Semiconductor structure and method for forming a semiconductor structure - Patents.com

Abstract

Improve device performance of semiconductor structures. A method for forming a semiconductor structure includes the steps of: forming a material layer on a first region and a second region of a substrate; forming a mask layer on the material layer; forming a patterned layer on the mask layer, the patterned layer including a plurality of openings, the plurality of openings including a first opening and a second opening, the first opening being larger than the second opening; patterning the mask layer to form the patterned mask layer; and using the patterned mask layer to form a first channel hole 450-1 through the first opening and a second channel hole 450-2 through the second opening in the material layer. The aspect ratio of the first channel hole 450-1 is the same as or lower than the aspect ratio of the second channel hole 450-2.

Description

[Technical field]

[0001] FIELD OF THE DISCLOSURE The present disclosure relates to semiconductor structures and methods of forming semiconductor structures. [Background technology]

[0002] [CROSS REFERENCE TO RELATED APPLICATIONS] This application claims priority to Chinese Patent Application No. 201710134033.9, filed on March 7, 2017, the entire contents of which are incorporated herein by reference.

[0003] Semiconductor memories can be classified into volatile and non-volatile memories according to their operating characteristics. Volatile memories refer to memory devices that may lose data storage when no external power is applied. Volatile memories include, for example, static RAM (SRAM), dynamic RAM (DRAM), and synchronous DRAM (SDRAM). Non-volatile memories include, for example, read-only memory (ROM), electrically programmable ROM (EPROM), electrically erasable programmable ROM (EEPROM), flash memory, phase-change RAM (PRAM), magnetic RAM (MRAM), resistive RAM (RRAM), and ferroelectric RAM. Currently, flash memory has become an important type of non-volatile memory, including NOR flash memory and NAND flash memory.

[0004] As the demand for integration and storage continues to grow, 3D (three-dimensional) NAND memory has emerged. 3D NAND memory is a new type of product based on planar NAND memory. The main feature of 3D NAND memory is its three-dimensional structure, which is developed from the planar structure. This three-dimensional structure significantly reduces the layout area of ​​the chip and reduces the manufacturing cost. Summary of the Invention

[0005] Disclosed herein are embodiments of a 3D memory architecture and a method for fabricating the same.

[0006] According to an embodiment of the present disclosure, a method for forming a semiconductor structure is provided. In one embodiment, the method for forming a semiconductor structure includes the steps of forming a material layer on a first region and a second region of a substrate aligned in a direction in a plan view of the substrate, the first region being adjacent to the second region, forming a mask layer on the material layer, the mask layer covering the first region and the second region, and forming a patterned layer on the mask layer, the patterned layer covering the first region and the second region and including a plurality of openings corresponding to the first region, the plurality of openings being adjacent to a boundary between the first region and the second region. the first opening and a second opening spaced further from the boundary than the first opening, the size of the first opening being greater than the size of the second opening along a plane parallel to a top surface of the substrate; forming a patterned mask layer by patterning the mask layer using the patterning layer; and forming a first channel hole through the first opening and a second channel hole through the second opening in the material layer using the patterned mask layer, the aspect ratio of the first channel hole being the same as the aspect ratio of the second channel hole. Therefore, the first channel hole is more susceptible to under-etching caused by an etching load effect than the second channel hole. .

[0007] According to an embodiment of the present disclosure, a semiconductor structure is provided. In one example, the semiconductor structure includes a substrate including a first region and a second region adjacent to the first region aligned in one direction in a plan view of the substrate, a material layer above the first region and the second region, and a plurality of device openings in the material layer corresponding to the first region, a size of a first device opening closest to a boundary between the first region and the second region is larger than a size of a second device opening further away from the boundary than the first device opening, a bottom of the first device opening exposes the substrate, and an aspect ratio of the first device opening is the same as an aspect ratio of the second device opening. Therefore, the first device opening is more susceptible to under-etching caused by an etching load effect than the second device opening. . Effect of the Invention

[0008] The technical solutions provided by the present disclosure, including the disclosed methods and structures, have the following advantages over the prior art:

[0009] According to the technical solution, the dimension of the first opening can be larger than the dimension of the second opening, and the dimension of the first opening along the first direction is larger than the dimension of the second opening along the second direction. Also, the aspect ratio of the first channel hole is the same as or lower than the aspect ratio of the second channel hole. In one embodiment, the first opening is adjacent to the second region. That is, the first opening is located on the boundary of the first region. In semiconductor manufacturing, when a stack structure is etched to form a channel hole, the etching load effect (e.g., the dependence of the etching rate on the amount of material to be etched) that occurs on a part of the stack structure when forming the first opening is different from the etching load effect that occurs on a part of the stack structure when forming the second opening. Therefore, by using the technical solution provided by the present disclosure, technical problems such as the inability to expose the substrate due to an excessively small size of the channel hole (e.g., corresponding to the first opening) can be avoided or reduced. Also, the current characteristics of the semiconductor channel can be improved. In another aspect, technical problems such as an excessively short distance between the first opening and the second opening can be avoided or reduced. In semiconductor manufacturing, trenches are often formed to form word lines between adjacent semiconductor channels in a stack structure, and a conductor layer is deposited to fill the trench. The provided technical solution can avoid or reduce obstacles to subsequent filling of a conductor in the trench between the semiconductor channel formed from the first opening and the semiconductor channel formed from the second opening. Thus, the device performance of the formed semiconductor structure can be improved.

[0010] In some embodiments, the array of patterned openings includes an odd number of columns along the first direction. In some embodiments, the distance between adjacent patterned openings along the direction pointing from the second region to the first region can decrease, and the distance between the middle column and the two adjacent columns can be the same. In some embodiments, the array of patterned openings includes an even number of columns along the first direction. In some embodiments, the distance between adjacent patterned openings along the direction pointing from the second region to the first region decreases. In many semiconductor manufacturing processes, the filling of trenches to form wordlines is accomplished by filling a trench in the space between the semiconductor channel formed from the first opening and the semiconductor channel formed from the second opening with a conductor. The conductor is often flowable, so that it can fill other trenches along the direction pointing from the second region to the first region. Thus, the gradual decrease in the distance between adjacent patterned openings can more effectively fill the trench with the conductor due to its flowability. The resulting semiconductor structure can have improved device performance. [Brief description of the drawings]

[0011] The accompanying drawings, which are incorporated in and form a part of this specification, illustrate embodiments of the present disclosure and, together with the description, further serve to explain the principles of the disclosure and enable those skilled in the art to make and use the disclosure. [Figure 1] 1A-1D are diagrams illustrating a manufacturing process for a semiconductor structure. [Diagram 2] 1A-1D are diagrams illustrating a manufacturing process for a semiconductor structure. [Diagram 3] 1A-1D are diagrams illustrating a manufacturing process for a semiconductor structure. [Figure 4] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Diagram 5] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 6]1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 7] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 8] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 9] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 10] 1A-1D illustrate an exemplary manufacturing process for a semiconductor structure, according to some embodiments. [Figure 11] 1 is a flow chart illustrating an exemplary manufacturing process for forming a semiconductor structure, in accordance with some embodiments. [Figure 12] 4 is a flowchart illustrating an exemplary method for determining a size of a device opening in a material layer, according to some embodiments.

