materials Japan LLC).

[0022] The component (C) used in the present invention is available as a commercial product and can be used. As the commercial product of the component (C), either a product containing only the component (C) itself or a product previously dispersed or dissolved in a dispersion medium such as silicone oil or hydrocarbon oil may be used.

[0023] The content of the component (C) used in the present invention is preferably 0.05 to 10%, more preferably 0.1 to 7%, and still more preferably 0.2 to 5%. When the component (C) is less than 0.05%, the coherence at the time of finishing becomes poor. When the component (C) exceeds 10%, the feel when passing a finger during rinsing, the feel when passing a finger at the time of finishing, the coherence at the time of finishing, and the lack of stickiness at the time of finishing become poor.

[0024] Among the component (D) used in the present invention, from the viewpoints of the feel when passing a finger at the time of finishing and the coherence at the time of finishing, it contains linoleamidopropyl PG-dimonium chloride dimethicone phosphate.

[0025] The linoleamidopropyl PG-dimonium chloride dimethicone phosphate used in the present invention is available as a commercial product and can be used as it is. Examples of such commercial products include Arlasilk-PLN-LQ-(AP) (manufactured by CRODA Co., Ltd.).

[0026] The content of the component (D) used in the present invention is preferably 0.06 to 2.5%, more preferably 0.12 to 2%, and still more preferably 0.25 to 1.5%. When the component (D) is less than 0.06%, the feel when passing a finger at the time of finishing and the coherence at the time of finishing become poor. When the component (D) exceeds 2.5%, the feel when passing a finger during rinsing, the feel when passing a finger at the time of finishing, the coherence at the time of finishing, and the lack of stickiness at the time of finishing become poor.

[0027] In addition to the components (A) to (D) above, the hair cosmetic composition of the present invention may contain various components commonly used in cosmetics, quasi-drugs, pharmaceuticals, etc., as long as they do not impair its effects. Examples include cationic surfactants, anionic surfactants, amphoteric surfactants, nonionic surfactants, higher alcohols, higher fatty acids, silicones, hydrocarbon oils, ester oils, vegetable oils, cationic polymers, anionic polymers, amphoteric polymers, nonionic polymers, thickeners, alcohols, polyhydric alcohols, sugars, amino acids, plant extracts, pH adjusters, fragrances, preservatives, etc. These components are not particularly limited and may contain one or more as long as they do not impair the effects of the present invention. However, these are not limited to examples.

[0028] The viscosity of the hair cosmetic composition in the present invention at 20°C is not particularly limited, but is preferably 1,000 to 100,000 mPa·s.

[0029] The viscosity of the hair cosmetic composition in this invention at 20°C was measured by filling a 140g sample bottle (Food 140 (manufactured by Daiichi Glass Co., Ltd.)) with 120g of the hair cosmetic composition prepared by a conventional method, allowing it to stand at 20°C for 24 hours to regulate the temperature, and then measuring it using a Type B viscometer (Model: Digital Viscometer TVB-10M, manufactured by Toki Sangyo Co., Ltd.) with a No. 4 rotor for 1 minute at a rotation speed of 6 rpm.

[0030] The pH of the hair cosmetic composition in the present invention at 20°C is not particularly limited, but is preferably between 1.5 and 6.5.

[0031] The pH of the hair cosmetic composition in this invention at 20°C was measured using a glass electrode type hydrogen ion concentration indicator (F-71, manufactured by Horiba, Ltd.) after the hair cosmetic composition, prepared by a conventional method, was allowed to stand at 20°C for 24 hours to regulate the temperature.

[0032] The hair cosmetic composition in this invention can be prepared and used in the form of an emulsion, cream, gel, or the like.

[0033] The hair cosmetic composition in this invention is filled into various containers such as a pump dispenser, a bottle with a cap, a jar, a tube, or a pouch, and stored until use.

[0034] The method of using the hair cosmetic composition in the present invention is not particularly limited, but it can be applied to wet or dry hair, and it is particularly preferable to apply it to wet hair.

[0035] The hair cosmetic composition of the present invention is preferably used as a hair conditioning agent such as a hair treatment.

