Laser welding of stacked thin pieces

Abstract

A method is disclosed for laser keyhole welding a stack of metal laminae (22) onto a metal tab (24). The method independently adjusts the power of a focused central beam and the power of a focused annular beam to form a weld (34) through all laminae (22) and tabs (24). The annular beam provides sufficient power to heat the metal to about the melting temperature, widen the keyhole mouth, and stabilize the molten pool. The central beam provides additional power sufficient to form the keyhole. The power of the annular beam is sustained for a longer time than the power of the central beam. Multiple such welds are formed to provide mechanical strength and electrical conductivity.

Description

[Technical field]

[0001] (Priority) This application claims priority to U.S. Patent Application No. 16 / 828,194, filed March 24, 2020, the disclosure of which is incorporated herein by reference in its entirety.

[0002] TECHNICAL FIELD OF THEINVENTION The present invention relates generally to welding using a focused beam of laser radiation, and more particularly to welding a stack of metal foils using a focused central beam and a focused annular beam. [Background technology]

[0003] Background Field Discussion Beams of laser radiation are increasingly being used to cut, drill, weld, mark and scribe workpieces made from a wide range of materials, including metals and alloys. Traditional mechanical processes produce unwanted defects, such as microcracks that propagate when stress is applied to the machined workpiece, thereby degrading and weakening the machined workpiece. Laser processing minimizes such unwanted defects, resulting in cleaner and smaller heat affected zones. Laser processing uses a focused laser beam to produce precision cuts and holes with high quality edges and walls while minimizing the formation of unwanted defects.

[0004] In laser welding, a focused laser beam precisely positions each weld spot or seam while minimizing the associated heating. It is useful to distinguish between two main laser welding regimes. Conduction welding occurs at lower laser power and lower power density. The absorbed laser power heats the irradiated material and melts the material of each part being joined, which flows, mixes, and solidifies. Keyhole welding occurs at higher laser power and higher power density that is sufficient to vaporize a portion of the irradiated material. The pressure of the vaporized material on the surrounding molten material opens a channel through the molten material with a characteristic narrow and deep morphology that allows for deep penetration of the laser beam. The resulting keyhole weld is generally narrower, deeper, and stronger than conduction welding. However, it can be difficult to maintain a stable keyhole in a dynamic pool of hot molten material.

[0005] Lithium-ion batteries are an essential technology for portable electronics, electric vehicles, and most other modern rechargeable electrical devices. Each cell of the battery contains two stacks of thin metal flakes immersed in an electrolyte. The metal is most often aluminum or copper, and the flakes have a thickness of about 10 micrometers (μm). There are typically 20 to 40 individual flakes in each flake stack. The flake stacks can be rolled into a cylindrical shape or laid flat. The electrolyte is a lithium salt dissolved in a solvent. Each flake stack is electrically connected to a metal tab that protrudes from the cell for electrical connection. Multiple cells are electrically connected to form a battery in series and / or parallel depending on the voltage and current requirements of the electrical device. Multiple batteries can be electrically connected in series and / or parallel to form a battery pack.

[0006] The mechanical attachment and electrical connection of each lamination in the stack to its respective tab is important for the integrity, reliability, and performance of the battery. However, joining multiple thin metal laminations to a fairly thick metal tab is difficult, especially when the lamination stack and tabs are made of different materials. The completed joint must be strong, durable, and have low electrical resistance. Precision resistance welding is used, but depends on the interface resistance for these metals with high electrical conductivity, and the high thermal conductivity of these metals means that many electrical currents must be applied. Ultrasonic welding is used, but requires mechanical compression of the parts to be joined, which must be joined before any assembly. Aluminum has a durable oxide layer that must be broken in such non-laser processes. For this reason, laser welding is preferred, providing precise delivery power to minimize overall heat buildup. Keyhole laser welding is capable of forming a strong weld through the entire thickness of the lamination stack and tab. Some battery designs include additional lamination-to-tab joints to attach and connect cells within the battery, which also benefit from keyhole laser welding.

[0007] One problem with keyhole laser welding is the ejection of molten material from the weld pool due to a combination of vapor pressure, shear stress caused by the vapor flow, recoil due to evaporation, and rapid material circulation around the weld pool, which overcomes the surface tension of the molten material. This ejected material droplets, known as "spatter," recondense on the metal surface causing contamination. This ejection leaves the top and bottom surfaces of the completed weld clear of material, thereby weakening the completed weld. Another problem with keyhole laser welding is inconsistent penetration depth due to the complex dynamics involved in forming and maintaining the keyhole.