[0012] Embodiments of the present disclosure will now be described with reference to the accompanying drawings. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] While specific configurations and arrangements are discussed, it should be understood that this is done for illustrative purposes only. A person skilled in the art will recognize that other configurations and arrangements can be used without departing from the spirit and scope of the present disclosure. It will be apparent to those skilled in the art that the present disclosure can also be used in a variety of other applications.

[0014] It should be noted that references herein to "one embodiment," "an embodiment," "an exemplary embodiment," "some embodiments," and the like indicate that the embodiment being described may include a particular feature, structure, or characteristic, but that not all embodiments necessarily include that particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Moreover, when a particular feature, structure, or characteristic is described in connection with an embodiment, it would be within the knowledge of one of ordinary skill in the art to also describe such feature, structure, or characteristic in connection with other embodiments, whether or not they are explicitly described.

[0015] Typically, terms may be understood, at least in part, from their usage in context. For example, when the term "one or more" is used herein, it may be used to refer to any feature, structure, or characteristic in the singular sense, or it may be used to refer to a combination of such features, structures, or characteristics in the plural sense, depending at least in part on the context. Similarly, terms such as "a," "an," or "the" may be understood to refer to the singular use or the plural use, again depending at least in part on the context.

[0016] It should be readily understood that the meanings of "on," "above," and "over" in this disclosure should be interpreted in the broadest sense, such that "on" not only means "directly on" something, but also includes the meaning of "on" something with an intermediate feature or layer between them, and "above" or "over" not only means "on the side" or "above" something, but also can include the meaning of "on the side" or "above" something without any intermediate feature or layer between them (i.e., directly on top of something).

[0017] Additionally, spatially relative terms such as "beneath," "below," "lower," "above," "upper," and the like may be used herein for ease of description when describing the relationship of one element or feature illustrated in the figures to another element(s) or feature(s). The spatially relative terms are intended to encompass various orientations of the device during use or operation in addition to the orientation depicted in the figures. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may be similarly interpreted accordingly.

[0018] As used herein, the term "substrate" refers to a material onto which subsequent layers of material are applied. The substrate itself can be patterned. Materials applied on top of the substrate can be patterned or left unpatterned. The substrate can also comprise a variety of semiconductor materials, such as silicon, germanium, gallium arsenide, indium phosphide, etc. Alternatively, the substrate can be made from a non-conductive material, such as glass, plastic, or a sapphire wafer.

[0019] As used herein, the term "layer" refers to a portion of material that includes a region having a thickness. A layer may extend throughout an underlying or overlying structure, or its extent may be less than the extent of the underlying or overlying structure. A layer may also be a uniform or non-uniform region of a continuous structure whose thickness is less than the thickness of the continuous structure. For example, a layer may be disposed between the top and bottom surfaces of a continuous structure, or between any pair of horizontal surfaces at the top and bottom surfaces. A layer may extend horizontally, vertically, and / or along a tapered surface. A substrate may be a layer and may comprise one or more layers therein and / or have one or more layers on, above, and / or below it. A layer may include multiple layers. For example, an interconnect layer may include one or more conductor layers and contact layers (in which contacts, interconnect lines, and / or vias are formed) and one or more dielectric layers.

[0020] As used herein, the term "nominal" refers to a desired or target value, including a range of values ​​above and / or below the desired value, for a component or process operational characteristic or parameter established during the design phase of a product or process. The range of values ​​may be due to slight variations in the manufacturing process or manufacturing tolerances. As used herein, the term "about" refers to a value of a given quantity that may vary based on the particular technology node associated with the semiconductor device. Based on the particular technology node, the term "about" may refer to a value of a given quantity that varies within 10-30% of the value, for example (e.g., ±10%, ±20%, or ±30% of the value).

[0021] As used herein, the term "3D memory device" refers to a semiconductor device in which strings of memory cell transistors (such as NAND strings, referred to herein as "memory strings") are arranged vertically on a horizontal substrate such that the memory strings extend in a vertical direction relative to the substrate. As used herein, the term "vertical" means nominally perpendicular to the outer surface of the substrate.

[0022] In this disclosure, the term "corresponding to" refers to two objects having at least overlapping horizontal projections in the same region. For example, a substrate may have a region, and a layer above and covering the substrate may be referred to as corresponding to the region, where the horizontal projections of the region and the layer overlap each other. As a result, a pattern (e.g., an opening) formed on or in the layer may also correspond to the region. In some embodiments, the horizontal projection of the layer covers the horizontal projection of the region. In some embodiments, the top surface of the substrate is nominally horizontal.

[0023] The problems of the prior art are as follows. Figures 1 to 3 show a part of a manufacturing process for a conventional semiconductor structure. Figure 1 shows a top view 100 of the semiconductor structure, and Figure 2 shows a cross-sectional view 200 along the A-A1 direction of the structure shown in Figure 1. As shown in Figures 1 and 2, the semiconductor structure includes a substrate 20, a stack structure 60 above the substrate 20, a hard mask layer 50 above the stack structure 60, and a patterned photoresist layer 10 on the stack structure 60. The semiconductor structure includes a first region (I) along an extension direction (e.g., y-axis) and two second regions (II) on both sides of the first region. A first direction (e.g., along the y-axis) is parallel to the top surface of the substrate 20 and points from the second region to the first region. A second direction (e.g., along the x-axis) is parallel to the top surface of the substrate 20 and perpendicular to the first direction.

[0024] The stack structure 60 may be a dielectric stack. For example, the stack structure 60 may include a plurality of silicon oxide layers 30 and a plurality of silicon nitride layers 40 that are alternately arranged. The silicon nitride layer 40 is formed between two adjacent silicon oxide layers 30. The hard mask layer 50 includes a dielectric material, such as silicon nitride, and covers the first region I and the second region II. A patterned photoresist layer 10 is disposed on the hard mask layer 50, and includes a plurality of openings that expose portions of the hard mask layer 50 corresponding to the first region I. The plurality of openings are arranged in an array along the first direction and the second direction. As shown in FIG. 1 and FIG. 2, the opening adjacent to the second region II along the first direction is the first opening 11, and the other openings are the second openings 12.

[0025] The dimensions of the first openings 11 are the same as the dimensions of the second openings 12 along the first and second directions, respectively. Specifically, the shapes of the first openings 11 and the second openings 12 are each circular along the xy plane. The openings in adjacent rows are staggered along the first direction, and the distance (S) between adjacent openings is the same. With reference to FIG. 1, S1=S2=S3=S4. The patterned photoresist layer 10 is then used as an etching mask to pattern the hard mask layer 50, thereby forming openings (e.g., the first openings 11 and the second openings 12) in the hard mask layer 50. After the hard mask layer 50 is patterned, the patterned photoresist layer 10 is removed.

