Ion Conducting Electrolytes

Abstract

To provide a novel formulation for an electrolyte containing a liquefied gas solvent.SOLUTION: An ion-conducting electrolyte according to the present invention includes vapor pressure of over 100 kPa at room temperature of 293.15 K, and includes a compressed gas solvent having fluoromethane, difluoromethane, trifluoromethane, fluoroethane, tetrafluoroethane, pentafluoroethane, 1,1-difluoroethane, 1,2-difluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1,1,2-tetrafluoroethane, salt, and an additive consisting of trimethyl phosphate and / or triethyl phosphate.SELECTED DRAWING: None

Description

[Technical field]

[0001] (CROSS REFERENCE TO RELATED APPLICATIONS) This application claims priority to U.S. Provisional Patent Application No. 62 / 908,515, filed September 30, 2019, U.S. Provisional Patent Application No. 62 / 911,505, filed October 7, 2019, and U.S. Provisional Patent Application No. 62 / 911,508, filed October 7, 2019, each of which is incorporated by reference in its entirety.

[0002] This application is also a continuation of U.S. Patent Application No. 16 / 666155, filed October 28, 2019, PCT / US2019 / 032413, filed May 15, 2019, U.S. Provisional Application No. 62 / 673792, filed May 18, 2018, U.S. Patent Application No. 16 / 666131, filed October 28, 2019, PCT / US2019 / 032414, filed May 15, 2019, U.S. Provisional Application No. 62 / 673752, filed May 18, 2019, U.S. Provisional Application No. 62 / 749046, filed October 22, 2018, U.S. Provisional Application No. 61 / 972101, filed March 28, 2014 ... This application claims priority to U.S. Provisional Application No. 61 / 905,057, filed November 15, 2015, PCT / US14 / 066015, filed November 17, 2014, U.S. Provisional Application No. 15 / 036,763, filed February 18, 2020, PCT / US17 / 29821, filed April 27, 2017, U.S. Provisional Application No. 62 / 342,838, filed November 28, 2018, PCT / US2020 / 026086, filed May 27, 2016, and U.S. Patent Application No. 62 / 800,955, filed February 4, 2019, the contents of each of which are incorporated herein by reference in their entirety.

[0003] (STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT) GOVERNMENT SUPPORT This invention was made with Government support under Grant 1831087 awarded by the National Science Foundation (NSF) and the Government has certain rights in this invention. [Background technology]

[0004] SUMMARY OF THE DISCLOSURE Embodiments of the present invention relate to electrolyte compositions and chemical formulations for use in electrochemical energy devices such as batteries and electrochemical capacitors. Summary of the Invention [Problem to be solved by the invention]

[0005] Electrochemical energy storage devices such as batteries and double layer capacitors utilize ionically conductive electrolytes to carry charge between positive and negative electrodes. Typically, these electrolytes are liquid at standard room temperature +20°C and standard pressure (approximately 1.01325 bar). Electrolytes use a mixture of solvents and salts and additional components or additives in amounts to improve the electrochemical stability of the device. Common component additives include vinyl carbonate, fluoroethylene carbonate, lithium bis(oxalato)borate, propane sultone, and others. Such additives serve for surface modification of the electrodes, safety aspects, or other useful methods. The solubility of the salt is generally a function of the primary solvent, not the additives. Furthermore, the cell voltage is generally limited by all electrolyte components, but most importantly by the solvent and any additives. Finally, the flammability of the electrolyte is generally a safety concern associated with the operation of lithium batteries. [Means for solving the problem]

[0006] Some disclosed embodiments relate to novel formulations for electrolytes that include liquefied gas solvents. One embodiment is a novel formulation for electrolytes that includes liquefied gas solvents having a vapor pressure of more than 100 kPa at room temperature of 293.15 K, and includes fluoromethane, difluoromethane, trifluoromethane, fluoroethane, tetrafluoroethane, pentafluoroethane, 1,1-difluoroethane, 1,2-difluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, pentafluoroethane, chloromethane, chloroethane, thionyl fluoride, thionyl fluoride chloride, phosphoryl fluoride, phosphiyl fluoride chloride, sulfuryl fluoride, sulfuryl fluoride chloride, 1-fluoropropane, 2-fluoropropane, 1,1-difluoropropane, 1,2-difluoropropane, 2,2-fluoropropane, 1, The present invention relates to an ionically conductive electrolyte comprising a compressed gas solvent containing one or more of 1,1-trifluoropropane, 1,1,2-trifluoropropane, 1,2,2-trifluoropropane, fluoroethylene, cis-1,2-fluoroethylene, 1,1-fluoroethylene, 1-fluoropropylene, 2-propylene, chlorine, chloromethane, bromine, iodine, ammonia, methylamine, dimethylamine, trimeramine, molecular oxygen, molecular nitrogen, carbon monoxide, carbon dioxide, sulfur dioxide, dimethyl ether, methyl vinyl ether, difluoroethylene, nitrous oxide, nitrogen dioxide, nitric oxide, carbon disulfide, hydrogen fluoride, hydrogen chloride, and isomers thereof; a salt; and an additive consisting of trimethyl phosphate and / or triethyl phosphate.

