Vibration damping material

Abstract

To provide a vibration damping material capable of exhibiting excellent vibration damping performance and of reducing its own weight while having high rigidity.SOLUTION: A vibration damping material of the present invention, used to be installed on a panel 300 of a vehicle, includes a viscoelastic layer 200 and a constraining layer 100 provided on one surface of the viscoelastic layer 200, wherein the constraining layer 100 has a multilayer structure including a core layer 10 with cylindrical cells arranged in multiple rows and film layers 40, 50 provided on both sides of the core layer 10, and wherein the relationship between a strain εa and a strain εb is 0<εa / εb<1, the strain εa being a strain on a surface 100a of the constraining layer 100 on the opposite side to the viscoelastic layer, and the strain εb being a strain on a surface 100b of the constraining layer 100 on the side in contact with the viscoelastic layer.SELECTED DRAWING: Figure 2

Description

[Technical field]

[0001] The present invention relates to a vibration damping material, and more particularly to a vibration damping material for automobiles. [Background technology]

[0002] In automobiles, electrical appliances, and the like, metal plates such as thin steel plates and aluminum plates are generally used as structural members. In order to reduce vibrations in automobiles and electrical appliances, it is possible to impart vibration damping performance (vibration control performance) to the structural members by attaching a viscoelastic material to the surface of the metal plate. Such vibration control structures can be broadly classified into two types: a structure called a non-constrained type in which a viscoelastic material is simply attached to one or both surfaces of a metal plate, and a structure called a constrained type in which a constraining plate such as a metal plate or a polymeric material is further attached to the surface of the viscoelastic material on the opposite side to the metal plate (Non-Patent Document 1).

[0003] Furthermore, as an example of a constrained vibration-damping structure using a constraining plate made of a polymer material, Patent Document 1 describes a carbon fiber reinforced plastic molded body comprising a first carbon fiber reinforced plastic layer, a second carbon fiber reinforced plastic layer laminated on one side of the first carbon fiber reinforced plastic layer, and a first vibration-damping layer disposed between the first carbon fiber reinforced plastic layer and the second carbon fiber reinforced plastic layer, wherein the thickness of the second carbon fiber reinforced plastic layer is thinner than the thickness of the first carbon fiber reinforced plastic layer, and the first vibration-damping layer is provided with voids extending in a direction intersecting the orientation direction of the carbon fibers contained in the second carbon fiber reinforced plastic layer. The document also describes that by making the first carbon fiber reinforced plastic relatively thick and the second carbon fiber reinforced plastic layer relatively thin in this manner, the first vibration damping layer is positioned closer to the surface than the center of the carbon fiber reinforced plastic molded body, thereby suppressing the decrease in the flexural modulus of the carbon fiber reinforced plastic molded body, and by providing a predetermined gap, the stress caused by the expansion of the carbon fiber reinforced plastic layer and the contraction of the vibration damping layer is alleviated by the gap, and as a result, even if the second carbon fiber reinforced plastic layer is configured to be thin, it is possible to prevent distortion from occurring on the surface of the second carbon fiber reinforced plastic layer during molding of the carbon fiber reinforced plastic molded body.

[0004] On the other hand, a typical automobile structure has an engine room in the front, a trunk room in the rear, and a passenger compartment in between. The passenger compartment has seats such as a driver's seat, a passenger seat, and a rear seat. In addition, a dash insulator, a floor carpet, a floor spacer, a trunk trim, and a trunk floor are installed in the passenger compartment so as to cover the outside of the automobile interior, and these parts are molded into uneven shapes that match the shape of the car body and the design of the parts. Furthermore, a front fender liner, a rear fender liner, and an undercover molded into an uneven shape to control air flow are installed on the exterior under the car body. Many of these parts are made of thermoplastic resin, which is heated and press-molded using a mold of the shape of the part to be finished into an uneven part having multiple parts with different thicknesses.

[0005] A recent trend in automobile development is that quietness inside the vehicle is important. Noise transmitted inside the vehicle includes noise from the windows, noise from the tires, noise from under the vehicle body, noise from the engine, noise from the motor, and the like. Noise generated from an automobile is transmitted into the vehicle cabin via vibration of the air or vibration of objects, but the above-mentioned vibration control structure blocks noise transmitted mainly via vibration of objects, so that sufficient acoustic performance can be achieved against noise generated by the automobile. On the other hand, reducing fuel consumption is also important, and there is a demand for weight reduction in the interior and exterior parts of automobiles. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] JP 2012-162062 A [Non-patent literature]

[0007] [Non-Patent Document 1] "Vibration Control Engineering Handbook," edited by the Vibration Control Engineering Handbook Editorial Committee, Corona Publishing Co., Ltd., May 13, 2008, pp. 84-86 Summary of the Invention [Problem to be solved by the invention]

[0008] As described in Non-Patent Document 1, in a non-constrained vibration-damping structure, the thicker the viscoelastic material, the higher the vibration-damping performance, so in order to obtain a desired vibration-damping performance, the thickness of the viscoelastic material must be very large, which is a problem of lack of practicality. On the other hand, in a constrained vibration-damping structure, the vibration-damping performance is maximized when the metal plate used as the constraining plate and the metal plate of the substrate have the same thickness, so in order to obtain a desired vibration-damping performance, the weight of the constraining plate must be large, and although the rigidity is high, it is difficult to reduce the weight. In addition, when the carbon fiber reinforced plastic molded body described in Patent Document 1 is installed on an automobile panel and used for vibration damping of the panel, it is necessary to further provide a vibration-damping layer (viscoelastic layer) between the carbon fiber reinforced plastic molded body and the panel, so that multiple CFRP layers and multiple viscoelastic layers are laminated on the panel, which also has the problem of making it difficult to reduce the weight.

