Systems and methods for semiconductor metrology and surface analysis using secondary ion mass spectrometry - Patents.com

Abstract

To provide a system and a method for semiconductor measurement and surface analysis using secondary ion mass spectrometry (SIMS).SOLUTION: A secondary ion mass spectrometry (SIMS) system includes a sample stage. A primary ion beam is directed to the sample stage. A retraction lens is directed toward the sample stage. The retraction lens is configured to provide a low retraction field for secondary ions emitted from the sample on the sample stage. A magnetic sector analyzer is coupled to the retraction lens along an optical path of the SIMS system. The magnetic sector analyzer includes an electrostatic analyzer (ESA) coupled to a magnetic sector analyzer (MSA).SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application claims the benefit of U.S. Provisional Patent Application No. 62 / 114,521, filed February 10, 2015, the entire contents of which are incorporated herein by reference. This application also claims the benefit of U.S. Provisional Patent Application No. 62 / 114,519, filed February 10, 2015, the entire contents of which are incorporated herein by reference. This application also claims the benefit of U.S. Provisional Patent Application No. 62 / 114,524, filed February 10, 2015, the entire contents of which are incorporated herein by reference.

[0002] Embodiments of the invention are in the field of semiconductor metrology, and more particularly, to systems and approaches for semiconductor metrology and surface analysis using Secondary Ion Mass Spectrometry (SIMS). [Background technology]

[0003] Secondary ion mass spectrometry (SIMS) is a technique used to analyze the composition of solid surfaces and thin films by sputtering the surface of a specimen with a focused primary ion beam and collecting and analyzing the secondary ions that are emitted. The mass / charge ratio of these secondary ions is measured with a mass spectrometer to determine the elemental, isotopic, or molecular composition of the surface to a depth of 1-2 nanometers. Due to the large variation in ionization probability between different materials, SIMS is generally considered to be a qualitative technique, although quantitation is possible in standard use. SIMS is the most sensitive surface analysis technique, with elemental detection limits ranging from parts per million to parts per billion.

[0004] Generally, SIMS is 10 -4 A high vacuum is required, with an atmosphere of less than 10 Pa. The high vacuum is needed to prevent the secondary ions from colliding with the background gas on their way to the detector (i.e. the mean free path of the gas molecules in the detector must be large compared to the size of the device) and to prevent surface contamination that would otherwise occur due to adsorption of background gas particles during the measurement.

[0005] Three basic types of ion guns are used in SIMS analysis. One type is usually used with duoplasmatrons or with noble gases, e.g. 40 Ar + ,Xe + ),oxygen( 16 O - , 16 O 2+ , 16 O 2- ) or by electron ionization such as SF5 + (Produced from SF6) or C 60 + In this type of source, ions of gaseous elements are produced by ionized molecules such as fullerenes. This type of ion gun is easy to operate and produces loosely focused but high current ion beams. The second source type is the surface ionization source, which 133 Cs +The cesium atoms are evaporated through a porous tungsten plug and ionized during evaporation. Depending on the gun design, fine focus or high current can be obtained. A third source type is the liquid metal ion gun (LMIG), which operates with a metal or metal alloy that is liquid at room temperature or slightly higher. The liquid metal covers a tungsten tip and releases ions under the influence of a strong electric field. Gallium sources can operate with elemental gallium, but recently gold, indium and bismuth sources have been developed that use alloys with lower melting points. LMIGs provide a tightly focused ion beam (less than 50 nanometers) with moderate intensity and can even produce short pulsed ion beams. They are therefore commonly used in static SIMS instruments.

[0006] The choice of ion species and ion gun depend on the required current (pulsed or continuous), the required beam dimensions of the primary ion beam, and the sample to be analyzed, respectively. Oxygen primary ions are often used to investigate electropositive elements due to the increased probability of generating positive secondary ions, whereas cesium primary ions are often used when electropositive elements are investigated. For short pulsed ion beams in static SIMS, LMIG is most frequently deployed for analysis. LMIG can be combined with an oxygen gun or a cesium gun during elemental depth profiling and with a C gun during molecular depth profiling. 60 + Alternatively, it can be combined with a gas cluster ion source.

[0007] Depending on the type of SIMS, three basic analyzers are available: sector, quadrupole, and time-of-flight. Sector field mass spectrometers use a combination of electrostatic and magnetic analyzers to separate secondary ions by their mass to charge ratio. Quadrupole mass analyzers separate masses using resonant electric fields that allow only selected masses to pass. Time-of-flight mass analyzers separate ions according to their velocity in a field-free drift path. Since all ions have the same kinetic energy, the velocity, and therefore the time-of-flight, varies with mass. Time-of-flight mass analyzers require pulsed secondary ion generation using either a pulsed primary ion gun or pulsed secondary ion extraction. Time-of-flight mass analyzers are the only analyzer type that can simultaneously detect all generated secondary ions and are the standard analyzer for static SIMS instruments.

[0008] In the field of surface analysis it is common to distinguish between static and dynamic SIMS. Static SIMS is a process concerned with surface atomic monolayer or molecular analysis, usually using a pulsed ion beam and a time-of-flight mass spectrometer. Dynamic SIMS, on the other hand, is a process concerned with bulk analysis, and is closely related to sputtering processes. Dynamic SIMS uses a DC primary ion beam and a magnetic sector or quadrupole mass spectrometer.

[0009] SIMS is a very powerful technique, however improvements are needed in the areas of SIMS measurement instruments, systems and methodologies. DISCLOSURE OF THEINVENTION

[0010] Embodiments of the present invention include systems and methods for semiconductor metrology and surface analysis using secondary ion mass spectrometry (SIMS).

[0011] In one embodiment, a secondary ion mass spectrometry (SIMS) system includes a sample stage. A primary ion beam is directed to the sample stage. An extraction lens is directed to the sample stage. The extraction lens is configured to provide a low extraction field for secondary ions emitted from a sample on the sample stage. A magnetic sector spectrograph is coupled to the extraction lens along an optical path of the SIMS system. The magnetic sector spectrograph includes an electrostatic analyzer (ESA) coupled to a magnetic sector analyzer (MSA).

[0012] In one embodiment, a method for measuring and controlling a surface potential of a specimen includes measuring the kinetic energy of charged particles emitted from a surface of the specimen. The method also includes determining a shift in the kinetic energy of the charged particles. The surface potential of the specimen surface changes in response to the shift in the kinetic energy of the charged particles.