[0008] There is a need for a rapid, simple, and reliable process for laser welding the metal foil stack to the metal tab that produces clean and consistent welds. The process must produce a strong joint through the entire thickness of the entire foil stack and tab with low electrical resistance between them. Preferably, the process does not increase the cost per weld and is compatible with high volume automated manufacturing. Summary of the Invention [Means for solving the problem]

[0009] In one aspect, a method for laser welding multiple copper flakes onto a copper tab according to the present invention includes assembling the flakes into a stack and compressing the stack of flakes and the tab to form a workpiece. A focused beam of laser radiation is directed at a surface of the workpiece at a location to be welded. The focused beam includes a central beam and a concentric annular beam. The power of the annular beam is increased to a first power and sustained for a first time sufficient to heat the surface of the workpiece at the location to be welded to at least 1100 Kelvin (K). The power of the central beam is increased to a second power and reaches a second power after the surface of the workpiece at the location to be welded reaches 1100K. The power of the central beam is sustained for a second time sufficient to melt all of the flakes and the tab, thereby forming a weld joining all of the flakes and the tab.

[0010] In another aspect, a method for laser welding a plurality of aluminum laminae onto an aluminum tab according to the present invention includes assembling the laminae into a stack and compressing the stack of laminae and the tab to form a workpiece. A focused beam of laser radiation is directed at a surface of the workpiece at a location to be welded. The focused beam includes a central beam and a concentric annular beam. The power of the annular beam is increased to a first power while the power of the central beam is increased to a second power. The power of the annular beam is sustained for a first time. The power of the central beam is sustained for a second time, and then the power of the central beam is decreased. The first time is greater than the second time. The second time is sufficient to melt all of the laminae and the tab, thereby forming a weld joining all of the laminae and the tab. The present invention provides, for example, the following: (Item 1) 1. A method for laser welding a plurality of copper foils onto a copper tab, the method comprising: assembling the laminae into a stack and compressing the stack of laminae and the tab to form a workpiece; directing a focused beam of laser radiation at a surface of the workpiece at a location to be welded, the focused beam including a central beam and concentric annular beams; increasing the power of the annular beam to a first power; sustaining power to the annular beam for a first time sufficient to heat the surface of the workpiece at the location to be welded to at least 1100 Kelvin; increasing the power of the central beam to a second power, the central beam reaching the second power after the surface of the workpiece at the location to be welded reaches 1100 Kelvin; sustaining power on the central beam for a second time period sufficient to melt all of the laminae and the tab, thereby forming a weld joining all of the laminae and the tab. A method comprising: (Item 2) 2. The method of claim 1, wherein during the step of maintaining the power of the annular beam, the power of the annular beam is maintained at the first power. (Item 3) 2. The method of claim 1, wherein during the step of sustaining the power of the annular beam, the power of the annular beam is modulated. (Item 4) 4. The method according to any one of items 1 to 3, wherein during the step of maintaining the power of the central beam, the power of the central beam is maintained at a second power. (Item 5) 4. The method according to any one of items 1 to 3, wherein during the step of sustaining the power of the central beam, the power of the central beam is modulated. (Item 6) 2. The method of claim 1, wherein during the step of increasing the power of the central beam, the power of the annular beam is decreased to a third power. (Item 7) 7. The method of claim 6, wherein the power of the annular beam is maintained at the third power for the second time period. (Item 8) 7. The method of claim 6, wherein the power of the annular beam is modulated during the second time period. (Item 9) The method according to any one of items 6 to 8, wherein the third power is about 700 watts to about 1300 watts. (Item 10) 2. The method of claim 1, wherein the first power is between about 1350 watts and about 1650 watts. (Item 11) The method of any preceding item, wherein the second power is between about 1300 watts and about 1600 watts. (Item 12) 2. The method