[0009] SUMMARY OF THE PRESENT EMBODIMENTS Accordingly, an object of the present invention is to provide a vibration-damping material that can exhibit excellent vibration-damping performance and can also be made lighter in weight. [Means for solving the problem]

[0010] In order to achieve the above-mentioned object, the present invention provides a vibration-damping material comprising a viscoelastic layer and a constraining layer provided on one side of the viscoelastic layer, wherein the relationship between a strain εa of the constraining layer on the side opposite the viscoelastic layer and a strain εb of the constraining layer on the side in contact with the viscoelastic layer is 0<εa / εb<1.

[0011] The constraining layer may have a multi-layer structure including at least a core layer in which cylindrical cells are arranged in a plurality of rows. The cylindrical cells may be polygonal, such as a substantially square or hexagonal cylinder, or may be curved, such as a substantially cylindrical or elliptical cylinder. Each of the cells in the core layer has a closed surface at one end and an open end at the other end, and the open ends of the cells communicate the internal space of the cells with the outside, and the open ends of the cells are preferably arranged such that adjacent rows of cells are arranged in alternate rows on both sides of the core layer. The open ends, the one-side closed surface, and the other-side closed surface may be polygonal, such as a substantially square or hexagonal shape, or curved, such as a substantially circular or elliptical shape, according to the shape of the cells. The constraining layer may further include film layers provided on both sides of the core layer. Each of the film layers may have a plurality of openings penetrating the layer.

[0012] The thickness of the viscoelastic layer may be in the range of 0.5 to 2 mm. The constraining layer may be molded to match the shape of the panel so that the thickness of the viscoelastic layer is uniform. That is, the constraining layer is not limited to a flat shape, and may have a curved shape or a wavy shape corresponding to the shape of the panel. The relationship between the strain εa and the strain εb is preferably 0.2<εa / εb<0.7.

[0013] The viscoelastic layer may be partially provided on the surface of the constraining layer on the side in contact with the viscoelastic layer. The constraining layer may have a multi-layer structure including a fiber layer on the side of the constraining layer in contact with the viscoelastic layer. The constraining layer may have a multi-layer structure including a metal layer on the side of the constraining layer opposite to the side in contact with the viscoelastic layer. Effect of the Invention

[0014] In this way, the vibration-damping material according to the present invention can improve the vibration-damping performance of the vibration-damping material by making the strain ratio εa / εb between the strain εa of the surface of the constraining layer provided on the viscoelastic layer opposite the viscoelastic layer and the strain εb of the surface in contact with the viscoelastic layer satisfy the formula 0<εa / εb<1, so that the bending central axis of the constraining layer moves in the direction opposite the viscoelastic layer from the center position of the thickness of the constraining layer. Therefore, even if the constraining layer is made of a resin material without being made of a thick metal plate, it is possible to exhibit excellent vibration-damping performance, and therefore it is possible to achieve weight reduction while maintaining high rigidity.

[0015] In particular, by making the constraining layer have a multi-layer structure including at least a core layer in which cylindrical cells are arranged in multiple rows, it is possible to exhibit excellent vibration damping performance, and to achieve lightweight construction while maintaining high rigidity. [Brief description of the drawings]

[0016] [Figure 1] FIG. 1A is a cross-sectional view showing one embodiment of a vibration-damping material according to the present invention, and FIG. 1B is a schematic diagram showing the position of the neutral axis of bending when this vibration-damping material is bent. [Diagram 2] FIG. 4 is an exploded perspective view showing another embodiment of a vibration damping material according to the present invention. [Diagram 3] FIG. 3 is a schematic cross-sectional view of the embodiment of the vibration-damping material shown in FIG. 2. [Figure 4] 1 is a perspective view showing a manufacturing process of a core material used in a core layer in a vibration-damping material according to the present invention. FIG. [Diagram 5] FIG. 2 is a schematic plan view showing a core layer in the vibration-damping material according to the present invention. [Figure 6] 6 is a schematic cross-sectional view showing the core layer of FIG. 5 along line VI-VI. [Figure 7] 1(a) to 1(c) are rear views showing various embodiments of the vibration-damping material according to the present invention. [Figure 8] FIG. 11 is an exploded perspective view showing still another embodiment of a vibration damping material according to the present invention. [Figure 9]9 is a schematic diagram showing an enlarged partial cross section of the embodiment of the vibration damping material shown in FIG. 8. [Figure 10] FIG. 2 is a schematic diagram illustrating a method for measuring the strain of a vibration-damping material according to the present invention. [Figure 11] FIG. 2(a) is a schematic diagram illustrating a method for measuring the loss factor of a vibration-damping material according to the present invention, and FIG. 2(b) is a graph showing how the loss factor is calculated from the measured values. [Figure 12] 1 is a graph showing the measurement results of loss factors in examples and comparative examples of vibration damping materials according to the present invention. [Figure 13] FIG. 11 is an exploded perspective view showing still another embodiment of a vibration damping material according to the present invention. [Figure 14] FIG. 1(a) is a perspective view showing a schematic view of an automobile body, and FIG. 1(b) is a cross-sectional view taken along line BB showing a schematic view of an example of a state in which a vibration-damping material according to the present invention is installed, the vibration-damping material being molded to match the shape of a panel of the body shown in FIG. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0017] Hereinafter, an embodiment of the vibration-damping material according to the present invention will be described with reference to the attached drawings. Each embodiment describes the case where the vibration-damping material is used in an automobile, but the present invention is not limited to this and can also be used in electrical products, etc. Furthermore, the drawings are not intended to be drawn to scale unless otherwise specified.

