Oily stick cosmetic preparation and its manufacturing method

Abstract

The present invention aims to provide an oily stick-shaped cosmetic which has excellent qualities such as the speed of secondary adhesion prevention effect, color retention, and smooth spreadability, while suppressing separation during the cosmetic production process and exhibiting excellent releasability during filling. The method for producing an oily stick-type cosmetic composition that solves the problems of the present invention comprises the following components (A) to (E); (A) Wax (B) Kinematic viscosity at 25°C is 20 to 10,000 mm 2 / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains the mass ratio of the component (B) to the component (C), (B) / (C), is 0.5 to 3.0; The method for producing an oily stick-type cosmetic preparation comprises the following steps 1 to 4. Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110°C, and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3.

Description

[Technical field]

[0001] The present invention relates to an oily stick-type cosmetic preparation and a method for producing the same. [Background technology]

[0002] The main effects required for oil-based stick-type cosmetics are, for example, lip cosmetics that give a color to the lips and give a healthy impression through the color, and cosmetics that give a three-dimensional effect to the mouth and make them stand out beautifully. In addition, ease of use when applying to the lips is also a very important factor in finishing an ideal cosmetic film. In particular, the surface of the lips is soft and it is difficult to apply cosmetics to the lips, so it is required that the cosmetics spread smoothly and easily when applied. In addition to these qualities, in recent years, the number of opportunities to put on and take off masks has increased from the perspective of preventing infectious diseases, and a secondary adhesion-free effect that prevents the cosmetics from physically adhering to other substances is required, and among them, lip cosmetics that can quickly exert a secondary adhesion-free effect after the cosmetics are applied to the lips are very popular. When the secondary adhesion-free effect is exerted, the silicone oil in the cosmetic application film separates to the upper layer after the lip cosmetics are applied and coats the surface of the cosmetic application film, thereby exerting the effect.

[0003] To date, a lip cosmetic has been proposed that combines hydrogenated polyisobutene, one or more types of methylphenyl silicone that separate when mixed with hydrogenated polyisobutene at 25°C, a lipophilic surfactant that does not separate when mixed with either of the above two types at 90°C, and a specific amount of wax, which has an excellent secondary adhesion-resistant effect immediately after application, maintains shine after application, and is also highly stable (see, for example, Patent Document 1).

[0004] In addition, a method has been proposed that includes a step of combining a first fluid containing one or more solid oily components at 25°C with a second fluid containing one or more components that are incompatible with the components contained in the first fluid inside a vibration-type stirring mixer or immediately before said device to obtain a mixed liquid, thereby enabling the stable production of oil-based solid cosmetics containing incompatible or unstable components (see, for example, Patent Document 2). [Prior art documents] [Patent documents]

[0005] [Patent Document 1] JP 2011-140481 A [Patent Document 2] JP 2015-124204 A DISCLOSURE OF THEINVENTION [Problem to be solved by the invention]

[0006] However, when the separation speed of the cosmetic coating film is increased to quickly exert the secondary adhesion-free effect, separation is likely to progress during the manufacturing process of the oil-based stick-type cosmetic, resulting in a non-uniform cosmetic. In addition, when color retention and secondary adhesion-free properties are simultaneously achieved, releasability may deteriorate when molding into a stick shape. Therefore, there has been a demand for an oil-based stick-type cosmetic that has excellent qualities in terms of color retention, smooth spreadability, and the speed of the secondary adhesion-free effect, while suppressing separation during the cosmetic manufacturing process and having excellent releasability when filled. For example, as in the technology of Patent Document 1, there has been an idea to maintain quality by combining materials that prevent layer separation of oily agents that tend to separate, but the speed at which the secondary adhesion-reducing effect occurs is slow, and no oil-based cosmetic products with excellent noticeable effects have been developed. In addition, for example, as in Patent Document 2, there have been efforts in the past to use a vibration-type stirring and mixing device to mix a component contained in a first fluid with a second fluid containing one or more incompatible components, but there was no focus on the issue of separating the component from the colorant, nor was there any focus on solving the problem by devising the order of addition of the colorant.

[0007] In other words, an object of the present invention is to provide a method for producing an oily stick-shaped cosmetic preparation that has excellent quality in terms of color retention, smooth spreadability, and speed of secondary adhesion-free effect, while suppressing separation during the cosmetic preparation production process and having excellent releasability when filled. [Means for solving the problem]

[0008] In view of the above circumstances, the present inventors have conducted extensive research. As a result, it has been found that the kinematic viscosity of the wax at 25° C. is in the range of 20 to 10,000 mm 2 / s, non-volatile silicone oil, non-volatile liquid ester oil, colored powder, and polyhydric alcohol, and has a kinetic viscosity of 20 to 10,000 mm at 25°C. 2 The inventors have discovered that by producing an oil-based stick-type cosmetic composition having a mass ratio of non-volatile silicone oil (N / s) to non-volatile liquid ester oil of 0.5 to 3.0, or a method for producing the same, in a specific process, it is possible to obtain a cosmetic composition having excellent quality in terms of color retention, smooth spreadability, and speed of secondary adhesion-free effect, while suppressing separation of ingredients during the production process and providing excellent releasability during filling, and have thus completed the present invention.

[0009] That is, the present invention provides the following method for producing an oily stick-type cosmetic preparation. [1] The following components: (A)~(E); (A) Wax (B) Kinematic viscosity at 25°C is 20 to 10,000 mm 2 / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains the mass ratio of the component (B) to the component (C), (B) / (C), is 0.5 to 3.0; A method for producing an oily stick-type cosmetic preparation, comprising the steps of: A method for producing an oily stick-type cosmetic preparation comprising the following steps 1 to 4: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110°C, and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3. [2] The method for producing an oily stick-type cosmetic preparation according to [1], wherein the component (B) is one or more selected from (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane. [3] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the content of the component (E) is 0.05 to 1.5% by mass. [4] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the component (C) contains (C1) a non-volatile liquid ester oil having a viscosity of less than 1,000 mPa s at 25°C and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa s or more at 25°C. [5] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], further comprising adding a volatile oil as component (F) in step 1 and / or step 2. [6] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the step 2 is the step (2-1). [7] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the dispersion treatment in step 2 is a high shear dispersion treatment. [8] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the container into which the cosmetic composition is filled in step 3 is a rubber mold or a metal mold.

[0010] The present invention also provides the following oily stick-type cosmetic preparation. [9] The following components: (A)~(E); (A) Wax (B) Kinematic viscosity at 25°C is 20 to 10,000 mm2 / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains The mass ratio (B) / (C) of the component (B) to the component (C) is 0.5 to 3.0, Steps 1 to 4 below: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110°C, and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3. The oily stick-shaped cosmetic preparation is obtained by a production method comprising the steps of:

[10] The oily stick-type cosmetic preparation according to [9], wherein the content of the component (B) is 25 to 55 mass %.

[11] The oily stick-shaped cosmetic preparation according to [9] or

[10] , wherein the component (B) comprises (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane.

[12] The oily stick-type cosmetic preparation according to [9] or

[10] , wherein the component (C) is one or more selected from (C1) a polyglycerol fatty acid ester having a viscosity of less than 1,000 mPa s at 25°C and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa s or more at 25°C.

[13] The oily stick-type cosmetic preparation according to [9] or

[10] , wherein the average kinetic viscosity ratio of the component (B1) to the component (B2), (B1) / (B2), is 1 to 250.

[14] The oil-based stick-type cosmetic preparation according to [9] or

[10] , wherein the component (C) comprises one or more selected from (C1) polyglyceryl-2 triisostearate, and (C2) (VP / hexadecene) copolymer, and dimer dilinoleyl bisisostearyl dimer dilinoleate.

[15] The oily stick-type cosmetic preparation according to [9] or

[10] , wherein the component (E) is one or more selected from the group consisting of 1,3-butylene glycol, dipropylene glycol, 1,2-hexanediol, glycerin and tripropylene glycol.

[16] The oily stick-type cosmetic preparation according to [9] or

[10] , further comprising a volatile oil as component (F). Effect of the Invention

[0011] The present invention can provide an oil-based stick-shaped cosmetic preparation that is excellent in color retention, smooth spreadability, and secondary adhesion resistance, suppresses separation of ingredients during the production process, and has excellent releasability when filled. BEST MODE FOR CARRYING OUT THEINVENTION

[0012] Preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments, and can be freely modified within the scope of the present invention. In this specification, percentages are expressed by mass unless otherwise specified. In addition, in this specification, when a numerical range is expressed using "~", the range includes both ends of the numerical range.

