Conductive material and heater

Abstract

This energizing member (11) has an electrode pad (14) for applying a voltage to a conductive film (13), a plurality of non-conductive parts (16) are arranged to form a regularly repeating pattern on the conductive film (13), the plurality of non-conductive parts (16) contain a plurality of units having elongated shapes so as to be connected to each other at a connection point (C1) and extend from the connection point (C1) in different directions, and a line segment connecting the connection points (C1) of the two closet non-conductive parts (16) from among the plurality of non-conductive parts (16) extends in a direction that differs from the direction in which each of the plurality of units extends.

Description

[Technical Field]

[0001] The present invention relates to a current-carrying member that is transparent to electromagnetic waves in a specific frequency band, and a heater that includes the current-carrying member. [Background technology]

[0002] Sensors and communication devices using electromagnetic waves such as millimeter waves and microwaves have been widely used. These devices are often mounted in automobiles and other vehicles, surrounded by protective covers. Snow and ice buildup on such covers, or fogging caused by water vapor, is known to cause false detection in sensors located inside the covers or communication problems in communication devices. To remove snow, ice, and fogging, a heat-generating member has been developed, as disclosed in Patent Document 1, for example. The heat-generating member of Patent Document 1 includes a three-dimensional structure with a plated layer and a conductive laminate having a metal layer disposed on the plated layer, with the metal layer functioning as a heating wire.

[0003] Furthermore, it is known that electromagnetic waves in a frequency band different from the frequency band of electromagnetic waves transmitted and received by sensors, communication devices, etc. can cause false detection in sensors and communication interference in communication devices. To suppress such false detection and communication interference in sensors, a metal mesh structure such as that disclosed in Non-Patent Document 1 is known. The metal mesh in Non-Patent Document 1 has multiple cross-shaped non-conductive portions formed in a grid pattern along two mutually perpendicular directions. These multiple non-conductive portions allow electromagnetic waves in a frequency band corresponding to the size of the cross shape to easily pass through the metal mesh, while blocking electromagnetic waves in other frequency bands. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] International Publication No. 2017 / 163830 [Non-patent literature]

[0005] [Non-Patent Document 1] Vyachesla V. Komarov, Valery P. Meschanov, “Transmission properties of metal mesh filters at 90 GHz,” Journal of Computational Electronics, February 28, 2019, 18:696-704 Summary of the Invention [Problem to be solved by the invention]

[0006] However, the heat-generating member disclosed in Patent Document 1 cannot transmit only electromagnetic waves in a specific frequency band, making it difficult to achieve both the heat-generating function and the function of transmitting only electromagnetic waves in a specific frequency band. Furthermore, the inventors discovered that when an attempt is made to heat the metal mesh disclosed in Non-Patent Document 1 by passing current through it, the current flows intensively between multiple non-conductive parts, causing localized heat generation and resulting in the metal mesh being oxidized in those areas, deteriorating the metal mesh. Therefore, it has been considered to increase the spacing between the multiple non-conductive parts in order to avoid the current concentration, but increasing this spacing reduces the transmittance of electromagnetic waves having a specific frequency band corresponding to the size of the non-conductive parts, resulting in the problem that the function of transmitting only electromagnetic waves in a specific frequency band is not fully exhibited.

[0007] The present invention is intended to solve these problems and aims to provide an electrically conductive member that can suppress localized deterioration while simultaneously achieving both a heat-generating function and a function of transmitting only electromagnetic waves in a specific frequency band. [Means for solving the problem]

[0008] In order to achieve the above object, the conductive member of the present invention is a conductive member having a conductive film formed thereon, which has electrode pads for applying a voltage to the conductive film, and in which a plurality of non-conductive parts are formed in the conductive film and arranged to form a regularly repeated pattern, and each of the plurality of non-conductive parts includes a plurality of unit units having an elongated shape that are connected to each other at a connection point and extend in different directions from the connection point, and the direction in which a line segment connecting the connection points of two non-conductive parts that are closest to each other among the plurality of non-conductive parts extends is different from the direction in which each of the plurality of unit units extends.

[0009] It is preferable that a pair of electrode pads are connected to both ends of the conductive film, and that a non-conductive portion is disposed on any path in the conductive film connecting the pair of electrode pads along the surface of the conductive film. The conductive film may also extend in a plane, in which case the non-conductive portion may be disposed on any path that linearly connects a pair of electrode pads along the surface of the conductive film.

[0010] The non-conductive portion can be configured by four units, and in this case, the four units are preferably connected to each other at connection points so as to form a cross shape. In this case, the distance between the two closest non-conductive parts among the multiple non-conductive parts is preferably 20% or more and 50% or less of the distance between the connection points of the two non-conductive parts, and more preferably 30% or more and 40% or less.

[0011] It is preferable that the current-carrying member has a plurality of conductive wires forming a mesh shape, and the conductive film is formed by the plurality of conductive wires. In this case, the direction in which at least one unit of the non-conductive portion extends may be the same as or different from the direction in which the plurality of conductive wires extend.

[0012] The electrode pad preferably has a width at least 10 times wider than the line width of the conductive wiring. The current-carrying member may have, within the non-conductive portion, a plurality of dummy wirings that are arranged on extensions of the plurality of conductive wirings and are electrically insulated from the plurality of conductive wirings. The conductive film can have a shape that conforms to the curved surface. The conductive film preferably has a sheet resistance of 0.1 Ω / □ or more and 10.0 Ω / □ or less, and more preferably has a sheet resistance of 0.3 Ω / □ or more and 3.0 Ω / □ or less. The unit preferably has a width of 0.1 mm or more and 1000.0 mm or less along the direction in which the unit extends.

[0013] A heater according to the present invention is characterized by including the above-described current-carrying member. [Effects of the Invention]

[0014] The electrically conductive member of the present invention has an electrode pad for applying a voltage to a conductive film, and has a plurality of non-conductive parts arranged to form a regularly repeated pattern on the conductive film, and each of the plurality of non-conductive parts includes a plurality of unit units having an elongated shape that are connected to each other at a connection point and extend in different directions from each other from the connection point, and the direction in which the line segment connecting the connection points of two closest non-conductive parts among the plurality of non-conductive parts extends is different from the direction in which each of the plurality of unit units extends, so that the heat generation function and the function of transmitting only electromagnetic waves in a specific frequency band can be achieved at the same time, while local deterioration can be suppressed. [Brief explanation of the drawings]

[0015] [Figure 1] 2 is a cross-sectional view schematically showing a part of a current-carrying member according to the first embodiment of the present invention. FIG. [Figure 2] 1 is a plan view of a current-carrying member according to a first embodiment of the present invention. [Figure 3] 2 is an enlarged schematic view showing a conductive mesh according to the first embodiment of the present invention. FIG. [Figure 4] 3 is a diagram showing a non-conductive portion according to the first embodiment of the present invention. FIG. [Figure 5]FIG. 3 is a diagram showing three adjacent non-conductive portions in the first embodiment of the present invention. [Figure 6] 5A and 5B are diagrams illustrating modified examples of the non-conductive portion in the first embodiment of the present invention. [Figure 7] 10 is an example showing another modified example of the non-conductive portion in the first embodiment of the present invention. [Figure 8] FIG. 10 is a plan view of a current-carrying member according to a modified example of the first embodiment of the present invention. [Figure 9] FIG. 10 is a diagram showing a non-conductive portion according to a second embodiment of the present invention. [Figure 10] FIG. 10 is an enlarged view showing a gap according to the second embodiment of the present invention. [Figure 11] FIG. 10 is a plan view of a current-carrying member according to a third embodiment of the present invention. [Figure 12] FIG. 10 is a plan view of a current-carrying member of Comparative Example 1. DETAILED DESCRIPTION OF THE INVENTION

[0016] Hereinafter, the current-carrying member of the present invention will be described in detail based on preferred embodiments shown in the accompanying drawings. It should be noted that the drawings described below are illustrative for explaining the present invention, and the present invention is not limited to the drawings shown below. In the following, "to" indicating a numerical range includes the values ​​written on both sides. For example, if ε is between α and β, the range of ε includes α and β, and expressed in mathematical notation, α≦ε≦β. Unless otherwise specified, angles such as "parallel" and "perpendicular" include a generally acceptable error range in the relevant technical field. Furthermore, the term "same" includes a margin of error generally accepted in the relevant technical field.

[0017] Additionally, "(meth)acrylate" refers to either or both of acrylate and methacrylate, "(meth)acrylic" refers to either or both of acrylic and methacrylic, and "(meth)acryloyl" refers to either or both of acryloyl and methacryloyl. Unless otherwise specified, "transparent to visible light" means that the visible light transmittance is 40% or more, preferably 80.0% or more, and more preferably 90.0% or more in the visible light wavelength range of 380 nm to 800 nm. Furthermore, in the following description, "transparent" means transparent to visible light, unless otherwise specified. The visible light transmittance is measured using "Plastics - Determination of total light transmittance and total light reflectance" as defined in JIS (Japanese Industrial Standards) K 7375:2008.