[0007] One embodiment relates to a rechargeable electrochemical device that includes an ionically conductive electrolyte that includes one or more liquefied gas solvents, one or more salts, and one or more additives, a housing that encapsulates the ionically conductive electrolyte and is structured to provide a pressurized condition for the liquefied gas solvent, and at least two conductive electrodes in contact with the ionically conductive electrolyte.

[0008] In some embodiments, the liquefied gas solvent can be under a compression pressure equal to or greater than the vapor pressure of the liquefied gas solvent at the temperature when the compression pressure is applied, thereby maintaining the liquefied gas solvent in a liquid phase. In some embodiments, the liquefied gas solvent has a vapor pressure greater than atmospheric pressure of 100 kPa at room temperature of 293.15 K.

[0009] In some embodiments, the liquefied gas solvent comprises one or more materials selected from the group consisting of fluoromethane, difluoromethane, sulfuryl fluoride, thionyl fluoride, carbon dioxide, 1,1-difluoroethane, chloromethane, nitrous oxide, dimethyl ether, nitrogen, argon, and any combination thereof. In some embodiments, the liquefied gas solvent comprises fluoromethane, difluoromethane, and carbon dioxide. In some embodiments, the ratio of sulfuryl fluoride to fluoromethane is less than 1:9. In some embodiments, the ratio of sulfuryl fluoride to carbon dioxide is about 1:1.

[0010] In some embodiments, the one or more additives are selected from the group consisting of organic phosphate compounds. In some embodiments, the one or more additives comprise trimethyl phosphate. In other embodiments, the one or more additives comprise triethyl phosphate. In other embodiments, the one or more additives are tripropyl phosphate. In other embodiments, the one or more additives are dimethylethyl phosphate.

[0011] In some embodiments, the molar ratio of the one or more additives to the one or more lithium salts is about 0.01, 0.2, 0.5, 0.7, 1, 1.2, 1.4, 1.6, 1.8, 2, 2.2, 2.4, 2.6, 3, 4, 5, 6, 7, 8, 9, or 10.

[0012] Another embodiment relates to a rechargeable lithium ion or lithium metal battery. The lithium secondary battery may include an ion-conducting electrolyte. The ion-conducting electrolyte may include a liquefied gas solvent. In some embodiments, the ion-conducting electrolyte may further include one or more additives selected from the group consisting of organic phosphate compounds. In some embodiments, the rechargeable lithium ion battery may also include a housing surrounding the two conductive electrodes and the ion-conducting electrolyte. In some embodiments, the liquefied gas solvent has a vapor pressure equal to or greater than atmospheric pressure at a room temperature of 293.15 K. In some such embodiments, the liquefied gas solvent may be placed under a compression pressure equal to or greater than the vapor pressure of the liquefied gas solvent at the temperature at which the compression pressure is applied, thereby maintaining the liquefied gas solvent in a liquid phase.

[0013] Alternative or additional embodiments described herein provide electrolyte compositions including one or more of the features described above or anywhere else herein.

[0014] Alternative or additional embodiments described herein provide a device comprising one or more of the features of any of the descriptions above or elsewhere herein.

[0015] Alternative or additional embodiments described herein provide methods of using electrolyte compositions or devices that include one or more of the features of any of the descriptions above or elsewhere herein.

[0016] As will be apparent to those skilled in the art, additional embodiments, alternatives, and variations are also disclosed herein and specifically contemplated as being included as part of the present invention. The present invention is described only in the claims granted by the Patent Office in this or a related application, and the following summary of specific examples is in no way intended to limit, define, or otherwise establish the scope of legal protection. [Brief description of the drawings]

[0017] FIG. 1 shows the performance of a battery coin cell using a lithium metal anode, a lithium nickel-cobalt-manganese oxide (NMC622) cathode, and an electrolyte consisting of 1.0 M LiTFSI, 1.0 M triethyl phosphate in CHF:CO with a molar ratio of 9:1.

[0018] FIG. 2 shows the performance of a battery coin cell using a lithium metal anode, a lithium nickel-cobalt-manganese oxide (NMC622) cathode, and an electrolyte composed of 1.0 M LiFSI, 1.2 M triethyl phosphate in CHF:CO with a molar ratio of 9:1.

[0019] FIG. 3 shows the performance of a battery coin cell using a lithium metal anode, a lithium nickel-cobalt-manganese oxide (NMC622) cathode, and an electrolyte consisting of 1.0 M LiTFSI, 1.0 M trimethyl phosphate in CHF:CO with a molar ratio of 9:1.