[0013] In one embodiment, a method for measuring wafer backside contact resistance includes measuring a gap distance value for a surface of a wafer based on a comparison of a primary capacitive sensor electrode driven with a first drive signal and a compensation capacitive sensor electrode driven with a second drive signal that is amplitude or phase shifted compared to the first drive signal. A value of the second drive signal is measured. The value of the second drive signal is calibrated against a reference impedance standard to determine an impedance value of the wafer relative to ground. A contact resistance value for the surface of the wafer is determined based on the gap distance value and the impedance value of the wafer relative to ground. [Brief description of the drawings]

[0014] [Figure 1] 1 shows a schematic layout of a SIMS measurement system according to one embodiment of the present invention. [Diagram 2] 1 illustrates a schematic of charge compensation considerations for a SIMS system, according to one embodiment of the present invention. [Diagram 3] 1 illustrates a stage area including a Faraday cup and an area for storing calibration standards according to one embodiment of the present invention. [Figure 4A] 1 is a schematic representation of the use of a system of energy slits with an electrostatic analyzer and a current sensor to monitor and control a charge compensation system, according to one embodiment of the present invention. [Figure 4B] 1 is a schematic representation of the use of a system of energy slits with an electrostatic analyzer and a current sensor to monitor and control a charge compensation system, according to one embodiment of the present invention. [Diagram 5] 1 illustrates a secondary ion beam path through an upper spectrometer and curved electrostatic analyzer (ESA) section according to one embodiment of the present invention. [Figure 6] 1 illustrates the secondary ion beam path for positive (cation) ions through the upper spectrometer and curved electrostatic analyzer (ESA) section according to one embodiment of the present invention. [Figure 7]1 shows an energy distribution scan towards high energy using a low energy current sensor and a high energy current sensor followed by a curved ESA 116 as feedback to change the mean passing energy of the electrostatic analyzer according to one embodiment of the present invention. [Figure 8A] FIG. 8 is a schematic diagram for measuring secondary ion energy distribution using the electrostatic bending ESA 116 and high and low energy slit sensors described in connection with FIG. 7 according to one embodiment of the present invention. [Figure 8B] FIG. 8 is a schematic diagram for measuring secondary ion energy distribution using the electrostatic bending ESA 116 and high and low energy slit sensors described in connection with FIG. 7 according to one embodiment of the present invention. [Figure 8C] FIG. 8 is a schematic diagram for measuring secondary ion energy distribution using the electrostatic bending ESA 116 and high and low energy slit sensors described in connection with FIG. 7 according to one embodiment of the present invention. [Figure 8D] FIG. 8 is a schematic diagram for measuring secondary ion energy distribution using the electrostatic bending ESA 116 and high and low energy slit sensors described in connection with FIG. 7 according to one embodiment of the present invention. [Figure 9] 1 shows an energy distribution scan including a curved ESA scan at ESA 116 and ESA 118 at the same voltage according to one embodiment of the present invention. [Figure 10] 1 illustrates a schematic of a positive potential on a sample due to surface charging, according to one embodiment of the present invention. [Figure 11] FIG. 1 is a schematic diagram illustrating electron beam based charge neutralization and control according to one embodiment of the present invention. [Figure 12] FIG. 2 is a schematic diagram showing photoconduction of a sample using a photon source of variable intensity according to one embodiment of the present invention. [Figure 13A] FIG. 2 is a schematic diagram illustrating charge neutralization through the use of electron emitting material away from the sample according to one embodiment of the present invention. [Figure 13B] FIG. 2 is a schematic diagram illustrating effective charge neutralization when electron flux exceeds the primary ion induced positive surface charge according to one embodiment of the present invention. [Figure 14] 13 illustrates generally some parameters related to using a compensation electrode to determine the gap distance. [Figure 15] FIG. 1 shows a block diagram of an exemplary computer system according to one embodiment of the present invention. EXAMPLES

[0015] Systems and methods for semiconductor metrology and surface analysis using secondary ion mass spectrometry (SIMS) are described. In the following, a number of specific details, such as SIMS analysis techniques and system configurations, are described in order to provide a thorough understanding of embodiments of the invention. It will be apparent to one of ordinary skill in the art that embodiments of the invention can be practiced without these specific details. Additionally, well-known features, such as the overall semiconductor device stack, have not been described in detail in order to not unnecessarily obscure embodiments of the invention. Additionally, it should be understood that the various embodiments illustrated in the figures are illustrative representations and are not necessarily drawn to scale.

[0016] SUMMARY OF THE DISCLOSURE In a first aspect, an embodiment of the present invention relates to a system and method for characterizing and process controlling structures on semiconductor wafers during manufacture using secondary ion mass spectrometry (SIMS).

[0017] State-of-the-art semiconductor manufacturing inherently involves hundreds of process operations. Each process operation is subject to processing variations that can lead to variations and degradation in the performance of the final device. For this reason, many measurements and inspections are performed to ensure that the manufacturing process is performed correctly and within specifications, as well as to provide feedforward and feedback to control the manufacturing process. Process control requires several key attributes to enable its effectiveness:

[0018] First, the costs of measurement and inspection must be consistent with economical equipment manufacturing. In practice, this means that the cost of the tool, the cost of consumables, the cost of ownership (including maintenance, calibration and other costs), its useful life, the time required to make the measurement, and the labor costs associated with its effective use must be consistent with the manufacturing environment. Perhaps most importantly, the characteristics must be nondestructive, because the cost of semiconductor wafers in process is so high that techniques requiring destructive testing are not always feasible.

[0019] Second, inspection and metrology must measure samples that are directly related to process control requirements. While techniques that can measure only "monitor" wafers, i.e., wafers that have been subjected to only one or a few process operations, can be useful for fine or crude quality control of a tool, effective process control requires that the structures being measured are as similar as possible to those of the actual equipment, and that measurement sampling can be performed as frequently as possible compared to the rate of process variation and drift.

[0020] Third, and perhaps most importantly, the inspection or measurement operation must have the desired information content needed for process control, ie, the required relevance, resolution, accuracy and precision.

[0021] More essentially, secondary ion mass spectrometry (SIMS) is a known materials characterization technique that can determine the depth profile of elemental composition with high accuracy and precision. Due to this unique capability, SIMS is widely used in materials science and analytical laboratory settings. SIMS is currently used in an "off-line" mode in semiconductor manufacturing, and its use in "in-line" process control is currently impractical due to its inability to address the practical issues mentioned above. Thus, there is a need for a secondary ion mass spectrometry system that provides the known capabilities of SIMS while addressing the gaps that prevent its use in in-line process control.

[0022] To meet the requirements of an in-line semiconductor manufacturing environment, several gaps in current SIMS designs must be addressed. Such gaps include the challenges associated with measurements on a typical wafer production, the time it takes to perform the measurements, tool availability / uptime (including, for example, time for calibration and validation), and the costs associated with maintaining such tools. Design details that address one or more of the above issues are described below in accordance with one or more embodiments of the present invention.

[0023] With respect to measurements on production wafers, performing SIMS measurements on production wafers involves three design-constraining challenges. First, measurements on production wafers must typically be confined to a small designated area such as a 50 μm x 50 μm pad. Second, at the same time, manufacturers are typically concerned with compositional changes at very small differences in depth. Third, there may be an unpredictable grounding path to the measurement site. With poor or non-existent grounding, the wafer may become charged during the SIMS measurement, which leads to several challenges including deflection of the primary beam away from the desired site, reduced detected secondary ion signal, and reduced ability to accurately identify and resolve secondary ion masses.

[0024] To address one or more of the above problems with measurements performed on production wafers, in one embodiment of the present invention, the SIMS approach described herein involves the use of a low extraction voltage at a secondary extraction lens of the SIMS measurement system. In particular, only a very weak electric field is used between the focusing lens and the sample under measurement. This approach is the opposite of typical SIMS designs, which use a strong electric field between the extraction lens and the sample to attract secondary ions towards the lens, increasing the number of ions collected. In one embodiment, the extraction field threshold is up to about 10 Volts / mm (absolute).

[0025] FIG. 1 shows a schematic layout of a SIMS measurement system 100 according to one embodiment of the present invention.

