Cosmetic product including a cosmetic composition contained in an applicator

A cosmetic product with endothermic materials and ceramic/metal applicators provides a moderate, long-lasting cooling sensation and moisturization, addressing the limitations of menthol and ethanol in existing products.

JP7719211B2Active Publication Date: 2025-08-05PROCTER & GAMBLE CO
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Patent Information

Application Number
JP2023572681
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Priority Date
2021-05-30
Filing Date
2022-05-25
Publication Date
2025-08-05
Estimated Expiration
2042-05-25

AI Technical Summary

Technical Problem

Existing cosmetic products struggle to provide a long-lasting, moderate cooling sensation while maintaining moisturization, especially for sensitive skin areas like the facial skin around the eyes, as menthol and ethanol can be too intense or drying.

Method used

A cosmetic product containing a cosmetic composition with 2% to 20% of endothermic materials like sugar alcohols or disaccharides, applied via a ceramic or metal applicator surface, providing a moderate cooling sensation through heat absorption.

Benefits of technology

The product offers a prolonged, comfortable cooling sensation without refrigeration, enhancing moisturization and skin health by using endothermic materials in conjunction with specific application surfaces.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention relates to a cosmetic product comprising a cosmetic composition contained in an applicator, the cosmetic composition comprising about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, the endothermic material having an endothermic amount of 5 cal / g or more when dissolved in water, and the applicator comprising an application surface for applying the cosmetic composition, the application surface comprising a ceramic and / or a metal, and a reservoir having an opening fluidically connecting the application surface to the reservoir. The cosmetic of the present invention provides a moisturizing feeling while maintaining an appropriate cooling feeling during and after application.
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Description

[Technical Field]

[0001] The present invention relates to a cosmetic product containing a cosmetic composition contained in an applicator, wherein the cosmetic composition contains about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, and the endothermic material has an endothermic value of 5 cal / g or more when dissolved in water, and the applicator comprises an application surface for applying the cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidically connecting the application surface to the reservoir. The cosmetic product of the present invention provides a moisturizing feeling while maintaining a moderate cooling sensation during and after application. [Background technology]

[0002] Mammalian keratinous tissue, particularly human skin, is subject to various damages caused by both exogenous and endogenous factors. Such exogenous factors include ultraviolet light, environmental pollution, wind, heat, infrared rays, low humidity, harsh surfactants, abrasives, etc. Meanwhile, endogenous factors include chronological aging and other biochemical changes within the skin. Whether exogenous or endogenous, these factors result in visible signs of skin damage. Typical skin damage in aged or damaged skin includes fine lines, wrinkles, hyperpigmentation, pale skin, sagging, dark circles under the eyes, puffy eyes, enlarged pores, a slow turnover rate, and abnormal desquamation or peeling. Additional damage caused by both exogenous and endogenous factors includes visible necrotic skin, i.e., peeling, flaking, dryness, and roughness.

[0003] Currently, there are several personal care products available to consumers that are aimed at improving the health and physical appearance of keratinous tissues such as skin, hair, and nails.Most of these products are aimed at delaying, minimizing, or even eliminating skin wrinkles, age spots, and other histological changes that are typically associated with skin aging or environmental damage to human skin.Consumers prefer topically applied products because they are not only effective, but also safe and comfortable to use.

[0004] Some cosmetic compositions are provided with applicators for delivering the above benefits to target areas of the skin, for example, eye care products.

[0005] Some cosmetic products are known that provide a cooling sensation during application of the product. The cooling sensation can be provided by the cosmetic composition. Alternatively, the cooling sensation can be provided by the applicator, for example, from heat transfer from the skin to its metallic application surface.

[0006] Menthol and its derivatives are known to provide a cooling sensation when included in a cosmetic composition. However, this cooling sensation may be too strong for some users and / or users who apply such compositions to sensitive areas of the skin, such as the facial skin around the eyes. Ethanol is also known to provide a cooling and / or refreshing sensation when included in a cosmetic composition. However, it may be difficult to provide a long-lasting cooling and / or refreshing sensation from ethanol. Ethanol may also cause a dry sensation and / or reduce moisturizing sensation. Summary of the Invention [Problem to be solved by the invention]

[0007] Based on the above, there is a need for a cosmetic product that provides a moisturizing feel while also providing a moderate cooling sensation during and after application for an extended period of time. [Means for solving the problem]

[0008] The present invention relates to a cosmetic product comprising a cosmetic composition contained in an applicator, The cosmetic composition comprises about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, the endothermic material having an endothermic value of 5 cal / g or more when dissolved in water; The applicator comprises an application surface for applying the cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir.