[0020] FIG. 4 shows the electrolytic conductivity of various liquefied gas electrolyte solutions including electrolyte solution 1 (1.0 M LiTFSI and 1.0 M triethyl phosphate (TEP) in CHF(FM)), electrolyte solution 2 (1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in CHF(FM)), and electrolyte solution 3 (1.0 M LiTFSI and 1.0 M 2-methyltetrahydrofuran (2MeTHF) in CHF(FM)).

[0021] FIG. 5 shows the electrolyte pressure for various liquefied gas electrolyte solutions including electrolyte solution 1 (1.0 M LiTFSI and 1.0 M triethyl phosphate (TEP) in CHF(FM)), electrolyte solution 2 (1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in CHF(FM)) and electrolyte solution 3 (1.0 M LiTFSI and 1.0 M 2-methyltetrahydrofuran (2MeTHF) in CHF(FM)).

[0022] FIG. 6 shows the performance of two battery coin cells composed of a lithium metal anode and a lithium nickel-manganese-cobalt oxide (NMC622) cathode (the first cell used electrolyte 1 with 1.0 M LiTFSI and 1.0 M 2-methyltetrahydrofuran in CHF:CO at a molar ratio of 9:1, and the second cell used electrolyte 2 with 1.0 M LiTFSI and 1.0 M triethylphosphate in CHF:CO at a molar ratio of 9:1). The inset is the cycle spectrum of electrolyte 2.

[0023] FIG. 7 shows leakage current measurements of coin cells containing four different electrolytes at room temperature. The coin cells were constructed with a lithium metal negative electrode and a lithium nickel manganese cobalt oxide (NMC622) positive electrode. The four electrolytes had 1.0 M LiTFSI salt and 1.0 M additive in a 9 to 1 molar mixture of CH3F and CO2. The four additives tested were 2Me-tetrahydrofuran, dimethyl ether, trimethyl phosphate, and triethyl phosphate. DETAILED DESCRIPTION OF THE PRESENT EMBODIMENT

[0024] Reference is made herein to certain specific embodiments of the invention, including any best mode contemplated by the inventor for carrying out the invention. Examples of these specific embodiments are illustrated in the accompanying drawings. Although the invention has been described in connection with these specific embodiments, it will be understood that they are not intended to limit the invention to the embodiments described or illustrated. On the contrary, they are intended to cover alternatives, modifications, and equivalents that may be included within the spirit and scope of the invention as defined by the appended claims.

[0025] In the following description, numerous specific details are set forth to provide a thorough understanding of the present invention. Certain exemplary embodiments of the present invention may be implemented without some or all of these specific details. In other instances, process operations well known to those skilled in the art have not been described in detail so as not to unnecessarily obscure the present invention. Various techniques and mechanisms of the present invention will sometimes be described in a single form for clarity. However, it should be noted that some embodiments include multiple iterations of a technique or mechanisms unless otherwise noted. Thus, some implementations of the methods described herein may include more or fewer steps than shown or described. Furthermore, the techniques and mechanisms of the present invention may, in some cases, include more or fewer steps than shown or described. It should be noted that a connection or relationship between entities does not necessarily imply a direct, unobstructed connection.

[0026] It is known that certain additives can increase the solubility of salts in liquefied gas solvents. These additives have typically been ether or nitrile based (see PCT / US2019 / 032414). However, these additives have been shown through studies in electrochemical devices to reduce the voltage stability of the cell due to unexpected decomposition of such additives. In addition, these additives are highly flammable and can contribute to potential fire and safety hazards. Finally, some salts are believed to have low solubility with these ether or nitrile based additives and require a higher molar ratio of the additive to solubilize the salt. For example, 1M THF in fluoromethane is believed to fully solubilize 1M LiTFSI but not LiPF6 or LiFSI type salts. It would be highly preferable to find a high voltage stability additive with lower flammability, which could also increase the solubility of various salts with a lower additive to salt ratio. It is also important that the additive solubilize the salt and form a homogenous solution in the liquefied gas electrolyte without phase separation to maintain a high performance electrolyte.

[0027] It has been found through considerable experimentation with various additives that the disclosed additives meet the above requirements. For example, trimethyl phosphate has surprisingly been shown to maintain high voltage stability when used in batteries as an electrolyte additive. Thus, while individual electrolyte components may exhibit a particular voltage stability, mixing components into a complete electrolyte can often alter the voltage stability characteristics. Thus, it is also seen that these phosphates solubilize various salts at lower additive to salt ratios. As shown in Figure 7, it was impressive that trimethyl phosphate maintained a very high voltage stability. It is also seen that these phosphates solubilize various salts at lower additive to salt ratios. This indicates that the binding strength of the lithium cation in the liquefied gas solvent is strong and not as much additive is needed to dissolve a certain type or amount of salt. Furthermore, these phosphates significantly reduce the flammability of the disclosed liquefied gas electrolytes. This indicates that solutions with trimethyl phosphate and lithium-based salts in various liquefied gas solvents are uniformly dispersed without phase separation. This is important for the proper operation of the battery device. Previously, it was found that only electrolytes in which the additive has both good binding to the salt and good miscibility with the solvent do not undergo phase separation over a wide temperature range. However, electrolytes in which the additive is both well bound to the salt and well miscible with the solvent do not undergo phase separation over a wide temperature range. It was not previously apparent to those skilled in the art that phosphate type compounds (e.g., trimethyl phosphate or triethyl phosphate) would maintain these highly desirable qualities without experimentation, formulation, and study of these electrolyte compositions in battery devices.