[0026] Referring to FIG. 1, the SIMS measurement system 100 includes an XY stage that holds a sample for analysis. It is noted that the stage does not have to be XY, but can be any type, such as XYZ, XY-theta, R-theta, etc. The XY stage can include a Faraday cup and fiducials, which are described in detail below. A primary ion beam 104, generated by an ion source, refined by a mass filter, and focused using a set of ion optics, is directed to the XY stage 102, for example, at an angle of incidence of 40 degrees. A charge compensation electron gun 106 may be directed to the XY stage, as shown in FIG. 1. A drawing lens 108 is positioned above the XY stage 102. In one embodiment, the pull-in lens 108 has a portion near ground potential to maintain a small extraction field between the lens and the sample, typically on the order of 10 V / mm or less. A secondary ion beam 110 is collected from the sample on the XY stage toward the pull-in lens 108 and toward the collection / detection path of the SIMS system 100. Although not shown, it should be understood that the SIMS measurement system 100 of FIG. 1 can be housed in a vessel or chamber having a vacuum environment.

[0027] Referring again to FIG. 1, following the drawing lens 108, an array of elements 112 may be included along the path 110. The illustrated array of elements 112 may include secondary ion optics, deflectors, and / or additional compensation mechanisms. The secondary ion beam 110 is then directed through a slit 114 before being directed to a first electrostatic analyzer (ESA) 116 and a second ESA 118. A slit 120 is located between the first ESA 116 and the second ESA 118. The slit may be located at a location where the beam 110 diverges with energy. In the SIMS system 100, the two ESAs 116 and 118 direct the beam to the floor of the SIMS system 100. The two ESAs 116 and 118 may also generate a point where the beam diverges with energy, which may be provided as a signal (e.g., along signal line 121) to the charge compensation system 106.

[0028] Referring again to FIG. 1, the beam 110 is then directed through a slit 120A and other mechanisms. For example, wired slits and apertures 122 can be placed at several points along the beam path 110 to restrict / shape the beam and monitor the current and beam position, many of which are on operable actuators. Various other elements 124 such as optics and deflectors are included along said path 110 to keep the beam aligned and properly shaped.

[0029] 1, the beam 110 is then directed through slit 126 to a third ESA 128, and out through slit 130 and additional optics 132. The beam 110 is then directed to a magnetic sector analyzer (MSA) 134. The MSA 134 includes multiple (e.g., ten) detectors 136 along a focal plane 138, allowing for up to ten detections in parallel, as will be described in more detail below. It should be understood that the MSA 134 and the third ESA 128 together comprise a magnetic sector analyzer.

[0030] In one embodiment, referring again to system 100, by using a low extraction voltage between the extraction lens 108 and the sample 102, 80% of the signal available with a normal SIMS measurement is sacrificed. However, in exchange, it is much easier to accurately position the primary beam. For example, in systems with strong extraction fields, the primary beam is deflected by tens or even hundreds of microns when passing through the field, which means that the aim of the primary beam must be changed to compensate. This makes the control of a typical SIMS measurement difficult and makes accurate rastering of the beam in a small 50 μm area very difficult.

[0031] The deflection of the primary beam due to the entrainment field is more severe for lower energy primary ions. Thus, under typical or conventional SIMS operation, there is an incentive to maintain a high primary energy to minimize beam deflection. However, a high energy primary beam has two effects that reduce depth resolution. First, the high energy primary beam penetrates deeper into the sample, producing ions over a range of depths other than the surface. Second, the higher energy pushes the surface atoms of the sample deeper into the substrate, essentially smearing the material over depth. In one embodiment, the fine depth resolution required by the semiconductor industry is benefited by the use of a low energy primary beam, as opposed to the high energy primary beams used in typical SIMS measurements. Thus, in one embodiment, the above-mentioned advantages of using a low entrainment field design are greater when designing for maximum depth resolution, since the otherwise severe deflection of the low energy primary beam is mitigated by the low entrainment field design.

[0032] Furthermore, in one embodiment, by using a low pulling field, it is easier to address sample charging in the case of poor grounding. For example, by reducing the field above the sample, a low energy electron flood can be used to neutralize the charge. In contrast, in more typical SIMS designs using strong pulling fields, the charge compensation beam must be operated at high energy and precisely steered to overcome the field deflection and precisely position the beam at the measurement site, which is a very complicated process. Figure 2 shows a schematic of the charge compensation considerations for a SIMS system. The details of the charge compensation system are described in more detail below, along with examples.

[0033] 2, a portion of the system 100 of FIG. 1 is depicted on the left, in particular a section including the first and second ESAs 116 and 118 and the charge compensation system 106. In a first scenario 200, when the analysis wafer is at ground potential, the ion beam is nominally located in the middle of the slit 120. The tails of the beam provide a small signal to each of the two current detectors 201. In a second scenario 202, when the wafer is charged, the ion beam shifts to one of the slits 120 depending on the sign of the charge. The current in the two detectors 201 changes, which can be used to control the charge compensation system 106.

[0034] With respect to throughput, the time required to perform a series of measurements on a wafer is a critical factor in the economic application of the measurement technique. In one or more embodiments of the present invention, several secondary ion species are measured in parallel (simultaneously) to improve throughput.

[0035] Essentially, in terms of throughput, common SIMS designs can be divided into three categories: (1) time-of-flight (TOF), (2) quadrupole detection, and (3) magnetic sector detection. In TOF SIMS, the primary beam is pulsed and the sputtered secondary ion species are classified according to the time they reach the detector. TOF SIMS has the advantage that a wide range of secondary ion species is collected in parallel, but the pulsed nature of the measurement slows down the measurement speed. In quadrupole detection techniques, the primary beam is delivered continuously, but the detector can only measure one ion species at a time (switching from one species to another can be done quickly). Finally, the third common technique, the magnetic sector, separates ion species according to mass / charge using a combination of electric and magnetic fields. As in quadrupole systems, the primary beam is turned on continuously. However, in a typical magnetic sector system, a single detector is used as the spectrometer, which is also limited to the detection of a single species at a time.

[0036] None of the above conventional approaches provide the speed and parallel detection likely required for a semiconductor manufacturing environment. In contrast, in one or more embodiments of the present invention, a magnetic sector spectrograph is used. Like a spectrometer, a magnetic sector analyzer separates different mass species by sending a beam through a magnetic field. However, the analyzer design focuses the different masses along a line or "focal plane." By placing multiple detectors at various locations along the focal plane, the different masses can be measured in parallel. In a specific embodiment, the SIMS system design includes ten different detectors capable of measuring the majority of species present in any single semiconductor measurement. It is understood that fewer or more than ten detectors may be used. It is also understood that, like TOF SIMS, in this configuration the entire available mass range may not be collected in parallel, but since there are a limited number of species typically used in a given semiconductor process and manufacturers usually have a good notion of which species are likely to be present, a multiple detector approach is not detrimental. It should also be noted that multiple detectors can be mounted on a translation stage and their positions along the focal plane, and therefore the species collected, can be adjusted according to the needs of a particular measurement.

[0037] Regarding availability and serviceability, due to the time-critical nature of process control measurements, it is essential that the tools are available when wafers are ready to be measured. This makes it important that the tools have a high mean time between failures and a low mean time to repair. Furthermore, measurement tools are required to be calibrated at all times. Therefore, SIMS tools must be able to automatically check and update their calibration.

