Toner for developing electrostatic images, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Abstract

To provide an electrostatic image developing toner which offers both releasability of fixed images and capability to prevent image density reduction when images are successively formed in a low-temperature, low-humidity environment.SOLUTION: An electrostatic image developing toner provided herein comprises toner particles containing a binder resin and a release agent and having an area fraction Sa / St of 2% or greater and an area fraction Sb / St of 20% or greater, where, in cross-sections of the toner particles, St represents area of the entire cross-sections of the toner particles, Sa represents total area of a cross-section of a domain with major axes in a range of 10-500 nm, inclusive, and Sb represents total area of a cross-section of a domain with major axes of 1500-3000 nm, inclusive, within a cross-section of a domain of the release agent.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a toner for developing an electrostatic image, an electrostatic image developer, a toner cartridge, a process cartridge, an image forming apparatus, and an image forming method. [Background technology]

[0002] Patent Document 1 discloses a toner for developing electrostatic images that contains at least a binder resin and a release agent, wherein the release agent is contained as domains having a diameter of 10 nm or more and 500 nm or less, and fibers are contained in the domains of the release agent. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Laid-Open No. 2011-197205 Summary of the Invention [Problem to be solved by the invention]

[0004] In image formation using a toner for developing an electrostatic image, for example, a toner image transferred to a recording medium is fixed to the recording medium by heating the toner image while the toner image is in contact with a fixing member. When a toner image is fixed to a recording medium while the toner image is in contact with the fixing member to form a fixed image, the fixed image is required to be easily peeled from the fixing member.

[0005] As a method for improving the releasability of the fixed image, for example, there is a method of using a toner for developing electrostatic images in which a release agent is dispersed in the toner particles so that the major axis of the domain of the release agent contained in the toner particles becomes small. However, when a toner for developing electrostatic images containing toner particles in which the major axis of the domain of the release agent is small is used and low-density images are continuously formed in a low-temperature, low-humidity environment (for example, an environment with a temperature of 10°C and a humidity of 15%), a decrease in image density may occur.

[0006] The object of the present invention is to provide a toner for developing electrostatic images which, compared to a toner having an area fraction Sa / St of less than 2%, an area fraction Sb / St of less than 20%, an Na of less than 15, or an Nb of less than 3, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. [Means for solving the problem]

[0007] The above problems can be solved by the following means.

[0008] <1> Toner particles containing a binder resin and a release agent, a toner for developing electrostatic images, the toner comprising toner particles having an area fraction Sa / St of 2% or more and an area fraction Sb / St of 20% or more, where St is the area of ​​the entire cross section of the toner particle, Sa is the total area of ​​the cross sections of domains of the release agent whose major axes are 10 nm or more and 500 nm or less, and Sb is the total area of ​​the cross sections of domains of the release agent whose major axes are 1500 nm or more and 3000 nm or less, respectively. <2> the ratio Sb / Sa of Sb to Sa is 1 or more and 20 or less; <1> 2. The toner for developing electrostatic images according to claim 1. <3> The area fraction Sa / St is 20% or less, and the area fraction Sb / St is 40% or less. <1> or <2> 2. The toner for developing electrostatic images according to claim 1.

[0009] <4> Toner particles containing a binder resin and a release agent, The toner for developing electrostatic images has toner particles in which Na is 15 or more and Nb is 3 or more, where Na is the number of cross sections of domains of the release agent in which the major axis is 10 nm or more and 500 nm or less, and Nb is the number of cross sections of domains of the release agent in which the major axis is 1500 nm or more and 3000 nm or less, in the cross section of one toner particle. <5> The ratio of Nb to Na, Nb / Na, is 0.05 or more and 0.30 or less. <4> 2. The toner for developing electrostatic images according to claim 1. <6> The Na is 45 or less and the Nb is 5 or less. <4> or <5> 2. The toner for developing electrostatic images according to claim 1.

[0010] <7> In the cross section of the toner particle, when the area of ​​the entire cross section of the toner particle is St and the total area of ​​the cross section of the domain of the release agent is Sw, the area fraction Sw / St is 30% or more and 50% or less. <1> ~ <6> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <8> the average circularity of the cross section of the domains having a major axis of 1500 nm or more and 3000 nm or less is 0.6 or more; <1> ~ <7> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <9> The melting temperature Tm of the release agent is 65°C or higher and 95°C or lower. <1> ~ <8> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <10> The release agent is an ester wax. <9> 2. The toner for developing electrostatic images according to claim 1.

[0011] <11> The binder resin contains a styrene (meth)acrylic resin. <1> ~ <10> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <12> the content of units derived from a monomer having a styrene skeleton relative to the entire toner particles is 25% by mass or more and 40% by mass or less; <11> 2. The toner for developing electrostatic images according to claim 1. <13> the difference (Tm-Tg) between the melting temperature (Tm) of the release agent and the glass transition temperature (Tg) of the binder resin is 15°C or more and 30°C or less; <1> ~ <12> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <14> the toner particles contain a cationic surfactant and an anionic surfactant; <1> ~ <13> 10. The toner for developing electrostatic images according to claim 9, wherein the toner is a toner for developing electrostatic images. <15> the cationic surfactant is a quaternary ammonium salt, and the anionic surfactant is a sulfonate; <14> 2. The toner for developing electrostatic images according to claim 1.

[0012] <16> <1> ~ <15> 10. An electrostatic image developer comprising the toner for developing electrostatic images according to any one of claims 1 to 9. <17> <1> ~ <15> The toner for developing electrostatic images according to any one of the above items is contained in the container. A toner cartridge that is detachably attached to an image forming device. <18> <16> and a developing means for developing an electrostatic image formed on the surface of an image carrier into a toner image by using the electrostatic image developer, A process cartridge is detachably mounted in an image forming apparatus. <19> an image carrier; a charging means for charging the surface of the image carrier; an electrostatic image forming means for forming an electrostatic image on the charged surface of the image carrier; <16> a developing means for developing the electrostatic image formed on the surface of the image carrier into a toner image by using the electrostatic image developer; a transfer means for transferring the toner image formed on the surface of the image carrier to the surface of a recording medium; a fixing means for fixing the toner image transferred onto the surface of the recording medium; An image forming apparatus comprising: <20> a charging step of charging the surface of the image carrier; an electrostatic image forming step of forming an electrostatic image on the charged surface of the image carrier; <16> a developing step of developing the electrostatic image formed on the surface of the image carrier as a toner image using the electrostatic image developer according to claim 1; a transfer step of transferring the toner image formed on the surface of the image carrier to the surface of a recording medium; a fixing step of fixing the toner image transferred onto the surface of the recording medium; An image forming method comprising the steps of: [Effects of the Invention]

[0013] <1> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the area fraction Sa / St is less than 2% or the area fraction Sb / St is less than 20%, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <2> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the ratio Sb / Sa is less than 1 or more than 20, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <3> According to the invention, there is provided a toner for developing electrostatic images, which suppresses a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the area fraction Sa / St is more than 20% or the area fraction Sb / St is more than 40%.

[0014] <4> According to the invention, there is provided a toner for developing electrostatic images which, compared to when Na is less than 15 or Nb is less than 3, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <5> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the ratio Nb / Na is less than 0.05 or more than 0.30, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <6> According to the present invention, there is provided a toner for developing electrostatic images that suppresses a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when Na is more than 45 or Nb is more than 5.

[0015] <7> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the area fraction Sw / St is less than 30% or more than 50%, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <8> According to the invention, there is provided a toner for developing electrostatic images, which suppresses a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the average circularity of the cross section of the domains having a major axis of 1500 nm or more and 3000 nm or less is less than 0.6. <9> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the melting temperature Tm of the release agent is less than 65°C or more than 90°C, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <10> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the release agent is a hydrocarbon wax, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment.

