Aqueous surfactant composition and solid soap

Abstract

A surfactant composition is suggested, comprising one or more alpha-sulfofatty acid di-salts (A) of general formula (I) R1CH(SO3M1)COOM2 (I), wherein the R1 group represents a linear or branched alkyl or alkenyl group having 6 to 18 C atoms, and the M1 and M2 groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups, and one or more polysaccharides (B) selected from the group consisting of dextrins and derivatives thereof, starch and derivatives thereof, cellulose and derivatives thereof, preferably one or more dextrins (B) of general formula (II), wherein n is an integer from 3 to 200. TIFF2022532073000011.tif26129

Description

[Technical field]

[0001] The present invention relates to surfactant compositions, particularly aqueous and solid surfactant compositions, containing alpha-sulfofatty acid di-salts and polysaccharides. [Background technology]

[0002] Anionic surfactants are some of the most widespread surface active compounds, and apart from being used in detergents and cleaners, are used for various purposes in the field of cosmetics.The usual anionic surfactants used especially in cosmetics are the salts of alkyl ether sulfates (alkyl polyether sulfates, fatty alcohol polyglycol ether sulfates, in short also ether sulfates).They are characterized by strong foaming ability, high detergency, low sensitivity to water hardness and grease, and are widely used for the manufacture of cosmetic products such as hair shampoos, foams or shower baths, as well as hand dishwashing cleaners.

[0003] For many current applications, apart from good surface active effect, further requirements are imposed on anionic surfactants.High degree of dermatological compatibility is required, especially in cosmetics.Furthermore, sufficient solubility in water, good compatibility with as many active ingredients and auxiliaries as possible used in cosmetics, good foaming ability and good thickening are generally desired.Especially for hair care compositions, dermatological compatibility and ease of use are the objectives of new development.

[0004] Furthermore, there is a need for anionic surfactants that can be produced at least in part from biological sources, and in particular from renewable raw materials. Furthermore, there is also a need for surfactants that are free of alkoxylated groups and therefore do not require the use of ethylene oxide, in particular, for their production.

[0005] US Patent Application Publication No. 2012 / 208898 discloses aqueous personal care compositions comprising salts of sulfonated fatty acid esters and / or salts of sulfonated fatty acids in combination with alkyl betaines as hair care formulations. Although salts of sulfonated fatty acid esters are well tolerated surfactants, their good solubility in water makes it difficult to form solid surfactant compositions with these surfactants.

[0006] The present invention aims to provide a composition for skin cleansing, which provides a pleasant rinsing sensation, smoothness, softness and low dryness of the skin after rinsing.Especially for hair treatment, another aim was to achieve a conditioning effect without stickiness and long drying time.Improved drying of hair care surfactant compositions for time-saving use (fast drying effect of hair) is an important aim.

[0007] Anionic surfactants are the surfactants most often used in solid compositions. Previously, solid cleaning agents, which were traditional soap bars, contained alkali metal salts of fatty acids (soap in the classical sense), but in recent years, cleaning agents are also made from surfactants. Soap-like solids consisting entirely of synthetic cleaning compositions are called synthetic detergent bars, and their combination with surfactants of fatty acid salts was sold as combibars. Traditional soaps, which are salts of fatty acids, hydrolyze in aqueous solution, resulting in an alkaline environment with a pH of 10.2-10.4, which causes damage to the normal protection of the epithelium, the skin which usually has an acidic pH of 5.5-6.5. The destruction of the natural skin barrier by the persistent use of these surfactant soaps leads to poor skin resistance to itching, dehydration and cracking of the epithelium. To overcome these disadvantages, "refatting agents", such as oils and fats selected from natural oils, mineral oils, petrolatum, stearic acid or lanolin, or "moisturizing creams", such as glycerin, urea and sorbitol, are incorporated into the soap bars, which often result in a sticky feel and prolong the drying time. Moreover, the addition of these additives is accompanied by the drawback of poor foaming and cleaning properties of the soap. Moreover, traditional soaps have the property of forming undesirable scum or curd due to their incompatibility with hard water and the low solubility of their calcium salts.

[0008] The same is partly true for the common fillers of soaps, which are used to reduce costs and improve the handling of the bars by providing sufficient hardness. Previously, sodium silicate, talc or borax were used as the main ingredients. However, these fillers are poorly tolerated, especially by sensitive skin. In WO 92 / 07931, common anionic surfactants and polysaccharide solid surfactants are disclosed. Talc, clay, calcium carbonate and dextrin are listed as possible filler materials.

[0009] The preferred surfactants used in detergent bars have been alkali metal salts of acyl isethionates, fatty alcohol sulfates, or alkanesulfonates, and are still the predominant surfactants used in surfactant-containing bars.

[0010] US Pat. No. 2,894,912 discloses a solid detergent comprising an alkali metal salt of an isethionate ester; mixed fatty acids; so-called foam enhancing detergent salts such as alkylarylsulfonates; water; higher fatty acid soaps; and higher fatty acids.

[0011] US Patent No. 4,100,097 relates to a solid synthetic detergent consisting of coconut fatty acid esters of sodium isethionate and / or sodium lauryl sulfoacetate, paraffin, powdered starch, dextrin, coconut fatty acid and water.