[0038] In one or more embodiments, several design aspects of the SISM system are tailored to address the challenges of availability and maintainability. In one embodiment, a monolithic system architecture is employed to improve the overall stability of the hardware. For example, each of the major subsystems, such as the pull optics, lower primary column, and mass analyzer, are rigidly mounted to each other. This may result in a tradeoff for flexible alignment, but the benefit is a system that can maintain a more secure alignment. In addition, in one embodiment, two turning electrostatic analyzers (ESAs) are added to the secondary path to divert the beam in a direction that allows a several-hundred pound spectrometer magnet to be mounted below a main measurement chamber, near the floor, as shown in FIG. 1. Such a configuration improves service access and vibration stability.

[0039] In one or more embodiments, several internal checks and calibrations are added to the SIMS system to maintain measurement consistency, which may include one or more of: (1) a Faraday cup as shown in FIG. 1 with a fiducial overlay to verify the primary beam current, position, and focus, and / or (2) the ability to read current at multiple apertures and slits along the secondary path, including the ability to mechanically scan the slits to verify beam alignment and monitor aperture wear, as shown in FIG.

[0040] In one embodiment, a set of internal reference samples is included with the SIMS system. The internal samples can be automatically moved to the measurement locations to periodically check various important aspects of the beam. This includes layered materials of predetermined thicknesses to monitor primary sputtering rate and raster uniformity, patterned boxes of known dimensions to verify raster size and location, and simple chips of various compositions to monitor overall signal strength. Multiple tests can be performed at multiple primary energies and currents. As an example, FIG. 3 shows a stage area including an area for storing a Faraday cup and calibration standards according to one embodiment of the invention.

[0041] Referring to Figure 3, a portion of the system 100 of Figure 1 is shown on the left, specifically a section including the XY stage 102 and the drawing lens 108. A wafer or sample 103 is placed on the XY stage 102 below the drawing lens 104. The XY stage 300 includes a Faraday cup 300, the top of which is also shown in Figure 3. A transfer robot 302 may be included, along with a "parking lot" for one or more reference wafers, such as layered films of known composition and / or thickness.

[0042] In a second aspect, one or more embodiments include measuring the surface potential of the sample by observing a shift in kinetic energy of the emitted charged particles or ions. One or more embodiments include measuring and controlling the surface potential by using the shift in kinetic energy as a feedback mechanism.

[0043] Essentially, secondary ions are created by dislodging atoms from the surface, some of which are ionized. The secondary ions are emitted at a range of velocities, or equivalently, a range of kinetic energies. As an ion travels along its optical path, its kinetic energy at any point A is the sum of the initial kinetic energy (KE), the surface potential of the sample, the local potential at A, and any KE contributions from electrodynamic elements (e.g. bunchers, cyclotrons, etc.). Determining the KE distribution and comparing it to a distribution from a reference sample with known surface potential provides a measure of the sample potential.

[0044] The main reason for measuring surface potential is the charging of insulating samples caused by the uneven flow of positive and negative charges through the sample. Secondary ions can be formed by bombarding the surface with atoms, ions, electrons, or photons. Ions and electrons add charge to the surface, while secondary charged particles emitted from the surface remove charge. If the sample is conductive, the imbalance in charge transport can be dissipated. If the sample is not electrically connected to an electrode at a stable potential, the insulating overlayer (which is often patterned laterally, for example) will become charged and the entire sample will become charged. Additionally, surface potential can be measured when material is removed from the surface, possibly subjecting it to variations in sample conductivity or variations in the emission of charged particles.

[0045] In one embodiment of the invention, the emitted secondary ions are passed through an electrostatic analyzer, which distributes the ions in space according to their energy. The complete KE distribution is measured by changing the electric field of the ESA as the dispersed ion beam passes through an ion detector 120. The change in KE can be measured by using one or two detectors positioned at the tails while intercepting only the low and / or high tails of the energy distribution. In one embodiment, the slope of a tail is measured by slightly modulating the ESA deflection field. To maintain the position of the main transmit beam, the device can have an arrangement of two ESAs and an ion detector 120 between them. In this embodiment, the second ESA or the second ESA with a matching lens has an equal and opposite dispersive strength to the first ESA.

[0046] A particular embodiment of the invention measures and controls the surface potential of a sample by observing the shift in kinetic energy of emitted charged particles and using the shift in kinetic energy as a feedback mechanism. Although the illustrated embodiment is described in the context of SIMS measurements, it should be understood that the embodiments described herein are applicable to other measurements and metrology techniques and systems.

[0047] One or more embodiments relate to a system of at least one electrostatic analyzer with an energy slit equipped with ion current sensors. One or more embodiments relate to a system and / or method for measuring the energy distribution and energy shift of all secondary charged particles transported from the sample surface before the mass analyzer. One or more embodiments relate to the implementation of an electrostatic analyzer and an energy slit feedback system for monitoring the surface charge. One or more embodiments relate to the use of an active control system for adjusting the surface potential. In one embodiment, a system of at least one electrostatic analyzer with an energy slit equipped with ion current sensors, a system and / or method for measuring the energy distribution and energy shift of all secondary charged particles transported from the sample surface before the mass analyzer, and an electrostatic analyzer and an energy slit feedback system implemented for monitoring the surface charge are used together as a feedback system for changes in the surface potential.

[0048] In embodiments applicable to SIMS measurements where the primary ion beam is sent through a mass analyzer, it is often analytically desirable to reject secondary ions generated near the edge of the eroded area, as this can perturb the depth profile. It is possible to measure the complete KE distribution while the primary beam is rejected. In one embodiment, the tails of the distribution are measured while the primary beam passes through the mass analyzer.

[0049] 4A and 4B include a schematic diagram of the use of an energy slit system equipped with an electrostatic analyzer and a current sensor to monitor and control a charge compensation system according to one embodiment of the present invention.

[0050] Referring to FIG. 4A, the first part of the flow chart 400 starts at operation 402 where it is determined whether charge compensation is needed. If charge compensation is not needed, charge compensation is turned off at operation 404. This is confirmed using the charge compensation slit in the bent ESA at operation 406 and proceeds to 408 of FIG. 4B. If charge compensation is needed, charge compensation is turned on at operation 410. This is monitored using the charge compensation slit in the bent ESA at operation 412. At operation 414, the condition is judged to see if no signal on low energy charge compensation (CC) Jaw / Si intensity fades away. If yes, the decision proceeds to 416 of FIG. 4B. If no, the decision proceeds to 418 of FIG. 4B.

[0051] 4B, path 408 proceeds to operation 420 where analysis begins to run. Path 416 proceeds to operation 422 where it is determined if the signal continues to decrease. Adjustments to charge compensation are made in operation 424. Monitoring is performed with a charge compensation slit in the curved ESA in operation 426. The total energy distribution is measured in operation 428.

[0052] 4B, path 418 proceeds to act 430 where the signal is constant but positively biased. Charge compensation is adjusted in act 432. Monitoring is performed with a charge compensation slit in the curved ESA in act 426. The total energy distribution is measured in step 428.