[0018] Embodiment 1 1 shows a current-carrying member 11 according to an embodiment of the present invention. The current-carrying member 11 is a film-like member that includes an insulating transparent substrate 12 and a conductive film 13 formed on one surface of the substrate 12. The conductive film 13 is transparent and has a visible light transmittance of, for example, 75.0% or more.

[0019] 2, the current-carrying member 11 includes a pair of electrode pads 14 connected to both ends of the conductive film 13 in order to apply a voltage to the conductive film 13. Each of the pair of electrode pads 14 has a rectangular shape and is arranged so that its long sides face each other. Each of the pair of electrode pads 14 has a width W in the direction of its short side perpendicular to the long side. Hereinafter, for ease of explanation, the direction from one electrode pad 14 to the other electrode pad 14 will be referred to as a first direction D1, and the direction perpendicular to the first direction D1 will be referred to as a second direction D2.

[0020] The conductive film 13 is formed of a plurality of conductive wires 15 extending in the first direction D1 and the second direction D2. The plurality of conductive wires 15 also form a conductive mesh M1.

[0021] As shown in FIG. 3, the plurality of conductive wires 15 have a line width T and are arranged at a pitch E, which is defined as the distance between center lines CL of the conductive wires 15. The conductive mesh M has a plurality of square openings 17, forming a so-called square lattice.

[0022] The line width T of the conductive wiring 15 is not particularly limited, but the upper limit is preferably 1000.00 μm or less, more preferably 500.00 μm or less, and even more preferably 300.00 μm or less. The lower limit of the line width T is preferably 1.00 μm or more, and more preferably 3.00 μm or more. If the line width T is within the above range, the conductive mesh M can have high conductivity. Furthermore, from the viewpoint of conductivity, the thickness of the conductive wiring 15 can be set to 0.01 μm or more and 200.00 μm or less, but the upper limit is preferably 30.00 μm or less, more preferably 20.00 μm or less, even more preferably 9.00 μm or less, and particularly preferably 5.00 μm or less. The lower limit of the thickness of the conductive wiring 15 is preferably 0.01 μm or more, more preferably 0.10 μm or more, and even more preferably 0.5 μm or more.

[0023] The sheet resistance of the conductive film 13 formed by the plurality of conductive wirings 15 is preferably 0.1 Ω / □ or more and 10.0 Ω / □ or less, and more preferably 0.3 Ω / □ or more and 3.0 Ω / □ or less. Because the conductive film 13 has a low sheet resistance of 10.0 Ω / □ or less, it has high heating performance with a large amount of heat generated under voltage-limited conditions, and also has high electromagnetic wave transmittance. Furthermore, because the conductive film 13 has a resistance value of 0.10 Ω / □ or more, it has high heating performance with a large amount of heat generated under current-limited conditions.

[0024] As shown in FIG. 2, the conductive film 13 has a plurality of cross-shaped non-conductive portions 16 formed thereon, which are arranged in the same direction so as to form a regularly repeated pattern. 4, the non-conductive portion 16 is formed by the conductive wiring 15 and is surrounded by the edge portion 18 of the cross shape, where the conductive wiring 15 is not present, and electricity does not flow through the interior of the non-conductive portion 16. The non-conductive portion 16 is formed by connecting one end of four rectangular units U1 at the connection point C1, with the center of the cross shape being the connection point C1. These four units U1 extend from the connection point C1 in different directions, namely, a first direction D1, a direction opposite to the first direction D1, a second direction D2, and a direction opposite to the second direction D2.

[0025] 4, each of the four units U1 included in the non-conductive portion 16 has a rectangular shape, with a width L1 in the long side direction and a width L2 in the short side direction. The non-conductive portion 16 also has a width L3 in the first direction D1 and the second direction D2 that is twice the width L1 of the unit U1.

[0026] Here, the non-conductive portion 16 is intended to transmit electromagnetic waves of a specific frequency band corresponding to its size, i.e., width L2 and width L3 (width L1). Therefore, the size of the non-conductive portion 16 is designed according to the frequency band of the electromagnetic waves to be transmitted through the non-conductive portion 16. For example, if the non-conductive portion 16 is to transmit electromagnetic waves of a frequency band known as millimeter waves centered at 76.5 GHz, it is preferable to design the width L2 to 120 μm and the width L3 to 1330 μm. However, since the widths L2 and L3 also depend on the relative positions of the multiple non-conductive portions, they can be adjusted as appropriate. In this way, since the non-conductive portions 16 are formed in the conductive film 13, the conductive film 13 can transmit electromagnetic waves having a specific frequency band and block electromagnetic waves in other frequency bands.

[0027] 2, the non-conductive portions 16 are arranged alternately such that the two closest non-conductive portions 16 are offset by a pitch P1 in the first direction D1 and a pitch P2 in the second direction D2. Because the non-conductive portions 16 are arranged alternately in this manner, they are arranged at intervals of a pitch Q1 that is twice the length of the pitch P1 along the first direction D1, and at intervals of a pitch Q2 that is twice the length of the pitch P2 along the second direction D2.

[0028] Here, pitch P1 indicates the distance in the first direction D1 between the connection points C1 of the two closest non-conductive portions 16, and pitch P2 indicates the distance in the second direction D2 between the connection points C1 of the two closest non-conductive portions 16. Furthermore, pitch Q1 indicates the distance between the connection points C1 of the two non-conductive portions 16 arranged adjacently along the first direction D1, and pitch Q2 indicates the distance between the connection points C1 of the two non-conductive portions 16 arranged adjacently along the second direction D2.

[0029] Also, as shown in Figure 5, the direction in which the line segment F1 connecting the connection points C1 of the two closest non-conductive portions 16 among the multiple non-conductive portions 16 extends is different from the directions in which the four unit units U1 of each of the multiple non-conductive portions 16 extend, i.e., the first direction D1, the opposite direction to the first direction D1, the second direction D2, and the opposite direction to the second direction D2.

[0030] Here, it is generally known that when attempting to transmit electromagnetic waves in a specific frequency band corresponding to the size of the non-conductive parts while blocking electromagnetic waves in other frequency bands by arranging multiple non-conductive parts, it is necessary to set the distance between the connection points of adjacent non-conductive parts to an appropriate value corresponding to the frequency band of the electromagnetic waves to be transmitted.

[0031] Furthermore, the inventors discovered that when applying a voltage to a current-carrying member having a plurality of non-conductive portions to heat the current-carrying member, the closer the distance between the non-conductive portions is designed, the more likely it is that current will concentrate between the non-conductive portions, resulting in localized heat generation. Therefore, if the distance between the non-conductive portions is increased to avoid current concentration, there is a problem in that the ability to transmit electromagnetic waves in a specific frequency band corresponding to the size of the conductive portions is reduced.

[0032] 5, in the current-carrying member 11 according to the first embodiment of the present invention, the non-conductive portions 16 are arranged such that the direction in which a line segment F1 connecting the connection points C1 of the two closest non-conductive portions 16 among the plurality of non-conductive portions 16 extends is different from the direction in which each of the units U1 of the non-conductive portions 16 extends. Therefore, the distance between the connection points C1 of the non-conductive portions 16 can be designed to an appropriate value corresponding to the frequency band of the electromagnetic waves to be transmitted through the current-carrying member 11, and the distance K1 between the two closest non-conductive portions 16 and the distance K2 between two adjacent non-conductive portions 16 in the first direction D1 or the second direction D2 can be designed to be wide so as to prevent excessive current concentration. This makes it possible to prevent the density of the current passing between two adjacent non-conductive portions 16 from becoming high, without impairing the function of transmitting electromagnetic waves having a specific frequency band.

[0033] Here, as shown in Figure 5, by designing the distance K1 between the two closest non-conductive parts 16 among the multiple non-conductive parts 16 to be 20% or more and 50% or less of the distance K3 between the connection points C1 of these two non-conductive parts 16, the density of the current passing between two close non-conductive parts 16 can be further prevented from becoming high, and by designing it to be 30% or more and 40% or less, the density of the current passing between two close non-conductive parts 16 can be further prevented from becoming high.

[0034] From the above, according to the conductive member 11 of embodiment 1 of the present invention, the multiple non-conductive portions 16 are arranged so that the direction in which the line segment F1 connecting the connection points C1 of the two closest non-conductive portions 16 among the multiple non-conductive portions 16 extends is different from the direction in which the four unit units U1 of each non-conductive portion 16 extend, thereby making it possible to suppress local deterioration while achieving both the heat generation function and the function of transmitting only electromagnetic waves of a specific frequency band.

[0035] 2, in the current-carrying member 11, non-conductive portions 16 are arranged on any path A1 that linearly connects a pair of electrode pads 14 in the first direction D1 along the surface of the conductive film 13. Therefore, it is presumed that the current flowing from one electrode pad 14 to the other electrode pad 14 on the conductive film 13 will relatively evenly detour around the multiple non-conductive portions 16. In this way, in the current-carrying member 11, non-conductive portions 16 are arranged on any path A1 that connects a pair of electrode pads 14 in the first direction D1, i.e., on any shortest path that linearly connects a pair of electrode pads 14 to each other along the surface of the conductive film 13, thereby further suppressing localized current flow on the conductive film 13.

