Optical Camouflage Filter

Abstract

An optical filter that prevents undesirable optical interference due to visible wavelengths, or camouflages an electromagnetic radiation source from vision, while at least partially allowing desired near-infrared wavelengths to be transmitted by a light emitter or received by a light receiver, or at the same time, allowing transmission of near-infrared wavelengths with relatively high transparency. [Solution] The article includes an optical filter comprising a wavelength-selective reflective layer and at least one wavelength-selective absorbing layer. The optical filter has a visible transmittance of less than 30% in the 400nm to 700nm range and a near-infrared transmittance of greater than 30% in the 830nm to 900nm range.

Description

[Background technology]

[0001] (Related Applications) This application is related to U.S. Patent Application No. 62 / 281,643, filed January 21, 2016, and International Application No. PCT / CN2016 / 081271, filed May 6, 2016, which applications are incorporated by reference herein in their entireties.

[0002] Light can reflect from a surface in different ways, for example, as specular or diffuse reflection. In opaque materials, specular reflection can occur on the top layer of the material, for example, at the air / material interface, and reflection can transmit the entire spectrum of the incident light. Specular reflection can appear as a shine or gloss, which can account for less than 4% of the total reflected light. In contrast, diffuse reflection can occur below the surface of the material, and can transmit selected wavelengths or colors. For example, color can be seen in the diffuse reflection of a non-metallic object. In hybrid surfaces, such as a surface containing a paint coat covered with a clear finish, both types of reflection can be observed. Thus, specular reflection can occur at the air / finish interface, and diffuse reflection can occur at the finish / paint interface.

[0003] Optical filters are used in a wide variety of applications, including optical communication systems, sensors, imaging, scientific and industrial optical instruments, and display systems. Optical filters can include optical layers that manage the transmission of incident electromagnetic radiation, including light. Optical filters can reflect or absorb portions of the incident light and transmit other portions of the incident light. The optical layers within an optical filter can differ in wavelength selectivity, optical transmittance, optical clarity, optical haze, and refractive index. Summary of the Invention

[0004] In some embodiments, the article comprises an optical filter comprising a wavelength-selective reflective layer and at least one wavelength-selective absorbing layer, the optical filter having a visible transmittance of less than about 30% from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm.

[0005] Some embodiments relate to a printed article including an optical filter. The optical filter includes a wavelength-selective reflective layer and at least one printed wavelength-selective absorbing layer. The optical filter has a visible transmittance of less than about 30% from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm.

[0006] According to some embodiments, a system includes one or both of a light emitter and a light receiver, and an optical filter adjacent to one or both of the light emitter and the light receiver. The optical filter includes a wavelength-selective reflective layer and at least one wavelength-selective absorbing layer. The optical filter has a visible transmittance of less than about 30% from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm.

[0007] In some embodiments, the article comprises an optical filter, the optical filter comprising a wavelength-selective reflective layer and at least one wavelength-selective absorbing layer having a visible absorption of greater than about 30% from 400 nm to 700 nm, the optical filter having a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm.

[0008] According to some embodiments, a system includes one or both of a light emitter and a light receiver, and an optical filter adjacent to one or both of the light emitter and the light receiver. The optical filter includes a wavelength-selective reflective layer having a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm. The optical filter includes at least one wavelength-selective absorbing layer having a visible absorption of greater than about 30% from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% from 830 nm to 900 nm.

[0009] In some embodiments, the article includes an optical filter. The optical filter includes a wavelength-selective scattering layer including at least one of a dye and a pigment. The wavelength-selective scattering layer scatters visible wavelengths between 400 nm and 700 nm and transmits near-infrared wavelengths between 830 nm and 900 nm. The optical filter further includes a wavelength-selective reflective layer configured to transmit near-infrared wavelengths between 830 nm and 900 nm.

[0010] Some embodiments relate to a method of making an optical filter, comprising forming a wavelength-selective absorbing layer and a wavelength-selective reflecting layer such that the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm, and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0011] The details of one or more aspects of various embodiments are set forth in the accompanying drawings and the description below. [Brief explanation of the drawings]

[0012] [Figure 1A] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1B] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1C] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1D] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1E] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1F] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1G] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1H] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1I] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1J] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 1K] 1 is a cross-sectional view of an exemplary article including an optical filter. [Figure 2A] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2B] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2C] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2D] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2E] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2F] 1 is a conceptual diagram of an exemplary system including an optical filter. [Figure 2G] 1A and 1B are front and back views, respectively, of an article including an optical filter, the article being configured to conform to an object. [Figure 2H] 1A and 1B are front and back views, respectively, of an article including an optical filter, the article being configured to conform to an object. [Figure 3A] FIG. 1 is a conceptual diagram of an exemplary system including an exemplary optical filter and an electronic display showing visible and invisible near-infrared patterns. [Figure 3B] FIG. 1 is a conceptual diagram of an exemplary system including an exemplary optical filter and an electronic display showing visible and invisible near-infrared patterns. [Figure 3C] FIG. 1 is a conceptual diagram of an exemplary system including an exemplary optical filter and an electronic display showing visible and invisible near-infrared patterns. [Figure 3D] FIG. 1 is a conceptual diagram of an exemplary system including an exemplary optical filter and an electronic display showing visible and invisible near-infrared patterns. [Figure 4]1 is a flowchart of an exemplary technique. [Figure 5] 1 is a photograph of an exemplary article including an exemplary optical filter and an ink pattern. [Figure 6A] This is a photo of a solar panel. [Figure 6B] 1 is a photograph of a solar panel camouflaged with an exemplary optical filter. [Figure 7] 1 is a photograph of an exemplary article including an exemplary optical filter and an ink pattern. [Figure 8A] 1 is a photograph of an exemplary system including an exemplary optical filter and a near-infrared LED. [Figure 8B] 1 is a photograph of an exemplary system including an exemplary optical filter and a near-infrared LED. [Figure 8C] 1 is a photograph of an exemplary system including an exemplary optical filter and a near-infrared LED. [Figure 9] 1 is an atomic force microscopy (AFM) photograph of the surface of an exemplary optical filter. [Figure 10A] 1 is a scanning electron microscopy (SEM) photograph of an exemplary optical filter. [Figure 10B] 1 is a scanning electron microscopy (SEM) photograph of an exemplary optical filter. [Figure 11] 1 is a chart showing % reflectance and % transmittance versus wavelength for exemplary optical filters. [Figure 12A] 1 is a chart showing % transmission versus wavelength for exemplary optical filters. [Figure 12B] 1 is a chart showing % transmission versus wavelength for exemplary optical filters. [Figure 13] 1 is a chart showing % transmission versus wavelength for exemplary optical filters. [Figure 14]1 is a chart illustrating Mie scattering results showing scattering efficiency versus wavelength for an exemplary optical filter. [Figure 15] 1 is a chart illustrating near-infrared scattering ratio as a function of particle size and refractive index difference for an exemplary wavelength-selective scattering layer including a medium and a plurality of particles. [Figure 16A] 1 is a photograph comparing the wet-out of a near-infrared film with and without a near-infrared black ink coating. [Figure 16B] 1 is a photograph comparing the wet-out of a near-infrared film with and without a near-infrared black ink coating. [Figure 16C] 1 is a photograph comparing the wet-out of a near-infrared film with and without a near-infrared black ink coating. [Figure 16D] 1 is a photograph comparing the wet-out of a near-infrared film with and without a near-infrared black ink coating. [Figure 17] 16A-16D are charts showing % transmittance versus wavelength for the near-infrared films of FIGS. 16A-16D. [Figure 18A] 1 is a photograph of an exemplary near-infrared film including a colored absorbing layer. [Figure 18B] 1 is a photograph of an exemplary near-infrared film including a colored absorbing layer. [Figure 19] 1 is a chart showing % transmission versus wavelength for a reflective multilayer optical film coated with a near-infrared anti-reflective coating compared to a reflective multilayer optical film without a near-infrared anti-reflective coating. [Figure 20A] 1 is a photograph of an exemplary system including an infrared LED with a visible light component. [Figure 20B] 1 is a photograph of an exemplary system including an infrared LED having a visible light component filtered by a reflective multilayer optical film without an absorbing layer. [Figure 21]1 is a chart showing % transmission versus wavelength for a reflective multilayer optical film without an infrared dye coating. [Figure 22] 1 is a chart showing % transmission versus wavelength for a reflective multilayer optical film having an infrared dye coating compared to a comparative optical filter having no dye coating. [Figure 23] 1 shows a graph of the transmittance at normal incidence for five film samples with increasing dye loading. [Figure 24] The transmittance of a dye laminated to a mirror film is shown at normal incidence, 20 degrees and 60 degrees from normal incidence. [Figure 25] The transmittance of a dye laminated to a mirror film is shown at normal incidence, 20 degrees and 60 degrees from normal incidence. [Figure 26] 1 shows a modeled graph of samples at normal incidence with dye concentrations varying from 3 to 34.7% laminated to an optimized mirror film. [Figure 27] This shows the transmittance of light transmitted through the mirror at normal incidence. [Figure 28] The same data is plotted as in Figure 26, but using a transmittance scale of 0 to 0.1%. [Figure 29] 1 shows the transmittance of a wavelength-selective reflective polarizer. [Figure 30] FIG. 29 shows the transmission of samples at normal incidence with dye concentrations varying from 3 to 34.7% in combination with a reflective polarizer.

[0013] It should be understood that certain illustrative features of the present disclosure are not necessarily drawn to scale, and that the figures are non-exclusive examples of the technology disclosed herein. DETAILED DESCRIPTION OF THE INVENTION

[0014] In this disclosure, "visible" refers to wavelengths in the range of about 400 nm to about 700 nm, and "near infrared" refers to wavelengths in the range of about 700 nm to about 2000 nm, e.g., about 800 nm to about 1200 nm. ULI (ultra-low index) film refers to an optical film comprising a binder, a plurality of particles, and a plurality of interconnected voids, as described in U.S. Patent Application Publication No. 2012 / 0038990, the entirety of which is incorporated herein by reference.

[0015] Ambient electromagnetic radiation sources can interfere with receivers configured to receive light of specific wavelengths or from specific light sources, or with emitters configured to emit light of specific wavelengths. For example, visible wavelengths can interfere with the reception, sensing, or transmission of near-infrared wavelengths, e.g., by increasing noise in the receiver or emitter. Electromagnetic radiation sources can also be unintentionally revealed. For example, light emitted by an emitter configured to emit only near-infrared wavelengths is not visible, but the device or structure responsible for the emission, e.g., the emitter's housing, can be visible. Masking, concealing, or otherwise camouflaging an emitter can present challenges because camouflage techniques can unnecessarily block, interfere with, or reduce the transmission of desired near-infrared wavelengths. Optical filters according to examples of the present disclosure may be used to prevent unwanted optical interference from visible wavelengths or camouflage electromagnetic radiation sources from view, while at least partially allowing desired near-infrared wavelengths to be transmitted by an emitter or received by an optical receiver, or while allowing transmission of near-infrared wavelengths with relatively high transparency.

[0016] For example, an optical receiver operative to receive or sense near-infrared wavelengths can be shielded from visible wavelengths to prevent interference with the reception or sensing of near-infrared wavelengths that may occur from visible wavelengths. An optical transmitter operative to transmit near-infrared wavelengths can be camouflaged to the human eye by scattering visible wavelengths. For example, the scattered visible wavelengths can conceal the presence of the optical transmitter without interfering with the transmission of near-infrared wavelengths.

[0017] The amount of specular reflection from a surface can be determined by the Fresnel reflection of the air interface. For an opaque surface with a transparent top layer, it can be assumed that all specular reflection comes from the upper air interface, and the remaining reflection is diffuse reflection from the lower layer. Opaque colored materials could also follow a similar model, using their refractive index to calculate the Fresnel reflection on the top surface and treating all other reflections as diffuse. An exemplary optical filter could have a diffusive coating disposed on a transparent substrate or a reflective film. If the diffusive coating is coated on a transparent substrate, it may have a higher haze to hide the underlying elements. If the coating is coated on a reflector, the coating will diffuse the incident light twice by reflection. In this case, the coating may have less haze.

[0018] Thus, exemplary systems may include an optical filter including one or both of a light receiver and a light emitter and a wavelength-selective scattering layer that can at least partially reduce the transmission of visible wavelengths while at least partially allowing the transmission of near-infrared wavelengths. For example, the wavelength-selective scattering layer can scatter a large portion of incident visible light. Exemplary systems and articles according to the present disclosure may include exemplary optical articles that include an exemplary wavelength-selective scattering layer that transmits near-infrared light with relatively high transparency while reducing the transmission of visible wavelengths, for example, by selectively scattering or reflecting the visible wavelengths.

[0019] 1A-1K are cross-sectional views of exemplary articles including optical filters. FIG. 1A shows a cross-sectional view of exemplary article 10a. Article 10a includes a substrate 12 and a wavelength-selective scattering layer 14. Substrate 12 can include glass, a polymer, a metal, or any other suitable rigid, semi-rigid, or flexible material, and combinations thereof. While substrate 12 is shown as a layer in exemplary article 10a of FIG. 1A, in various examples, substrate 12 can take any suitable three-dimensional form, including a flat, substantially flat, or textured surface. In various examples, substrate 12 can include a housing, a screen, a component, or a surface of a device, such as a personal computing or communication device, e.g., an electronic device such as a mobile phone or a smartwatch. In some embodiments, substrate 12 can be flexible. In some embodiments, substrate 12 can include glass or a polymer.

[0020] One or more layers of the optical filter may be laminated or adhered to the substrate 12, or may be integrally formed on the substrate 12. In some embodiments, the substrate 12 may be a molded component. In some embodiments, the substrate 12 may be a molded part. One or more layers of the optical filter, e.g., one or more of the wavelength-selective layers 14, 16, 34, may be applied to the substrate 12 during an insert injection molding process. For example, the wavelength-selective layers 14, 16, 34 (and / or other layers of the optical filter) may be placed in an injection mold prior to molding. After the layers are placed in the mold, a molding material is injected into the injection mold to form the molded substrate. The injection-molded substrate with the attached optical filter layers is then removed from the mold.

[0021] The optical filters according to any of the examples 10a-10k shown in Figures 1A-1K may be formed into two-dimensional or three-dimensional shapes. In some embodiments, one or more of the wavelength-selective layers 14, 16, 34 (and / or other layers of the optical filter) may be formed into a three-dimensional shape before or after being disposed on and / or attached to the substrate 12. The optical filters according to any of the examples 10a-10k shown in Figures 1A-1K may be flexible. The optical filters according to any of the examples 10a-10k shown in Figures 1A-1K may include various features, including slots, holes, protrusions, and / or other features.

[0022] The wavelength-selective scattering layer 14 selectively scatters visible light and transmits near-infrared light. In various examples, the wavelength-selective scattering layer can have a near-infrared scattering ratio of less than about 0.9, less than about 0.8, less than about 0.7, less than about 0.6, or less than about 0.5. The near-infrared scattering ratio is the ratio of average near-infrared scattering to average visible scattering. For example, the average scattering within a selected narrow or wide near-infrared wavelength band (e.g., bandwidths of 1300 nm, 500 nm, 100 nm, 10 nm, or 1 nm) can be determined, and the average scattering within a selected narrow or wide visible wavelength band can be determined, and the ratio of the respective averages can be determined. For example, the wavelength-selective scattering layer 14 can have a visible reflective haze greater than about 0.5, greater than about 0.7, or greater than about 0.9. The visible reflective haze is the ratio of average visible diffuse reflectance to average visible total reflectance. In some examples, the wavelength-selective scattering layer 14 can transmit less than about 50% of the incident visible light. In some examples, the wavelength-selective scattering layer 14 can transmit more than about 50% of the incident near-infrared light. In some examples, the wavelength-selective scattering layer 14 can transmit less than about 50% of the incident visible light and transmit more than about 50% of the incident near-infrared light. In some examples, the wavelength-selective scattering layer 14 can scatter more than about 50% of the incident visible light. For example, the wavelength-selective scattering layer 14 can transmit less than about 50% of the incident visible light by scattering more than about 50% of the incident visible light. In some examples, the wavelength-selective scattering layer 14 can scatter more than about 50% of the incident visible light as white light.