[0026] 3 shows a cross-sectional view of the semiconductor structure after patterning the hard mask layer 50 and etching the stack structure 60 using the patterned hard mask layer 50' as an etching mask. As shown in FIG. 3, the stack structure 60 is etched to form channel holes 45 in the stack structure 60. The channel holes 45-1 refer to the device openings at the boundaries of the first region I and are formed from the etching of the first openings 11, and the channel holes 45-2 refer to the other device openings and are formed from the etching of the second openings 12.

[0027] As shown in FIG. 3, in this manufacturing process, when the hard mask layer 50 is patterned, the etching rate of the patterned hard mask layer 50' away from the boundary of the first region I is higher than the etching rate of the patterned hard mask layer 50' close to the boundary of the first region I, so that the aspect ratio (e.g., the ratio of the depth of the opening to the width of the opening) of the mask opening formed from the first opening 11 is higher than the aspect ratio of the mask opening formed from the second opening 12. As a result, when the stack structure 60 is etched using the patterned hard mask layer 50', the etching load effect of the portion of the stack structure 60 corresponding to the first opening 11 is different from the etching load effect of the portion of the stack structure 60 corresponding to the second opening 12. Therefore, the etching rate of the portion of the stack structure 60 corresponding to the first opening 11 is lower than the etching rate of the portion of the stack structure 60 corresponding to the second opening 12, so that the depth and width of the channel hole 45-1 are smaller than the depth and width of the channel hole 45-2. Also, under-etching may occur in the channel hole 45-1, which may cause the channel hole 45-1 to be less able to expose the substrate 20. Current may not be able to flow from a semiconductor channel subsequently formed in the channel hole 45-1 to the substrate 20, which may impair the electrical performance of the semiconductor structure.

[0028] Then, the silicon nitride layer 40 between adjacent silicon oxide layers 30 is removed to form trenches for forming word lines in the stack structure 60, and the silicon nitride between the channel holes 45 of each trench is etched away. Then, the trenches are filled with tungsten to form the word lines. Specifically, the space between the channel holes 45-1 and 45-2 in the trench (e.g., region B in FIG. 1) is often filled with tungsten. Then, due to its flowability, the tungsten is directed toward the inner part of the first region I (e.g., along a direction substantially pointing from the second region II to the first region I) to fill the space in the other part of the trench. Because the distance between the openings of adjacent columns is the same, it may be difficult to fill the space between the channel holes 45-1 and 45-2 with metal along a direction substantially pointing from the second region II to the first region I.

[0029] The present disclosure provides a semiconductor structure and a method for forming the semiconductor structure. According to the method, device holes (e.g., holes formed in the semiconductor structure, including channel holes) in areas more susceptible to etching loading effects are formed using photoresist openings of different sizes (e.g., larger) to compensate for underetching caused by etching loading effects. The size of the photoresist openings in forming the device holes can be gradually changed (e.g., smaller) as the photoresist openings are located further away from the areas most susceptible to etching loading effects. In one example, the photoresist openings in areas most susceptible to etching loading effects have the largest dimensions, and the photoresist openings in areas least susceptible to etching loading effects have the smallest dimensions. The dimensions of the photoresist openings can be changed along a desired direction to correspond to the layout of the semiconductor structure, such that neither the overall layout of the semiconductor structure (e.g., the number of components and the relative positions between the components) nor the number of photoresist openings need to be changed after the dimensions are changed. Also, the dimensions of the photoresist openings can be adjusted along the direction of the conductor to change (e.g., reduce) the distance between two adjacent photoresist openings / device holes, and subsequently encourage the conductor to fill more effectively between the device holes. The dimensions of the photoresist openings to compensate for the etch loading effect and encourage more effective filling of the conductor can be determined from calculations based on the desired device hole dimensions. Thus, the characteristics of the device holes formed from these photoresist openings can be more desirable, and the electrical properties of the semiconductor structure can be improved.

[0030] For illustrative purposes, the embodiments of the present disclosure are directed to the formation of channel holes in three-dimensional memory devices. In various embodiments, the methods and structures provided by the present disclosure can be used to form other device holes in various other semiconductor devices / structures. Device holes, including channel holes, can be susceptible to etch loading effects during formation. Using the disclosed methods and structures, these device holes can be made less susceptible to etch loading effects and the semiconductor devices / structures can have improved electrical performance / characteristics. Figures 4-10 show a partially formed three-dimensional memory structure at different stages of a typical fabrication process, according to some embodiments. The figures of the present disclosure are for illustrative purposes only and are not intended to be drawn to scale or to represent the actual dimensions of the structure.

[0031] FIG. 4 illustrates a top view 400 of a substrate according to some embodiments, and FIG. 5 illustrates a cross-sectional view of the substrate 200 along the C-C' direction according to some embodiments. At the start of the manufacturing process, the substrate 200 can be provided. The substrate 200 can include a region for forming devices / structures and a region adjacent to the region for forming devices. The xy plane represents a plane (e.g., a horizontal plane) that is nominally parallel to the top surface of the substrate 200. For ease of explanation, the top surface of the substrate 200 can be divided into a region I and two regions II in FIG. 4. The region II can be located on one or more sides of the region I. For illustrative purposes in this disclosure, the region II is located on both sides of the region I along the y axis. In various other embodiments, the region II can further surround or partially surround the region I. The region II can include any suitable region having a change in aperture arrangement (e.g., aperture density) compared to the first region I. The direction pointing from region II to region I is referred to as a first direction (e.g., the y-axis) and the direction perpendicular to the first direction is referred to as a second direction (e.g., the x-axis). Substrate 200 can then provide a fabrication platform for forming other structures.

[0032] Substrate 200 may comprise any suitable material. For example, substrate 200 may comprise silicon, germanium, silicon germanium, silicon carbide, gallium arsenide, indium arsenide, indium gallium arsenide, glass, gallium nitride, and / or other suitable III-V compounds. Substrate 200 may further comprise silicon-on-insulator and / or germanium-on-insulator. Appropriate buried layers (e.g., functional layers and / or auxiliary layers) may also be formed on substrate 200. In some embodiments, substrate 200 comprises silicon.

[0033] Figure 6 illustrates a top view 600 of a structure with a hardmask layer formed on a substrate according to some embodiments, and Figure 7 illustrates a cross-sectional view 700 of the structure along the D-D' direction according to some embodiments. In some embodiments, the structure illustrated in Figures 6 and 7 comprises a material layer 600 formed on a substrate 200 and a hardmask layer 500 formed on the material layer 600. In some embodiments, the material layer 600 and the hardmask layer 500 overlie the substrate 200. In some embodiments, the material layer 600 comprises a dielectric stack.