[0013] The melting point in the present invention is defined as the melting point (Tm) defined as the peak top of the peak observed on the highest temperature side of the melting endothermic curve measured by using a differential scanning calorimeter (DSC) by holding a sample at -10°C for 5 minutes under a nitrogen atmosphere and then heating at a rate of 10°C / min.

[0014] In the present invention, the viscosity at 25°C (mPa·s) = (CSt: centistokes) is calculated by filling a measurement sample into a glass bottle with an outer diameter of 45 mm, an inner diameter of 38 mm, and a height of 82 mm without leaving any air spaces, covering it, and leaving it in a thermostatic chamber at 25°C for a whole day and night.Then, using a single-cylinder rotational viscometer Vismetron (registered trademark) (manufactured by Shibaura Systems Co., Ltd.) (B-type viscometer) with the attached rotors No. 1 to 4, the measurement value after 1 minute was read at 0.3 to 30 rpm, and multiplied by the respective multipliers. Viscosity indicates the difficulty of an object moving in a fluid, while kinetic viscosity (mm 2 / s) represents the difficulty of the fluid itself to move, and the factors that affect this difficulty are the density of the object and the kinetic viscosity (mm 2 / s) = viscosity (mPa s) / density.

[0015] The wax component (A) in the present invention is not limited to origins such as animal, vegetable, or synthetic, as long as it is one that is usually used in cosmetics, and any of them can be used. For example, hydrocarbon waxes (A1) such as polyethylene wax, paraffin wax, ceresin wax, ozokerite wax, microcrystalline wax, hydrogenated microcrystalline wax, Fischer-Tropsch wax, (ethylene / propylene) copolymer, and synthetic wax; wax esters (A2) such as hard lanolin, carnauba wax, beeswax, stearyl stearate, montan wax, hydrogenated jojoba oil, behenyl behenate, candelilla wax, sunflower seed wax, and rice bran wax; and silicone waxes such as long-chain alkoxy-modified silicone and long-chain alkyl-modified silicone (e.g., stearyl dimethicone, etc.), and one or more of these can be used in combination. From the viewpoints of releasability during filling, color retention, prevention of separation during the manufacturing process, and speed improvement of the secondary adhesion-free effect, it is preferable to use the hydrocarbon wax (A1) and the wax ester (A2) in combination.

[0016] Among the components (A) in the present invention, from the viewpoints of mold releasability during filling and smooth spreading, (A1) the hydrocarbon wax is preferably polyethylene wax, paraffin wax, synthetic wax, etc. Also, (A1) has a melting point of preferably 65° C. or higher, more preferably 80° C. or higher, and even more preferably 90° C. or higher. Also, from the viewpoints of mold releasability during filling and smooth spreading, (A2) the wax ester is preferably candelilla wax, carnauba wax, or beeswax, more preferably candelilla wax or carnauba wax, and even more preferably candelilla wax.

[0017] When (A1) and (A2) are used in combination as component (A), the mass ratio (A1) to (A2), (A1) / (A2), is preferably at least 0.2 in terms of its lower limit, more preferably at least 1, and even more preferably at least 4. The upper limit is preferably at most 40, more preferably at most 15, and even more preferably at most 8. The range is preferably from 0.2 to 40, more preferably from 1 to 15, and even more preferably from 4 to 8. This range is particularly preferable in terms of color retention and prevention of separation of the components during processing.

[0018] The content of component (A) in the present invention is preferably 3% by mass (hereinafter abbreviated as %) or more, more preferably 4.5% or more, and even more preferably 5% or more, based on the total amount of the oil-based stick-type cosmetic preparation. The upper limit is preferably 12% or less, more preferably 9% or less, and even more preferably 8% or less. The range is preferably 3 to 12%, more preferably 4.5 to 9%, and even more preferably 5 to 8%. This range is more preferable in terms of releasability during filling, smooth spreading, speed of secondary adhesion-free effect, and color retention.

[0019] The component (B) used in the present invention has a kinetic viscosity at 25°C of 20 to 10,000 mm 2The non-volatile silicone oils in / s are not limited to those that are generally used in cosmetics and are not solid at room temperature, regardless of the manufacturing method, degree of polymerization, or whether they are mixtures. For example, chain silicone oils such as dimethylpolysiloxane and methylphenylpolysiloxane, high molecular weight silicones such as amino-modified silicones and highly polymerized dimethylpolysiloxane, polyether-modified silicones such as polyoxyethylene-modified organopolysiloxane and polyoxyethylene-polyoxypropylene-modified organopolysiloxane, amino-modified silicones such as amodimethicone, fatty acid-modified polysiloxane, higher alcohol-modified polysiloxane, alkyl-modified polysiloxane, and other modified silicones can be mentioned. One or more of these can be appropriately selected and used as component (B).

[0020] The component (B) in the present invention has a kinetic viscosity at 25°C of 20 to 10,000 mm 2 The non-volatile silicone oil having a viscosity of 1 / s is not particularly limited, but from the viewpoints of releasability during filling, color retention, prevention of separation during the manufacturing process, and speed improvement of the secondary adhesion-free effect, it is preferable to use (B1) methylphenyl polysiloxane and (B2) dimethyl polysiloxane in combination. Examples of (B1) include trimethylsiloxyphenyl dimethicone, trimethylpentaphenyl trisiloxane, diphenyl dimethicone, phenyl trimethicone, and diphenyl siloxyphenyl trimethicone. Among these, from the viewpoints of releasability during filling and speed of the secondary adhesion-free effect, diphenyl dimethicone, trimethylsiloxyphenyl dimethicone, and phenyl trimethicone are preferred, diphenyl dimethicone and trimethylsiloxyphenyl dimethicone are more preferred, and diphenyl dimethicone is even more preferred. In addition, from the viewpoints of speed of the secondary adhesion-free effect, color retention, and smooth spreadability, the kinetic viscosity is 10,000 mm 2 / s or less, and 1,000 mm 2 / s or less is preferable, and 50 mm 2 / s or less is even more preferable.

[0021] When (B1) and (B2) are used in combination as component (B), the lower limit of the content mass ratio (B1) to (B2), (B1) / (B2), is preferably 1 or more, more preferably 2 or more, and even more preferably 3 or more. The upper limit is preferably 10 or less, more preferably 6 or less, and even more preferably 5 or less. The range is preferably 1 to 10, more preferably 2 to 6, and even more preferably 3 to 5. This range is more preferable in terms of releasability during filling, speed of secondary adhesion-free effect, and prevention of separation during the manufacturing process. The average kinetic viscosity ratio (B1) / (B2) of (B1) to (B2) contained in the component (B) used in the present invention is not particularly limited, but the lower limit is preferably 1 or more, more preferably 3 or more, and even more preferably 20 or more. The upper limit is preferably 250 or less, more preferably 200 or less, and even more preferably 100 or less. The range is preferably 1 to 250, more preferably 3 to 200, and even more preferably 20 to 100. This range is more preferable in terms of the speed of the secondary adhesion-less effect. In this specification, the average kinetic viscosity ratio (B1) / (B2) means the ratio of the value obtained by multiplying the kinetic viscosity value of (B1) by the content of (B1) in the cosmetic composition to the value obtained by multiplying the kinetic viscosity value of (B2) by the content of (B2) in the cosmetic composition.

[0022] The content of component (B) in the present invention is preferably 25% or more, more preferably 35% or more, and even more preferably 40% or more, based on the total amount of the oil-based stick-type cosmetic preparation. The upper limit is preferably 55% or less, more preferably 47% or less, and even more preferably 45% or less. The range is preferably 25 to 55%, more preferably 35 to 47%, and even more preferably 40 to 45%. This range is more preferable in terms of releasability during filling, smooth spreading, speed of secondary adhesion-free effect, and color retention.

[0023] The content mass ratio (A) / (B) of component (A) to component (B) used in the present invention is preferably 0.07 or more, more preferably 0.1 or more, and even more preferably 0.12 or more. The upper limit is preferably 0.29 or less, more preferably 0.22 or less, and even more preferably 0.2 or less. The range is 0.07 to 0.29, more preferably 0.1 to 0.22, and even more preferably 0.12 to 0.2. This range is more preferable in terms of releasability during filling, smooth spreading, speed of secondary adhesion-free effect, and color retention.

