Platinum and zinc-containing zeolites

Abstract

The present invention relates to a zeolite containing zinc and platinum, and a catalyst containing said zeolite.

Description

[Technical Field]

[0001] The present invention relates to a zeolite containing platinum and zinc and its use as an oxidation catalyst for purifying the exhaust gases of lean-burn internal combustion engines, in particular diesel engines. [Background technology]

[0002] Carbon monoxide CO, hydrocarbons HC, and nitrogen oxides NO x In addition, the untreated exhaust gases of diesel engines contain a relatively high oxygen content of up to 15% by volume, as well as particulate emissions consisting mainly of soot residues and in some cases organic agglomerates, which result from the partially incomplete combustion of fuel in the cylinder.

[0003] Carbon monoxide and hydrocarbons can be rendered harmless by diesel oxidation catalysts, but diesel particulate filters, with or without catalytically active coatings, are suitable for removing particulate emissions. Nitrogen oxides can be converted to nitrogen, for example, by selective catalytic reduction (SCR) over a so-called SCR catalyst using ammonia as the reducing agent. Ammonia can be made available by thermal decomposition and hydrolysis of ammonia precursor compounds fed to the exhaust gas. Examples of such precursor compounds are ammonium carbamate, ammonium formate, and preferably urea. Alternatively, ammonia can be formed by catalytic reactions in the exhaust gas. For the most complete conversion of nitrogen oxides in an SCR catalytic converter, it may be necessary to supply ammonia in superstoichiometric amounts, typically 10-20% above stoichiometric. This then results in unreacted ammonia in the exhaust gas, which is undesirable due to its toxic effects and greenhouse gas properties. As a result, exhaust gas regulations are increasingly restricting ammonia emissions.

[0004] To avoid ammonia emissions, so-called ammonia slip catalysts (ASC) have already been developed. These catalysts usually contain an oxidation catalyst for oxidizing ammonia at the lowest possible temperature. Such oxidation catalysts generally comprise a noble metal, such as palladium and especially platinum, on a support oxide, but have the drawback of oxidizing ammonia not only to nitrogen, water, and oxygen, but also to harmful species such as nitrous oxide (NO), nitric oxide (NO), and nitrogen dioxide (NO).

[0005] It is known that combining an oxidation catalyst with an SCR catalyst improves the selectivity of ammonia oxidation relative to nitrogen. Typically, the components are present in a layered arrangement, with the SCR layer usually forming the upper layer and arranged above the underlying oxidation layer. ASC catalysts are typically applied to monolithic support substrates, such as flow-through substrates or wall-flow filters. ASC catalysts of this type are known, for example, from EP 410440 A1, WO 02 / 100520 A1, EP 2117702 A2 and WO 2010 / 062730 A2.

[0006] However, there remains a need for ASC catalysts that have good selectivity for nitrogen, good thermal stability, and, in particular, form only small amounts of NO. Surprisingly, zeolites containing platinum and zinc have now been found to possess the required properties.

[0007] Platinum-impregnated Zn-ZSM-5 nanocatalyst for xylene isomerization reaction is described in Catalysis Letters 148(2), June 2018. A platinum and zinc-containing zeolite of structural type LTA for ethane oxidation is disclosed in Journal of Energy Chemistry, volume 30, March 2019, pages 42-48. US Patent Application Publication No. 2018 / 280945 discloses an ammonia slip catalyst comprising a zeolite containing zinc incorporated into the zeolite framework. GB 2552262(A) also discloses zeolites containing zinc incorporated into the zeolite framework. These products are used as oxidation catalysts for stoichiometrically operated natural gas engines. German Patent No. 1545293 discloses a method for preparing previously hydroformed hydrocarbons. In this method, platinum and zinc-containing zeolites of the structural type "zeolite A" and erionite can be used as catalysts. However, the document does not provide any information on the SAR values ​​of these zeolites. EP 2604590 A1 relates to a process for producing unsaturated hydrocarbons and discloses as catalysts zeolites of structural type MFI in the presence of, inter alia, platinum and zinc. The zeolites used have very high SAR values. JP 2013-163647(A) relates to a similar subject matter to EP 2604590(A1), in which zeolites of structural types MFI, FER and BEA are used as zeolites. Summary of the Invention [Means for solving the problem]