[0036] The hair cosmetic of the present invention is preferably used by applying it to the hair before or after applying a hair dye, bleach, or decolorizer. In this case, the hair cosmetic of the present invention may be applied to the hair before applying a hair dye, bleach, or decolorizer, or after applying a hair dye, bleach, or decolorizer, or both. In particular, from the viewpoint of suppressing the widening of the hair cuticle due to the chemical treatment of hair dyeing, bleaching, or decolorization, and suppressing the outflow of dye or internal hair components, it is preferable to apply it to the hair after applying a hair dye, bleach, or decolorizer. [Examples]

[0037] The present invention will be described in more detail below with reference to examples, but these examples are not intended to limit the present invention in any way.

[0038] In the evaluation tests described herein, the components and their contents in the hair cosmetic were varied and tested. All units indicating the content of each component are in mass%, and these were prepared by conventional methods. In parentheses, "EO" indicates ethylene oxide, and the number indicates the number of moles of ethylene oxide added.

[0039] In the evaluation test methods described herein, the following were evaluated for "ease of combing during rinsing," "ease of combing after finishing," "cohesion after finishing," and "lack of stickiness after finishing."

[0040] The bleaching agent compositions listed in Table 1 were mixed in a ratio of 15:16:5 for agent 1:agent 2:agent 3, and 200g was uniformly applied to a wig (100% human black hair, Queen Cut No. 775N, manufactured by Beaulux Co., Ltd.). After leaving it for 40 minutes, it was thoroughly rinsed with water, washed with shampoo (GREEN BOTTLE Botanical Rich Shampoo, Luxury Bergamot scent, manufactured by Dariya Co., Ltd.), and then dried with a hairdryer to prepare the evaluation wig.

[0041] The evaluation wigs were wet with lukewarm water at 40°C, and 20g of the hair cosmetic obtained in each example and comparative example was applied uniformly to the evaluation wigs. After leaving it for 5 minutes, it was rinsed with lukewarm water at 40°C. The feel of the hair at this time was evaluated as "ease of combing during rinsing". After that, the hair was towel-dried and then dried with a hairdryer. The feel of the hair was evaluated as "ease of combing after finishing", "manageability after finishing", and "lack of stickiness after finishing".

[0042] <Method for evaluating how easily hair feels to the touch during rinsing> In the evaluation tests related to "smoothness during rinsing" described in this specification, 10 panelists judged whether or not the hair was "smooth during rinsing" and evaluated it according to the following evaluation criteria. <Evaluation criteria for smoothness of hair during rinsing> ◎: 8 or more out of 10 people rated the hair as having good manageability during rinsing. ○: 6-7 out of 10 people rated the hair as having good manageability during rinsing. △: 4-5 out of 10 people rated the hair as having good manageability during rinsing. ×: Three out of ten people rated the hair as having good manageability during rinsing.

[0043] <Method for evaluating the smoothness of the finished product> In the evaluation tests related to "finger-friendly feel" described in this specification, 10 panelists judged whether the finished product had "good finger-friendly feel" and evaluated it according to the following criteria. <Evaluation criteria for smoothness of the finished product> ◎: 8 or more out of 10 people rated the finished product as having a smooth feel to the touch. ○: 6-7 out of 10 people rated the finished result as having good manageability. △: 4-5 out of 10 people rated the finished product as having a smooth feel to the touch. ×: Three out of ten people rated the finished product as having good manageability.

[0044] <Method for evaluating the cohesiveness of the finished product> In the evaluation tests related to "cohesion upon completion" as described in this specification, 10 panelists judged whether or not the "cohesion upon completion was good," and evaluated it according to the following evaluation criteria. <Evaluation criteria for the overall cohesiveness of the finished product> ◎: More than 8 out of 10 people rated the finished product as having a good overall cohesive look. ○: 6-7 out of 10 people rated the finished product as having a good overall cohesive look. △: 4-5 out of 10 people rated the finished product as having a good overall cohesive look. ×: Three or fewer out of ten people rated the finished product as having a good overall cohesive look.

[0045] <Method for evaluating the absence of stickiness upon application> In the evaluation test related to "lack of stickiness upon application" as described in this specification, 10 panelists judged whether or not there was "no stickiness upon application" and evaluated it according to the following evaluation criteria. <Evaluation criteria for the absence of stickiness upon application> ◎: More than 8 out of 10 people rated it as not feeling sticky after application. ○: 6-7 out of 10 people rated the product as not feeling sticky after application. △: 4-5 out of 10 people rated the product as not feeling sticky after application. ×: Three out of ten people rated the product as not feeling sticky after application.