[0024] The mass ratio (B1) / (A2) of the component (B1) to the component (A2) used in the present invention is preferably 5 or more, more preferably 10 or more, and even more preferably 17 or more. The upper limit is preferably 340 or less, more preferably 70 or less, and even more preferably 42 or less. The range is 5 to 340, more preferably 10 to 70, and even more preferably 17 to 42. This range is more preferable in terms of the speed of the secondary adhesion-free effect, smooth spreading, and releasability during filling.

[0025] The non-volatile liquid ester oil (C) used in the present invention is not particularly limited as long as it is not solid at room temperature and is liquid to paste-like, as is commonly used in cosmetics. Regardless of the production method, degree of polymerization, whether it is a mixture, etc., examples of the non-volatile liquid ester oil include those in which a fatty acid is ester-bonded with an alcohol, those in which a fatty acid is ester-bonded with a polyhydric alcohol, those in which a carboxyl group of an amino acid is ester-bonded with an alcohol, and dimer acid and / or dimer diol diesters. The non-volatile liquid ester oil, component (C), in the present invention is not particularly limited, but it is preferable to use a combination of (C1) a non-volatile liquid ester oil with a viscosity of less than 1,000 mPa s and (C2) a non-volatile liquid ester oil with a viscosity of 1,000 mPa s or more, and of these, from the viewpoints of releasability during filling, color retention, prevention of separation during the production process, rapid improvement of the secondary adhesion-free effect, and smooth spreadability, it is more preferable that (C2) is a non-volatile liquid ester oil with a viscosity of 10,000 mPa s or more.

[0026] Specific examples of the component (C) non-volatile liquid ester oil in the present invention include (C1) non-volatile liquid ester oils having a viscosity of less than 1,000 mPa s, such as ester oils in which a fatty acid and an alcohol are ester-bonded, such as isopropyl palmitate, isopropyl myristate, isopropyl stearate, isobutyl stearate, 2-ethylhexyl stearate, isopropyl isostearate, butyl isostearate, decyl isostearate, lauryl isostearate, isodecyl isodecanoate, isodecyl isononanoate, isotridecyl isononanoate, isononyl isononanoate, diethyl sebacate, cetyl 2-ethylhexanoate, ethylhexyl palmitate, octyldodecyl myristate, oleyl oleate, and ethyl oleate. Examples of ester oils in which fatty acids and polyhydric alcohols are ester-bonded include neopentyl glycol dioctanoate, propylene glycol dicaprate, propylene glycol dicaprylate, glyceryl tri-2-ethylhexanoate, polyglyceryl-2 noisostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, etc. Among these, from the viewpoint of smooth spreading and the speed of secondary adhesion-free effect, it is preferable to use a polyglycerin fatty acid ester having 1 to 10 fatty acid bonds as (C1), preferably a polyglycerin fatty acid ester having 2 to 4 fatty acid bonds, and more preferably a polyglycerin fatty acid ester having 2 to 3 fatty acid bonds. Specific examples include polyglyceryl-2 monoisostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, etc. Furthermore, (C2) non-volatile liquid ester oils of 1,000 mPa s or more include ester oils in which fatty acids and alcohols are ester-bonded, such as diisostearyl malate, and ester oils in which fatty acids and polyhydric alcohols are ester-bonded, such as pentaerythrityl fatty acid esters, such as dipentaerythrityl pentaisostearate, dipentaerythrityl hexa(behenic acid / benzoic acid / ethylhexanoic acid), and dipentaerythrityl hexa(hydroxystearic acid / stearic acid / rosin acid). Specific examples of oil agents that are copolymers of vinyl compounds having amide groups and vinyl compounds having alkyl groups include (VP / hexadecene) copolymers. Specific examples of ester oils in which the carboxyl group of an amino acid and an alcohol are ester-bonded include N-lauroyl-glutamic acid, di(phytosteryl / 2-octyldodecyl) acid, N-lauroyl-glutamic acid, di(phytosteryl / behenyl / 2-octyldodecyl) acid, N-lauroyl-glutamic acid, di(cholesteryl / 2-octyldodecyl) acid, N-lauroyl-glutamic acid, di(cholesteryl / behenyl / 2-octyldodecyl) acid, and N-lauroyl-sarcosine-isopropyl. The diester of dimer acid and / or dimer diol refers to a diester of dimer acid obtained by dimerizing mono- or di-unsaturated fatty acid and then hydrogenating it as necessary with various alcohols, a diester of dimer diol obtained by reducing dimer acid with various fatty acids, an ester of dimer acid and dimer diol, etc., and examples thereof include dimer dilinoleate di(phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleate di(isostearyl / phytosteryl), dimer dilinoleate dilinoleyl, dimer dilinoleate diisostearate dimer dilinoleyl, etc. Among them, component (C2) is preferably a nonvolatile liquid ester oil of 10,000 mPa·s or more, and more preferably a copolymer of a vinyl compound having an amide group and a vinyl compound having an alkyl group, and an ester of dimer acid and dimer diol.

[0027] The viscosity of (C1) of component (C) in the present invention is preferably from 50 to less than 1,000 mPa s, more preferably from 50 to 750 mPa s, and even more preferably from 50 to 600 mPa s, from the viewpoints of the speed of the secondary adhesion-free effect, prevention of separation during the production process, and smooth spreadability. The viscosity of (C2) of the component (C) in the present invention is preferably 10,000 mPa·s to 15,000 mPa·s from the viewpoints of the speed of the secondary adhesion-free effect, color retention, and prevention of separation of the components during processing.

[0028] When (C1) and (C2) are used in combination as component (C), the mass ratio (C1) / (C2) of (C1) to (C2) is preferably 0.1 or more as a lower limit, more preferably 0.2 or more, and even more preferably 0.3 or more. The upper limit is preferably 1.4 or less, more preferably 0.85 or less, and even more preferably 0.7 or less. The range is preferably 0.1 to 1.4, more preferably 0.2 to 0.85, and even more preferably 0.3 to 0.7. This range is more preferable in terms of releasability during filling, speed of secondary adhesion-free effect, color retention, and prevention of separation of components during processing. The content of component (C) in the present invention is preferably 15% or more, more preferably 22% or more, and even more preferably 25% or more, based on the total amount of the oily stick-type cosmetic preparation. The upper limit is preferably 42% or less, more preferably 38% or less, and even more preferably 36% or less. The range is preferably 15 to 42%, more preferably 22 to 38%, and even more preferably 25 to 36%. This range is more preferable in terms of the speed of the secondary adhesion-free effect and color retention.

[0029] The content mass ratio (B) / (C) of component (B) to component (C) used in the present invention is 0.5 or more, preferably 1 or more, more preferably 1.2 or more, and even more preferably 1.3 or more. The upper limit is 3.0 or less, preferably 2.8 or less, and more preferably 2.1 or less, and even more preferably 1.8 or less. The range is 0.5 to 3.0, preferably 1 to 2.8, more preferably 1.2 to 2.1, and even more preferably 1.3 to 1.8. This range is more preferable in terms of releasability during filling, smooth spreading, speed of secondary adhesion-free effect, and color retention.

[0030] The mass ratio of the total content of components (A) and (C) to component (B) used in the present invention [(A)+(C)] / (B) is preferably 0.5 or more, more preferably 0.6 or more, and even more preferably 0.7 or more. The upper limit is preferably 2.3 or less, more preferably 1.3 or less, and even more preferably 1 or less. The range is preferably 0.5 to 2.3, more preferably 0.6 to 1.3, and even more preferably 0.7 to 1.0. This range is more preferable in terms of color retention and releasability.