[0028] An embodiment is an electrochemical device that includes an ionically conductive electrolyte having one or more additives, the ionically conductive electrolyte may be liquid, solid, or gaseous at standard pressure (about 1.01325 bar) and one or more salts, the one or more salts may be liquid, solid, or gaseous at standard room temperature of +20° C. and standard pressure (about 1.01325 bar).

[0029] The ionically conductive electrolyte of the preceding paragraph may also include a solution of one or more solvents. The one or more solvents may be selected from the group consisting of liquefied gas solvents, liquid solvents, or solid solvents. Those skilled in the art will appreciate that the term "solid solvent" refers to a solvent that is solid at room temperature and can form a liquid solution when mixed with another liquid or liquids. In some embodiments, the solution of one or more solvents may be a solution of one or more liquefied gas solvents. Each liquefied gas solvent solution is in a liquid-only phase or a gas-liquid mixed phase at standard room temperature of +20°C and standard pressure (about 1.01325 bar) while in a mechanically rigid container that contains the electrolyte. Due to the nature of high vapor pressure electrolytes, some liquid components of the electrolyte may be mixed with one or more vapor components in equal or unequal ratios, if the volume in the electrolyte housing allows. The one or more liquid components may be mixed with one or more vapor components in equal or unequal ratios in both liquid and vapor states. This mixing ratio may occur at any temperature or pressure. Any single component of the liquefied gas solvent may have a vapor pressure above atmospheric pressure at room temperature, but mixtures of any number of liquefied gas solvents, any number of additives, any number of solvents, and any number of salts may also reduce the vapor pressure of the complete solution to below atmospheric pressure at room temperature. Solutions of the above liquefied gas solvents may have vapor pressures above or below atmospheric pressure at room temperature.

[0030] The ionically conductive electrolyte may further include one or more additives (or additive components), which may be liquid, solid, or gaseous at standard room temperature of +20° C. and standard pressure (about 1.01325 bar). In one embodiment, the additive includes trimethyl phosphate in an equal molar ratio to the salt in a liquefied gas solvent solution such as fluoromethane with a LiTFSI salt. In another embodiment, the additive includes trimethyl phosphate in a 2:1 molar ratio of additive to lithium hexafluorophosphate (LiPF6) salt.

[0031] Some such embodiments of the electrochemical device may further include a housing that encloses the ion-conducting electrolyte and is structured to provide pressurized conditions for a solution of one or more salts and one or more solvents, such as a liquefied gas solvent, and a pair of electrodes in contact with the ion-conducting electrolyte.

[0032] In some embodiments, the ionically conductive electrolyte may include a lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt. In some such embodiments, the ionically conductive electrolyte may include a solution of one or more liquefied gas solvents including fluoromethane, difluoromethane, carbon dioxide, sulfuryl fluoride, or a combination thereof. In some such embodiments, the ionically conductive electrolyte may include one or more additives selected from the group consisting of organic phosphate esters. In some embodiments, the electrochemical device is an electrochemical energy storage device as described in PCT / US2014 / 066015, PCT / US2017 / 029821, PCT / US2019 / 032413, and PCT / US2019 / 032414, in some embodiments, the electrochemical device is a rechargeable battery or an electrochemical capacitor, in some embodiments, the rechargeable battery may be a lithium ion battery or a lithium metal battery. In some other embodiments, the battery is a sodium battery, a magnesium battery, an aluminum battery, a potassium battery, or a zinc battery. In other embodiments, the cell is an electrochemical capacitor device or a hybrid capacitor device.

[0033] Those skilled in the art will understand that the terms "one or more salts," "one or more solvents" (including "liquefied gas solvents" and "liquid solvents"), and "one or more additives" as used herein in connection with "ionically conductive electrolyte" refer to one or more electrolyte components.

[0034] In some embodiments, the ionically conductive electrolyte may be comprised of a solvent and a salt, the solvent further comprising only materials that are gaseous under standard conditions. In some embodiments, the materials comprised fluoromethane, difluoromethane, and carbon dioxide. In some embodiments, additional additives are used that provide beneficial uses such as those related to improved salt solubility, improved voltage stability, or low flammability. The embodiments relate to material additives that improve the solubility of the electrolyte salt components. Without such additives, the solubility of the salt may be limited. However, some additives that increase the solubility of the salt may result in low voltage stability. To maximize the energy contained within the battery device, high voltage stability is preferred. The additive also preferably has a low flammability component. Here, the additive may be treated as an additional component to the overall solvent solution. The additive may also limit the electrolytic conductivity of the electrolyte. By selecting a particular additive that exhibits good solubility, high electrolytic conductivity is obtained, which improves the performance of the cell device.