[0018] (First embodiment) 1(a), the vibration-damping material of the first embodiment includes a constraining layer 100 and a viscoelastic layer 200 provided on one surface of the constraining layer 100. The vibration-damping material of the present invention is used such that the viscoelastic layer 200 is located on the noise source side, i.e., the vibration-damping material of the present invention is provided on the vehicle interior side with the viscoelastic layer 200 installed on the vehicle body panel 300 side.

[0019] The constraining layer 100 has a ratio εa / εb between a strain εa on the surface 100a opposite to the viscoelastic layer 200 and a strain εb on the surface 100b in contact with the viscoelastic layer 200, which satisfies the formula 0<εa / εb<1. When the constraining layer 100 has a strain ratio εa / εb that satisfies the above formula, as shown in Fig. 1(b), when a vibration-damping material installed on the panel 300 is bent (i.e., when subjected to vibration), the bending central axis NA of the constraining layer 100 moves in a direction opposite to the viscoelastic layer 200 from the center position of the thickness of the constraining layer 100, thereby improving the vibration-damping performance of the vibration-damping material.

[0020] The constraining layer 100 is not particularly limited as long as the strain ratio εa / εb satisfies the above formula, but may be, for example, a multi-layer structure of two or more layers. Each layer of this multi-layer structure may be made of, for example, a metal material, a synthetic resin material, a fiber-reinforced resin material, or the like, and may be made of, for example, a solid film layer, a hollow core layer, a nonwoven fabric layer, or a foam layer. All layers may be made of the same material or different materials. All layers may have the same configuration or different configurations. The constraining layer 100 can be made such that the strain ratio εa / εb satisfies the above formula by, for example, changing the material for each layer, changing the configuration or thickness for each layer, or performing surface treatment. The lower limit of εa / εb is preferably 0.1 or more, more preferably 0.15 or more, and even more preferably 0.2 or more. The upper limit of εa / εb is preferably 0.95 or less, more preferably 0.7 or less, and even more preferably 0.5 or less.

[0021] The viscoelastic layer 200 is not particularly limited as long as it is a material that is usually used for a viscoelastic layer in a vibration-damping material, but may be, for example, a rubber material or an elastomer material. Examples of the rubber material include butyl-based rubber, acrylic-based rubber, and chloroprene-based rubber. Examples of the elastomer material include olefin-based elastomers and isobutylene-based elastomers. The constraining layer 100 and the viscoelastic layer 200 can be bonded to each other by the viscosity of the viscoelastic layer 200.

[0022] From the viewpoint of panel conformability, the lower limit of the thickness of the viscoelastic layer 200 is, for example, preferably 0.5 mm or more, more preferably 1 mm or more, and even more preferably 2 mm or more. From the viewpoint of mass efficiency, the upper limit of the thickness of the viscoelastic layer 200 is, for example, preferably 5 mm or less, more preferably 4 mm or less, even more preferably 3 mm or less, and most preferably 2 mm or less.

[0023] According to the first embodiment, by providing the viscoelastic layer 200 with a constraining layer 100 having a strain ratio εa / εb that satisfies the formula 0<εa / εb<1, the vibration control performance can be improved, and noise that is mainly transmitted via the vibration of an object can be blocked, thereby providing sufficient sound insulation performance.

[0024] Second embodiment As shown in Figs. 2 and 3, the vibration damping material of the second embodiment includes a core layer 10 having a hollow structure, a first film layer 40 provided on one side of the core layer 10, a second film layer 50 provided on the other side of the core layer 10, and a viscoelastic layer 200 in contact with the second film layer 50. The multilayer structure of the core layer 10 and the first and second film layers 40, 50 constitutes the constraining layer 100 of the first embodiment. That is, the ratio εa / εb between the strain εa on the surface of the constraining layer 100 facing the first film layer 40 and the strain εb on the surface of the constraining layer 100 facing the second film layer 50 satisfies the formula 0<εa / εb<1. Note that the same reference numerals are used for the same configurations as those of the first embodiment, and detailed description thereof will be omitted here.