[0009] Surprisingly, it has been found that by using a specific heat-absorbing material in conjunction with a specific application surface, the cosmetic product of the present invention provides a moisturizing sensation while maintaining a moderate cooling sensation during and after application. The cosmetic product of the present invention provides such a long-lasting, suitable cooling sensation at ambient temperature without the need for refrigeration or external cooling.

[0010] Unlike menthol, which provides a cooling sensation through sensory receptor activation (TRPM8), certain endothermic materials provide a suitable cooling sensation when combined with certain application surfaces. Also, unlike ethanol, which provides a cooling sensation through the evaporation of ethanol, certain endothermic materials provide a prolonged cooling sensation, especially when combined with certain application surfaces.

[0011] It is known that endothermic materials can provide a cooling sensation when dissolved in water.Without being bound by theory, it is believed that certain endothermic materials in the present composition are at least partially solidified during application due to the evaporation of the aqueous carrier in the composition, and then the solidified endothermic material is dissolved in the moisture of skin, sweat, and / or the remaining aqueous carrier from the composition on the skin surface.In addition, it is believed that certain application surfaces, particularly rolling balls, can accelerate the evaporation of the aqueous carrier of the composition, and therefore provide a cooling sensation at an earlier time of application. DETAILED DESCRIPTION OF THE INVENTION

[0012] References herein to "embodiments" or "combinations" or the like mean that a particular material, feature, structure, and / or characteristic described in connection with that embodiment is included in at least one embodiment, and optionally in multiple embodiments, but do not mean that all embodiments incorporate the described material, feature, structure, and / or characteristic. Furthermore, materials, features, structures, and / or characteristics may be combined in any suitable manner across different embodiments, and materials, features, structures, and / or characteristics may be excluded or substituted from those described. Accordingly, the embodiments and aspects described herein can include or be combined with elements or components of other embodiments and / or aspects, even if not explicitly illustrated in combination, unless otherwise stated or unless incompatibility is explicitly stated.

[0013] In all embodiments, unless otherwise specified, all ingredient percentages are by weight of the cosmetic composition. Unless otherwise specified, all ratios are by weight. The number of significant digits does not represent a limitation on the stated amount or on the precision of the measurements. Unless otherwise specified, all quantities are understood to be modified by the word "about." Unless otherwise specified, all measurements are understood to be made at ambient conditions of approximately 25°C, where "ambient conditions" means conditions of about 1 atmosphere and about 50% relative humidity. All numerical ranges are inclusive and can be combined to form smaller ranges not expressly disclosed. For example, delimited upper and lower range limits are interchangeable to create further ranges.

[0014] The compositions of the present invention can comprise, consist essentially of, or consist of the essential and optional ingredients described herein. As used herein, "consisting essentially of" means that the composition or component may include only additional ingredients that do not materially alter the basic and novel characteristics of the claimed composition or method. As used in this specification and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly dictates otherwise.

[0015] definition "About" modifies a particular value by referring to a range equal to plus or minus 20 percent (±20%) or less (e.g., less than 15%, 10%, or even less than 5%) of the stated value.

[0016] "Applying" or "application" as used in reference to a composition means applying or spreading a composition of the present invention onto the surface of human skin, such as the epidermis.

[0017] As used herein, "derivative" refers to amide, ether, ester, amino, carboxyl, acetyl, and / or alcohol derivatives of a given compound.

[0018] "Effective amount" means an amount of compounds and compositions sufficient to significantly induce a positive effect on keratinous tissue over the course of a treatment period. The positive effect may be a health, appearance, and / or feel effect, including the effects disclosed herein, individually or in combination.

[0019] "Cosmetic agent" means any substance and any components thereof intended to be rubbed, poured, sprinkled, sprayed, introduced, or otherwise applied to the mammalian body or any part thereof to produce a cosmetic effect. Cosmetic agents can include substances generally recognized as safe (GRAS) by the U.S. Food and Drug Administration, food additives, and materials used in non-cosmetic consumer products such as over-the-counter drugs.

[0020] "Cosmetic composition" means a composition containing a cosmetic agent. Examples of cosmetic compositions include color cosmetics (e.g., foundation, lipstick, concealer, and mascara), skin care compositions (e.g., moisturizers and sunscreens), personal care compositions (e.g., rinse-off and leave-in body washes and soaps), and hair care compositions (e.g., shampoos and conditioners).