[0034] In some embodiments, the dielectric stack 600 includes a plurality of alternating first and second material layers. A first material layer can be formed between two adjacent second material layers, or vice versa. The second material layer can include any material different from the first material layer. In some embodiments, the first material layer includes a sacrificial material layer 400, and the second material layer includes an insulating material layer 300. In some embodiments, the sacrificial material layer 400 and the underlying insulating material layer 300 each form a dielectric pair. In a subsequent manufacturing operation, the dielectric pairs can be etched in stages (e.g., pair by pair) to form a staircase structure. Each dielectric pair can be etched to a different length to form the staircase. A staircase can include a sacrificial layer and an insulating layer. For example, the length of the staircases can decrease along a vertical direction (e.g., perpendicular to the xy plane or along the z-axis) as they move away from the top surface of the substrate 200. In this disclosure, a staircase structure refers to a set of surfaces that includes at least two horizontal surfaces (e.g., along the xy plane) and at least two (e.g., first and second) vertical surfaces (e.g., along the z axis), such that each horizontal surface is adjacent to a first vertical surface extending upward from a first edge of the horizontal surfaces and to a second vertical surface extending downward from a second edge of the horizontal surfaces. A "step" or "staircase" refers to a vertical shift in height between adjacent surfaces of a set of surfaces.

[0035] In some embodiments, the sacrificial material comprises silicon nitride and the insulating material comprises silicon oxide. In some embodiments, the sacrificial material layer can be removed and replaced with a suitable conductive material, such as, for example, tungsten, aluminum, and / or copper, in a subsequent manufacturing operation. The conductive layers can then form the gate electrodes (e.g., word lines) of the memory device. In some embodiments, these conductive layers comprise tungsten. For illustrative purposes, only seven dielectric pairs are shown in the figures of this disclosure. In various embodiments, other numbers of dielectric pairs can be formed, such as, for example, 64 dielectric pairs. The number of dielectric pairs and the thickness of each material layer are determined based on various application requirements and should not be limited by the embodiments of this disclosure.

[0036] In some embodiments, the insulating material layer 300a at the bottom of the dielectric stack 600 and located on the top surface of the substrate 200 has a sufficient thickness (e.g., thicker than at least some of the insulating material layers). The reason for the insulating material layer 300a to have such a thickness is described below. In a subsequent operation, a channel hole can be formed in the substrate 200 through the dielectric stack 600, and a doped epitaxial layer can be formed at the bottom of the channel hole by a suitable epitaxial growth method, such as selective epitaxial growth (SEG). The channel hole can then be filled with insulating and semiconductor materials to form a semiconductor channel. To prevent the doped epitaxial layer from contacting the adjacent sacrificial material layer 400 and causing a short circuit between the semiconductor channel and the sacrificial material layer 400, in some embodiments, the insulating material layer 300a has a thickness thicker than at least some of the insulating material layers 300 in the dielectric stack 600. As a result, the top surface of the epitaxial layer can be lower than the adjacent sacrificial material layer 400 , so that no contact is formed between the substrate 200 and the sacrificial material layer 400 .

[0037] The hardmask layer 500 may comprise any suitable material that can be used as an etch mask in etching the dielectric stack structure 600. For example, the hardmask layer 500 may comprise carbon, silicon carbide, silicon nitride, and / or a composite stack layer of silicon nitride and silicon oxide. In some embodiments, the hardmask layer 500 comprises carbon.

[0038] In some embodiments, a photoresist layer may be formed on the hard mask layer 500. The photoresist layer may be patterned to form a patterned photoresist layer. The patterned photoresist layer may be used to define openings formed in the hard mask layer 500, which is used as an etch mask when etching the dielectric stack 600. Any suitable photolithography process may be used to pattern the photoresist layer.

[0039] FIG. 8 illustrates a top view 800 of a structure having a patterned photoresist layer above a substrate, and FIG. 9 illustrates a cross-sectional view 900 of the structure along the E-E1 direction, according to some embodiments. In some embodiments, the structure illustrated in FIGS. 8 and 9 includes a patterned photoresist layer 101 above a hard mask layer 500. The patterned photoresist layer 101 includes a plurality of openings in region I that expose portions of the hard mask layer 500. The plurality of openings includes a plurality of first openings and a plurality of second openings. The first openings 110 may refer to the openings adjacent to the second region II, and the second openings 120 may refer to the other openings. In some embodiments, the plurality of openings are arranged in an array in region I, with the first openings 110 formed on the borders of the array and the second openings 120 formed between the first openings on the two borders of the array. In some embodiments, the first openings 110 are arranged in two rows, each at one boundary between the first region I and the second region II, and the second openings 120 are arranged in a row between the two rows formed by the first openings 110. The dimension or length of the first opening 110 along the first direction (e.g., y-axis) is D1, the dimension of the width of the first opening 110 along the second direction (e.g., x-axis) is D2, the dimension or length of the second opening 120 along the first direction is D3, and the dimension or width of the second opening 120 along the second direction is D4. R1, R2, R3, R4, and R5 refer to the first through fifth rows, counting from the boundary of the first region. C1, C2, and C3 refer to the first through third columns, counting from the boundary of the array of openings. Region G (circled in FIG. 8) illustrates a number of spaces / distances between adjacent openings in the patterned photoresist layer 101. The first opening 110 can be in R1. The distance between two adjacent first openings 110 can be about L0. The distance between the first opening 110 and its closest adjacent second opening 120 in R2 can be about L1. The distance between the second opening 120 in R2 and its closest adjacent second opening 120 in R3 can be about L2.The distance between the second opening 120 in R3 and the closest adjacent second opening 120 in R4 may be approximately L3. The distance between the second opening 120 in R4 and the closest adjacent second opening 120 in R5 may be approximately L4. The distance between two openings refers to the shortest straight line distance between the boundaries of the openings. These distances (e.g., L1-L5) may be or may be determined to be the distance between two channel holes formed in a subsequent manufacturing operation. Nine rows of openings are shown for ease of illustration, with each row having three openings.

[0040] The dimensions of the openings in the patterned photoresist layer 101 can be transferred to the hardmask layer 500 by any suitable patterning process to determine the dimensions of the mask openings subsequently formed in the hardmask layer 500. The pattern transfer allows the subsequently formed patterned mask layer to have substantially the same pattern as the patterned photoresist layer 101. The subsequently formed patterned hardmask layer can be used as an etch mask in etching the dielectric stack 600, so that the first opening 110 and the second opening 120 can dictate or influence the etching of the dielectric stack 600. For ease of explanation, the openings formed in the hardmask layer 500 are referred to as mask openings. The mask openings formed by etching the first openings are referred to as first mask openings, and the mask openings formed by etching the second openings are referred to as second mask openings.