[0016] <11> According to the invention, there is provided a toner for developing electrostatic images, which, even when the binder resin contains a styrene (meth)acrylic resin, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the area fraction Sa / St is less than 2%, the area fraction Sb / St is less than 20%, the number of Na atoms is less than 15, or the number of Nb atoms is less than 3. <12> According to the invention, there is provided a toner for developing electrostatic images, which, even when the content of units derived from a monomer having a styrene skeleton relative to the entire toner particles is 25% by mass or more and 40% by mass or less, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the area fraction Sa / St is less than 2%, the area fraction Sb / St is less than 20%, the number of Na's is less than 15, or the number of Nb's is less than 3. <13> According to the invention, there is provided a toner for developing electrostatic images which, compared to when the difference Tm-Tg is less than 15°C or more than 30°C, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. <14> or <15> According to the invention, there is provided a toner for developing electrostatic images, which achieves both better releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the toner particles contain only either a cationic surfactant or an anionic surfactant.

[0017] <16> , <17> , <18> , <19> , or <20> According to the invention, there is provided an electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, or image forming method which, compared to the case where an electrostatic image developing toner having an area fraction Sa / St of less than 2%, an area fraction Sb / St of less than 20%, an Na of less than 15, or an Nb of less than 3, achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. [Brief explanation of the drawings]

[0018] [Figure 1] 1 is a schematic configuration diagram illustrating an example of an image forming apparatus according to an embodiment of the present invention. [Figure 2] 1 is a schematic diagram illustrating an example of a process cartridge that is detachably mounted to an image forming apparatus according to an exemplary embodiment of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0019] Hereinafter, an embodiment of the present invention will be described. These descriptions and examples are intended to illustrate the embodiment and are not intended to limit the scope of the invention. In the present specification, the upper or lower limit of one numerical range may be replaced with the upper or lower limit of another numerical range. In addition, in the present specification, the upper or lower limit of a numerical range may be replaced with a value shown in the examples. In this specification, (meth)acrylic means both acrylic and methacrylic, and in this specification, a (meth)acryloyl group means both an acryloyl group and a methacryloyl group.

[0020] In this specification, the term "process" includes not only an independent process but also a process that cannot be clearly distinguished from other processes, as long as the intended purpose of the process is achieved. Each component may contain multiple types of the corresponding substance. When referring to the amount of each component in a composition, if there are multiple substances corresponding to each component in the composition, the amount refers to the total amount of those multiple substances present in the composition, unless otherwise specified.

[0021] [Electrostatic image developing toner] <First form> A toner for developing electrostatic images (hereinafter also referred to as "toner") according to a first embodiment is a toner particle containing a binder resin and a release agent, and has an area fraction Sa / St of 2% or more and an area fraction Sb / St of 20% or more, where St is the area of ​​the entire cross section of the toner particle, Sa is the total area of ​​the cross sections of domains of the release agent whose major axes are 10 nm or more and 500 nm or less, and Sb is the total area of ​​the cross sections of domains whose major axes are 1500 nm or more and 3000 nm or less. The toner according to the first embodiment, having the above-mentioned constitution, achieves both good releasability of the fixed image and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. The reason for this is not clear, but is presumed to be as follows.

[0022] As described above, one method for improving the releasability of a fixed image is to use a toner for developing electrostatic images in which a release agent is dispersed in toner particles so that the major axis of the domain of the release agent contained in the toner particles is small. Hereinafter, the domain of the release agent will also be referred to as a "release agent domain," and the major axis of the release agent domain will also be referred to as a "release agent domain diameter." When the release agent domain diameter is small, the release agent domains in the toner particles tend to exude to the surfaces of the toner particles when heated during fixing, which is thought to improve the releasability of the fixed image.

[0023] However, when low-density images are continuously formed using a toner containing toner particles with a small release agent domain diameter, the toner is agitated in the toner storage unit of the developing device, which places a load on the toner and can cause cracking of the toner particles. In particular, when low-density images are continuously formed in a low-temperature, low-humidity environment, the susceptibility of the toner particles to cracking becomes significant. Since the toner in which cracks have occurred has low fluidity and therefore a low amount of triboelectric charge, when an image is formed using the toner in which cracks have occurred, the image density may decrease.

[0024] In contrast, in the first embodiment, the area fraction Sa / St in the toner particles is 2% or more, and the area fraction Sb / St is 20% or more. That is, in the first embodiment, the toner particles include both release agent domains having a release agent domain diameter of 10 nm or more and 500 nm or less (hereinafter also referred to as "small diameter domains") and release agent domains having a release agent domain diameter of 1500 nm or more and 3000 nm or less (hereinafter also referred to as "large diameter domains"). Large-diameter domains are less likely to seep onto the surface of toner particles during fixing than small-diameter domains, but are more flexible than binder resins and therefore more likely to act as buffers when toner particles collide with each other due to external loads. Therefore, in the toner according to the first embodiment, the small-diameter domains are more likely to seep onto the surface of toner particles during fixing, and the large-diameter domains act as buffers during agitation in the toner storage section of the developing unit, thereby suppressing cracking of toner particles. As a result, the first embodiment is expected to achieve both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment.

[0025] Note that toner particles obtained by a conventional technique for increasing the diameter of a release agent domain differ from the toner particles of the first embodiment in that at least the area fraction Sa / St is outside the above range. Also, toner particles obtained by a conventional technique for decreasing the diameter of a release agent domain differ from the toner particles of the first embodiment in that at least the area fraction Sb / St is outside the above range.

[0026] <Second form> The toner according to the second embodiment is a toner particle containing a binder resin and a release agent, and in a cross section of one toner particle, when the number of cross sections of domains of the release agent having a major axis of 10 nm or more and 500 nm or less is Na and the number of cross sections of domains of the release agent having a major axis of 1500 nm or more and 3000 nm or less is Nb, Na is 15 or more and Nb is 3 or more. The toner according to the second embodiment has the above-mentioned constitution, and therefore achieves both good releasability of the fixed image and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment.

[0027] As described above, when the release agent domain diameter is small, the release agent domains in the toner particles tend to exude to the surfaces of the toner particles due to heating during fixing, which is thought to improve the releasability of the fixed image. However, when the release agent domain diameter is small, when low-density images are continuously formed in a low-temperature, low-humidity environment, the image density may decrease due to cracking of the toner particles.

[0028] In contrast, in the second embodiment, Na is 15 or more and Nb is 3 or more. That is, in the second embodiment, the toner particles include both small-diameter domains and large-diameter domains. Therefore, in the second embodiment, as in the first embodiment, the small-diameter domains tend to seep out to the surface of the toner particles during fixing, and the large-diameter domains act as a buffer during agitation in the toner storage section of the developing unit, suppressing cracking of the toner particles. As a result, in the second embodiment, it is presumed that both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment are achieved.

[0029] Note that toner particles obtained by a conventional technique for increasing the diameter of a release agent domain differ from the toner particles of the second embodiment in that at least Na is outside the above range, and toner particles obtained by a conventional technique for decreasing the diameter of a release agent domain differ from the toner particles of the second embodiment in that at least Nb is outside the above range.

[0030] Hereinafter, a toner that corresponds to both the toner according to the first embodiment and the toner according to the second embodiment will be referred to as "toner according to the present embodiment." However, an example of the toner of the present invention may be a toner that corresponds to at least one of the toner according to the first embodiment and the toner according to the second embodiment.