[0008] The present invention relates to a zeolite comprising zinc and platinum and selected from the group consisting of zeolites of structural type AEI, AFX, BEA, CHA, ERI, FER, KFI, LEV and MFI, wherein the zinc is present (i) as zinc cations in ion-exchanged form in the zeolite structure and / or (ii) as zinc oxide in and / or on the surface of the zeolite structure, and wherein the zeolite has an SAR (silica to alumina ratio) value of 2 to 1000.

[0009] Zeolites are two- or three-dimensional structures, the smallest of which are SiO4 and AlO4 tetrahedra. These tetrahedra combine to form larger structures, where two are always connected via a common oxygen atom. Rings of different sizes can be formed, for example, with 4, 6, or even 9 tetrahedrally coordinated silicon or aluminum rings. Various zeolite types are often defined by their maximum ring size, since this determines which guest molecules can and cannot penetrate the zeolite structure. A distinction is usually made between large-pore zeolites with a maximum ring size of 12 members, medium-pore zeolites with a maximum ring size of 10 members, and small-pore zeolites with a maximum ring size of 8 members.

[0010] Zeolites are further divided into structural types by the Structural Commission of the International Zeolite Association, each of which is assigned a three-letter code, see, e.g., Zeolite Framework Types, Elsevier, 5th edition, 2001.

[0011] Preferred zeolites are selected from the group consisting of zeolites of structural type AEI, AFX, CHA and FER.

[0012] Highly preferred zeolites belong to the structure type AEI. Another highly preferred zeolite belongs to the structure type AFX. Another highly preferred zeolite belongs to the structural type CHA. Another highly preferred zeolite belongs to the structure type FER.

[0013] The zeolites according to the invention in particular have an SAR (silica to alumina ratio) value of 2-500, preferably 2-100, particularly preferably 5-50.

[0014] In the context of the present invention, the term "zeolite" expressly does not include mixed oxides comprising aluminum oxide and silicon oxide, such as "SiO2 / Al2O3", as described in the literature.

[0015] The platinum in the zeolite according to the invention is preferably present as platinum cations in the zeolite structure, i.e. in ion-exchanged form, however, it may also be present wholly or partly as platinum metal and / or platinum oxide in the zeolite structure and / or on the surface of the zeolite structure.

[0016] The platinum may be present in an amount of 0.01 to 20% by weight, calculated as zinc metal and platinum metal, based on the combined weight of the zeolite, zinc, and platinum. Platinum is preferably present in an amount of preferably 0.5 to 10, particularly preferably 0.5 to 6% by weight, very particularly preferably 0.5 to 5% by weight, calculated as zinc metal and platinum metal, based on the total weight of zeolite, zinc and platinum.

[0017] In the zeolite, (i) according to the invention, zinc is present as zinc cations in ion-exchanged form in the zeolite structure, and / or (ii) as zinc oxide in and / or on the surface of the zeolite structure. This means, in particular, that the zinc according to the invention is not part of the zeolite framework or a component thereof. Zinc may be present in an amount of 0.01 to 20% by weight, calculated as zinc metal and platinum metal, based on the total weight of the zeolite, zinc, and platinum. Zinc is preferably present in an amount of preferably 0.5 to 10, particularly preferably 0.5 to 6% by weight, very particularly preferably 0.5 to 5% by weight, calculated as zinc metal and platinum metal, based on the total weight of zeolite, zinc and platinum.

[0018] The zeolite of material A preferably has a platinum to zinc mass ratio of 10:1 to 1:17, particularly preferably 6:1 to 1:10, very particularly preferably 1:2 to 1:7, with platinum calculated as platinum metal and zinc calculated as zinc metal.