[0021] "Skin care" means regulating and / or improving skin condition (e.g., skin health, appearance, or texture / feel). Some non-limiting examples of improving skin condition include improving the appearance and / or feel of skin by providing a smoother, more uniform appearance and / or feel, increasing the thickness of one or more layers of skin, improving skin elasticity or resilience, improving skin firmness, as well as reducing the oily, shiny, and / or dull appearance of skin, improving skin hydration or moisturization, improving the appearance of fine lines and / or wrinkles, improving skin exfoliation or scaling, plumping skin, improving skin barrier properties, improving skin tone, reducing the appearance of redness or skin blemishes, and / or improving skin brightness, radiance, or clarity.

[0022] "Skin care active" means a compound or combination of compounds that, when applied to the skin, produces an acute and / or chronic effect on the skin or a type of cell normally found in the skin. Skin care actives can regulate and / or improve the skin or cells associated therewith (e.g., improve skin elasticity, skin hydration, skin barrier function, and / or cellular metabolism).

[0023] "Skin care composition" means a composition that contains skin care actives and that regulates and / or improves the condition of the skin.

[0024] "Synergistic" and variations thereof mean that the effect provided by the combination of two or more materials is greater than the expected additive effect of those materials.

[0025] As used herein, "treatment period" refers to the length of time and / or frequency that a material or composition is applied to a target skin surface.

[0026] cosmetics The cosmetic product of the present invention includes a cosmetic composition contained in an applicator, The cosmetic composition comprises about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, the endothermic material having an endothermic value of 5 cal / g or more when dissolved in water; The applicator comprises an application surface for applying the cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir.

[0027] Preferably, the cosmetic product is an eye care product in which the cosmetic composition is applied to the facial skin around the eyes.

[0028] Details of the cosmetic composition and applicator are described below.

[0029] Applicator Applicators useful herein include an application surface for applying a cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir. Preferably, the applicator surface is a rolling ball comprising ceramic and / or metal to provide a cooling sensation.

[0030] Cosmetic composition The cosmetic compositions useful herein comprise from about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, wherein the endothermic material has an endothermic value of 5 cal / g or greater when dissolved in water.

[0031] The composition preferably has a viscosity of about 100 cP to about 15,000 cP, more preferably about 1,000 cP to about 12,000 cP, and even more preferably about 4,000 cP to about 9,000 cP, from the viewpoint of at least one of the following: refreshing penetration feeling during application; ease of application to the skin; and ease of dispensing from an applicator.

[0032] Preferably, the cosmetic compositions useful herein are substantially free of menthol and its derivatives in order to provide a moderate cooling sensation. In the present invention, "the composition is substantially free of menthol and its derivatives" means that the composition does not contain menthol and its derivatives, or if the composition contains menthol and its derivatives, the concentration of such menthol and its derivatives is very low. In the present invention, the total concentration of such menthol, if present, is 0.05% by weight or less of the composition, preferably 0.01% by weight or less, and more preferably 0% by weight.

[0033] Preferably, the composition of the present invention contains a limited amount of ethanol, for example, at a concentration of about 5% by weight or less of the composition, more preferably about 3% by weight or less, even more preferably about 1% by weight, from the viewpoint of imparting a moisturizing feeling, and even more preferably 0%, i.e., the composition does not contain ethanol.

[0034] The cosmetic compositions herein are intended for topical application to human skin. The compositions herein may optionally contain one or more additional skin active agents or other ingredients of the type typically found in topical cosmetic compositions.

[0035] The cosmetic compositions herein may be cosmetic compositions, pharmaceutical compositions, or cosmeceutical compositions and may be provided in a variety of product forms, including, but not limited to, solutions, suspensions, lotions, gels, toners, washes, hydrogels, film-forming products, and the like. In some cases, the form of the composition may depend on the particular dermatologically acceptable carrier selected. For example, the composition (and carrier) may be provided in the form of an emulsion (e.g., water-in-oil, oil-in-water, or water-in-oil-in-water) or an aqueous dispersion. Preferably, the cosmetic compositions of the present invention are in the form of an oil-in-water emulsion.

[0036] heat-absorbing materials Endothermic materials useful herein are those selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, and the endothermic materials have an endothermic value of 5 cal / g or more, preferably 15 cal / g or more, and more preferably 30 cal / g or more when dissolved in water.

[0037] Examples of such sugar alcohols include xylitol (which has an endothermic value of approximately 36.6 cal / g when dissolved in water), erythritol (which has an endothermic value of approximately 43 cal / g when dissolved in water), and sorbitol (which has an endothermic value of approximately 26.6 cal / g when dissolved in water).

[0038] An example of such a disaccharide is trehalose (which has an endothermic value of about 12.1 cal / g when dissolved in water).