[0031] The colored powder of component (D) used in the present invention may be any powder normally used in cosmetics, and may be inorganic or organic, with no particular limitation on the hue. For example, metal oxides such as titanium oxide, zinc oxide, cerium oxide, iron oxide, titanium-titanium oxide sinter, chromium oxide, chromium hydroxide, Prussian blue, ultramarine, etc., organic pigment powders such as Red No. 201, Red No. 202, Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, etc., Black No. 401, Brown No. 201, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 203, Blue No. 205, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Green No. 401, Green No. 402, Examples of organic dyes include zirconium, barium or aluminum lakes such as Yellow No. 4, Yellow No. 5, Yellow No. 202(1), Yellow No. 202(2), Yellow No. 203, Yellow No. 402, Yellow No. 403(1), Yellow No. 406, Yellow No. 407, Orange No. 205, Orange No. 402, Red No. 2, Red No. 3, Red No. 102, Red No. 104(1), Red No. 105(1), Red No. 106, Red No. 227, Red No. 230(1), Red No. 231, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506, etc. Other examples include white inorganic powders such as talc, mica, sericite, silicic acid anhydride, synthetic phlogopite, kaolin, silicon carbide, bentonite, smectite, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth, glass powder, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, and barium sulfate; organic polymer resin powders such as polyethylene resins, polyester resins, fluorine resins, cellulose resins, copolymer resins such as styrene-acrylic copolymer resins, polypropylene resins, and nylon powder; organic low molecular weight powders such as metal soap powders and N-acyl lysine; starch powders such as acrylic starch and rice starch; natural organic powders such as silk powder, cellulose powder, and dextrin powder; silicone powder, polymethyl methacrylate powder, polystyrene powder, and urethane powder.Among these, metal oxides or organic pigments are preferred, with iron oxide, Red No. 202, and Red No. 201 being preferred, and Red No. 202 being more preferred from the viewpoint of color retention, etc. Also, from the viewpoint of smooth spreading and color retention, white inorganic body powders and natural organic powders are preferred. In particular, among the white inorganic body powders, silicic anhydride, calcium carbonate, mica, sericite, synthetic phlogopite, and barium sulfate are more preferred, and among the natural organic powders, cellulose powder and starch powder are more preferred. The colored powder, component (D), used in the present invention may be surface-treated with a commonly known treating agent such as a phospholipid, an amino acid, an amino acid derivative, a ceramide, a dextrin derivative, a silicone compound, a fatty acid metal salt, a fluorine compound, or a surfactant.

[0032] The content of component (D) in the present invention is preferably 0.01% or more, more preferably 1.25% or more, and even more preferably 1.5% or more, as a lower limit, based on the total amount of the oil-based stick-type cosmetic preparation. The upper limit is preferably 10% or less, more preferably 6% or less, and even more preferably 3% or less. The range is preferably 0.01 to 10%, more preferably 1.25 to 6%, and even more preferably 1.5 to 3%. This range is more preferable in terms of smooth spreading, speed of secondary adhesion-free effect, color retention, and prevention of separation during the manufacturing process.

[0033] The mass ratio (C) / (D) of component (C) to component (D) used in the present invention is preferably 3 or more, more preferably 7 or more, and even more preferably 11 or more. The upper limit is preferably 32 or less, more preferably 25 or less, and even more preferably 20 or less. The range is 3 to 32, more preferably 7 to 25, and even more preferably 11 to 20. This range is more preferable in terms of color retention.

[0034] The mass ratio (C2) / (D) of component (C2) to component (D) used in the present invention is preferably 1.0 or more, more preferably 2.5 or more, and even more preferably 3 or more. The upper limit is preferably 20 or less, more preferably 10 or less, and even more preferably 7 or less. The range is 1.0 to 20, more preferably 2.5 to 10, and even more preferably 3 to 7. This range is more preferable in terms of color retention and prevention of separation during the production process.

[0035] The polyhydric alcohol of component (E) used in the present invention is a glycol having a structure with two or more hydroxyl groups in the molecule, and more preferably a glycol having 3 to 12 carbon atoms. There are no particular limitations as long as it is one that is normally used in cosmetics and the like, but specific examples include methylene glycol, glycol (ethylene glycol), propylene glycol, propanediol (1,3-propanediol), diethylene glycol, methylenepropanediol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, 2,3-butanediol, 1,2-pentanediol, 1,3-pentanediol, 1,4-pentanediol, 1,5-pentanediol, 2,4-pentanediol, 1,2-cyclopentanediol, 1,3-cyclopentanediol, 1,4-cyclopentanediol, 1,5-cyclo ... Examples of the polyglycerin include pentanediol, neopentyl glycol, isopentyl diol, aminoethyl propanediol, 1,2-hexanediol, 1,6-hexanediol, triethylene glycol, dipropylene glycol, butoxydiglycol, dipropylene glycol, ethyl hexanediol, butyl ethyl propanediol, 1,10-decanediol, glycerin, trimethylolethane, trimethylolbutane, 1,2,6-hexanetriol, phytantriol, sorbitol, erythritol, pentaerythritol, diglycerin, and polyglycerin. Examples of the polyglycerin include polyoxyethylene methyl glucoside, polyethylene glycol, and polyglycerin. In particular, in the case of glycols containing polyethylene glycol chains, the degree of polymerization is preferably 20 or less, but is not particularly limited. In the case of polyglycerin, the degree of polymerization is preferably 3 to 10, but is not particularly limited.

[0036] The component (E) used in the present invention is not particularly limited, but is preferably 1,3-butylene glycol, dipropylene glycol, 1,2-hexanediol, glycerin, or tripropylene glycol, more preferably dipropylene glycol or 1,2-hexanediol, and even more preferably dipropylene glycol.

[0037] The content of component (E) used in the present invention is preferably 0.05% or more, more preferably 0.2% or more, and even more preferably 0.25% or more, based on the total amount of the oily stick-type cosmetic preparation. The upper limit is preferably 1.5% or less, more preferably 0.8% or less, and even more preferably 0.5% or less. The range is preferably 0.05 to 1.5%, more preferably 0.2 to 0.8%, and even more preferably 0.25 to 0.5%. This range is more preferable in terms of the speed of the secondary adhesion-free effect and color retention.

[0038] Furthermore, in the present invention, it is preferable to use a volatile oil as component (F). The volatile oil is not particularly limited as long as it is volatile at 1 atmospheric pressure and 25°C and is normally used in cosmetics, and specifically, the volatile hydrocarbon oil includes light liquid isoparaffin, and the volatile silicone oil includes decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, ethyltrisiloxane, etc. Here, the light liquid isoparaffin is not limited to those used as the solubility standard and can be used. As commercially available products, examples of light liquid isoparaffin include Isopar H (manufactured by Esso Chemical Co., Ltd.), isododecane (manufactured by Bayer), isohexadecane (manufactured by Uniqema Co., Ltd.), IP Solvent 1620MU, IP Solvent 2028MU, and IP Solvent 2835 (all manufactured by Idemitsu Kosan Co., Ltd.). Examples of decamethylcyclopentasiloxane include TFS405 (manufactured by Toshiba Silicone Co., Ltd.), SH245, DC345 (manufactured by Toray Dow Corning Co., Ltd.), and KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.). Examples of methyltrimethicone include Silicone TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.). Examples of methylpolysiloxane include KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.), and examples of decamethyltetrasiloxane include KF-96L-1.5CS (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0039] The component (F) used in the present invention is not particularly limited, but in terms of the speed of the secondary adhesion-resisting effect and color retention, a volatile hydrocarbon oil is preferred, and further, the use of light liquid isoparaffin is more preferred.

[0040] The content of component (F) used in the present invention is, based on the total amount of the oily stick-type cosmetic preparation, preferably 1% or more, more preferably 2% or more, and even more preferably 4% or more as a lower limit. The upper limit is preferably 15% or less, more preferably 12% or less, and even more preferably 10% or less. The range is preferably 1 to 15%, more preferably 2 to 12%, and even more preferably 4 to 10%. This range is more preferable in terms of smooth spreading, color retention, and prevention of separation during the manufacturing process.

[0041] In the present invention, from the viewpoint of color retention and smooth spreading, it is more preferable to contain one or more of the following resins having a skeleton derived from plants (G) and plant-extracted resins. Although not particularly limited, examples of the resins include dextrin-based resins such as dextrin isostearate, which is a parent material derived from plants; examples of plant-extracted resins obtained by fractionating resins from plants include oil-soluble resins such as candelilla resin and carnauba wax extract resin, and one or more of these can be used. Examples of commercially available products include candelilla resins E-1 and E-2 (manufactured by Nippon Natural Products Co., Ltd.), TOWAX-1B4 (manufactured by Toa Kasei Co., Ltd.), and Unifilma HVY (manufactured by Chiba Flour Mills Co., Ltd.).

[0042] The content of component (G) that may be used in the present invention is not particularly limited, but is preferably 0.1% or more, more preferably 0.3% or more, and even more preferably 0.5% or more, based on the total amount of the oily stick-type cosmetic preparation. It is also preferably 30% or less, more preferably 20% or less, and even more preferably 8% or less. It is also preferably 0.1 to 30%, more preferably 0.3 to 20%, and even more preferably 0.5 to 8%. This range is preferable because it provides excellent color retention and smooth spreadability.