[0012] The required amount of synthetic detergents in the solid surfactants frequently results in mashability and insufficient firmness, stickiness, difficulty in fabrication, cracking of the solids and insufficient foaming. Furthermore, the use of these surfactants is currently being reduced for environmental reasons, and alternatives made from raw materials from renewable resources, free of ethylene oxide and sulfate impurities, are becoming more and more preferred.

[0013] The patent family related to International Patent Applications WO 03 / 063819, WO 06 / 062665 and WO 07 / 133582 discloses the combination of a C6-C22 fatty acid salt, a polyhydric alcohol, and a mixture of anionic surfactants including alpha-sulfonated alkyl esters and sulfonated fatty acids. These compositions show improved processability and improved skin feel after use. However, the high amount of at least 40% by weight of fatty acid soap still brings about the disadvantages of the traditional soap of fatty acid salt, and the main objective was to avoid the high amount of traditional soap.

[0014] From the above, it is clear that there is still a need for a solid surfactant composition consisting of a well-accepted cleaning agent having a pH close to that of human skin and in any case exhibiting good handling, foaming and cleaning properties. The solid surfactant composition should be easily processable. It was therefore another object to provide an anionic surfactant in the form of a composition containing a solid surfactant having good foaming properties, surfactant mildness, good compatibility with water hardness and increased firmness.

[0015] Hair treatments comprising the surfactant composition should also be possible in the form of solid surfactant compositions, which should exhibit advanced foaming behavior, conditioning properties and improved drying times during rinsing, as compared to commercial surfactant compositions, such as solid surfactants comprising sodium cocoyl isethionate. Summary of the Invention [Problem to be solved by the invention]

[0016] The present invention aimed to provide improved surfactant compositions containing well-tolerated anionic surfactants, either liquid aqueous surfactant compositions or solid compositions. [Means for solving the problem]

[0017] The object of the present invention is to provide a surfactant composition comprising one or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO3M 1 )COOM 2 (I) [In the formula, R 1 The group is a linear or branched alkyl or alkenyl group having 6 to 16 carbon atoms, M 1 and M 2 The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups; Contains one or more polysaccharides (B) selected from the group consisting of dextrin and its derivatives, starch and its derivatives, and cellulose and its derivatives; However, the following The surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 2 CH(SO3M 7 )COOR 3 (V) [In the formula, R 2 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 3 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 3 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 7 The problem has been solved by a surfactant composition, wherein the proviso that when the compound (A) contains a radical selected from the group consisting of Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine radicals, the compound (A) must be present in an amount of more than 50% by weight relative to the sum of the compounds (A) and (E). [Brief description of the drawings]

[0018] [Figure 1] FIG. 2 is a schematic diagram showing the configuration of equipment for a mash resistance performance test method. [Diagram 2] FIG. 1 is a diagram showing the results of a panel test. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0019] Surfactant compositions are characterized by good foaming ability, especially initial foaming behavior. Initial foaming behavior plays a very important role as so-called rinseable products, which should be understood to mean products that come into contact with skin or hair during cleaning or care, but then can be rinsed off again (such as shower gels, shower preparations, shampoos, liquid soaps, etc.). In this field, a foam volume as large as possible is desired.

[0020] The surfactant composition further has hydrolytic stability in both acidic and alkaline pH ranges, avoids ethylene oxide or propylene oxide components for ecological reasons, and further avoids constituent molecules, including surfactants containing sulfate groups, in order to improve skin and mucous membrane tolerance.

[0021] The surfactant composition also has storage stability at room temperature (23° C.) for at least 8 weeks without any visible change of any kind (e.g., cloudiness, phase separation, discoloration, etc.) and without any change in viscosity or chemical composition.

[0022] The surfactant composition of the invention is an aqueous surfactant composition, which may be a liquid aqueous surfactant composition or a solid composition.

[0023] The amount of water in the solid composition is 1% to 20% by weight, preferably 5 to 15% by weight, more preferably 7 to 15% by weight. The amount of water in the liquid aqueous composition is more than 30% by weight, preferably more than 40% by weight, more preferably more than 50% by weight, based on the aqueous composition.

[0024] The aim is to reduce the amount of anionic surfactants in personal care and household products due to poor skin tolerance. The surfactant composition of the present invention should contain less than 40% by weight, preferably less than 25% by weight, most preferably less than 15% by weight of anionic surfactants other than compounds (A) and (C) based on the weight of the composition. Very often, the other anionic surfactants are traditional soaps which are alkaline salts of fatty acids. In the case of solid compositions, the fatty acids are mainly saturated C12-C22 fatty acids, especially stearic acid. Compositions containing salts of long chain fatty acids, especially stearic acid, are difficult to handle due to incompatibility with water hardness, poor foaming properties, scum or curd forming properties and poor skin tolerance resulting from alkaline pH values. Therefore, the composition of the present invention should contain less than 30% by weight, preferably less than 20% by weight, most preferably less than 10% by weight of fatty acid salts of stearic acid based on the weight of the composition.

[0025] Preferably, the present invention provides a surfactant composition comprising: one or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO3M 1 )COOM 2 (I) [In the formula, R 1 The group is a linear or branched alkyl or alkenyl group having 6 to 16 carbon atoms, M 1 and M 2 The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups; one or more dextrins (B) of general formula (II)

[0026] [ka] wherein the average degree of polymerization n is an integer from 3 to 200, preferably from 5 to 100, most preferably from 10 to 40; However, the following The aqueous surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 3 CH(SO3M 5 )COOR 4 (V) [In the formula, R 3 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 4 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 4 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 5 groups are selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups], said compound (A) must be present in an amount of more than 50% by weight, preferably more than 60% by weight, more preferably more than 70% by weight and most preferably more than 95% by weight, relative to the sum of said compounds (A) and (E).