[0035] Disclosed herein are additives that can be used in liquefied gas electrolytes to improve salt solubility, electrolyte conductivity, and voltage stability. In some embodiments, the additives are used in combination with fluoromethane or difluoromethane as the primary solvent and a lithium-based salt. In some embodiments, other liquefied gas solvents, such as fluoromethane, difluoromethane, trifluoromethane, fluoroethane, tetrafluoroethane, pentafluoroethane, 1,1-difluoroethane, 1,2-difluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, pentafluoroethane, chloromethane, chloroethane, thionyl fluoride, thionyl fluoride chloride, phosphoryl fluoride, phosphoryl fluoride chloride, sulfuryl fluoride, sulfuryl fluoride chloride, 1-fluoropropane, 2-fluoropropane, 1,1-difluoropropane, 1,2-difluoroethane ... The liquefied gas solvent may be fluoropropane, 1,1,1-trifluoropropane, 1,1,2-trifluoropropane, 1,2,2-trifluoropropane, fluoroethylene, cis-1,2-fluoroethylene, 1,1-fluoroethylene, 1-fluoropropylene, 2-propylene, chlorine, chloromethane, bromine, iodine, ammonia, methylamine, dimethylamine, trimethylamine, molecular oxygen, molecular nitrogen, carbon monoxide, or in combination with these additives, carbon dioxide, sulfur dioxide, dimethyl ether, methyl vinyl ether, difluoroethylene, nitrous oxide, nitrogen dioxide, carbon disulfide, hydrogen fluoride, hydrogen chloride, or any combination thereof. In some embodiments, the liquefied gas solvent may be difluoromethane. In some embodiments, the liquefied gas solvent may be chloromethane. In some embodiments, the liquefied gas solvent may be fluoromethane. In some embodiments, the liquefied gas solvent may be 1,1-difluoroethane. In some embodiments, the liquefied gas solvent may be sulfuryl fluoride. In some embodiments, the liquefied gas solvent can be thionyl chloride or thionyl fluoride.In some embodiments, the liquefied gas solvent can be selected from the group consisting of fluoromethane, difluoromethane, sulfuryl fluoride, chloromethane, carbon dioxide, 1,1-difluoroethane, and any combination thereof. In some embodiments, the liquefied gas electrolyte comprises a single liquefied gas solvent or a combination of liquefied gas solvents, and one or more additives and one or more salts. These additives may be gaseous, liquid, or solid at standard room temperature +20°C and standard pressure (about 1.01325 bar). Additionally, any of the gaseous additives can be used as the primary solvent. In some embodiments, the amount of the primary solvent or mixture of primary solvents is greater than about 10%, about 20%, about 30%, about 40%, about 50%, about 60%, about 70%, about 80%, about 90%, about 95%, about 98%, or about 99% based on the total weight of the liquefied gas electrolyte. In some embodiments, the amount of the first solvent is less than about 99%, about 98%, about 95%, about 90%, about 80%, about 70%, about 60%, about 50%, about 40%, about 30%, or about 20% by weight based on the total weight of the liquefied gas electrolyte. In some embodiments, the amount of the additive is less than about 80%, about 70%, about 60%, about 50%, about 40%, about 30%, about 20%, about 10%, about 5%, about 2%, or about 1% based on the total weight of the liquefied gas electrolyte.