[0023] The wavelength-selective scattering layer 14 may include a medium and a plurality of particles having respective predetermined refractive indices. In some examples, the wavelength-selective scattering layer 14 may include a beaded diffusing layer. For example, the wavelength-selective scattering layer 14 may include a medium and beads dispersed in the medium. The medium of the beaded diffusing layer may include glass, a polymer, or any other suitable optical medium, or a combination thereof. The beads may include silica, glass, a polymer, an organic, an inorganic, a metal oxide, polystyrene, or other suitable scattering material, or a combination thereof. The diffusing layer may include pores containing a gas, such as air. In some examples, the pores containing the gas may be enclosed within the beads.

[0024] The wavelength-selective scattering layer 14 may include an optical medium having a first refractive index. The optical medium may include a plurality of particles. The plurality of particles may have a second refractive index such that the absolute difference between the first refractive index and the second refractive index is less than about 0.1. In some examples, the plurality of particles may have an average particle size less than about 5 μm, and the absolute difference between the first refractive index and the second refractive index may be less than about 0.1. In some examples, the plurality of particles may have an average particle size less than about 1 μm, and the absolute difference between the first refractive index and the second refractive index may be less than about 0.2. In some examples, the plurality of particles may have an average particle size less than about 0.5 μm, and the absolute difference between the first refractive index and the second refractive index may be less than about 0.4. In some examples, the plurality of particles may have an average particle size less than about 0.3 μm, and the absolute difference between the first refractive index and the second refractive index may be less than about 0.6. In some examples, the plurality of particles may have an average particle size less than about 0.2 μm, and the absolute difference between the first refractive index and the second refractive index may be less than about 1.8.

[0025] In some examples, the average particle size, the first refractive index, and the second refractive index of the particles are selected from the area below line 82 in FIG. 15 below. Therefore, the near-infrared scattering ratio of the wavelength-selective scattering layer 14 can be less than 0.2. In some examples, the average particle size, the first refractive index, and the second refractive index of the particles are selected from the area below line 84 in FIG. 15 below. Therefore, the near-infrared scattering ratio of the wavelength-selective scattering layer 14 can be less than 0.4. In some examples, the average particle size, the first refractive index, and the second refractive index of the particles are selected from the area below line 86 in FIG. 15 below. Therefore, the near-infrared scattering ratio of the wavelength-selective scattering layer 14 can be less than 0.6. In some examples, the average particle size, the first refractive index, and the second refractive index of the particles are selected from the area below line 88 in FIG. 15 below. Therefore, the near-infrared scattering ratio of the wavelength-selective scattering layer 14 can be less than 0.8. In examples, the near-infrared scattering ratio of the wavelength-selective scattering layer 14 can be less than 0.7, or less than 0.5. In examples, the area under each of lines 82, 84, 86, 88, or any other area, can be bounded by a lower particle size limit. For example, the area can include only particle sizes greater than 10 nm, or 30 nm, or 50 nm, or larger than the particle size at which Rayleigh scattering can occur or dominate.

[0026] In various examples, the wavelength-selective scattering layer 14 may have a total visible reflectance of less than 50%, at least 50%, at least 60%, or at least 70%. In various examples, the total visible reflectance may be less than 50%, and the wavelength-selective scattering layer 14 may conceal objects through visible haze. In various examples, the total visible reflectance may be greater than 50%, and the wavelength-selective scattering layer 14 may conceal objects through a combination of visible reflection and visible haze. In various examples, the wavelength-selective scattering layer 14 may have an average near-infrared scattering of less than 60%, or less than 40%. In various examples, the wavelength-selective scattering layer may have an average visible scattering of greater than 10%, or greater than 25%, or greater than 58%. In various examples, the difference between the % total visible reflectance and the % diffuse visible reflectance of the wavelength-selective scattering layer 14 may be less than 20%. In examples, the wavelength-selective scattering layer may have an average near-infrared scattering of less than 40% and an average visible scattering of greater than 58%, and the difference between the % total visible reflectance and the % diffuse visible reflectance may be less than 18.

[0027] In examples, the wavelength-selective scattering layer 14 may have a visible haze of at least 15%, or at least 25%, or at least 35%, or at least 50%. In examples, the optical filter 10a may include a surface optical microstructure, such as a microreplicated surface structure.

[0028] In some examples, the wavelength-selective scattering layer 14 may include a ULI layer including a binder, a plurality of particles, and a plurality of interconnected voids. The volume fraction of the interconnected voids in the optical filter may be about 20% or greater. The weight ratio of the binder to the plurality of particles may be about 1:2 or greater.

[0029] The wavelength-selective scattering layer 14 may be configured to transmit near-infrared wavelengths, e.g., wavelengths between 830 nm and 900 nm, 900 nm and 980 nm, and / or 800 nm and 1200 nm, and to scatter at least visible wavelengths, e.g., wavelengths between 400 nm and 700 nm. The wavelength-selective scattering layer 14 may include one or both of a dye and a pigment that scatters light. For example, the wavelength-selective scattering layer 14 may include a coating containing a dye and / or a pigment. The dye and / or pigment may contain more than about 11%, more than about 12%, more than about 13%, or even more than about 14% solids. The dye and / or pigment of the wavelength-selective scattering layer 14 may include one or both of a black dye and / or pigment and a color dye and / or pigment, e.g., a cyan, magenta, and / or yellow color dye or pigment. In some embodiments, the absorber, e.g., dye or pigment, may be one absorber material or a combination of more than one absorber material, for example, multiple dyes, pigments, and / or other absorber materials may be combined in any manner, such as mixed together and / or layered on top of one another.

[0030] FIG. 1B shows a cross-sectional view of an exemplary article 10b. Article 10b can include a substrate 12, a wavelength-selective scattering layer 14, and a reflective layer 16. Although article 10b shows the reflective layer 16 between the wavelength-selective scattering layer 14 and the substrate 12, in some examples, article 10b does not include a substrate 12, and the wavelength-selective scattering layer can be disposed on the reflective layer 16. In some examples, substrate 12 can include the reflective layer 16, for example, on a major surface of or within the substrate 12. In some examples, the reflective layer 16 can be disposed below the substrate 12. In some examples, the reflective layer 16 can be disposed above the substrate 12. In some examples, the reflective layer 16 can be perforated. In some examples, article 10b can reflect less than 50% of visible light and transmit more than 50% of near-infrared light. In some examples, the reflective layer 16 can be wavelength-selective, for example, reflecting only selected wavelengths. The reflective layer 16 may include a reflective surface such as a multilayer optical film, a dichroic reflector, an interference film, an inorganic multilayer stack, a metal-dielectric stack, a polished substrate, a mirror, a reflective polarizer, or a reflective metal or glass surface. In some examples, the article 10b may include a dye layer (not shown) located between the reflective layer and the wavelength-selective scattering layer 14, above the wavelength-selective scattering layer 14, or adjacent to any layer within the article 10b. The dye layer may include a spectrally selective dye that can be transmissive or transparent in the near infrared and neutral in the visible, thereby reducing the visible reflectance of the reflective layer 16. In some examples, the dye layer may have an absorption of at least 30%, 50%, 70%, or 90%. In some examples, the dye layer may be tinted to have a visible color while remaining transmissive in the near infrared.

[0031] FIG. 1C shows a cross-sectional view of an exemplary article 10c. The article 10c may include a substrate 12 and a wavelength-selective scattering layer 14. The article 10c may optionally include one or more of a reflective layer 16, an ink-receiving layer 18, a printed pattern layer 22, and a protective layer 24, as shown in FIG. 1C. Although FIG. 1C shows a specific arrangement for the layers in the article 10c, the layers may be rearranged in any suitable configuration. For example, if the reflective layer 12 is present, the substrate 16 may be omitted. The protective layer 24 may include a sealant layer. In some examples, the ink pattern layer 22 includes a printed pattern of ink or pigment that may be deposited on the ink-receiving layer 18. In some examples, the ink-receiving layer may be omitted, and the ink pattern layer 22 may be deposited on the wavelength-selective scattering layer 14. In some examples, the protective layer 24 may be disposed between the ink pattern layer 22 and the wavelength-selective scattering layer 14. In some examples, two protective layers 24 may be disposed, one above the ink pattern layer 22 and the other adjacent to the wavelength-selective scattering layer 14 .

[0032] FIG. 1D shows a cross-sectional view of an exemplary article 10d. The article 10d may include a substrate 12, a wavelength-selective scattering layer 14, a first sealant layer 26, and a second sealant layer 28. One of the first sealant layer 26 and the second sealant layer 28 may include a latex coating. Each sealant layer may protect the integrity of the wavelength-selective scattering layer 14, for example, by preventing or reducing the ingress of moisture or other reactants or disintegrants. Each sealant layer may also provide structural support and physical stability to the wavelength-selective scattering layer 14. For example, one or both of the first sealant layer 26 and the second sealant layer 28 may enable the wavelength-selective scattering layer 14 to be peeled or removed from a production substrate and then transferred and applied to a product substrate, such as substrate 12.

[0033] 1E shows a cross-sectional view of an exemplary article 10e. The article 10e may include a substrate 12, a wavelength-selective scattering layer 14 adjacent to the substrate 12, and an ink pattern layer 24 deposited on the wavelength-selective scattering layer 14. A sensor layer 32 including sensor segments 32a, 32b, 32c, and 32d may be disposed adjacent to the substrate 12. In examples, the substrate 12 may be omitted, and the wavelength-selective scattering layer 14 may be deposited on the sensor layer 32. In examples, the wavelength-selective scattering layer 14 may include selective scattering segments 14a, 14b, 14c, and 14d, which may be aligned with the sensor segments 32a, 32b, 32c, and 32d. One or more of the selective scattering segments may be omitted, and the wavelength-selective scattering layer 14 may include at least one perforation that may be aligned with at least one of the sensor segments. The different selective scattering segments can be tailored by varying the near-infrared scattering ratio, visible haze, or other optical properties that can improve the performance of the sensor segment aligned with each selective scattering segment. Although four segments are shown in wavelength-scattering layer 14 and sensor layer 32 in FIG. 1E, in some examples, wavelength-scattering layer 14 and sensor layer 32 can have any suitable number of segments. While sensor layer 32 is shown in the example of FIG. 1E, in some examples, article 10e can include light sources 32a, 32b, 32c, and 32d instead of sensor segments.

[0034] 1F shows a cross-sectional view of an exemplary article 10f. Article 10f may include a substrate 12, a wavelength-selective scattering layer 14, a reflective layer 16, and a wavelength-selective absorbing layer 34. The reflective layer 16 may include a wavelength-selective reflective layer. For example, the reflective layer 16 may include a wavelength-selective interference filter or a wavelength-selective multilayer optical film. In some examples, the wavelength-selective absorbing layer 34 may include any suitable dye or pigment that has a higher infrared transmittance than a visible transmittance, such as a near-infrared black ink that transmits near-infrared wavelengths while substantially absorbing visible wavelengths. For example, the wavelength-selective absorbing layer 34 may include a dye or ink such as Spectre™ ink, e.g., Spectre™ 100, 110, 120, 130, 140, 150, or 160 (Epolin, Newark, NJ), Mimaki ink, e.g., Mimaki ES3, SS21, BS3, SS2, or HS (Mimaki Global, Tomi-city, Nagano, Japan), or Seiko ink, e.g., Seiko 1000, 1300, SG700, SG740, or VIC (Seiko Advance Ltd., Japan). In various examples, the wavelength-selective absorbing layer 34 may include one or more cyan, magenta, yellow, or black dye components, or may include a dye having any desired color, for example, by scattering or reflecting a predetermined wavelength band, peak, or spectrum associated with the predetermined color. In some examples, the wavelength-selective absorbing layer 34 may include a spectrally selective multilayer absorbing film that may have a higher infrared transmittance than a visible transmittance. In various examples, the color of the wavelength-selective absorbing layer 34 can be selected to adjust the overall appearance of the article 10f, e.g., to adjust the wavelengths reflected or scattered to change the appearance color of the article 10f exhibited by the major surfaces of the article 10f. The wavelength-selective absorbing layer 34 can transmit at least some, or substantially all, near-infrared wavelengths while blocking visible wavelengths. In some examples, the wavelength-selective absorbing layer 34 can include a separate coating that includes one or both of a dye or a pigment. In some examples, the wavelength-selective absorbing layer 34 can be dye-free and include a near-infrared-transmitting, visible-blocking pigment.For example, the wavelength-selective absorbing layer 34 may include Lumogen® Black FK 4280 or Lumogen Black FK 4281 (BASF, Southfield, MI). In some examples, the wavelength-selective absorbing layer 34 may include a multilayer film, one or more of the layers of which include one or both of a dye or a pigment. In some examples, the wavelength-selective absorbing layer 34 may include or be an adhesive layer, a polymer layer, a skin layer, or any other layer of a multilayer film that includes a dye or pigment. In some examples, article 10f may not include a separate wavelength-selective absorbing layer 34, and instead may include a wavelength-selective dye or pigment in any other suitable layer. In some examples, the wavelength-selective absorbing layer 34, or any other layer of article 10f, may include a dye or pigment only in a predetermined pattern or area. In some examples, The wavelength-selective absorbing layer 34 can exhibit broadband absorption, e.g., absorption across a predetermined wavelength band, by including one or more absorbing dyes or pigments that at least absorb in at least each subband of the predetermined wavelength band.

[0035] In some examples, the wavelength-selective absorbing layer 34 may include beads or particles to exhibit diffusion or scattering. For example, the wavelength-selective absorbing layer 34 may include a medium and beads or particles dispersed within the medium. The medium may include glass, a polymer, or any other suitable optical medium, or a combination thereof. The beads or particles may include silica, glass, a polymer, an organic, an inorganic, a metal oxide, polystyrene, or other suitable scattering material, or a combination thereof. The wavelength-selective absorbing layer 34 may include diffusive or scattering voids or pores, and the voids or pores may contain a gas, such as air.

[0036] Thus, each respective wavelength selective layer (14, 16, 34) may be transmissive to near-infrared wavelengths. For example, one or more of the wavelength selective layers, or article 10f as a whole, may have a transmittance of, for example, greater than 5%, greater than 10%, greater than 20%, greater than 50%, or greater than 7% near-infrared transmittance at wavelengths greater than 830 nm. In various examples, article 10f may transmit less than 5%, less than 1%, or about 0%. In various examples, article 10f may have a near-infrared transmittance greater than 10% for wavelengths greater than 830 nm. In various examples, article 10f may have a near-infrared transmittance greater than 20% for wavelengths greater than 850 nm. In various examples, article 10f may have a near-infrared transmittance greater than 50% for wavelengths greater than 870 nm. In various examples, article 10f may have a near-infrared transmittance greater than 50% for wavelengths greater than 900 nm. In examples, article 10f can have an average near-infrared transmittance of greater than 75% for wavelengths greater than 900 nm.