[0036] Although not shown, a heater can be configured by the current-carrying member 11 according to the first embodiment of the present invention and a power supply device for applying a voltage to the conductive film 13 of the current-carrying member 11. This heater is particularly useful when it is disposed to cover sensors and communication devices that use electromagnetic waves such as millimeter waves and microwaves, which are installed in automobiles, for example.

[0037] For example, it is known that snow or ice accumulation around a sensor, communication device, etc. can easily cause false detection in the sensor or communication failure in the communication device. It is also known that when electromagnetic waves of a frequency band different from the frequency band of the electromagnetic waves transmitted and received by the sensor, communication device, etc. are present around the sensor, communication device, etc., the electromagnetic waves of the different frequency bands can cross each other, easily causing false detection or communication failure.

[0038] A heater including the current-carrying member 11 according to the first embodiment of the present invention can remove snow or ice that has accumulated on the heater, and can transmit electromagnetic waves in a frequency band corresponding to the size of the plurality of non-conductive portions 16 in the current-carrying member 11 while blocking electromagnetic waves in other frequency bands, thereby suppressing the effects of snow or ice and suppressing false detections and communication failures in sensors or communication devices, etc. Furthermore, this heater includes the current-carrying member 11 according to the first embodiment of the present invention, and is therefore excellent in durability because local deterioration of the conductive film 13 due to heat generation is suppressed.

[0039] The pair of electrode pads 14 preferably have a width W that is at least 10 times wider than the line width T of the conductive wiring 15. By designing the width W of the electrode pads 14 to be wide in this way, it is possible to reduce voltage loss due to contact resistance at the connection between the electrode pads 14 and a power source (not shown) and voltage loss within the voltage pads 14, thereby suppressing unnecessary energy loss in the electrode pads 14.

[0040] 1 shows that the conductive film 13 has a shape that follows a plane, but it may also have a shape that follows a curved surface. For example, by forming the conductive film 13 on a substrate 12 that has a curved surface, the conductive film 13 can be formed to have a shape that follows the curved shape of the substrate 12. Examples of such curved shapes include shapes that follow the surface of any three-dimensional shape, such as a sphere, a cylinder, or a cone.

[0041] When the conductive film 13 has a shape that follows a curved surface, it is preferable that a non-conductive portion 16 is disposed on any path that connects a pair of electrode pads 14 connected to both ends of the conductive film 13 along the surface of the conductive film 13. Here, the path that connects the electrode pads 14 along the surface of the conductive film 13 refers to a path that is perpendicular to the edges of the pair of opposing electrode pads 14 and that runs straight from one electrode pad 14 to the other electrode pad 14 along the curved shape of the conductive film 13. It is preferable that this path connects the pair of electrode pads 14 over the shortest distance. By disposing a plurality of non-conductive portions 16 on the conductive film 13 in this manner, localized current flow on the conductive film 13 can be further suppressed.

[0042] The conductive film 13 may also have a shape that conforms to the surface of a more complex three-dimensional object. Examples of complex three-dimensional objects include an automobile emblem, a radar radome, a radar front cover, an automobile headlamp cover, an antenna, and a reflector. By arranging the current-carrying member 11 according to the embodiment of the present invention along the shape of such a three-dimensional object, it is possible to, for example, arrange the current-carrying member 11 along the automobile emblem and install a radar inside the emblem.

[0043] Furthermore, when the current-carrying member 11 is arranged along the emblem of a vehicle, or when the design of the member covered by the current-carrying member 11 needs to be visible to an outside observer, it is desirable that the current-carrying member 11 be transparent. In such cases, in order to make the presence of the conductive mesh M1 less noticeable, the upper limit of the pitch E of the conductive mesh M1 is preferably 800.00 μm or less, more preferably 600.00 μm or less, and even more preferably 400.00 μm or less. The lower limit of the pitch E is preferably 5.00 μm or more, more preferably 30.00 μm or more, and even more preferably 80.00 μm or more.

[0044] Furthermore, in order for the current-carrying member 11 to have a visible light transmittance of 75.0% or more, the aperture ratio of the conductive mesh M is preferably 75% or more, and more preferably 80% or more. Here, the aperture ratio of the conductive mesh M refers to the proportion of the transparent portion excluding the conductive wiring 15 in the area occupied by the conductive mesh M, i.e., corresponds to the proportion of the total area occupied by the multiple openings 17 to the entire area of ​​the conductive mesh M.

[0045] The shape of the multiple openings 17 of the conductive mesh M is not limited to a square, but can be, for example, a triangle such as an equilateral triangle, an isosceles triangle, or a right-angled triangle; a quadrangle such as a square, a rectangle, a parallelogram, or a trapezoid; a (regular) polygon such as a (regular) hexagon or a (regular) octagon; a circle, an ellipse, or a star; or a geometric figure that combines these shapes.

[0046] Furthermore, although the conductive film 13 is described as being formed by a plurality of conductive wirings 15, this is not particularly limited to this. For example, the conductive film 13 may be formed by a film of a so-called transparent conductive oxide such as ITO (Indium Tin Oxide) or a metal, and the conductive film 13 may be formed by the surface thereof.

[0047] In this case, the non-conductive portion 16 is formed, for example, by cutting a film of transparent conductive oxide or metal in a cross shape. The non-conductive portion 16 formed in this manner allows electromagnetic waves in a frequency band corresponding to the size of the non-conductive portion 16 to pass through the current-carrying member 11, while blocking electromagnetic waves in other frequency bands. Furthermore, when a voltage is applied to the current-carrying member 11, the current flowing from one electrode pad 14 to the other electrode pad 14 bypasses the non-conductive portion 16. Therefore, even when the conductive film 13 is made of a film of transparent conductive oxide or metal, and the non-conductive portion 16 is formed by cutting out a film of transparent conductive oxide or metal, it is possible to suppress localized deterioration while achieving both the heat-generating function and the function of transmitting only electromagnetic waves in a specific frequency band.

[0048] It is also explained that the size of the unit U1 of the non-conductive portion 16 is designed according to the frequency band of the electromagnetic waves to be transmitted through the non-conductive portion 16. For example, in order to transmit electromagnetic waves in the millimeter wave frequency band centered at 76.5 GHz, the width of the unit U1 in the direction in which the unit U1 extends, i.e., width L1, can be designed to be 665 μm. In the present invention, for example, this length L1 can be designed to be 0.1 mm or more, i.e., 100 μm or more and 1000.0 mm or less.

[0049] Furthermore, although the non-conductive portion 16 has been described as being composed of four unit units U1, it may also be composed of two unit units, three unit units, or five or more unit units. 6 shows an example of a non-conductive portion 36 made up of three unit units U3. The non-conductive portion 36 is made up of three rectangular unit units U3 connected to each other at a connection point C3, and is surrounded by an edge 38 formed by the conductive wiring 15. Furthermore, these three unit units U3 extend in different directions from the connection point C3.

[0050] Furthermore, although the unit U1 of the non-conductive portion 16 has been described as having a rectangular shape, the shape of the unit U1 is not particularly limited to a rectangle as long as it is an elongated shape. 7 shows an example of a non-conductive portion 46 having a unit U4 with an elongated elliptical shape. The non-conductive portion 46 is configured by four elliptical units U4 connected to each other at connection points C4 to form a cross. These four units U4 extend in different directions, namely, a first direction D1, a direction opposite to the first direction D1, a second direction D2, and a direction opposite to the second direction D2, respectively.

[0051] Furthermore, the four unit units U1 of the non-conductive portion 16 extend in the same direction as the plurality of conductive wirings 15. However, as shown in Fig. 8, the extension direction of the four unit units U1 and the extension direction of the plurality of conductive wirings 15 may be different from each other. In the example of Fig. 8, the plurality of conductive wirings 15 extend in a direction intersecting the first direction D1 and the second direction D2, thereby forming a conductive mesh M3. Even in this case, the current-carrying member 11 can suppress localized deterioration while simultaneously achieving both a heat generation function and a function of transmitting only electromagnetic waves in a specific frequency band.

[0052] However, if the extending direction of the four unit units U1 and the extending direction of the plurality of conductive wires 15 are the same, the presence of the cross-shaped non-conductive portion 16 is less noticeable when viewing the current-carrying member 11. Therefore, for example, if transparency is required for the current-carrying member 11, it is preferable that the extending direction of the four unit units U1 and the extending direction of the plurality of conductive wires 15 are the same, from the viewpoint of making the presence of the non-conductive portion 16 less noticeable.

[0053] Embodiment 2 In embodiment 1, no conductive wiring 15 is arranged inside the non-conductive portion 16, but conductive wiring 15 that is not electrically connected to a pair of electrode pads 14 can be arranged inside the non-conductive portion 16.

[0054] 9 shows a non-conductive portion 56 in the second embodiment. Similar to the non-conductive portion 16 in the first embodiment, the non-conductive portion 56 is surrounded by a cross-shaped edge portion 58 formed by the conductive wiring 15, and rectangular units U5 are connected in a cross shape at connection points C5, and the non-conductive portion 56 includes a plurality of dummy wirings 59. The dummy wirings 59 are made of the same material as the conductive wirings 15, and are arranged so as to overlap in parallel with the extensions of the conductive wirings 15 that are electrically connected to a pair of electrode pads 14.