[0019] The zeolite according to the invention can be produced by known methods. For example, it can be obtained by impregnating a zeolite, for example in the form of H or NH, with an aqueous solution of a mixture of corresponding amounts of platinum and zinc salts according to the incipient wetness method, followed by drying and calcination. In particular, platinum nitrate (Pt[NO]) is considered a water-soluble platinum salt, and in particular zinc acetate (Zn[Ac]) is considered a water-soluble zinc salt. The calcination of the impregnated zeolite is carried out in particular at a temperature of 250 to 550°C.

[0020] In an alternative process, an aqueous suspension of zeolite is mixed with a platinum salt, such as Pt-TEAH (tetraethylammonium), at an alkaline pH value such that platinum can be adsorbed onto the zeolite. The acidic pH value is then adjusted and zinc is added, for example in the form of zinc acetate.

[0021] In a preferred embodiment of the present invention, the zeolite according to the present invention is present on a support substrate.

[0022] The present invention therefore also relates to a catalyst comprising a support substrate of length L and a zeolite comprising zinc and platinum, the zeolite being selected from the group consisting of zeolites of structural type AEI, AFX, BEA, CHA, ERI, FER, KFI, LEV and MFI, the zinc being present (i) as zinc cations in ion-exchanged form in the zeolite structure and / or (ii) as zinc oxide in and / or on the surface of the zeolite structure, and the zeolite having an SAR (silica to alumina ratio) value of 2 to 1000.

[0023] The support substrate can be a flow-through substrate or a wall-flow filter. A wall-flow filter is a carrier substrate with channels of length L that run parallel between a first end and a second end of the wall-flow filter and are alternately closed at either the first end or the second end and separated by porous walls. Flow-through substrates differ from wall-flow filters, inter alia, in that the channels of length L are open at both ends.

[0024] In an uncoated state, the wall-flow filter has a porosity of, for example, 30 to 80%, specifically 50 to 75%. In an uncoated state, the wall-flow filter has an average pore size of, for example, 5 to 30 micrometers. Generally, the pores of wall-flow filters are so-called open pores, i.e., they have connections to channels. Furthermore, the pores are generally interconnected with one another. This allows, on the one hand, easy coating of the inner pore surfaces and, on the other hand, easy passage of exhaust gases through the porous walls of the wall-flow filter.

[0025] Like wall-flow filters, flow-through substrates are known to those skilled in the art and are commercially available. They are made of, for example, silicon carbide, aluminum titanate, or cordierite.

[0026] In one embodiment of the catalyst according to the invention, the zeolite comprising zinc and platinum is present in the form of a coating on a support substrate, whereby the coating may extend over the entire length L of the support substrate or over only a portion thereof. In both cases, the support substrate may also carry one or more further catalytically active coatings.

[0027] In the case of a wall-flow filter, the coating may be located on the surface of the inlet channel, on the surface of the outlet channel, and / or within the porous wall between the inlet and outlet channels.

[0028] The catalyst according to the present invention, in which the zeolite containing zinc and platinum is present in the form of a coating on a support substrate, can be produced by methods well known to those skilled in the art, for example, by conventional dip coating or by pump coating and suction coating with subsequent thermal post-treatment (calcination). Those skilled in the art will recognize that in the case of wall-flow filters, the average pore size and average particle size of the coating material can be adapted to each other so that it is present on the porous walls forming the channels of the wall-flow filter (on-wall coating). The average particle size of the coating material can also be selected so that it is located within the porous walls forming the channels of the wall-flow filter, i.e., so that the inner pore surfaces are coated (in-wall coating). In this case, the average particle size of the coating material must be small enough to penetrate into the pores of the wall-flow filter.

[0029] In another embodiment of the present invention, the support substrate is formed from a zeolite that also contains zinc and platinum and a matrix component. Those skilled in the art are familiar with support substrates, flow-through substrates, and wall-flow substrates that do not simply consist of an inert material such as cordierite, but also contain a catalytically active material. To produce them, a mixture consisting of 10 to 95% by weight of an inert matrix component and 5 to 90% by weight of a catalytically active material is extruded, for example, according to a method known per se. In this case, all inert materials that are otherwise used to produce catalyst substrates can be used as matrix components. These are, for example, silicates, oxides, nitrides, or carbides, and magnesium aluminum silicate is particularly preferred. In some embodiments of the present invention, the extruded support substrate containing zinc and platinum, ie, zeolite, may be coated with one or more catalytically active coatings.