[0041] As described above, the channel hole formed from the first opening 110 is more susceptible to under-etching caused by the etching load effect. In some embodiments, the size of the first opening 110 is larger than the size of the second opening 120 to reduce or prevent under-etching of the channel hole formed from the first opening 110. In this disclosure, the term "size" may refer to the area of ​​an object and / or the dimensions of an object along a certain direction. For example, the area of ​​the first opening 110 may be about 2% to about 8% larger than the area of ​​the second opening 120. In some embodiments, the area of ​​the first opening 110 is about 5% larger than the area of ​​the second opening 120.

[0042] In some embodiments, the length D1 of the first opening 110 is greater than the width D2. In some embodiments, the width D2 of the first opening 110 is greater than the width D4 of the second opening 120. In some embodiments, the width D2 of the first opening 110 is greater than the length D3 of the second opening 120. The reasons for such dimensioning are described below.

[0043] Since the channel holes formed from the first openings 110 are most susceptible to under-etching caused by the etch load effect, increasing the size of the first mask openings can increase the amount of material etched through the first mask openings and expose the substrate 200 at the bottom of the channel holes formed from the etching of the first mask openings. In some embodiments, it is desirable to increase the area of ​​the first openings 110 as large as possible. Furthermore, in subsequent manufacturing operations, the sacrificial layer can be removed to form trenches between the insulating layers, and the conductive material can be delivered to the trenches, for example, from the boundary of the first region I to the inner portion of the first region I, so that the distance between the openings of adjacent rows gradually decreases along the y axis, and the conductive material can more easily fill the trenches due to the flowability of the conductive material. In the present disclosure, the inner portion of the first region I refers to a region that is spaced apart from the boundary between the first region I and other regions. For example, the inner portion can include the geometric center of the opening of the region I. For example, the conductor material can begin filling the trench at the space between R1 and R2. Flow can cause the conductor material to fill the trench toward R5. A gradual decrease in the distance between adjacent rows of openings substantially along the y-axis can facilitate the delivery of the conductor into the spaces between those openings.

[0044] However, the distance L0 between two adjacent first openings 110 in the same row (e.g., R1) and the distance between the first opening 110 and the adjacent second opening 120 may not be too short so that the conductive material can fill the spaces between the openings more completely and uniformly. Thus, in one embodiment, the length D1 of the first opening 110 is larger than the width D2 of the first opening 110, the width D2 of the first opening is larger than the width D4 of the second opening 120, the width D2 of the first opening 110 is equal to or larger than the length D3 of the second opening 120, and the distance between adjacent openings along the y-axis may be L1≧L2≧L3≧L4, etc. In some embodiments, the width D2 of the first opening 110 is larger than the length D3 of the second opening 120, such that L1>L2>L3>L4. In some embodiments, the difference in the distance between adjacent openings along the y-axis may be about 2 nm to about 3 nm. For example, L1 can be about 2 nm longer than L2. In some embodiments, the difference between width D2 of first opening 110 and width D4 of second opening 120 can be about 1 nm to about 2 nm. In some embodiments, the difference between width D2 of first opening 110 and width D4 of second opening 120 can be about 1 nm to about 2 nm.

[0045] Furthermore, in order to improve the uniformity of the etching and ensure the electrical performance of the semiconductor channel formed thereafter, the difference between the length D1 and the width D2 and the difference between the length D3 and the width D4 are not made too large so that the cross-sectional shape of the channel hole formed thereafter from the first mask opening and the second mask opening can be sufficiently close to a circle. In some embodiments, the difference between the length D1 and the width D2 can be about 2 nm to about 3 nm. In some embodiments, the length D3 and the width D4 can be substantially the same.

[0046] In various embodiments, the difference in distance between the openings in adjacent rows may be the same or different. For example, the difference between distance L1 and distance L2 may be the same or different from the difference between distance L2 and distance L3. In some embodiments, the difference in distance may vary in a predetermined pattern along the y-axis. In some embodiments, the difference in distance may be the same along the y-axis. The particular value of the difference in distance may depend on the application and design and should not be limited by the embodiments of the present disclosure.

[0047] In some embodiments, the size of the openings along the same row can be varied to better compensate for the etching loading effect. In some embodiments, region I may be adjacent to two or more other regions (e.g., second region II), and the openings on the boundary may be susceptible to the etching loading effect. In some embodiments, the size of the openings along each boundary can be larger than the size of the other openings that are not on the boundary. For ease of explanation, the openings on the boundary can be referred to as boundary openings, including the first opening. In some embodiments, two openings at opposite ends of the same row or column (e.g., the first and last openings adjacent to the boundary between the first region I and another region) can be boundary openings, and the size of these openings can be larger than the size of the openings between them. The reason for such an arrangement is that the etching loading effect is most severe at the boundary of the array. In one example, at least one of the length D1 and width D2 of the boundary opening 110-1 is larger than at least one of the length D1 and width D2 of the other first opening 110 between the boundary opening 110-1 and another boundary opening 110 at the other end of R1. In another example, at least one of the length D3 and width D4 of the boundary opening 120-1 is greater than at least one of the length D3 and width D4 of another second opening 120 between the boundary opening 120-1 and another boundary opening 120 at the other end of R2. Such an arrangement can be applied to one or more of the other columns of the array. The size difference between adjacent boundary openings along the y-axis can be the same or can vary. For example, the difference between the length D1 and the length D3 can be the same or different from the difference between the length D2 and the length D3. The specific value of the size difference can depend on the application and design, and should not be limited by the embodiments of the present disclosure.

[0048] In some embodiments, the size of the openings in the same row can be gradually changed (e.g., decreased) toward the center / midpoint of the row. In some embodiments, the size of the openings in the same column can be gradually changed (e.g., decreased) toward the center / midpoint of the column. For example, the length D1 of the first opening 110-1 can be longer than the length D1 of the first opening 110-2, and the length D1 of the first opening 110-3 can be longer than the length D1 of the first opening 110-2. In another example, the width D4 of the second opening 120-1 can be larger than the width D4 of the second opening 120-4, and the width D4 of the second opening 120-6 can be larger than the width D4 of the second opening 120-5. In some embodiments, the size of the openings (e.g., any openings in the array) can be changed (e.g., decreased) along a direction toward the center (e.g., geometric center) of the array. For example, the area of ​​second opening 120-2 can be larger than the area of ​​second opening 120-4, which can be larger than the area of ​​second opening 120-7. In some embodiments, the opening substantially in the center of the array (e.g., second opening 120-7) has a smallest dimension compared to other openings in the array. In various embodiments, the variation in size along a particular direction can be uniform or non-uniform. In some embodiments, the size of the openings in each row is the same.

[0049] In some embodiments, the openings in adjacent rows are staggered, as shown in FIG. 8. The term "staggered" refers to substantially aligning the openings in the (N+1)th row with the space between the openings in the Nth or (N+2)th rows, e.g., along the x-axis, where N is an integer. For example, the second opening 120-1 can be located between the first opening 110-1 and the first opening 110-2 along the x-axis. In some embodiments, the distance between an opening (e.g., the first opening 110 or the second opening 120) and two adjacent openings in the same adjacent rows can be the same. For example, the distance between the second opening 120-1 and the first opening 110-1 and the distance between the second opening 120-1 and the first opening 110-2 can be the same, e.g., both of them are L1.