[0025] The core layer 10 is not particularly limited as long as it is a core layer that is typically used in soundproofing and sound-absorbing materials, such as a core layer in which cylindrical cells are arranged in multiple rows, but it is preferable to use a core layer having the structure described below.

[0026] 4 is a perspective view showing a manufacturing process of a core material that becomes the core layer 10. The manufacturing method of this core material is described in detail in International Publication No. WO 2006 / 053407, which is incorporated herein by reference.

[0027] As shown in FIG. 4, the core material 1 is formed by thermoforming a flat material sheet with a roller (not shown) having a predetermined shape, and plastically deforming the sheet without substantially cutting it. The material of the core material 1 is not limited to these, but may be, for example, thermoplastic resin such as polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), composite material with fibers, paper, metal, etc., and is particularly preferably thermoplastic resin. In this embodiment, a case where a thermoplastic resin is used will be described. The thickness of the material sheet is not limited to these, but is preferably in the range of, for example, 0.05 mm to 0.50 mm, and the thickness of the core material 1 after thermoforming is approximately the same.

[0028] The core material 1 has a three-dimensional structure in which peaks 11 and valleys 12 are alternately arranged in a width direction X perpendicular to the manufacturing direction Y. Each peak 11 is composed of two side surfaces 13 and a top surface 17 between them, and each valley 12 is composed of two side surfaces 13 shared with adjacent peaks 11 and a bottom surface 14 between them. Note that in this embodiment, a case in which the peaks 11 have a trapezoidal shape as shown in Fig. 4 will be described, but the present invention is not limited to this, and the peaks 11 may have a polygonal shape such as a triangle or a rectangle, or a curved shape such as a sinusoidal curve or an arch shape.

[0029] The core material 1 has the above-mentioned three-dimensional structure so as to be continuous in the manufacturing direction Y. That is, as shown in Fig. 4, a plurality of peaks 11a, 11b, 11c, and 11d are continuously formed in the manufacturing direction Y. Similarly, valleys 12 are continuously formed. The connections between the peaks 11 and the connections between the valleys 12 are made by alternately repeating two types of connection methods.

[0030] In the first connection method, as shown in FIG. 4, the top surfaces 17b, 17c of two adjacent peaks 11b, 11c are connected via trapezoidal peak connection surfaces 15b, 15c at the first widthwise folding line X1. The peak connection surface 15 is formed at a right angle to the top surface 17. In the first widthwise folding line X1, the bottom surfaces 14b, 14c of two adjacent valleys are directly connected. In the second connection method, as shown in FIG. 4, the bottom surfaces 14a, 14b (or 14c, 14d) of two adjacent valleys are connected via trapezoidal valley connection surfaces 16a, 16b (or 16c, 16d) at the second widthwise folding line X2. The valley connection surface 16 is formed at a right angle to the bottom surface 14. At the second folding line X2 in the width direction, the top surfaces 12a, 12b (or 12c, 12d) of two adjacent peaks are directly connected to each other.

[0031] In this way, the core material 1 has a plurality of three-dimensional structures (peaks 11, valleys 12) connected via connection regions (peak connection surfaces 15, valley connection surfaces 16), and the core layer of the vibration-damping material of the present invention is formed by folding the connection regions. Specifically, the first folding line X1 is folded in a mountain manner so that the bottom surfaces 14b, 14c of two adjacent valleys overlap each other via their back surfaces, and the angle between the peak connection surfaces 15b, 15c of the two adjacent peaks opens to 180 degrees. Also, the second folding line X2 is folded in a valley manner so that the top surfaces 17a, 17b (or 17c, 17d) of the two adjacent peaks overlap each other, and the angle between the valley connection surfaces 16a, 16b (or 16c, 16d) of the two adjacent valleys closes to 180 degrees. The core layer 10 of the vibration damping material of the present invention obtained by folding the core material 1 in this manner is shown in FIGS.

[0032] 5 and 6, the core layer 10 has substantially hexagonal cylindrical cells 20 arranged in a plurality of rows, with cells 20A, 20C, and 20E formed from two adjacent peaks and cells 20B and 20D formed from two adjacent valleys arranged in every other row. The dashed line 18 in Fig. 6 is the surface that was the back surface of the core material, and generally shows the inner wall of the substantially hexagonal cylindrical cells 20.

[0033] Each of the cells 20A, 20C, and 20E formed from the ridges has six cell side walls forming a substantially hexagonal cylindrical shape, and these cell side walls are formed from two top surfaces 17 and four side surfaces 13 of the cell material. Each of the cells 20A, 20C, and 20E has substantially hexagonal cylindrical closing surfaces 21A, 21C, and 21E that close the cell end at the cell end on one surface 10a (the front surface in FIG. 5) of the core layer 10, and each of these closing surfaces 21 on one side is formed by two trapezoidal ridge connection surfaces 15 of the cell material. Each of the cells 20A, 20C, and 20E has substantially hexagonally opened open ends 22A, 22C, and 22E at the cell end on the other surface 10b, which is the opposite side of the core layer 10. The open ends 22A, 22C, 22E allow the internal spaces of the cells 20A, 20C, 20E to communicate with the outside.