[0030] In another embodiment of the present invention, a carrier substrate is used that is composed of a corrugated sheet of an inert material. Such carrier substrates are known to those skilled in the art as "corrugated substrates." Suitable inert materials are, for example, fibrous materials having an average fiber diameter of 50 to 250 μm and an average fiber length of 2 to 30 mm. Preferably, the fibrous material is heat-resistant and consists of silicon dioxide, especially glass fibers. In the manufacture of such a carrier substrate, for example, sheets of the aforementioned fibrous material are corrugated in a known manner, and the individual corrugated sheets are formed into cylindrical monolithic structures having channels extending through their bodies. Preferably, monolithic structures having transverse corrugations are formed by stacking several corrugated sheets in parallel layers with different corrugation orientations between the layers. In one embodiment, non-corrugated (i.e., flat) sheets can be placed between the corrugated sheets. Substrates made from corrugated sheet can be directly coated with zeolites containing zinc and platinum, but it is preferred to first coat them with an inert material, such as titanium dioxide, and then only then with the catalytic material.

[0031] A catalyst according to the present invention in which the zeolite containing zinc and platinum is present in the form of a coating on a support substrate may be used as an ammonia slip catalyst or the like. The present invention therefore also relates to a method for oxidizing ammonia contained in an exhaust gas stream, characterized in that the exhaust gas stream is passed over a catalyst according to the invention.

[0032] Furthermore, the invention also includes a device for purifying the exhaust gases of a diesel engine, which comprises a catalyst according to the invention. In addition to the catalyst according to the invention, the device according to the invention especially comprises an SCR catalyst. DETAILED DESCRIPTION OF THE INVENTION

[0033] Example 1 First, a mixed platinum nitrate / zinc acetate solution is prepared, the volume of which corresponds to a 50 percent water absorption of the zeolite (a commercially available zeolite of structural type CHA). Based on the final composition of the platinum and zinc-containing zeolite, 0.42 wt.% platinum and 0.07 wt.% zinc (mass ratio Pt:Zn = 6:1) are applied to the zeolite in a mechanical mixer. Subsequent heat treatment involves drying at 120°C, calcination at 350°C, and annealing at 550°C in air. In the subsequent washcoat preparation, 10% (based on total loading) of a commercially available aluminum oxide sol is added, whereby a commercially available support substrate made of ceramic is coated with a washcoat loading of 25 g / L, which is finally dried at 120°C, calcined at 350°C, and tempered at 550°C. The catalyst obtained is hereinafter referred to as K1.

[0034] Example 2 Example 1 is repeated, except that the amount of zinc is 0.2 wt % (mass ratio Pt to Zn=2:1). The catalyst obtained is hereinafter referred to as K2.

[0035] Example 3 Example 1 is repeated, except that the amount of zinc is 0.6 wt % (mass ratio Pt to Zn=1:1.5). The catalyst obtained is hereinafter referred to as K3.

[0036] Example 4 Example 1 is repeated, except that the amount of zinc is 2.64 wt % (mass ratio Pt to Zn=1:6.6). The catalyst obtained is hereinafter referred to as K4.

[0037] Comparative Example 1 Example 1 is repeated, except that no zinc is used. The catalyst obtained is hereinafter referred to as VK1.

[0038] Example 5 Commercially available zeolite of structural type CHA was first placed in water and the pH was adjusted to 10. Pt-TEAH was then added and the suspension was stirred for 24 hours. Subsequently, the pH was adjusted to 6, and zinc acetate and 10% aluminum oxide sol were added. The mass ratio of Pt to Zn was 1:1.7. Following linear grinding, a commercially available ceramic support substrate is then coated with a washcoat amount of 25 g / L. Final temperature treatment in air includes drying at 120°C, followed by calcination and tempering at 350°C and 550°C. The total precious metal concentration on the final catalyst (hereinafter referred to as K5) is 0.42 wt%.