[0043] In addition to the above-mentioned components (A) to (G), the oily stick-shaped cosmetic preparation of the present invention may contain components that are usually used in cosmetics, such as oily components other than the components (B), (C), and (F), surfactants, fibers, alcohols, oily solidifying agents other than the component (A), water-soluble polymers, resinous film-forming agents other than (G), aqueous components such as moisturizers other than component (E), sugars, antioxidants, antifoaming agents, cosmetic ingredients, preservatives other than component (E), fragrances, etc., within the range that does not impair the effects of the present invention.

[0044] The oily stick-shaped cosmetic preparation of the present invention can be produced by the following method. Specifically, the method includes a step of dissolving component (A) at a temperature equal to or higher than the melting point thereof, and then components (C) and (D) are uniformly mixed at a temperature equal to or higher than the melting point of component (A), and then component (B) is added to the mixture, which is then filled into a container, but is not limited to this manufacturing method. As for the preferred steps, the manufacturing method is a method for manufacturing an oily stick-type cosmetic preparation having the following steps 1 to 4, and specifically, Step 1: melting the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D); Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) a step of adding the component (B) to the mixture obtained in the step 1, and dispersing the mixture at 30 to 110°C to obtain a cosmetic composition; (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: Cooling the cosmetic composition filled in the container obtained in step 3. The temperature in step 1 is not particularly limited as long as it is equal to or higher than the melting point of component (A), but for example, 70 to 130°C is preferred, and 80 to 110°C is more preferred. In step 1, components (B) and (C) may be mixed with component (A) separately, but it is preferred to mix components (C) and (D) in advance and then add and mix with component (A). This process is preferred because it provides excellent color retention, smooth spreadability, and secondary adhesion resistance. Thus, in step 1, it is necessary to mix components (A), (C), and (D), and if component (D) is not added in step 1, for example, it may be inferior in terms of preventing separation in the process. The equipment used in the dispersion treatment of the mixture in step (2-1) of step 2, the further dispersion treatment after adding component (B), and the dispersion treatment after adding component (B) to the mixture in step (2-2) is not particularly limited as long as it is a dispersion equipment usually used in the production of cosmetics, but examples thereof include media dispersers such as Henschel mixers, kneaders, bead mills and ball mills, media-less nano high pressure dispersers, stone mill grinders, roll mills, homogenizers, Ajidespa, triple mixers, ultra mixers, high viscosity mixers, and other equipment utilizing self-rotation and revolution, and media dispersers such as bead mills and ball mills, media-less nano high pressure dispersers, stone mill grinders, and roll mills are preferred. Among these, high shear dispersion treatment using equipment that performs high shear dispersion treatment is preferred. As equipment that performs high shear dispersion treatment, media dispersers such as bead mills and ball mills, media-less nano high pressure dispersers, stone mill grinders, roll mills, and equipment utilizing self-rotation and revolution are more preferred. Such a process is preferable because it provides excellent color retention and smooth spreadability. It is important that the oily stick cosmetic of the present invention has a high rate of manifestation of the secondary adhesion-free effect, but it is also important that after application of the oily stick cosmetic, component (B) rapidly separates onto the surface of the applied film, and the phase containing components (A), (C), and (D) rapidly moves to the vicinity of the skin. However, if the components are separated during the process, this affects the smooth spreading during use, the releasability during filling, and the stability over time, so it is preferable that they are mixed more uniformly during the process, and it is preferable to devise a method in step 2 in order to simultaneously satisfy the opposing effects. Specifically, step (2-1) is a step of adding component (B) at a specific temperature into the oil phase in which component (D) has been uniformly dispersed in advance, and component (B) is mixed evenly afterwards, but step (2-1) is preferable from the viewpoint of preventing separation during the process. The temperature at which component (B) is added in step (2-1) is 30 to 110°C, preferably 60 to 110°C, and more preferably 60 to 90°C. This range is preferable because it does not promote re-aggregation of the oil phase components containing component (D) due to poor compatibility between component (B) and other components, the secondary adhesion-free effect is achieved quickly, and it is possible to prevent separation of the components during processing and achieve releasability.In step (2-1), the temperature at which the mixture obtained in step 1 is dispersed is from 5 to 80°C, and more preferably from 10 to 60°C. Component (E) may be added, mixed or dispersed in either step 1 or step 2, or in both steps 1 and 2, but adding and mixing in step 1 is preferred because it provides better color retention and smoother spreadability. When component (F) is used, it may be added, mixed or dispersed in either step 1 or step 2, or in both steps 1 and 2, but adding and mixing in step 2 is preferred because it provides better smoother spreadability. Regarding the container in step 3, it is possible to fill the oil-based stick-type cosmetic preparation into a rubber molded container, a metal molded container, a plastic container, etc., but a rubber molded container or a metal molded container is preferred, and a rubber molded container is more preferred. This step is preferred because it provides excellent releasability when filling the oil-based stick-type cosmetic preparation and excellent stability over time. In addition, there is no limitation on the inclusion of components other than those described in each step. In step 4, the cosmetic composition filled in the container in step 3 is cooled and solidified. The temperature is not particularly limited, but is, for example, about -20 to 0°C.

[0045] The oily stick cosmetic composition of the present invention is not particularly limited as long as it is solid, and can be used for lip cosmetics such as lipstick and lip gloss, foundation, concealer, eyeliner, eye color, blush, etc. In particular, the good color retention and smooth spreadability of the oily stick cosmetic composition of the present invention make it suitable for use in lip cosmetics, which are often applied to the lips by smoothly applying to soft areas that are frequently moved on a daily basis.

[0046] The present invention can also adopt the following configuration. [1] The following components: (A)~(E); (A) Wax (B) Kinematic viscosity at 25°C is 20 to 10,000 mm 2 / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains the mass ratio of the component (B) to the component (C), (B) / (C), is 0.5 to 3.0; A method for producing an oily stick-type cosmetic preparation, comprising the steps of: A method for producing an oily stick-type cosmetic preparation comprising the following steps 1 to 4: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110°C, and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3. [2] The method for producing an oily stick-type cosmetic preparation according to [1], wherein the component (B) is one or more selected from (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane. [3] The method for producing an oily stick-type cosmetic preparation according to [1] or [2], wherein the content of the component (E) is 0.05 to 1.5% by mass. [4] The method for producing an oily stick-type cosmetic preparation according to any one of [1] to [3], wherein the component (C) contains (C1) a non-volatile liquid ester oil having a viscosity of less than 1,000 mPa s at 25°C and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa s or more at 25°C. [5] The method for producing an oily stick-type cosmetic preparation according to any one of [1] to [4], further comprising adding a volatile oil as component (F) in step 1 and / or step 2. [6] The method for producing an oily stick-type cosmetic preparation according to any one of [1] to [5], wherein the step 2 is the step (2-1). [7] The method for producing an oily stick-type cosmetic preparation according to any one of [1] to [6], wherein the dispersion treatment in step 2 is a high shear dispersion treatment. [8] The method for producing an oily stick-type cosmetic preparation according to any one of [1] to [7], wherein the container into which the cosmetic composition is filled in the step 3 is a rubber mold or a metal mold. [9] The following components: (A)~(E); (A) Wax (B) Kinematic viscosity at 25°C is 20 to 10,000 mm 2 / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains The mass ratio (B) / (C) of the component (B) to the component (C) is 0.5 to 3.0, Steps 1 to 4 below: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) A step of dispersing the mixture obtained in the step 1 at 5 to 80°C, and further adding and dispersing the component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110°C, and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3. The oily stick-shaped cosmetic preparation is obtained by a production method comprising the steps of:

[10] The oily stick-type cosmetic preparation according to [9], wherein the content of the component (B) is 25 to 55 mass %.

[11] The oily stick-shaped cosmetic preparation according to [9] or

[10] , wherein the component (B) comprises (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane.

[12] The oily stick-type cosmetic preparation according to any one of [9] to

[11] , wherein the component (C) is one or more selected from (C1) a polyglycerol fatty acid ester having a viscosity of less than 1,000 mPa s at 25°C and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa s or more at 25°C.

[13] The oily stick-type cosmetic preparation according to any one of [9] to

[12] , wherein the average kinetic viscosity ratio of the component (B1) to the component (B2), (B1) / (B2), is 1 to 250.

[14] The oily stick-type cosmetic preparation according to any one of [9] to

[13] , wherein the component (C) comprises one or more selected from (C1) polyglyceryl-2 triisostearate, and (C2) (VP / hexadecene) copolymer, and dimer dilinoleyl bisisostearyl dimer dilinoleate.