[0039] Among such endothermic materials, sugar alcohols are preferred, sugar alcohols selected from the group consisting of xylitol, erythritol, sorbitol and mixtures thereof are more preferred, and xylitol is even more preferred.

[0040] The endothermic material is contained in the composition at a concentration of about 2% to about 10% by weight, preferably about 2.2% to about 7% by weight, and more preferably about 2.5% to about 5% by weight of the composition.

[0041] Silicone oil Preferably, from the viewpoint of reducing the sticky and / or tacky feeling caused by the specific endothermic material of the present invention while simultaneously maintaining the moist feeling caused by the specific endothermic material of the present invention, the cosmetic composition further comprises a silicone oil which is a mixture of a high molecular weight silicone having a viscosity of about 100,000 mPa·s or more at 25°C and a silicone solvent having a viscosity of about 1 mPa·s to about 5,000 mPa·s, preferably about 2 mPa·s to about 2,000 mPa·s, and more preferably about 2 mPa·s to about 1,000 mPa·s.

[0042] Preferably, the weight ratio of high molecular weight silicone to silicone solvent is from about 1:2 to about 1:100, more preferably from about 1:5 to about 1:70.

[0043] Preferably, the weight ratio of high molecular weight silicone to endothermic material is from about 1:10 to about 1:100, more preferably from 1:15 to about 1:70, and even more preferably from about 1:20 to about 1:50.

[0044] Preferably, the weight ratio of silicone oil to endothermic material is from about 1:20 to about 5:1, more preferably from about 1:10 to about 3:1, and even more preferably from about 1:5 to about 3:1.

[0045] Viscosity can be measured with a glass capillary viscometer as described in Dow Corning Corporate Test Method CTM0004 (July 20, 1970).

[0046] High molecular weight silicones useful herein include, for example, polydimethylsiloxane, also known as dimethicone, dimethiconol, polydiethylsiloxane, and polymethylphenylsiloxane (phenyldimethicone). Dimethicone and dimethiconol are particularly preferred.

[0047] High molecular weight silicones useful herein also include silicone gums. As used herein, the term "silicone gum" refers to polyorganosiloxane materials having a viscosity of 1,000,000 centistokes or greater at 25°C and / or a mass molecular weight greater than about 200,000, typically from about 200,000 to about 4,000,000 or about 1,000,000. It is recognized that the silicone gums described herein may overlap somewhat with the silicone compounds disclosed above. This overlap is not intended to limit any of these materials. Specific examples include polydimethylsiloxane (dimethicone), dimethiconol, poly(dimethylsiloxane-methylvinylsiloxane) copolymer, poly(dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane) copolymer, and mixtures thereof. Silicone gums are often available as mixtures with silicone compounds, for example, having lower viscosities. Such mixtures include, for example, a blend of 12% dimethiconol gum and 88% dimethicone (5 cSt) available from Dow Corning under the trade name DC1503 having a viscosity of 1500 cP; a blend of dimethiconol gum and cyclopentasiloxane available from Dow Corning under the trade name DC1501 having a viscosity of 6000 cP; a blend of dimethicone having a viscosity of 18,000,000 mPa·s and dimethicone having a viscosity of 200 mPa·s available from GE Toshiba; and a blend of dimethicone having a viscosity of 18,000,000 mPa·s and cyclopentasiloxane available from GE Toshiba.

[0048] Silicone solvents useful herein include, for example, polydimethylsiloxane, also known as dimethicone, polydiethylsiloxane, and polymethylphenylsiloxane. Dimethicone is particularly preferred. Preferably, the silicone solvent is non-volatile.

[0049] Dermatologically acceptable carrier The compositions disclosed herein can include a dermatologically acceptable carrier (which may be referred to as a "carrier"). The phrase "dermatologically acceptable carrier" means that the carrier is suitable for topical application to keratinous tissue, has good aesthetic properties, is compatible with the active agents in the composition, and does not raise any undue safety or toxicity concerns. In one embodiment, the carrier is present in a concentration of about 50% to about 99%, about 60% to about 98%, about 70% to about 98%, or alternatively about 80% to about 95% by weight.