[0027] A solid composition comprising an anionic surfactant with good foaming properties should be suitable for treating hair and have improved properties in anti-mash performance and faster drying performance to be preferred as a hair care composition for shampoo. Surprisingly, a solid composition comprising an alpha-sulfo fatty acid di-salt and one or more polysaccharides selected from the group consisting of dextrin and its derivatives, starch and its derivatives, and cellulose and its derivatives shows improved anti-mash performance and has fast drying performance after hair treatment.

[0028] A "composition suitable for treating hair" according to the present invention may be any composition suitable for cleaning hair, may be a composition for conditioning hair (conditioner), may be a mask for treating hair. The solid surfactant composition may be a combination solid or a solid synthetic detergent.

[0029] Preferably, the present invention provides a solid surfactant composition comprising: one or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO3M 1 )COOM 2 (I) [In the formula, R 1 The group is a linear or branched alkyl or alkenyl group having 6 to 16 carbon atoms, M 1 and M 2 The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups; Contains one or more polysaccharides (B) selected from the group consisting of dextrin and its derivatives, starch and its derivatives, and cellulose and its derivatives; However, the following The surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 2 CH(SO3M7 )COOR 3 (V) [In the formula, R 2 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 3 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 3 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 7 wherein the groups are selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups, with the proviso that said compound (A) must be present in an amount of more than 50% by weight, preferably more than 60% by weight, more preferably more than 70% by weight and most preferably more than 95% by weight, relative to the sum of said compounds (A) and (E).

[0030] More preferably, the present invention provides a solid surfactant composition comprising: one or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO3M 1 )COOM 2 (I) [In the formula, R 1 The group is a linear or branched alkyl or alkenyl group having 6 to 16 carbon atoms, M 1 and M 2 The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups; one or more dextrins (B) of general formula (II)

[0031] [ka] wherein the average degree of polymerization n is an integer from 3 to 200, preferably from 5 to 100, most preferably from 10 to 40; However, the following The surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 3 CH(SO3M 5 )COOR 4 (V) [In the formula, R 3 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 4 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 4 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 5 groups are selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups], said compound (A) must be present in an amount of more than 50% by weight, preferably more than 60% by weight, more preferably more than 70% by weight and most preferably more than 95% by weight relative to the sum of said compounds (A) and (E).

[0032] The amount of water in the solid composition is 1% to 20% by weight, preferably 5 to 15% by weight, more preferably 7 to 15% by weight, based on the weight of the composition. Preferably, the solid composition contains less than 30% by weight, preferably less than 20% by weight, most preferably less than 10% by weight of fatty acid salts of stearic acid based on the weight of the composition.

[0033] Compound (A) Within the context of the present invention, compounds (A) are referred to as alpha-sulfofatty acid di-salts and are essential to the aqueous and solid surfactant compositions according to the present invention. They have the aforementioned formula (I) R 1 CH(SO3M 1 )COOM 2 (I) [In the formula, R 1 The group is a linear or branched alkyl or alkenyl group having 6 to 16 carbon atoms, M 1 and M 2The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups. Particularly preferred alkanolamines of the invention are monoethanolamine, diethanolamine, triethanolamine and monoisopropanolamine.

[0034] In the context of the present invention, the compound (A), designated as "alpha-sulfofatty acid di-salt", has the formula (I): 1 and M 2 The groups are independently selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups, thus including di-salts and / or mono-salts and / or protonated acids.

[0035] In one embodiment, R 1 The proviso applies that the fraction of compounds (A) in the surfactant composition in which the radical is an alkenyl group is less than or equal to 3% by weight relative to the total amount of compounds (A).

[0036] In a preferred embodiment, R in formula (I) 1 The group means a saturated, linear group having 10 to 16 carbon atoms, in which, for compound (A), R 1 The fraction of compounds (A) in which the radicals are decyl and / or dodecyl radicals is more than 70% by weight, preferably more than 80% by weight, more preferably more than 90% by weight, particularly preferably more than 95% by weight, based on the total amount of compounds (A).

[0037] Preferably, M in formula (I) 1 and M 2 The group is Na.

[0038] The liquid aqueous composition will usually contain more than 0.1-10% by weight of alpha-sulfo fatty acid di-salt (A) relative to the weight of the composition, preferably more than 1-8%, more preferably 3-6% by weight of alpha-sulfo fatty acid di-salt.

[0039] The solid composition usually comprises from 10 to 90% by weight of the alpha-sulfo fatty acid di-salt (A), preferably from 20 to 70%, more preferably from 30 to 50% by weight of the alpha-sulfo fatty acid di-salt, relative to the weight of the composition.

[0040] Compound (A) can be prepared by any method known to be suitable to the skilled artisan. A particularly preferred preparation method here is the sulfation of the corresponding carboxylic acid. Here, the corresponding carboxylic acid and in particular the corresponding fatty acid are reacted with gaseous sulfur trioxide, preferably in an amount such that the molar ratio of SO3 to fatty acid is in the range of 1.0:1 to 1.1:1. The crude product obtained in this way is an acidic sulfonation product, which is then partially or completely neutralized, preferably by completing the neutralization with aqueous NaOH. If desired, it is also possible to undertake a purification step and / or decolorization (to adjust the product to the desired light color).

