Battery

Abstract

A battery 1100 according to the present disclosure comprises: a battery element 100 that includes a first electrode 120, a solid electrolyte layer 130, and a second electrode 140; an insulation member 200; lead terminals 300a and 300b; and a first solder material 400. The insulation member 200 encloses the battery element 100 and the first solder material 400. The lead terminals 300a and 300b are electrically connected to the battery element 100. The first solder material 400 is located between the insulation member 200 and the lead terminals 300a and 300b.

Description

[Technical Field]

[0001] The present disclosure relates to batteries. [Background technology]

[0002] Patent Document 1 discloses a molded battery in which a battery and lead terminals are housed in molded resin, while Patent Document 2 discloses a battery that uses an electrolyte solution and houses lead terminals in an insulating material housing. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 04-345749 [Patent Document 2] Japanese Patent Application Laid-Open No. 2004-356461 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present disclosure is to provide a battery having a structure suitable for improving reliability. [Means for solving the problem]

[0005] The battery of the present disclosure comprises: a battery element including a first electrode, a solid electrolyte layer, and a second electrode; An insulating member; A lead terminal; a first solder material; Equipped with the insulating member encloses the battery element and the first solder material; the lead terminal is electrically connected to the battery element, The first solder material is located between the insulating member and the lead terminal. [Effects of the Invention]

[0006] The present disclosure provides a battery having a structure suitable for improving reliability. [Brief explanation of the drawings]

[0007] [Figure 1] FIG. 1 shows a schematic configuration of a battery 1000 according to a first embodiment. [Figure 2] FIG. 2 shows a cross-sectional view of a schematic configuration of a battery 1100 according to the first embodiment, in a state before the first solder material 400 in the battery 1000 melts. [Figure 3] FIG. 3 shows a schematic configuration of a battery 1200 according to the second embodiment. [Figure 4] FIG. 4 shows a schematic configuration of a battery 1300 according to the third embodiment. DETAILED DESCRIPTION OF THE INVENTION

[0008] Hereinafter, embodiments of the present disclosure will be described in detail with reference to the drawings.

[0009] The embodiments described below are all comprehensive or specific examples, and the numerical values, shapes, materials, components, arrangement positions and connection forms of the components shown in the following embodiments are merely examples and are not intended to limit the present disclosure.

[0010] In this specification, terms indicating the relationship between elements, such as parallelism, terms indicating the shape of elements, such as rectangular parallelepiped, and numerical ranges are not expressions that express only the strict meaning, but are expressions that include a substantially equivalent range, for example, a difference of about a few percent.

[0011] The drawings are not necessarily strict illustrations, and in the drawings, substantially the same components are denoted by the same reference numerals, and redundant explanations are omitted or simplified.

[0012] In this specification and the drawings, the x-axis, y-axis, and z-axis represent the three axes of a three-dimensional Cartesian coordinate system. In each embodiment, the z-axis direction is the thickness direction of the battery. Furthermore, in this specification, unless otherwise specified, the "thickness direction" refers to the direction perpendicular to the plane on which each layer of the battery element is stacked.

[0013] In this specification, unless otherwise specified, the term "planar view" refers to the battery viewed along the stacking direction of the battery element. The term "thickness" in this specification refers to the length of the battery element and each layer in the stacking direction.

[0014] In this specification, the terms "upper" and "lower" in the battery configuration do not refer to the upper direction (vertically upper) and lower direction (vertically lower) in absolute spatial recognition, but are used as terms defined by a relative positional relationship based on the stacking order in the stacking configuration. Furthermore, the terms "upper" and "lower" are used not only when two components are arranged closely together and in contact with each other, but also when two components are arranged with a gap between them and another component is present between them.

[0015] In this specification, unless otherwise specified, in a battery element, the "side surface" means a surface along the stacking direction, and the "main surface" means a surface other than the side surface.

[0016] In this specification, the terms "inside" and "outside" refer to the center side of the battery being the "inside" and the peripheral side of the battery being the "outside" when the battery is viewed along the stacking direction of the battery element.

[0017] (First embodiment) The configuration of the battery according to the first embodiment will be described below.

[0018] The battery according to the first embodiment includes a battery element including a first electrode, a solid electrolyte layer, and a second electrode, an insulating member, a lead terminal, and a first solder material. The insulating member contains the battery element and the first solder material. The lead terminal is electrically connected to the battery element. The first solder material is located between the insulating member and the lead terminal. Here, "the insulating member contains the battery element and the first solder material" means that the battery element and the first solder material are embedded within the insulating member, meaning that the battery element and the first solder material are contained within the insulating member regardless of the direction from which the battery is viewed. Hereinafter, the term "contain" will be used in the same sense in this specification.

[0019] As described in the [Background Art] section, Patent Document 1 discloses a molded battery in which a battery and lead terminals are enclosed in a molded resin. However, in the battery disclosed in Patent Document 1, the solder material is provided in a mounting portion outside the molded resin. Therefore, no solder material exists between the molded resin and the lead terminals inside the molded resin. This can create gaps between the molded resin and the lead terminals, allowing moisture and other contaminants to penetrate. As a result, long-term use can lead to performance degradation. Patent Document 2 discloses a battery that uses an electrolyte and houses lead terminals in an insulating material housing. However, like Patent Document 1, the battery disclosed in Patent Document 2 does not have solder material on the lead terminals enclosed in the insulating material. Furthermore, because it uses an electrolyte, it generally has low heat resistance, making reflow-compatible surface mounting difficult and causing problems with high-temperature reliability. Therefore, as surface-mounted components, the batteries disclosed in Patent Documents 1 and 2 have limited mounting methods and also limit the reliability of the entire battery.

[0020] In the battery according to the first embodiment, a first solder material is present between the insulating member and the lead terminal. When the first solder material melts during heat treatment or solder mounting, the melted and re-solidified first solder material seals the gap between the insulating member and the lead terminal. This prevents moisture and other contaminants from entering the battery through the gap between the lead terminal and the insulating member. Therefore, the battery according to the first embodiment has a structure suitable for improving reliability.

[0021] The battery according to the first embodiment is, for example, a surface-mount battery.

[0022] The battery according to the first embodiment may be an all-solid-state battery. In the case of an all-solid-state battery, the solder can be melted at a high temperature that an electrolyte cannot withstand, and a sealed structure can be realized. Therefore, problems with the mounting method and high-temperature reliability do not arise.

[0023] FIG. 1 shows a schematic configuration of a battery 1000 according to a first embodiment.