[0050] The carrier may be in a wide variety of forms. In some cases, the form and characteristics of the carrier may be determined by the solubility or dispersibility of the components (e.g., extracts, sunscreen actives, additional ingredients). Non-limiting examples include simple solutions (e.g., aqueous or anhydrous), dispersions, emulsions, and solid forms (e.g., gels, sticks, flowable solids, or amorphous materials). In some cases, the dermatologically acceptable carrier is in the form of an emulsion. Emulsions may have a continuous aqueous phase (e.g., oil-in-water or water-in-oil-in-water emulsions) or a continuous oil phase (e.g., water-in-oil or oil-in-water-in-oil emulsions). The oil phase of the present invention may include non-silicone oils such as silicone oils, hydrocarbon oils, esters, ethers, and mixtures thereof. The aqueous phase typically includes water and water-soluble ingredients (e.g., water-soluble moisturizers, conditioning agents, antibacterial agents, humectants, and / or other skin care actives). However, in some cases, the aqueous phase may include components other than water, including, but not limited to, water-soluble moisturizers, conditioning agents, antimicrobial agents, humectants, and / or other water-soluble skin care actives. In some cases, the non-water components of the composition include humectants, such as glycerin and / or other polyol(s).

[0051] In some cases, the compositions herein are in the form of oil-in-water ("O / W") emulsions, which provide a light, non-greasy sensory feel. Suitable O / W emulsions herein may comprise greater than 50% by weight of the composition as a continuous aqueous phase, with the remainder being a dispersed oil phase. The aqueous phase may comprise 1% to 99% water, based on the weight of the aqueous phase, along with any water-soluble and / or water-miscible ingredients. In these cases, the dispersed oil phase is typically present at less than 30% by weight of the composition (e.g., 1% to 20%, 2% to 15%, 3% to 12%, 4% to 10%, or even 5% to 8%) to help avoid some of the undesirable sensory effects of oily compositions. The oil phase may comprise one or more volatile and / or non-volatile oils (e.g., vegetable oils, silicone oils, and / or hydrocarbon oils).

[0052] Aqueous Carrier The composition preferably comprises an aqueous carrier. Preferably, the aqueous carrier is substantially water. Preferably, deionized water is used. Depending on the desired properties of the product, water from natural sources containing mineral cations can also be used.

[0053] In one embodiment, the aqueous carrier may be present at a concentration of from about 50% to about 99% by weight of the composition, preferably from about 60% to about 98% by weight, more preferably from about 70% to about 98% by weight, and even more preferably from about 80% to about 95% by weight.

[0054] Skin conditioning agent Optionally, the compositions of the present invention may further comprise a skin conditioning agent. These agents may be selected from moisturizers and emollients. The amount of skin conditioning agent may be from about 1% to about 50%, preferably from about 2% to about 40%, and more preferably from about 5% to about 30% by weight of the composition.

[0055] Humectants are polyhydric alcohols that are intended to moisturize, reduce flaking, and stimulate the removal of accumulated flaking from the skin.Typical polyhydric alcohols include polyalkylene glycols, more preferably alkylene polyols and their derivatives.Exemplary examples include propylene glycol, dipropylene glycol, polypropylene glycol, polyethylene glycol, sorbitol, hydroxypropyl sorbitol, hexylene glycol, 1,3-butylene glycol, 1,2,6-hexanetriol, ethoxylated glycerin, propoxylated glycerin, and mixtures thereof.Most preferably, the humectant is glycerin.

[0056] When the conditioning agent is an emollient, it may be selected from hydrocarbons, fatty acids, fatty alcohols, and esters.

[0057] Fatty alcohol The compositions herein may include a fatty alcohol, which refers to a high molecular weight, straight-chain primary alcohol having the following general structure:

[0058] [ka] In the formula, n=8 to 32.

[0059] Fatty alcohols can be natural or synthetic, saturated or unsaturated, branched or straight-chain. Some non-limiting examples of fatty alcohols commonly used in cosmetic compositions include capric alcohol, caprylic alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, and behenyl alcohol. Fatty alcohols herein can be referred to generically by the number of carbon atoms in the molecule. For example, "C12 alcohol" refers to an alcohol with 12 carbon atoms in its chain (i.e., dodecanol).

[0060] Fatty alcohols may be included in the compositions herein at 0.0001% to 15% (e.g., 0.0002% to 10%, 0.001% to 15%, 0.025% to 10%, 0.05% to 7%, 0.05% to 5%, or even 0.1% to 3%) by weight of the composition.

[0061] Whitening agent The present composition can contain a whitening agent.The whitening agent useful herein refers to an active ingredient that not only changes the appearance of skin, but also further improves hyperpigmentation compared to before treatment.The whitening agent useful herein includes ascorbic acid compounds, vitamin B3 compounds, azelaic acid, butylhydroxyanisole, gallic acid and its derivatives, hydroquinone, kojic acid, arbutin, mulberry extract, tetrahydrocurcumin, and mixtures thereof.The use of a combination of whitening agents is considered to be advantageous in that they can provide whitening benefits through different mechanisms.