[0050] In some embodiments, the number of columns can be odd or even. When the array includes an odd number of columns, the distance between the openings in two adjacent columns decreases toward the middle column, and the distance between the second opening 120 in the middle column and the adjacent second opening 120 in the adjacent column can be the same. When the array includes an even number of columns, the distance between the openings in two adjacent columns decreases toward a center line (e.g., a line across the geometric center of the array), and the distance between the two second openings 120 in the two columns closest to the center line can be the same.

[0051] The shape of the apertures of the array can be any suitable shape, such as circular, elliptical, rectangular, irregular, etc. The specific selection of these shapes can be determined by various factors, such as ease of manufacture and electrical performance of the subsequently formed device. In some embodiments, the shape of the first aperture 110 can be elliptical, where D1 is the major axis and D2 is the minor axis. In some embodiments, the shape of the second aperture 120 can be substantially circular, where D3 and D4 are the diameters of the second aperture 120, and D3 is substantially the same as D4.

[0052] Furthermore, the patterned photoresist layer 101 can be used as an etch mask in patterning the hardmask layer 500. Any suitable etch (e.g., wet and / or dry depending on the material of the hardmask layer 500) can be used to remove the portions of the hardmask layer 500 exposed by the openings. A portion of the dielectric stack 600 can be exposed by the patterned hardmask layer, and the pattern of the patterned photoresist layer 101 can be transferred to the patterned hardmask layer. A first mask opening can be formed from the first opening 110, and a second mask opening can be formed from the second opening 120. Furthermore, the patterned photoresist layer 101 can be removed.

[0053] FIG. 10 illustrates a cross-sectional view 1000 of the structure according to some embodiments shown in FIGS. 8 and 9 after patterning the hard mask layer 500 and forming the channel hole 450 in the dielectric stack 600. The structure illustrated in FIG. 10 includes the patterned hard mask layer 500' after being used as an etch mask in removing the portions of the dielectric stack 600 defined by the pattern of the patterned hard mask layer 500' and corresponding to the channel hole 450. The dielectric stack 600' refers to the dielectric stack 600 after removing these portions. The channel hole formed from the first mask opening is represented by element 450-1, and the channel hole formed from the second mask opening is represented by element 450-2. The etching of the dielectric stack 600 to form the channel hole 450 can be accomplished by any suitable etch, depending on the material of the dielectric stack 600. For example, the insulating material layer 300 and the sacrificial material layer 400 can be etched using the same or different etching processes, and such etching process(es) can include dry etching and / or wet etching. In some embodiments, a wet etching process including phosphoric acid can be used to form the channel hole 450.

[0054] As shown in FIG. 10, the substrate 200 is exposed at the bottom of the channel hole 450-1. In some embodiments, the channel hole 450-1 may have a tapered cross section along the yz plane (e.g., a dimension at the top that is larger than a dimension at the bottom along the y axis). In some embodiments, along the y axis, the dimension D1' of the bottom channel hole 450-1 is substantially the same as the dimension D2' of the channel hole 450-2. In some embodiments, along the z axis, the depth H1' of the channel hole 450-1 is substantially the same as the depth H2' of the channel hole 450-2. In some embodiments, the aspect ratio of the channel hole 450-1 (substantially equal to H1' / D1') is substantially the same as or lower than the aspect ratio of the channel hole 450-2 (equal to H2' / D2').

[0055] Further, a doped epitaxial layer can be formed at the bottom of each channel hole 450, for example by a SEG process, and suitable insulating and semiconducting materials can be deposited to fill the channel holes 450 to form a semiconducting channel. In some embodiments, the channel hole can include a dielectric core, a semiconducting channel layer, a memory layer, and a dielectric layer disposed from the center to the boundary of the channel hole. Each layer can include any suitable material. In some embodiments, the dielectric layer can include silicon oxide, the memory layer can include silicon nitride, the semiconducting channel layer can include silicon, and the dielectric core can include silicon oxide.

[0056] Further, the dielectric stack 600' can be repeatedly etched to form a staircase structure, and the sacrificial layer 400 can be removed by a suitable isotropic etching process. The staircase structure can include multiple insulating layers and multiple sacrificial layers stacked alternately along the z-axis. Furthermore, a suitable conductor material (e.g., tungsten, copper, and / or aluminum) can be deposited in the trenches formed between adjacent insulating layers to form the gate electrodes (e.g., word lines) of the subsequently formed semiconductor structures. In some embodiments, the conductor material includes tungsten. In some embodiments, the staircase structure can be formed before the formation of the channel hole. The order of forming the staircase structure and the channel hole should be determined by various manufacturing requirements and should not be limited by the embodiments of the present disclosure.

[0057] By applying the disclosed methods and structures, the channel holes can have sufficient length, width, and / or depth for depositing conductive material; the substrate can be exposed at the bottom of the channel holes so that the semiconductor channel can make sufficient electrical contact with the substrate; under-etching caused by etch loading effects can be reduced or prevented; and the distance between adjacent channel holes can be configured as disclosed so that the trenches can be filled with conductive material more easily and uniformly during the formation of the gate electrodes; the gate electrodes can be formed with greater uniformity; and the electrical performance of the semiconductor device can be improved.

[0058]

[0023] Embodiments of the present disclosure further provide methods of forming a semiconductor structure. Figure 11 illustrates an exemplary manufacturing process flow for forming a semiconductor structure, according to some embodiments. The operations illustrated in Figure 11 are for illustrative purposes only. In various embodiments, the operations in Figure 11 may be performed in a different order or may be modified.

[0059] In operation 1101, a material layer is formed on a substrate and a hard mask layer is formed on the material layer. The substrate, material layer, and hard mask layer may each comprise any suitable material. In some embodiments, the substrate comprises silicon and the hard mask layer comprises carbon. In some embodiments, the material layer comprises alternating sacrificial and insulating material layers. In some embodiments, the sacrificial material layer comprises silicon nitride and the insulating material layer comprises silicon oxide. For a detailed description of the substrate, material layer, and hard mask, reference may be made to the description of FIGS. 6 and 7.

[0060] In operation 1102, a patterned photoresist layer is formed on the hard mask layer to pattern the hard mask layer and use the patterned photoresist layer as an etch mask to form a patterned mask layer. The pattern of the patterned photoresist layer is transferred to the patterned hard mask layer. The pattern of the patterned photoresist layer includes openings that form an array, the array including larger sized openings on its borders and smaller sized openings in its interior. In some embodiments, the patterned photoresist layer can be used directly as an etch mask in etching an underlying material layer. For example, the patterned photoresist can have a sufficient thickness and can be processed (e.g., baked) to have sufficient rigidity to survive a subsequent etch process.