[0024] Fig. 1(a) shows a cross-sectional view of the battery 1000 as viewed from the y-axis direction. Fig. 1(b) shows a plan view of the battery 1000 as viewed from below in the z-axis direction. Fig. 1(a) shows a cross section taken along line II in Fig. 1(b).

[0025] As shown in FIG. 1 , the battery 1000 includes a battery element 100 including a first electrode 120, a solid electrolyte layer 130, and a second electrode 140, an insulating member 200, a lead terminal 300a, a lead terminal 300b, and a first solder material 400. The battery element 100 has a structure in which the first electrode 120, the solid electrolyte layer 130, and the second electrode 140 are stacked in this order. The first electrode 120 includes a first current collector 110 and a first active material layer 160. The second electrode 140 includes a second current collector 150 and a second active material layer 170. The solid electrolyte layer 130 is located between the first active material layer 160 and the second active material layer 170. The lead terminal 300a is electrically connected to the first current collector 110. The lead terminal 300b is electrically connected to the second current collector 150. Hereinafter, the lead terminals 300a and 300b may be collectively referred to as lead terminals.

[0026] The insulating member 200 contains the battery element 100, the first solder material 400, and the lead terminals 300a and 300b except for their mounting terminal portions. The mounting terminal portions are exposed to the outside of the insulating member 200 for electrical connection with an external circuit. The first solder material 400 is located between the insulating member 200 and the lead terminals.

[0027] The battery 1000 is, for example, an all-solid-state battery.

[0028] Each component of the battery 1000 will be described in detail below with reference to FIGS. 1(a) and 1(b).

[0029] (Battery element 100) The battery element 100 has a structure in which a first electrode 120, a solid electrolyte layer 130, and a second electrode 140 are stacked in this order. The first electrode 120 includes, for example, a first current collector 110 and a first active material layer 160. The second electrode 140 includes, for example, a second current collector 150 and a second active material layer 170. That is, the battery element 100 has a structure in which, for example, the first current collector 110, the first active material layer 160, the solid electrolyte layer 130, the second active material layer 170, and the second current collector 150 are stacked in this order.

[0030] The battery element 100 has a main surface and a side surface.

[0031] The battery element 100 is enclosed in an insulating member 200 .

[0032] The shape of the battery element 100 may be a rectangular parallelepiped or may be another shape, such as a cylinder or a polygonal prism.

[0033] In this specification, the term "rectangular parallelepiped" means that the general shape is a rectangular parallelepiped, and is a concept that also includes shapes obtained by chamfering a rectangular parallelepiped. The same applies to other expressions of shape in this specification.

[0034] In the first electrode 120, another layer such as a bonding layer made of a conductive material may be provided between the first current collector 110 and the first active material layer 160.

[0035] In the second electrode 140, another layer such as a bonding layer made of a conductive material may be provided between the second current collector 150 and the second active material layer 170.

[0036] The first electrode 120 may not include the first current collector 110. That is, the first electrode 120 may be made of the first active material layer 160. In this case, to extract electricity from the first electrode 120, a second current collector 150, an electrode separate from the first electrode 120 and the second electrode 140, or a substrate supporting the battery 1000 may be used. Similarly, the second electrode 140 may not include the second current collector 150. That is, the second electrode 140 may be made of the second active material layer 170.

[0037] The first electrode 120 may be a positive electrode, in which case the first active material layer 160 is a positive electrode active material layer.

[0038] The second electrode 140 may be a negative electrode, in which case the second active material layer 170 is a negative electrode active material layer.

[0039] Hereinafter, the first electrode 120 and the second electrode 140 may be simply referred to as "electrodes". Also, the first current collector 110 and the second current collector 150 may be simply referred to as "current collectors".

[0040] The positive electrode active material layer contains a positive electrode active material. The positive electrode active material is a substance in which metal ions such as lithium (Li) or magnesium (Mg) are inserted into or removed from the crystal structure at a potential higher than that of the negative electrode, and oxidation or reduction occurs accordingly. The type of the positive electrode active material can be appropriately selected according to the type of the battery, and known positive electrode active materials can be used. When the battery element 100 is, for example, a lithium secondary battery, the positive electrode active material is a substance in which lithium (Li) ions are inserted into or removed from, and oxidation or reduction occurs accordingly. In this case, examples of the positive electrode active material include compounds containing lithium and transition metal elements. More specifically, oxides containing lithium and transition metal elements, and phosphate compounds containing lithium and transition metal elements, etc. are included. Examples of the oxide containing lithium and transition metal elements include, for example, LiNi x M 1-x O2 (where M is at least one of Co, Al, Mn, V, Cr, Mg, Ca, Ti, Zr, Nb, Mo, and W, and x is 0 < x ≦ 1), such as lithium nickel composite oxides, layered oxides such as lithium cobalt oxide (LiCoO2), lithium nickel oxide (LiNiO2), lithium manganate (LiMn2O4), and lithium manganate (LiMn2O4, Li2MnO3, LiMnO2) having a spinel structure are used. Examples of the phosphate compound containing lithium and transition metal elements include, for example, lithium iron phosphate (LiFePO4) having an olivine structure. Also, sulfides such as sulfur (S) and lithium sulfide (Li2S) can be used as the positive electrode active material. In that case, a material obtained by coating or adding lithium niobate (LiNbO3) or the like to the positive electrode active material particles can be used as the positive electrode active material. Note that only one type of these materials may be used as the positive electrode active material, or two or more of these materials may be combined and used.

[0041] The positive electrode active material layer may contain not only the positive electrode active material but also other additive materials. That is, the positive electrode active material layer may be a mixture layer. Examples of additive materials include solid electrolytes such as inorganic solid electrolytes or sulfide-based solid electrolytes, conductive additives such as acetylene black, and adhesive binders such as polyethylene oxide or polyvinylidene fluoride. By mixing the positive electrode active material with other additive materials, such as the solid electrolyte and conductive additives, in a predetermined ratio, the positive electrode can improve both ionic conductivity and electronic conductivity within the positive electrode. Examples of solid electrolytes that can be used include those exemplified as materials for the solid electrolyte layer 130 described below.

[0042] The thickness of the positive electrode active material layer may be, for example, 5 μm or more and 300 μm or less.