[0053] 4B, from operation 428, in operation 436, the low energy Charge compensation (CC) jaw / Si intensity is determined. In operation 438, the charge compensation for the low energy CC slit signal is adjusted to determine if it resembles a conductive sample. If no, operation 440 returns to operation 424. If yes, operation 442 proceeds to operation 444 where a stable Si intensity is determined. Then in operation 446, it is determined if the low energy CC slit signal resembles a conductive sample. If so, the flow chart proceeds to operation 420 where the analysis begins to run.

[0054] FIG. 5 illustrates the secondary ion beam path through the upper spectrometer and the curved electrostatic analyzer (ESA) according to one embodiment of the present invention.

[0055] Referring to FIG. 5, a portion of the system 100 of FIG. 1 is shown in more detail for a specific embodiment. The beam 110 in the slit region 120 between the ESA 118 and the ESA 116 is split into an inner trace 110A and an outer trace 110B. The inner trace 110A represents a conductive sample (e.g., surface potential=0V). The outer trace 110B represents an identical secondary ion distribution on the sample with a +50V surface potential. The function of the secondary ion blanker 500 included in the system 100 is to deflect ions to a total ion current sensor 502.

[0056] Referring again to Figure 5, the effect of varying the specimen bias from 0V to +50V for the same secondary ion energy distribution is shown. A positive specimen bias (or positive charging of the surface) effectively shifts the beam path towards the high energy sensor of the energy slit of the curved ESA, increasing the measured current at the high energy slit jaw (see outer trace for +50V specimen bias). At the same time, the low energy slit jaw effectively measures no current (see inner trace for 0V bias).

[0057] In one embodiment, the high energy slit sensor signal can be used to monitor the effect of a charge neutral system (for positive secondary ions): for negative secondary ions or electrons, a positive surface potential leads to a shift in the energy distribution towards the low energy slit sensor, and in the extreme can completely suppress secondary ion emission from the sample surface (negatively charged particles are attracted to a positive sample potential).

[0058] FIG. 6 illustrates the secondary ion beam path for positive ions through the upper analyzer and curved electrostatic analyzer (ESA) sections according to one embodiment of the present invention.

[0059] 6, a portion of the system 100 of FIG. 1 for a specific embodiment is shown in more detail with the sample position 103 shown. The trajectory trace shows the surface charging towards a negative surface potential (e.g., -20V). That is, the positive secondary ions appear to shift towards lower secondary ion energies. The secondary ions are cut off at the low energy slit sensor.

[0060] In one embodiment, when the sample surface accumulates a negative potential, the positive secondary ions are noticeably shifted toward lower secondary ion energies. This shift occurs when the overall sample potential changes from a positive potential to a less positive potential. This shift occurs due to one or more of the following factors: (a) an intentional sample bias used to eliminate low energy secondary ions, (b) when a constant positive surface potential is induced on a semi-insulating sample and the sample is bombarded with high energy electrons that create a net negative surface charge, and / or (c) when the overall sample bias is set to a more negative potential for a conductive sample to eliminate low energy ions from the measurement.

[0061] FIG. 7 shows an energy distribution scan towards high energy using a curved ESA 116 as feedback followed by low and high energy current sensors to vary the mean passing energy of the electrostatic analyzer, according to one embodiment of the present invention.

[0062] 7, a portion of the system 100 of FIG. 1 is shown in more detail for a particular embodiment, with the sample position 103 shown. The technique involves a curved ESA scan of only the ESA 116 (outer ESA Vo -10V, inner Vi +10V), while the ESA 118 is at a nominal voltage. Since the ESA 118 is still tuned to the nominal pass energy, the system does not send secondary ions to the mass analyzer.

[0063] Figures 8A, 8B, 8C and 8D include a schematic diagram 800 for measuring secondary ion energy distribution using the electrostatic bending ESA 116 and high and low energy slit sensors described with respect to Figure 7 according to one embodiment of the present invention. In one embodiment, the same or similar experimental setup can be used to monitor the effect of a charge compensation system as described with respect to Figures 4A and 4B. This implementation can be done in conjunction with additional features to control or adjust the surface potential of the sample as described in the above technique for adjusting the surface potential.

[0064] Referring to FIG. 8A, the energy distribution scan is performed at the charge compensation (CC) slit 120 after the curved ESA 116. In an exemplary embodiment, the sample is silicon or SiGe and well grounded. This setting is also used for the charge compensation reference. The energy adjustment must be achieved through the e-beam current / energy that returns the ion energy to the slit detector. In operation 802, the charge compensation is turned off. In operation 804, the curved ESA 116 is at nominal voltage. In operation 806, wafer auto-z is performed and checked OK. In the corresponding control module 850, the vision system / stage operation 852 is used to perform the operation 806. In operation 808, the silicon polariry set is loaded with the standard settings. In the corresponding control module 850, the upper spectro (or lower spectro) operation 854 is used to perform the operation 808. In operation 810, the primary beam energy / raster size / rotation adjustment is performed. In the corresponding control module 850, a primary column operation 856 is used to perform operation 810. In operation 812, synchronization with the beam is performed. In the corresponding control module 850, an upper analysis operation 858 is used to perform operation 812. In operations 814 and 816, the primary beam is blanked and then set on, respectively. In the corresponding control module 850, an upper analysis operation 860 and a primary current operation 862 are used to perform operations 814 and 816, respectively. In operation 818, a charge compensation slit width is set (e.g., 3.5 mm for a 50 eV energy path). In the corresponding control module 850, a smart stage controller operation 864 is used to perform operation 818. In operation 820, charge compensation (CC) is determined by measuring the slit current. In the corresponding control module 850, a smart stage controller operation 866 and an upper analysis charge compensation slit current operation 868 are used to perform operation 820. Flow from operation 820 continues in FIG. 8B.

[0065] 8B, from operation 820, a scan block high energy operation 822 is performed which marks a smart energy scan operation 824 in the ESA 116, followed by operations 824A-824E as shown in FIG. 8B. In operation 826, the charge compensation program ends operation 822 by turning off the beam blank setting. The bend ESA 116 is then set to nominal in operation 828. The flow from operation 828 continues in FIG. 8C.

[0066] 8C from operation 828, a reverse bend ESA 116 scan is performed. Next a scan block low energy operation 832 is performed which marks the start of an energy scan operation 834 on the ESA 116 and proceeds to operations 834A-834E shown in FIG. 8C. The charge compensation program ends operation 832 with operation 836 which turns off the secondary beam blank setting. The bend ESA 116 is then set to nominal in operation 838.

[0067] 8D, however, if further compensation is needed, a further determination is performed in operation 840. For example, in operation 840A, the charge compensation (CC) slit is moved at constant width for a target voltage, if needed. It should also be appreciated that in one embodiment, the charge compensation slit can be used to eliminate low energy secondary ions. It should also be appreciated that a voltage offset can be applied to allow passage of minimum path energy to ESA 116 and ESA 118. In operation 840B, the primary beam is stopped (off position).

[0068] 9 illustrates an energy distribution scan including a curved ESA scan at the same voltage ESA 116 and ESA 118 according to one embodiment of the present invention. With reference to FIG. 9, a portion of the system 100 of FIG. 1 is shown in more detail for a particular embodiment. The approach involves setting the outer portions of the ESAs 116 and 118 to Vo-10V. The inner portions of the ESAs 116 and 118 are set to Vi+10V.