[0061] In some embodiments, a patterned photoresist layer can be used to form a device hole, e.g., a channel hole, in a first region. The first region can be adjacent to one or more other regions, e.g., a second region. The material layer can then be etched to form the channel hole while forming the device hole, thereby exposing the substrate. To reduce or prevent underetching caused by etch loading effects, the size of the openings on the border of the array can be larger than the size of the openings inside the array. The openings on the border of the array (e.g., first openings) refer to openings adjacent to other regions and / or at the end of a row / column, and the openings inside the array (e.g., second openings) refer to other openings in the array. In some embodiments, the size of the openings gradually decreases toward the center (e.g., geometric center) of the array. In some embodiments, the dimension of the first opening along a first direction pointing from the border to the center is larger than the dimension of the first opening along a second direction perpendicular to the first direction. In some embodiments, the dimension of the first opening along the first direction is larger than the dimension of the second opening along the first direction. In some embodiments, the distance between adjacent openings in adjacent columns decreases along the first direction toward the center of the array, which allows the material layer to be filled more easily and uniformly with the conductive material. The pattern of the patterned photoresist layer can be transferred to the patterned mask layer by a suitable etching process on the hard mask layer. A first mask opening can be formed based on the first opening, and a second mask opening can be formed based on the second opening. After forming the patterned mask layer, the patterned photoresist layer can be removed. For a detailed description of the openings, reference can be made to the description of FIG. 8 and FIG. 9.

[0062] In operation 1103, a channel hole is formed in the material layer using the patterned mask layer as an etch mask. A suitable etch process may be performed to remove portions of the material layer exposed by the patterned mask layer. As a result, the channel hole may be formed and the substrate may be exposed at the bottom of the channel hole. A dimension of the first channel hole formed based on the first mask opening may be larger than a dimension of the second channel hole formed based on the second mask opening. In some embodiments, the substrate may be exposed at the bottom of the first channel hole. In some embodiments, the depth of the first channel hole may be substantially the same as the depth of the second channel hole. For details regarding the structure and formation of the channel hole, reference may be made to the description of FIG. 10.

[0063] Further, a doped epitaxial layer can be formed at the bottom of each channel hole, for example by a SEG process, and suitable insulating and semiconducting materials can be deposited to fill the channel holes and form a semiconducting channel. In some embodiments, the channel hole can include a dielectric core, a semiconducting channel layer, a memory layer, and a dielectric layer disposed from the center to the boundary of the channel hole. Each layer can include any suitable material. In some embodiments, the dielectric layer can include silicon oxide, the memory layer can include silicon nitride, the semiconducting channel layer can include silicon, and the dielectric core can include silicon oxide.

[0064] Additionally, the material layers can be repeatedly etched to form a staircase structure, and the sacrificial layers can be removed by a suitable isotropic etching process. The staircase structure can include multiple insulating layers and multiple sacrificial layers, stacked alternately along a direction perpendicular to the substrate. Additionally, a suitable conductive material (e.g., tungsten) can be deposited in trenches formed between adjacent insulating layers to form gate electrodes (e.g., word lines) of a subsequently formed semiconductor structure.

[0065] Embodiments of the present disclosure further provide a method for determining the size (e.g., dimensions) of a device opening in a material layer above a substrate using an etching process. Figure 12 shows an exemplary flow chart of the method, according to some embodiments. The operations shown in Figure 12 are for illustrative purposes only. In various embodiments, the operations in Figure 12 may be performed in a different order or may be modified.

[0066] In operation 1201, an actual etch profile is determined. In some embodiments, the actual etch profile includes a prior art etch profile or an etch profile that needs improvement. For example, the actual etch profile may include an etch profile of a device opening that may be under-etched due to etch loading effects or may have an undesirably high aspect ratio.

[0067] In operation 1202, an estimated etch profile is determined. In some embodiments, the estimated etch profile includes a desired etch profile required for the manufacturing process. For example, the estimated etch profile may include an etch profile for a device opening having sufficient width and depth, such as exposing the substrate at the bottom of a channel hole, and having a desired low aspect ratio, as an example.

[0068] In operation 1203, etching conditions are determined. In some embodiments, the etching conditions include various factors that may affect the etching process. For example, these factors may include the etchant, the type of etch, the chamber conditions, the location of the material being etched, the material being etched, etc.

[0069] At operation 1204, an etch mask is determined based on the actual etch profile, the estimated etch profile, and / or the etch conditions. In some embodiments, the etch mask may be patterned by a patterned photoresist layer (e.g., an initial etch mask). The pattern of the patterned photoresist layer may be transferred to the etch mask. The pattern of the patterned photoresist may be determined based on the estimated etch profile, the etch conditions, and / or the estimated etch profile.

[0070] Using this method, differences between the actual and estimated etch profiles can be identified and an etch mask can be designed to compensate for those differences so that the device openings formed have desired characteristics, such as depth, width, aspect ratio, etc.

[0071] In some embodiments, a method for forming a plurality of device openings includes forming a material layer on a first region and a second region of a substrate, the first region being adjacent to the second region, forming a mask layer on the material layer, the mask layer covering the first region and the second region, and forming a patterned layer on the mask layer, the patterned layer covering the first region and the second region and including a plurality of openings corresponding to the first region. The plurality of openings includes a first opening adjacent to a boundary between the first region and the second region and a second opening further away from the boundary than the first opening. The size of the first opening is larger than the size of the second opening along a plane parallel to the top surface of the substrate. The method further includes forming a patterned mask layer by patterning the mask layer using the patterned layer, and patterning the material layer using the patterned mask layer.

[0072] In some embodiments, a semiconductor structure includes a substrate including a first region and a second region adjacent to the first region, a material layer over the first region and the second region, and a plurality of device openings in the material layer corresponding to the first region. A size of the first device opening closest to the boundary between the first region and the second region is larger than a size of a second device opening further away from the boundary than the first device opening. A bottom of the first device opening exposes the substrate.

[0073] In some embodiments, a method for determining a size of a device opening in a manufacturing process includes determining an actual etch profile of the device opening, determining an estimated etch profile of the device opening, determining etch conditions for the device opening, and determining an etch mask based on one or more of the actual etch profile, the estimated etch profile, and the etch conditions. The etch mask includes a mask opening that forms a profile of the device opening that is not under-etched.

[0074] The foregoing description of specific embodiments makes the general nature of the present disclosure fully clear, so that those skilled in the art can easily modify such specific embodiments and / or adapt them to various applications by applying knowledge within their scope without undue experimentation and without departing from the general concept of the present disclosure. Such adaptations and modifications are therefore intended to be within the meaning and range of equivalents of the disclosed embodiments, based on the teaching and guidance provided herein. It should be understood that the phraseology or terminology used herein is for the purpose of description and not of limitation, and thus should be interpreted by those skilled in the art in light of the teaching and guidance.