[0043] The negative electrode active material layer contains a negative electrode active material. The negative electrode active material is a material in which metal ions such as lithium (Li) or magnesium (Mg) are inserted or extracted into or from the crystal structure at a potential lower than that of the positive electrode, resulting in oxidation or reduction. The type of negative electrode active material can be appropriately selected depending on the type of battery, and known negative electrode active materials can be used. Examples of the negative electrode active material include carbon materials such as natural graphite, artificial graphite, graphite carbon fiber, and resin-baked carbon, as well as alloy-based materials that are mixed with a solid electrolyte. Examples of alloy-based materials include LiAl, LiZn, Li3Bi, Li3Cd, Li3Sb, Li4Si, and Li 4.4 Pb, Li 4.4 Sn, Li 0.17 C, lithium alloys such as LiC6, lithium titanate (Li4Ti5O 12 ), zinc oxide (ZnO), and silicon oxide (SiO x ) and other metal oxides can be used. The negative electrode active material may be made of only one of these materials, or a combination of two or more of these materials.

[0044] The negative electrode active material layer may contain not only the negative electrode active material but also other additive materials. That is, the negative electrode may be a mixture layer. Examples of additive materials include solid electrolytes such as inorganic solid electrolytes or sulfide-based solid electrolytes, conductive additives such as acetylene black, and adhesive binders such as polyethylene oxide or polyvinylidene fluoride. Mixing the negative electrode active material with other additive materials, such as the solid electrolyte and conductive additives, in a predetermined ratio can improve both ionic conductivity and electronic conductivity within the negative electrode. Examples of solid electrolytes that can be used include those exemplified as materials for the solid electrolyte layer 130 described below.

[0045] The thickness of the negative electrode active material layer may be, for example, 5 μm or more and 300 μm or less.

[0046] The current collector may be made of any conductive material, and the material is not particularly limited. Examples of current collectors include foils, plates, or meshes made of stainless steel, nickel, aluminum, iron, titanium, copper, palladium, gold, platinum, or alloys of two or more of these metals. The current collector material may be selected appropriately based on the characteristics of the current collector, such as its resistance to melting and decomposition during the manufacturing process, operating temperature, and operating pressure, as well as the battery operating potential and electrical conductivity applied to the current collector. The current collector material may also be selected based on the required tensile strength and heat resistance. The current collector may be a high-strength electrolytic copper foil or a clad material made by laminating foils of different metals.

[0047] The thickness of the current collector may be, for example, 10 μm or more and 100 μm or less.

[0048] The solid electrolyte layer 130 is located between the first electrode 120 and the second electrode 140. The solid electrolyte layer 130 may be in contact with the lower surface of the first electrode 120 and the upper surface of the second electrode 140. That is, there may not be another layer between the solid electrolyte layer 130 and the electrodes.

[0049] The solid electrolyte layer 130 may not be in contact with the lower surface of the first electrode 120 and the upper surface of the second electrode 140.

[0050] The solid electrolyte layer 130 may be in contact with the side surfaces of the first electrode 120 and the second electrode 140, the lower surface of the first electrode 120, and the upper surface of the second electrode 140 so as to cover the respective side surfaces of the first electrode 120 and the second electrode 140.

[0051] The solid electrolyte layer 130 contains a solid electrolyte. The solid electrolyte layer 130 may be a known solid electrolyte having ion conductivity for a battery, and for example, a solid electrolyte that conducts metal ions such as lithium ions and magnesium ions can be used. The solid electrolyte may be appropriately selected according to the conduction ion species, and for example, an inorganic solid electrolyte such as a sulfide-based solid electrolyte or an oxide-based solid electrolyte can be used. Examples of the sulfide-based solid electrolyte include lithium-containing sulfides such as Li2S-P2S5, Li2S-SiS2, Li2S-B2S3, Li2S-GeS2, Li2S-SiS2-LiI, Li2S-SiS2-Li3PO4, Li2S-Ge2S2, Li2S-GeS2-P2S5, Li2S-GeS2-ZnS, etc. Examples of the oxide-based solid electrolyte include lithium-containing metal oxides such as Li2O-SiO2, Li2O-SiO2-P2O5, lithium-containing metal nitrides such as Li x P y O 1-z N z (0 < z ≦ 1), etc., lithium-containing transition metal oxides such as lithium phosphate (Li3PO4), and lithium titanate. As the solid electrolyte, only one of these materials may be used, or two or more of these materials may be used in combination.

[0052] The solid electrolyte layer 130 may contain not only a solid electrolyte but also a binder for binding such as polyethylene oxide or polyvinylidene fluoride.

[0053] The thickness of the solid electrolyte layer 130 may be, for example, 5 μm or more and 150 μm or less.

[0054] The solid electrolyte layer 130 may be configured as an aggregate of solid electrolyte particles, or may be configured as a sintered structure of the solid electrolyte.

[0055] (insulating member 200) The insulating member 200 is an exterior material that houses the battery element 100. The insulating member 200 encapsulates the battery element 100, a portion of the lead terminal, and the first solder material 400. The portion of the lead terminal that is not encapsulated in the insulating member 200 is exposed from the insulating member 200 and serves as, for example, a mounting terminal portion.

[0056] The material of the insulating member 200 may be any electrical insulator. The insulating member 200 may be any insulating material that does not affect the battery's characteristics. The insulating member 200 may contain a resin. The resin may be a thermosetting resin or a thermoplastic resin. The resin may be a thermosetting resin. The resin may be a thermosetting resin whose curing temperature is lower than the melting point of the first solder material 400. Examples of the resin include epoxy resin, acrylic resin, polyimide resin, or silsesquioxane. The insulating member 200 may be made of a spreadable resin, such as a liquid or powder thermosetting epoxy resin. By applying such a spreadable resin in liquid or powder form as an exterior body for the battery 1000 and thermally curing it, a compact battery can be integrated. This improves the reliability of the battery. The insulating member 200 may contain an epoxy resin.

[0057] The insulating member 200 may be made of epoxy resin. Since epoxy resin has heat resistance above the melting point of common solder materials, the first solder material 400 melts and can seal the gap between the insulating member 200 and the lead terminals. This allows for a highly reliable surface-mounted battery.

[0058] The insulating member 200 may be softer than, for example, any of the components of the battery element 100, specifically, the first electrode 120, the solid electrolyte layer 130, and the second electrode 140. This allows the relatively soft insulating member 200 to absorb stress generated between the components. This can prevent structural defects in the battery 1000, such as cracks in the sealing structure formed by the first solder material 400 or peeling of the current collector, as described below.

[0059] The Young's modulus of the insulating member 200 may be 10 GPa or more and 40 GPa or less. For example, an epoxy resin having a Young's modulus in this range may be used for the insulating member 200. This can improve the reliability of the battery 1000.