[0041] In a particularly preferred embodiment, compound (A) is used in technical grade form. This means that the corresponding carboxylic acid, in particular natural fatty acid, is sulfonated with gaseous sulfur trioxide, resulting in a mixture of compounds (A), (C) and (D) after partial or complete neutralization of the resulting acidic sulfonation product. It is possible to control the ratio of compounds (A), (C) and (D) by corresponding adjustment of the reaction parameters (in particular the molar ratio of carboxylic acid and sulfur trioxide, and also the reaction temperature). Compounds (C) and (D) are described in the chapter entitled "Preferred embodiments".

[0042] Within the context of the present invention, technical grade mixtures of alpha-sulfo fatty acid di-salts having the following composition are preferred: provided that in this mixture the sum of components (A), (C) and (D) is 100% by weight. The content of (A) is in the range of 60 to 100% by weight, preferably in the range of 70 to 85% by weight, The content of (C) is in the range of 0 to 20% by weight, preferably in the range of 5 to 15% by weight, The content of (D) is in the range of 0 to 20% by weight, preferably in the range of 10 to 15% by weight.

[0043] Compound (B) The functionality of compound (B) in the aqueous surfactant composition is based on its conditioning and hair care benefits as a liquid and solid composition, and its propensity to bulk and form solid compositions.

[0044] The liquid aqueous composition will usually contain 0.1 to 10% by weight of polysaccharide, preferably 0.2 to 5%, more preferably 1 to 3% by weight of polysaccharide, based on the weight of the composition.

[0045] The solid composition usually contains 1-60% by weight of polysaccharide, preferably 5-50%, more preferably 15-40% by weight of polysaccharide, based on the weight of the composition.

[0046] For solid surfactant compositions, compound B is a filler whose function is to allow the use of the surfactant in solid form while reducing costs without compromising the foaming performance of the anionic surfactant, to toughen the composition, and to increase the wear rate, hardness and sensory feel of the composition.

[0047] Preferred fillers for the solid surfactant composition are polysaccharide powders such as dextrin and its derivatives, starch and its derivatives, cellulose and its derivatives.

[0048] Compound (B), which in the context of the present invention is called a polysaccharide, is selected from the group consisting of dextrin and its derivatives, starch and its derivatives, cellulose and its derivatives, at least one of which is essential for the surfactant composition according to the invention.

[0049] Starch and its derivatives Starch The binder / filler component may be unprocessed starch or a modified, powdered, hydrolyzed starch or derivative, and in the solid composition, it should be present in an amount ranging from about 5% to about 20% by weight, preferably from about 7% to about 12% by weight.

[0050] Starch derivatives used in food production and cosmetics, such as oxidized starch, phosphorylated starch, phosphate crosslinked starch, monoesterified phosphate crosslinked starch, acetylated phosphate crosslinked starch, acetylated starch, acetylated adipate crosslinked starch, hydroxypropyl starch, hydroxypropylated phosphate crosslinked starch, are likewise possible fillers and binders.

[0051] It is particularly preferred to use unsubstituted potato, wheat and / or corn starches which may be used in untreated or, preferably, digested, ie partially hydrolyzed, form.

[0052] Cellulose and its derivatives In the food industry and cosmetics, cellulose ethers are often used as thickening agents and, besides this function, they are used as fillers and binders as well.

[0053] Suitable cellulose derivatives are, for example, cellulose ethers. Cellulose ethers are prepared by substitution of hydrogen atoms of hydroxyl groups of cellulose with alkyl and / or arylalkyl groups, which can be further substituted with nonionic, anionic, cationic or nonionic groups. The alkyl groups are typically linear or branched C1-C8 alkyl groups. Preferred alkyl groups are C1-C4 alkyl groups, for example methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl or tert-butyl. The alkyl groups may be substituted with aromatic groups, for example phenyl groups, to form arylalkyl groups. One preferred arylalkyl group is benzyl. The alkyl or arylalkyl groups may be functionally substituted, for example with hydroxyl, carboxyl or carboxylato groups. When carboxylato groups are present, the corresponding counterions are present as well, for example alkali metal ions, for example sodium or potassium or ammonium ions. It is also possible to use mixed cellulose ethers, which contain several types of alkyl, arylalkyl or functionally substituted alkyl groups.

[0054] Preferred hydrophilic polymeric cellulose derivatives are methyl-, ethyl-, propyl-, carboxymethyl-, hydroxyethyl-, hydroxypropyl-, hydroxypropylmethyl-, ethylmethylcellulose-, methylhydroxyethyl-, methylhydroxybutyl-, ethylhydroxyethyl- and / or carboxymethylhydroxyethylcellulose. Among the carboxymethylcelluloses are sodium carboxymethylcellulose, crosslinked sodium carboxymethylcellulose or enzymatically hydrolyzed carboxymethylcellulose.

[0055] Dextrin and its derivatives Dextrins and their derivatives include dextrin, maltodextrin and cyclodextrin. In the context of the present invention, the most preferred compound (B) is dextrin. They have the above formula (II):

[0056] [ka] wherein the average degree of polymerization, n, is an integer from 3 to 200, preferably from 5 to 100, and most preferably from 10 to 40.