[0069] That is, embodiments include techniques for controlling the surface potential of the sample. In one embodiment, the potential of the sample surface can be controlled using one or more of the following: (1) adjusting the bias voltage of the sample substrate (described in more detail with reference to FIG. 10); (2) steering the electron beam at the surface and varying the current delivered to the sample surface (described in more detail with reference to FIG. 11); (3) steering the electron beam at the surface and varying the electron impact energy such that the secondary electron factor is either greater than 1 (driving the sample potential more positive) or less than 1 (driving the sample potential more negative); (4) a combination of (2) and (3) that allows the net charge flux delivered by the electron beam to be either variable in polarity and intensity; (5) generating charge carriers in the sample, (6) directing a variable intensity of photons to the sample surface so that its conductivity changes (described in more detail with reference to FIG. 12); (7) directing a variable intensity of photons to the sample surface so that photoelectrons are emitted from the sample, driving the sample potential more positive; (8) directing a variable intensity of photons leaving the sample surface into a material with a high secondary electron coefficient, flooding the sample surface with low energy electrons, i.e., driving the sample potential more negative (described in more detail below with reference to FIGS. 13A and 13B); and / or (8) applying a positive or negative potential to an electron emitting material to control the electron flux and energy impinging on the sample surface (7).

[0070] FIG. 10 illustrates a schematic of a positive potential on a sample due to surface charging, according to one embodiment of the present invention.

[0071] 10, a positive primary ion beam 1002 is directed toward a portion 1004 of a sample 1006. Secondary ions 1008 are generated and collected in a pull module 1010. The sample potential of the sample 1006 (and particularly the portion 1004 of the sample 1006) can be adjusted, for example, by adjusting the bias voltage of the sample substrate.

[0072] FIG. 11 illustrates a schematic of electron beam based charge neutralization and control according to one embodiment of the present invention.

[0073] 11, a positive primary ion beam 1102 is directed to a site 1104 of a sample 1106. Secondary ions 1108 are generated and collected in a pull module 1110. A beam of electrons 1112 is directed to the surface 1104. Meanwhile, the current delivered to the sample surface is changed.

[0074] FIG. 12 shows a schematic diagram of photo conductivity of a sample using a variable intensity photon source according to one embodiment of the present invention.

[0075] 12, a positive primary ion beam 1202 is directed to a site 1204 of a sample 1206. Secondary ions 1208 are generated and collected in a pull module 1210. Photons 1212 of variable intensity are directed to the surface 1204, generating charge carriers within the sample and changing its conductivity.

[0076] FIG 13A illustrates a schematic of charge neutralization by the use of an electron emitting material away from the sample, according to one embodiment of the present invention. Referring to FIG 13A, a region 1304A of a sample 1306A is positively charged. An electron emitter 1350A is included in the system. Low energy electrons 1352A are attracted by the positive surface potential of region 1304A of sample 1306A.

[0077] FIG. 13B illustrates a schematic of effective charge neutralization if the electron flux exceeds the primary ion induced positive surface charge according to one embodiment of the present invention. With reference to FIG. 13B, region 1304B of sample 1306B is charge neutral. An electron emitter 1350B is included in the system. The net surface potential is equal to the maximum electron energy of electrons 1352B. With reference collectively to FIGS. 13A and 13B, a variable intensity of photons is directed away from the sample surface into a material with a high secondary electron coefficient, flooding the sample surface with low energy electrons and driving the sample potential more negative.

[0078] In a third aspect, an embodiment of the invention relates to a method for determining wafer backside contact resistance using multiple capacitive height sensors.

[0079] Essentially, semiconductor wafer metrology tools typically use a charged particle (electron / ion) beam as a primary excitation source and / or to measure the properties of the charged particles emitted from the wafer. Wafer charging (electron / ionization) can cause errors in the measurement of the properties of the emitted particles or can deflect the primary charged particles to adjacent areas, causing damage to these areas. To prevent the wafer from becoming charged, it is common to contact the backside of the wafer with a conductive electrode. However, in some cases, a high resistance exists between the electrode and the wafer due to contamination of the electrode or the insulating film on the backside of the wafer. It may be desirable to measure the backside contact resistance to ensure the reliability of the application of the relevant primary ion or electron beam to the sample.

[0080] In one embodiment of the invention, a technique for measuring contact resistance by using multiple capacitive height sensors is described. To illustrate the concepts described herein, consider first the case where a single sensor is used to measure height to a well-grounded wafer. The sensor includes parallel plate electrodes that are within sensing distance of the wafer. The structure forms a parallel plate capacitor where one plate is the sensor and the other is the wafer. When an AC voltage is applied to the sensor, a current flows through the gap between the plates. The amount of current that flows through the gap is determined by the voltage, the area of ​​the plates, the material that separates the plates, and the distance between the plates.

[0081] The relevant equation describing the current is: ac =x * C * V, where i ac = AC current (amperes), C = capacitance (farads), V = voltage, and x is a constant that depends only on the AC frequency. Capacitance (C) is defined as: C=K * E0 * A / D, where C = capacitance (Farads), K = dielectric constant of the material between the plates (e.g., air = 1.0), E0 = dielectric constant of free space (constant), A = area of ​​the plates (square meters), and D = distance between the plates (meters). Thus, if the area of ​​the sensor is kept constant, the distance (D) converts the voltage (V) into a current (i ac ) For AC voltages, this is directly proportional to the impedance of the circuit.

[0082] Electronic control of the sensor can be implemented in several ways. For example, some capacitive sensors hold the current constant and vary the voltage. These are called constant current capacitive sensors. Other capacitive sensors hold the voltage constant and vary the current. These are constant voltage designs. Neither design is superior to the other.

[0083] The above discussion assumes that the wafer is well grounded to the measurement electronics and that the impedance measured is due to the gap between the sensor and the wafer. If the wafer is not well grounded, then what is measured is the sum of the impedance due to the gap from the sensor to the wafer and the impedance from the wafer to ground. Unfortunately, this results in a reported distance that is the sum of the errors from the wafer to sensor gap and the wafer impedance. To reduce the errors in the distance measurement, techniques are described that minimize the wafer to ground current using a second sensor or compensation electrode. The general idea is to supply the second electrode with an AC voltage that is an amplitude and / or phase shifted version of the drive signal applied to the main sensor electrode. When the net current of the two electrodes is zero, the value from the main electrode is an accurate measure of the gap distance.

[0084] Figure 14 illustrates generally some of the parameters associated with using a compensation electrode to determine gap distance. Referring to Figure 14, there is shown a compensation electrode 1402 coupled to a sensor signal generator 1404. A sensor 1406 is coupled to the sensor signal generator 1404. The configuration of Figure 14 illustrates the relationship of the compensation electrode 1402, the sensor signal generator 1404, and the sensor 1406 to a target 1408.

[0085] It should be appreciated that in one embodiment of the present invention, it is important to further determine the value of the signal driven to the compensation electrode. This value is a measure of the wafer impedance relative to ground. By determining said signal and calibrating it with a known reference impedance standard added between ground and the conductive wafer, the signal can be calibrated so that the unknown contact resistance can be determined.