[0037] In some examples, as shown in FIG. 1F, the wavelength-selective absorbing layer 34 may be located between the wavelength-selective scattering layer 14 and the wavelength-selective reflecting layer 16. Positioning the wavelength-selective absorbing layer 34 behind the wavelength-selective scattering layer 14 can be used to adjust the grayscale or apparent whiteness of the wavelength-selective scattering layer 14. As described above, the wavelength-selective absorbing layer 34 may include a non-neutral color to adjust the visual appearance, e.g., color coordinates in a predetermined color space. In some examples, the wavelength-selective absorbing layer 34 can reduce the total visible reflectance of the optical filter by a predetermined amount without substantially reducing the total near-infrared transmittance. While article 10f includes a separate wavelength-selective absorbing layer 34, in some examples, such as the exemplary article 10g in FIG. 1G, a wavelength-selective dye may be added to the wavelength-selective scattering layer 14g, thereby causing the wavelength-selective scattering layer to also function as an absorbing layer. In some examples, the wavelength-selective scattering layer 14 may be disposed on a dyed wavelength-selective scattering layer 14g.

[0038] In some examples, as shown in FIG. 1H , an exemplary article 10h can include a wavelength-selective reflecting layer 16 positioned between the wavelength-selective scattering layer 14 and the wavelength-selective absorbing layer 34. The wavelength-selective absorbing layer 34 can uniformly reduce total visible reflectance across an area of ​​a major surface of the article 10h without substantially reducing total near-infrared transmittance. This uniform reduction in total visible reflectance can be utilized to reduce or prevent wetout. Wetout is a phenomenon that can result from visible light leakage or transmission through all layers of the article 10h, which can result in the appearance of visible discontinuities, disruptions, aberrations, variations, or disturbances in the uniform appearance of the optical filter. For example, areas where the optical filter contacts the underlying substrate can exhibit wetout, which can cause shapes corresponding to the contact areas to be perceptible through the optical filter. The wavelength-selective absorbing layer 34 reduces visible reflectance uniformly across the entire article 10h and prevents leakage of visible light, while still allowing near-infrared wavelengths to be transmitted, thereby preventing discontinuities or disruptions across the major surfaces of the article 10h and thus avoiding wetout.

[0039] In some examples, the wavelength-selective absorbing layer 34 can occupy the entire intermediate area adjacent to the major surface of the wavelength-selective reflective layer 16. However, in some examples, as shown in FIG. 1H , the wavelength-selective absorbing layer 34 may occupy a partial area adjacent to the major surface of the wavelength-selective reflective layer 16, with the light diffusing layer 36 occupying the remaining area adjacent to the major surface of the wavelength-selective reflective layer 16. This configuration can be used, for example, to reduce the amount of near-infrared dye that may be required to create the wavelength-selective absorbing layer 34; for example, in this case, a relatively dark or visible light absorbing component may be disposed adjacent to the light diffusing layer 36. In examples where a visible light absorbing component, such as a sensor, is disposed adjacent to an area of ​​the wavelength-selective reflective layer 16, wet-out may not be expected to occur in that area. Therefore, it may not be necessary to cover that area with the wavelength-selective absorbing layer 34; instead, the light diffusing layer 36 can be used adjacent to that component, reducing costs associated with the near-infrared dye, for example.

[0040] In some examples, the exemplary article may not include the wavelength-selective scattering layer 14 and may include only the wavelength-selective reflective layer 16 and the wavelength-selective absorbing layer 34, as shown in FIGS. 1I-1K. In some examples, as shown in FIG. 1I, the exemplary article 10i may include the wavelength-selective reflective layer 16 disposed adjacent to the substrate 12, with the wavelength-selective absorbing layer 34 between the substrate 12 and the wavelength-selective reflective layer 16. In various embodiments, the order of the layers in FIGS. 1A-1K may be varied. In some embodiments, one or more intervening layers may be disposed between any of the layers of the articles 10a-10k illustrated in FIGS. 1A-1K. For example, an intervening layer may be provided between the wavelength-selective scattering layer 14 and the wavelength-selective reflective layer 16, between the wavelength-selective scattering layer 14 and the wavelength-selective absorbing layer 34, and / or between the wavelength-selective absorbing layer 34 and the wavelength-selective reflective layer 16.

[0041] In some examples, as shown in FIG. 1J, the exemplary article 10j may include a wavelength-selective reflective layer 16 disposed adjacent to the substrate 12, with the wavelength-selective reflective layer 16 between the wavelength-selective absorbing layer 34 and the substrate 12. In some examples, as shown in FIG. 1K, the exemplary article 10k may include the wavelength-selective reflective layer 16 between the first wavelength-selective absorbing layer 34a and the second wavelength-selective absorbing layer 34b. The wavelength-selective absorbing layers 34, 34a, and 34b may be used to compensate for uneven blocking of visible wavelengths by the wavelength-selective reflective layer 16. For example, the wavelength-selective reflective layer 16 may block transmission of most visible wavelengths, but the wavelength-selective reflective layer 16 may still allow certain visible wavelength peaks or bands to pass. Therefore, the wavelength-selective reflective layer 16 may "leak" some visible light, which may reveal objects that should be hidden from view by the wavelength-selective reflective layer 16, for example. The wavelength-selective dyes can be selected to block at least those visible wavelengths transmitted by the wavelength-selective reflective layer 16, such that the exemplary articles 10i-10k transmit near-infrared wavelengths while substantially blocking all visible wavelengths.

[0042] In various examples, articles 10i-10k may have an average visible transmittance of less than 0.1% for wavelengths from 380 to 800 nm or from 400 to 700 nm, and an average near-infrared transmittance of greater than 50% for wavelengths from 830 to 900 nm, 900 to 980 nm, and / or 800 to 1200 nm. As used herein, the average visible transmittance for a wavelength range is the average value of the transmittance for all wavelengths within the range. In various examples, articles 10i-10k may have an average visible transmittance of less than 0.01% for wavelengths from 380 to 800 nm or from 400 to 700 nm, and an average near-infrared transmittance of greater than 75% for wavelengths from 830 to 900 nm, 900 to 980 nm, and / or 800 to 1200 nm. Articles 10i-10k may have a visible transmittance of less than 0.1% for all wavelengths from 380 to 800 nm or for all wavelengths from 400 to 700 nm, and a near-infrared transmittance of greater than 50% for all wavelengths from 830 to 900 nm, 900 to 980 nm, and / or 800 to 1200 nm. In various examples, articles 10i-10k may have a visible transmittance of less than 0.01% for wavelengths from 380 to 800 nm or 400 to 700 nm, and a near-infrared transmittance of greater than 75% for wavelengths from 830 to 900 nm, 900 to 980 nm, and / or 800 to 1200 nm. In various examples, exemplary articles 10i-10k may further include a sealant layer or protective layer, as described above with reference to FIGS. 1A-1E.

[0043] In some embodiments, articles 10f-10k including wavelength-selective absorbent layer 34 may have an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm, and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm, 900 nm and 980 nm, and / or 800 nm and 1200 nm. In some embodiments, the average visible transmittance of articles 10f-10k for wavelengths between 400 nm and 700 nm may be less than about 20%, less than about 10%, less than about 5%, less than about 2%, or less than about 1%. In some embodiments, the average near-infrared transmittance of articles 10f-10k for wavelengths between 830 nm and 900 nm, 900 nm and 980 nm, and / or 800 nm and 1200 nm may be greater than about 40%, greater than about 50%, or greater than about 75%. In some embodiments, articles 10f-10k including wavelength-selective absorbent layer 34 may have a visible transmittance of less than about 30% for all wavelengths from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% for all wavelengths from 830 nm to 900 nm, 900 nm to 980 nm, and / or 800 nm to 1200 nm. In some embodiments, the visible transmittance of articles 10f-10k for all wavelengths from 400 nm to 700 nm may be less than about 20%, less than about 10%, less than about 5%, less than about 2%, or less than about 1%. In some embodiments, the near-infrared transmittance of articles 10f-10k for all wavelengths from 830 nm to 900 nm, 900 nm to 980 nm, and / or 800 nm to 1200 nm may be greater than about 40%, greater than about 50%, or greater than about 75%.

[0044] The wavelength-selective absorbing layer 34, in some embodiments, may have an average visible absorption of greater than about 30%, greater than about 40%, greater than about 50%, greater than about 70%, or greater than about 90%, for wavelengths between 400 nm and 700 nm. The wavelength-selective absorbing layer 34, in some embodiments, may have an average visible absorption of greater than about 30%, greater than about 40%, greater than about 50%, greater than about 70%, or greater than about 90% for all wavelengths between 400 nm and 700 nm. The wavelength-selective absorbing layer 34 may have an average near-infrared transmittance of greater than about 30%, greater than about 40%, or greater than about 50% for wavelengths between 830 nm and 900 nm, 900 nm and 980 nm, and / or 800 nm and 1200 nm. The wavelength-selective absorption layer 34 may have a near-infrared transmittance of greater than about 30%, greater than about 40%, or greater than about 50% for all wavelengths between 830 nm and 900 nm, 900 nm and 980 nm, and / or 800 nm and 1200 nm.

[0045] The effect of the angle of incidence of light on an article comprising a wavelength-selective absorbing layer is described below, with particular reference to Example 22. It should be noted that the angle of minimum visible transmittance of light for an optical filter as discussed herein may or may not be normal incidence. In some embodiments, the article may have a visible transmittance of light at normal incidence that is less than the visible transmittance of light at an oblique angle. In some embodiments, the article may have a visible transmittance of light at an oblique angle, e.g., 0 to 60 degrees, that is less than the visible transmittance of light at normal incidence.

[0046] The wavelength-selective absorbing layer 34 can include one or both of a wavelength-selective dye and a wavelength-selective pigment. In some embodiments, the wavelength-selective absorbing layer can include a porous layer with the dye and / or pigment disposed within the pores of the porous layer.

[0047] A dye or pigment can absorb light in a first spectral range and re-emit light in a different second spectral range. For example, the dye or pigment can include a fluorescent dye, phosphor, or quantum dot that absorbs light at shorter wavelengths and re-emits light at longer wavelengths. Therefore, the dye or pigment can function as a downconverter. For example, the dye or pigment can absorb ultraviolet or blue wavelengths and re-emit visible wavelengths. To control the appearance of an object, an optical filter containing a dye or pigment that absorbs and re-emits light at different wavelengths can be placed adjacent to or attached to the object. For example, a spectral conversion layer, e.g., a downconverting layer, can enhance the brightness of white or impart various special color effects to an object.

[0048] An optical filter may include more than one wavelength-selective absorbing layer, as shown by article 10k in FIG. 1K. For example, article 10k may include first and second wavelength-selective absorbing layers 34a, 34b, where the first wavelength-selective absorbing layer 34a has optical properties different from those of the second wavelength-selective absorbing layer 34b. For example, the first wavelength-selective absorbing layer 34a may include one or both of a black dye and a black pigment, and the second wavelength-selective absorbing layer 34b may include one or both of a color dye and a color pigment. In embodiments including wavelength-selective absorbing layers with color dyes or color pigments, the dyes or pigments may include one or more of cyan, magenta, and yellow components. While FIG. 1K shows the wavelength-selective reflective layer 16 disposed between the first and second wavelength-selective absorbing layers 34a, 34b, this is not required. In some embodiments, the layers can be arranged differently, for example, the second wavelength-selective absorbing layer can be disposed between the first wavelength-selective absorbing layer and the wavelength-selective reflecting layer, etc. For example, one or more intervening layers can be disposed between any of the layers of article 10k shown in FIG.

[0049] As described above, in some embodiments, the optical filters represented by articles 10f-10k in Figures 1F-1K may include a sealant layer and / or a protective coating. For example, the wavelength-selective absorbing layer may be disposed as a patterned layer coated or printed on another layer of articles 10f-10k. For example, the wavelength-selective absorbing layer may be coated or printed on the wavelength-selective reflecting layer 16, the wavelength-selective scattering layer 14, the substrate 12, the ink-receiving layer 18, the protective layer 24, and / or the sealant layers 26, 28. In some embodiments, the wavelength-selective absorbing layer may be coated together with the wavelength-selective reflecting layer 16, the wavelength-selective scattering layer 14, the ink-receiving layer 18, the protective layer 24, and / or the sealant layers 26, 28. For example, in some embodiments, the wavelength-selective scattering layer coating solution may include a wavelength-selective absorbing material, such as a dye and / or a pigment. In some embodiments, the wavelength-selective absorbing material may be mixed into an aqueous solution of a latex coating. The coating is then applied to the porous wavelength-selective scattering layer. The aqueous solution flows into the pores of the scattering layer, staining it with color. The latex particles remain on the surface of the composite scattering / absorbing layer, forming a sealant layer. In some embodiments, a dye or pigment may be combined in the solvent of the wavelength-selective scattering coating solution, allowing the combined solution to be applied and coated into a single layer that provides both scattering and absorbing coatings. If the wavelength-selective absorbing layer is a printed layer, it may be printed onto the base layer by, for example, screen printing, jet printing, flexographic printing, and / or other types of printing. In some embodiments, the printed article comprises an optical filter including a wavelength-selective reflecting layer and a printed wavelength-selective absorbing layer. A method for producing an optical filter having an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of more than about 30% for wavelengths between 830 nm and 900 nm comprises forming at least a wavelength-selective absorbing layer and a wavelength-selective reflecting layer.According to some aspects, forming the wavelength-selective absorbing layer and the wavelength-selective reflecting layer can include forming a wavelength-selective absorbing layer on a wavelength-selective reflecting layer or forming a wavelength-selective reflecting layer on a wavelength-selective absorbing layer. In some embodiments, the wavelength-selective absorbing layer and the wavelength-selective reflecting layer can be formed as a single composite layer. Forming the wavelength-selective absorbing layer and / or the wavelength-selective reflecting layer can include printing or coating a wavelength-selective absorbing material and / or a wavelength-selective reflecting material. Printing or coating the wavelength-selective absorbing layer and / or the wavelength-selective reflecting layer can include printing or coating a solution including two or more of a wavelength-selective absorbing material, a wavelength-selective scattering material, a wavelength-selective reflecting material, and a sealant material. In some embodiments, the wavelength-selective absorbing layer can be formed by coating a solution including a wavelength-selective absorbing material onto a porous layer. The porous layer can be a wavelength-selective scattering layer as described herein. The wavelength-selective absorbing material includes a dye that enters the pores of the porous layer. The solution can include particles that remain on the surface of the porous layer to form a sealant. Forming the wavelength-absorbing layer may include forming a mixture of two or more wavelength-selective absorbing materials and depositing the mixture as the wavelength-selective absorbing layer. Alternatively, the wavelength-selective absorbing layer may include two or more layers, where a first layer includes a first wavelength-selective absorbing material and a second layer includes a second wavelength-selective absorbing material.

[0050] The wavelength-selective absorbing layer 34 may scatter and absorb light. For example, the wavelength-selective absorbing layer may scatter more light in the visible range of 400 nm to 700 nm than in the near-infrared range of 830 nm to 900 nm, 900 nm to 980 nm, and / or 800 nm to 1200 nm. According to some implementations, the wavelength-selective absorbing layer 34 may scatter less than about 50%, less than about 40%, less than about 30%, or less than about 25% of light in the visible wavelength range of 400 nm to 700 nm, and may scatter less than about 50%, less than about 40%, less than about 30%, or less than about 25% of light in the near-infrared range of 830 nm to 900 nm, 900 nm to 980 nm, and / or 800 nm to 1200 nm.

[0051] 1A-1K depict each of articles 10a-10k as including a flat layer, in various examples, articles 10a-10k can have any suitable shape, circumference, or cross-section, and the layers of articles 10a-10k can have regular, irregular, or compound curvatures, or can have flat or curved geometries in different regions or otherwise conform to the contours of the substrate beneath the layer or article 10a-10k. For example, articles 10a-10k can have hemispherical or lenticular shapes, or surfaces with irregular contours. In some examples, each wavelength-selective layer, e.g., any of wavelength-selective scattering layer 14, reflective layer 16, and wavelength-selective absorbing layer 34, can have a shape and thickness that varies across a major dimension, e.g., by having a spatially varying pattern covering at least a portion of the substrate 12 or underlying layer, from about 1% to about 100%, or a periodic pattern. Furthermore, in some examples, articles 10a-10k in FIGS. 1A-1K may include a substrate 12, while in other examples, articles 10a-10k may not include a substrate 12. In some examples, substrate 12 may be flexible. In some examples, articles 10a-10k may be flexible and disposed on a flexible substrate. For example, the flexible substrate may include a light source, a sensor, or a photovoltaic cell. In some examples, articles 10a-10k may be continuously flexible or flexible only within predetermined regions. Thus, exemplary articles according to the examples described with reference to FIGS. 1A-1K may include an optical filter that blocks visible wavelengths while allowing near-infrared wavelengths to be transmitted. The exemplary articles and optical filters may be used in the exemplary optical systems described below.