[15] The oily stick-type cosmetic preparation according to any one of [9] to

[14] , further comprising one or more components selected from the group consisting of 1,3-butylene glycol, dipropylene glycol, 1,2-hexanediol, glycerin, and tripropylene glycol.

[16] The oily stick-shaped cosmetic preparation according to any one of [9] to

[15] , further comprising a volatile oil as component (F). EXAMPLES

[0047] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples. Examples 1 to 47 and Comparative Examples 1 to 4: Oil-based stick lipstick Stick-type lipsticks having the formulations shown in Tables 1 to 5 below were prepared by Production Method 1, and (a) the speed of secondary adhesion-free effect, (b) color retention, (c) smoothness of spread, (d) prevention of separation during processing, and (e) releasability were evaluated by the evaluation methods described below.

[0048] [Table 1] *1 CIREWAX90 (manufactured by CIREBELLE) *2 CIREWAX80 (manufactured by CIREBELLE) *3 CB303 (SONNEBORN) *4 Refined Candelilla Wax SR-3 (Nippon Natural Products) *5 TOWAX 1F-6 (manufactured by Toa Chemical Industries, Ltd.) *6 WHITE BEES WAX (Made by Miki Chemical) *8 KF-54 (Shin-Etsu Chemical Co., Ltd.)

[0049] [Table 2] *9 BELSIL PDM 1000 (manufactured by Wacker Asahi Kasei) *10 DOWSILSH 556 Fluid (Toray Dow)

[0050] [Table 3]

[0051] [Table 4]

[0052] [Table 5] *7 Leopard KL2 (manufactured by Chiba Flour Mills)

[0053] 《Manufacturing method》 (Manufacturing method 1) (Ingredients with no ingredient number listed are not included.) Step 1: a. Components (1) to (7) (component (A) and others) are homogeneously dissolved at a temperature of 80 to 110°C, which is equal to or higher than the melting point. b. Mix and disperse components (15) to (22) (component (C)) and components (24) to (25) (component (D)). Add b to ca, and then add component (23) and components (26) to (28) (component (E)), and heat and mix at 80 to 110°C. Process 2(2-1): dc is mixed and dispersed uniformly using a roll mill at 10℃ to 60℃. Components (8) to (14) (component (B) and others) and component (29) (component (F)) are added to ed, and the mixture is heated and mixed at 80°C. (Cosmetic composition) Step 3: The fe is poured into a lipstick rubber mold (12Φ) container while stirring at a temperature of at least 100°C, which is higher than the melting point of (component (A) and others). Step 4: gf was cooled to -10°C to obtain an oily stick lipstick.

[0054] Examples 1-2 to 1-12 The oil-based stick-shaped lipsticks shown in Table 6 below were prepared using manufacturing methods 2 to 12, and were evaluated for (a) the speed of secondary adhesion-free effect, (b) color retention, (c) smooth spreading, (d) prevention of separation during processing, and (e) releasability using the evaluation methods described below, and compared with those of Example 1 (manufacturing method 1).

[0055] [Table 6]

[0056] 《Manufacturing method》 (Manufacturing method 2) In the process of (production method 1), step 1:b "Add components (15) to (22) (component (C)), components (24) to (25) (component (D)), components (26) to (28) (component (E)), and component (23) to ba and mix at 110°C." It was manufactured in a different process.

[0057] (Manufacturing method 3) In the process of (Production Method 1), step 2(2-1):e "Add components (8) to (14) (component (B) and others) and component (29) (component (F)) to ed and heat and mix at 110°C (cosmetic composition)." It was manufactured in a different process.

[0058] (Manufacturing method 4) In the process of (Production Method 1), step 2(2-1):e "Add components (8) to (14) (component (B) and others) and component (29) (component (F)) to ed and heat and mix at 30°C (cosmetic composition)." It was manufactured in a different process.

[0059] (Manufacturing method 5) In the process of (production method 1), step 1:c Add b to ca, then add component (23) and components (26) to (28) (component (E)), heat and mix at 110°C, add component (29) (component (F)), and heat and mix at 70°C. e. The step of adding component (29) (component (F)) was deleted from the process. It was manufactured in a different process.

[0060] (Manufacturing method 6) In the process of (Production Method 1), step 2(2-1):e "Add components (8) to (14) (component (B) and others) to ed, heat and mix at 80°C, add component (29) (component (F)), and mix at 40°C (cosmetic composition)." It was manufactured in a different process.

[0061] (Manufacturing method 7) In the process of (Production Method 1), step 2(2-1):e "Components (8) to (14) (component (B) and others) and component (29) (component (F)) are added to ed, component (E) is omitted from the addition in step c., and the mixture is transferred to step e., where it is heated and mixed at 80°C. (Cosmetic composition)." It was manufactured in a different process.

[0062] (Manufacturing method 8) In the process of (production method 1), step 3:f "Fe is poured into a 12φ stainless steel container made of lipstick mold while stirring at a temperature 100°C or higher, which is higher than the melting point of (component (A) and others)." It was manufactured in a different process.

[0063] (Manufacturing method 9) In the process of (production method 1), step 3:f "Fe is mixed into a 12φ capsule container made of PP material for lipstick while stirring at a temperature of 100°C or higher, which is higher than the melting point of (ingredient (A) and other ingredients)." It was manufactured in a different process.

[0064] (Manufacturing method 10) In the process of (Production Method 1), step 2(2-1):d "Mix and disperse dc uniformly at 10℃~60℃ using a high viscosity mixer." It was manufactured in a different process.

[0065] (Manufacturing method 11) In the step of (Production Method 1), Step 1: c "Add b to ca, then add component (23) and components (26) to (28) (component (E)), heat and mix at 110°C." Step 2 (2-2): d, [d. Components (8) to (14) (component (B) and others) are added and mixed by heating at 80°C. The mixture is uniformly mixed and dispersed using a roll mill at 10°C to 60°C.] Delete the step of adding components (8) to (14) (component (B) and others) from step (d) in step (e), "e. Add component (29) (component (F)) and heat and mix at 80°C. (Cosmetic composition)" It was manufactured in a different process.

[0066] (Manufacturing method 12) In the step of (Production Method 1), Step 1: c "Add b to ca, further add component (23) and components (26) to (28) (component (E)), heat and mix at 110°C, add component (29) (component (F)), and heat and mix at 80°C." Step 2 (2-2): d, [d. Components (8) to (14) (component (B) and others) are added and mixed by heating at 80°C. The mixture is uniformly mixed and dispersed at 10°C to 60°C using a roll mill (cosmetic composition)] It was manufactured by replacing the process with one that eliminated e.

[0067] (Evaluation method) (a) Speed ​​of secondary adhesion effect (b) Color retention (C) Smooth spread A panel of 12 cosmetic evaluation experts conducted a usability test for each sample for the following items (A) to (C). Each panel member used the oily stick lipstick of the Example and Comparative Example, and rated and scored it on a 5-point scale according to the absolute evaluation criteria below. The average score for each sample was calculated from the total scores of all panel members, and the sample was judged according to the following criteria. (A) Regarding the speed of the secondary adhesion-free effect, each sample was applied to the lips and wiped off with a tissue one minute later, and judged for whether or not it was felt that secondary adhesion was suppressed; (B) Regarding color retention, each sample was applied to the lips and whether or not it was felt that the color retention was maintained after 8 hours; and (C) Regarding smooth spreadability, whether or not each sample spread smoothly when applied to the lips.

[0068] <Evaluation items> (a) Speed ​​of secondary adhesion effect (b) Color retention (C) Smooth spread

[0069] <Absolute evaluation criteria> (Score):(Evaluation) 5: Very good 4: Good 3: Neither 2: Bad 1: Very bad <Five-level evaluation criteria> (Judgment): (Evaluation) AA: 4.5 or higher A: 4.0 points or more and less than 4.5 points B: 3.5 points or more and less than 4.0 points C: 3.0 points or more and less than 3.5 points D: Less than 3.0 points

[0070] (2) Prevention of separation during the process As for prevention of separation during the process, the separation immediately before filling was evaluated by dissolving the stick-shaped cosmetic preparations of the above Examples and Comparative Examples at 110°C, filling 50 g of the preparation into a cylindrical glass bottle with a diameter of 4 cm and a height of 8 cm, and observing the state after leaving it to stand for 10 minutes while continuing to apply heat, and judging according to the following criteria. These evaluations enable verification of the separation behavior of the oil and coloring material during the actual manufacturing process. (In-process separation prevention judgment criteria) (Judgment): (Evaluation) AA: No oil separation or uneven coloring observed in cosmetics A: The color of the cosmetic is slightly uneven and separated, but it can be homogenized by shaking once. Becoming One B: The cosmetic has uneven color and separation, but it becomes homogenous after shaking twice. R C: Separation was observed in the cosmetic material and it was not uniform even after shaking twice. D: A lot of separation has occurred in the cosmetic material.