[0060] The hardness (i.e., the degree of hardening) of the insulating member 200 can be adjusted by selecting the curing temperature or curing time. For example, the hardness of the insulating member 200 can be increased by increasing the curing temperature, extending the curing time, or increasing the number of times the curing process is performed. The hardness can also be adjusted by incorporating pores into the insulating member 200. As described above, even with the same insulating material, the hardness can be controlled by changing the thermal history through the selection of the curing conditions or manufacturing process.

[0061] The softness (e.g., elastic modulus such as Young's modulus) of the constituent members of the battery element 100 and the insulating member 200 can be measured by applying a rigid indenter, similar to measuring Vickers hardness, and comparing the magnitude of the traces to compare the relative softness of the constituent members of the battery element 100 and the insulating member 200. For example, when an indenter is pressed with the same force against each part of the cross section of the battery 1000, if the insulating member 200 is depressed more than any of the constituent members of the battery element 100, the insulating member 200 can be determined to be softer than any of the constituent members of the battery element 100.

[0062] (Lead terminals 300a and 300b) The lead terminal is electrically connected to a current collector included in the electrode.

[0063] To connect the lead terminals to the current collectors, a highly conductive adhesive or solder containing conductive metal particles such as Ag particles may be used. To connect the lead terminals to the current collectors, a material having the same composition as the first solder material 400 may be used. Alternatively, various known conductive resins containing Cu or Al, or conductive materials including lead-free, lead-based, or gold-tin-based solder may be used. Alternatively, a conductive tape may be used. The hardening temperature (melting point) of the material connecting the lead terminals to the current collectors may be lower than the melting point of the first solder material 400.

[0064] The lead terminal may be flat within the insulating member 200. The lead terminal may be composed of, for example, a flat portion and a bent portion. The bent portion may be formed, for example, by bending a flat lead terminal. When the lead terminal has a bent portion, it is possible to further prevent air or moisture from entering the battery through the gap between the lead terminal and the insulating member 200. Furthermore, when the lead terminal has a bent portion, the molten first solder material 400 tends to collect at the bent portion. Therefore, when the molten first solder material 400 cools and solidifies, the bent portion closes and seals the gap between the insulating member 200 and the lead terminal, further preventing the intrusion of moisture and the like.

[0065] Each of the lead terminals 300a and 300b has two bent portions bent at 90° inside the insulating member 200. The lead terminals 300a and 300b have two bent portions bent at 90° in contact with the surface of the insulating member 200. However, the angle, number, and arrangement of the bent portions are not limited to these. For example, the angle of the bent portion may be 10° to 90°, and the number of bent portions may be one to three. To prevent the intrusion of moisture, etc., the lead terminals 300a and 300b may have two or more bent portions enclosed within the insulating member 200.

[0066] The lead terminal 300a connected to the first current collector 110 may extend along the main surface of the first current collector 110 of the battery element 100, and then bend in a direction along the side surface of the battery element 100. The lead terminal 300b connected to the second current collector 150 may extend along the main surface of the second current collector 150 of the battery element 100, and then bend in a direction along the side surface of the battery element 100. In this way, the lead terminal may be bent in a direction along the side surface of the battery element 100. In other words, the lead terminal may have a portion that extends along the side surface of the battery element 100.

[0067] The bent portion of the lead terminal 300a connected to the main surface of the first current collector 110 may include a crank-shaped bent portion 301a that extends along the main surface of the first current collector 110 of the battery element 100, then bends in a direction along the side surface of the battery element 100, and is bent so as to extend toward the outside of the insulating member 200. The bent portion of the lead terminal 300b connected to the main surface of the second current collector 150 may include a crank-shaped bent portion 301b that extends along the main surface of the second current collector 150 of the battery element 100, then bends in a direction along the side surface of the battery element 100, and is bent so as to extend toward the outside of the insulating member 200.

[0068] By having bent portions 301a and 301b, the lead terminal can be more effectively prevented from passing between the lead terminal and insulating member 200 and allowing air or moisture to enter the battery.

[0069] First solder material 400 may be located between bent portion 301a and insulating member 200, or may be located between bent portion 301b and insulating member 200. As a result, when molten first solder material 400 is cooled and solidified, bent portions 301a and 301b close and seal the gap between insulating member 200 and the lead terminal, further suppressing the intrusion of moisture and the like.

[0070] The first solder material 400 may be in contact with the bent portion. This causes the molten first solder material 400 to solidify and seal at the bent portion, improving sealing and further suppressing the intrusion of moisture and the like. The first solder material 400 may be in contact with the bent portion 301a or may be in contact with the bent portion 301b. The first solder material 400 may form a sealing portion at the bent portions 301a and 301b that seals between the lead terminal and the insulating member 200. The sealing portion may be formed in a portion other than the bent portion.

[0071] The lead terminal may have an outer portion located outside the outer edge of the battery element 100 in a plan view, and the first solder material 400 may be present between the outer portion and the insulating member 200.

[0072] The first solder material 400 may contact the outer portion of the lead terminal.

[0073] The lead terminals may be exposed on the surface of the battery 1000. The lead terminals exposed on the surface of the battery 1000 may be arranged along the side surfaces of the battery 1000 and then bent inward again at the bottom surface of the battery 1000 to form a joint with the mounting board. In this way, the lead terminals have mounting terminal portions.

[0074] The lead terminals may be made of common stainless steel (SUS) or phosphor bronze. The lead terminals may be made of any electrically conductive material, such as stainless steel, iron, or copper, that is solder-wettable. Alloy or clad materials may also be used. Other conductors may be used depending on the application, taking into consideration ease of assembly, ease of mounting, durability against vibration or thermal cycle testing, and the like.

[0075] The width of the lead terminal may be adjusted appropriately according to the size of the battery element 100 or the land pattern of the mounting substrate. The width of the lead terminal may be narrower than that of the battery element 100. This allows the outer periphery of the battery element 100 to be used for positioning. Furthermore, the reduced heat capacity of the lead terminal can increase productivity in the heat treatment process.

[0076] 1 are rectangular flat plates, the shape of the lead terminals is not limited to this. For example, the lead terminals may have a portion where the width is narrowed.

[0077] The lead terminal may have a thickness of 200 μm or more and 1000 μm or less.

[0078] To accommodate large currents and to strengthen the adhesive strength, the lead terminals may be made wider or thicker.

[0079] The lead terminal may have a hole in the insulating member 200. This can further improve the sealing performance between the insulating member 200 and the lead terminal.