of claim 1, wherein the first period of time has a duration of about 0.2 milliseconds to about 10 milliseconds. (Item 13) The method of any of the preceding items, wherein the second period of time has a duration of about 0.1 milliseconds to about 5 milliseconds. (Item 14) 2. The method of claim 1, wherein the focused beam is directed onto the surface of the workpiece at an angle of incidence between 80 degrees and 90 degrees. (Item 15) The method according to any of the preceding items, wherein 20 to 100 sheets are welded onto the tab. (Item 16) The method of any of the preceding items, wherein each slice has a thickness of about 5 micrometers to about 15 micrometers. (Item 17) 20. The method of claim 19, wherein the steps of directing a focused beam, increasing a power of the annular beam, maintaining a power of the annular beam, increasing a power of the central beam, and maintaining a power of the central beam are repeated multiple times to form multiple welds at multiple locations. (Item 18) 2. The method of claim 1, wherein the central beam has a diameter of about 100 microns to about 400 microns at the surface of the workpiece and the annular beam has a diameter of about 300 microns to about 1200 microns at the surface of the workpiece. (Item 19) 1. A method for laser welding a plurality of aluminum laminations onto an aluminum tab, the method comprising: assembling the laminae and compressing the stack of laminae and the tabs to form a workpiece; directing a focused beam of laser radiation at a surface of the workpiece at a location to be welded, the focused beam including a central beam and a concentric annular beam; increasing a power of the annular beam to a first power while increasing a power of the central beam to a second power; sustaining the power of the annular beam for a first time period; maintaining the power of the central beam for a second time period and then ramping down the power of the central beam, the first time period being greater than the second time period; Including, The method, wherein the second time is sufficient to melt all of the laminae and the tab, thereby forming a weld joining all of the laminae and the tab. (Item 20) 20. The method of claim 19, wherein during the step of maintaining the power of the annular beam, the power of the annular beam is maintained at the first power. (Item 21) 20. The method of claim 19, wherein during the step of sustaining the power of the annular beam, the power of the annular beam is modulated. (Item 22) 22. The method according to any one of items 19 to 21, wherein during the step of maintaining the power of the central beam, the power of the central beam is maintained at the second power. (Item 23) 22. The method according to any one of items 19 to 21, wherein during the step of sustaining the power of the central beam, the power of the central beam is modulated. (Item 24) 24. The method according to any one of items 19 to 23, wherein the first power is about 1350 watts to about 1650 watts. (Item 25) 25. The method according to any one of items 19 to 24, wherein the second power is about 1450 watts to about 1750 watts. (Item 26) 26. The method according to any one of items 19 to 25, wherein the first period of time has a duration of about 0.5 milliseconds to about 20 milliseconds. (Item 27) 27. The method according to any one of items 19 to 26, wherein the second period of time has a duration of about 0.1 milliseconds to about 5 milliseconds. (Item 28) 28. The method according to any one of items 19 to 27, wherein the focused beam is directed at the surface of the workpiece at an angle of incidence between 80 degrees and 90 degrees. (Item 29) 29. The method according to any one of items 19 to 28, wherein 20 to 100 sheets of foil are welded onto the tab. (Item 30) 30. The method according to any one of items 19 to 29, wherein each slice has a thickness of about 5 micrometers to about 15 micrometers. (Item 31) 31. The method of any of items 19-30, wherein the steps of directing the focused beam, increasing the power of the annular beam and the central beam, maintaining the power of the annular beam, and maintaining the power of the central beam are repeated multiple times to form multiple welds at multiple locations. (Item 32) 32. The method according to any one of items 19 to 31, wherein the central beam has a diameter of about 100 microns to about 400 microns on the surface of the workpiece, and the annular beam has a diameter of about 300 microns to about 1200 microns on the surface of the workpiece. [Brief description of the drawings]

[0011] The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate preferred embodiments of the invention and, together with the general description given above and the detailed description of the preferred embodiments given below, serve to explain the principles of the invention.