[0057] Dextrins are a group of low molecular weight carbohydrates accessible by hydrolysis starting from the α-(1→6) glycosidic bond of starch forming D-glucose units linked by α-(1→4) bonds.

[0058] Preferably, they have a dextrose equivalent of 1 to 30%, preferably 1 to 13%, with dextrose (glucose) having 100%. Dextrose equivalent (DE) is a measure of the amount of reducing sugar present in a sugar product, expressed as a percentage on a dry basis relative to dextrose. Dextrose equivalent gives a measure of the average degree of polymerization (DP) for starch sugars, which is inversely proportional to the molecular weight. Degree of polymerization (DP) is a measure of the degree of hydrolysis, with unhydrolyzed starch having a DE of 0, while glucose has a DE value of 100.

[0059] These polysaccharides are produced from starch using enzymes such as amylase or by drying and heating under acidic conditions (pyrolysis or roasting). Industrial production of dextrins is generally accomplished by acid hydrolysis of potato starch.

[0060] The finished dextrins are very fine powders of various colours, from pure white to brown. Depending on their molecular weight and colour, three main types of dextrins are distinguished: white dextrin, canary or yellow dextrin and British gum. British gum is the dextrin with the highest molecular weight and strong adhesive properties, with an average degree of polymerization of about 20, yellow dextrin has the lowest molecular weight and white dextrin has a molecular weight between the other types. They are often used in adhesives and coatings that come into contact with food products.

[0061] Although not the preferred dextrin, maltodextrins may also be included in the composition as polysaccharides and dextrin derivatives, which are composed exclusively of α-(1→4) linked glucose and have an average degree of polymerization of 10-20 and a dextrose equivalent of 3-20%, preferably 10-20%.

[0062] The cyclodextrin may be any of the known cyclodextrins, for example unsubstituted cyclodextrins containing 6 to 12 glucose monomers, especially alpha-, beta- and gamma-cyclodextrins, and / or derivatives thereof, and / or mixtures thereof. Alpha-, beta- and gamma-cyclodextrins contain 6, 7 and 8 glucose monomer units, respectively, arranged in a doughnut-shaped ring. Examples of cyclodextrin derivatives suitable for use in the present invention include methyl beta-cyclodextrin, hydroxy-ethyl beta-cyclodextrin and hydroxypropyl beta-cyclodextrin with different degrees of substitution. Water-soluble cyclodextrin derivatives are preferred cyclodextrin derivatives. Preferably, at least the majority of the cyclodextrin is alpha-, beta- and / or gamma-cyclodextrin, more preferably alpha- and beta-cyclodextrin. A particularly preferred cyclodextrin for use in the present invention is beta-cyclodextrin. It is also preferred to use mixtures of cyclodextrins.

[0063] In the present invention, the amount of dextrin contributes to improved drying and conditioning benefits of the aqueous surfactant composition, but does not impair the foaming performance of the anionic surfactant, and the processability of the solid surfactant composition.

[0064] The liquid aqueous composition usually contains 0.1-10% by weight of dextrin, preferably 0.2-5% by weight, more preferably 1-3% by weight of dextrin, based on the weight of the composition. When used for hair cleaning, it shows that it can improve the blow-drying speed of hair, and improve the viscosity build-up of the liquid aqueous composition depending on the dextrose equivalent.

[0065] The solid compositions typically contain 1-60% by weight of dextrin, preferably 5-50%, more preferably 15-40%, and most preferably 25 to 35% by weight of dextrin, based on the weight of the composition. The dextrin allows the solid compositions containing the alpha-sulfo fatty acid di-salt to be processed and allows the solid to be molded. By using these solid compositions in hair care compositions, good conditioning benefits are achieved while improving the blow-drying speed of the hair.

[0066] Further Additives The solid surfactant and liquid aqueous compositions may contain further additives, such as skin moisturising creams, e.g. sodium lactate, glycerin, pyrrolidone carboxylic acid; pH regulators (regulans), complexing agents; dyes; bleaching agents; fragrances; salts such as sodium chloride, sodium sulfate, sodium phosphate; antioxidants, antimicrobial agents and preservatives or stabilizers.

[0067] The surfactant composition preferably comprises a pH adjusting agent, most preferred being citric acid, added in an amount of 1-10 wt.%, preferably 1-6 wt.%, based on the weight of the composition. To achieve good skin tolerance, the pH of a 10 wt.% solution of the composition in water has a value of 4-7, preferably 4.5-6.0.

[0068] Preferred Embodiments In one embodiment, the surfactant composition according to the invention further comprises, besides the compounds (A) and (B), one or more compounds (C) of the general formula (III). R 4 COOM 3 (III)

[0069] In formula (III), R 4 The group is a linear or branched alkyl or alkenyl group having 7 to 19 carbon atoms, preferably R 4 is a saturated linear alkyl group having 11 to 15 carbon atoms, and with respect to compound (C), R 4 The proportion of the compound (C) having an undecyl or tridecyl group is more than 60% by weight based on the total amount of the compound (C), and M 3 The groups are selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups. Particularly preferred alkanolamines are monoethanolamine, diethanolamine, triethanolamine and monoisopropanolamine.

[0070] In one embodiment, the surfactant composition according to the invention further comprises, in addition to the compounds (A) and (B), one or more inorganic salts of sulfate (D) of general formula (IV): (M 4 )2SO4(IV) [In the formula, M 4 is selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups.