[0080] The shape of the holes is not limited. The shape of the holes may be, for example, circular or rectangular. The number of holes may be one or more. Any number may be used as long as it does not cause problems in assembly, strength, etc.

[0081] The holes are formed, for example, by punching the lead terminals using a die or by etching. By providing the holes, the heat capacity of the lead terminals is reduced, improving the solder melting response during heat treatment and achieving sealing in a short time. This also improves productivity. In addition, an anchoring effect with the insulating member 200 is obtained, improving adhesion.

[0082] The surface of the mounting terminal portion may contain a solder component. For example, it may be coated with Sn plating, Sn-based solder paste, or solder dip coating. This allows for reflow using commonly used industrial mounting methods, allowing for simultaneous mounting on a board with other surface-mounted components, improving the productivity of board mounting. Furthermore, improving the solder wettability of the mounting terminal portion improves the adhesion between the board and the mounting terminal portion, increasing reliability during actual use. The thickness of the solder component layer formed by coating may be 1 μm or more and 10 μm or less.

[0083] The battery 1000 according to the first embodiment may further include a water-repellent material, which may be in contact with the lead terminals.

[0084] (First solder material 400) The first solder material 400 is located between the insulating member 200 and the lead terminal. The first solder material 400 may be in contact with both the insulating member 200 and the lead terminal.

[0085] The first solder material 400 may be a common material used for mounting. The first solder material 400 may be any material that melts upon heat treatment. The first solder material 400 may be any material that does not adversely affect the battery element 100 and the insulating member 200 during heat treatment. The first solder material 400 may be a lead-free material. An example of such a material is an Sn-based material. Examples of Sn-based solder materials include Sn-Sb, Sn-Cu, Sn-Ag, Sn-Cu-Ag, Sn-Zn, Sn-Zn-Bi, and Sn-In. Alternatively, the first solder material 400 may be a lead-based material that has been widely used in the past. An example of a lead-based solder material is an Sn-Pb-based material. Generally, lead-free solder materials have poor wettability, so when melted, they tend to spread out in islands rather than completely wet the lead terminals. Therefore, the sealing effect of the gap is more likely to be strengthened in the portion where the height of the first solder material 400 increases (the apex of the island shape) between the insulating member 200 and the lead terminal.

[0086] The first solder material 400 shown in FIG. 1(a) is formed by heat treatment to melt the solder material and then re-solidifying it into scattered islands. However, the shape of the first solder material in the battery according to the first embodiment is not limited thereto. In the battery according to the first embodiment, the first solder material may include a solder film provided on the surface of the lead terminal, or the first solder material may be formed from a solder film provided on the surface of the lead terminal. A battery with such a solder film is obtained, for example, when the battery element 100 and the lead terminals with solder films provided on their surfaces are enclosed in the insulating member 200, but no heat treatment is performed. FIG. 2 shows a cross-sectional view of the schematic configuration of a battery 1100 according to the first embodiment, before the first solder material 400 in the battery 1000 is melted. As shown in FIG. 2, the battery 1100 has a configuration in which the first solder material is provided between the lead terminals and the insulating member 200 in the form of a solder film 410. The solder film 410 may be a solder plating film that covers the surface of the lead terminal. An example in which the solder film 410 is a solder plating film will be described below. Therefore, the solder film 410 will be referred to as a solder plating film 410 hereinafter.

[0087] The battery 1100 is subjected to heat treatment, for example, at a temperature equal to or higher than the melting point of the solder plating film 410. This heat treatment melts the solder plating film 410, forming, for example, island-shaped first solder material 400 as shown in FIG. 1(a). That is, the first solder material 400 is dispersed in a discontinuous stripe pattern. As a result, areas where the first solder material 400 is dispersed are thicker than the solder plating film 410 before melting. As the first solder material 400 thus formed cools and solidifies, areas that fill the gaps between the insulating member 200 and the lead terminals are formed everywhere. As a result, the gaps between the lead terminals and the insulating member 200 are blocked by the first solder material 400. This prevents moisture and other contaminants from penetrating into the battery via the gap between the insulating member 200 and the lead terminals. As described above, the battery 1100 can prevent moisture and other contaminants from penetrating into the battery when subjected to heat treatment at a temperature equal to or higher than the melting point of the solder material. That is, the battery 1100 has a structure suitable for improving battery reliability. While the linear expansion coefficient of typical solder materials is approximately +20 ppm / °C, the linear expansion coefficient of typical insulating materials (e.g., epoxy resin-based materials) used for the insulating member 200 is approximately +5 ppm / °C. Therefore, during thermal cycling, the vertices of the island-shaped first solder material 400 may press into the wall surface of the insulating member 200 at high temperatures. However, by using a material for the insulating member 200 that is softer than the materials for the first solder material 400 and the lead terminals, the thermal expansion difference can be absorbed. A soft epoxy resin or the like is suitable for the insulating member 200 over a wide temperature range (e.g., the operating temperature range of −25°C to 90°C). This allows for high sealing performance without structural defects even under thermal cycling. Therefore, the battery according to the first embodiment has a structure suitable for improving reliability.

[0088] The shape of the first solder material 400 is not limited. The first solder material 400 may be island-shaped (island-like), and the first solder material 400 may have a width of 10 μm or more and 1000 μm or less. This allows the gap between the insulating member 200 and the lead terminal to be blocked by multiple portions whose thickness increases due to the surface tension of the molten first solder material 400. Although the first solder material 400 shown in FIG. 1(a) is island-shaped, the first solder material 400 may also include a film-shaped solder material. In other words, the first solder material 400 may not be entirely island-shaped, but may be partially film-shaped. This first solder material 400 fills the gap between the insulating member 200 and the lead terminal, thereby blocking the gap between the insulating member 200 and the lead terminal.

[0089] The first solder material 400 may close at least a part of the gap between the insulating member 200 and the lead terminal, thereby preventing moisture and the like from entering the battery through the gap between the insulating member 200 and the lead terminal, thereby improving the reliability of the battery.

[0090] The space sealed by the first solder material 400 that closes the gap between the insulating member 200 and the lead terminal may be filled with a gas such as air. The gas may be nitrogen or argon. Any gas may be used as long as it does not adversely affect the characteristics of the battery element 100 or the insulating member 200. If a dry gas is used, the lead terminal can also be protected from rust.