[0012] [Figure 1A] FIG. 1A is a schematic side view, partially in cross section, of one preferred embodiment of a laser welding apparatus for implementing the laser welding method of the present invention, the apparatus including a laser source generating at least two beams of laser radiation, an optical fiber, and a focusing lens. [Figure 1B] FIG. 1B is a cross-sectional schematic diagram illustrating a detail of the optical fiber of FIG. 1A, having a central core for directing a central beam and an annular core for directing an annular beam. [Diagram 2] FIG. 2 is a graph of beam power versus time that is a schematic illustrating a laser welding method according to the present invention using the apparatus of FIGS. 1A and 1B to weld a stack of copper foils to a copper tab. [Diagram 3] FIG. 3A is a plan view of a weld in a copper workpiece made using the method of the present invention of FIG. 2, and FIG. 3B is an enlarged plan view thereof, with the photograph showing the surface of the stack of laminae that was in the front during welding. [Figure 4] FIG. 4 is a graph of beam power versus time that is a schematic illustrating a laser welding method according to the present invention using the apparatus of FIGS. 1A and 1B to weld a stack of aluminum laminations to an aluminum tab. [Figure 5A] FIG. 5A is a top view of a weldment of an aluminum workpiece made using the method of the present invention of FIG. 4, with the photograph showing the surface of the stack of laminae that was in the front during welding. [Figure 5B] FIG. 5B is a top view of the weld in the workpiece of FIG. 5A, with the photograph showing the front side of the tab that was the back side during welding. [Figure 6] FIG. 6 is a top view of a weldment of an aluminum workpiece made using the method of the present invention of FIG. 4, with the photograph showing the surface of the tab that was in the front during welding. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] Detailed Description of the Invention Referring now to the drawings, in which like components are designated by like numerals, FIGS. 1A and 1B diagrammatically illustrate an apparatus 10 used in the laser welding method of the present invention. A laser source 12 delivers at least two beams of laser radiation through an optical fiber 14 to a focusing lens 16. The optical fiber 14 includes a central core 40 for guiding a central beam of laser radiation. The central core 40 has a concentric low-index cladding 42. The optical fiber 14 further includes an annular core 44 for guiding an annular beam of laser radiation. The annular core 44 is concentrically located between the low-index cladding 42 and the low-index cladding 46. The laser source 12 is configured to deliver a central beam to the central core 40 and an annular beam to the annular core 44. Laser systems integrating such laser sources with such optical fibers are commercially available. For example, the Highlight 1000 Series from Coherent Inc. of Santa Clara, Calif. TM FL-ARM laser. One feature of this laser system is that the power of the central beam and the annular beam can be independently selected and adjusted.

[0014] Focusing lens 16 forms a focusing beam 18, which comprises a converging central beam depicted as a converging solid line and concentric converging annular beams depicted as converging dashed lines. The converging beam converges towards a focal point 20, the converging central beam having a much smaller diameter than the concentric converging annular beams. The converging beam 18 is directed at a workpiece comprising a stack 22 of metal laminae and a metal tab 24 to be welded together. The stack 22 and tab 24 may be made of copper, nickel, nickel-plated copper, aluminum, alloy steel, or other metals or metal alloys selected to make cells or batteries. The stack and tab may be made of the same metal or may be made of different metals. The stack 22 and tab 24 are compressed by clamp 26 to form the workpiece, eliminating gaps between the individual laminae in the stack and between the stack and the tab. Any remaining gaps are preferably less than 20% of the thickness of the individual laminae, and most preferably less than 10% of the thickness of the individual laminae. In the drawings, the workpiece and clamp are depicted in cross section.

[0015] The workpiece is supported and moved as necessary by a translation stage 28. A focal spot 20 is located proximate to the front surface of the workpiece. The focal spot is moved laterally across the workpiece by a beam scanner 30, which may include an acousto-optic deflector or galvanometer-actuated mirror to allow rapid movement of the focal spot 20 during laser welding. The beam scanner 30 and the focusing lens 16 may be conveniently integrated into a laser processing head 32. By way of example, the focusing lens 16 may be a flat-field objective lens to maintain a consistent depth of focus across the entire surface of the workpiece accessible with the laser processing head 32. The processing head 32 may also include an optional beam expander (not shown here), which is located between the optical fiber 14 and the focusing lens 16 to expand and collimate the beam emerging from the optical fiber before focusing. A weld 34 is formed through the workpiece upon exposure to the focused beam 18.

[0016] FIG. 2 shows a schematic of the power in the central core and the power in the annular core versus time for a preferred embodiment of a laser welding method 50 according to the invention for welding a plurality of laminae onto a tab, where the laminae and the tab are made of copper, nickel-plated copper, or a copper alloy. The laminae are first assembled into a stack, and the stack of laminae is pressed onto the tab by a clamp. The front surface of the workpiece is exposed to a focused beam 18, which is directed to the location to be welded on the front surface. The power of the annular beam is increased to a first power P1 and is maintained at the first power P1 for a first time T1, which is sufficient to heat the surface of the workpiece at the location to be welded to at least 1100 K, more preferably to 1300 K. During the first time T1, the annular beam preheats the surface of the workpiece. It is known that for copper at about 1300 K there is a sharp decrease in thermal conductivity and a sharp increase in optical absorption for radiation having a wavelength of about 1 μm. Heating copper through this temperature reduces its thermal conductivity by about a factor of two and increases its near-infrared light absorption by about a factor of three.