[0052] 2A-2F are conceptual diagrams of an exemplary optical system including an optical filter. FIG. 2A is a conceptual diagram of an exemplary optical system including an optical filter 10 and an optical receiver 40. In various examples, the optical receiver 40 may include a light sensor, a camera, a CCD, or any other sensor configured to sense at least a predetermined wavelength range of light. For example, the optical receiver 40 may include a near-infrared sensor. In various examples, the optical receiver 40 may include an object that receives light, such as an object that at least partially absorbs incident light, such as a solar heater, or any other object that receives light. The optical filter 10 may include any of the exemplary optical filters including a wavelength-selective scattering layer described above with reference to FIGS. 1A-1E or other exemplary optical filters described herein. As shown in FIG. 2A, the optical filter 10 may be disposed adjacent to the optical receiver 40. Incident near-infrared light 42a may include near-infrared wavelengths and may be substantially transmitted through the optical filter 10 to the optical receiver 40. Incident visible light 44a may include visible wavelengths and may be substantially reflected or scattered by optical filter 10, such that receiver 40 is at least partially blocked from visible light 44a and at least partially receives near-infrared light 42a. In examples, receiver 40 may be substantially or completely blocked from visible light 44a by optical filter 10 and may receive substantially all of the near-infrared light 42a.

[0053] FIG. 2B is a conceptual diagram of an exemplary optical system including an optical filter 10, a light receiver 40, a light emitter 46, and an object 48. In various examples, the light emitter 46 may include a source of any suitable wavelength of light or electromagnetic radiation, including visible, near-infrared, or ultraviolet wavelengths. In various examples, the light emitter 46 may include a light bulb, an incandescent light source, a compact fluorescent lamp, an LED, a light guide, or any natural or artificial light source. In various examples, the light emitter 46 may not generate light but may only reflect or transmit light generated by the light source. The optical filter 10 may be disposed between the light receiver 40 and the object 48. The light emitter may be disposed on the same side of the optical filter 10 as the light receiver 40. Near-infrared light 42b transmitted from the light emitter 46 may include near-infrared wavelengths and may be substantially transmitted through the optical filter 10 to the object 48. The light 42b may be reflected by the object 48, and the reflected light may be modified by the optical properties of the object 48. The reflected light 42 may be substantially transmitted through the optical filter 10 to the receiver 40. The incident visible light 44b may include visible wavelengths and may be substantially reflected or scattered by the optical filter 10, thereby at least partially blocking one or both of the receiver 40 and the emitter 46 from the visible light 44a. In some examples, the receiver may be substantially or completely blocked by the optical filter 10 from the visible light 44b and may receive substantially all of the near-infrared light 42b.

[0054] 2C is a conceptual schematic diagram of an exemplary optical system including an optical filter 10, an optical receiver 40, and an object 48. The optical filter 10 may be disposed between the optical receiver 40 and the object 48. Incident near-infrared light 42c may include near-infrared wavelengths and may be substantially transmitted through the object 48 and the optical filter 10 to the optical receiver 40. Incident visible light 44c may include visible wavelengths and may be substantially reflected or scattered by the optical filter 10, causing the optical receiver 40 to be at least partially blocked from the visible light 44c and to at least partially receive the near-infrared light 42c. In various examples, the optical receiver 40 may be substantially or completely blocked from the visible light 44c by the optical filter 10 and may receive substantially all of the near-infrared light 42c.

[0055] 2D is a conceptual schematic diagram of an exemplary optical system including an optical filter 10 and an optical receiver 40. The optical filter 10 may be disposed adjacent to the optical receiver 40. Incident near-infrared light 42d may include near-infrared wavelengths and may be substantially reflected from the optical filter 10 to the optical receiver 40. Incident visible light 44d may include visible wavelengths and may be substantially reflected or scattered by the optical filter 10, such that the optical receiver 40 at least partially receives the visible light 44d while at least partially receiving the near-infrared light 42d.

[0056] FIG. 2E is a conceptual schematic diagram of an exemplary optical system including an optical filter 10, a light receiver 40, and a light emitter 46. The optical filter 10 may be disposed between the light emitter 46 and the light receiver 40. Near-infrared light 42e transmitted from the light emitter 46 may include near-infrared wavelengths and may be substantially transmitted through the optical filter 10 to the light receiver 40. Incident visible light 44e may include visible wavelengths and may be substantially reflected or scattered by the optical filter 10, thereby at least partially shielding the light emitter 46 from the visible light 44e. In some examples, the light emitter 46 may be substantially or completely shielded from the visible light 44e by the optical filter 10. Although the light receiver 40 is shown in the exemplary optical system of FIG. 2E, in some examples, the exemplary optical system of FIG. 2E may not include the light receiver 40. For example, the exemplary optical system may include the light emitter 46 and the optical filter 10, and the optical filter 10 may conceal the light emitter 46 from being visible.

[0057] FIG. 2F is a conceptual diagram of an exemplary optical system including an optical filter 10, a light receiver 40, a light emitter 46, and an object 48f. In various examples, the light emitter 46 may include a source of near-infrared wavelengths, such as a near-infrared light bulb or LED. For example, the light emitter may include a laser, a laser diode, or an injection laser. The light receiver 40 may include a sensor or camera sensitive to near-infrared wavelengths. For example, the sensor may include a photoelectric sensor, such as a gesture sensor, an optical touch sensor, or a sensor that detects disruptions in a continuously sensed light beam. The sensor may include an array or any other group of sensors of one or different types. The optical filter 10 may be disposed between the light receiver 40 and the object 48f. The light emitter 46 may be disposed on the same side of the optical filter 10 as the light receiver 40. Near-infrared light 42b transmitted from the light emitter 46 may include near-infrared wavelengths and may be substantially transmitted through the optical filter 10 to the object 48f. Light ray 42b may be reflected by object 48f, and the reflected light ray 42b may be modified by the optical properties of object 48f. Reflected light ray 42b may be substantially transmitted through optical filter 10 to receiver 40. In some examples, incident visible light ray 44b may include visible wavelengths and may be substantially reflected or scattered by optical filter 10, thereby at least partially blocking one or both of receiver 40 and emitter 46 from visible light ray 44a. In some examples, the receiver may be substantially or completely blocked by optical filter 10 from visible light 44b and may receive substantially all of the near-infrared light 42b.

[0058] In some examples, an iris scanning system can include the exemplary optical system of FIG. 2F , where, for example, the object 48 f includes an eye or iris, and the light receiver 40 is an iris scanner that receives near-infrared light emitted by the light emitter 46 and reflected by the object 48 f. While the light emitter 46 can emit near-infrared wavelengths, the light emitter 46 can also emit visible wavelengths that can indicate the presence of the light emitter 46, for example, to a user or observer. An article including a wavelength-selective layer 16 can be used to block the transmission of visible wavelengths to camouflage the light emitter 46 from view, while the wavelength-selective reflective layer 16 can allow some visible wavelengths, e.g., a peak or band of visible wavelengths, to be transmitted. In some examples, the optical filter 10 can include a wavelength-selective absorbing layer 34 that blocks the transmission of visible wavelengths transmitted by the wavelength-selective reflective layer 16, as described above with reference to FIGS. 1 i- 1 k. Thus, in some examples, the optical filter 10 may have a visible transmittance of less than 0.1% from 380 to 800 nm and a near-infrared transmittance of greater than 50% from 830 to 900 nm. Thus, the optical filter 10 may camouflage the light emitter 46 from view, even if the light emitter 46 emits visible wavelengths, while allowing an iris scanning system to scan the iris by transmitting near-infrared wavelengths in both directions across the optical filter 10. In some examples, the exemplary optical system of FIG. 2F may include more than one optical filter 10. For example, a first optical filter may be positioned adjacent to the light emitter 46 or the light receiver 40, and a second optical filter may be positioned adjacent to the major surface of the object 48f. In some examples, the first and second optical filters each include the same or different optical filters. In some examples, the optical filters 10 may include retroreflective films or may be positioned across or along the retroreflective path. In some examples, object 48f may include a retroreflective film. While an iris scanning system is described above with reference to Figure 2F, in some examples, the example of Figure 2F may include any biometric or identification system that uses near-infrared wavelengths for identification while emitting visible wavelengths that are to be hidden or camouflaged from view.For example, the exemplary system of FIG. 2F may include a fingerprint scanner, a facial recognition system, or a thermal recognition system.

[0059] In some embodiments, articles 10a-10k shown in FIGS. 1A-1K can be formed as components that can be attached to an object, such as an electronic device that includes one or both of a light emitter and a light receiver. In some embodiments, articles 10a-10k can be attached, detached, and reattached to the object. In some embodiments, the object can be retroreflective. Articles 10a-10k can be, for example, skins or films that can be applied to electronic devices or other objects, such as cell phones, tablets, notebook computers, automobiles, etc. Articles 10a-10k can also be decorative and can have text, logos, and / or designs disposed thereon. FIGS. 2G and 2H show front and back views, respectively, of article 200 configured to fit object 210. In FIGS. 2G and 2H, object 210 is depicted as a cell phone, and article 200 is depicted as a cell phone cover that fits the cell phone. Article 200 includes at least one or more regions 201a, 201b that include a wavelength-selective layer of an optical filter. The wavelength-selective layer of the optical filter scatters and / or absorbs light, camouflaging one or both of the light emitter and light receiver (not shown in FIGS. 2G and 2H ). In some embodiments, the wavelength-selective layer of the optical filter extends across most or substantially all of the article, and in some embodiments, portions of the article include the optical filter layer while other portions do not and may be opaque. Article 200 may include a cling film surface, adhesive, and / or mounting structure to facilitate attachment of article 200 to object 210. For example, cell phone cover 200 shown in FIGS. 2G and 2H may be attached to cell phone 210 via a mounting structure including walls 202 b and / or lips 202 a that provide a press-fit when attached to the cell phone. Alternatively, article 200 may be attached to object 210 using other types of mounting structures besides a press-fit structure, for example, a bolted mounting structure, such as holes configured to receive bolts or screws that attach article 200 to object 210.

[0060] In various examples, the optical filter 10 may include at least one removable or repositionable layer, or the optical filter 10 may be removable or repositionable in its entirety, such that the optical filter 10 can be removed or repositioned relative to a substrate below or adjacent to the optical filter 10. In various examples, the perimeter of the optical filter 10 may extend beyond the perimeter of one or both of the light emitters 46 or light receivers 40, or the area of ​​the major surfaces of the optical filter 10 may be greater or less than the surface area of ​​one or both of the light emitters 46 or light receivers 40. In various examples, the optical filter 10 may be configured to camouflage other components, such as electronics, circuits, boards, sensors, transmitters, etc., by shielding these components from view with the optical filter. In various examples, one or more light emitters 46 or light receivers 40, e.g., an array, could be positioned adjacent to the optical filter 10. In various examples, one or both of the light emitter 46 or the light receiver 40 may be relatively distant, e.g., at least 1 cm, or 10 cm, or 1 m, or 10 m, or 100 m, or 1 km, or even further away, from the optical filter 10. While Figures 2A-2F show, for example, a direct path between one or both of the light emitter 46 and the light receiver 40 and the optical filter 10, in various examples, light between one or both of the light emitter 46 and the light receiver 40 and the optical filter 10 may follow a non-direct path, including an optically guided path, a reflected path, or a path involving optical manipulation including refraction or filtering, or a path that travels through a different optical medium.

[0061] Thus, in examples, the optical filter 10 may be configured to at least partially block the optical receiver 40 from visible wavelengths while substantially allowing the optical receiver 40 to receive near-infrared wavelengths. For example, the optical filter 10 may be configured to conceal or camouflage one or more of the optical receiver 40, the light emitter 46, or the object 48. In examples, the optical filter 10 may be configured to camouflage one or both of the optical receiver 40 or the light emitter 46 from view by scattering visible wavelengths, for example, as described above with reference to FIGS. 2A-2F.

[0062] 3A-3D are conceptual diagrams of an exemplary system including an exemplary optical filter and an electronic display displaying a visible pattern and an invisible near-infrared pattern. An imaging sensor, such as a charge-coupled device (CCD), detects in the near-infrared range and could generate a sign including a visibly reflective graphic. The sign could conceal an invisible image that is detectable by a camera. For example, the image could include a predetermined pattern encoding a signal or information, such as a barcode, 2D barcode, or QR code. The physical size of QR codes may limit the amount of information they can contain. However, an invisible QR code could have the same physical dimensions as the sign without obscuring or obscuring the visible graphic. In one example, an electronic display 60 may be capable of simultaneously displaying visible and near-infrared light patterns emitted by respective visible and near-infrared emitters concealed behind the display 60. The electronic display 60 may be coated with the exemplary optical filter described above with reference to FIGS. 1A-1E. For example, electronic display 60 may simultaneously display visible pattern 62 and invisible near-infrared pattern 64, as shown in FIG. 3B. Pattern 62 may include a relatively smaller QR code or other indicia with a relatively smaller display footprint, and pattern 64 may include a relatively larger QR code or other indicia with a relatively larger footprint. Pattern 62 may be visible as a result of reflection or scattering of visible wavelengths by an optical filter (not shown). As seen in FIG. 3A, only pattern 62 is visible, while pattern 64 may remain invisible to the human eye while being presented with relatively high transparency at near-infrared wavelengths. Therefore, a camera capable of sensing near-infrared wavelengths may sense pattern 64 with sufficient resolution, e.g., to decode information that may be contained within pattern 64.In the example shown in FIG. 3C, only a predetermined pattern is visible on display 60, while an invisible near-infrared pattern detectable only by a near-infrared camera may be simultaneously displayed on display 60, as shown in FIG. 3D. Thus, in each of the exemplary systems 3A, 3B, 3C, and 3D, exemplary optical filters may be used to conceal or camouflage the source of the near-infrared pattern while revealing only the predetermined visible pattern. In some examples, invisible near-infrared pattern 64 may be used to encode covert information, while visible pattern 62 may be used to present visible information, or at least information that can be encoded but remains visible. For example, pattern 62 may encode a first set of information, such as a website, while pattern 64 may encode a second set of information, such as the location of display 60. In various examples, electronic display 60 may display a visible pattern, an invisible pattern, or both. In various examples, electronic display 60 may display multiple patterns. In various examples, electronic display 60 may display static or dynamic patterns. Therefore, exemplary optical filters can provide camouflage with high clarity near-infrared transmission.

[0063] 4 is a flowchart of an exemplary technique. The exemplary technique may include disposing (52) an optical filter 10 adjacent to one or both of the light emitter 46 or the light receiver 40. The optical filter 10 includes a wavelength-selective scattering layer, as described above with reference to FIGS. 1A-1E and 2A-2E. The exemplary technique may optionally further include disposing (54) a reflective layer 16 between the optical filter 10 and one or both of the light emitter 46 or the light receiver 40. The optical filter 10 may optionally camouflage (56) one or both of the light emitter 46 or the light receiver 40. The optical filter 10 may optionally at least partially block (58) one or both of the light emitter or the light receiver from visible wavelengths.