[0062] If used, the present composition preferably contains from about 0.1% to about 10%, more preferably from about 0.2% to about 5%, by weight of the composition, of a whitening agent.

[0063] Ascorbic acid compounds are useful whitening agents, and ascorbyl glucoside is a preferred derivative of ascorbic acid compounds.

[0064] Conditioning Agent The compositions herein may comprise 0.1% to 50% by weight of a conditioning agent (e.g., 0.5% to 30%, 1% to 20%, or even 2% to 15% by weight). The addition of a conditioning agent can help provide the composition with desirable feel characteristics (e.g., a silky, smooth feel upon application). Some non-limiting examples of conditioning agents include hydrocarbon oils and waxes, silicones, fatty acid derivatives, cholesterol, cholesterol derivatives, diglycerides, triglycerides, vegetable oils, vegetable oil derivatives, acetoglyceride esters, alkyl esters, alkenyl esters, lanolin, wax esters, beeswax derivatives, sterols and phospholipids, salts, isomers, and derivatives thereof, and combinations thereof.

[0065] Particularly suitable examples of conditioning agents include non-volatile silicone fluids other than those listed above under the heading "silicone oils," such as dimethicone copolyol, dimethylpolysiloxane, diethylpolysiloxane, mixed C1-30 alkylpolysiloxane, phenyldimethicone, dimethiconol, dimethicone, dimethiconol, silicone crosspolymers, and combinations thereof. Dimethicone may be particularly suitable because some consumers associate the feel properties provided by certain dimethicone fluids with good moisturizing.

[0066] thickener In some embodiments, the compositions of the present invention may further comprise one or more thickening agents.

[0067] Non-limiting classes of thickening agents include those selected from the following: carboxylic acid polymers, crosslinked polyacrylate polymers, polyacrylamide polymers, polysaccharides, and gums.

[0068] If present, the composition preferably comprises from about 0.01% to about 5%, more preferably from about 0.1% to about 4%, and even more preferably from about 0.1% to about 3%, by weight of the composition, of a thickening agent.

[0069] emulsifier When the composition is in the form of an emulsion, it may contain an emulsifier. The emulsifier may be nonionic, anionic, cationic, or zwitterionic. Some non-limiting examples of emulsifiers are disclosed in U.S. Patent Nos. 3,755,560 and 4,421,769, U.S. Patent Application Publication No. 2006 / 0275237, and McCutcheon's Detergents and Emulsifiers, North American Edition, pages 317-324 (1986). Suitable examples of emulsifiers include nonionic stearic acid derivative emulsifiers such as polysorbate-20, PEG-100 stearate, steareth-2, steareth-21, glyceryl-25 pyrrolidone carboxylic acid isostearate, and combinations thereof.

[0070] Other optional ingredients. The compositions herein may contain one or more optional ingredients known for use in topical cosmetic compositions, provided that the optional components do not unacceptably alter the desired benefits of the composition. In some cases, it may be desirable to select cosmetic active substances that function through different biological pathways so that the active substances do not interfere with each other. When the composition is in the form of an emulsion, the additional ingredients should not introduce instability (e.g., syneresis) into the emulsion. For example, it may be desirable to select optional ingredients that do not complex with other ingredients in the composition, particularly pH-sensitive ingredients such as vitamin B3 compounds, salicylates, and peptides.

[0071] Additional ingredients should be suitable for use in contact with human skin tissue without undue toxicity, incompatibility, instability, allergic response, etc. If present, optional ingredients may be included in an amount of about 0.001% to 50% by weight (e.g., 0.01% to 40%, 0.1% to 30%, 0.5% to 20%, or 1% to 10%) of the composition. Some non-limiting examples of additional ingredients include vitamins, minerals, peptides and peptide derivatives, sugar amines, sunscreens, oil control agents, microparticles, flavonoid compounds, hair growth regulators, antioxidants and / or antioxidant precursors, preservatives, protease inhibitors, tyrosinase inhibitors, anti-inflammatory agents, moisturizers, exfoliants, skin lightening agents, sunscreens, sunless tanning agents, lubricants, anti-acne agents, anti-cellulite agents, chelating agents, anti-wrinkle actives, anti-atrophy actives, phytosterols and / or plant hormones, N-acyl amino acid compounds, antibacterial agents, and antifungal agents. Some particularly suitable examples of additional ingredients include one or more skin care actives selected from the group consisting of vitamin B3 compounds (e.g., niacinamide), n-acyl amino acids (e.g., undecylenoyl phenylalanine), vitamin E compounds (e.g., tocopheryl acetate), palmitoylated dipeptides (e.g., palmitoyl-lysine-threonine), palmitoylated pentapeptides (e.g., palmitoyl-lysine-threonine-threonine-lysine-serine), vitamin A compounds (e.g., retinol and retinyl propionate), and combinations thereof.Other non-limiting examples of optional ingredients and / or skin care actives that may be suitable for use herein are described in U.S. Patent Application Publication Nos. 2002 / 0022040, 2003 / 0049212, 2004 / 0175347, 2006 / 0275237, 2007 / 0196344, 2008 / 0181956, 2008 / 0206373, 2010 / 0092408, 2008 / 0206373, 2010 / 0239510, 2010 / 0189669, 2010 / 019634 ... Nos. 010 / 0272667, 2011 / 0262025, 2011 / 0097286, 2012 / 0197016, 2012 / 0128683, 2012 / 0148515, 2012 / 0156146, and 2013 / 0022557, as well as U.S. Patent Nos. 5,939,082, 5,872,112, 6,492,326, 6,696,049, 6,524,598, 5,972,359, and 6,174,533.