[0071] (e) Release property Regarding the releasability, each sample after being molded into a rod shape was unwound to the end and the appearance was visually evaluated according to the following criteria. (Mold releasability criteria) (Judgment): (Evaluation) AA: Almost no peeling, cracks, breaks, or chips (percentage of appearance) is less than 2.5%) A: Slight peeling or chipping is observed (percentage of appearance) is 2.5-5% or less) B: Both peeling and chipping are observed (occupying 2.5-5% of the appearance) below) C: Peeling or chipping is clearly visible, but there is little effect on usability. However, the level is unacceptable in terms of the appearance quality of the product (the (The percentage of people with HIV infection is less than 5-10%) D: Significant peeling, cracks, breaks, or chips are observed, affecting usability. Bell (occupies 10% or more of the appearance)

[0072] As is clear from the results in Tables 1 to 5, the oily stick lipsticks of Examples 1 to 47 of the present invention were superior in color retention, smooth spread, speed of secondary adhesion-free effect, prevention of separation in processing, and releasability, compared to the oily stick lipsticks of Comparative Examples 1 to 4. On the other hand, Comparative Example 1, which did not contain component (A), lacked color retention, smooth spreading, secondary adhesion-free effect speed, and releasability, and was therefore unsatisfactory. Moreover, in Comparative Example 2, which did not contain component (B), color retention, smooth spreading, secondary adhesion-free effect speed, and releasability were lacking, and a satisfactory product was not obtained. Moreover, in Comparative Example 3, which did not contain the component (C), the color retention, smooth spreading, secondary adhesion-free effect speed, and releasability were lacking, and a satisfactory result was not obtained. Furthermore, in Comparative Example 4, which did not contain the component (E), the smooth spreading and the speed of the secondary adhesion-free effect were lacking, and a satisfactory result was not obtained.

[0073] As is clear from the results in Table 6, the oily stick lipsticks of Examples 1 and 1-8 of the present invention were far superior in color retention, smooth spreading, secondary adhesion-free effect speed, in-process separation prevention, and releasability compared to the oily stick lipsticks of Examples 1-2 to 1-7 and 1-9 to 1-12. In particular, Example 1 also had a desirable surface pattern. In Example 1-2 of Production Method 2, since components (C) and (D) were not brought into contact with each other in advance, there was a tendency for color retention to be slightly reduced, but the product was extremely excellent in terms of smooth spreading, the speed of the secondary adhesion-free effect, prevention of separation during processing, and releasability. In Examples 1-3 of Production Method 3, because the temperature at which component (B) was added was high, the fluidity of the product produced in Step 1 increased and the viscosity decreased, making components (B) and (D) more likely to come into contact with each other and making separation during the process a little easier. However, the product was extremely excellent in color retention, smooth spreadability, speed of the secondary adhesion-free effect, and releasability. In Examples 1-4 of Production Method 4, because the temperature at which component (B) was added was low, the viscosity of the product produced in step 1 was high, and component (B) was difficult to mix. Since the component (B) was not mixed uniformly, separation was somewhat likely to occur during the process, and smooth spreadability tended to decrease slightly. However, the product was extremely excellent in color retention, the speed of the secondary adhesion-free effect, and releasability. In Examples 1-5 of Production Method 5, component (F) is added in step 1 rather than step 2. Although there was a tendency for smooth spreading to decrease slightly, the color retention, the speed of the secondary adhesion-free effect, the prevention of separation during processing, and the releasability were excellent. In Examples 1-6 of Production Method 6, the temperature at which component (F) is added in step 2 is lowered. As the viscosity of the previous composition increases, component (F) is less likely to be mixed uniformly, and there is a slight tendency for the continuous wax crystal structure of components (A) to (E) to be destroyed. However, the results were excellent in terms of color retention, the speed of the secondary adhesion-free effect, and prevention of separation during the process. In Examples 1-7 of Manufacturing Method 7, component (E) was added from step 1 to step 2. Although the color retention effect was slightly reduced due to contact between components (D) and (E), the product was extremely excellent in terms of smooth spreading, the speed of the secondary adhesion-free effect, prevention of separation during processing, and releasability. In Examples 1-9 of Manufacturing Method 9, the container was changed in step 3. Although this affected the smooth spreading due to the release properties, the color retention, the speed of the secondary adhesion-free effect, and the prevention of separation during the process were excellent. Examples 1-10 of Manufacturing Method 10 used different dispersion equipment in Step 2. Although color retention was slightly affected by the influence of component (D), the smooth spreading, the speed of the secondary adhesion-free effect, the prevention of separation during the process, and the releasability were excellent. In Examples 1-11 and 1-12 of Production Method 11, since component (B) is added beforehand and then dispersed in Step (2-2) instead of in Step (2-1) where component (B) is added later in Step 2, the dispersed component (D) is expelled by component (B) during dispersion, which tends to promote separation within the process and may also affect releasability. Furthermore, Example 1-12 of Production Method 12, in which component (F) is added before Step 2, also tends to reduce color retention and smooth spreadability, but the speed of the secondary adhesion-free effect was maintained.

[0074] Example 48: Oil-based stick eye shadow Ingredients (%) (1) Polyethylene wax (melting point 90°C) *12 6 (2) Carnauba wax (melting point 85°C)*5 0.5 (3) Candelilla wax (melting point 72°C)*4 1 (4) Diphenyl dimethicone (viscosity: 400cs (kinetic viscosity) *1.08(density)mPa s)*8 28 (5) Dimethylpolysiloxane (Viscosity: 100cs (kinetic viscosity) *0.97 (density) mPa s) 3 (6) Dimethylpolysiloxane (Viscosity: 20cs (Kinematic viscosity) *0.97 (density) mPa s) 6 (7) Polyglyceryl-2 triisostearate (Viscosity 550mPa·s) 15 (8) Dimer dilinoleyl bisisostearyl dimer dilinoleate (Viscosity 12,500mPa·s) 10 (9) Vanillyl butyl ether 0.1 (10) Mineral oil remaining (11) Cellulose powder 0.2 (12) Olive fruit oil 0.1 (13) Jojoba seed oil 0.1 (14) Sesame seed oil 0.1 (15) Red No. 202 1.5 (16) Yellow No. 4 1 (17) Blue No. 1 0.5 (18) Red iron oxide 0.5 (19) Yellow iron oxide 0.5 (20) Black iron oxide 0.5 (21) Polyglyceryl-2 tetraisostearate (2% surface treatment) Titanium mica (interference color: blue, average particle size 40μm) 6 (22) Titanium mica (interference color: red, average particle size: 20 μm) 1 (23) Tocopherol 0.1 (24) Mica (average particle size 20 μm) 0.2 (25) l-Menthol 0.5 (26) Tripropylene glycol 0.4 (27) Isododecane 5 *12: LIPWAX A-4 (manufactured by Nippon Natural Products)

[0075] A. Dissolve ingredients (1) to (3) homogeneously at 110°C. B. Mix and disperse components (7) to (24). Add B and components (25) and (26) to CA and mix at 110°C. D. Mix and disperse C uniformly using a roll mill at 10℃~60℃. E. Add ingredients (4) to (6) to D and heat and mix at 80°C. (Step (2-1)) F. Add component (27) to E and heat and mix at 80°C. G. Fill F into a rubber mold (12Φ) container while stirring at 100°C or higher. H. G was cooled at -10°C to obtain an oil-based stick-shaped eye shadow.

[0076] The oil-based stick-shaped eye shadow of Example 48 had excellent color retention, smooth spreadability, secondary adhesion-free effect speed, in-process separation prevention, and releasability.