[0075] The embodiments of the present disclosure have been described above using functional building blocks that show implementation forms of specific functions and their relationships. The boundaries of these functional building blocks are arbitrarily defined in this specification for the convenience of description. Alternative boundaries can be defined as long as the specific functions and their relationships are appropriately performed.

[0076] The Summary and Abstract sections describe one or more exemplary embodiments of the present disclosure, but not all, contemplated by the inventor(s), and are therefore not intended to be limiting of the scope of the disclosure and the appended claims in any way.

[0077] The scope and breadth of the present disclosure should not be limited by any of the above-described exemplary embodiments, but should be defined only in accordance with the following claims and their equivalents.

Claims

1. 1. A method of forming a semiconductor structure, comprising: forming a material layer on a first region and a second region of the substrate aligned in one direction in a plan view of the substrate, the first region being adjacent to the second region; forming a mask layer on the material layer, the mask layer covering the first region and the second region; forming a patterned layer on the mask layer, the patterned layer covering the first region and the second region and including a plurality of openings corresponding to the first region, the plurality of openings including a first opening adjacent to a boundary between the first region and the second region and a second opening spaced further from the boundary than the first opening, the size of the first opening being larger than the size of the second opening along a plane parallel to a top surface of the substrate; using the patterning layer to pattern the mask layer to form a patterned mask layer; forming a first channel hole through the first opening and a second channel hole through the second opening in the material layer using the patterned mask layer; Including, an aspect ratio of the first channel hole is the same as an aspect ratio of the second channel hole; the first channel hole is more susceptible to under-etching caused by an etching load effect than the second channel hole; method.

2. a length of the first opening along a first direction that is parallel to the top surface of the substrate and points from the second region to the first region is greater than a width of the first opening along a second direction that is parallel to the top surface of the substrate and perpendicular to the first direction; A conductive material is delivered to the plurality of openings along the first direction. The method of claim 1.

3. The length of the second opening along the first direction is the same as the width of the second opening along the second direction. The method of claim 2.

4. a length of the first opening along the first direction is 2 to 3 nm greater than a width of the first opening along the second direction; a width of the first opening along the second direction is 1 to 2 nm larger than a width of the second opening along the second direction; a width of the first opening along the second direction is 1 to 2 nm larger than a length of the second opening along the first direction; The method according to claim 2 or 3.

5. the plurality of openings further includes one or more first openings adjacent to the boundary and one or more second openings spaced further from the boundary than the first openings, and a size of the first openings is larger than a size of the second openings; 5. The method according to any one of claims 2 to 4.

6. the first openings and the second openings form an array including a plurality of rows along the first direction and a plurality of columns along the second direction, the first openings being in a first row adjacent the boundary and the second openings being in at least a second row adjacent the first row that is further spaced from the boundary along the first direction; The method according to claim 5.

7. the first openings are the same size and elliptical in shape; the second openings in the second row are the same size and circular in shape; The method according to claim 6.

8. the second region and the first region further include one or more boundaries therebetween, the size of the openings decreasing along a direction from each boundary toward an interior portion of the array. The method according to claim 6 or 7.

9. the second openings are further disposed in at least a third row adjacent to the second row, the third row being further spaced from the boundary along the first direction; a distance between the first opening in the first row and an adjacent second opening in the second row is longer than a distance between the second opening in the second row and an adjacent second opening in the third row, and a distance between two openings in two adjacent rows decreases along the first direction; The method according to claim 6 or 7.

10. the second region has two boundaries with the first region, and the first region is disposed between the two boundaries along the first direction; responsive to the array including an odd number of columns, a distance between adjacent openings in two adjacent columns decreases toward a middle column of the array, and a distance between an opening in the middle column and an adjacent opening in one of the columns adjacent to the middle column, and a distance between an opening in the middle column and an adjacent opening in the other of the columns adjacent to the middle column are the same; responsive to the array including an even number of columns, a distance between adjacent openings in two adjacent columns decreases toward a centerline of the array, and a distance between two second openings in the two columns closest to the centerline is the same.

10. The method of claim 9.

11. forming the first channel hole through the first opening and the second channel hole through the second opening includes etching the material layer using the patterned mask layer as an etch mask to expose the substrate.

11. The method according to any one of claims 1 to 10.

12. The first channel hole has a tapered cross-sectional shape.

12. The method according to any one of claims 1 to 11.

13. A substrate including a first region aligned in one direction in a plan view of the substrate and a second region adjacent to the first region; a layer of material overlying the first region and the second region; a plurality of device openings in the material layer corresponding to the first regions; Equipped with a size of a first device opening closest to a boundary between the first region and the second region is larger than a size of a second device opening further away from the boundary than the first device opening; a bottom of the first device opening exposing the substrate; an aspect ratio of the first device opening is the same as an aspect ratio of the second device opening; the first device opening is more susceptible to under-etching caused by an etching load effect than the second device opening; Semiconductor structure.

14. a length of the first device opening along a first direction that is parallel to an upper surface of the substrate and points from the second region to the first region is longer than a width of the first device opening along a second direction that is parallel to an upper surface of the substrate and perpendicular to the first direction; 14. The semiconductor structure of claim 13.

15. a length of the second device opening along the first direction is the same as a width of the second device opening along the second direction; 15. The semiconductor structure of claim 14.

16. the plurality of device openings further comprising one or more first device openings adjacent the boundary and one or more second device openings spaced further from the boundary than the first device openings; the one or more first device openings and the one or more second device openings form an array including a plurality of rows along the first direction and a plurality of columns along the second direction, the first device openings being in a first row adjacent the boundary and the second device openings being in at least a second row adjacent the first row that is further spaced from the boundary along the first direction; 16. The semiconductor structure of claim 14 or 15.

17. the first device openings are the same size and elliptical in shape; the second device openings in the second row are the same size and circular in shape; 20. The semiconductor structure of claim 16.

18. the second device openings are further disposed in at least a third row adjacent the second row, the third row being further spaced from the boundary along the first direction; a distance between a first device opening in the first row and an adjacent second device opening in the second row is greater than a distance between a second device opening in the second row and an adjacent second device opening in the third row; 18. The semiconductor structure of claim 16 or 17.

19. the second region has two boundaries with the first region, and the first region is disposed between the two boundaries along the first direction; responsive to the array including an odd number of columns, a distance between adjacent device openings in two adjacent columns decreases towards a middle column of the array, and a distance between a device opening in the middle column and adjacent device openings in an adjacent column is the same; responsive to the array including an even number of columns, a distance between the adjacent device openings in two adjacent columns decreases towards a centerline of the array, and a distance between two second device openings in the two columns closest to the centerline is the same.

20. The semiconductor structure of claim 18.

20. the first device opening has a tapered cross-sectional shape; 20. The semiconductor structure of any one of claims 13 to 19.

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