[0031] <Release Agent Domain> (Measurement method) Here, the release agent domain is observed as follows. Toner particles (or toner particles with external additives attached) are mixed and embedded in epoxy resin, and the epoxy resin is solidified. The solidified material is cut using an ultramicrotome (Leica Ultracut UCT) to prepare thin section samples with thicknesses of 80 nm to 130 nm. The obtained thin section samples are then stained with ruthenium tetroxide for 3 hours in a desiccator at 30°C. An ultra-high-resolution field emission scanning electron microscope (FE-SEM, Hitachi High-Technologies Corporation S-4800) is then used to obtain STEM observation images (accelerating voltage: 30 kV, magnification: 20,000x) in transmission image mode of the stained thin section samples.

[0032] The contours of the release agent domains in the toner particles are determined from the contrast and shape of the obtained STEM observation images. In the STEM images, the binder resin other than the release agent has many double bond moieties and is stained with ruthenium tetroxide, so the release agent part and the binder resin part other than the release agent can be distinguished. In other words, with ruthenium staining, the release agent is the domain that is stained the lightest, and the amorphous resin is stained the darkest. By adjusting the contrast, the release agent appears white and the amorphous resin appears black, allowing the cross-sectional shape of the release agent domain to be confirmed.

[0033] One hundred toner particles are observed, and the release agent domain region is subjected to image analysis to determine the release agent domain diameter of each release agent domain, the cross-sectional area of ​​each release agent domain, and the cross-sectional area of ​​each toner particle. From the results, the total cross-sectional area St of the toner particle being observed, the total cross-sectional area Sa of the small diameter domains, the total cross-sectional area Sb of the large diameter domains, the average number Na of the small diameter domains per toner particle, the average number Nb of the large diameter domains per toner particle, and the total area Sw of all the release agent domains are calculated. Note that, since STEM images contain toner particle cross sections of various sizes, toner particle cross sections whose diameter is 70% or more of the volume average particle diameter of the toner particles are selected as the toner particles to be observed. Here, the diameter of the toner particle cross section refers to the longest length (so-called major axis) of a line drawn between any two points on the outline of the toner particle cross section.

[0034] (Area fraction) In this embodiment, as described above, the area fraction Sa / St is 2% or more, and from the viewpoint of obtaining good releasability of the fixed image, it is preferably 2.5% or more, and more preferably 3% or more. In addition, the area fraction Sa / St is preferably 20% or less, more preferably 18% or less, and even more preferably 15% or less, from the viewpoint of suppressing a decrease in toner fluidity caused by the release agent seeping out onto the toner particle surface due to the load during toner agitation in the developing means. The area fraction Sa / St is preferably 2% or more and 20% or less, more preferably 2.5% or more and 18% or less, and even more preferably 3% or more and 15% or less.

[0035] As described above, the area fraction Sb / St is 20% or more, and from the viewpoint of suppressing a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, it is preferably 23% or more, and more preferably 26% or more. Furthermore, the area fraction Sb / St is preferably 40% or less, more preferably 38% or less, and even more preferably 36% or less, from the viewpoint of suppressing a decrease in toner fluidity caused by the release agent seeping out onto the toner particle surface due to the load during toner agitation in the developing means. The area fraction Sb / St is preferably 20% or more and 40% or less, more preferably 23% or more and 38% or less, and even more preferably 26% or more and 36% or less.

[0036] From the viewpoint of achieving both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, the ratio Sb / Sa is preferably 1 or more and 20 or less, more preferably 1 or more and 15 or less, and even more preferably 1 or more and 12 or less.

[0037] When the total area of ​​the cross sections of domains having a major axis greater than 500 nm and less than 1500 nm (hereinafter also referred to as "medium-diameter domains") among the cross sections of the release agent domains is Sc, the value of the area fraction Sc / St is not particularly limited. The area fraction Sc / St may be 1% or less, 1% or more and 5% or less, or 1% or more and 10% or less. Furthermore, the total area Sc may be smaller than the total area Sa, or may be smaller than the total area Sb. The ratio Sc / Sa may be less than 1, 0.1 or greater and less than 1, or 0.2 or greater and 0.8 or less. The ratio Sc / Sb may be less than 1, 0.05 or greater and less than 1, or 0.05 or greater and 0.3 or less. Furthermore, when the total area of ​​the cross sections of the domains of the release agent is Sw, the value of (Sa+Sb) / Sw may be 0.9 or more, 0.93 or more, or even 1.

[0038] The area fraction Sw / St is preferably 30% or more and 50% or less, more preferably 35% or more and 50% or less, and even more preferably 35% or more and 45% or less. By having the area fraction Sw / St in the above range, it is possible to achieve both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, compared to when the area fraction Sw / St is smaller than the above range. Also, by having the area fraction Sw / St in the above range, it is possible to suppress a decrease in toner fluidity caused by the release agent seeping out to the toner particle surface due to the load during toner agitation in the developing means, and thus a decrease in image density caused by the decrease in toner fluidity, compared to when the area fraction Sw / St is larger than the above range.

[0039] (Number of domains) In this embodiment, as described above, Na is 15 or more, and from the viewpoint of obtaining good releasability of the fixed image, it is preferably 17 or more, and more preferably 20 or more. In addition, from the viewpoint of suppressing a decrease in toner fluidity caused by the release agent seeping out onto the toner particle surface due to the load during toner agitation in the developing means, Na is preferably 45 or less, more preferably 40 or less, and even more preferably 35 or less. Na is preferably 15 or more and 45 or less, more preferably 17 or more and 40 or less, and even more preferably 20 or more and 35 or less.

[0040] As described above, Nb is 3 or more, and from the viewpoint of suppressing a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, it is preferably 3.2 or more, and more preferably 3.5 or more. Furthermore, from the viewpoint of suppressing a decrease in toner fluidity caused by the release agent seeping out onto the toner particle surface due to the load during toner agitation in the developing means, Nb is preferably 5 or less, more preferably 4.8 or less, and even more preferably 4.6 or less. The number of Nb is preferably 3 or more and 5 or less, more preferably 3.2 or more and 4.8 or less, and further preferably 3.5 or more and 4.6 or less.

[0041] From the viewpoint of achieving both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment, the ratio Nb / Na is preferably 0.05 or more and 0.30 or less, more preferably 0.05 or more and 0.25 or less, and even more preferably 0.1 or more and 0.2 or less.

[0042] When the number of medium diameter domains in the cross section of one toner particle is defined as Nc, Nc is not particularly limited and may be 3 or less, 0.5 to 3, or 0.5 to 2. Furthermore, Nc may be smaller than Na or may be smaller than Nb. The ratio Nc / Na may be less than 1, may be 0.01 or more and 0.1 or less, or may be 0.01 or more and 0.05 or less. The ratio Nc / Nb may be less than 1, may be 0.05 or more and 0.5 or less, or may be 0.1 or more and 0.3 or less. Furthermore, when the sum of Na, Nb, and Nc is Nw, the value of (Na+Nb) / Nw may be 0.9 or more, 0.95 or more, or even 1.

[0043] (Average circularity of large diameter domains) The average circularity of the cross section of the large diameter domains is preferably 0.6 or more, more preferably 0.7 or more, even more preferably 0.8 or more, and particularly preferably 0.85 or more. When the average circularity of the cross section of the large diameter domains is in the above range, cracks originating from the interface between the release agent domain and the binder resin in the toner particle due to the load during toner agitation in the developing unit are less likely to occur, compared to when the average circularity is smaller than the above range, and a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment is suppressed. The upper limit of the average circularity of the cross section of the large diameter domains is not particularly limited, and may be, for example, 1.00 or less. The average circularity of the cross section of the large diameter domains is the number average of the circularities of each large diameter domain in the STEM image, and the circularity of each large diameter domain is obtained by dividing the equivalent circular perimeter (i.e., the perimeter of a circle having the same area as the cross section of the large diameter domain) by the actual perimeter.