[0034] The cells 20B, 20D formed from the valleys also have six cell side walls each forming an approximately hexagonal cylindrical shape, and these cell side walls are formed from two bottom surfaces 14 and four side surfaces 13 of the cell material. Furthermore, these cells 20B, 20D have open ends 22B, 22D that open in an approximately hexagonal shape at the cell end of the one surface 10a of the core layer 10. The open ends 22B, 22D allow the internal spaces of the cells 20B, 20D to communicate with the outside. Furthermore, these cells 20B, 20D have approximately hexagonal cylindrical closed surfaces 21B, 21D that close the cell end at the cell end of the other surface 10b, which is the opposite side of the core layer 10, and these closed surfaces 21 on the other side are each formed by two trapezoidal valley connection surfaces 16 of the cell material.

[0035] In this way, the core layer 10 has one-side closed surfaces 21A, 21C, 21E formed from the peaks of the cell material in every other row at the cell ends of one face 10a, and other-side closed surfaces 21B, 21D formed from the valleys of the cell material in a different row of cells at the cell ends of the other face 10b, but unless otherwise specified, both the one-side closed surfaces 21 and the other-side closed surfaces have substantially the same function.

[0036] The overall thickness of the core layer 10 varies depending on which part of the automobile the vibration-damping material is used in, so is not limited to the following; however, from the standpoint of the sound absorption performance of the core layer 10 itself, and the strength and weight of the core layer 10, a range of 3 mm to 50 mm is preferable, and a range of 5 mm to 30 mm is more preferable.

[0037] The basis weight (weight per unit area) of the core layer 10 varies depending on which part of the automobile the vibration-damping material is used for, so is not limited thereto, but is preferably 400 g / m 2 to 4000g / m 2 The range of 500 g / m 2 to 3000g / m 2 It is more preferable that the thickness of the core layer 10 is in the range of 10 / 100 mm. Generally, the strength of the core layer 10 increases as the thickness of the core layer 10 increases and the basis weight of the core layer 10 increases.

[0038] The basis weight of the core layer 10 can be adjusted by the type of material of the core layer 10, the overall thickness of the core layer 10, the wall thickness of the cells 20 (the thickness of the material sheet), as well as the pitch Pcx and Pcy (the distance between the central axes of the cells) between the cells 20 of the core layer 10. In order to set the basis weight of the core layer 10 within the above range, for example, the pitch Pcy between the cells 20 in the direction in which the cells 20 form a row adjacent to each other, which is the manufacturing direction Y of the core, is preferably set to a range of 2 mm to 20 mm, more preferably set to a range of 3 mm to 15 mm, and even more preferably set to a range of 4 mm to 10 mm.

[0039] When the core layer 10 is used as the constraining layer 100, in order to ensure that the strain ratio εa / εb of the constraining layer 100 satisfies the equation 0<εa / εb<1, the material, thickness, and Young's modulus of the first and second film layers 40, 50 are changed, etc.

[0040] The material of the first and second film layers 40, 50 is not limited to these, but may be, for example, a resin film such as polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), polyamide (PA), etc. The first film layer 40 and the second film layer 50 may be made of the same material, or different materials may be used so that the strain ratio εa / εb satisfies the above formula.

[0041] The thickness of the first and second film layers 40, 50 is not particularly limited, but for example, the lower limit is preferably 0.03 mm or more, more preferably 0.04 mm or more, and even more preferably 0.05 mm or more. The upper limit of the thickness is preferably 0.5 mm or less, more preferably 0.4 mm or less, and even more preferably 0.3 mm or less. The first film layer 40 and the second film layer 50 may have the same thickness, or may have different thicknesses so that the strain ratio εa / εb satisfies the above formula.

[0042] The first and second film layers 40, 50 may be bonded to the core layer 10 by heat welding or via an adhesive (not shown). The adhesive is not particularly limited, but may be, for example, an epoxy or acrylic adhesive. Each of the first and second film layers 40, 50 may have a three-layer structure with a central layer and two adhesive layers located on both sides of the central layer. In this case, the adhesive layer is made of a material having a melting point lower than that of the material used for the central layer. For example, by using polyamide having a melting point of 190°C to 220°C for the central layer and polyethylene having a melting point of 90°C to 130°C for the adhesive layer, the heating temperature when bonding the first and second film layers 40, 50 to the core layer 10 or the viscoelastic layer 200 and the temperature for thermoforming the vibration-damping material into a predetermined shape can be set to about 150°C to 160°C, so that the central layer does not melt and only the adhesive layer melts and can be firmly bonded to the core layer 10. In addition to polyamide, polypropylene is another resin with a melting point higher than that of the polyethylene of the adhesive layer.