[0072] Sucrose esters may be used herein. Such sucrose esters may be a blend of two or more sucrose esters, where the two or more sucrose esters are present in a ratio of 1:10 to 1:1 (e.g., 1:7, 1:5, 1:3, or 1:2) of any one sucrose ester to another. In some cases, the sucrose ester may be a blend of sucrose laurate and sucrose dilaurate, where the sucrose laurate is present at 50% to 80% by weight of the sucrose esters and the sucrose dilaurate is present at 20% to 45% by weight of the sucrose esters. Alternatively, the sucrose ester may be a blend of sucrose laurate, sucrose dilaurate, and sucrose trilaurate, where the sucrose dilaurate is present at 35% or more by weight of the sucrose esters. An example of a particularly suitable sucrose ester for use herein is sucrose dilaurate BC10034, available from BASF.

[0073] Method of using the cosmetic composition The method of use herein includes identifying a target area of skin on a human in need of treatment and applying the composition to the target area of skin during the treatment period. The target area of skin may be on the surface of the face, such as the forehead, perioral area, chin, periorbital area, nose, and / or cheeks, or on another part of the body (e.g., hands, arms, legs, back, chest). The human in need of treatment is one whose skin shows signs of oxidative stress, such as fine lines, wrinkles, hyperpigmentation, uneven skin tone, and / or other visible skin features typically associated with aging. In some cases, the target area of skin may not show visible signs of skin aging, but the user may still want to target such skin areas if they typically develop such problems as people age. In this way, the method can be used as a preventative measure to delay the onset of visible signs of skin aging.

[0074] The composition may be applied daily to the target area of skin, and to surrounding skin if desired, at least once daily, twice daily, or more frequently during the treatment period. If applied twice daily, there is an interval of at least 1 to 12 hours between the first and second applications. The composition is typically applied in the morning and / or at night before bedtime. The treatment period may last for at least one week (e.g., about two, four, eight, or even twelve weeks). In some cases, the treatment period will extend for several months (i.e., three to twelve months). In some cases, the composition may be applied at least once daily, or even twice daily, for the majority of days of the week (e.g., at least four, five, or six days per week) during a treatment period of at least two, four, eight, or twelve weeks.

[0075] The step of applying the composition can be performed by topical application. With respect to the application of the composition, the terms "topical," "topical," or "topically" mean that the composition is delivered to a target area (e.g., wrinkles or fine lines) while minimizing delivery to skin surfaces where treatment is not desired. The composition can be applied to a skin area and gently massaged in. The form of the composition or dermatologically acceptable carrier should be selected to facilitate topical application. While certain embodiments herein contemplate applying the composition to a region topically, it will be understood that the composition herein can be applied broadly to one or more skin surfaces. In certain embodiments, the composition herein can be used as part of a multi-step cosmetic regimen, in which case the composition can be applied before and / or after one or more other compositions.