[0086] In one embodiment of the invention, there are several options for performing the measurement of the compensating electrode signal. A first embodiment is an approach that involves driving the compensating electrode with a 180 degree shifted version of the main electrode signal. The amplitude is adjusted until the net current is zero (or the distance measured by the main electrode is minimal). The amplitude of the voltage on the compensating electrode can then be calibrated against the impedance. In a second embodiment, the distance shown by the main sensor is measured when the compensating electrode is driven by a phase shifted version of the main signal. The distance is plotted against a number of different phase angles and a curve fitting algorithm is used to determine the phase angle of the minimum distance. The resulting phase angle is then calibrated against the impedance. In a third embodiment, the compensating electrode to the wafer or the exposed area of ​​the compensating electrode is varied. The distance on the main electrode is measured to determine the minimum value, thus providing a value that can be calibrated against the impedance.

[0087] An embodiment of the invention may be provided as a computer program product or software that includes a machine-readable medium having instructions stored thereon that can be used to program a computer system (or other electronic device) to perform the processes of the invention. A machine-readable medium includes any mechanism for storing or transmitting information in a form readable by a machine (e.g., a computer). For example, a machine-readable (e.g., computer-readable) medium includes a machine (e.g., computer) readable storage medium (e.g., read-only memory (ROM), random access memory (RAM), magnetic disk storage media, optical storage media, flash memory devices, etc.), and a machine (computer) readable transmission medium (electronic, optical, acoustic, or other form of propagated signal (e.g., infrared signal, digital signal, etc.)).

[0088] FIG. 15 shows a schematic diagram of a machine in the exemplary form of a computer system 1500 including a set of instructions that can cause the machine to perform one or more of the methods described above. In a variant, the machine can be connected (networked) to machines in a local area network (LAN), an intranet, an extranet, or the Internet. The machine can operate in the capacity of a server or a client machine in a client-server network environment, or as a peer machine in a peer-to-peer (or distributed) network environment. The machine can be a personal computer (PC), a tablet PC, a set-top box (STB), a personal digital assistant (PDA), a cellular phone, a web appliance, a server, a network router, a switch or bridge, or any machine capable of executing a set of instructions (sequential or otherwise) that specify actions to be taken by the machine. Moreover, although only a single machine is shown, the term "machine" is intended to include any collection of machines (e.g., multiple computers) that individually or jointly execute a set of instructions (or multiple sets of instructions) to perform any one or more of the methodologies described herein. For example, in one embodiment, the machine is configured to execute one or more instructions for measuring a sample using secondary ion mass spectrometry (SIMS). In one embodiment, the computer system 1500 is suitable for use with a system such as the SIMS system shown and described in connection with FIG.

[0089] The exemplary computer system 1500 includes a processing unit 1502, a main memory 504 (e.g., read only memory (ROM), flash memory, dynamic random access memory (DRAM) such as synchronous DRAM (SDRAM) or Rambus DRAM (RDRAM), etc.), a static memory 1506 (e.g., flash memory, static random access memory (SRAM), etc.), and a secondary memory 1518 (e.g., a data storage device) in communication with each of the other devices via a bus 1530.

[0090] Processing unit 1502 represents one or more general-purpose processing units, such as a microprocessor, a central processing unit, or the like. More specifically, processing unit 1502 may be a complex instruction set computing (CISC) microprocessor, a reduced instruction set computing (RISC) microprocessor, a very long instruction word (VLIW) microprocessor, a processor implementing other instruction sets, or a processor implementing a combination of instruction sets. Processing unit 1502 may also be one or more special-purpose processing units, such as an application specific integrated circuit (ASIC), a field programmable gate array (FPGA), a digital signal processor (DSP), a network processor, or the like. Processing unit 1502 is configured to execute processing logic 1526 to perform the operations described herein.

[0091] The computer system 1500 may further include a network interface device 1508. The computer system 1500 may also include a video display unit 1510 (e.g., a liquid crystal display (LCD) or a cathode ray tube (CRT)), an alphanumeric input device 1512 (e.g., a keyboard), a cursor control device 1514 (e.g., a mouse), and a signal generating device 1516 (e.g., a speaker).

[0092] The secondary memory 1518 may include a machine-accessible storage medium (or more specifically, a computer-readable storage medium) 1531 having stored thereon one or more sets of instructions (e.g., software 1522) embodying any one or more of the methodologies or functions described herein. The software 1522 may also reside, completely or at least partially, within the main memory 1504 and / or within the processing unit 1502 during execution by the computer system 1500, with the main memory 1504 and processing unit 1502 also constituting machine-readable storage media. The software 1522 may further be transmitted or received via the network 1520 through the network interface unit 1508.

[0093] Although the machine-accessible storage medium 531 is shown in the exemplary embodiment as being a single medium, the term "machine-readable storage medium" may include a single medium or multiple media (e.g., a centralized or distributed database, and / or associated caches and servers) that store one or more sets of instructions. The term "machine-readable storage medium" may include any medium capable of storing or encoding a set of instructions for execution by the machine, causing the machine to perform any one or more methodologies of the present invention. Thus, the term "machine-readable storage medium" is intended to include, but is not limited to, solid-state memories, and optical and magnetic media.

[0094] Thus, a system and methodology for semiconductor metrology and surface analysis using secondary ion mass spectrometry (SIMS) has been described.

[0095] In one embodiment, a secondary ion mass spectrometry (SIMS) system includes a sample stage. A primary ion beam is directed to the sample stage. A drawing lens is directed to the sample stage. The drawing lens is configured to provide a low extraction field for secondary ions emitted from a sample on the sample stage. A magnetic sector spectrograph is coupled to the drawing lens along an optical path of the SIMS system. The magnetic sector spectrograph includes an electrostatic analyzer (ESA) coupled to a magnetic sector analyzer (MSA).

[0096] In one embodiment, the sample stage includes a Faraday cup.

[0097] In one embodiment, the SIMS system further includes a plurality of detectors spaced along a face of the magnetic sector analyzer.

[0098] In one embodiment, the plurality of detectors detect a corresponding plurality of different species from the beam of secondary ions emitted from the sample.

[0099] In one embodiment, the SIMS system further includes a first additional ESA coupled along an optical path of the SIMS system between a pull-in lens and an ESA of a magnetic sector analyzer, and a second additional ESA coupled along an optical path of the SIMS system between the first additional ESA and the ESA of the magnetic sector analyzer.

[0100] In one embodiment, the first additional ESA is configured to diverge the beam of secondary ions emitted from the sample, and the second additional ESA is configured to concentrate the beam of secondary ions received from the first additional ESA.

[0101] In one embodiment, the SIMS system further comprises one or more slits along the optical path of the SIMS system between the first additional ESA and the second additional ESA.

[0102] In one embodiment, the first additional ESA, the second additional ESA, and the one or more slits are included within a charge compensation system of the SIMS system.

[0103] In one embodiment, the first additional ESA and the second additional ESA direct the optical path of a SIMS system from above the sample stage to below the sample.

[0104] In one embodiment, the magnet of the MSA is positioned below the sample stage.

[0105] In one embodiment, the low entrainment field has an absolute value of up to about 10 Volts / mm.

[0106] In one embodiment, the SIMS system further includes a transfer robot coupled to the sample stage.

[0107] In one embodiment, the SIMS system further includes a receptacle coupled to the transfer robot, the receptacle including calibration standards.