[0043] The first and second film layers 40, 50 may be permeable with a plurality of openings penetrating the layers, or may be non-permeable without such openings. By providing openings, the strain ε on the surface of the film layer side where the openings are provided can be increased, and the above-mentioned strain ratio εa / εb can be easily controlled. When openings are provided, the openings are made in advance before the first or second film layer 40, 50 is bonded to the core layer 10, and are opened, for example, by a hot needle or punch processing (punching processing using a male and female mold), and it is preferable to make the hole shape with as little burrs as possible to prevent the holes from being blocked. The opening pattern is not particularly limited, but it is preferable to arrange them in a staggered or lattice pattern. The opening rate of the first or second film layer 40, 50 is not particularly limited, but is preferably in the range of 0.2% to 5%. The diameter of the openings is preferably in the range of 0.25 mm to 2.5 mm, and more preferably in the range of 0.3 mm to 2.0 mm. The pitch of the holes in the first or second film layer 40, 50 does not necessarily have to match the pitch Pcx, Pcy of the cells 20 in the core layer 10 shown in Fig. 5, and the holes do not necessarily have to be aligned with the cells 20 when the first or second film layer 40, 50 is bonded to the core layer 10. This is because the holes in the first or second film layer 40, 50 and the open ends 22 of the cells 20 in the core layer 10 randomly overlap each other to ensure proper internal and external communication. It is preferable that the pitch of the holes in the first or second film layer 40, 50 is smaller than the pitch of the cells 20 in the core layer 10 in at least either the X direction or the Y direction.

[0044] According to the second embodiment, by providing a constraining layer 100 in which first and second film layers 40, 50 are provided on both sides of a core layer 10 in which open ends and closed surfaces are arranged in alternating rows, it is possible to provide a vibration-damping material that can achieve the same effects as the first embodiment while also being lightweight while providing high rigidity.

[0045] (Third embodiment) In the first and second embodiments, the surface of the viscoelastic layer 200 in contact with the constraining layer 100 has the same area as the surface of the constraining layer 100 on the viscoelastic layer 200 side, but the present invention is not limited to this. As shown in each example of Fig. 7(a) to (c), the vibration damping material of the third embodiment has the viscoelastic layer 200 partially provided on the surface 100b of the constraining layer 100 on the side in contact with the viscoelastic layer. Note that the same reference numerals are used for the same configurations as those of the first and second embodiments, and detailed description thereof will be omitted here.

[0046] For example, as shown in FIG. 7(a), a plurality of linear viscoelastic layers 200A may be arranged in parallel on the surface 100b of the constraining layer 100 that contacts the viscoelastic layer. Also, as shown in FIG. 7(b), a curved viscoelastic layer 200B, such as an S-shape, may be provided on the surface 100b of the constraining layer 100 that contacts the viscoelastic layer. Furthermore, as shown in FIG. 7(c), a plurality of rectangular viscoelastic layers 200C may be arranged in a lattice pattern or a staggered pattern on the surface 100b of the constraining layer 100 that contacts the viscoelastic layer. In this way, for example, the area of ​​the surface of the viscoelastic layer 200 that contacts the constraining layer 100 is preferably in the range of 5% to 50% of the area of ​​the surface of the constraining layer 100 on the viscoelastic layer 200 side, and more preferably in the range of 10% to 20%.

[0047] According to the third embodiment, by partially providing the viscoelastic layer 200 on the surface 100b of the constraining layer 100 that contacts the viscoelastic layer, it is possible to obtain the same effects as the first and second embodiments even if the amount of viscoelastic layer 200 used is reduced.

[0048] (Fourth embodiment) As shown in Figs. 8 and 9, the vibration damping material of the fourth embodiment includes a core layer 10, a first film layer 40 provided on one side of the core layer 10, a second film layer 50 and a fiber layer 60 provided in this order on the other side of the core layer 10, and a viscoelastic layer 200 in contact with the fiber layer 60. The multilayer structure of the core layer 10, the first and second film layers 40, 50, and the fiber layer 60 constitutes the constraining layer 100 of the first embodiment described above. That is, the ratio εa / εb between the strain εa on the first film layer 40 side surface of the constraining layer 100 and the strain εb on the fiber layer 60 side surface satisfies the formula 0<εa / εb<1. Note that the same reference numerals are used for the same configurations as those of the first to third embodiments, and detailed description thereof will be omitted here.

[0049] In the fourth embodiment, a fiber layer 60 is provided between the second film layer 50 and the viscoelastic layer 200. The fiber layer 60 is not particularly limited as long as it maintains the above-mentioned strain ratio εa / εb within a predetermined range, but it is preferable to use various nonwoven fabrics such as spunbond, spunlace, or needle punch using resin fibers such as polyethylene terephthalate (PET), polypropylene (PP), and polyethylene (PE). The basis weight of the ..., for example, 10 g / m 2 From 600g / m 2 The range is preferably 20 g / m 2 From 500g / m 2 More preferably, the range is 30 g / m 2 from 300 g / m 2 The range is more preferable.

[0050] The fiber layer 60 and the second film layer 50 can be bonded to each other by the thermal adhesion of the second film layer 50 or by using an adhesive. The fiber layer 60 and the viscoelastic layer 200 can be bonded to each other by the viscosity of the viscoelastic layer 200.