[0044] (Control of domain size distribution of release agent) There are no particular limitations on the method for controlling the domain diameter distribution of the release agent to make the area fraction Sa / St, the area fraction Sb / St, Na, and Nb fall within the above ranges. A method for controlling the release agent domain size distribution includes, for example, producing toner particles having a core-shell structure described below by the aggregation-coalescence method described below, and using a surfactant with the opposite polarity to that used in the release agent particle dispersion for forming the coating layer (hereinafter also referred to as the "shell layer") as a surfactant used in the release agent particle dispersion for forming the core portion (hereinafter also referred to as the "core particle") (hereinafter also referred to as the "opposite polarity surfactant method"). Specifically, for example, when a cationic surfactant is used in the release agent particle dispersion for forming the core particles, an anionic surfactant is used in the release agent particle dispersion for forming the shell layer. Furthermore, for example, when an anionic surfactant is used in the release agent particle dispersion for forming the core particles, a cationic surfactant is used in the release agent particle dispersion for forming the shell layer.

[0045] The reason why the domain size distribution of the release agent is controlled by the reverse polarity surfactant method is not clear, but is presumed to be as follows. For example, when a resin particle dispersion containing dispersed binder resin particles contains an anionic surfactant, forming core particles using a release agent particle dispersion containing a cationic surfactant reduces the release agent domain diameter within the core particles. Specifically, the polarity of the resin particles is opposite to that of the release agent particles, which increases the affinity between the resin particles and the release agent particles. During the aggregation process, the resin particles surround the release agent particles, suppressing their aggregation, thereby reducing the release agent domain diameter. Furthermore, forming a shell layer on the surface of a core particle using a resin particle dispersion containing an anionic surfactant and a release agent particle dispersion containing an anionic surfactant results in the release agent domain diameter within the shell layer being larger than the release agent domain diameter within the core particle. In other words, a single toner particle contains both release agent domains with large release agent domain diameters and release agent domains with small release agent domain diameters. Therefore, it is believed that the area fractions Sa / St, Sb / St, Na, and Nb are controlled within the above ranges.

[0046] As an example of the toner according to this embodiment, a toner in which the distribution of the domain diameter of the release agent is controlled by the reverse polarity surfactant method will be described in detail below.

[0047] The toner according to this embodiment contains toner particles and, if necessary, an external additive.

[0048] (toner particles) The toner particles are composed of, for example, a binder resin, a release agent, and, if necessary, a colorant and other additives.

[0049] -Binder resin- Examples of binder resins include homopolymers of monomers such as styrenes (e.g., styrene, parachlorostyrene, α-methylstyrene, etc.), (meth)acrylic acid esters (e.g., methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, lauryl methacrylate, 2-ethylhexyl methacrylate, etc.), ethylenically unsaturated nitriles (e.g., acrylonitrile, methacrylonitrile, etc.), vinyl ethers (e.g., vinyl methyl ether, vinyl isobutyl ether, etc.), vinyl ketones (vinyl methyl ketone, vinyl ethyl ketone, vinyl isopropenyl ketone, etc.), and olefins (e.g., ethylene, propylene, butadiene, etc.), and vinyl resins made of copolymers of two or more of these monomers. Examples of the binder resin include non-vinyl resins such as epoxy resins, polyester resins, polyurethane resins, polyamide resins, cellulose resins, polyether resins, and modified rosin, mixtures of these with the vinyl resins, and graft polymers obtained by polymerizing vinyl monomers in the presence of these. These binder resins may be used alone or in combination of two or more.

[0050] Among the above, it is preferable that the binder resin contains a styrene (meth)acrylic resin obtained by copolymerizing a monomer having a styrene skeleton and a monomer having a (meth)acrylic acid ester skeleton, from the viewpoint of low-temperature fixability. Toner particles containing a styrene (meth)acrylic resin as a binder resin tend to form small-diameter wax domains, and the increased interface with the resin makes them more susceptible to cracking due to external loads. However, in this embodiment, the presence of large-diameter domains within the toner particles suppresses cracking of the toner particles, thereby achieving both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment.

[0051] The styrene (meth)acrylic resin is a copolymer obtained by copolymerizing at least a monomer having a styrene skeleton and a monomer having a (meth)acryloyl group.

[0052] Examples of monomers having a styrene skeleton (hereinafter also referred to as "styrene-based monomers") include styrene, alkyl-substituted styrenes (e.g., α-methylstyrene, 2-methylstyrene, 3-methylstyrene, 4-methylstyrene, 2-ethylstyrene, 3-ethylstyrene, 4-ethylstyrene, etc.), halogen-substituted styrenes (e.g., 2-chlorostyrene, 3-chlorostyrene, 4-chlorostyrene, etc.), vinylnaphthalene, etc. The styrene-based monomers may be used alone or in combination of two or more. Of these, styrene is preferred as the styrene-based monomer in terms of ease of reaction, ease of reaction control, and availability.

[0053] Examples of the monomer having a (meth)acryloyl group (hereinafter also referred to as "(meth)acrylic monomer") include (meth)acrylic acid and (meth)acrylic acid esters. Examples of the (meth)acrylic acid ester include (meth)acrylic acid alkyl esters (e.g., n-methyl (meth)acrylate, n-ethyl (meth)acrylate, n-propyl (meth)acrylate, n-butyl (meth)acrylate, n-pentyl (meth)acrylate, n-hexyl acrylate, n-heptyl (meth)acrylate, n-octyl (meth)acrylate, n-decyl (meth)acrylate, n-dodecyl (meth)acrylate, n-lauryl (meth)acrylate, n-tetradecyl (meth)acrylate, n-hexadecyl (meth)acrylate, n-octadecyl (meth)acrylate, isopropyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, isopentyl (meth)acrylate, amyl (meth)acrylate, Examples of (meth)acrylic acid monomers include neopentyl acrylate, isohexyl (meth)acrylate, isoheptyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, cyclohexyl (meth)acrylate, t-butylcyclohexyl (meth)acrylate, etc.), (meth)acrylic acid aryl esters (for example, phenyl (meth)acrylate, biphenyl (meth)acrylate, diphenylethyl (meth)acrylate, t-butylphenyl (meth)acrylate, terphenyl (meth)acrylate, etc.), dimethylaminoethyl (meth)acrylate, diethylaminoethyl (meth)acrylate, methoxyethyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, β-carboxyethyl (meth)acrylate, and (meth)acrylamide. One (meth)acrylic acid monomer may be used alone, or two or more may be used in combination.

[0054] The copolymerization ratio of the styrene-based monomer to the (meth)acrylic monomer (based on mass, styrene-based monomer / (meth)acrylic monomer) is preferably, for example, 85 / 15 to 70 / 30.

[0055] The styrene (meth)acrylic resin may have a crosslinked structure. Examples of the styrene (meth)acrylic resin having a crosslinked structure include a crosslinked product obtained by copolymerizing at least a monomer having a styrene skeleton, a monomer having a (meth)acrylic acid skeleton, and a crosslinkable monomer, followed by crosslinking.

[0056] Examples of the crosslinkable monomer include bifunctional or higher functional crosslinking agents. Examples of bifunctional crosslinking agents include divinylbenzene, divinylnaphthalene, di(meth)acrylate compounds (e.g., diethylene glycol di(meth)acrylate, methylene bis(meth)acrylamide, decanediol diacrylate, glycidyl (meth)acrylate, etc.), polyester-type di(meth)acrylate, 2-([1'-methylpropylideneamino]carboxyamino)ethyl methacrylate, etc. Examples of polyfunctional crosslinking agents include tri(meth)acrylate compounds (e.g., pentaerythritol tri(meth)acrylate, trimethylolethane tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, etc.), tetra(meth)acrylate compounds (e.g., tetramethylolmethane tetra(meth)acrylate, oligoester (meth)acrylate, etc.), 2,2-bis(4-methacryloxy, polyethoxyphenyl)propane, diallyl phthalate, triallyl cyanurate, triallyl associanurate, triallyl isocyanurate, triallyl trimellitate, diaryl chlorendate, etc.