[0036] In some embodiments, the liquefied gas solvent consists of two solvents. In some embodiments, the liquefied gas solvent consists of three solvents. In some embodiments, the liquefied gas solvent consists of four or more solvents. In some embodiments, the liquefied gas solvent consists of fluoromethane, sulfuryl fluoride, and carbon dioxide. In some embodiments, the liquefied gas solvent consists of fluoromethane and carbon dioxide. In some embodiments, the liquefied gas solvent comprises difluoromethane and carbon dioxide. In some embodiments, the liquefied gas solvent consists of sulfuryl fluoride and carbon dioxide. In some embodiments, the liquefied gas electrolyte consists of fluoromethane, difluoromethane, and carbon dioxide. In some embodiments, the liquefied gas solvent comprises a halogenated hydrocarbon and a sulfuryl halide. In some embodiments, the liquefied gas solvent consists of a halogenated hydrocarbon, a sulfuryl halide, and carbon dioxide. In some embodiments, the molar ratio of additive to salt is greater than about 0.01, about 0.05, about 0.1, about 0.2, about 0.30, about 0.5, about 0.7, about 0.9, about 0.95, about 0.98, about 1.0, about 1.05, about 1.1, about 1.5, about 2, about 3, about 5, about 10 or about 100. In some embodiments, having a low molar concertation additive compared to the salt, such as about 0.9, about 0.95, or about 0.98, is preferred to ensure that the majority of the additive material in the electrolyte is generally bonded or coordinated with the ions in the electrolyte, thus increasing the electrochemical stability of the cell. It is important to note that additive or solvent molecules that are bonded to the salt generally increase voltage stability from interaction with the salt, enhancing overall cell performance. Therefore, it is important to ensure the bonding of the additive to the salt by properly managing the molar ratio of both in the electrolyte solution.In some embodiments, the molar ratio of additive to salt is less than 0.8, less than 0.85, less than 0.9, less than 0.95, less than 0.98, less than 0.99, less than 1.0, less than 1.1, less than 1.2, less than 1.3, less than 1.4, less than 1.5, less than 1.6, less than 1.7, less than 1.8, less than 1.9, less than 2.0, less than 2.1, less than 2.2, less than 2.3, less than 2.4, less than 2.5, less than 2.6, less than 2.7, less than 2.8, less than 2.9, less than 3.0. In some embodiments, the molar ratio of additive to salt is less than about 0.8, about 0.85, about 0.9, about 0.95, about 0.98, about 0.99, about 1.0, about 1.1, about 1.2, about 1.3, about 1.4, about 1.5, about 1.6, about 1.7, about 1.8, about 1.9, about 2.0, about 2.1, about 2.2, about 2.3, or about 2.4. In some embodiments, the molar ratio of additive to salt is within the range of about 0.5 to about 1.0, about 0.8 to about 0.98, about 0.9 to about 1.0, about 0.9 to about 0.98, about 1 to about 1.5, about 1.5 to about 2, about 2 to about 2.5, about 1.9 to about 2.1, or about 2 to about 2.2. In some embodiments, having a high molar concentration of additive to salt, such as a ratio of about 1.1, about 1.2, or about 2.0, may be advantageous to ensure maximum solubility of the salt for improved performance. In some embodiments, multiple additives are used, each of which may have a molar ratio with the salt of greater than about 0.01, about 0.05, about 0.1, about 0.2, about 0.30, about 0.5, about 0.7, about 0.9, about 0.95, about 0.98, about 1.0, about 1.05, about 1.1, about 1.5, about 2, about 3, about 5, about 10, or about 100. In some embodiments, the salt concentration in the electrolyte solution is greater than about 0.1, about 0.3, about 0.5, about 0.8, about 1.0, about 1.3, about 1.5, about 1.8, about 2.0, about 3.0, about 4.0, about 5.0, or about 8.0 moles per liter of solution.

[0037] In some embodiments, the liquefied gas electrolyte can include one or more additives. In some embodiments, the liquefied gas electrolyte can include one additive. In some embodiments, the liquefied gas electrolyte can include two or more additives. In some embodiments, the additive can be an acyclic carbonate, a cyclic carbonate, an acyclic ether, a cyclic ether, a nitrile compound, an organic phosphate ester, or any combination thereof. In some embodiments, the one or more additives comprise trimethyl phosphate. In another embodiment, the one or more additives comprise triethyl phosphate.

[0038] In one embodiment, the additive may be an organophosphate compound. TIFF0007640824000001.tif36167

[0039] In the formula, R1, R2, and R3 may be any group consisting of hydrogen, fluorine, methyl, ethyl, propyl, butyl, pentyl, hexyl, phenyl, allyl, dimethylamide, diethylamide, and any combination thereof.

[0040] In an exemplary electrochemical device using a liquefied gas electrolyte composed of one or more liquefied gas components and one or more liquid components, one or more solid components, or one or more salt components, the electrodes are composed of any combination of two electrodes of interlayer type (e.g., graphite, carbon, activated carbon, lithium titanate, titanium disulfide, molybdenum disulfide, lithium iron phosphate, lithium cobalt phosphate, lithium nickel phosphate, lithium cobalt oxide, lithium nickel manganese oxide, lithium nickel manganese cobalt oxide, nickel cobalt aluminum oxide), any combination of electrodes (e.g., sulfur, acid, carbon dioxide, nitrogen, nitrous oxide, sulfur dioxide, thionyl fluoride, thionyl fluoride chloride, sulfuryl fluoride, sulfuryl fluoride chloride), or any combination of metal electrodes having lithium, sodium, magnesium, tin, aluminum, zinc, or alloys containing lithium, sodium, tin, magnesium, aluminum, zinc, or any combination thereof. These components may be combined with a variety of binder polymer components, including polyvinylidene fluoride, carboxymethyl cellulose, styrene-butadiene rubber, or polytetrafluoroethylene, to maintain the structural integrity of the electrode.