[0077] Example 49: Oily stick concealer Ingredients (%) (1) Synthetic wax (melting point 80℃)*2 5 (2) Beeswax (melting point 63℃)*6 1 (3) Rice bran wax (melting point 78°C)*13 0.5 (4) Dextrin isostearate 1 (5) Dextrin (palmitic acid / ethylhexanoic acid) 0.2 (6) Trimethylsiloxyphenyl dimethicone (Viscosity 100mPa·s)*9 20 (7) Dimethylpolysiloxane (Viscosity: 100cs (kinetic viscosity) *0.97 (density) mPa s) 10 (8) Polyglyceryl-10 Pentaisostearate (Viscosity 4,500mPa·s) 17 (9) Diisostearyl malate (viscosity 2500 mPa s) 10 (10) Rose fruit oil 1 (11) Disteardimonium hectorite 0.5 (12) Dimethylsilylated silica 0.4 (13) Tea Flower Extract 0.1 (14) Olive Squalane 0.1 (15) Rosa canina fruit oil 0.1 (16) Macadamia nut oil remaining (17) Jojoba seed oil 1 (18) Lauroyl Lysine (2% surface treatment) Red Iron Oxide 0.7 (19) Lauroyl Lysine (2% surface treatment) Yellow Iron Oxide 0.4 (20) Lauroyl Lysine (2% surface treatment) Black Iron Oxide 0.1 (21) Lauroyl Lysine (2% surface treatment) Titanium dioxide 0.5 (22) Silica anhydride (spherical, average particle size 10 μm) 1 (23) Dipropylene glycol 0.4 (24) Isododecane 5 *13: Rice Wax SS-I (manufactured by BOSO Oils and Fat Co., Ltd.)

[0078] A. Dissolve ingredients (1) to (5) homogeneously at 110°C. B. Mix and disperse components (8) to (22). Add B and component (23) to CA and mix at 110°C. The DC is mixed and dispersed uniformly at 10℃ to 60℃ using a roll mill. Components (6) to (7) are added to ED and mixed at 80°C. (Step (2-1)) Add component (24) to FE and heat and mix at 80°C. Fill the GF into a rubber mold (12Φ) container while stirring at 100℃ or higher. The HG was cooled at -10°C to obtain an oil-based stick-type concealer.

[0079] The oily stick concealer of Example 49 had excellent color retention, smooth spreadability, secondary adhesion-free effect speed, in-process separation prevention, and releasability.

[0080] Example 50: Oily stick blush Ingredients (%) (1) (Ethylene / propylene) copolymer (melting point 95°C) 7 (2) Candelilla wax (melting point 72°C)*4 1.5 (3) Ethyl cellulose 0.5 (4) Dimethylpolysiloxane (Viscosity: 100cs (kinetic viscosity) *0.97 (density) (mPa s)) 10 (5) Phenyl trimethicone (viscosity: 20cs (kinetic viscosity) * 0.98(density)(mPa s))*10 25 (6) Polyglyceryl-2 triisostearate (Viscosity 550mPa·s) 20 (7) Polyglyceryl-2 Tetraisostearate (Viscosity 750mPa·s) 5 (8) (VP / hexadecene) copolymer (Viscosity 10,700mPa·s) 10 (9) Zanthoxylum extract 0.05 (10) Lecithin 0.5 (11) Mineral oil remaining (12) Mica (average particle size 15 μm) 3 (13) Talc (average particle size 5 μm) 3 (14) Blue No. 1 0.05 (15) Red No. 202 1 (16) Red No. 226 1 (17) Polylactic acid (spherical, average particle size 15 μm) 1 (18) Purified water 0.01 (19) Sodium hyaluronate 0.1 (20) Dipropylene glycol 0.4 (21) Isohexadecane 8

[0081] A. Dissolve ingredients (1) to (3) homogeneously at 110°C. B. Mix and disperse components (6) to (17). Add B and components (18) to (20) to CA and mix at 110°C. The DC is mixed and dispersed uniformly at 10℃ to 60℃ using a roll mill. Components (4) to (5) are added to ED and mixed at 80°C. (Step (2-1)) Add component (21) to FE and heat and mix at 80°C. Fill the GF into a rubber mold (12Φ) container while stirring at 100℃ or higher. The HG was cooled at -10°C to obtain an oily stick-shaped blush.

[0082] The oil-based stick-shaped blush of Example 50 had excellent color retention, smooth spreadability, secondary adhesion-free effect speed, in-process separation prevention, and releasability.

Claims

1. The following components (A) to (E): (A) Wax (B) A kinematic viscosity at 25°C of 20 to 10,000 mm ２ / s non-volatile silicone oil (C) Non-volatile liquid ester oil (D) Colored powder (E) Polyhydric alcohol Contains the mass ratio of the component (B) to the component (C), (B) / (C), is 0.5 to 3.0; A method for producing an oily stick-type cosmetic preparation, comprising the steps of: A method for producing an oily stick-type cosmetic preparation comprising the following steps 1 to 4: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) dispersing the mixture obtained in step 1 at 5 to 80°C, and then adding and dispersing component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110° C., and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3.

2. 2. The method for producing an oily stick-type cosmetic preparation according to claim 1, wherein the component (B) is one or more selected from the group consisting of (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane.

3. The method for producing an oily stick-type cosmetic preparation according to claim 1 or 2, wherein the content of the component (E) is 0.05 to 1.5% by mass.

4. 3. The method for producing an oily stick-type cosmetic preparation according to claim 1 or 2, wherein the component (C) contains (C1) a non-volatile liquid ester oil having a viscosity of less than 1,000 mPa·s at 25° C., and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa·s or more at 25° C.

5. The method for producing an oily stick-type cosmetic preparation according to claim 1 or 2, further comprising adding a volatile oil as component (F) in step 1 and / or step 2.

6. The method for producing an oily stick-type cosmetic preparation according to claim 1 or 2, wherein the step 2 is the step (2-1).

7. The method for producing an oily stick-type cosmetic preparation according to claim 1 or 2, wherein the dispersion treatment in the step 2 is a high shear dispersion treatment.

8. The method for producing an oily stick-shaped cosmetic preparation according to claim 1 or 2, wherein the container into which the cosmetic composition is filled in step 3 is a rubber mold or a metal mold.

9. The following components (A) to (E): (A) Wax (B) A kinetic viscosity at 25°C of 20 to 10,000 mm ２ / s non-volatile silicone oil (C) a non-volatile liquid ester oil, (D) Colored powder (E) Polyhydric alcohol Contains a content mass ratio (B) / (C) of the component (B) to the component (C) is 0.5 to 3.0, Steps 1 to 4 below: Step 1: A step of dissolving the component (A) at a temperature equal to or higher than the melting point of the component (A), and adding and mixing the components (C) and (D). Step 2: (2-1) dispersing the mixture obtained in step 1 at 5 to 80°C, and then adding and dispersing component (B) at 30 to 110°C to obtain a cosmetic composition; or (2-2) A step of adding the component (B) to the mixture obtained in the step 1, dispersing the mixture at 30 to 110° C., and obtaining a cosmetic composition. (However, the component (E) is added, mixed or dispersed in step 1 and / or step 2.) Step 3: Heating the cosmetic composition obtained in step 2 at 80 to 110°C and filling the composition into a container while stirring. Step 4: A step of cooling the cosmetic composition filled in the container obtained in step 3. The oily stick-shaped cosmetic preparation is obtained by a production method comprising the steps of:

10. The oily stick-shaped cosmetic preparation according to claim 9, wherein the content of the component (B) is 25 to 55% by mass.

11. The oily stick-shaped cosmetic preparation according to claim 9 or 10, wherein the component (B) comprises (B1) methylphenylpolysiloxane and (B2) dimethylpolysiloxane.

12. 11. The oily stick-type cosmetic preparation according to claim 9 or 10, wherein the component (C) is one or more selected from (C1) a polyglycerol fatty acid ester having a viscosity of less than 1,000 mPa·s at 25° C. and (C2) a non-volatile liquid ester oil having a viscosity of 10,000 mPa·s or more at 25° C.

13. The oily stick-type cosmetic preparation according to claim 9 or 10, wherein the average kinetic viscosity ratio of the component (B1) to the component (B2), (B1) / (B2), is 1 to 250.

14. The oily stick cosmetic preparation according to claim 9 or 10, wherein the component (C) comprises one or more selected from (C1) polyglyceryl-2 triisostearate, (C2) (VP / hexadecene) copolymer, and dimer dilinoleyl bisisostearyl dimer dilinoleate.

15. The oily stick-shaped cosmetic preparation according to claim 9 or 10, wherein the component (E) is one or more selected from the group consisting of 1,3-butylene glycol, dipropylene glycol, 1,2-hexanediol, glycerin and tripropylene glycol.

16. The oily stick-shaped cosmetic preparation according to claim 9 or 10, further comprising a volatile oil as component (F).

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