[0064] The articles described above may include multilayer films or may include multiple layers, but in some instances, one or more layers may be fused to adjacent layers or may form a visually indistinct graduated boundary with adjacent layers. In some instances, multilayer films or articles may be engineered so that different layers transition to adjacent layers without a discernible boundary or major surface separating one or more layers. In some instances, layer may refer to a predetermined substantially planar or curved geometric area rather than a physically separate or discrete layer.

[0065] Thus, exemplary systems, articles, and techniques according to the present disclosure may include exemplary optical articles that include exemplary wavelength-selective scattering layers that selectively scatter or reflect, for example, visible wavelengths, thereby reducing the transmission of visible wavelengths, while transmitting near-infrared light with relatively high transparency.

[0066] Exemplary articles and techniques according to the present disclosure are illustrated by the following non-limiting embodiments and examples.

[0067] Embodiment Embodiments of the present invention include the items listed below.

[0068] Item 1. One or both of a light emitter and a light receiver; an optical filter adjacent to one or both of the light emitter or the light receiver, the optical filter comprising a wavelength-selective scattering layer, the wavelength-selective scattering layer having a near-infrared scattering ratio less than about 0.9, the near-infrared scattering ratio being the ratio of average near-infrared scattering to average visible scattering, and the wavelength-selective scattering layer having a visible reflective haze factor greater than about 0.5, the visible reflective haze factor being the ratio of average visible diffuse reflectance to average visible total reflectance.

[0069] Item 2. The system of item 1, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.7.

[0070] Item 3. The system of item 1, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.6.

[0071] Item 4. The system of any one of items 1 to 3, wherein the wavelength-selective scattering layer has a visible reflective haze ratio greater than about 0.6.

[0072] Item 5. The system of any one of items 1 to 4, wherein the wavelength-selective scattering layer has a visible reflective haze ratio greater than about 0.7.

[0073] Item 6. The system according to any one of Items 1 to 5, wherein one or both of the light emitter and the light receiver have an operating wavelength within the near-infrared range.

[0074] Item 7. The system of any one of items 1 to 6, wherein the wavelength-selective scattering layer transmits less than about 50% of incident visible light and the wavelength-selective scattering layer transmits more than about 50% of incident near-infrared light.

[0075] Item 8. The system of any one of items 1 to 7, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light.

[0076] Item 9. The system of any one of items 1 to 8, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light as white light.

[0077] Item 10. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 5 μm, and wherein the absolute difference between the first refractive index and the second refractive index is less than about 0.1.

[0078] Item 11. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 1 μm, and wherein the absolute difference between the first refractive index and the second refractive index is less than about 0.2.

[0079] Item 12. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.5 μm, and wherein the absolute difference between the first refractive index and the second refractive index is less than about 0.4.

[0080] Item 13. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.3 μm, and wherein the absolute difference between the first refractive index and the second refractive index is less than about 0.6.

[0081] Item 14. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.2 μm, and wherein the absolute difference between the first refractive index and the second refractive index is less than about 1.8.

[0082] Item 15. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 82 in FIG.

[0083] Item 16. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 84 in FIG. 15 .

[0084] Item 17. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 86 in FIG. 15 .

[0085] Item 18. The system of any one of items 1 to 9, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 88 in FIG. 15 .

[0086] Item 19. The system of any one of items 1 to 18, wherein the wavelength-selective scattering layer has a visible haze of at least 25%.

[0087] Item 20. The system of any one of items 1 to 19, wherein the optical filter comprises a surface optical microstructure.

[0088] Item 21. The system according to any one of items 1 to 20, wherein the light emitter comprises a near-infrared LED or a near-infrared laser.

[0089] Item 22. The system according to any one of Items 1 to 21, wherein the receiver includes a near-infrared camera or an optical sensor having a near-infrared receiving band.

[0090] Item 23. The system of any one of Items 1 to 9, wherein the wavelength-selective scattering layer includes a binder, a plurality of particles, and a plurality of interconnected voids, wherein a volume fraction of the plurality of interconnected voids in the wavelength-selective scattering layer is about 20% or more, and a weight ratio of the binder to the plurality of particles is about 1:2 or more.

[0091] Item 24. The system of any one of items 1 to 23, wherein the optical filter includes a reflective layer.

[0092] Item 25. The system of any one of items 1 to 23, wherein the optical filter comprises a beaded diffusing layer.

[0093] Item 26. The system of any one of items 1 to 25, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while substantially allowing the receiver to receive near-infrared wavelengths.

[0094] Item 27. The system of any one of items 1 to 26, wherein the optical filter is configured to camouflage one or both of the light receiver or light emitter from view.

[0095] Item 28. The system of item 27, wherein the optical filter is configured to at least partially camouflage one or both of the receiver or emitter from view by scattering visible wavelengths.

[0096] Item 29. A method comprising disposing an optical filter adjacent to one or both of an emitter or a receiver, wherein the optical filter comprises a wavelength-selective scattering layer, the wavelength-selective scattering layer having a near-infrared scattering ratio less than about 0.9, the near-infrared scattering ratio being the ratio of average near-infrared scattering to average visible scattering, and the wavelength-selective scattering layer having a visible reflective haze factor greater than about 0.5, the visible reflective haze factor being the ratio of average visible diffuse reflectance to average visible total reflectance.

[0097] Item 30. The method of item 29, further comprising disposing a reflective layer between the optical filter and one or both of the light emitter or light receiver.

[0098] Item 31. A method comprising at least partially camouflaging one or both of the light emitter or the light receiver, wherein the camouflaging comprises the method of items 29 or 30.

[0099] Item 32. A method comprising at least partially shielding one or both of the light emitter or light receiver from visible wavelengths, wherein the shielding comprises the method of items 29 or 30.

[0100] Item 33. The method of any one of Items 29 to 32, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light.

[0101] Item 34. The method of item 33, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light as white light.

[0102] Item 35. An article comprising an optical filter, the optical filter comprising a wavelength-selective scattering layer, the wavelength-selective scattering layer having a near-infrared scattering ratio less than about 0.9, the near-infrared scattering ratio being the ratio of average near-infrared scattering to average visible scattering, and the wavelength-selective scattering layer having a visible reflective haze greater than about 0.5, the visible reflective haze being the ratio of average visible diffuse reflectance to average visible total reflectance.

[0103] Item 36. The article of item 35, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.7.

[0104] Item 37. The article of item 36, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.6.

[0105] Item 38. The article of any one of items 35 to 37, wherein the wavelength-selective scattering layer has a visible reflective haze ratio of greater than about 0.6.

[0106] Item 39. The article of any one of items 35 to 37, wherein the wavelength-selective scattering layer has a visible reflective haze ratio of greater than about 0.7.

[0107] Item 40. The article of any one of Items 35 to 39, wherein the wavelength-selective scattering layer transmits less than about 50% of incident visible light and the wavelength-selective scattering layer transmits more than about 50% of incident near-infrared light.

[0108] Item 41. The article of any one of Items 35 to 40, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light.

[0109] Item 42. The article of any one of Items 35 to 40, wherein the wavelength-selective scattering layer scatters more than about 50% of incident visible light as white light.

[0110] Item 43. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 5 μm, and the absolute difference between the first refractive index and the second refractive index is less than about 0.1.

[0111] Item 44. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 1 μm, and the absolute difference between the first refractive index and the second refractive index is less than about 0.2.

[0112] Item 45. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.5 μm, and the absolute difference between the first refractive index and the second refractive index is less than about 0.4.

[0113] Item 46. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.3 μm, and the absolute difference between the first refractive index and the second refractive index is less than about 0.6.

[0114] Item 47. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprising a plurality of particles, the plurality of particles having a second refractive index and an average particle size of less than about 0.2 μm, and the absolute difference between the first refractive index and the second refractive index is less than about 1.8.

[0115] Item 48. The article of any one of items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 82 in FIG. 15 .

[0116] Item 49. The article of any one of items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 84 in FIG. 15 .

[0117] Item 50. The article of any one of items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 86 in FIG. 15 .

[0118] Item 51. The article of any one of items 35 to 42, wherein the wavelength-selective scattering layer comprises an optical medium having a first refractive index, the optical medium comprises a plurality of particles, the plurality of particles having a second refractive index, and the average particle size, the first refractive index, and the second refractive index of the plurality of particles are selected from the area below line 88 in FIG.

[0119] Item 52. The article of any one of items 35 to 51, wherein the wavelength-selective scattering layer has a visible haze of at least 25%.

[0120] Item 53. The article of any one of items 35 to 52, wherein the optical filter comprises a surface optical microstructure.

[0121] Item 54. The article of any one of Items 35 to 42, wherein the wavelength-selective scattering layer comprises a binder, a plurality of particles, and a plurality of interconnected voids, wherein the volume fraction of the plurality of interconnected voids in the wavelength-selective scattering layer is about 20% or more, and the weight ratio of the binder to the plurality of particles is about 1:2 or more.

[0122] Item 55. The article of any one of items 35 to 54, wherein the optical filter comprises a reflective layer.

[0123] Item 56. The article of any one of items 35 to 55, wherein the optical filter comprises a beaded diffusing layer.

[0124] Item 57. The article of any one of items 35 to 56, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while allowing the receiver to at least partially receive near-infrared wavelengths.

[0125] Item 58. The article of any one of items 35 to 56, wherein the optical filter is configured to at least partially camouflage one or both of the light receiver and light emitter from view.

[0126] Item 59. The article of item 58, wherein the optical filter is configured to at least partially camouflage one or both of the receiver or emitter from view by at least partially scattering visible wavelengths.

[0127] Item 60. The article of any one of items 35 to 59, wherein the optical filter comprises an ink-receptive coating adjacent to a wavelength-selective scattering layer.

[0128] Item 61. The article of any one of items 35 to 60, wherein the optical filter comprises an ink pattern disposed on the ink-receptive coating.

[0129] Item 62. The article of any one of items 35 to 61, wherein the optical filter comprises a sealant layer.

[0130] Item 63. The article of any one of items 35 to 62, wherein the optical filter includes a protective coating.

[0131] Item 64. The article of any one of Items 35 to 63, wherein the wavelength-selective scattering layer has a total visible reflectance of at least 50%.

[0132] Item 65. The article of item 64, wherein the wavelength-selective scattering layer has a total visible reflectance of at least 60%.

[0133] Item 66. The article of item 65, wherein the wavelength-selective scattering layer has a total visible reflectance of at least 70%.

[0134] Item 67. An article comprising an optical filter, the optical filter comprising a wavelength-selective scattering layer, the wavelength-selective scattering layer having average near-infrared scattering less than 60%, the wavelength-selective scattering layer having average visible scattering greater than 10%, and the difference between % total visible reflectance and % diffuse visible reflectance is less than 20.

[0135] Item 68. The article of item 67, wherein the wavelength-selective scattering layer has average near-infrared scattering of less than 40%, the wavelength-selective scattering layer has average visible scattering of greater than 58%, and the difference between % total visible reflectance and % diffuse visible reflectance is less than 18.

[0136] Item 69. One or both of a light emitter and a light receiver; an optical filter adjacent to one or both of the light emitter or light receiver, a wavelength-selective scattering layer configured to substantially scatter visible wavelengths; and a wavelength-selective reflective layer; at least one wavelength-selective absorbing layer; and a wavelength-selective scattering layer; a wavelength-selective reflective layer, and and an optical filter, wherein each of the at least one wavelength-selective absorbing layer is configured to transmit near-infrared wavelengths.

[0137] Item 70. The system of Item 69, wherein the optical filter has a visible transmittance of less than 5% and a near-infrared transmittance of greater than 5% for wavelengths greater than 830 nm.

[0138] Item 71. The system of Item 70, wherein the optical filter has a visible transmittance of less than 1%.

[0139] Item 72. The system according to Item 70 or 71, wherein the optical filter has a near-infrared transmittance of greater than 10% for wavelengths greater than 830 nm.

[0140] Item 73. The system of Item 72, wherein the optical filter has a near-infrared transmittance of greater than 20% for wavelengths greater than 850 nm.

[0141] Item 74. The system of Item 73, wherein the optical filter has a near-infrared transmittance greater than 50% for wavelengths greater than 870 nm.

[0142] Item 75. The system of Item 74, wherein the optical filter has a near-infrared transmittance greater than 50% for wavelengths greater than 900 nm.

[0143] Item 76. The system of Item 75, wherein the optical filter has an average near-infrared transmittance greater than 75% for wavelengths greater than 900 nm.

[0144] Item 77. The system of any one of items 69 to 76, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.9, where the near-infrared scattering ratio is the ratio of average near-infrared scattering to average visible scattering, and the wavelength-selective scattering layer has a visible reflective haze factor of greater than about 0.5, where the visible reflective haze factor is the ratio of average visible diffuse reflectance to average visible total reflectance.

[0145] Item 78. The system of any one of items 69 to 76, wherein the wavelength-selective scattering layer has an average near-infrared scattering of less than 60%, the wavelength-selective scattering layer has an average visible scattering of greater than 10%, and the difference between % total visible reflectance and % diffuse visible reflectance is less than 20.

[0146] Item 79. The system of any one of items 69 to 76, wherein the wavelength-selective scattering layer transmits less than about 50% of incident visible light and the wavelength-selective scattering layer transmits more than about 50% of incident near-infrared light.

[0147] Item 80. The system of any one of Items 69 to 79, wherein the wavelength-selective scattering layer comprises a binder, a plurality of particles, and a plurality of interconnected voids, wherein the volume fraction of the plurality of interconnected voids in the wavelength-selective scattering layer is about 20% or more, and the weight ratio of the binder to the plurality of particles is about 1:2 or more.

[0148] Item 81. The system of any one of items 69 to 80, wherein the light emitter includes a near-infrared LED or a near-infrared laser.

[0149] Item 82. The system of any one of Items 69 to 81, wherein the receiver includes a near-infrared camera or an optical sensor having a near-infrared receiving band.

[0150] Item 83. The system of any one of items 69 to 82, wherein the reflective layer comprises a multilayer optical film.

[0151] Item 84. The system of any one of Items 69 to 83, wherein the reflective layer comprises a wavelength-selective interference filter.

[0152] Item 85. The system of any one of Items 69 to 84, wherein the optical filter is disposed on the substrate layer.

[0153] Item 86. The system of any one of items 69 to 85, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while substantially allowing the receiver to receive near-infrared wavelengths.

[0154] Item 87. The system of any one of items 69 to 86, wherein the optical filter is configured to camouflage one or both of the light receiver or light emitter from view.

[0155] Item 88. The system of item 87, wherein the optical filter is configured to at least partially camouflage one or both of the receiver or emitter from view by scattering visible wavelengths.

[0156] Item 89. The system of any one of Items 69 to 88, wherein the wavelength-selective absorbing layer is between the wavelength-selective scattering layer and the wavelength-selective reflecting layer, and the wavelength-selective absorbing layer is configured to reduce the total visible reflectance of the optical filter by a predetermined amount without substantially reducing the total near-infrared transmittance.

[0157] Item 90. The system of any one of Items 69 to 88, wherein the wavelength-selective reflective layer is between the wavelength-selective scattering layer and the wavelength-selective absorbing layer, and the wavelength-selective absorbing layer is configured to uniformly reduce total visible reflectance over an area of ​​a major surface of the optical filter without substantially reducing total near-infrared reflectance.

[0158] Item 91. An article including an optical filter, the optical filter comprising: a wavelength-selective scattering layer configured to substantially scatter visible wavelengths; and a wavelength-selective reflective layer; at least one wavelength-selective absorbing layer; and a wavelength-selective scattering layer; a wavelength-selective reflective layer, and The article, wherein each of the at least one wavelength-selective absorbing layer is configured to transmit near-infrared wavelengths.

[0159] Item 92. The article of item 91, wherein the optical filter has a visible transmittance of less than 5% and a near-infrared transmittance of greater than 5% for wavelengths greater than 830 nm.