[0055] 10, the dummy wiring 59 is disposed across a gap G from the conductive wiring 15 electrically connected to the pair of electrode pads 14. Therefore, the dummy wiring 59 is electrically insulated from the pair of electrode pads 14. In order to make the presence of the gap G less noticeable, the gap G is preferably designed to have a length in the range of 0.01 μm to 2.00 μm.

[0056] In this way, by arranging a plurality of dummy wirings 59 inside non-conductive portion 56, the presence of non-conductive portion 56 can be made less noticeable when an observer looks at the current-carrying member of embodiment 2. Therefore, the current-carrying member of embodiment 2 is particularly useful when covering a component whose design is desired to be visible to an outside observer, such as an automobile emblem, because it can prevent the design of the component from being damaged.

[0057] Embodiment 3 In the conductive member 11 of embodiment 1, the non-conductive portion 16 is arranged on any path A1 in the conductive film 13 that connects a pair of electrode pads 14 in a straight line along the first direction D1. However, if the multiple non-conductive portions 16 are arranged so that the direction in which the line segment F1 connecting the connection points C1 of two non-conductive portions 16 that are closest to each other extends is different from the direction in which each of the four unit units U1 extends, there may be a path A1 that connects a pair of electrode pads 14 in a straight line and passes between the non-conductive portions 16.

[0058] 11 shows a current-carrying member 61 according to embodiment 3. The current-carrying member 61 is configured such that, instead of the non-conductive portion 16 in the current-carrying member 11 according to embodiment 1, it includes a non-conductive portion 66 formed by rotating the non-conductive portion 16 by 45 degrees, and further, instead of the conductive mesh M1, it includes a conductive mesh M6 formed by rotating a plurality of conductive wires 15 by 45 degrees.

[0059] The two closest non-conductive portions 66 among the plurality of non-conductive portions 66 are aligned along the first direction D1 or the second direction D2, and the four unit elements U6 of the non-conductive portion 66 each extend from a connection point C6 in a direction intersecting the first direction D1 and the second direction D2. Therefore, the plurality of non-conductive portions 66 are arranged such that the direction in which a line segment F2 connecting the connection points C6 of the two closest non-conductive portions 66 among the plurality of non-conductive portions 66 extends is different from the direction in which each of the four unit elements U6 extends.

[0060] In the conductive film 63, a path that linearly connects a pair of electrode pads 14 along the first direction D1 exists between the two closest non-conductive portions 66, but the direction in which the line segment F2 connecting the connection points C6 of the two closest non-conductive portions 66 among the multiple non-conductive portions 66 extends is different from the direction in which each of the four units U6 extends, so that the distance K6 between the two non-conductive portions 66 can be designed to be wide so that the current does not concentrate excessively. This alleviates a local increase in the density of the current flowing between the pair of electrode pads 14, and suppresses deterioration of the conductive mesh M6.

[0061] From the above, according to the conductive member 61 of embodiment 3, the multiple non-conductive portions 66 are arranged so that the direction in which the line segment F2 connecting the connection points C6 of the two closest non-conductive portions 66 among the multiple non-conductive portions 66 extends is different from the direction in which the four unit units U6 of each non-conductive portion 66 extend, thereby making it possible to suppress local deterioration while achieving both the heat generation function and the function of transmitting only electromagnetic waves of a specific frequency band.

[0062] The following describes in detail each of the components constituting the current-carrying member 11 of embodiment 1. The following description also applies to each of the components of the current-carrying member of embodiment 2 and current-carrying member 61 of embodiment 3.

[0063] <Substrate> The substrate 12 is not particularly limited as long as it has insulating properties and can support at least the conductive film 13, but it is preferably transparent and made of a resin material. Specific examples of the resin material constituting the substrate 12 include polymethyl methacrylate (PMMA), acrylonitrile butadiene styrene (ABS), polyethylene terephthalate (PET), polycarbonate (PC), polycycloolefin, (meth)acrylic, polyethylene naphthalate (PEN), polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyvinylidene difluoride (PVDF), polyarylate (PAR), polyethersulfone (PES), polymeric acrylic, fluorene derivatives, and crystalline cycloolefin polymer (Cyclo Olefin Polymer). Polymer (COP), triacetylcellulose (TAC), etc.

[0064] Here, from the viewpoint of the transparency and durability of the substrate 12, the substrate 12 is preferably composed mainly of one of polymethyl methacrylate resin, polycarbonate resin, acrylonitrile butadiene styrene resin, and polyethylene terephthalate resin. Here, the term "main component of the substrate 12" means that the main component accounts for 80% or more of the components constituting the substrate 12.

[0065] The visible light transmittance of the substrate 12 is preferably 85.0% to 100.0%. The thickness of the substrate 12 is not particularly limited, but from the viewpoint of ease of handling, it is preferably 0.05 mm or more and 2.00 mm or less, and more preferably 0.10 mm or more and 1.00 mm or less.

[0066] <Primer layer> In order to firmly support the conductive layer 13, a primer layer may be provided between the substrate 12 and the conductive layer 13. The material of the primer layer is not limited as long as it can firmly support the conductive layer 13, but when the conductive film 13 is formed of a plurality of conductive wires 15, it is particularly preferable that the primer layer be made of a urethane-based resin material.

[0067] <Conductive wiring> The conductive wiring 15 is made of a conductive material. Examples of materials that can be used for the conductive wiring 15 include metals, metal oxides, carbon materials, and conductive polymers. For example, when the conductive wiring 15 is made of a metal, the type of metal is not particularly limited, and examples include copper, silver, aluminum, chromium, lead, nickel, gold, tin, and zinc. However, from the viewpoint of conductivity, copper, silver, aluminum, and gold are more preferred. Methods for forming metallic conductive wiring include semi-additive methods, full-additive methods, subtractive methods, silver salt methods, printing of metal-containing inks or their precursors, inkjet printing, and laser direct structuring methods, and combinations thereof can also be used. Bulk materials can be used as the metal, and nanowires and nanoparticles can also be used. When the conductive wiring 15 is made of a carbon material, the structure and composition of the conductive wiring 15 are not particularly limited, and examples of materials that can be used include carbon nanotubes, fullerenes, carbon nanotubes, graphene, and graphite. When the conductive wiring 15 is made of a metal oxide, ITO (Indium Tin Oxide) can be used as the conductive wiring 15. When the conductive wiring 15 is made of a conductive polymer, PEDOT-PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate) or the like can be used as the conductive wiring 15. [Example]

[0068] The present invention will be described in more detail below with reference to examples. The materials, amounts used, ratios, treatment details, treatment procedures, etc. shown in the following examples can be appropriately changed without departing from the spirit of the present invention, and the scope of the present invention should not be construed as being limited by the following examples.

[0069] Example 1 (Preparing the substrate) A polycarbonate resin film (Teijin Panlite PC-2151) having a thickness of 250.0 μm was prepared as a substrate.

[0070] (Preparation of primer layer-forming composition) The following components were mixed to obtain a composition for forming a primer layer. Z913-3 (manufactured by Aica Kogyo Co., Ltd.) 33 parts by weight IPA (isopropyl alcohol) 67 parts by weight

[0071] (Formation of primer layer) The obtained primer layer-forming composition was bar-coated onto a substrate so that the average dry film thickness was 1.0 μm, and dried for 3 minutes at 80° C. Thereafter, the formed layer of the primer layer-forming composition was irradiated with ultraviolet (UV) rays at an irradiation dose of 1000 mJ to form a primer layer with a thickness of 0.8 μm.

[0072] (Preparation of composition for forming a plated layer precursor layer) The following components were mixed to obtain a composition for forming a plateable layer precursor layer. IPA (isopropyl alcohol) 38.00 parts by mass Polybutadiene maleic acid 4.00 parts by mass FOM-03008 (Fujifilm Wako Pure Chemical Industries, Ltd.) 1.00 parts by mass IRGACURE OXE02 (BASF, ClogP=6.55) 0.05 parts by mass FOM-03008 contains the compound represented by the following chemical formula as its main component. [ka]

[0073] (Preparation of a substrate with a plating layer precursor layer) The obtained composition for forming a plateable layer precursor layer was bar-coated onto the primer layer to a film thickness of 0.2 μm and dried for 1 minute in an atmosphere at 120° C. Immediately thereafter, a polypropylene film having a thickness of 12.0 μm was laminated onto the composition for forming a plateable layer precursor layer to produce a substrate with a plateable layer precursor layer.

[0074] (Preparation of substrate with plating layer) A quartz glass photomask was prepared, having a width of 110.804 mm in the first direction D1, a width of 100.804 mm in the second direction D2, and a thickness of 6.00 mm, and on which exposure patterns corresponding to the conductive mesh M1, the pair of electrode pads 14, and the plurality of non-conductive portions 16 shown in Fig. 2 were formed. In this photomask, the exposure patterns corresponding to the plurality of non-conductive portions 16 are arranged so that the direction in which a line segment F1 connecting the connection points C1 of two of the plurality of non-conductive portions 16 that are closest to each other extends is different from the direction in which each of the four units U1 of the non-conductive portion 16 extends.