[0071] M of compound (A) 1 and M 2 Group, M of compound (C) 3 Group and M of compound (D) 4 The group may be an alkanolamine, with monoethanolamine, diethanolamine, triethanolamine and monoisopropanolamine being particularly preferred in this regard.

[0072] In a preferred embodiment, the surfactant composition according to the invention comprises compounds (A), (B), (C) and (D), wherein M of compound (A) 1 and M 2 It is particularly preferred if is selected from the H (hydrogen) group and the Na (sodium) group.

[0073] In one embodiment, the surfactant composition according to the present invention further comprises, in addition to the compounds (A) and (B), one or more compounds (F) of formula (VI): R 5 CH2-CO-CHR 6 (SO3M 6 ) (VI) [In the formula, R 5 and R 6 The groups each independently represent a linear or branched alkyl group having 6 to 18 carbon atoms; M 6 The groups are selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups. Particularly preferred alkanolamines are monoethanolamine, diethanolamine, triethanolamine and monoisopropanolamine.

[0074] Use of the composition A further subject of the invention is the use of the compositions described above as cosmetic and cleaning and purification products.

[0075] As for the cosmetic products including rinse-off and leave-on compositions for skin care, those in the form of hair shampoo, solid surfactant composition, shower gel, soap, synthetic detergent, paste detergent, solid detergent, lotion detergent, scrub preparation, foam bath, oil bath, shower bath, solid soap, shaving foam, shaving lotion, shaving cream, lotion and cream, and dental care products (e.g. toothpaste, mouthwash, etc.) are particularly preferred.Preferred cosmetic products are hair care compositions, such as shampoos, and solid surfactant compositions are particularly preferred as solid synthetic detergents for use in cosmetic cleaning and hair care compositions.

[0076] In particular, low pH agents are preferred for cleaning hard surfaces, such as baths, and toilet cleaners, such as rim blocks, and cleaning and / or fragrance gels used in hygiene facilities.

[0077] Solid Surfactant Composition Solid surfactant compositions are suitable for a variety of forms, such as bars, noodles, beads, granules, pads, needles, plates or tablets, depending on their manufacturing process and intended use.

[0078] A preferred solid surfactant composition having particularly favorable skin feel and creamy lather according to the present invention is By weight of the solid surfactant composition (wt% is active material for each compound) 30-70 wt% of alpha-sulfofatty acid di-salt (compound A); 10-50 wt% dextrin (compound B), Contains 5-20wt% water.

[0079] More preferably, the solid surfactant composition according to the present invention comprises: by weight of the solid surfactant composition 30-50 wt% of alpha-sulfofatty acid di-salt (compound A); 20-40 wt% dextrin (compound B), Contains 10-15wt% water.

[0080] Most preferably, the solid surfactant composition according to the present invention comprises: by weight of the solid surfactant composition 35-45 wt% alpha-sulfofatty acid di-salt (compound A); 23-35 wt% dextrin (compound B); Contains 7-15wt% water.

[0081] In particular, the most preferred solid surfactant compositions according to the present invention are by weight of the solid surfactant composition 40-44 wt% alpha-sulfofatty acid di-salt (compound A); 26-30 wt% dextrin (compound B); Contains 7-15wt% water.

[0082] The solid surfactant composition comprising alpha-sulfofatty acid di-salt, dextrin and water preferably comprises a pH adjusting agent, most preferred being citric acid, added in an amount of 1-10 wt %, preferably 1-6 wt %, based on the weight of the composition. Preferably, the pH of a 10 wt % solution of the composition in water has a value of 4-7, preferably 4.5-6.0.

[0083] The composition may contain further additives such as skin moisturizers, e.g. sodium lactate, glycerin, pyrrolidone carboxylic acid; pH adjusters, complexing agents; dyes; bleaching agents; fragrances; salts, e.g. sodium chloride, sodium sulfate, sodium phosphate; antioxidants, antimicrobial agents and preservatives or stabilizers.

[0084] The process for making solid surfactants has similarities to traditional soap making, which uses fatty acid soaps: the raw materials are mixed and can be processed by kneading, grinding, extruding, cutting and pressing into a solid form suitable for shipping or use.

[0085] [Example] 1. Ingredients used: Alpha-sulfo fatty acid di-salts (A): Texapon SFA Powder (BASF SE): Technical grade alpha-sulfo fatty acid di-salt based on natural C12 / 14 fatty acids; composition: 79% by weight disodium 2-sulfolaurate, 8% by weight sodium laurate, 11.8% by weight sodium sulfate, balance water to 100% by weight. The term "lauric acid" here means that the mixture of underlying natural fatty acids has a C12 / 14 weight ratio of 70:30.

[0086] Texapon SFA Paste (BASF SE): technical grade alpha-sulfo fatty acid di-salt based on natural C12 / 14 fatty acids; composition: 32.5% by weight disodium 2-sulfolaurate, 4.3% by weight sodium laurate, 4.9% by weight sodium sulfate, balance water to 100% by weight. The term "lauric acid" here means that the mixture of underlying natural fatty acids has a C12 / 14 weight ratio of 70:30.