[0160] Item 93. The article of item 92, wherein the optical filter has a visible transmittance of less than 1%.

[0161] Item 94. The article of item 92 or 93, wherein the optical filter has a near-infrared transmittance of greater than 10% for wavelengths greater than 830 nm.

[0162] Item 95. The article of item 94, wherein the optical filter has a near-infrared transmittance of greater than 20% for wavelengths greater than 850 nm.

[0163] Item 96. The article of item 95, wherein the optical filter has a near-infrared transmittance of greater than 50% for wavelengths greater than 870 nm.

[0164] Item 97. The article of item 96, wherein the optical filter has a near-infrared transmittance of greater than 50% for wavelengths greater than 900 nm.

[0165] Item 98. The article of item 97, wherein the optical filter has an average near-infrared transmittance of greater than 75% for wavelengths greater than 900 nm.

[0166] Item 99. The article of any one of items 91 to 98, wherein the wavelength-selective scattering layer has a near-infrared scattering ratio of less than about 0.9, where the near-infrared scattering ratio is the ratio of average near-infrared scattering to average visible scattering, and wherein the wavelength-selective scattering layer has a visible reflective haze of greater than about 0.5, where the visible reflective haze is the ratio of average visible diffuse reflectance to average visible total reflectance.

[0167] Item 100. The article of any one of items 91 to 99, wherein the wavelength-selective scattering layer has average near-infrared scattering of less than 60%, the wavelength-selective scattering layer has average visible scattering of greater than 10%, and the difference between % total visible reflectance and % diffuse visible reflectance is less than 20.

[0168] Item 101. The article of any one of items 91 to 100, wherein the wavelength-selective scattering layer transmits less than about 50% of incident visible light and the wavelength-selective scattering layer transmits more than about 50% of incident near-infrared light.

[0169] Item 102. The article of any one of Items 91 to 101, wherein the wavelength-selective scattering layer comprises a binder, a plurality of particles, and a plurality of interconnected voids, wherein the volume fraction of the plurality of interconnected voids in the wavelength-selective scattering layer is about 20% or more, and the weight ratio of the binder to the plurality of particles is about 1:2 or more.

[0170] Item 103. The article of any one of items 91-102, wherein the reflective layer comprises a multilayer optical film.

[0171] Item 104. The article of any one of items 91 to 103, wherein the reflective layer comprises a wavelength-selective interference filter.

[0172] Item 105. The article of any one of items 91 to 104, wherein the optical filter is disposed on the substrate layer.

[0173] Item 106. The article of any one of items 91 to 105, wherein the optical filter comprises an ink-receptive coating adjacent to a wavelength-selective scattering layer.

[0174] Item 107. The article of item 106, wherein the optical filter comprises an ink pattern disposed on the ink-receptive coating.

[0175] Item 108. The article of any one of items 91 to 107, wherein the optical filter comprises a sealant layer.

[0176] Item 109. The article of any one of items 91 to 107, wherein the optical filter comprises a protective coating.

[0177] Item 110. The article of any one of items 91 to 109, wherein the wavelength-selective absorbing layer is between the wavelength-selective scattering layer and the wavelength-selective reflecting layer, and the wavelength-selective absorbing layer is configured to reduce the total visible reflectance of the optical filter by a predetermined amount without substantially reducing the total near-infrared transmittance.

[0178] Item 111. The article of any one of items 91 to 109, wherein the wavelength-selective reflective layer is between the wavelength-selective scattering layer and the wavelength-selective absorbing layer, and the wavelength-selective absorbing layer is configured to uniformly reduce total visible reflectance over an area of ​​a major surface of the optical filter without substantially reducing total near-infrared reflectance.

[0179] Item 112. One or both of a light emitter and a light receiver; an optical filter adjacent to one or both of the light emitter or light receiver, a wavelength-selective reflective layer; at least one wavelength-selective absorbing layer; a wavelength-selective reflecting layer; and each of the at least one wavelength-selective absorption layers is configured to transmit near-infrared wavelengths, and the optical filter has a visible transmittance of less than 0.1% from 380 to 800 nm and a near-infrared transmittance of greater than 50% from 830 to 900 nm.

[0180] Item 113. The system according to Item 112, wherein the optical filter has a visible transmittance of less than 0.01% from 380 to 800 nm and a near-infrared transmittance of greater than 75% from 830 to 900 nm.

[0181] Item 114. The system of item 112 or 113, wherein the light emitter comprises a near-infrared LED or a near-infrared laser.

[0182] Item 115. A system described in any one of Items 112 to 114, wherein the receiver includes a near-infrared camera or an optical sensor having a near-infrared receiving band.

[0183] Item 116. A system described in any one of items 112 to 115, wherein the receiver includes an iris scanning system.

[0184] Item 117. A system including an iris-based identification system, including the system described in any one of items 112 to 116.

[0185] Item 118. The system of any one of items 112 to 117, wherein the reflective layer comprises a wavelength-selective interference filter.

[0186] Item 119. The system of any one of items 112 to 118, wherein the reflective layer comprises a multilayer optical film.

[0187] Item 120. The system of any one of items 112 to 119, wherein the optical filter is disposed on the substrate layer.

[0188] Item 121. The system of any one of items 112 to 120, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while substantially allowing the receiver to receive near-infrared wavelengths.

[0189] Item 122. The system of any one of items 112 to 121, wherein the optical filter is configured to camouflage one or both of the light receiver or light emitter from view.

[0190] Item 123. The system of any one of Items 112 to 122, wherein the at least one wavelength-selective absorbing layer includes a first wavelength-selective absorbing layer and a second wavelength-selective absorbing layer, and the wavelength-selective reflective layer is between the first wavelength-selective absorbing layer and the second wavelength-selective absorbing layer.

[0191] Item 124. An article including an optical filter, the optical filter comprising: a wavelength-selective reflective layer; at least one wavelength-selective absorbing layer; a wavelength-selective reflecting layer; and The article, wherein each of the at least one wavelength-selective absorbing layers is configured to transmit near-infrared wavelengths, and the optical filter has a visible transmittance of less than 0.1% from 380 to 800 nm and a near-infrared transmittance of greater than 50% from 830 to 900 nm.

[0192] Item 125. The article of item 124, wherein the optical filter has a visible transmittance of less than 0.01% from 380 to 800 nm and a near-infrared transmittance of greater than 75% from 830 to 900 nm.

[0193] Item 126. The article of items 124 or 125, wherein the reflective layer comprises a wavelength-selective interference filter.

[0194] Item 127. The article of any one of items 124 to 126, wherein the reflective layer comprises a multilayer optical film.

[0195] Item 128. The article of any one of items 124 to 127, wherein the optical filter is disposed on the substrate layer.

[0196] Item 129. The article of any one of items 124 to 128, wherein the at least one wavelength-selective absorbing layer comprises a first wavelength-selective absorbing layer and a second wavelength-selective absorbing layer, and the wavelength-selective reflective layer is between the first wavelength-selective absorbing layer and the second wavelength-selective absorbing layer.

[0197] Item 130. The article of any one of items 124 to 130, wherein the optical filter comprises a sealant layer.

[0198] Item 131. The article of any one of items 124 to 130, wherein the optical filter comprises a protective coating.

[0199] Item 132. The article of any one of items 124 to 131, wherein the wavelength-selective absorbing layer comprises one or both of a wavelength-selective dye or a wavelength-selective pigment.

[0200] Item 133. The system of any one of Items 69 to 90, wherein the wavelength-selective absorbing layer comprises one or both of a wavelength-selective dye or a wavelength-selective pigment.

[0201] Item 134. The article of any one of items 91 to 111, wherein the wavelength-selective absorbing layer comprises one or both of a wavelength-selective dye or a wavelength-selective pigment.

[0202] Item 135. The system of any one of Items 112 to 123, wherein the wavelength-selective absorbing layer comprises one or both of a wavelength-selective dye or a wavelength-selective pigment.

[0203] Item 136. An article including an optical filter, the optical filter being: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0204] Item 137. The article of item 136, having an average visible transmittance for wavelengths from 400 nm to 700 nm of less than about 5%.

[0205] Item 138. The article according to Item 136 or 137, having an average near-infrared transmittance for wavelengths of 830 nm to 900 nm of greater than about 50%.

[0206] Item 139. The article of any one of items 136 to 138, wherein the wavelength-selective reflective layer comprises an interference filter.

[0207] Item 140. The article of any one of items 136 to 138, wherein the wavelength-selective reflective layer comprises a multilayer optical film.

[0208] Item 141. The article of any one of items 136 to 138, wherein the wavelength-selective reflective layer comprises a reflective polarizer.

[0209] Item 142. The article of any one of items 136 to 141, wherein the wavelength-selective absorbing layer comprises one or both of a wavelength-selective dye and a wavelength-selective pigment.

[0210] Item 143. The article according to item 142, wherein the wavelength-selective absorbing layer comprises a porous layer, and one or both of the wavelength-selective dye and the wavelength-selective pigment are disposed within the pores of the porous layer.

[0211] Item 144. The article of item 142, wherein one or both of the wavelength-selective dye and the wavelength-selective pigment absorbs light within a first spectral range and re-emits light within a different second spectral range.

[0212] Item 145. The article of any one of items 136 to 144, wherein the at least one wavelength-selective absorbing layer comprises a first wavelength-selective absorbing layer and a second wavelength-selective absorbing layer, and the wavelength-selective reflective layer is between the first wavelength-selective absorbing layer and the second wavelength-selective absorbing layer.

[0213] Item 146. The article of item 145, wherein the first wavelength-selective absorbing layer has different optical properties than the second wavelength-selective absorbing layer.

[0214] Item 147. the first wavelength-selective absorbing layer comprises one or both of a black dye and a black pigment; the second wavelength-selective absorbing layer comprises one or both of a color dye and a color pigment; The article described in item 146.

[0215] Item 148. The article according to item 147, wherein the color dyes and color pigments comprise one or more of a cyan component, a magenta component, and a yellow component.

[0216] Item 149. The article of any one of items 136 to 148, wherein the optical filter comprises a sealant layer.

[0217] Item 150. The article of item 149, wherein the wavelength-selective absorbing layer is disposed on the sealant layer.

[0218] Item 151. The article of item 150, wherein the wavelength-selective absorbing layer is coated or printed on the sealant layer.

[0219] Item 152. The article of any one of items 136 to 151, wherein the wavelength-selective absorbing layer scatters less than about 50% of wavelengths between 400 nm and 700 nm and less than about 50% of wavelengths between 830 nm and 900 nm.

[0220] Item 153. The article of item 52, wherein the wavelength-selective absorbing layer scatters less than about 30% of wavelengths between 400 nm and 700 nm and less than about 30% of wavelengths between 830 nm and 900 nm.

[0221] Item 154. The article of any one of items 136 to 153, wherein the wavelength-selective absorbing layer scatters more light within visible wavelengths of 400 nm to 700 nm compared to light scattered within near-infrared wavelengths of 830 nm to 900 nm.

[0222] Item 155. The article of any one of items 136 to 153, wherein the wavelength-selective absorbing layer scatters more light within visible wavelengths of 400 nm to 700 nm compared to light scattered within near-infrared wavelengths of 800 nm to 1200 nm.

[0223] Item 156. The article of any one of items 136 to 153, wherein the wavelength-selective absorbing layer scatters more light within visible wavelengths of 400 nm to 700 nm compared to light scattered within near-infrared wavelengths of 900 nm to 980 nm.

[0224] Item 157. The article of any one of items 136 to 156, wherein the wavelength-selective absorbing layer is a printed layer.

[0225] Item 158. The article of any one of items 136 to 156, wherein the wavelength-selective absorbing layer comprises a coating on another layer.

[0226] Item 159. The article of any one of items 136 to 158, further comprising a wavelength-selective scattering layer.

[0227] Item 160. The article of item 159, wherein the wavelength-selective absorbing layer is disposed on the wavelength-selective scattering layer.

[0228] Item 161. The article of item 159, wherein the wavelength-selective absorbing layer is coated on the wavelength-selective scattering layer.

[0229] Item 162. The article of item 159, wherein the wavelength-selective absorbing layer is printed on the wavelength-selective scattering layer.

[0230] Item 163. The article of any one of items 136 to 162, wherein the optical filter is flexible.

[0231] Item 164. The article of any one of items 136 to 163, wherein the optical filter has a three-dimensional shape.

[0232] Item 165. The article of any one of items 136 to 164, further comprising a substrate.

[0233] Item 166. The article of item 165, wherein the substrate comprises at least one of glass and a polymer.

[0234] Item 167. The article according to item 165, wherein the substrate is a three-dimensional substrate.

[0235] Item 168. The article of any one of items 136 to 167, wherein the article has a three-dimensional shape and includes one or more attachment structures configured to attach the article to an object.

[0236] Item 169. The article of item 168, wherein the mounting structure includes one or more press-fit mounting structures.

[0237] Item 170. The article of item 168, wherein the object is an electronic component.

[0238] Item 171. The article of any one of items 136 to 170, wherein the optical filter has a visible transmittance of less than about 30% for all wavelengths from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% for all wavelengths from 830 nm to 900 nm.

[0239] Item 172. The article of any one of items 136 to 170, wherein the optical filter has an average near-infrared transmittance of greater than about 30% for wavelengths from 800 nm to 1200 nm.

[0240] Item 173. The article of any one of items 136 to 170, wherein the optical filter has a near-infrared transmittance of greater than about 30% for all wavelengths from 800 nm to 1200 nm.

[0241] Item 174. The article of any one of items 136 to 173, wherein the visible transmittance of the optical filter at normal incidence is less than the visible transmittance of the optical filter at an oblique angle.

[0242] Item 175. The article of any one of items 136 to 173, wherein the visible transmittance of the optical filter at an oblique angle is less than the visible transmittance of the optical filter at normal incidence.

[0243] Item 176. The article according to any one of items 1 to 173, wherein the visible transmittance of the optical filter at an inclination angle of 0 to 60 degrees is less than the visible transmittance of the optical filter at normal incidence.

[0244] Item 177. An article including an optical filter, the optical filter comprising: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 900 nm and 980 nm.

[0245] Item 178. A printed matter including an optical filter, the optical filter being: a wavelength-selective reflective layer; and at least one printed wavelength-selective absorbing layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0246] Item 179. The printed matter according to Item 178, wherein the optical filter has a visible transmittance of less than about 30% for all wavelengths from 400 nm to 700 nm and a near-infrared transmittance of more than about 30% for all wavelengths from 830 nm to 900 nm.

[0247] Item 180. The printed matter according to Item 178, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths from 400 nm to 700 nm and an average near-infrared transmittance of more than about 30% for all wavelengths from 800 nm to 1200 nm.

[0248] Item 181. A printed matter including an optical filter, the optical filter being: a wavelength-selective reflective layer; and at least one printed wavelength-selective absorbing layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 900 nm and 980 nm.

[0249] Item 182. A printed matter including an optical filter, the optical filter being: a wavelength-selective reflective layer; and at least one printed wavelength-selective absorbing layer, wherein the optical filter has a visible transmittance of less than about 30% for all wavelengths from 400 nm to 700 nm and a near-infrared transmittance of greater than about 30% for all wavelengths from 900 nm to 980 nm.

[0250] Item 183. Objects and an optical filter adjacent to the object, the optical filter comprising: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0251] Item 184. The system according to Item 183, wherein the average visible transmittance is less than about 1%.

[0252] Item 185. The system according to Item 183 or 184, wherein the average near-infrared transmittance is greater than about 75%.

[0253] Item 186. The system of any one of Items 183 to 185, wherein the wavelength-selective absorbing layer scatters less than 50% of wavelengths between 400 nm and 700 nm and less than 50% of wavelengths between 830 nm and 900 nm.