[0075] The line width of the exposure pattern corresponding to the conductive wiring 15 was 4 μm, and the interval between the exposure patterns corresponding to adjacent conductive wirings 15 was 150 μm. The width of the exposure pattern corresponding to the width L2 of the unit U1 was 120 μm, and the width of the exposure pattern corresponding to the width L3 of the non-conductive portion 16 was 1330 μm. In the exposure pattern, the distance between the connection points C1 of two adjacent non-conductive portions 16 in the first direction D1 or the second direction D2, i.e., the distance corresponding to the pitch Q1 and the pitch Q2, was 2100 μm.

[0076] The photomask has an exposure pattern formed so that 48 square regions, each having four connecting points C1 at its vertices and surrounding one non-conductive portion 16 in the center, are arranged in the first direction D1 and the second direction D2. 2+(48-1) 2 An exposure pattern corresponding to 4513 non-conductive portions 16 is formed.

[0077] This photomask is applied to the substrate with the plating layer precursor layer through a film mask, and ultraviolet light (energy amount 200 mJ / cm 2 The substrate with the plated layer precursor layer after being irradiated with ultraviolet light was then developed with a pure water shower for 5 minutes to produce a substrate with a plated layer.

[0078] (Conductive film formation) The substrate with the plated layer was immersed in a 1% by mass aqueous solution of sodium bicarbonate at 35°C for 5 minutes. Next, the substrate with the plated layer was immersed in a palladium catalyst solution, RONAMERSE SMT (manufactured by Rohm and Haas Electronic Materials Co., Ltd.), at 55°C for 5 minutes. After rinsing the substrate with the plated layer with water, it was subsequently immersed in CIRCUPOSIT 6540 (manufactured by Rohm and Haas Electronic Materials Co., Ltd.) at 35°C for 5 minutes, and then rinsed again with water. The substrate with the plated layer was then immersed in CIRCUPOSIT 4500 (manufactured by Rohm and Haas Electronic Materials Co., Ltd.) at 45°C for 20 minutes, followed by rinsing with water to form a conductive film on the plated layer. This resulted in the current-carrying member of Example 1, which had a copper conductive film on the substrate, including a pair of electrode pads 14, multiple conductive wirings 15, and multiple non-conductive portions 16, as shown in FIG. 2 .

[0079] In the current-carrying member of Example 1, the distance between the two closest non-conductive portions was 504 μm, and the distance between the connecting points of those two non-conductive portions was 1485 μm, so the distance between the two closest non-conductive portions was approximately 34% of the distance between the connecting points of those two non-conductive portions.

[0080] <Example 2> The conductive member of Example 2 was produced in the same manner as Example 1, except that instead of using a photomask having an exposure pattern corresponding to the non-conductive portion 16 shown in Figure 4 formed thereon, a photomask having an exposure pattern corresponding to the non-conductive portion 56 including a plurality of dummy wirings 59, as shown in Figure 9, was used as the photomask used in the process of producing the substrate with the plated layer of Example 1.

[0081] In this photomask, the line width of the exposure pattern corresponding to the conductive wiring 15 was 4 μm, and the interval between the exposure patterns corresponding to adjacent conductive wirings 15 was 150 μm. The width of the exposure pattern corresponding to the width L2 of the unit U5 was 150 μm, and the width of the exposure pattern corresponding to the width L3 of the non-conductive portion 56 was 1350 μm. In the exposure pattern, the distance corresponding to the distance between the connection points C5 of two adjacent non-conductive portions 56 in the first direction D1 or the second direction D2 was 2100 μm.

[0082] In the current-carrying member of Example 2, the distance between the two closest non-conductive portions was 424 μm, and the distance between the connecting points of those two non-conductive portions was 1485 μm, so the distance between the two closest non-conductive portions was about 29% of the distance between the connecting points of those two non-conductive portions.

[0083] Example 3 An electric-conductive member of Example 3 was produced in the same manner as in Example 1, except that, instead of using a photomask on which an exposure pattern corresponding to a plurality of conductive wirings 15 extending along the first direction D1 and the second direction D2 and non-conductive portions 16 as shown in Fig. 2 was formed, a photomask on which an exposure pattern as shown in Fig. 11 in which the plurality of conductive wirings 15 and the plurality of non-conductive portions 16 were rotated 45° was used as the photomask used in the process of producing the plated layer-provided substrate of Example 1. In the electric-conductive member of Example 3, as shown in Fig. 11, the direction in which line segment F2 connecting connection points C6 of two closest non-conductive portions 66 among the plurality of non-conductive portions 66 extends is different from the direction in which each of the plurality of unit units U6 extends, but there was a portion on the path connecting a pair of electrode pads 14 in a straight line along the surface of the conductive film 13 where no non-conductive portion 66 was arranged.

[0084] Example 4 The conductive member of Example 4, which has a silver conductive film having a pair of electrode pads 14, a plurality of conductive wirings 15, and a plurality of non-conductive portions 16 as shown in FIG. 2, was obtained by a silver salt method including the steps of preparing a silver halide emulsion, preparing a composition for forming a photosensitive layer, forming a photosensitive layer, exposure and development processing, heat treatment, gelatin decomposition processing, and polymer crosslinking processing, as shown below.

[0085] (Preparation of Silver Halide Emulsion) To Solution 1 (shown below), maintained at 38°C and pH 4.5, 90% of each of Solutions 2 and 3 (shown below) were added simultaneously over 20 minutes with stirring to form 0.16 μm core particles. Solutions 4 and 5 (shown below) were then added over 8 minutes, followed by the addition of the remaining 10% of Solutions 2 and 3 over 2 minutes, allowing the particles to grow to 0.21 μm. 0.15 g of potassium iodide was then added, and the mixture was ripened for 5 minutes to complete the particle formation.

[0086] 1 liquid: 750ml water 8.6g gelatin Sodium chloride 3g 1,3-dimethylimidazolidine-2-thione 20mg Sodium benzenethiosulfonate 10mg Citric acid 0.7g 2 liquid: 300ml water Silver nitrate 150g 3 liquid: 300ml water 38g sodium chloride 32g potassium bromide Potassium hexachloroiridate(III) (0.005%KCl 20% aqueous solution) 5ml Ammonium hexachlororhodate (0.001%NaCl 20% aqueous solution) 7ml 4 liquid: 100ml water Silver nitrate 50g 5 liquid: 100ml water Sodium chloride 13g Potassium bromide 11g Yellow prussic acid 5mg

[0087] The mixture was then washed using the usual flocculation method. Specifically, the temperature was lowered to 35°C, and the pH was lowered using sulfuric acid until the silver halide precipitated (pH was in the range of 3.6±0.2). Next, approximately 3 liters of the supernatant was removed (first washing). Another 3 liters of distilled water was added, and then sulfuric acid was added until the silver halide precipitated. Another 3 liters of the supernatant was removed (second washing). The same procedure as the second washing was repeated once more (third washing), completing the washing and desalting process. After washing and desalting, the emulsion was adjusted to pH 6.4 and pAg 7.5, and then chemically sensitized at 55°C to obtain the optimum sensitivity with the addition of 2.5 g of gelatin, 10 mg of sodium benzenethiosulfonate, 3 mg of sodium benzenethiosulfinate, 15 mg of sodium thiosulfate, and 10 mg of chloroauric acid. 100 mg of 1,3,3a,7-tetraazaindene as a stabilizer and 100 mg of Proxel (trade name, manufactured by ICI Co., Ltd.) as a preservative were added. The final emulsion was a silver iodochlorobromide cubic grain emulsion containing 0.08 mol% silver iodide and a silver chlorobromide ratio of 70 mol% silver chloride and 30 mol% silver bromide, with an average grain size of 0.22 μm and a coefficient of variation of 9%.

[0088] (Preparation of composition for forming photosensitive layer) The above emulsion was treated with 1.2 × 10 -4 mol / mol Ag, hydroquinone 1.2 x 10 -2 mol / mol Ag, citric acid 3.0 x 10 -4 The coating solution contained 0.90 g / mol Ag of 2,4-dichloro-6-hydroxy-1,3,5-triazine sodium salt and a trace amount of hardener, and the pH of the coating solution was adjusted to 5.6 using citric acid. To the above-mentioned coating solution, a polymer latex containing a polymer represented by the following formula (P-1) and a dispersant consisting of dialkylphenyl PEO sulfate (dispersant / polymer mass ratio: 2.0 / 100=0.02) was added so that the polymer / gelatin (mass ratio) became 0.5 / 1 relative to the gelatin contained therein. Furthermore, EPOXY RESIN DY 022 (trade name: manufactured by Nagase ChemteX Corporation) was added as a crosslinking agent. The amount of the crosslinking agent added was determined so that the amount of the crosslinking agent in the silver halide-containing photosensitive layer described below was 0.09 g / m 2 It was adjusted so that In this manner, a composition for forming a photosensitive layer was prepared. The polymer represented by the following formula (P-1) was synthesized with reference to Japanese Patent Nos. 3305459 and 3754745.