[0091] The position of the first solder material 400 is not limited. The first solder material 400 may be located between the bent portion of the lead terminal and the insulating member 200, or the first solder material 400 may be in contact with both the bent portion of the lead terminal and the insulating member 200. As described above, the first solder material 400 may be located between the bent portion 301a or 301b of the lead terminal and the insulating member 200, or the first solder material 400 may be in contact with both the bent portion 301a or 301b of the lead terminal and the insulating member 200. The first solder material 400 may be in contact with the bent portion 301a or 301b of the lead terminal. When the first solder material 400 solidifies at the bent portion 301a or 301b, the paths through which moisture and the like can penetrate become more complex and more likely to be blocked. This makes it possible to more effectively prevent moisture and the like from penetrating into the battery. The first solder material 400 may be located between the battery element 100 and the lead terminal. The first solder material 400 may join the battery element 100 and the lead terminal.

[0092] When the first solder material 400 is in an island shape, the number of islands is not limited, and the number may be one or more.

[0093] The shape and number of the first solder material 400 do not have to be symmetrical between the lead terminal 300a and the insulating member 200 and between the lead terminal 300b and the insulating member 200. For example, the first solder material 400 may be located only either between the lead terminal 300a and the insulating member 200 or between the lead terminal 300b and the insulating member 200.

[0094] The first solder material 400 can be confirmed by a cross-sectional observation method using a general optical microscope or a scanning electron microscope (SEM). It can also be observed by non-destructive analysis such as CT scanning. The sealing property of the first solder material 400 can be determined by, for example, immersion aging in a liquid or vacuum suction to confirm whether or not the material has penetrated into the internal structure.

[0095] The first solder material 400 may include a flux material.

[0096] The flux material is located, for example, between the insulating member 200 and the first solder material 400. This allows the solder wettability of the surfaces of the first solder material 400 and the lead terminals to be controlled over a wide range, making it possible to adjust the sealing state of the gap between the insulating member 200 and the lead terminals. This can further improve the reliability of the battery.

[0097] The flux material may be, for example, a resin-based material such as rosin or synthetic resin, an organic acid-based material, or an inorganic acid-based material, which are commonly used in solder mounting.

[0098] By combining the heat treatment atmosphere (for example, nitrogen atmosphere), the first solder material 400, and the flux material, it is possible to adjust the wettability and melting state of the solder suitable for obtaining sealing properties.

[0099] The lead terminals may be coated with solder plating film 410 to a thickness of, for example, 1 μm or more and 7 μm or less. When the lead terminals are pre-plated with Sn during battery assembly, the Sn plating may melt and re-solidify when the battery is mounted, thereby providing sealing with first solder material 400.

[0100] The solder plating film 410 may cover a part of the surface of the lead terminal. The solder plating film 410 may also be present between the lead terminal and the battery element 100. The solder plating film 410 may cover the surface of the lead terminal, avoiding the portion that is bonded to the battery element 100.

[0101] The solder plating film 410 may be located between the bent portions 301a and 301b of the lead terminals and the insulating member 200. The solder plating film 410 may cover the bent portions 301a and 301b of the lead terminals. When the solder plating film 410 melts at the bent portion 301a or 301b, the paths through which moisture and the like can infiltrate become more complex, facilitating sealing with the first solder material 400. This makes it possible to better prevent moisture and the like from infiltrating into the battery.

[0102] In the battery 1100, the solder plating film 410 may also be located on the surface of the lead terminal exposed from the insulating member 200. The solder plating film 410 may also be located on the mounting terminal portion. The solder plating film 410 may cover the entire surface of the lead terminal.

[0103] In FIG. 2, the battery 1100 is assembled using lead terminals whose surfaces are coated with a solder plating film 410, which is a plating film made of a solder material. However, the battery 1100 may also be assembled using lead terminals whose surfaces are coated with a coating film made of a solder material. That is, the solder material may be formed between the lead terminals and the insulating member 200 by application, such as printing. The material may be a solder paste. The material may be Sn—Sb-based. The thickness of the coating film made of the solder material may be 5 μm or more and 10 μm or less. The solder paste may melt and re-solidify, thereby providing sealing by the first solder material 400.

[0104] The battery 1000 may further include a second solder material that covers at least a portion of the surface of the lead terminal that is exposed from the insulating member 200. The second solder material may cover the mounting terminal portion.

[0105] The second solder material may be the same material as the first solder material 400. The second solder material may be formed of the same material as the first solder material 400 in succession.

[0106] Flux material can also be applied to the mounting terminals of the lead terminals to adjust the solder wettability to suit the mounting application and conditions. This configuration enables the battery to be reflow-compatible with improved reliability and can be mounted on a board in the same way as other general surface-mount components such as multilayer ceramic capacitors (MLCCs), making it highly useful in industrial applications.

[0107] (Second embodiment) A battery 1200 according to a second embodiment will now be described.

[0108] Figure 3 shows a schematic configuration of a battery 1200 according to the second embodiment. Figure 3(a) shows a cross-sectional view of the schematic configuration of the battery 1200 according to the second embodiment as seen from the y-axis direction. Figure 3(b) shows a plan view of the schematic configuration of the battery 1200 according to the second embodiment as seen from below in the z-axis direction. Figure 3(a) shows a cross section taken along line III-III in Figure 3(b).

[0109] Battery 1200 differs from battery 1000 in that it includes a sealing material 500. The sealing material 500 is located between the insulating member 200 and the lead terminal.

[0110] According to the above configuration, the sealed state can be maintained by sealing voids that may occur at the solder-sealed interface, i.e., the interface between the insulating member 200 and the first solder material 400, due to differences in thermal expansion between these materials during thermal cycles, using the elastic deformation of the sealing material 500. Therefore, the battery 1300 according to the third embodiment has improved reliability against thermal cycles and bending stress.

[0111] The position of the sealing material 500 is not limited as long as it is located between the insulating member 200 and the lead terminals and is on the path from the outside of the insulating member 200 to the battery element 100 .

[0112] For example, the sealant 500 can be applied by applying a silicone-based sealant or the like with a dispenser to the periphery of the exposed portion of the lead terminal from the insulating member 200, and then vacuum suctioning. If there is a gap between the insulating member 200 and the lead terminal that the sealant can fit into, the sealant can be injected and filled deep into the insulating member 200 (the battery exterior material, for example, into the battery element 100). This method allows the sealant to be injected into gaps of, for example, 1 μm to 100 μm. Vacuum suction may be repeated, which can also improve the integrity of the seal.

[0113] As the sealant 500, a known sealant such as a silicone-based, polysulfide-based, acrylic urethane-based, polyurethane-based, acrylic-based, or butyl rubber-based sealant is used.