[0057] The copolymerization ratio of the crosslinkable monomer to the total monomers (based on mass, crosslinkable monomer / total monomers) is preferably, for example, 2 / 1000 or more and 30 / 1000 or less.

[0058] The weight average molecular weight of the styrene (meth)acrylic resin is, for example, from 30,000 to 200,000, preferably from 40,000 to 100,000, and more preferably from 50,000 to 80,000, from the viewpoint of releasability. The weight average molecular weight of the styrene (meth)acrylic resin is measured by the same method as that for the weight average molecular weight of the polyester resin described below.

[0059] The content of units derived from styrene-based monomers (hereinafter also referred to as "styrene content") is preferably 15% by mass or more and 25% by mass or less, more preferably 15% by mass or more and 23% by mass or less, and even more preferably 17% by mass or more and 22% by mass or less, based on the total mass of the toner particles. A styrene content in the above range is advantageous in terms of heat storage stability compared to when the styrene content is less than the above range, and is advantageous in terms of low-temperature fixability compared to when the styrene content is more than the above range. It should be noted that, for example, when the toner particles contain a plurality of vinyl resins as binder resins, the styrene content means the total content of units derived from styrene monomers contained in each of the plurality of vinyl resins. The styrene content in the toner particles is determined from a calibration curve of the styrene compound previously measured by liquid chromatography (LC-UV) after the styrene compound is identified by chemical analysis. The content of the styrene (meth)acrylic resin relative to the binder resin is, for example, 50% by mass to 80% by mass, preferably 50% by mass to 70% by mass, and more preferably 60% by mass to 70% by mass.

[0060] The binder resin may contain a polyester resin, or may contain both a styrene (meth)acrylic resin and a polyester resin. Examples of polyester resins include known amorphous polyester resins. The polyester resin may be used in combination with a crystalline polyester resin. However, the content of the crystalline polyester resin is preferably in the range of 2% by mass to 40% by mass (preferably 2% by mass to 20% by mass) relative to the total binder resin.

[0061] The "crystalline" nature of a resin refers to the presence of a clear endothermic peak rather than a stepwise change in endothermic heat in differential scanning calorimetry (DSC). Specifically, this refers to the half-width of the endothermic peak being within 10°C when measured at a heating rate of 10°C / min. On the other hand, the term "amorphous" for a resin means that the half-width exceeds 10°C, that the endothermic amount exhibits a stepwise change, or that no clear endothermic peak is observed.

[0062] Amorphous polyester resin Examples of the amorphous polyester resin include a condensation polymer of a polycarboxylic acid and a polyhydric alcohol. Note that, as the amorphous polyester resin, a commercially available product or a synthesized product may be used.

[0063] Examples of polycarboxylic acids include aliphatic dicarboxylic acids (such as oxalic acid, malonic acid, maleic acid, fumaric acid, citraconic acid, itaconic acid, glutaconic acid, succinic acid, alkenylsuccinic acid, adipic acid, and sebacic acid), alicyclic dicarboxylic acids (such as cyclohexanedicarboxylic acid), aromatic dicarboxylic acids (such as terephthalic acid, isophthalic acid, phthalic acid, and naphthalenedicarboxylic acid), anhydrides thereof, and lower alkyl esters thereof (e.g., having 1 to 5 carbon atoms). Among these, aromatic dicarboxylic acids are preferred as polycarboxylic acids. The polycarboxylic acid may be a trivalent or higher carboxylic acid having a crosslinked or branched structure in combination with a dicarboxylic acid. Examples of the trivalent or higher carboxylic acid include trimellitic acid, pyromellitic acid, anhydrides thereof, and lower alkyl esters thereof (e.g., having 1 to 5 carbon atoms). The polycarboxylic acids may be used alone or in combination of two or more.

[0064] Examples of polyhydric alcohols include aliphatic diols (e.g., ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, butanediol, hexanediol, neopentyl glycol, etc.), alicyclic diols (e.g., cyclohexanediol, cyclohexanedimethanol, hydrogenated bisphenol A, etc.), and aromatic diols (e.g., ethylene oxide adducts of bisphenol A, propylene oxide adducts of bisphenol A, etc.). Among these, preferred polyhydric alcohols are aromatic diols and alicyclic diols, and more preferred are aromatic diols. As the polyhydric alcohol, a trihydric or higher polyhydric alcohol having a crosslinked or branched structure may be used in combination with the diol. Examples of trihydric or higher polyhydric alcohols include glycerin, trimethylolpropane, and pentaerythritol. The polyhydric alcohols may be used alone or in combination of two or more.

[0065] The glass transition temperature (Tg) of the amorphous polyester resin is preferably 50°C or higher and 80°C or lower, and more preferably 50°C or higher and 65°C or lower. The glass transition temperature is determined from a DSC curve obtained by differential scanning calorimetry (DSC), more specifically, from the "extrapolated glass transition onset temperature" described in JIS K 7121-1987 "Method for measuring transition temperatures of plastics."

[0066] The weight average molecular weight (Mw) of the amorphous polyester resin is preferably 5,000 or more and 1,000,000 or less, and more preferably 7,000 or more and 500,000 or less. The number average molecular weight (Mn) of the amorphous polyester resin is preferably 2,000 or more and 100,000 or less. The molecular weight distribution Mw / Mn of the amorphous polyester resin is preferably 1.5 or more and 100 or less, and more preferably 2 or more and 60 or less. The weight-average molecular weight and number-average molecular weight are measured by gel permeation chromatography (GPC). Molecular weight measurements by GPC are performed using a Tosoh GPC HLC-8120GPC measuring device and a Tosoh TSKgel SuperHM-M (15 cm) column in THF solvent. The weight-average molecular weight and number-average molecular weight are calculated from the measurement results using a molecular weight calibration curve prepared with monodisperse polystyrene standard samples.

[0067] The amorphous polyester resin can be obtained by a known manufacturing method, for example, by carrying out the reaction at a polymerization temperature of 180°C or higher and 230°C or lower, reducing the pressure in the reaction system as necessary, and removing water and alcohol generated during the condensation. If the raw material monomer is not soluble or compatible at the reaction temperature, a high-boiling solvent may be added as a solubilizer to dissolve it. In this case, the polycondensation reaction is carried out while distilling off the solubilizer. If a monomer with poor compatibility is present, it is advisable to first condense the poorly compatible monomer with the acid or alcohol to be polycondensed, and then polycondense the monomer with the main component.

[0068] Crystalline polyester resin The crystalline polyester resin may be, for example, a polycondensate of a polycarboxylic acid and a polyhydric alcohol. Note that, as the crystalline polyester resin, a commercially available product or a synthesized product may be used. Here, the crystalline polyester resin is preferably a polycondensate using a polymerizable monomer having a linear aliphatic group rather than a polymerizable monomer having an aromatic group, since it easily forms a crystalline structure.