[0076] combination A. A cosmetic product comprising a cosmetic composition contained in an applicator, a. the cosmetic composition comprises about 2% to about 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof, wherein the endothermic material has an endothermic value of 5 cal / g or more when dissolved in water; b. A cosmetic product, wherein the applicator comprises an application surface for applying a cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir. B. The cosmetic product according to Feature A, wherein the endothermic material is a sugar alcohol, preferably a sugar alcohol selected from the group consisting of xylitol, erythritol, sorbitol, and mixtures thereof, more preferably xylitol. C. The cosmetic product according to Feature A or B, wherein the composition comprises about 2.2% to about 7% of an endothermic material. D. A cosmetic product according to any one of Features A to C, wherein the composition further contains a silicone oil that is a mixture of a high molecular weight silicone having a viscosity of about 100,000 mPa·s to about 30,000,000 mPa·s and a silicone solvent having a viscosity of about 1 mPa·s to 5,000 mPa·s. E. The cosmetic product according to any one of Features A to D, wherein the silicone solvent has a viscosity of about 2 mPa·s to about 2,000 mPa·s. F. The cosmetic product according to any one of Features A to E, wherein the weight ratio of the high molecular weight silicone to the silicone solvent is from about 1:2 to about 1:100. G. The cosmetic product according to any one of Features A to F, wherein the weight ratio of high molecular weight silicone to endothermic material is about 1:10 to about 1:100, preferably about 1:15 to about 1:70, and more preferably about 1:20 to about 1:50. H. The cosmetic product according to any one of Features A to G, wherein the composition is substantially free of menthol and its derivatives. I. The cosmetic product according to any one of Features A to H, wherein the applicator surface is a rolling ball. J. The product according to any one of Features A to I, wherein the cosmetic is an eye care product. [Example]

[0077] Cosmetic composition (wt%)

[0078] [Table 1]

[0079] Details of the ingredients used in the table above

[0080] [Table 2]

[0081] Applicator Applicator 1: As used herein, an applicator comprises an application surface for applying a cosmetic composition, the application surface being a rolling ball comprising ceramic, and a reservoir having an opening fluidly connecting the application surface to the reservoir.

[0082] Applicator 2: As used herein, an applicator comprises an application surface for applying a cosmetic composition, the application surface being a rolling ball comprising metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir.

[0083] cosmetics

[0084] [Table 3]

[0085] Cosmetic Examples 1 to 6 are cosmetics of the present invention that are suitable for use as eye care products. The cosmetics of the present invention provide a moisturizing feeling while maintaining a moderate cooling sensation during and after application.

[0086] Dimensions and values disclosed herein should not be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise indicated, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm."

[0087] All documents cited herein, including any cross-referenced or related patents or patent applications, and any patent applications or patents to which this application claims priority or benefit, are incorporated herein by reference in their entirety, unless expressly stated to the contrary. The citation of any document shall not be deemed to be prior art to any invention disclosed or claimed herein, or to teach, suggest, or disclose any such invention, either alone or in combination with any other reference or references. Furthermore, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

[0088] While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims

1. A cosmetic product comprising a cosmetic composition contained in an applicator, the cosmetic composition comprises 2% to 20% of an endothermic material selected from the group consisting of sugar alcohols, disaccharides, and mixtures thereof; and a silicone oil which is a mixture of a high-molecular-weight silicone having a viscosity of 100,000 mPa·s or more and a silicone solvent having a viscosity of 1 mPa·s to 5,000 mPa·s, wherein the endothermic material has an endothermic value of 5 cal / g or more when dissolved in water; The applicator comprises an application surface for applying the cosmetic composition, the application surface comprising ceramic and / or metal, and a reservoir having an opening fluidly connecting the application surface to the reservoir.

2. The cosmetic product according to claim 1 , wherein the heat-absorbing material is a sugar alcohol.

3. The cosmetic product according to claim 2, wherein the heat-absorbing material is a sugar alcohol selected from the group consisting of xylitol, erythritol, sorbitol, and mixtures thereof.

4. The cosmetic product according to claim 3, wherein the heat-absorbing material is xylitol.

5. The cosmetic product according to any one of claims 1 to 4, wherein the composition comprises 2.2% to 7% of the endothermic material.

6. The cosmetic product according to claim 1, wherein the silicone solvent has a viscosity of 2 mPa·s to 2,000 mPa·s.

7. 2. The cosmetic product according to claim 1, wherein the weight ratio of the high molecular weight silicone to the silicone solvent is from 1:2 to 1:

100.

8. 2. The cosmetic product according to claim 1, wherein the weight ratio of the high molecular weight silicone to the endothermic material is 1:10 to 1:

100.

9. 9. The cosmetic product according to claim 8, wherein the weight ratio of the high molecular weight silicone to the endothermic material is 1:15 to 1:

70.

10. 10. The cosmetic product according to claim 9, wherein the weight ratio of the high molecular weight silicone to the endothermic material is 1:20 to 1:

50.

11. The cosmetic product according to claim 1, wherein the composition is free of menthol and its derivatives.

12. The cosmetic product of claim 1 , wherein the applicator surface is a rolling ball.

13. The cosmetic product according to claim 1 , wherein the cosmetic product is an eye care product.

Citation Information

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