[0046] [Table 1]

[0047] [Table 2]

[0048] [Table 3]

[0049] [Table 4]

[0050] [Table 5]

[0051] Examples 1 to 32 of the present invention yielded good results regarding smoothness of the hair during rinsing, smoothness of the hair after finishing, manageability after finishing, and lack of stickiness after finishing.

[0052] Examples 33 to 35 of the hair cosmetic are described below.

[0053] When various tests were conducted using Examples 33 to 35, it was confirmed that good results were obtained regarding smoothness of the hair during rinsing, smoothness of the hair after finishing, manageability after finishing, and lack of stickiness after finishing.

[0054] Furthermore, good results were obtained when using Examples 33 to 35 on hair that had not been treated with hair dye, bleach, or decolorizer.

[0055] <Example 33> Component Content (mass%) (A) Dimethyldiallylammonium chloride / acrylamide copolymer 0.255 (B) O-[2-hydroxy-3- chloride] (Trimethylammonio)propyl guar gum 0.400 (C) Aminopropyl Dimethicone 0.500 (D) Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone 0.500 Cetanol 6,000 Stearyl alcohol 2,000 Behenyltrimethylammonium chloride 2,400 Ethanol 0.600 Liquid paraffin 6,000 Methylpolysiloxane 4.500 Citric acid 0.300 1,3-Butylene glycol 3.000 Methyl parahydroxybenzoate 0.200 Centella Asiatica Extract (Centella Asiatica Extract BG70: Manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.010 Fragrance 0.500 Purified water 72.835 Total 100,000 pH (20℃): 2.70 Viscosity (20℃): 60,000mPa·s

[0056] <Example 34> Component Content (mass%) (A) Dimethyldiallylammonium chloride / acrylamide copolymer 0.04 (B) O-[2-hydroxy-3- chloride] (Trimethylammonio)propyl guar gum 0.05 (C) Aminopropyl dimethicone 0.05 (D) Linoleamidopropyl PG-Dimonium Chloride Dimethicone 0.06 Cetanol 6.00 Stearyl alcohol 2.00 Behenyltrimethylammonium chloride 2.40 Ethanol 0.60 Liquid paraffin 6.00 Methylpolysiloxane 4.50 Citric acid 0.30 1,3-Butylene glycol 3.00 Methyl parahydroxybenzoate 0.20 Centella asiatica extract (Centella asiatica extract BG70: manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.01 Fragrance 0.50 Purified water 74.29 Total 100.00 pH (20℃): 2.55 Viscosity (20℃): 75,000mPa·s

[0057] <Example 35> Component Content (mass%) (A) Dimethyldiallylammonium chloride / acrylamide copolymer 1.70 (B) O-[2-hydroxy-3- chloride] (Trimethylammonio)propyl guar gum 2.00 (C) Aminopropyl Dimethicone 10.00 (D) Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone 2.50 Cetanol 6.00 Stearyl alcohol 2.00 Behenyltrimethylammonium chloride 2.40 Ethanol 0.60 Liquid paraffin 6.00 Methylpolysiloxane 4.50 Citric acid 0.30 1,3-Butylene glycol 3.00 Methyl parahydroxybenzoate 0.20 Centella asiatica extract (Centella asiatica extract BG70: manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.01 Fragrance 0.50 Purified water 58.29 Total 100.00 pH (20℃): 2.85 Viscosity (20℃): 55,000mPa·s [Industrial applicability]

[0058] The present invention provides a hair cosmetic that offers smoothness during rinsing, smoothness during the finished hair treatment, good manageability during the finished hair treatment, and no stickiness during the finished hair treatment.

Claims

[Claim 1] (A) One or more selected from dimethyldiallylammonium chloride / acrylamide copolymer, polydimethylmethylenepyrrolidinium chloride, dimethyldiallylammonium chloride / acrylic acid copolymer, or acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer. (B) One or more selected from O-[2-hydroxy-3-(trimethylammonio)propyl]guar gum chloride or O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethylcellulose chloride, (C) One or more selected from aminopropyl dimethicone, amodimethicone, or biscetearyl amodimethicone. (D) Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone It contains, The content of component (A) is 0.04 to 1.7% by mass, The content of component (B) is 0.05 to 2% by mass, The content of component (C) is 0.05 to 10% by mass, A hair cosmetic comprising the above-mentioned component (D) in a content of 0.06 to 2.5% by mass.

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