[0114] For example, by using a silicone-based sealant that is heat-resistant to 250 to 300 degrees Celsius, surface mounting such as reflow is possible. This configuration allows for a battery that can be sealed from outside air and moisture and has improved reliability.

[0115] The battery 1200 may include a water-repellent material in addition to the sealing material 500. The water-repellent material may be located between the insulating member 200 and the lead terminals, similar to the sealing material 500. The water-repellent material may be in contact with the lead terminals. This allows the surfaces of the lead terminals and the surfaces of the minute pores in the insulating member 200 to repel moisture, suppressing deterioration due to moisture penetration and further improving the reliability of the battery.

[0116] The water repellent material may be a silane coupling material.

[0117] A silane coupling material may be applied to the lead terminals before assembly. The silane coupling material is particularly effective in preventing moisture from entering the battery through tiny gaps of 1 μm or less.

[0118] The silane coupling material may be a general one, such as a known silane coupling material of the methoxy, ethoxy, dialkoxy, trialkoxy, etc. The silane coupling material may be any silane coupling material that has a water-repellent effect on the surfaces of the lead terminal and insulating member 200 used.

[0119] (Third embodiment) A battery 1300 according to a third embodiment will now be described.

[0120] Figure 4 shows a schematic configuration of a battery 1300 according to a third embodiment. Figure 4(a) shows a cross-sectional view of the schematic configuration of the battery 1300 according to the third embodiment as seen from the y-axis direction. Figure 4(b) shows a plan view of the schematic configuration of the battery 1300 according to the third embodiment as seen from below in the z-axis direction. Figure 4(a) shows a cross section taken along line IV-IV in Figure 4(b).

[0121] 4, a battery 1300 according to the third embodiment includes a battery element 600. The battery element 600 has a configuration in which a plurality of battery elements 100 are stacked.

[0122] Opposing electrodes are electrically connected between the plurality of battery elements 100. Therefore, the battery 1300 forms a bipolar electrode.

[0123] The plurality of battery elements 100 are bonded together with, for example, a conductive adhesive.

[0124] The conductive adhesive may be a thermosetting conductive paste. For example, a thermosetting conductive paste containing silver metal particles may be used. The resin used in the thermosetting conductive paste may be any resin that functions as a binder for adhesion. Furthermore, a resin appropriate for the manufacturing process employed, such as printability and applicability, may be selected. Examples of the resin used in the thermosetting conductive paste include thermosetting resins. Examples of thermosetting resins include: (i) amino resins such as urea resin, melamine resin, and guanamine resin; (ii) epoxy resins such as bisphenol A, bisphenol F, phenol novolac, and alicyclic; (iii) oxetane resin; (iv) phenolic resins such as resol and novolac; and (v) silicone-modified organic resins such as silicone epoxy and silicone polyester. Only one of these materials may be used as the resin, or two or more of these materials may be used in combination.

[0125] The battery element 600 may have a structure in which two battery elements 100 are stacked in series in the z-axis direction, or may have a structure in which three or more battery elements 100 are stacked.

[0126] Note that a plurality of battery elements 100 may be stacked so as to be electrically connected in parallel, thereby achieving a high-capacity, highly reliable stacked battery.

[0127] [Battery manufacturing method] Next, a method for manufacturing the battery of the present disclosure will be described. As an example, a method for manufacturing the battery 1300 according to the third embodiment will be described below.

[0128] In the following description of the manufacturing method, the first electrode 120 is the positive electrode and the second electrode 140 is the negative electrode. Therefore, the first current collector 110 is the positive electrode current collector and the second current collector 150 is the negative electrode current collector. The battery element 600 has a configuration in which two battery elements 100 are stacked in series.

[0129] First, pastes to be used for printing the first active material layer 160 (hereinafter referred to as the positive electrode active material layer) and the second active material layer 170 (hereinafter referred to as the negative electrode active material layer) are prepared. As the solid electrolyte raw material used for the mixture of the positive electrode active material layer and the negative electrode active material layer, for example, a glass powder of Li2S-P2S5-based sulfide containing triclinic crystals as the main component and having an average particle size of about 10 μm is prepared. This glass powder has a density of, for example, 2 × 10 -3 S / cm or more and 3×10 -3 As the positive electrode active material, for example, a layered Li·Ni·Co·Al composite oxide (e.g., LiNi 0.8 Co 0.15 Al 0.05 A powder of (O2) is used. A mixture containing the above-mentioned positive electrode active material and the above-mentioned glass powder is dispersed in an organic solvent or the like to prepare a paste for a positive electrode active material layer. As the negative electrode active material, for example, a powder of natural graphite having an average particle size of about 10 μm is used. A mixture containing the above-mentioned negative electrode active material and the above-mentioned glass powder is dispersed in an organic solvent or the like to prepare a paste for a negative electrode active material layer.

[0130] Next, copper foils, for example, about 15 μm thick, are prepared as the first current collector 110 (hereinafter referred to as the positive electrode current collector) and the second current collector 150 (hereinafter referred to as the negative electrode current collector). For example, by screen printing, the above-mentioned positive electrode active material layer paste and negative electrode active material layer paste are printed in a predetermined shape and to a thickness of about 50 μm or more and 100 μm or less on one surface of each copper foil. The positive electrode active material layer paste and negative electrode active material layer paste are dried at a temperature of 80°C or more and 130°C or less. In this way, a positive electrode active material layer is formed on the positive electrode current collector, and a negative electrode active material layer is formed on the negative electrode current collector. The positive electrode active material layer and negative electrode active material layer each have a thickness of 30 μm or more and 60 μm or less.

[0131] Next, the glass powder is dispersed in an organic solvent or the like to prepare a paste for a solid electrolyte layer. The paste for a solid electrolyte layer is printed on the positive electrode and the negative electrode using a metal mask, for example, to a thickness of about 100 μm. Thereafter, the positive electrode and the negative electrode on which the paste for a solid electrolyte layer is printed are dried at a temperature of 80° C. or higher and 130° C. or lower.

[0132] Next, the solid electrolyte printed on the positive electrode and the solid electrolyte printed on the negative electrode are stacked so as to be in contact with and face each other.

[0133] Next, the laminated body is pressed in a pressing mold. Specifically, a 70 μm thick, 5×10 elastic modulus, 5×10 6 An elastic sheet having a pressure of about 300 MPa is inserted. With this configuration, pressure is applied to the laminate via the elastic sheet. Thereafter, the laminate is pressed for 90 seconds while the pressing mold is heated to 50°C at a pressure of 300 MPa. This results in a battery element 100.