[0087] Dextrin: from Haiyan Liuhe Pharmaceutical Industry Co. LTD, Sanlian Village, Yucheng Town, Haiyan County. Pharmaceutical grade dextrin, mesh size: 120 mesh, reducing sugar <0.20g. Dehyton PK45 (BASF SE): dry residue 44-46.0 wt%, INCI: Cocamidopropyl betaine; Eumulgin EO33 (BASF SE): Polyethylene glycol 6000 distearate, INCI: PEG-150 distearate Plantacare 818 UP (BASF SE): C8~C16 fatty alcohol glycoside; INCI: Coconut glucoside Ucare JR-400 (Dow Chemical): INCI: Polyquaternium-10;

[0088] 2. Preparation of solid surfactants The preparation of the solid surfactant comprises the following steps: First step: Preparation of a solid surfactant composition in the form of noodles: 1. Dissolve citric acid in deionized water. 2. Texapon SFA powder and polysaccharide powder were first mixed in a plowshare mixer (L20, Loedige Process Technology, Gebruder Lodige Maschinenbau, Paderborn, Germany) at 30 RPM for 3-5 min. Inert gas (e.g., nitrogen gas) was used as protective gas in the mixer to avoid dust explosions. 3. The citric acid solution was then added to the mixer by feeding it using a pressure nozzle at 30 RPM for 20-30 minutes. The mixer was then operated at 50-100 RPM for 20-30 minutes to form a wet paste. The pH of the paste (10 wt% solution in water) after mixing was 5-6. 4. Mix the paste in a Mix-Muller (LG, Simpson Technologies, Euskirchen Germany) at 15-30 RPM for an additional 20-30 minutes, and then 5. SFA noodles were produced by extrusion in an extruder (LSRE 75 R, Sela Maschinen GmbH, Harbke, Germany) using a 3 mm die at extrusion speeds of 3–10 RPM.

[0089] Second step: Preparation of solids from solid surfactant noodles: 6. The lumps formed into noodles were ground twice in a three-roller grinding mill (Weber & Seelander, Harbke, Germany) to obtain solid surfactant platelets. 7. The solid surfactant plate was loaded into a soap bar extruder (Weber & Seelander, Sela-Maschinen GmbH, Harbke, Germany) and pressed to obtain a solid surfactant.

[0090] 3. Mash resistance test method The soap bar was placed in a 250 ml beaker filled with 250 ml of deionized water at 22°C ± 2°C (Figure 1: Apparatus for the anti-mash performance test method). The bar was immersed in the water to a depth of approximately 4 cm. The length (a) and width (b) of the base were measured for the calculation of the porridge surface (A=a*b).

[0091] After 2 hours of soaking, the solids were removed from the water, carefully shaken to remove any excess water, and weighed (W1).

[0092] The mash was then removed by careful scraping with a plastic scraper, the scraped solids were wiped with tissue paper, and allowed to dry overnight to determine the terminal weight (W2).

[0093] Mash performance was calculated: Mash percent %=(W2-W0) / W0 * W0 = weight of solid before immersion * W2 = weight of solids after 2 hours soaking, mash removal and overnight drying

[0094] For hair care applications, one of the important performances is foaming, but mashability is an additional important property. If the anti-mush value is too low, the solid agent is too hard and difficult to apply to hair. If the anti-mush value is too high, the solid agent is too soft and easily dissolved in water. The best range for the mash percentage value of the solid surfactant was 5% to 40%, preferably 15% to 25%.

[0095] 4. Foaming test Brush foaming method 1. Grind the bar soap in a household automatic grinder to achieve a powder particle size of 20um~3000um. 2. Add 0.15g of soap powder and 14.85g of water to a 50ml graduated cylinder and shake gently for 1 minute for homogeneous dispersion. Place the test tube brush in the cylinder and rotate the brush vertically inside the cylinder 30 times to create bubbles. 3. Remove the brush from the cylinder and read the foam height.

[0096] 5. Drying speed test Hair Blowing Test Protocol 1. Pre-treatment of hair fibers Standard hair fibers from IHIP (Chinese hair, 15 cm / 2 g) were bundled and glued at the top. The hair fibers were washed and bleached. 2. Weighing the hair. 3. Rinse the hair for 1 minute at 38°C with a water flow rate of 1 L / min and comb once on the wide side. Then remove excess water three times using the middle and index fingers. Weigh the wet hair (maintaining a 75% increase in initial moisture of the dry hair weight). 4. The hair fibres are placed in a special tray and treated with a quantity of product, brushed evenly on each side for 30 seconds, then incubated for a total time of 3 minutes. 5. For the rinsing process, rinse the hair again with 1 L / min water flow rate at 38°C for 1 minute, and remove excess water three times using the middle and index fingers. Weigh the wet hair with the product (maintaining an initial moisture gain of 75% of the dry hair weight). For residual products, skip step 5 and proceed directly to step 6. 6. Transfer the hair to a blow dryer and blow dry until the gain is <0.05g. 7. Comb the hair fibers with the wide side after 1, 3 and 5 minutes of blow drying. 8. Record hair weight every minute.

[0097] 6. Examples using solid surfactant compositions The mash tendency and foaming properties of the bars were investigated to compare different fillers for a solid soap bar.

[0098] These bars were used for shampooing the hair to test the drying performance after hair washing.

[0099] Stearic acid was used as a comparison to dextrin as a standard filler for solid soap bars.