[0051] According to the fourth embodiment, by providing the constraining layer 100 so that the fiber layer 60 is in contact with the viscoelastic layer 200, the same effect as in the first embodiment can be obtained, and, as shown in FIG. 9, the fibers 62 of the fiber layer 60 of the constraining layer 100 penetrate into and are bonded to the inside of the viscoelastic layer 200, so that the vibration damping effect is improved by mixing the fibers into the viscoelastic layer 200, and the adhesive strength between the constraining layer 100 and the viscoelastic layer 200 is also improved.

[0052] Fifth embodiment As shown in FIG. 13, the vibration damping material of the fifth embodiment includes a core layer 10, a first film layer 40 and a metal layer 70 provided in order on one side of the core layer 10, a second film layer 50 provided on the other side of the core layer 10, and a viscoelastic layer 200 in contact with the second film layer 50. The multilayer structure of the core layer 10, the first and second film layers 40, 50, and the metal layer 70 is the constraining layer 100 of the first embodiment described above. That is, the ratio εa / εb between the strain εa on the metal layer 70 side surface of the constraining layer 100 and the strain εb on the second film layer 50 side surface satisfies the formula 0<εa / εb<1. Note that the same reference numerals are used for the same configurations as those of the first to third embodiments, and detailed description thereof will be omitted here.

[0053] In the fifth embodiment, a metal layer 70 is provided on the surface side of the first film layer 40. The metal layer 70 is not particularly limited as long as it maintains the above-mentioned strain ratio εa / εb within a predetermined range, but it is preferable to use a metal thin film such as a steel plate, aluminum foil, or copper foil. The thickness of the metal layer 70 is not particularly limited as long as it maintains the above-mentioned strain ratio εa / εb within a predetermined range, but for example, the lower limit is preferably 5 μm or more, more preferably 7 μm or more, and even more preferably 10 μm or more, and the upper limit is preferably 1 mm or less, more preferably 0.5 mm or less, and even more preferably 0.1 mm or less. The metal layer 70 and the first film layer 40 can be bonded by the heat-welding property of the first film layer 40 or by using an adhesive.

[0054] According to the fifth embodiment, by providing a metal layer 70 on the side of the constraint layer 100 opposite the viscoelastic layer 200, the same effect as in the first embodiment can be obtained, and the strain εa on the side of the constraint layer 100 opposite the viscoelastic layer 200 can be significantly reduced, and the strain ratio εa / εb can be easily controlled.

[0055] Sixth embodiment The vibration damping material of the sixth embodiment has a structure in which a constraining layer 100R is molded to fit the shape of a roof panel 300R of an automobile so that the thickness of a viscoelastic layer 200R is uniform, as shown in Fig. 14. Note that the same components as those of the first embodiment are denoted by the same reference numerals, and detailed description thereof will be omitted here.

[0056] In the case of a vibration-damping material molded in this manner, with regard to the above-mentioned strain ratio εa / εb, as shown in Figure 14(b), in the molded constraint layer 100R, the ratio εa / εb of the strain εa of the surface opposite the viscoelastic layer 200R to the strain εb of the surface in contact with the viscoelastic layer 200R satisfies the equation 0<εa / εb<1.

[0057] According to the sixth embodiment, even if the constraining layer 100R of the vibration-damping material is not flat but has a curved or wavy shape corresponding to the shape of the panel 300R, if the thickness of the viscoelastic layer 200R is uniform, the vibration-damping performance can be improved as in the first embodiment by the constraining layer 100R having the strain ratio εa / εb that satisfies the above formula, and the noise transmitted mainly through the vibration of the object can be blocked, and sufficient sound insulation performance can be exhibited. Note that, although FIG. 14 shows the vibration-damping material provided on the roof panel of the automobile, the present invention is not limited to this, and the same effect can be obtained with panels of various shapes that are not flat, such as the dash, floor, and door of the automobile. EXAMPLES

[0058] Examples and comparative examples of the present invention will be described below.

[0059] As Example 1, a vibration-damping material having a constraining layer and a viscoelastic layer shown in FIG. 2 was produced. First, a first film layer (material: polypropylene (PP) film, thickness: 350 μm) was attached to one side of a core layer (material: polypropylene (PP) resin, cell pitch Pcy: 8 mm, core layer thickness: 10 mm) having a structure shown in FIG. 5 and FIG. 6, and a second film layer (material: polypropylene (PP) film, thickness: 300 μm) was attached to the other side to produce a constraining layer. Then, this constraining layer was subjected to three-point bending using a universal material testing machine (Instron, model 5900) to measure the strain. The dimensions of the test piece were 60 mm x 200 mm. As shown in FIG. 10, the test piece 100S was supported by two supports 102 located at an interval of 100 mm, and a bending load of 0.5 mm was applied to the center position by an indenter 104. The strain was measured using a strain gauge (Kyowa Electric Co., Ltd., PCD-400A) to measure the strains εa and εb on both sides of the constrained layer. As a result, the strain ratio εa / εb was 0.91.