[0254] Item 187. The system of any one of Items 183 to 186, wherein the wavelength-selective absorbing layer scatters less than about 25% of wavelengths between 400 nm and 700 nm and less than 25% of wavelengths between 830 nm and 900 nm.

[0255] Item 188. The system of any one of items 183 to 187, wherein the wavelength-selective absorbing layer scatters more light within visible wavelengths of 400 nm to 700 nm compared to light scattered within near-infrared wavelengths of 830 nm to 900 nm.

[0256] Item 189. A system described in any one of items 183 to 188, wherein the light emitter comprises a near-infrared LED or a near-infrared laser.

[0257] Item 190. A system according to any one of items 183 to 188, wherein the receiver includes a near-infrared camera or an optical sensor having a near-infrared receiving band.

[0258] Item 191. The system of any one of items 183 to 188, wherein the receiver includes an iris scanning system.

[0259] Item 192. A system described in any one of items 183 to 191, wherein an optical filter is disposed on the substrate layer.

[0260] Item 193. The system of any one of items 183 to 192, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while substantially allowing the receiver to receive near-infrared wavelengths.

[0261] Item 194. The system of any one of items 183 to 193, wherein the optical filter is configured to camouflage one or both of the light receiver and the light emitter from view.

[0262] Item 195. The system of any one of Items 183 to 194, wherein the optical filter further comprises a wavelength-selective scattering layer.

[0263] Item 196. The system of any one of items 183 to 195, wherein at least one of the light emitter and the light receiver is a component of an electronic device, and the optical filter is a component of an article having a three-dimensional shape and including one or more mounting structures configured to mount the article including the optical filter to the electronic device.

[0264] Item 197. The system of any one of claims 183 to 196, wherein the object includes one or more of a light emitter and a light receiver.

[0265] Item 198. The system of any one of claims 183 to 197, wherein the object is retroreflective.

[0266] Item 199. An article including an optical filter, the optical filter comprising: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer having an average visible absorption of greater than about 30% for wavelengths between 400 nm and 700 nm, wherein the optical filter has an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0267] Item 200. The article of item 199, wherein the at least one wavelength-selective absorbing layer has a visible absorption of greater than about 30% for all wavelengths from 400 nm to 700 nm, and the optical filter has a near-infrared transmittance of greater than about 30% for all wavelengths from 830 nm to 900 nm.

[0268] Item 201. The article of item 199, having an average visible absorption of greater than about 50% for wavelengths from 400 nm to 700 nm.

[0269] Item 202. The article of any one of Items 199 to 201, wherein the wavelength-selective absorbing layer scatters less than 50% of wavelengths between 400 nm and 700 nm and less than 50% of wavelengths between 830 nm and 900 nm.

[0270] Item 203. The article of any one of items 199 to 201, wherein the wavelength-selective absorbing layer scatters more light within visible wavelengths of 400 nm to 700 nm compared to light scattered within near-infrared wavelengths of 830 nm to 900 nm.

[0271] Item 204. The article of any one of Items 199 to 201, wherein the wavelength-selective reflective layer has an average near-infrared transmittance of greater than about 50% for wavelengths of 830 nm to 900 nm.

[0272] Item 205. The article of any one of Items 199 to 204, further comprising a wavelength-selective scattering layer.

[0273] Item 206. An article including an optical filter, the optical filter comprising: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer having an average visible absorption of greater than about 30% for wavelengths between 400 nm and 700 nm, wherein the optical filter has an average near-infrared transmittance of greater than about 30% for wavelengths between 900 nm and 980 nm.

[0274] Item 207. An article including an optical filter, the optical filter comprising: a wavelength-selective reflective layer; and at least one wavelength-selective absorbing layer having an average visible absorption of greater than about 30% for wavelengths between 400 nm and 700 nm, wherein the optical filter has an average near-infrared transmittance of greater than about 30% for wavelengths between 800 nm and 1200 nm.

[0275] Item 208. Objects and an optical filter adjacent to the object, the optical filter comprising: a wavelength-selective reflective layer having an average near-infrared transmittance of greater than about 30% for wavelengths of 830 nm to 900 nm; at least one wavelength-selective absorbing layer having an average visible absorption of greater than about 30% from 400 nm to 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths from 830 nm to 900 nm; Including, the system.

[0276] Item 209. The system of item 208, wherein the light emitter comprises a near-infrared LED or a near-infrared laser.

[0277] Item 210. The system of item 208, wherein the receiver includes a near-infrared camera or a light sensor having a near-infrared receiving band.

[0278] Item 211. The system of item 208, wherein the receiver includes an iris scanning system.

[0279] Item 212. The system of any one of items 208 to 211, wherein the optical filter is configured to at least partially block the receiver from visible wavelengths while substantially allowing the receiver to receive near-infrared wavelengths.

[0280] Item 213. A system described in any one of items 208 to 212, wherein the optical filter is configured to camouflage one or both of the light receiver and the light emitter from view.

[0281] Item 214. A system described in any one of claims 208 to 213, wherein the object includes one or more of a light emitter and a light receiver.

[0282] Item 215. The system of any one of claims 208-214, wherein the object is retroreflective.

[0283] Item 216. An article including an optical filter, the optical filter comprising: a wavelength-selective scattering layer including at least one of a dye and a pigment, the wavelength-selective scattering layer being configured to scatter visible wavelengths of 400 nm to 700 nm and transmit near-infrared wavelengths of 830 nm to 900 nm; a wavelength-selective reflective layer configured to transmit near-infrared wavelengths of 830 nm to 900 nm; Including, goods.

[0284] Item 217. The article of item 216, wherein the wavelength-selective scattering layer comprises a coating comprising at least one of a dye and a pigment.

[0285] Item 218. The article of item 216, wherein the coating contains greater than about 11% solids.

[0286] Item 219. The article of item 216, wherein the coating contains greater than about 12% solids.

[0287] Item 220. The article of item 216, wherein the coating contains greater than about 13% solids.

[0288] Item 221. The article of item 216, wherein the coating contains greater than about 14% solids.

[0289] Item 222. A method for making an optical filter, the method comprising: 1. A method comprising forming a wavelength-selective absorbing layer and a wavelength-selective reflecting layer, wherein the optical filter has an average visible transmittance of less than about 30% for wavelengths between 400 nm and 700 nm and an average near-infrared transmittance of greater than about 30% for wavelengths between 830 nm and 900 nm.

[0290] Item 223. The method according to Item 222, wherein forming the wavelength-selective absorbing layer and the wavelength-selective reflecting layer comprises forming the wavelength-selective absorbing layer on the wavelength-selective reflecting layer, or forming the wavelength-selective reflecting layer on the wavelength-selective absorbing layer.

[0291] Item 224. The method of item 222, wherein forming the wavelength-selective absorbing layer and the wavelength-selective reflecting layer comprises forming a single composite layer.

[0292] Item 225. The method according to any one of Items 222 to 224, wherein forming a wavelength-selective absorbing layer comprises printing or coating a wavelength-selective absorbing material.

[0293] Item 226. The method of item 225, wherein printing or coating the wavelength-selective absorbing layer comprises printing or coating a solution containing two or more of a wavelength-selective absorbing material, a wavelength-selective scattering material, a wavelength-selective reflecting material, and a sealant material.

[0294] Item 227. The method of item 222, wherein forming the wavelength-selective absorbing layer comprises coating a solution containing a wavelength-selective absorbing material onto the porous layer.

[0295] Item 228. The method according to Item 227, wherein the porous layer is a wavelength-selective scattering layer.

[0296] Item 229. The method of item 227, wherein the wavelength-selective absorbing material comprises a dye that enters the pores of the porous layer, and the solution comprises particles that remain on the surface of the porous layer to form a sealant.

[0297] Item 230. The method of item 222, wherein forming the wavelength absorbing layer includes forming a mixture of two or more wavelength-selective absorbing materials together and depositing the mixture as the wavelength-selective absorbing layer.

[0298] Item 231. Forming a wavelength absorbing layer forming a first wavelength-selective absorbing layer comprising a first wavelength-selective absorbing material; forming a second wavelength-selective absorbing layer comprising a second wavelength-selective absorbing material; Item 223. The method of item 222, comprising: [Example]

[0299] Example 1 The optical properties of various sample optical films were determined. Sample optical films S01 to S34 were prepared as described below. For each of Samples S01 to S33, visible scattering, near-infrared scattering, total visible reflectance, and diffuse visible reflectance were measured using a spectrometer (Lambda 900, PerkinElmer) with an integrating sphere to obtain diffuse and specular reflectance. The results are shown in Table 1. The presented reflectance values ​​include SPIN (specular, or total) reflectance and SPEX (specular, or diffuse) reflectance. The sensitivity of proximity sensors coated with each sample film was determined and classified as one of "not functioning," "functioning," "good," and "excellent." A haze meter (Haze-gard Plus, BYK-Gardner) was used to determine transmittance, haze, and transparency for Samples S01 to S34. The results are shown in Table 2.

[0300] Samples S01–S03 were ULI films, with sample S02 containing a high-haze, high-transparency ULI film. Sample S01 was prepared by combining Silquest A-174 75 nm silane particles (Momentive) with 60% wt. ratio of pentaerythritol triacrylate monomer (SR444, Sartomer) and 2.5% Irgacure 184 (Ciba Specialty Chemicals Company, High Point, NC) to achieve a coating thickness of 10 μm. Sample S04 contained a film of TiO nanoparticles and silicone microparticles. Sample S04 was prepared by mixing 19.13 g of M1192 (Miwon), 3.38 g of CN9018 (Sartomer), 2.5 g of Tospearl 145 (Momentive), 12.5 g of SR415 (Sartomer), 12.5 g of 42.3 wt% TiO in IBOA (UV-TITAN L-530, Sachtleben), 25 g of methyl ethyl ketone, and 0.5 g of photoinitiator TPO-L (BASF) and coating the formulation with a #8 Meyer bar. Sample S05 was a film with a microreplicated surface structure (Figure 9). Sample S6 contained 3 μm polystyrene beads coated onto ESR2 film (Enhanced Specular Reflector, 3M) with pentaerythritol triacrylate binder (SR444, Sartomer) and isopropyl alcohol solvent for a dry thickness of 10 μm. Sample S07 contained a nonwoven material (the bottom diffuser removed from a Sony TV model 40W600B). Sample S08 contained a TiO2-coated PET film, SH2FGST Fasara Film (3M). Samples S09 and S10 were bulk diffusers with different haze values. Sample S09 contained a PATTCLR0 matte acrylate sheet (ePlastics, San Diego, CA). Sample S10 contained a diffuser from a TCL TV (model 40FD2700).Sample S11 was the bottom diffuser sheet from an iPad (1st generation, Apple) backlight. Sample S12 included a plastic film with dispersed TiO2 (plastic 6"x8" small seal-top food bag with white writing block, from Elkay Plastics, Bensenville, IL). Sample S13 included white paper (HAmmermill Copy Plus multipurpose printer paper). Sample S14 included a film with a microreplicated surface structure (iPhone 6 backlight). Samples S15-S22 included films of ULI material. Sample S23 included Sample S04 folded over itself. Sample S24 included Sample S03 folded over itself. Sample S25 included Sample S15 folded over itself. Sample S26 included Sample S16 folded over itself. Sample S27 included Sample S17 folded over itself. Sample S28 included Sample S18 folded over itself. Sample S29 contains sample S19 folded onto itself. Sample S30 contains sample S20 folded onto itself. Sample S31 contains sample S21 folded onto itself. Sample S32 contains sample S2 folded onto itself. Sample S33 contains sample S22 folded onto itself.

[0301] [Table 1]

[0302] [Table 2]

[0303] Example 2 Figure 5 is a photograph of an exemplary article including an exemplary optical filter and an ink pattern. ESR2 was used as the reflective layer. A ULI layer (Sample S01 coating) was applied as the wavelength-selective scattering layer and the reflective layer. A layer of latex coating (PrintRite DP 261, Lubrizol) with a dry thickness of 1 mil was coated on top of the ULI layer as a combination ink-receiving layer and sealant layer. An inkjet (solvent ink) printing pattern was printed on top of the ink-receiving layer. As shown in Figure 5, the inkjet printing pattern was clear and free of smearing, blurring, or other defects.

[0304] Example 3 Figure 6A is a photograph of a solar panel. Figure 6B is a photograph of a solar panel camouflaged with an exemplary optical filter. A multilayer optical filter was formed by depositing a ULI layer (sample S01) on an ESR2 layer. The optical filter was printed with a camouflage pattern (imitation wood resembling background wood grain). The CIGS (copper indium gallium selenide) film solar panel in Figure 6A was camouflaged with an exemplary optical filter, as shown in Figure 6B. The filter was laminated to the solar panel using 3M 8211 Optically Clear adhesive. The camouflaged film panel generated 45% of its original power. The ESR2 film on the backside reflected almost all visible light. Power was measured using an IV5 solar output tester (PV Measurements, Inc., Boudler, CO).

[0305] Example 4 FIG. 7 is a photograph of an exemplary article including an exemplary optical filter and an ink pattern. The optical filter was formed with a ULI layer deposited on a reflective substrate. The right side of the optical filter was coated with a latex coating (PrintRite DP 261, Lubrizol) as the ink-receiving layer area, which formed a transparent film after drying. Patterns were inkjet printed on the ink-receiving coated area and the uncoated optical filter area. As shown in FIG. 7, the print quality on the uncoated area on the left was inferior to that in the ink-receiving layer-coated area on the right. For example, the printed pattern on the uncoated area was unclear and streaky.

[0306] Example 5 8A-8C are photographs of an exemplary system including an exemplary optical filter and a near-infrared LED (similar to the exemplary optical system shown in FIG. 2E). FIG. 8A shows a structure including a near-infrared-emitting LED. This structure was coated with an exemplary optical filter including a layer of ULI (sample S01) coated on an ESR2 layer. The coated structure was imaged using an infrared camera, resulting in the infrared image shown in FIG. 8B. As shown in FIG. 8B, the image of the LED light source is relatively clear compared to the unclear infrared image shown in FIG. 8C. Unlike FIG. 8B, the structure in FIG. 8C (sample S06) was coated with a bead layer instead of an optical filter including a wavelength-selective scattering layer. As shown in FIG. 8C, the non-selective bead layer transmitted the image of the IR LED with very low transparency.

[0307] Example 6 9 is an atomic force microscope (AFM) photograph of the surface of an exemplary optical filter, which included a surface-textured film (sample S05).

[0308] Example 7 10A and 10B are scanning electron microscope (SEM) photographs of exemplary optical filters: Fig. 10A shows an optical filter including a high haze, low transparency ULI layer (sample S22), and Fig. 10B shows an optical filter including a high haze, high transparency ULI layer (sample S02).

[0309] Example 8 FIG. 11 is a chart showing % reflectance and % transmittance versus wavelength for an exemplary optical filter. Curve 72 represents the % transmittance of a first sample ULI layer (Sample S01). Curve 74 represents the % transmittance of a second sample ULI layer (Sample S01, but 50% thicker). Curve 76 represents the % transmittance of the first sample ULI layer. Curve 78 represents the % reflectance of the second sample ULI layer. As shown in FIG. 11, both sample ULI layers selectively reflected visible wavelengths while transmitting near-infrared wavelengths.

[0310] Example 9 12A and 12B are charts showing % transmittance versus wavelength for exemplary optical filters. FIG. 12A shows the % transmittance for a first sample optical filter (Sample S06) comprising ESR2 coated with beads and limited with PET. FIG. 12B shows the transmittance for a second sample optical filter comprising ESR2 coated with a ULI and laminated with PET. As shown in FIGS. 12A and 12B, both sample optical filters transmitted near-infrared wavelengths, but the ULI-coated ESR selectively blocked transmission of visible wavelengths compared to the bead-coated ESR. The bead-coated ESR blocked visible wavelengths to a lesser extent.