[0017] Towards the end of the first time T1, the power of the central beam is increased to a second power P2 and sustained at the second power P2 for the second time T2, which is sufficient to melt all the laminae 22 and tabs 24 of the stack. This melting by the central beam forms a weld 34 joining all of the laminae 22 and tabs 24 of the stack. The focused central beam preferably forms a keyhole in the molten material that penetrates all the laminae and tabs. The power of the annular beam is decreased to a third power P3 while the power of the central beam is increased to the second power P2. The third power P3 is selected to keep the mouth of the keyhole wide open, sufficient to allow metal vapor to escape from the keyhole and to minimize the formation of spatter. During the second time T2, the power of the central beam is preferably limited to the minimum power required to melt all the laminae and tabs, and the power of the annular beam is preferably limited to the minimum power required to prevent spatter. Minimizing the total power applied to the workpiece reduces the heat affected zone around the completed weld and prevents the formation of any unwanted defects in the welded workpiece.

[0018] Figure 3A is a top view photograph of an exemplary workpiece welded using the method 50 of Figure 2. Figure 3B is a higher magnification top view photograph of the same welded workpiece. The workpiece was a stack of 25 copper foils pressed onto nickel plated copper tabs. Each foil had a thickness of 6 μm and the tab had a thickness of 300 μm.

[0019] 1A and 1B, a laser source 12 is TMThe laser was a FL8000-ARM laser, independently providing up to 4 kW of power through each core of the optical fiber 14 at a wavelength of 1070 nanometers. The central core 40 had a diameter of 100 μm and the annular core 44 had an outer diameter of 290 μm. The laser processing head 32 was a SCANLAB intelliSCAN 30 scan head available from SCANLAB GmbH of Puchheim, Germany. The focusing lens 16 provided a magnification of 1.4 times such that the focused central beam had a diameter of approximately 140 μm and the focused annular beam had an outer diameter of approximately 405 μm. Nitrogen shielding gas was directed to the location to be welded on the workpiece during welding. The focused beam 18 was focused at a near normal angle of incidence (90°) as depicted in the drawing. o ) was applied to the surface of the stack. o ~90 o It has been found that an incidence angle between 100 and 150 nm is beneficial. The clamp 26 was machined from a single block of metal and pressed onto the workpiece around the location to be welded. The focused beam 18 was directed onto the workpiece through a notch in the clamp.

[0020] 3A and 3B show the surface of the stack, which was the front of the workpiece exposed to the focused beam and thus the incidence surface during keyhole welding. The workpiece was welded at 42 locations along two zigzag rows. In the illustrated example, the rows were welded sequentially by directing the focused beam at successive locations along the row. At each location, power was applied through the annular core and the central core as depicted in FIG. 2 to create the weld, where the first power P1=1500 watts (W), the second power P2=1450 W, the third power P3=1000 W, the first time T1=1 millisecond (ms), and the second time T2=1 ms.

[0021] Here, "off power" refers to a power that is too low to melt the surface of the workpiece and too low to damage the workpiece during long-term exposure to the focused beam. The off power in this example is 0 W. The power of the annular beam was ramped up from the off power to the first power P1 in about 3 ms. The power of the central beam was ramped up from the off power to the second power P2 in about 1 ms, while the power of the annular beam was ramped down simultaneously from the first power P1 to the third power P3. The power of the central beam was ramped down from the second power P2 to the off power, and the power of the annular beam was ramped down simultaneously from the third power P3 to the off power in about 1 ms. The power was applied for a total time of about 7 ms at each location, and it took about 0.54 seconds overall to complete the 42 welds. This overall time includes the time it took to translate the focused beam between locations.

[0022] The preheating provided by the focused annular beam during the first time T1 reduced the near infrared power required for the deeper melting and welding provided by the focused central beam. The preheating thereby reduced the laser energy applied to the workpiece and reduced the heat affected zone. The preheating also allowed the focused central beam to penetrate deeper into the workpiece, which further improved the weld quality.

[0023] In the laser welding method 50 applied in the example of FIG. 3A and FIG. 3B, the power of the central beam was increased to the second power P2 and at the same time the power of the annular beam was decreased to the third power P3. However, this simultaneous ramping is not a necessary condition for forming a successful weld. It is sufficient that the central beam reaches the second power P2 after the surface of the stack reaches 1100K, and that the two focused beams together maintain at least this temperature until the central beam reaches the second power P2. Similarly, the simultaneous ramping of the two beams to the off power is not necessary for forming a successful weld. For some workpieces, it may be desirable to continue the power of the annular beam until the central beam is decreased to the power at which the keyhole is crushed.