[0089] [ka]

[0090] (Formation of photosensitive layer) The above-mentioned polymer latex was applied to the insulating substrate in Example 1 to provide an undercoat layer with a thickness of 0.05 μm. Next, a silver halide-free layer-forming composition, which was a mixture of the above-mentioned polymer latex and gelatin, was applied onto the undercoat layer to form a silver halide-free layer having a thickness of 1.0 μm. The mixture mass ratio of the polymer to the gelatin (polymer / gelatin) was 2:1, and the polymer content was 0.65 g / m. 2 It was. Next, the above-mentioned photosensitive layer-forming composition was applied onto the silver halide-free layer to form a 2.5 μm-thick silver halide-containing photosensitive layer. The mixture mass ratio of polymer to gelatin in the silver halide-containing photosensitive layer (polymer / gelatin) was 0.5:1, and the polymer content was 0.22 g / m 2 It was. Next, a protective layer of 0.15 μm in thickness was formed on the silver halide-containing photosensitive layer by coating the protective layer-forming composition prepared by mixing the above-mentioned polymer latex and gelatin. The mixed mass ratio of the polymer to the gelatin (polymer / gelatin) was 0.1:1, and the polymer content was 0.015 g / m. 2 It was.

[0091] (Exposure processing and development processing) The photosensitive layer formed on the insulating substrate was exposed to parallel light emitted from a high-pressure mercury lamp as a light source through the photomask of Example 1. After exposure, the layer was developed with the following developer, and further developed with a fixer (product name: N3X-R for CN16X: manufactured by Fujifilm Corporation), rinsed with pure water, and then dried.

[0092] Developer composition: The following compounds are contained in 1 liter (L) of developer: Hydroquinone 0.037 mol / L N-methylaminophenol 0.016 mol / L Sodium metaborate 0.140 mol / L Sodium hydroxide 0.360 mol / L Sodium bromide 0.031 mol / L Potassium metabisulfite 0.187 mol / L

[0093] (heat treatment) Furthermore, the dried insulating substrate was placed in a superheated steam bath at 120° C. for 130 seconds for heat treatment.

[0094] (Gelatin decomposition treatment) The heat-treated insulating substrate was then immersed for 120 seconds in a gelatin decomposition solution (40°C) prepared as follows, and then washed by immersion in warm water (liquid temperature: 50°C) for 120 seconds. The gelatin decomposition solution was prepared by adding triethanolamine and sulfuric acid to an aqueous solution of protease (Biophrase 30L, manufactured by Nagase ChemteX Corporation) (protease concentration: 0.5% by mass) to adjust the pH to 8.5.

[0095] (polymer cross-linking treatment) The conductive member was then immersed in a 1% aqueous solution of Carbodilite V-02-L2 (trade name: manufactured by Nisshinbo) for 30 seconds, removed from the aqueous solution, and immersed in pure water (room temperature) for 60 seconds for washing.

[0096] <Example 5> Using a silver nanowire method comprising the steps of preparing a silver nanowire dispersion, preparing an adhesive solution, producing a non-patterned silver nanowire conductive substrate, and producing a patterned silver nanowire conductive substrate, a conductive member of Example 5 was obtained, which had a silver conductive film having a pair of electrode pads 14, multiple conductive wirings 15, and multiple non-conductive portions 16, as shown in Figure 2. The conductive wirings 15 had a line width of 30 µm.

[0097] (Preparation of silver nanowire dispersion) The following additive solutions A, B, C, and D were prepared in advance. <Additive liquid A> 60 mg of stearyltrimethylammonium chloride, 6.0 g of a 10% aqueous solution of stearyltrimethylammonium hydroxide, and 2.0 g of glucose were dissolved in 120.0 g of distilled water to prepare reaction solution A-1. Separately, 72 mg of silver nitrate powder was dissolved in 2.0 g of distilled water to prepare aqueous silver nitrate solution A-2. Furthermore, while the reaction solution A-1 was kept at 25°C and vigorously stirred, the aqueous silver nitrate solution A-2 was added to the reaction solution A-1. After the addition of the aqueous silver nitrate solution A-2, the reaction solution A-1 was vigorously stirred for 180 minutes to obtain an added solution A.

[0098] <Additive liquid B> Additive solution B was obtained by dissolving 42.0 g of silver nitrate powder in 958 g of distilled water. <Additive liquid C> Additive solution C was obtained by mixing 75 g of 25% aqueous ammonia with 925 g of distilled water. <Additive liquid D> Additive solution D was obtained by dissolving 400 g of polyvinylpyrrolidone (K30) in 1.6 kg of distilled water.

[0099] Next, a silver nanowire dispersion was prepared as follows. First, 1.30 g of stearyltrimethylammonium bromide powder, 33.1 g of sodium bromide powder, 1,000 g of glucose powder, and 115.0 g of nitric acid (1N) were dissolved in 12.7 kg of distilled water at 80°C. This solution was maintained at 80°C and stirred at 500 rpm. Additive Solution A was added at a rate of 250 cc / min, Additive Solution B at 500 cc / min, and Additive Solution C at 500 cc / min. The solution containing Additive Solutions A, B, and C was heated and stirred for 100 minutes at a stirring speed of 200 rpm while maintaining the temperature at 80°C. The solution was then cooled to 25°C. The stirring speed was then changed to 500 rpm, and Additive Solution D was added to the solution at 500 cc / min. The solution to which Additive Solution D had been added was designated as Preparation Solution E1.

[0100] Next, while vigorously stirring the 1-propanol, the feed liquid E1 was added all at once so that the volume ratio of 1-propanol to feed liquid E1 was 1: 1. The liquid obtained by adding feed liquid E1 to 1-propanol in this way was stirred for 3 minutes to obtain feed liquid E2.

[0101] Furthermore, ultrafiltration of feed solution E2 was carried out using an ultrafiltration module with a molecular weight cutoff of 150,000 as follows: After concentrating the resulting feed solution E2 four-fold, a mixed solution of distilled water and 1-propanol (volume ratio 1:1) was added to the four-fold concentrated feed solution E2, and this was concentrated again, repeatedly until the conductivity of the filtrate finally reached 50 μS / cm or less, yielding a silver nanowire dispersion with a metal content of 0.45%.

[0102] (Preparation of adhesive solution) An adhesive solution was prepared according to the following formulation: <Adhesive solution> Tetraethoxysilane (KBE-04, manufactured by Shin-Etsu Chemical Co., Ltd.) 5.0 parts by mass 3-Glycidoxypropyltrimethoxysilane (KBM-403, manufactured by Shin-Etsu Chemical Co., Ltd.) 3.2 parts by mass 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane (KBM-303, manufactured by Shin-Etsu Chemical Co., Ltd.) 1.8 parts by mass Acetic acid aqueous solution (acetic acid concentration = 0.05%, pH = 5.2) 10.0 parts by mass Hardener (boric acid, manufactured by Wako Pure Chemical Industries, Ltd.) 0.8 parts by mass Colloidal Silica (Snowtex O, average particle size 10 nm to 20 nm, solid content 20%, pH = 2.6, manufactured by Nissan Chemical Industries, Ltd.) 60.0 parts by mass surfactants (Narrow Acty HN-100, manufactured by Sanyo Chemical Industries, Ltd.) 0.2 parts by mass

[0103] The adhesive solution was prepared in the following manner. First, while vigorously stirring an aqueous solution of acetic acid, 3-glycidoxypropyltrimethoxysilane was added dropwise over 3 minutes to obtain aqueous solution 1. Next, while vigorously stirring aqueous solution 1, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane was added over 3 minutes to obtain aqueous solution 2. Next, while vigorously stirring aqueous solution 2, tetraethoxysilane was added over 5 minutes, and stirring was continued for 2 hours to obtain aqueous solution 3. Next, colloidal silica, a curing agent, and a surfactant were added sequentially to aqueous solution 3 to prepare an adhesive solution.

[0104] (Fabrication of Unpatterned Silver Nanowire Conductive Substrates) The surface of a polycarbonate substrate (polycarbonate resin film (Teijin Panlite PC-2151) 250 μm thick) was subjected to corona discharge treatment, and then a 0.02% aqueous solution of N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane was applied to the surface at a rate of 8.8 mg / m using the bar coating method. 2 The coating was then dried at 100° C. for 1 minute to obtain a surface-treated polycarbonate substrate.

[0105] Furthermore, after subjecting the surface of the surface-treated polycarbonate substrate to a corona discharge treatment, the above adhesive solution was applied to the surface using a bar coating method, and the surface was dried by heating at 170°C for 1 minute to form an adhesive layer with a thickness of 0.5 μm, thereby obtaining a polycarbonate substrate with an adhesive layer.

[0106] A solution of an alkoxide compound having the following composition was stirred at 60°C for 1 hour, and after confirming that it was homogeneous, a sol-gel solution was obtained. 2.24 parts by mass of the resulting sol-gel solution and 17.76 parts by mass of the silver nanowire dispersion obtained in the silver nanowire dispersion preparation step were mixed, and the mixture was further diluted with distilled water and 1-propanol to obtain a liquid composition (sol-gel coating liquid). The solvent ratio of the resulting liquid composition was distilled water:1-propanol = 60:40.