[0041] Additionally, the one or more liquefied gas solvent solutions or electrolytes may be selected from the group consisting of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4), lithium hexafluoroarsenate (LiAsF6), lithium tetrachloroaluminate (LiAlCl4), lithium salts, lithium bis(oxalato)borate (LiBOB), lithium hexafluorostannate, lithium difluoro(oxalato)borate (LiDFOB), lithium bis(fluorosulfonyl)imide (LiFSI), lithium aluminum fluoride (LiAlF3), lithium nitrate (LiNO3), lithium chloroaluminate, lithium tetrafluoroborate ... and may be combined with one or more salts including one or more of lithium tetrafluoroborate (LiFSI), lithium tetrafluoro(oxalato)phosphate, lithium difluorobis(oxalato)phosphate, lithium chloride, lithium bromide, lithium iodide, lithium carbonate, lithium fluoride, lithium oxide, lithium hydroxide, lithium nitride, lithium superoxide, lithium azide, delta tellurite, dilithium squarate, croconate dihydrate, dilithium rhodizonate, lithium oxalate, dilithium ketomalonate, lithium diketosuccinate, or any corresponding salt having a positively charged lithium cation in place of sodium or magnesium, or any combination thereof.Further useful salts include tetramethylammonium, tetraethylammonium, tetrapropylammonium, tetrabutylammonium, triethylmethylammonium, spiro-(1,1')-bipyrrolidinium, 1,1-dimethylpyrroly 1-octylpyrrolidinium, 1-methyl-1-pentylpyrrolidinium, or N-methylpyrrolidinium paired with negatively charged anions such as acetate, bis(fluorosulfonyl)imide, bis(oxalato)borate, bis(trifluoromethanesulfonyl)imide, bromide, chloride, dicyanamide, diethyl phosphate, hexafluorophosphate, hydrogen sulfate, iodide, methanesulfonate, methyl-phosphonate, tetrachloroaluminate, tetrafluoroborate, and trifluoromethanesulfonate. EXAMPLES

[0042] Example 1 Battery coin cells were assembled consisting of a lithium metal anode and a lithium nickel-manganese-cobalt oxide (NMC622) cathode. The electrolyte was 1.0 M LiTFSI and 1.0 M triethyl phosphate (TEP) in a 9 to 1 molar mixture of fluoromethane (CH3F) and carbon dioxide (CO2). The cells were cycled at a 1c rate to various charge voltages of 4.2, 4.3, 4.4, and 4.5 V. The cell performance is shown in Figure 1.

[0043] Example 2 Battery coin cells were assembled consisting of a lithium metal anode and a lithium nickel-manganese-cobalt oxide (NMC622) cathode. The electrolyte was 1.0 M LiFSI and 1.2 M triethyl phosphate (TEP) in a 9 to 1 molar ratio mixture of CH3F and CO2. The cells were cycled at a 1c rate to various charge voltages of 4.2, 4.3, 4.4, and 4.5 V. The cell performance is shown in Figure 2.

[0044] Example 3 Battery coin cells were assembled consisting of a lithium metal anode and a lithium nickel-manganese-cobalt oxide (NMC622) cathode. The electrolyte was 1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in a 9 to 1 molar mixture of fluoromethane (CH3f) and carbon dioxide (CO2). The cells were cycled at a 1c rate to various charge voltages of 4.2, 4.3, 4.4, and 4.5 V. The cell performance is shown in Figure 3.

[0045] Example 4 Electrolytic conductivity measurements were performed on three electrolyte solutions. Electrolyte 1 contained 1.0 M LiTFSI and 1.0 M triethyl phosphate (TEP) in fluoromethane (CH3F, FM), and electrolyte 2 contained 1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in fluoromethane (CH3F, FM). Electrolyte 1 contained 1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in fluoromethane (CH3F, FM), and electrolyte 2 contained 1.0 M LiTFSI and 1.0 M 2-methyltetrahydrofuran (2MeTHF) in fluoromethane (CH3F, FM). As shown in Figure 4, the solutions containing the organophosphate additive were more conductive than the 2MeTHF additive.

[0046] Example 5 Electrolyte pressure measurements were performed on three different electrolyte solutions. Electrolyte 1 contained 1.0 M LiTFSI and 1.0 M triethyl phosphate (TEP) in fluoromethane (CH3F, FM), electrolyte 2 contained 1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in fluoromethane (CH3F, FM), and electrolyte 3 contained 1.0 M LiTFSI and 1.0 M trimethyl phosphate (TMP) in fluoromethane (CH3F, FM). It can be seen that the mixture of salts and additives had little effect on the total pressure of the liquefied gas electrolyte or pure fluoromethane solvent between the different electrolytes. The pressure data is shown in Figure 5.