[0134] Two battery elements 100 are prepared. A thermosetting conductive paste containing silver particles is screen-printed to a thickness of about 30 μm on the surface of the negative electrode current collector of one battery element 100. Then, the negative electrode current collector of this battery element 100 and the positive electrode current collector of the other battery element 100 are arranged and pressed together so as to be joined by the conductive paste. After this, the battery elements 100 are pressed together at a pressure of, for example, about 1 kg / cm. 2 The battery element 600 is then left stationary with a pressure of 100°C or more applied thereto, and subjected to a heat curing treatment. The curing temperature is, for example, about 100°C or more and 300°C or less. The curing time is, for example, 60 minutes. After the heat curing treatment, the battery element 600 is cooled to room temperature. This results in a battery element 600 in which two battery elements 100 are connected in series.

[0135] Next, two lead terminals 300a and 300b are prepared. The lead terminals are made of, for example, SUS and have a thickness of 300 μm. One lead terminal (for example, lead terminal 300a) is bonded to the main surface of the positive electrode current collector of the battery element 600, and the other lead terminal (for example, lead terminal 300b) is bonded to the main surface of the negative electrode current collector of the battery element 600 using a silver-based conductive resin, and the resin is then thermally cured. The curing temperature is, for example, 150°C or higher and 200°C or lower, which is lower than the melting point of the solder material. The curing time is, for example, 1 hour or higher and 2 hours or lower. In this manner, the lead terminals are bonded to the battery element 600. Here, the portion of the lead terminal that is enclosed in the insulating member 200 is previously plated with Sn-based solder (for example, 3 μm to 7 μm thick), which is the first solder material. At this time, the portion of the lead terminal that is bonded to the battery element 600 does not need to be solder-plated.

[0136] The lead terminal is bent so that it has a portion that fits along the side surface of the battery element 600. Furthermore, the lead terminal is bent again, for example, at a position about halfway through the thickness of the battery element 600. In this way, a crank-shaped bent portion is formed in the lead terminal.

[0137] Next, a thermosetting epoxy resin is poured into a mold, and the battery element 600 with the lead terminals connected thereto is immersed and placed in a predetermined position. This is then cured at 180°C to 210°C for 1 to 2 hours. After curing, the lead terminals exposed from the epoxy resin are bent and heat-treated at a temperature above the melting point of the first solder material, for example, 260°C, for 1 to 5 minutes. In this way, the battery 1300 is obtained. Heat treatment at a temperature above the melting point of the first solder material may be performed simultaneously with mounting.

[0138] The method and order of forming the battery are not limited to the above example.

[0139] In the above-described manufacturing method, the positive electrode active material layer paste, the negative electrode active material layer paste, the solid electrolyte layer paste, and the conductive paste are applied by printing in the manufacturing of the battery element 100 and the battery element 600. However, the present invention is not limited to this. Examples of printing methods that may be used include a doctor blade method, a calendar method, a spin coating method, a dip coating method, an inkjet method, an offset method, a die coating method, and a spray method.

[0140] While the battery of the present disclosure has been described above based on the embodiments, the present disclosure is not limited to these embodiments. As long as they do not deviate from the gist of the present disclosure, various modifications conceivable by those skilled in the art to the embodiments and other forms constructed by combining some of the components of the embodiments are also included in the scope of the present disclosure. [Industrial Applicability]

[0141] The battery according to the present disclosure can be used, for example, as a secondary battery such as an all-solid-state battery used in various electronic devices or automobiles.

Claims

1. a battery element including a first electrode, a solid electrolyte layer, and a second electrode; An insulating member; A lead terminal; a first solder material; Equipped with the insulating member encloses the battery element and the first solder material; the lead terminal is electrically connected to the battery element, the first solder material is located between the insulating member and the lead terminal; the first solder material includes a solder plating film provided on a surface of the lead terminal; the solder plating film covers the entire surface of the lead terminal inside the insulating member; battery.

2. the first solder material fills at least a portion of a gap between the insulating member and the lead terminal; The battery of claim 1 .

3. The lead terminal has a bent portion in the insulating member. The battery according to claim 1 or 2.

4. the lead terminal is connected to a main surface of the first electrode or a main surface of the second electrode, the bent portion includes a crank-shaped bent portion in which the lead terminal is bent from the main surface of the first electrode or the main surface of the second electrode in a direction along a side surface of the battery element and is bent so as to extend toward an outside of the insulating member. The battery of claim 3.

5. the first solder material includes a solder material in contact with the bent portion; The battery according to claim 3 or 4.

6. the lead terminal has an outer portion located outside an outer edge of the battery element in a plan view, the first solder material is between the outer portion and the insulating member; The battery of any one of claims 1 to 5.

7. The insulating member includes an epoxy resin. The battery of any one of claims 1 to 6.

8. A battery element including a first electrode, a solid electrolyte layer, and a second electrode; An insulating member; A lead terminal; a first solder material; Sealing material and Equipped with the insulating member encloses the battery element and the first solder material; the lead terminal is electrically connected to the battery element, the first solder material is located between the insulating member and the lead terminal; The sealing material is positioned between the insulating member and the lead terminal. battery.

9. A battery element including a first electrode, a solid electrolyte layer, and a second electrode; An insulating member; A lead terminal; a first solder material; Water-repellent material and Equipped with the insulating member encloses the battery element and the first solder material; the lead terminal is electrically connected to the battery element, the first solder material is located between the insulating member and the lead terminal; The water-repellent material is in contact with the lead terminal. battery.

10. Further comprising a flux material; the flux material is located between the insulating member and the first solder material; 10. The battery of claim 1.

11. Further comprising a second solder material; the second solder material covers at least a portion of the surface of the lead terminal exposed from the insulating member; The battery of any one of claims 1 to 10.

12. connecting a lead terminal to a battery element including a first electrode, a solid electrolyte layer, and a second electrode; Enclosing the battery element in an insulating member; applying heat to the lead terminal; Including, the lead terminal includes a first solder material; the first solder material is contained in the insulating member and is located between the lead terminal and the insulating member; the first solder material includes a solder plating film provided on a surface of the lead terminal; the solder plating film covers the entire surface of the lead terminal inside the insulating member, When applying heat to the lead terminals, a temperature equal to or higher than the melting point of the first solder material is applied to the lead terminals. How batteries are manufactured.

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