[0024] The laser welding method 50 has a typical first power P1 of about 1350 W to about 1650 W, a typical second power P2 of about 1300 W to about 1600 W, and a typical third power P3 of about 700 W to about 1300 W. The first time T1 is typically about 0.2 ms to about 10 ms and the second time T2 is typically about 0.1 ms to about 5 ms in duration.

[0025] FIG. 4 shows a schematic of the power of the central core and the power of the annular core versus time for another preferred embodiment of a laser welding method 60 according to the invention for welding multiple laminae onto a tab. Here, both the laminae and the tab are made of aluminum or an aluminum alloy. Again, the laminae are first assembled into a stack, and the stack of laminae is pressed onto the tab by a clamp. The front surface of the workpiece is exposed to a focused beam 18, which is directed to the location to be welded on the front surface of the workpiece. The power of the annular beam is increased to a first power P1, while the power of the central beam is increased to a second power P2. The power of the annular beam is sustained for a first time T1 and then decreased. The power of the central beam is sustained for a second time T2, shorter than the first time T1, and then decreased. The second time T2 is selected to be long enough to melt all the stack laminae 22 and the tab 24. This melting by the center beam forms a weld 34 joining all of the laminae and tabs 24 of the stack 22. The first time T1 is selected to be long enough to allow for a controlled collapse of the keyhole and a controlled collapse of the molten pool. This controlled collapse and contraction allows metal vapor to escape from the molten pool, thereby preventing voids in the welded workpiece as well as providing an anneal to minimize any crack formation.

[0026] 5A and 5B are planar photographs of an exemplary workpiece welded using the method 60 of FIG. 4. The workpiece was a stack of 24 aluminum flakes pressed onto an aluminum tab. Each flake had a thickness of 12 μm, and the tab had a thickness of 400 μm. The laser source, optical fiber, laser processing head, focusing lens, shielding gas, and clamps were identical to the example of FIGS. 3A and 3B. FIG. 5A shows the front side of the stack, which was the front side of the workpiece exposed to the focused beam and thus the incidence surface during keyhole welding. FIG. 5B is the back side of the tab. The workpiece was welded at 42 locations along two zigzag rows, with the rows welded sequentially. At each location, power was applied through the annular core and the central core as depicted in FIG. 4 to create a weld. Here, the first power P1=1500 W, the second power P2=1600 W, the first time T1=5 ms, and the second time T2=1 ms.

[0027] The off power in the illustrated example was 0 W. The power of the annular beam was ramped up from off power to the first power P1 in about 3 ms, while the power of the center beam was ramped up from off power to the second power P2 simultaneously. The power of the center beam was ramped down from the second power P2 to off power in about 1 ms. The power of the annular beam was ramped down from the first power P1 to off power in about 1 ms. Power was applied at each position for a total time of about 9 ms, and it took a total time of about 2.06 s to complete all 42 welds. The simultaneous tilting of the annular beam to the first power P1 and the center beam to the second power P2 in this example was found to be beneficial in preventing splashing.

[0028] FIG. 6 is a top view photograph of another exemplary workpiece welded using the method 60 of FIG. 4. The workpiece here was an aluminum tab pressed onto a stack of 24 aluminum laminae. Each laminae had a thickness of 12 μm, and the tab had a thickness of 400 μm. The laser source, optical fiber, shielding gas, and clamps were identical to those in the above examples. The laser processing head 32 was an RLSK 3d remote laser welding head available from II-VI Inc., Kleinmachnow, Germany. The focusing lens 16 provided a 3× magnification such that the focused central beam had a diameter of about 300 μm and the focused annular beam had an outer diameter of about 870 μm. The drawing shows the surface of the tab, which was the surface of the workpiece exposed to the focused beam and thus the incidence surface during keyhole welding. The workpiece was welded at 40 locations along two zigzag rows, with the rows being welded sequentially. Here, the first power P1=1500 W, the second power P2=1600 W, the first time T1=6 ms, and the second time T2=1 ms.

[0029] The off power in the illustrated example was 0 W. The power of the annular beam was ramped up from off power to the first power P1 in about 8 ms while the power of the center beam was ramped up from off power to the second power P2 simultaneously. The power of the center beam was ramped down from the second power P2 to off power in about 1 ms. The power of the annular beam was ramped down from the first power P1 to off power in about 2 ms. Power was applied at each location for a total time of about 16 ms, taking an overall time of about 1.07 s to complete all 40 welds.