[0047] Example 6 Two battery coin cells were assembled consisting of a lithium metal anode and a lithium nickel-manganese-cobalt oxide (NMC622) cathode. The first cell used electrolyte 1 with 1.0 M LiTFSI and 1.0 M 2-methyltetrahydrofuran in CH3F:CO2 at a molar ratio of 9:1. The second cell used electrolyte 2 with 1.0 M LiTFSI and 1.0 M triethylphosphate in CH3F:CO2 at a molar ratio of 9:1. The cells were cycled at a 1-C rate to various charge voltages of 4.2, 4.3, 4.4, and 4.5 V. There is an obvious capacity drop for electrolyte 1 due to the poor stability of this additive. Electrolyte 2 maintains stability even at high charge voltages. Cell performance data is shown in Figure 6.

[0048] Example 7 Four coin cells using different electrolytes were assembled and the leakage current was measured as a function of voltage at room temperature. Higher leakage current indicates faster decomposition of the electrolyte additive or poor voltage stability. The coin cells consisted of a lithium metal negative electrode and a lithium nickel manganese cobalt oxide (NMC622) positive electrode. The four electrolytes had 1.0 M LiTFSI salt and 1.0 M additive in a 9 to 1 molar ratio mixture of CH3F and CO2. The four additives tested were 2Me-tetrahydrofuran, dimethyl ether, trimethyl phosphate, and triethyl phosphate. The performance of these cells is shown in Figure 7. Trimethyl phosphate and triethyl phosphate have excellent stability at increased voltages of 4.4 V and 4.5 V, while the ether-based additives were unexpectedly found to have poor stability at these voltages. This surprising result could only be determined from experimentation, that through the combination of the liquefied gas solvent and additive, a unique chemistry was formed that creates a surface-electrolyte-interphase (SEI) on the cathode surface, which allows for exceptional stability even at high voltages. The combination of the liquefied gas solvent and additive created a unique chemistry that creates a surface-electrolyte-interphase (SEI) on the cathode surface, which allows for exceptional stability even at high voltages. The low leakage currents further reinforce this fact. Figures 6 and 7 reinforce these findings. These unexpected results with the phosphate compound additive are far superior to the previously disclosed ether type additives.

[0049] Example 8 A stainless steel cell with a glass window containing various electrolytes was assembled. Through this window, the solubility of the salts in the various electrolyte formulations can be seen. Table 1 below shows the observed solubilities for the various electrolytes. Trimethyl phosphate and triethyl phosphate were unexpectedly found to have excellent solubility for the various salts in fluoromethane. It is important to note that frequent phase separation exists in various combinations of liquefied gas solvents, additives, and salts. An ideal additive would exhibit good affinity or binding for the salt and high compatibility with the solvent system. These combinations generally result in mixtures with high solubility for the salt and no phase separation over a wide temperature range. On the other hand, ethers and carbonates tested with various salts do not exhibit such a unique combination of properties. The unexpected performance of the phosphate compounds can only be determined by experimentation, which led to these surprising discoveries.

[0050] [Table 1]

[0051] Although exemplary embodiments and applications of the invention have been described herein, including those described above and shown in the included exemplary figures, it is not intended that the invention be limited to these exemplary embodiments and applications or to the manner in which the exemplary embodiments and applications operate or are described herein. Indeed, many variations and modifications to the exemplary embodiments are possible, as will be apparent to those skilled in the art. The invention may include any device, structure, method, or functionality so long as the resulting device, system, or method falls within the scope of one of the claims allowed by the Patent Office on this patent application or any related patent application.

Claims

1. a compressed gas solvent having a vapor pressure of more than 100 kPa at room temperature of 293.15 K and consisting of fluoromethane or difluoromethane; A lithium salt; an additive consisting of trimethyl phosphate and / or triethyl phosphate; An ion-conducting electrolyte comprising:

2. 2. The ion-conducting electrolyte of claim 1, wherein the molar ratio of the additive to the lithium salt is in the range of 0.01 to 10.

3. The lithium salts include lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium hexafluorophosphate (LiPF ６ ), lithium perchlorate (LiClO ４ ), lithium hexafluoroarsenate (LiAsF ６ ), lithium tetrachloroaluminate (LiAlCl ４ ), lithium tetragallium aluminate, lithium bis(oxalato)borate (LiBOB), lithium hexafluorostannate, lithium difluoro(oxalato)borate (LiDFOB), lithium bis(fluorosulfonyl)imide (LiFSI), lithium aluminum fluoride (LiAlF ３ ), lithium nitrate (LiNO ３ ), lithium chloroaluminate, lithium tetrafluoroborate (LiBF ４ ), lithium tetrachloroaluminate, lithium difluorophosphate, lithium tetrafluoro(oxalato)phosphate, lithium difluorobis(oxalato)phosphate, lithium borate, lithium oxoacid, lithium thiocyanate, lithium tetrachlorogallate, lithium chloride, lithium bromide, lithium iodide, lithium carbonate, lithium fluoride, lithium oxide, lithium hydroxide, lithium nitride, lithium superoxide, lithium azide, delta tellurite, dilithium squarate, lithium croconic acid dihydrate, dilithium rhodizonate, lithium oxalate, dilithium ketomalonate, or lithium diketosuccinate.

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