[0060] Next, a viscoelastic layer (material: butyl-based rubber, thickness: 1 mm sheet) was attached to the second film layer side of the constraining layer to prepare a vibration-damping material. Furthermore, a panel (material: steel plate, thickness: 0.5 mm) was attached to the viscoelastic layer side of the vibration-damping material. Then, with the vibration-damping material attached to the panel, the loss factor was measured. As shown in FIG. 11(a), the test specimen had dimensions of 60 mm×180 mm for the constraining layer 100S and viscoelastic layer 200S, and 60 mm×200 mm for the panel 300S. The 20 mm long protruding portion of the panel was fixed to a fixing device 112 to support the test specimen on one side. Then, an FFT analyzer 116 (DS-3200, manufactured by Ono Sokki Co., Ltd.) was placed on the panel 300S of the test specimen, 40 mm away from the fixing device 112, and a load was applied to the free end side of the test specimen using a handy electromagnetic exciter 114 (TYPE5961, manufactured by B&K Co., Ltd.). The loss factor was calculated from the measurement results of the resonance characteristics obtained using the half-width method. As shown in Figure 11(b), a graph of frequency against the amplitude of the test specimen was created, and the frequency f 0 and the frequency f between 3 dB from the maximum amplitude 1 and f 2So, η=(f 2 -f 1 ) / f 0 The loss factor η was calculated from the formula above. The results are shown in Table 1 and Figure 12.

[0061] For comparison, the strain and loss factor of Comparative Example 1, which was prepared in the same manner as in Example 1 except that only a PP film (thickness: 300 μm) was used as the constraining layer, were measured in the same manner as in Example 1. The results are shown in Table 1 and FIG.

[0062] Examples 2 to 6 were prepared in the same manner as in Example 1, except that the thicknesses of the layer on the viscoelastic side of the constraining layer and the film layer on the opposite side were changed, or a metal layer (material: steel plate, thickness: 0.5 mm, or material: aluminum foil, thickness: 30 μm) was further provided on the film layer, as shown in Table 1, and the strain and loss factor were measured. These results are shown in Table 1 and FIG.

[0063] [Table 1]

[0064] As shown in Table 1 and FIG. 12, in Examples 1 to 6 in which the strain ratio εa / εb between the strain εa on the surface of the constraining layer opposite the viscoelastic layer and the strain εb on the surface in contact with the viscoelastic layer was set to less than 1, the loss factor was significantly improved compared to Comparative Example 1 in which the strain ratio εa / εb was 1. [Industrial Applicability]

[0065] The vibration-damping material of the present invention exhibits excellent vibration-damping performance (sound-insulating performance) while having high rigidity and being lightweight, and is therefore useful, specifically, for components that dampen panel vibrations between noise sources such as dash, floor, door, roof, wheel house, and fender panels and the interior of an automobile. [Explanation of symbols]

[0066] 1 Core Material 10 Core Layer 11 Yamabe 12 Valley 13 Side part 14 Bottom part 15 Mountain connection surface 16 Valley connection surface 17 Top surface 18 Core material back 20 cells 21 Closed surface 22 Open end 40 First film layer 50 Second Film Layer 60 Fiber Layer 70 metal layer 100 restraint layer 200 Viscoelastic layer 300 Panels

Claims

1. A viscoelastic layer; a constraint layer provided on one surface of the viscoelastic layer; A vibration-damping material comprising: the constraining layer has a multi-layer structure including at least a core layer in which cylindrical cells are arranged in a plurality of rows, The constraining layer further includes a film layer provided on each side of the core layer, A vibration-damping material having a configuration in which the relationship between the strain εa of the surface of the constraining layer opposite the viscoelastic layer and the strain εb of the surface of the constraining layer in contact with the viscoelastic layer is 0 < εa / εb < 1, and the central axis of bending of the constraining layer moves in the direction opposite the viscoelastic layer rather than the center position of the thickness of the constraining layer.

2. 2. The vibration damping material according to claim 1, wherein the thickness of the viscoelastic layer is in the range of 0.5 to 2 mm.

3. 3. The vibration-damping material according to claim 1, wherein the constraining layer has a structure in which the viscoelastic layer on the side to be mounted on the panel is molded to match the shape of the panel so that the thickness of the viscoelastic layer on the side to be mounted on the panel is uniform.

4. 4. The vibration damping material according to claim 1, wherein the relationship between the strain εa and the strain εb is 0.2<εa / εb<0.

7.

5. 5. The vibration damping material according to claim 1, wherein each of the film layers has a plurality of apertures penetrating the layer.

6. 6. The vibration damping material according to claim 1, wherein the viscoelastic layer is partially provided on a surface of the constraining layer on the side in contact with the viscoelastic layer.

7. The vibration damping material according to any one of claims 1 to 6, wherein the constraining layer has a multi-layer structure including a fiber layer on the side of the constraining layer that contacts the viscoelastic layer.

8. The vibration damping material according to any one of claims 1 to 7, wherein the constraining layer has a multi-layer structure including a metal layer on the side of the constraining layer opposite to the side in contact with the viscoelastic layer.

9. The vibration damping material according to any one of claims 1 to 4 and 6 to 8, wherein each of the cells of the core layer has a closed surface at one end and an open end at the other end, the open ends of the cells are arranged in every other row on one surface of the core layer, and the open ends of the cells are arranged in a row of cells different from the above on the other surface of the core layer.

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