[0069] Examples of polycarboxylic acids include aliphatic dicarboxylic acids (e.g., oxalic acid, succinic acid, glutaric acid, adipic acid, suberic acid, azelaic acid, sebacic acid, 1,9-nonanedicarboxylic acid, 1,10-decanedicarboxylic acid, 1,12-dodecanedicarboxylic acid, 1,14-tetradecanedicarboxylic acid, 1,18-octadecanedicarboxylic acid, etc.), aromatic dicarboxylic acids (e.g., dibasic acids such as phthalic acid, isophthalic acid, terephthalic acid, and naphthalene-2,6-dicarboxylic acid), anhydrides thereof, and lower alkyl esters thereof (e.g., having 1 to 5 carbon atoms). The polycarboxylic acid may be a tricarboxylic or higher carboxylic acid having a crosslinked or branched structure in combination with a dicarboxylic acid. Examples of the tricarboxylic acid include aromatic carboxylic acids (e.g., 1,2,3-benzenetricarboxylic acid, 1,2,4-benzenetricarboxylic acid, 1,2,4-naphthalenetricarboxylic acid, etc.), anhydrides thereof, and lower alkyl esters thereof (e.g., having 1 to 5 carbon atoms). As the polycarboxylic acid, a dicarboxylic acid having a sulfonic acid group and a dicarboxylic acid having an ethylenic double bond may be used in combination with these dicarboxylic acids. The polycarboxylic acids may be used alone or in combination of two or more.

[0070] Examples of polyhydric alcohols include aliphatic diols (for example, straight-chain aliphatic diols having 7 to 20 carbon atoms in the main chain). Examples of aliphatic diols include ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,14-tetradecanediol, 1,18-octadecanediol, and 1,14-eicosanedecanediol. Among these, 1,8-octanediol, 1,9-nonanediol, and 1,10-decanediol are preferred as aliphatic diols. The polyhydric alcohol may be a trihydric or higher alcohol having a crosslinked or branched structure, such as glycerin, trimethylolethane, trimethylolpropane, or pentaerythritol, in combination with the diol. The polyhydric alcohols may be used alone or in combination of two or more.

[0071] Here, the polyhydric alcohol has an aliphatic diol content of 80 mol % or more, preferably 90 mol % or more.

[0072] The melting temperature of the crystalline polyester resin is preferably 50°C or higher and 100°C or lower, more preferably 55°C or higher and 90°C or lower, and even more preferably 60°C or higher and 85°C or lower. The melting temperature is determined from a DSC curve obtained by differential scanning calorimetry (DSC) by using the "melting peak temperature" described in the method for determining the melting temperature in JIS K7121-1987 "Method for measuring transition temperatures of plastics."

[0073] The weight average molecular weight (Mw) of the crystalline polyester resin is preferably 6,000 or more and 35,000 or less.

[0074] The crystalline polyester resin can be obtained by a known manufacturing method, for example, in the same manner as the amorphous polyester.

[0075] The content of the binder resin is, for example, preferably 40% by mass to 95% by mass, more preferably 50% by mass to 90% by mass, and even more preferably 60% by mass to 85% by mass, based on the total mass of the toner particles.

[0076] -Coloring agent- Examples of colorants include carbon black, chrome yellow, Hansa Yellow, benzidine yellow, threne yellow, quinoline yellow, pigment yellow, permanent orange GTR, pyrazolone orange, Balkan orange, watch young red, permanent red, brilliant carmine 3B, brilliant carmine 6B, DuPont oil red, pyrazolone red, lithol red, rhodamine B lake, lake red C, pigment red, rose bengal, aniline blue, ultramarine blue, and the like. Examples of the dye include various pigments such as phosphorus blue, chalco oil blue, methylene blue chloride, phthalocyanine blue, pigment blue, phthalocyanine green, and malachite green oxalate, and various dyes such as acridine-based, xanthene-based, azo-based, benzoquinone-based, azine-based, anthraquinone-based, thioindigo-based, dioxazine-based, thiazine-based, azomethine-based, indigo-based, phthalocyanine-based, aniline black-based, polymethine-based, triphenylmethane-based, diphenylmethane-based, and thiazole-based dyes. The colorant may be used alone or in combination of two or more kinds.

[0077] The colorant may be surface-treated as needed, or may be used in combination with a dispersant. Furthermore, a plurality of colorants may be used in combination.

[0078] The content of the colorant is, for example, preferably 1% by mass or more and 30% by mass or less, and more preferably 3% by mass or more and 15% by mass or less, based on the total mass of the toner particles.

[0079] -Mold release agent- Examples of release agents include hydrocarbon waxes, natural waxes such as carnauba wax, rice wax, and candelilla wax, synthetic or mineral / petroleum waxes such as montan wax, and ester waxes such as fatty acid esters and montanic acid esters, but are not limited thereto.

[0080] The melting temperature Tm of the release agent is preferably 50°C or higher and 110°C or lower, and more preferably 60°C or higher and 100°C or lower. The melting temperature is determined from a DSC curve obtained by differential scanning calorimetry (DSC) by using the "melting peak temperature" as described in the method for determining the melting temperature in JIS K 7121-1987 "Method for measuring transition temperatures of plastics."

[0081] In particular, the melting temperature Tm of the release agent is preferably from 65° C. to 95° C., more preferably from 65° C. to 85° C. By using a release agent having a melting temperature Tm in the above range, it becomes easier to control the area fraction Sa / St, the area fraction Sb / St, Na, and Nb within the above ranges, and it becomes easier to achieve both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment.

[0082] Furthermore, the difference Tm-Tg between the melting temperature Tm of the release agent and the glass transition temperature Tg of the binder resin is preferably 15°C or more and 30°C or less, more preferably 18°C ​​or more and 30°C or less, and even more preferably 20°C or more and 30°C or less. By using a binder resin and a release agent whose difference Tm-Tg falls within the above ranges, it becomes easier to control the area fractions Sa / St, Sb / St, Na, and Nb within the above ranges, and it becomes easier to achieve both the releasability of the fixed image and the suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. Here, the "glass transition temperature Tg of the binder resin" refers to the glass transition temperature determined from the largest endothermic peak among endothermic peaks derived from an amorphous resin that appear in a temperature range of 30°C or higher in a DSC curve obtained by differential scanning calorimetry (DSC) of the toner.

[0083] The release agent having a melting temperature within the above range is preferably an ester wax or a hydrocarbon wax, and more preferably an ester wax. In particular, the use of an ester wax as a release agent facilitates the formation of larger diameter, spherical particles, which makes it easier to control the area fractions Sa / St, Sb / St, Na, and Nb within the above-mentioned ranges, thereby making it easier to achieve both good release properties for fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. From the viewpoint of cost reduction, it is preferable to use only one type of release agent.

[0084] The ester wax is a wax having an ester bond. The ester wax may be any of a monoester, diester, triester, and tetraester, and any known natural or synthetic ester wax can be used. Examples of ester waxes include ester compounds of higher fatty acids (such as fatty acids having 10 or more carbon atoms) and monohydric or polyhydric aliphatic alcohols (such as aliphatic alcohols having 8 or more carbon atoms). Examples of ester waxes include ester compounds of higher fatty acids (caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, oleic acid, etc.) with alcohols (monohydric alcohols such as methanol, ethanol, propanol, isopropanol, butanol, capryl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, and oleyl alcohol; and polyhydric alcohols such as glycerin, ethylene glycol, propylene glycol, sorbitol, and pentaerythritol). Specific examples include carnauba wax, rice wax, candelilla wax, jojoba oil, Japan wax, beeswax, privet wax, lanolin, and montan acid ester wax.

[0085] Specific examples of hydrocarbon waxes include polyethylene waxes, polypropylene waxes, polyolefin waxes, Fischer-Tropsch waxes, paraffin waxes, and microcrystalline waxes.

[0086] The content of the release agent is, for example, preferably 20% by mass or more and 60% by mass or less, and more preferably 30% by mass or more and 50% by mass or less, based on the total mass of the toner particles.