[0030] A typical workpiece for the laser welding methods 50 and 60 has 20 to 100 individual flakes to be welded onto the tab. Each flake has a typical thickness of about 5 μm to about 15 μm. A typical tab has a thickness of about 100 μm to about 500 μm. A typical focused central beam diameter is about 100 μm to about 400 μm, and a typical focused annular beam diameter is about 300 mm to about 1200 mm on the surface of the workpiece. The laser welding method 60 has a typical first power P1 of about 1350 W to about 1650 W and a typical second power P2 of about 1450 W to about 1750 W. The first time T1 is typically about 0.5 ms to about 20 ms, and the second time T2 is typically about 0.1 ms to about 5 ms in duration.

[0031] 5A, 5B, and 6 together show that the welding method of the present invention works with a focused beam 18 incident on either the outer surface of the stack 22 or the outer surface opposite the tab 24. Generally, it is necessary to make multiple welds to reliably join the stack of laminae to the tab. A greater number and density of welds provide a stronger joint with higher electrical conductivity. However, those skilled in the art will recognize that there is a tradeoff between the total number of welds and the overall time to complete all of those welds, so the number and density of welds is specific to a particular application. The overall area of ​​the workpiece to be welded is easily scaled by varying the number of individual welds. The method of the present invention can be applied to join a stack of laminae to an anode or cathode tab in a cell. The method of the present invention can also be applied to join laminae that electrically connect the cells in a battery.

[0032] A beam scanner 30 translates the focused beam 18 laterally between a number of locations on the workpiece to be welded. A weld is made at each of these locations by delivering a pulse of laser radiation through each core of the fiber through a focusing lens onto the workpiece. Figures 2 and 4 show the power profiles of the pulse pairs used to make each weld for laser welding methods 50 and 60, respectively. Although a linear power ramp has been shown and discussed herein, for ease of illustration and explanation, the welding method of the present invention may be optimized by applying other types of power ramping of the central and / or annular beams. For example, an exponential power ramp.

[0033] In the examples herein, the annular beam and the central beam were maintained at constant power, the first power P1 and the second power P2, respectively, but the welding method of the present invention may be further optimized by modulating the power of these beams during the first time T1 and the second time T2. For example, in the laser welding method 60 of FIG. 4, the power of the annular beam is rapidly cycled between the first power P1 and a much lower power to allow metal vapor to escape, thereby preventing the formation of voids in the weld. Alternatively, stepping down from the first power P1 to a lower power after the keyhole closes anneals the cooled metal, thereby preventing the formation of cracks in the weld. The important requirement is to provide sufficient power to the annular beam to widen the mouth of the keyhole during keyhole welding, stabilize the weld pool, and then allow for controlled collapse of the keyhole and controlled contraction of the molten pool.

[0034] In summary, the method of the present invention for welding a stack of metal laminae onto a metal tab using a focused laser beam including a central beam and an annular beam is described above. The focused annular beam has sufficient power to heat the locations to be welded to about the melting temperature of the metal. The focused central beam has sufficient additional power and is sustained for a sufficient time to form a keyhole weld joining all the laminae and the tab. The annular beam is sustained for a longer time, which provides preheat for metals with high thermal conductivity (such as copper) and postheat for metals prone to steam entrapment (such as aluminum). The method is repeated to form welds in a sufficient number and density of locations to provide the mechanical strength and electrical conductivity for the particular application.

[0035] The present invention has been described above with respect to preferred and alternative embodiments. However, the present invention is not limited to the embodiments described and illustrated herein. Rather, the present invention is limited only by the claims appended hereto.

Claims

1. 1. A method for laser welding a plurality of copper foils onto a copper tab, the method comprising: forming a workpiece by assembling the plurality of laminae into a stack and compressing the stack of laminae and the tab; directing a focused beam of laser radiation at a surface of the workpiece at a location to be welded, the focused beam including a central beam and concentric annular beams; increasing the power of the annular beam to a first power; sustaining power on the annular beam for a first time sufficient to heat the surface of the workpiece at the location to be welded to at least 1100 Kelvin; increasing the power of the central beam to a second power, the central beam reaching the second power after the surface of the workpiece at the location to be welded reaches 1100 Kelvin; sustaining power on the central beam for a second time period sufficient to melt all of the plurality of laminae and the tab, thereby forming a weld joining all of the plurality of laminae and the tab; A method comprising:

2. The method of claim 1 , wherein during the step of sustaining the power of the annular beam, the power of the annular beam is sustained at the first power.