[0107] <Alkoxide compound solution> Tetraethoxysilane (KBE-04, manufactured by Shin-Etsu Chemical Co., Ltd.) 5.0 parts by mass 1% acetic acid aqueous solution 11.0 parts by mass Distilled water 4.0 parts by mass

[0108] The surface of the adhesive layer of the polycarbonate substrate with the adhesive layer was subjected to corona discharge treatment, and the surface was coated with a silver film having a silver content of 0.015 g / m by bar coating. 2 , total solids coating weight 0.120 g / m 2 The liquid composition (sol-gel coating solution) was applied so that the conductive layer was formed by heating at 100°C for 1 minute to induce a sol-gel reaction. In this way, an unpatterned silver nanowire conductive substrate was obtained. The mass ratio of tetraethoxysilane (alkoxide compound) to silver nanowires in the conductive layer was 7:1.

[0109] (Fabrication of Patterned Silver Nanowire Conductive Substrates) A patterning treatment was carried out by applying a dissolving solution (etching solution) in a pattern to the non-patterned silver nanowire conductive substrate obtained above using a screen printing method.

[0110] For screen printing, a WHT-3 model manufactured by Mino Group and a No. 4 yellow squeegee were used. The silver nanowire etching solution for forming the pattern was prepared by mixing CP-48S-A liquid, CP-48S-B liquid (both manufactured by Fujifilm Corporation) and pure water in a ratio of 1:1:1, and thickening with hydroxyethyl cellulose, and this was used as the ink for screen printing. The pattern used for screen printing was the same as the exposure pattern of the photomask used in Example 1, with the line width of the portion corresponding to the conductive wiring 15 being 30 μm. The etching solution was applied to a non-patterned silver nanowire conductive substrate at a coating amount of 0.01 g / cm. 2 After leaving it at 25°C for 2 minutes, it was washed with pure water to perform a patterning treatment.

[0111] By carrying out the above patterning process, a patterned silver nanowire conductive substrate including a conductive layer having conductive regions and non-conductive regions was obtained. This patterned silver nanowire conductive substrate is the current-carrying member of Example 5.

[0112] Example 6 The conductive member of Example 6 was prepared in the same manner as Example 1, except for the steps of forming the primer layer, preparing the composition for forming the plateable layer precursor layer, and producing the substrate with the plateable layer precursor layer, as shown below. (Formation of primer layer) First, the following components were mixed to obtain a composition for forming a primer layer. Copolymer A 25.0 parts by mass MFG (1-methoxy-2-propanol) 74.8 parts by mass Omnirad184 (manufactured by IGM Resins BV) 0.2 parts by mass Omnirad184 contains the compound represented by the following chemical formula as its main component. [ka]

[0113] Here, copolymer A is a copolymer in which the polyol component ratio is doubled in commercially available 8UX-196A manufactured by Taisei Fine Chemical Co., Ltd., and the weight average molecular weight is set to 40,000.

[0114] The obtained primer layer-forming composition was bar-coated onto a substrate so that the average dry film thickness was 1.6 μm, and dried for 10 minutes at 100° C. Thereafter, the formed layer of the primer layer-forming composition was irradiated with ultraviolet (UV) rays at an irradiation dose of 500 mJ to form a primer layer with a thickness of 1.5 μm.

[0115] (Preparation of composition for forming a plated layer precursor layer) Next, a composition for forming a plateable layer precursor layer was prepared by mixing the following components to obtain a composition for forming a plateable layer precursor layer. IPA (isopropyl alcohol) 38.00 parts by mass Polybutadiene maleic acid 4.00 parts by mass FOM-03008 (Fujifilm Wako Pure Chemical Industries, Ltd.) 1.00 parts by mass IRGACURE OXE02 (BASF, ClogP=6.55) 0.10 parts by mass FOM-03008 contains the compound represented by the following chemical formula as its main component. [ka]

[0116] (Step of producing a substrate with a plating layer precursor layer) The obtained composition for forming a plateable layer precursor layer was bar-coated onto the primer layer to a film thickness of 0.4 μm and dried for 1 minute in an atmosphere at 120° C. Immediately thereafter, a polypropylene film having a thickness of 12.0 μm was laminated onto the composition for forming a plateable layer precursor layer to produce a substrate with a plateable layer precursor layer. The subsequent steps were carried out in the same manner as in Example 1, and a conductive member of Example 6 was produced.

[0117] <Comparative Example 1> The photomask used in the process of producing the substrate with a plated layer in Example 1 was, instead of a photomask having an exposure pattern corresponding to a plurality of non-conductive portions 16 arranged as shown in Figure 2, a photomask having an exposure pattern in which a plurality of non-conductive portions 76 were arranged in a square lattice pattern at regular intervals in the first direction D1 and the second direction D2, as shown in Figure 12, as disclosed in ``Transmission properties of metal mesh filters at 90 GHz'' by Vyachesla V. Komarov and Valery P. Meschanov, Journal of Computational Electronics, February 28, 2019, 18:696-704'', was used.The conductive member of Comparative Example 1 was produced in the same manner as Example 1, except that

[0118] In the photomask used in Comparative Example 1, the two non-conductive portions 76 arranged adjacent to each other in the first direction D1 and the two non-conductive portions 76 arranged adjacent to each other in the second direction D2 are the two non-conductive portions 76 that are closest to each other among the multiple non-conductive portions 76. In addition, in this photomask, the exposure patterns corresponding to the multiple non-conductive portions 26 are arranged so that the direction in which the line segment connecting the connection points C7 of these two closest non-conductive portions 76 extends, i.e., the first direction D1 and the second direction D2, are the same as the direction in which the four units U7 of the non-conductive portion 26 extend.

[0119] In this photomask, the line width of the exposure pattern corresponding to the conductive wiring 25 was 4 μm, and the interval between the exposure patterns corresponding to adjacent conductive wirings 25 was 150 μm. The width of the exposure pattern corresponding to the width L2 of the unit U2 was 120 μm, and the width of the exposure pattern corresponding to the width L3 of the non-conductive portion 56 was 1290 μm. In the exposure pattern, the distance between the connection points C2 of two adjacent non-conductive portions 56 in the first direction D1 or the second direction D2, i.e., the distance corresponding to the pitch P3, was 1500 μm.

[0120] Furthermore, this photomask has an exposure pattern formed such that 66 regions each including one non-conductive portion 16 in the center and having a width of 1500 μm in the first direction D1 and the second direction D2 are arranged in each of the first direction D1 and the second direction D2. Therefore, the photomask has exposure patterns formed thereon that correspond to 66×66=4356 non-conductive portions 26.

[0121] <Comparative Example 2> The conductive member of Comparative Example 2 was prepared in the same manner as Example 1, except that the photomask used in the process of preparing the substrate with the plated layer of Example 1 did not have an exposure pattern corresponding to the non-conductive portion, but instead had only an exposure pattern corresponding to the conductive mesh M1 and a pair of electrode pads 14 shown in Figure 2.

[0122] The current-carrying members of Examples 1 to 6 and Comparative Examples 1 and 2 obtained as described above were evaluated as follows. (Deterioration assessment) First, conductive tape was applied to each of the pair of electrode pads of the current-carrying member, and the resistance value R1 between the conductive tapes was measured. Next, the current-carrying member was fixed so that the conductive film was perpendicular to the horizontal plane. At this time, no obstacles were placed within 150 mm of either side of the conductive film. Next, alligator clips connected to a power supply (Kikusui Electronics DME1600; digital multimeter) were attached to each of the conductive tapes attached to the pair of electrode pads. In advance, two pieces of conductive tape were attached to the same electrode pad so that they did not touch each other, and the resistance between them was measured to measure the contact resistance through the electrode pads. The contact resistance was confirmed to be less than 0.05 Ω, which is sufficiently negligible compared to the resistance value R1.

[0123] The current-carrying member was then placed in a thermostatic chamber set at a temperature of 25°C, a relative humidity of 60%, and no wind. A voltage was applied to the conductive film for 2000 hours using a power supply to maintain the temperature of the conductive film at 100°C. The temperature of the conductive film was measured using a thermometer (FLIR ETS320). After 2000 hours of applying the voltage to the conductive film, the resistance R2 between each conductive tape attached to the pair of electrode pads was measured, and the degradation coefficient R2 / R1 was calculated as the ratio of the resistance R2 to the resistance R1. Current-carrying members with a calculated degradation coefficient R2 / R1 of 1.2 or less were assigned a rating of A, indicating that degradation was sufficiently suppressed. Current-carrying members with a degradation coefficient R2 / R1 greater than 1.2 were assigned a rating of B, indicating that significant degradation had occurred.