[0087] -Surfactants- The toner particles may contain a surfactant. Examples of the surfactant contained in the toner particles include a surfactant that is used for the purpose of dispersing the particles in a dispersion liquid during the production process of the toner particles and that remains in the toner particles. In particular, the toner particles in which the distribution of the release agent domain diameter is controlled by the above-mentioned reverse polarity surfactant method contain, for example, both a cationic surfactant and an anionic surfactant.

[0088] Examples of cationic surfactants include amine acetates such as octadecylamine acetate and tetradecylamine acetate; methylammonium hydrochlorides such as lauryltrimethylammonium chloride, tallow trimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride and didecyldimethylammonium chloride; benzyl chlorides such as octadecyldimethylbenzylammonium chloride and tetradecyldimethylbenzylammonium chloride; and quaternary ammonium salts such as dioleyldimethylammonium chloride and tetrabutylammonium bromide. Among these, from the viewpoint of toner granulation properties, the cationic surfactant is preferably a quaternary ammonium salt or a methylammonium hydrochloride, and more preferably a quaternary ammonium salt.

[0089] Examples of anionic surfactants include sulfonates in which at least one of an alkyl group and a phenyl group is substituted with a sulfonate, such as sodium dodecylbenzenesulfonate and sodium alkyldiphenyletherdisulfonate; metal soaps such as lithium stearate, magnesium stearate, calcium stearate, barium stearate, zinc stearate, calcium ricinoleate, barium ricinoleate, zinc ricinoleate, and zinc octoate; and alkyl sulfates such as sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, and sodium cetyl sulfate. Among these, the anionic surfactants are preferably sulfonates and metal soaps, more preferably sulfonates, from the viewpoint of imparting electric charge by friction.

[0090] Examples of combinations of cationic surfactants and anionic surfactants include combinations of quaternary ammonium salts and sulfonates, combinations of methylammonium hydrochlorides and sulfonates, and combinations of methylammonium hydrochlorides and metal soaps. Of these, combinations of quaternary ammonium salts and sulfonates are preferred.

[0091] -Other additives- Examples of other additives include well-known additives such as magnetic materials, charge control agents, inorganic powders, etc. These additives are contained in the toner particles as internal additives.

[0092] -Characteristics of toner particles, etc.- The toner particles in which the release agent domain size distribution is controlled by the reverse polarity surfactant method may be toner particles having a so-called core-shell structure, which is composed of a core (core particle) and a coating layer (shell layer) that coats the core. Here, the toner particles having a core-shell structure may be composed of, for example, a core containing a binder resin, a release agent, and optionally other additives such as a colorant, and a coating layer containing a binder resin and a release agent.

[0093] The toner particles having the core-shell structure may be toner particles in which the coating layer containing the binder resin and the release agent is the outermost layer, or may be toner particles in which another layer is further provided on the outer surface of the coating layer containing the binder resin and the release agent. The other layer may be, for example, a layer containing a binder resin. The other layer may also be a layer containing a binder resin but not a release agent. That is, the toner particles having the core-shell structure may be toner particles having a core containing a binder resin and a release agent, a first coating layer provided on the outer peripheral surface of the core and containing a binder resin and a release agent, and a second coating layer provided on the outer peripheral surface of the first coating layer and containing a binder resin.

[0094] The volume average particle size (D50v) of the toner particles is preferably from 2 μm to 10 μm, more preferably from 4 μm to 8 μm, and even more preferably from 5 μm to 7 μm.

[0095] The various average particle sizes and particle size distribution indices of the toner particles are measured using a Coulter Multisizer II (manufactured by Beckman Coulter), and the electrolyte is measured using an ISOTON-II (manufactured by Beckman Coulter). For the measurement, 0.5 mg to 50 mg of the sample to be measured is added to 2 ml of a 5% aqueous solution of a surfactant (preferably sodium alkylbenzene sulfonate) as a dispersant, and this is then added to 100 ml to 150 ml of the electrolyte. The electrolyte solution containing the suspended sample is dispersed for 1 minute using an ultrasonic disperser, and the particle size distribution of particles with a particle size range of 2 μm to 60 μm is measured using a Coulter Multisizer II with an aperture diameter of 100 μm. The number of particles sampled is 50,000. Based on the particle size distribution measured, cumulative distributions of volume and number are drawn for each divided particle size range (channel) from the smallest diameter side, and the particle size at 16% of the cumulative total is defined as the volume particle size D16v, the number particle size D16p, the particle size at 50% of the cumulative total as the volume average particle size D50v, the cumulative number average particle size D50p, and the particle size at 84% of the cumulative total as the volume particle size D84v and the number particle size D84p. Using these, the volumetric particle size distribution index (GSDv) is (D84v / D16v) 1 / 2 , the number particle size distribution index (GSDp) is (D84p / D16p) 1 / 2 It is calculated as:

[0096] The average circularity of the toner particles is preferably 0.94 or more and 1.00 or less, and more preferably 0.95 or more and 0.98 or less.

[0097] The average circularity of toner particles is calculated by (circular equivalent perimeter) / (perimeter) [(perimeter of a circle having the same projected area as the particle image) / (perimeter of the particle projected image)]. Specifically, this value is measured by the following method. First, the toner particles to be measured are sucked and collected, forming a flat flow, and a still image of the particles is captured by instantaneously activating a strobe light, and the particle image is analyzed using a flow-type particle image analyzer (FPIA-3000 manufactured by Sysmex Corporation).The number of samples to be sampled when calculating the average circularity is 3,500. When the toner contains external additives, the toner (developer) to be measured is dispersed in water containing a surfactant, and then ultrasonic treatment is performed to obtain toner particles from which the external additives have been removed.

[0098] (external additives) Examples of external additives include inorganic particles such as SiO2, TiO2, Al2O3, CuO, ZnO, SnO2, CeO2, Fe2O3, MgO, BaO, CaO, KO, Na2O, ZrO2, CaO·SiO2, KO·(TiO2)n, Al2O3·2SiO2, CaCO3, MgCO3, BaSO4, and MgSO4.

[0099] The surfaces of inorganic particles as external additives are preferably subjected to a hydrophobic treatment. The hydrophobic treatment is carried out, for example, by immersing the inorganic particles in a hydrophobic treatment agent. The hydrophobic treatment agent is not particularly limited, and examples thereof include silane coupling agents, silicone oils, titanate coupling agents, and aluminum coupling agents. These may be used alone or in combination of two or more. The amount of the hydrophobic treatment agent is usually, for example, 1 part by mass or more and 10 parts by mass or less per 100 parts by mass of the inorganic particles.

[0100] Examples of external additives include resin particles (resin particles such as polystyrene, polymethyl methacrylate (PMMA), and melamine resin), cleaning agents (for example, metal salts of higher fatty acids such as zinc stearate, and particles of fluorine-based polymers).

[0101] The amount of the external additive added is, for example, preferably 0.01% by mass or more and 5% by mass or less, and more preferably 0.01% by mass or more and 2.0% by mass or less, based on the toner particles.

[0102] (Toner manufacturing method) Next, a method for producing the toner according to this embodiment will be described. The toner according to the exemplary embodiment can be obtained by producing toner particles and then externally adding an external additive to the toner particles, if necessary.

[0103] Methods for producing toner particles include dry production methods (for example, kneading and pulverization methods) and wet production methods (for example, aggregation and coalescence methods, suspension polymerization methods, and dissolution and suspension methods). In the reverse polarity surfactant method, toner particles are obtained by the aggregation and coalescence method among these.