[0100] [Table 1]

[0101] [Table 2]

[0102] 7. Panel Testing A panel of 11 trained volunteers (9 Chinese women, 2 Chinese men) tested a commercial solid surfactant (Olaz Bar: INCI: Sodium Stearate, Sodium Cocoyl Isethionate, Paraffin, Water, Sodium Cocoglyceryl Ether Sulfonate, Glycerin, Sodium Stearate, Talc, Stearic Acid, Sodium Cocoate, Coconut Acid (from coconut), Sodium Isethionate, Sodium Chloride, Titanium Dioxide, Citric Acid, Fragrance, PEG-90M) and a solid surfactant composition according to the invention (Sample: S10 in Table 3). For all 11 participants, one bar of the control product and one bar of the inventive product were used. For the lathering test, the participants lathered the bar, described the lathering properties, and then rinsed it off. For the skin test, the participants rubbed the wet bar on their forearms for 20 seconds, rinsed it, and dried it. The test is carried out in an air-conditioned room at a temperature of 22° C. and a relative humidity of 50%. The results are shown in Figure 2. (Panel test results).

[0103] [Table 3] TIFF0007635152000007.tif25123

[0104] [Table 4]

Claims

1. 1. A liquid aqueous or solid surfactant composition for application to skin or hair, comprising: One or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO 3 M 1 )COOM 2 (I) [In the formula, R 1 The group represents a saturated linear alkyl group having 10 to 16 C atoms, M 1 and M 2 groups are independently selected from H and Na; (B) one or more polysaccharides selected from the group consisting of dextrin, maltodextrin, cyclodextrin, potato starch, wheat starch and / or corn starch; Including, However, the following The surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 2 CH(SO 3 M 7 )COOR 3 (V) [In the formula, R 2 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 3 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 3 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 7 groups are selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups, with the proviso that said compound (A) must be present in an amount of more than 50% by weight relative to the sum of said compounds (A) and (E), The compound (A) is present in an amount of 3 to 6 weight percent based on the total weight of the composition for a liquid aqueous composition, and the compound (B) is present in an amount of 1 to 3 weight percent based on the total weight of the composition for a liquid aqueous composition; or A surfactant composition, wherein compound (A) is present in an amount of 30 to 50 weight percent based on the weight of the composition for a solid composition, and compound (B) is present in an amount of 15 to 40 weight percent based on the weight of the composition for a solid composition.

2. One or more alpha-sulfofatty acid di-salts (A) of general formula (I) R 1 CH(SO 3 M 1 )COOM 2 (I) [In the formula, R 1 The group represents a saturated linear alkyl group having 10 to 16 C atoms, M 1 and M 2 groups are independently selected from H and Na; one or more dextrins (B) of general formula (II) 【Chemistry 1】 [wherein n is an integer from 3 to 200] Including, However, the following The surfactant composition comprises one or more sulfonic acid esters (E) of general formula (V) R 2 CH(SO 3 M 7 )COOR 3 (V) [In the formula, R 2 The group is a linear or branched alkyl or alkenyl group having 6 to 18 carbon atoms, R 3 The group is a linear or branched alkyl or alkenyl group having 1 to 20 carbon atoms, R 3 The group may logically be an alkenyl group or may be branched only in the case of more than 3 carbon atoms, M 7 groups are selected from Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups, with the proviso that said compound (A) must be present in an amount of more than 50% by weight relative to the sum of said compounds (A) and (E), The compound (A) is present in an amount of 3 to 6 weight percent based on the total weight of the composition for a liquid aqueous composition, and the compound (B) is present in an amount of 1 to 3 weight percent based on the total weight of the composition for a liquid aqueous composition; or 2. The liquid aqueous or solid surfactant composition for application to skin or hair according to claim 1, wherein compound (A) is present in an amount of 30 to 50 weight percent, based on the weight of the composition, for solid compositions, and compound (B) is present in an amount of 15 to 40 weight percent, based on the weight of the composition, for solid compositions.

3. 3. A liquid aqueous or solid surfactant composition according to claim 1 or 2, wherein said compound (A) must be present in greater than 60% by weight relative to the sum of said compounds (A) and (E).

4. 4. The liquid aqueous or solid surfactant composition according to claim 1, wherein, with respect to said compounds (A), the proportion of said compounds (A) in which the R group is a decyl or dodecyl group is greater than 60% by weight relative to the total amount of said compounds (A).

5. The liquid aqueous or solid surfactant composition contains less than 40% by weight of an anionic surfactant other than compound (A) and (C) of general formula (III), wherein formula (III) is R 4 COOM 3 (III) In formula (III), R 4 The group is a linear or branched alkyl or alkenyl group having 7 to 19 carbon atoms, and with respect to compound (C), R 4 The proportion of the compound (C) having an undecyl or tridecyl group is more than 60% by weight based on the total amount of the compound (C), 3 5. A liquid aqueous or solid surfactant composition according to any one of claims 1 to 4, wherein the groups are selected from H, Li, Na, K, Ca / 2, Mg / 2, ammonium and alkanolamine groups.

6. 6. Use of a liquid, aqueous or solid surfactant composition according to any one of claims 1 to 5 for cosmetic applications.

7. 6. Use of the liquid aqueous or solid surfactant composition according to any one of claims 1 to 5 for cosmetic products in the form of hair shampoos, solid surfactant compositions, shower gels, soaps, paste cleaners, solid cleaners, lotion cleaners, scrub preparations, foam baths, oil baths, shower baths, solid soaps, shaving foams, shaving lotions, shaving creams, lotions and creams.

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