[0311] Example 10 Figure 13 is a chart showing % transmittance versus wavelength for the sample films. The top curve shows the % transmittance for uncoated PET, and it can be seen that the % transmittance is relatively flat across the visible and near-infrared regions of the spectrum. The middle and bottom curves show the % transmittance for the #3 Meyer Bar bead-coated PET layer and the #10 Meyer Bar bead-coated PET layer, respectively. While the bead coating reduced the transmittance, the bead coating did not selectively reduce the transmittance, and the resulting transmittance curves were also relatively flat across the visible and near-infrared regions of the spectrum. Therefore, the bead-coated PET did not function as well as the wavelength-selective scattering layer formed by coating it with ULI.

[0312] Example 11 Figure 14 is a chart showing Mie scattering results, showing scattering efficiency versus wavelength for optical filters containing particles of different sizes. For optical filters containing particles dispersed in a medium, a Mie scattering-based model was prepared for scattering efficiency as a function of the particle size of the particles dispersed in the medium and the difference in refractive index between the medium and the particles. The model was evaluated by setting the refractive index of the medium to 1.5 and the refractive index of the scattering particles to 1.0. The particle size was varied from 0.2 μm to 1.0 μm in 0.1 μm increments (curves from left to right).

[0313] Example 12 FIG. 15 is a chart showing near-infrared scattering ratio as a function of particle size and refractive index difference for an optical filter including a medium and a plurality of particles dispersed in the medium. A model was used to evaluate the effect of particle size and the refractive index difference between the medium and the particles on near-infrared scattering ratio, and the model results are presented in FIG. 15. The X-axis represents refractive index difference (medium minus particle), and the Y-axis represents particle size (in μm). The contour lines represent different scattering ratios, such as 0.2, 0.4, 0.6, 0.8, 1, 1.2, 1.4, 1.6, and 1.8. Thus, curve 82 represents a near-infrared scattering ratio of 0.2. Curve 84 represents a near-infrared scattering ratio of 0.4. Curve 86 represents a near-infrared scattering ratio of 0.6. Curve 88 represents a near-infrared scattering ratio of 0.8.

[0314] Example 13 Table 3 presents the minimum scattering (transmission) of a diffusive coating that can mimic a hybrid surface (or non-metal) with a particular refractive index on an air interface.

[0315] [Table 3]

[0316] The surface is treated to a white color. R% is calculated by Fresnel reflection of air against a material of known RI. The theoretical maximum ratio of SPEX / SPIN (diffuse / total visible reflectance) was calculated assuming 100% total reflectance = Fresnel reflection + diffuse reflection.

[0317] Example 14 The diffuse and total reflectance of a number of samples was measured using an X-Rite, and the results are shown in Table 4.

[0318] [Table 4]

[0319] Example 15 Wet-out of the near-infrared films was evaluated. Wet-out is a visible disruption or disturbance of the uniform appearance of an optical film applied to a substrate, particularly in the area where the optical film contacts the substrate. Two near-infrared films were prepared by applying a wavelength-selective infrared-transmitting, visible-blocking ULI layer onto a reflective multilayer optical ESR2 film. Near-infrared-transmitting black ink was applied to one of the films. Figures 16A-16D are photographs comparing the wet-out of the near-infrared films. Figure 16A shows the front and Figure 16B shows the back of each near-infrared film, one without a near-infrared ink coating and one with a near-infrared ink coating. Double-sided tape was applied to the back of both films, and the films were adhered to respective glass slides. Figure 16C shows the front and Figure 16D shows the back of each near-infrared film, one without a near-infrared ink coating and one with a near-infrared ink coating, each adhered to a glass slide with double-sided tape. As can be seen by comparing Figures 16A and 16C, the near-infrared film without the near-infrared ink coating exhibited visible wet-out, while the near-infrared film with the near-infrared ink coating appeared uniform and did not exhibit wet-out. Figure 17 is a chart showing % transmittance versus wavelength for the near-infrared films of Figures 16A-16D. As shown in Figure 17, curve 92 represents the transmission spectrum of the near-infrared film without the near-infrared black ink coating, while curve 94 represents the transmission spectrum of the near-infrared film with the near-infrared black ink coating. Thus, since each respective film continued to transmit wavelengths above about 800 nm while blocking transmission of wavelengths below about 800 nm, applying the near-infrared black ink coating did not significantly affect the visible light blocking and infrared transmittance of the near-infrared film. Therefore, wet-out was eliminated without affecting the near-infrared filtering properties of the near-infrared film.

[0320] Example 16 A colored dye was applied to the near-infrared film. Figures 18A-18B are photographs of exemplary near-infrared films including a colored dye layer. Near-infrared films were prepared by applying a wavelength-selective, infrared-transmitting, visible-blocking ULI layer onto a reflective multilayer optical ESR2 film. In the example of Figure 18A, a cyan dye was applied on top of the scattering layer, on the side away from the reflective film. The dye coating exhibited visible non-uniformities, as can be seen in Figure 18A. In the example of Figure 18B, a cyan dye was applied between the scattering layer and the reflective film. The cyan dye layer imparted a visibly uniform cyan tint to the near-infrared film, as can be seen in Figure 18B.

[0321] Example 17 The effect of applying a near-infrared anti-reflective coating on a near-infrared film was evaluated. The transmittance of a reflective multilayer optical film coated with a near-infrared anti-reflective coating was compared to a reflective multilayer optical film without an infrared anti-reflective coating. Figure 19 is a chart showing the % transmittance versus wavelength for a reflective multilayer optical film coated with a near-infrared anti-reflective coating (curve 98) compared to a reflective multilayer optical film without a near-infrared anti-reflective coating (curve 96). As can be seen in curve 96, the reflective multilayer optical film exhibited high-order harmonics outside the main reflection band. The harmonic ripple became stronger closer to the main reflection band. As can be seen in curve 98, applying a near-infrared anti-reflective coating increased the transmittance and smoothed out the harmonic ripple.

[0322] Example 18 The effect of a near-infrared dye coating on blocking the visible red component emitted from an infrared source by a reflective multilayer optical film was evaluated. Figure 20A is a photograph of an exemplary system including an infrared LED with a visible red component. Figure 20B is a photograph of an exemplary system including an infrared LED with a visible component filtered by a reflective multilayer optical film (ESR2) without a dye coating. As can be seen in Figure 20B, the ESR2 film reduced the intensity of the visible component emitted by the infrared LED to some extent but did not completely block the transmission of the visible component. Figure 21 is a chart showing the % transmittance versus wavelength for a reflective multilayer optical film (ESR2) without a dye coating. As can be seen in Figure 21, ESR2 transmits wavelengths above about 830 nm (including near-infrared wavelengths) and blocks wavelengths below 830 nm (including visible wavelengths), but ESR2 cannot block all visible wavelengths. For example, the transmission spectrum exhibited peaks at 380-450 nm and 550-650 nm. FIG. 22 is a chart showing the percent transmittance versus wavelength for a reflective multilayer optical film with an infrared dye coating compared to a comparative optical filter without a dye coating. Curves 102 and 106 represent the transmittance of different optical filters without a dye coating. As can be seen in FIG. 22, the optical filters of curves 102 and 106, while blocking some visible wavelengths, did not completely block the visible component of the spectrum. In contrast, curve 104, which completely blocks visible wavelengths while substantially transmitting near-infrared wavelengths, represents an ESR2 film containing near-infrared dye coatings, MingBo Ink IR9508-A and MingBo Ink IR9508-B (available from Mingbo Anti-Forgery Technology (Shenzhen) Co., Ltd., Guangdong, China). Wavelengths between 380 and 800 nm are absorbed by the MingBo IR ink, while wavelengths between 830 and 900 nm are transmitted. In the example of curve 104, MingBo IR ink was coated on both sides of the ESR2. The transmission from 380 to 800 nm was nearly 0%, while the transmission from 830 to 900 nm was higher than 75%.The film of curve 104 was used to mask an infrared source in an iris scanning device. Therefore, applying a near-infrared dye coating improved the blocking of visible components by ESR2 while allowing transmittance of near-infrared wavelengths.

[0323] Example 19 Epolight™ 7527D Visible Opaque Dye, sold by Epolin, Inc., Newark, NJ, was the dye selected for its low transmittance in the visible up to 875 nm and its steep rise to high transmittance above 950 nm. Epolight 7527D was combined with a coating solution consisting of Vitel 2200 copolyester, sold by Bostik, Inc., Wauwatosa, WI, dissolved in MEK and toluene, in various ratios and coating thicknesses on a 75 μm clear PET substrate. Other binders besides Vitel 2200B could also be used as the dye carrier. Samples were prepared on a small scale using a Mayer rod and dried at 80°C in a lab solvent oven. Coating solutions for loadings (low to high dye concentrations) in Vitel are given in Tables 1–5, both in terms of total solution and total solids. By varying the coating thickness, various optical densities can be produced with these solutions.

[0324] [Table 5]

[0325] [Table 6]

[0326] [Table 7]

[0327] [Table 8]

[0328] [Table 9]

[0329] Five film samples with increasing dye loading were prepared using this procedure, where the term "dye loading" refers to concentration and / or dye strength. The transmission spectra at normal incidence were measured from 350 to 1400 nm on a Perkin-Elmer Lambda 900 spectrophotometer and are shown as curves 1, 2, 3, 4, and 5 in Figure 23, corresponding to Tables 1-5.

[0330] This series of samples demonstrates two fundamental problems with dyes. First, the gradient of the transition from extinction to NIR transmission increases significantly, resulting in a decrease in NIR transmission. Second, poor quality coatings at higher concentrations result from the dye not moving in or out of solution, resulting in a grainy appearance and scattering. In addition to causing poor visual quality in the coating, scattering can occur in the NIR that degrades image quality for NIR cameras.

[0331] Example 20 In this example, the dye as described in Example 19 was combined with an interference film. An Epolight 7527D dye coating on PET as measured in curve 3 was laminated to a mirror film ESR substrate using 8171 Optically Clear Adhesive from 3M, St. Paul, MN. The external transmission spectra of the laminate stack were measured in a Lambda 900 spectrophotometer at normal incidence, 20 degrees, and 60 degrees from normal incidence as curves 6, 7, and 8, respectively, in Figure 24.

[0332] Figure 25 shows the same data set as Figure 24, but using a 0-1% transmission scale. Transmission is seen to be between 0.1 and slightly over 0.2% within a broad range of the visible spectrum.

[0333] Example 21 We modeled the Epolight 7527D dye coating on PET, as measured in curves 1–5, laminated to an optimized mirror film substrate using 8171 Optically Clear Adhesive, sold by 3M, St. Paul, MN. Figure 26 shows the transmission of samples at normal incidence with dye concentrations varied from 3 to 34.7%, as in the previous example. The optimized mirror film was based on the ESR2 mirror film, sold by 3M, St. Paul, MN, consisting of 265 layers of alternating PEN and PMMA resins. The layer profile was optimized to increase the overall bandwidth, shift the LBE from ~420 nm to ~400 nm, and shift the right band edge from ~800 nm to ~860 nm, resulting in a steeper right band edge. This allows for higher transmission in the IR and lower visible transmission from 400 nm to 700 nm, up to angles of incidence of 60 degrees.

[0334] Figure 27 shows the transmittance of s-polarized (Ts) and p-polarized (Tp) light through the mirror at normal incidence only. Figure 28 plots the same data as in Figure 26, but using a transmission scale of 0 to 0.1%. The steepening of the right band edge and increased bandwidth come at the expense of higher transmission in the visible, and light leakage can be effectively controlled by adding dyes. If necessary, higher optical density can be achieved by increasing the number of bilayers in the mirror film structure.

[0335] The average visible transmittance for the curves in Figures 26 and 28, along with the associated dye concentration levels, are shown in Table 10. Average visible transmittance levels of up to 5.8% are seen at lower concentrations.

[0336] [Table 10]

[0337] Example 22 This example models the effect of angle of incidence on the previous examples.

[0338] Tables 11, 12, and 13 show the results of the previous examples for normal incidence, 30-degree, and 60-degree light, respectively. Each table shows the average visible transmission for each dye concentration level. Note that the angle of minimum visible transmission is not normal incidence. For this particular set, 60 degrees results in the lowest visible transmission. It may be possible to design a film that has the lowest Vt at angles other than 60 degrees, such as normal incidence.

[0339] [Table 11]

[0340] [Table 12]

[0341] [Table 13]

[0342] Example 23 This example models the case where the interference film is a reflective polarizer. The layer profile is the same as for the mirror, but the materials are now PEN and CoPEN, as in the APF reflective polarizer film sold by 3M, St. Paul, MN. Figure 29 is a graph showing the pass and block states of a reflective polarizer at normal incidence. The polarizer is spectrally selective and is designed to block visible light and transmit NIR light at normal incidence.

[0343] A reflective polarizer with the transmittance shown in Figure 29 was combined with the same Epolin dye as in the previous example. Figure 30 shows the transmission of samples at normal incidence with dye concentrations ranging from 3 to 34.7%, as in the previous example. Tables 14, 15, and 16 present the spectral response and visible transmission at angles of incidence of 0, 30, and 60 degrees, respectively. As before, tables of density and average visible transmission are presented. This example shows that even with interference films with relatively high visible transmission, Vt as low as 10%, 5%, or even 1% is possible when combined with appropriate dye concentrations.

[0344] [Table 14]

[0345] [Table 15]

[0346] [Table 16]

[0347] Unless otherwise indicated, all numbers expressing feature sizes, quantities, and physical properties used in the specification and claims are to be understood as being modified in all instances by the term "about." Accordingly, unless specifically indicated to the contrary, the numerical parameters set forth in the above specification and appended claims are approximations that may vary depending upon the desired properties sought to be obtained by those of ordinary skill in the art utilizing the teachings disclosed herein. The use of numerical ranges by endpoints includes all numbers within that range (e.g., 1 to 5 includes 1, 1.5, 2, 2.75, 3, 3.80, 4, and 5) and any range within that range.

[0348] While numerous features of various embodiments have been set forth in the foregoing description, along with details of the structure and function of the various embodiments, it is to be understood that this detailed description is by way of example only, and that changes may be made in the details, particularly in the construction and arrangement of parts shown by the various embodiments, to the fullest extent indicated by the broad general meaning of the terms in which the appended claims are expressed.

Claims

[Claim 1] An electronic display having a visible light emitter and a near-infrared light emitter, which simultaneously displays a visible pattern emitted by the visible light emitter and which is visible, and an invisible near-infrared light pattern emitted by the near-infrared light emitter and which is not visible; a light sensor configured to detect the visible pattern and the invisible near-infrared light pattern; an optical filter disposed between the electronic display and the light sensor to shield the light sensor from visible light; The optical filter comprises a wavelength-selective reflecting layer and at least one wavelength-selective absorbing layer; the wavelength-selective reflective layer includes an interference filter having a reflective multilayer optical film, has an average near-infrared transmittance of more than 50% for wavelengths of 830 nm to 900 nm, and transmits light of a specific visible wavelength among visible wavelengths of 400 nm to 700 nm, thereby causing leakage of visible light, the transmission spectrum of the wavelength-selective reflective layer exhibits a peak within the visible wavelength range of 400 nm to 700 nm, and the specific visible wavelength includes the peak visible wavelength; the at least one wavelength-selective absorbing layer is formed by a printed layer and is configured to block visible light leaked by the wavelength-selective reflective layer, and has an average visible absorptance of more than 30% for wavelengths of 400 nm to 700 nm and an average near-infrared transmittance of more than 30% for wavelengths of 830 nm to 900 nm; The optical filter has a visible transmittance of less than 0.1% for all wavelengths from 400 nm to 700 nm and a near-infrared transmittance of greater than 50% for all wavelengths from 800 nm to 1200 nm. system.

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