[0108] In one embodiment, a method of measuring and controlling a surface potential of a specimen includes measuring the kinetic energy of charged particles emitted from a surface of the specimen. The method also includes determining a shift in the kinetic energy of the charged particles. The surface potential of the specimen surface is charged in response to the shift in kinetic energy of the charged particles.

[0109] In one embodiment, adjusting the surface potential of the surface of the sample includes adjusting a bias voltage of an electrode supporting the sample.

[0110] In one embodiment, altering a surface potential on a surface of the specimen comprises directing an electron beam to the surface of the specimen.

[0111] In one embodiment, directing an electron beam to the surface of the sample includes varying a current delivered to the surface of the sample.

[0112] In one embodiment, directing the electron beam at the surface of the specimen includes varying an impact energy of the electron beam at the surface of the specimen.

[0113] In one embodiment, varying the surface potential of the surface of the sample includes directing photons of variable intensity at the surface of the sample.

[0114] In one embodiment, directing photons of variable intensity at the sample surface includes generating charge carriers in the sample to change the conductivity of the sample.

[0115] In one embodiment, directing photons of variable intensity at the sample surface includes ejecting photoelectrons from the sample to drive the sample potential more positive.

[0116] In one embodiment, altering the surface potential of the surface of the sample includes directing photons of variable intensity away from the sample surface.

[0117] In one embodiment, the method further comprises performing a secondary ion mass spectrometry (SIMS) measurement of the surface of the sample after altering the surface potential of the surface of the sample.

[0118] In one embodiment, a method for determining a backside contact resistance of a wafer includes measuring a gap distance value on a surface of the wafer based on a comparison between a primary capacitive sensor electrode driven with a first drive signal and a compensation capacitive sensor electrode driven with a second drive signal that is amplitude or phase shifted compared to the first drive signal. A value of the second drive signal is measured. The value of the second drive signal is calibrated against a reference impedance standard to determine an impedance value of the wafer to ground. A contact resistance value on the surface of the wafer is determined based on the gap distance value and the impedance value of the wafer to ground.

[0119] In one embodiment, measuring the value of the first drive signal includes driving the compensation capacitive sensor with a second drive signal that is a 180 degree shifted version of the first drive signal and adjusting the amplitude of the second drive signal to obtain an amplitude value when the net current in the main capacitive sensor electrode and the compensation capacitive sensor electrode is zero, and calibrating the value of the second drive signal relative to the reference impedance standard includes calibrating the amplitude value relative to the reference impedance standard.

[0120] In one embodiment, measuring the value of the second drive signal includes driving the compensation capacitive sensor with a second drive signal that is a phase-shifted version of the first drive signal and adjusting a phase angle of the second drive signal to obtain a phase angle value at which a minimum gap distance is obtained, and calibrating the value of the second drive signal relative to the reference impedance standard includes calibrating the phase angle value relative to the reference impedance standard.

[0121] In one embodiment, measuring the value of the second drive signal includes obtaining a minimum gap distance value by varying the distance of the compensation capacitive sensor electrode from the surface of the wafer, and calibrating the value of the second drive signal relative to the reference impedance standard includes calibrating the minimum gap distance value relative to the reference impedance standard.

[0122] In one embodiment, measuring the gap distance value includes measuring the gap distance value when a net current through the primary capacitive sensor electrode and the compensation capacitive sensor electrode is zero.

[0123] In one embodiment, the method further includes contacting a conductive electrode to a surface of the wafer and directing a charged particle beam to a second surface of the wafer when a contact resistance value for the surface of the wafer is below a threshold value.

[0124] In one embodiment, directing the charged particle beam to the second surface of the wafer includes initiating a secondary ion mass spectrometry (SIMS) measurement of the second surface of the wafer.

Claims

1. 1. A secondary ion mass spectrometry (SIMS) system for measuring a parameter of a semiconductor wafer, comprising: a main measurement chamber with a movable wafer stage; a primary ion source and ion optics for generating and directing a primary ion beam to the wafer stage; drag optics including a drag lens directed towards the wafer stage and configured to provide a low drag field for secondary ions emitted from a wafer on the wafer stage; a magnetic sector analyzer coupled to the pulling lens along an optical path of the SIMS system, the magnetic sector analyzer comprising a magnet and a plurality of detectors arranged at a predetermined position in a focal plane and configured to detect secondary ions in parallel; A charge compensation system, and Equipped with an automatic calibration system, the pulling optics, the primary ion source and the magnetic sector analyzer are rigidly attached to each other; a magnet of the magnetic sector analyzer is mounted near the bottom below the main measurement chamber; a first additional bent ESA configured to diverge the beam of secondary ions emitted from the wafer and a second additional bent ESA configured to focus the beam of secondary ions received from the first additional ESA, the first additional bent ESA being spaced apart in an optical path between the lead-in optics and the magnetic sector analyzer; the two ESAs and the magnetic sector analyzer guide the optical path of the SIMS system from above the wafer stage to below the wafer stage; SIMS system.

2. 2. The SIMS system of claim 1, wherein the movable wafer stage is of the XYZ type.

3. 10. The SIMS system of claim 1, wherein the multiple detectors are configured to detect different species of secondary ions in parallel.

4. 10. The SIMS system of claim 1, further comprising wired slits and apertures positioned at multiple locations along the path of the secondary ions.

5. 5. The SIMS system of claim 4, wherein the wired slit and aperture are configured to shape a secondary ion beam formed by the secondary ions.

6. 5. The SIMS system of claim 4, wherein the wired slit and aperture are configured to monitor a secondary ion beam formed by the secondary ions.

7. 10. The SIMS system of claim 1, wherein the automated calibration system comprises a parking lot configured to store one or more reference samples.

8. 8. The SIMS system of claim 7, wherein at least one of the reference samples is a wafer having a layered film.

9. 10. The SIMS system of claim 8, wherein the layered film exhibits at least one of a known characteristic of a known composition or a known thickness.

10. 2. The SIMS system of claim 1, wherein the wafer stage comprises a Faraday cup.

11. 2. The SIMS system of claim 1, wherein the low entrainment field has an absolute value of up to about 10 Volts / mm.

12. 10. The SIMS system of claim 1, further comprising a transfer robot coupled to the wafer stage.

13. 13. The SIMS system of claim 12, further comprising a container coupled to the transfer robot, the container capable of housing a calibration or reference wafer or a wafer-like carrier capable of containing a calibration or reference sample for the automated calibration system.

14. 2. The SIMS system of claim 1, wherein the charge compensation system is configured to adjust a bias voltage of an electrode supporting the wafer.

15. 10. The SIMS system of claim 1, wherein the charge compensation system is configured to direct an electron beam toward a surface of a wafer.

16. 16. The SIMS system of claim 15, wherein directing the electron beam toward the surface of the wafer comprises varying a current supplied to the surface of the wafer.

17. 10. The SIMS system of claim 1, wherein the charge compensation system is configured to direct photons of varying intensity onto a wafer surface.

18. 2. The SIMS system of claim 1, wherein the charge compensation system is configured to direct photons of varying intensity onto a wafer surface to generate charge carriers in the wafer and change the electrical conductivity of the wafer.

19. 10. The SIMS system of claim 1, enclosed in an enclosure or chamber having a vacuum environment.

20. 10. The SIMS system of claim 1 further comprising a vision system.

21. and a control module for controlling the vision system and wafer stage movement.

21. The SIMS system of claim 20,

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