[0124] (Millimeter wave transmission evaluation) The transmittance of a millimeter wave of a specific wavelength was measured for the current-carrying member using a millimeter-wave network analyzer (Keysight Technologies, Inc., Millimeter Wave Network Analyzers N5290A). First, the current-carrying member was attached to a 2 mm thick stainless steel plate with an 80 mm diameter hole. The two ports of the millimeter-wave network analyzer were placed facing each other. The current-carrying member attached to the stainless steel plate was positioned so that the 80 mm diameter hole in the stainless steel plate was located at the midpoint between the two ports, and so that the surface of the flat current-carrying member was perpendicular to the line connecting the two ports. In this state, the transmittance of a 76.5 GHz millimeter wave for the current-carrying member was measured. The transmittance measured without a current-carrying member between the two ports was set to 0 dB, and the transmittance of the current-carrying member was calculated. A rating of A was assigned when the measured transmittance was -1.0 dB or greater, and a rating of B was assigned when the transmittance was less than -1.0 dB.

[0125] (Temperature uniformity evaluation) As in the degradation test, conductive tape was applied to each of the pair of electrode pads of the current-carrying member, and the current-carrying member was fixed so that the conductive film was perpendicular to the horizontal plane. The current-carrying member was then placed in a thermostatic chamber set to a temperature of 10°C, a relative humidity of 60%, and no wind. While measuring the conductive film of the current-carrying member with a thermometer, a voltage was applied to the conductive film using a power supply device so that the temperature of the conductive film reached 35°C. Furthermore, the same thermometer was used to measure the temperature distribution in a 50 mm x 50 mm area at the center of the conductive film. Current-carrying members for which the difference between the measured maximum and minimum temperatures was less than 3°C were given a grade of A, indicating a uniform temperature distribution. Current-carrying members for which the difference between the measured maximum and minimum temperatures was 3°C or greater were given a grade of B, indicating a non-uniform temperature distribution.

[0126] (Visibility evaluation) Ten observers were positioned 1 m away from the conductive member, and while holding the conductive member up to a fluorescent lamp, each observer visually inspected the conductive member and evaluated whether the non-conductive portion was visible. If fewer than five of the ten observers judged that they could see the non-conductive portion, the conductive member was given a rating of A, and if five or more of the ten observers judged that they could see the non-conductive portion, the conductive member was given a rating of B.

[0127] Table 1 below shows the results of the degradation evaluation and millimeter wave transmission evaluation for Examples 1 to 6, Comparative Example 1 and Comparative Example 2. [Table 1]

[0128] As shown in Table 1, the conductive members of Examples 1 to 6 were rated A in both the deterioration evaluation and millimeter wave transmittance evaluation, indicating that while they have the function of transmitting millimeter waves, deterioration of the conductive wiring is unlikely to occur even when current is passed through the conductive film. In the conductive members of Examples 1 to 6, the multiple non-conductive parts are formed so that the direction in which the line segment connecting the connection points of two of the multiple non-conductive parts that are closest to each other extends is different from the direction in which each of the multiple unit parts of the non-conductive parts extends.As a result, the distance between the non-conductive parts is relatively wide and no points occur where the current density increases suddenly, which is thought to have suppressed oxidation of the conductive wiring due to excessive heat generation and also suppressed deterioration of the conductive wiring.

[0129] In contrast, the current-carrying member of Comparative Example 1 was rated as B in the deterioration evaluation, which indicates that the conductive wiring is prone to deterioration when a current is passed through the conductive film. In the conductive member of Comparative Example 1, the multiple non-conductive parts are formed so that the direction in which the line segment connecting the connection points of two of the multiple non-conductive parts that are closest to each other extends is the same as the direction in which each of the multiple unit parts of the non-conductive parts extends.As a result, the distance between the non-conductive parts is relatively narrow, and there are locations where the current density increases suddenly, which causes excessive heat to be generated locally, resulting in oxidation of the conductive wiring, etc., and making the conductive wiring more susceptible to deterioration.

[0130] Furthermore, the millimeter wave transmission evaluation of the current-carrying member of Comparative Example 2 was B, indicating that it does not have the function of transmitting millimeter waves. This is thought to be due to the fact that the current-carrying member of Comparative Example 2 does not have a non-conductive portion.

[0131] Next, the results of the temperature uniformity evaluation for Examples 1 to 6 are shown in Table 2 below. [Table 2]

[0132] Furthermore, the current-carrying members of Examples 1, 2, and 4 to 6 were evaluated as A in terms of temperature uniformity, while the current-carrying member of Example 3 was evaluated as B in terms of temperature uniformity.

[0133] In the current-carrying members of Examples 1, 2, and 4 to 6, non-conductive portions are arranged on any path in the conductive film that linearly connects a pair of electrode pads along the first direction D1, so it is believed that the current flowing from one electrode pad to the other electrode pad uniformly bypasses the multiple non-conductive portions, making it less likely that a local temperature rise will occur.

[0134] In the conductive member of Example 3, a path that linearly connects a pair of electrode pads along the first direction D1 exists between two non-conductive portions in the conductive film, which is likely to result in areas where the current density locally increases and areas where the current density locally decreases, making the temperature distribution of the conductive film likely to be uneven.

[0135] Next, the results of the visibility evaluation for Examples 1 to 6 are shown in Table 3 below. [Table 3]

[0136] The current-carrying member of Example 2 was evaluated as A in visibility, and the current-carrying members of Examples 1 and 3 to 6 were evaluated as B in visibility. In the current-carrying member of Example 2, a plurality of dummy wirings are arranged inside the non-conductive portion, so it is thought that the presence of the non-conductive portion is less noticeable. Furthermore, in the current-carrying members of Examples 1 and 3 to 6, the dummy wiring was not formed, which is thought to have made the presence of the non-conductive portion relatively more noticeable.

[0137] The present invention is basically configured as described above. While the current-carrying member of the present invention has been described in detail above, the present invention is not limited to the above-described embodiment, and various improvements and modifications may be made without departing from the spirit and scope of the present invention. [Explanation of symbols]

[0138] 11,61 Conductive member, 12 Substrate, 13,23 Conductive film, 14,24 Electrode pad, 15 Conductive wiring, 16,36,46,56,66,76 Non-conductive portion, 17 Opening, 18,38,58 Edge, 59 Dummy wiring, A1 Path, C1,C2,C3,C4,C5,C6,C7 Connection point, CL Center line, D1 First direction, D2 Second direction, E,P1,P2,Q1,Q2 Pitch, F1,F2 Line segment, G Gap, K1,K2,K3,K6 Distance, L1,L2,L3,W Width, M1,M3,M6 Conductive mesh, T Line width, U1,U3,U4,U5,U6,U7 Unit.

Claims

1. A current-carrying member having a conductive film formed thereon, a plurality of conductive wires forming a mesh shape; the conductive film is formed by the plurality of conductive wirings, an electrode pad for applying a voltage to the conductive film; a plurality of non-conductive portions are formed in the conductive film, the non-conductive portions being arranged to form a regular repeating pattern; each of the plurality of non-conductive portions includes a plurality of elongated units connected to each other at connection points and extending in different directions from the connection points; a direction in which a line segment connecting the connection points of two of the non-conductive portions that are closest to each other among the plurality of non-conductive portions extends is different from a direction in which each of the plurality of units extends; The non-conductive portion includes a plurality of dummy wirings arranged on extensions of the plurality of conductive wirings and electrically insulated from the plurality of conductive wirings. Current-carrying material.

2. a pair of the electrode pads are connected to both ends of the conductive film; 2. The current-carrying member according to claim 1, wherein the non-conductive portion is disposed on any path connecting the pair of electrode pads along the surface of the conductive film.

3. The conductive film extends in a plane, 3. The current-carrying member according to claim 2, wherein the non-conductive portion is disposed on any path that linearly connects the pair of electrode pads along the surface of the conductive film.

4. the non-conductive portion is composed of four of the unit elements, 4. The current-carrying member according to claim 1, wherein the four units are connected to each other at the connection points so as to form a cross shape.

5. 5. The conductive member according to claim 4, wherein the distance between the two closest non-conductive portions among the plurality of non-conductive portions is 20% or more and 50% or less of the distance between the connection points of the two non-conductive portions.

6. 6. The conductive member according to claim 5, wherein the distance between the two closest non-conductive portions among the plurality of non-conductive portions is 30% or more and 40% or less of the distance between the connection points of the two non-conductive portions.

7. 7. The current-carrying member according to claim 1, wherein the direction in which at least one of the units of the non-conductive portion extends is the same as the direction in which the plurality of conductive wires extend.

8. 7. The current-carrying member according to claim 1, wherein the direction in which the plurality of units of the non-conductive portion extend is different from the direction in which the plurality of conductive wires extend.

9. 9. The current-carrying member according to claim 1, wherein the electrode pad has a width that is at least 10 times larger than the line width of the conductive wiring.

10. The current-carrying member according to any one of claims 1 to 9, wherein the conductive film has a shape that conforms to a curved surface.

11. 11. The current-carrying member according to claim 1, wherein the conductive film has a sheet resistance of 0.1 Ω / □ or more and 10.0 Ω / □ or less.

12. The current-carrying member according to claim 11 , wherein the conductive film has a sheet resistance of 0.3Ω / □ or more and 3.0Ω / □ or less.

13. 13. The current-carrying member according to claim 1, wherein the unit has a width of 0.1 mm or more and 1000.0 mm or less along the direction in which the unit extends.

14. A heater comprising the current-carrying member according to any one of claims 1 to 13.

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