[0039] Comparative Example 2 After the addition of Pt-TEAH, the mixture is stirred for 20 hours and Example 5 is repeated, except that no zinc is used. The catalyst obtained is hereinafter referred to as VK2.

[0040] Measurement of NH3 light-off and N2O formation a) Aging Four drill cores were cut from each of catalysts K1 to K5 and VK1 and VK2, two of which were measured fresh and two of which were measured after 16 hours of hydrothermal aging in an oven at 800 °C (10% H2O, 10% O2, balance N2) (hereafter referred to as 16H800).

[0041] b) Test conditions in laboratory reactors In a laboratory reactor, a synthetic test exhaust gas consisting of 300 ppm NH, 5% O, 5% H, O, balance nitrogen (Test A or B) or a test exhaust gas consisting of 300 ppm NH, 200 ppm NO, 5% O, 5% H, O, balance N (Test C or D) was passed through the drill core obtained according to A) at 1950 L / h. In this case, the temperature of the test exhaust gas after the conditioning phase (150 to 600 °C at about 30 K / min in 5% O, balance N) was increased from 150 to 600 °C at 10 K / min and the NH reaction was measured by conventional methods.

[0042] c) Result The table below shows the results obtained.

[0043] [Table 1]

[0044] [Table 2]

[0045] [Table 3]

[0046] [Table 4]

[0047] The test results show that as a function of the zinc content of the inventive catalysts K1-K4 or K5, the light-off temperature for ammonia is reduced compared to the comparative catalysts VK1 and VK2, which contain only platinum. This higher activity results in higher NO formation, but lower, not higher, NO formation. Thus, the addition of zinc results in higher NO selectivity and lower NO selectivity. However, higher NO selectivity is not a disadvantage, since NO can be converted to nitrogen and oxygen by the SCR layer.

Claims

1. A method for the oxidation of ammonia contained in an exhaust gas stream, characterized in that the exhaust gas stream is carried out over a zeolite, 1. The method of claim 1, wherein the zeolite comprises zinc and platinum and is selected from the group consisting of zeolites of structure type AEI, AFX, BEA, CHA, ERI, FER, KFI, LEV, and MFI, wherein the zinc is present (i) as zinc cations in ion-exchanged form in the zeolite structure, and / or (ii) as zinc oxide in and / or on the surface of the zeolite structure, and wherein the zeolite has a SAR (silica to alumina ratio) value of 2 to 1000.

2. The method according to claim 1, characterized in that the zeolite is selected from the group consisting of zeolites of structural types AEI, AFX, CHA and FER.

3. The method described in claim 1 or 2, characterized in that the zeolite belongs to structural type AEI.

4. The method described in claim 1 or 2, characterized in that the zeolite belongs to the structural type AFX.

5. The method described in claim 1 or 2, characterized in that the zeolite belongs to the structural type CHA.

6. The method described in claim 1 or 2, characterized in that the zeolite belongs to the structural type FER.

7. 7. The method according to claim 1, wherein the zeolite has a SAR (silica to alumina molar ratio) value of between 2 and 500.

8. 8. The method according to claim 1, wherein the zeolite has a SAR (silica to alumina ratio) value between 2 and 100.

9. 9. The method according to any one of claims 1 to 8, characterized in that the zeolite has a SAR (silica to alumina ratio) value of between 2 and 50.

10. A method according to any one of claims 1 to 9, characterized in that the platinum is present in the zeolite in an amount of 0.01 to 20% by weight, calculated as zinc metal and platinum metal, based on the total weight of the zeolite, zinc and platinum.

11. A method according to any one of claims 1 to 10, characterized in that the zinc is present in the zeolite in an amount of 0.01 to 20% by weight, calculated as zinc metal and platinum metal, based on the total weight of the zeolite, zinc and platinum.

12. A method according to any one of claims 1 to 11, characterized in that the mass ratio of platinum to zinc in the zeolite is 6:1 to 1:7, with platinum calculated as platinum metal and zinc calculated as zinc metal.

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