3. The method of claim 1 , wherein during the step of sustaining the power of the annular beam, the power of the annular beam is modulated.

4. The method of claim 1 , wherein during the step of maintaining the power of the central beam, the power of the central beam is maintained at the second power.

5. The method of claim 1 , wherein during the step of sustaining the power of the central beam, the power of the central beam is modulated.

6. The method of claim 1 , wherein during the step of increasing the power of the central beam, the power of the annular beam is decreased to a third power.

7. The method of claim 6 , wherein the power of the annular beam is sustained at the third power for the second period of time.

8. The method of claim 6 , wherein the power of the annular beam is modulated during the second time period.

9. The method of claim 6, wherein the third power is between 700 watts and 1300 watts.

10. The method of claim 1 , wherein the first power is between 1350 Watts and 1650 Watts.

11. The method of claim 1 , wherein the second power is between 1300 Watts and 1600 Watts.

12. The method of claim 1 , wherein the first period of time is between 0.2 milliseconds and 10 milliseconds in duration.

13. The method of claim 1 , wherein the second period of time is between 0.1 milliseconds and 5 milliseconds in duration.

14. The method of claim 1 , wherein the focused beam is directed onto the surface of the workpiece at an angle of incidence between 0 and 10 degrees.

15. The method of claim 1, wherein between 20 and 100 laminae are welded onto the tab.

16. The method of claim 1 , wherein each flake has a thickness between 5 micrometers and 15 micrometers.

17. 10. The method of claim 1 , wherein the steps of directing the focused beam and increasing and maintaining the power of the annular beam and increasing and maintaining the power of the central beam are repeated multiple times to form multiple welds at multiple locations.

18. 10. The method of claim 1, wherein the central beam has a diameter of 100 microns to 400 microns on the surface of the workpiece and the annular beam has a diameter of 300 microns to 1200 microns on the surface of the workpiece.

19. 1. A method for laser welding a plurality of aluminum laminations onto an aluminum tab, the method comprising: forming a workpiece by assembling the plurality of laminae and compressing the stack of laminae and the tab; directing a focused beam of laser radiation at a surface of the workpiece at a location to be welded, the focused beam including a central beam and concentric annular beams; increasing a power of the annular beam to a first power while increasing a power of the central beam to a second power; sustaining the power of the annular beam for a first time period; maintaining the power of the central beam for a second time period and then ramping down the power of the central beam, the first time period being greater than the second time period; Including, The method, wherein the second time is sufficient to melt all of the plurality of laminae and the tab, thereby forming a weld joining all of the plurality of laminae and the tab.

20. 20. The method of claim 19, wherein during the step of sustaining the power of the annular beam, the power of the annular beam is sustained at the first power.

21. 20. The method of claim 19, wherein during the step of sustaining the power of the annular beam, the power of the annular beam is modulated.

22. 20. The method of claim 19, wherein during the step of sustaining the power of the central beam, the power of the central beam is sustained at the second power.

23. 20. The method of claim 19, wherein during the step of sustaining the power of the central beam, the power of the central beam is modulated.

24. 20. The method of claim 19, wherein the first power is between 1350 watts and 1650 watts.

25. 20. The method of claim 19, wherein the second power is between 1450 watts and 1750 watts.

26. 20. The method of claim 19, wherein the first period of time is between 0.5 milliseconds and 20 milliseconds in duration.

27. 20. The method of claim 19, wherein the second period of time is between 0.1 milliseconds and 5 milliseconds in duration.

28. The method of claim 19, wherein the focused beam is directed onto the surface of the workpiece at an angle of incidence between 0 and 10 degrees.

29. The method of claim 19, wherein between 20 and 100 laminae are welded onto the tab.

30. The method of claim 19, wherein each flake has a thickness between 5 micrometers and 15 micrometers.

31. 20. The method of claim 19, wherein the steps of directing the focused beam and increasing the power of the annular beam and the power of the central beam and maintaining the power of the annular beam and maintaining the power of the central beam are repeated multiple times to form multiple welds at multiple locations.

32. 20. The method of claim 19, wherein the central beam has a diameter of 100 microns to 400 microns on the surface of the workpiece and the annular beam has a diameter of 300 microns to 1200 microns on the surface of the workpiece.

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