[0104] Specifically, for example, the method includes a step of preparing a resin particle dispersion in which resin particles serving as a binder resin are dispersed and a release agent particle dispersion in which release agent particles are dispersed (dispersion liquid preparation step), a step of aggregating the resin particles and the release agent particles (and other particles as needed) in the dispersion obtained by mixing the resin particle dispersion and the release agent particle dispersion (in the dispersion obtained by mixing other particle dispersions as needed) to form first aggregated particles (first aggregated particle formation step), and a step of mixing the first aggregated particle dispersion in which the first aggregated particles are dispersed and the resin The toner particles are manufactured through a process of further mixing a resin particle dispersion liquid in which the particles are dispersed with a release agent particle dispersion liquid in which release agent particles are dispersed, and aggregating the first aggregated particles so that the resin particles and the release agent particles adhere to the surfaces of the first aggregated particles to form second aggregated particles (second aggregated particle forming process), and a process of heating the second aggregated particle dispersion liquid in which the second aggregated particles are dispersed to fuse and coalesce the second aggregated particles to form toner particles with a core-shell structure having a core and a coating layer (fusion and coalescence process).

[0105] Each step will be described in detail below. In the following description, a method for obtaining toner particles containing a colorant and a release agent will be described, but the colorant is used as needed. Of course, other additives besides the colorant may also be used.

[0106] -Dispersion liquid preparation process- First, a resin particle dispersion in which resin particles serving as a binder resin are dispersed, as well as a colorant particle dispersion in which colorant particles are dispersed and a release agent particle dispersion in which release agent particles are dispersed are prepared.

[0107] Here, the resin particle dispersion liquid is prepared, for example, by dispersing resin particles in a dispersion medium using a surfactant.

[0108] Examples of the dispersion medium used in the resin particle dispersion include aqueous media. Examples of aqueous media include water such as distilled water and ion-exchanged water, alcohols, etc. These may be used alone or in combination of two or more.

[0109] Examples of surfactants include anionic surfactants such as sulfate ester salts, sulfonate salts, phosphate esters, and soaps; cationic surfactants such as amine salts and quaternary ammonium salts; and nonionic surfactants such as polyethylene glycols, alkylphenol ethylene oxide adducts, and polyhydric alcohols. Among these, anionic surfactants and cationic surfactants are particularly preferred. Nonionic surfactants may be used in combination with anionic surfactants or cationic surfactants. The surfactants may be used alone or in combination of two or more.

[0110] In the resin particle dispersion, resin particles can be dispersed in a dispersion medium by a general dispersion method such as a rotary shear homogenizer, a ball mill having a medium, a sand mill, a dyno mill, etc. Depending on the type of resin particles, the resin particles may be dispersed in the resin particle dispersion by, for example, a phase inversion emulsification method. The phase inversion emulsification method involves dissolving the resin to be dispersed in a hydrophobic organic solvent in which the resin is soluble, adding a base to the organic continuous phase (O phase) to neutralize it, and then adding an aqueous medium (W phase), thereby converting the resin from W / O to O / W (so-called phase inversion) and forming a discontinuous phase, and dispersing the resin in particulate form in the aqueous medium.

[0111] The volume average particle size of the resin particles dispersed in the resin particle dispersion is, for example, preferably 0.01 μm or more and 1 μm or less, more preferably 0.08 μm or more and 0.8 μm or less, and even more preferably 0.1 μm or more and 0.6 μm or less. The volume average particle size of the resin particles is measured using a particle size distribution obtained by measurement with a laser diffraction particle size distribution analyzer (e.g., LA-700 manufactured by Horiba, Ltd.), and the cumulative distribution for the volume of the divided particle size range (channel) is subtracted from the small particle size side, and the particle size at which the cumulative 50% of all particles is measured is defined as the volume average particle size D50v. The volume average particle sizes of particles in other dispersions are also measured in the same way.

[0112] The content of resin particles contained in the resin particle dispersion is, for example, preferably from 5% by mass to 50% by mass, and more preferably from 10% by mass to 40% by mass.

[0113] Note that, for example, a colorant particle dispersion and a release agent particle dispersion are also prepared in the same manner as the resin particle dispersion. That is, the volume average particle size, dispersion medium, dispersion method, and particle content of the particles in the resin particle dispersion are the same for the colorant particles dispersed in the colorant particle dispersion and the release agent particles dispersed in the release agent particle dispersion.

[0114] Here, in the reverse polarity surfactant method, for example, an anionic surfactant is used as the surfactant contained in the resin particle dispersion, a cationic surfactant is used as the surfactant contained in the core particle-forming release agent particle dispersion for forming the core portion, and an anionic surfactant is used as the surfactant contained in the shell layer-forming release agent particle dispersion for forming the coating layer. Alternatively, a cationic surfactant may be used as the surfactant contained in the resin particle dispersion, an anionic surfactant may be used as the surfactant contained in the core particle-forming release agent particle dispersion, and a cationic surfactant may be used as the surfactant contained in the shell layer-forming release agent particle dispersion.

[0115] -First agglomerated particle formation process- Next, the colorant particle dispersion and the release agent particle dispersion are mixed together with the resin particle dispersion. In the first aggregate particle formation step for forming the core of the core-shell toner particles, for example, a surfactant having an opposite polarity to that of the surfactant contained in the resin particle dispersion is used as the surfactant contained in the release agent particle dispersion, thereby obtaining toner particles having many small-diameter domains in the core of the toner particles. Then, in the mixed dispersion, the resin particles, colorant particles, and release agent particles are hetero-aggregated to form aggregated particles (first aggregated particles) containing the resin particles, colorant particles, and release agent particles and having a diameter close to that of the target toner particles.

[0116] Specifically, for example, an aggregating agent is added to the mixed dispersion, and the pH of the mixed dispersion is adjusted to be acidic (for example, a pH of 2 or more and 5 or less), and a dispersion stabilizer is added as necessary.Then, the mixed dispersion is heated to the glass transition temperature of the resin particles (specifically, for example, a temperature between the glass transition temperature of the resin particles -30°C and the glass transition temperature -10°C), and the particles dispersed in the mixed dispersion are aggregated to form first aggregated particles. In the first aggregate particle formation step, for example, the mixed dispersion may be stirred with a rotary shear homogenizer, the aggregating agent may be added at room temperature (e.g., 25°C), the pH of the mixed dispersion may be adjusted to an acidic value (e.g., a pH of 2 or more and 5 or less), a dispersion stabilizer may be added as needed, and then the heating may be carried out.

[0117] Examples of the flocculant include a surfactant having a polarity opposite to that of the surfactant used as the dispersant added to the mixed dispersion, an inorganic metal salt, and a divalent or higher metal complex. In particular, when a metal complex is used as the flocculant, the amount of surfactant used can be reduced and the charging characteristics can be improved. If necessary, an additive that forms a complex or a similar bond with the metal ions of the flocculant may be used, and a chelating agent is preferably used as this additive.

[0118] Examples of inorganic metal salts include metal salts such as calcium chloride, calcium nitrate, barium chloride, magnesium chloride, zinc chloride, aluminum chloride, and aluminum sulfate, as well as inorganic metal salt polymers such as polyaluminum chloride, polyaluminum hydroxide, and calcium polysulfide. The chelating agent may be a water-soluble chelating agent, such as hydroxycarboxylic acid (e.g., tartaric acid, citric acid, gluconic acid), iminodiacetic acid (IDA), nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), etc. The amount of the chelating agent added is, for example, preferably 0.01 parts by mass or more and 5.0 parts by mass or less, and more preferably 0.1 parts by mass or more and less than 3.0 parts by mass, per 100 parts by mass of the resin particles.

[0119] -Second agglomerated particle formation process- Next, the first aggregated particle dispersion liquid containing the first aggregated particles, the resin particle dispersion liquid containing the resin particles, and the release agent particle dispersion liquid containing the release agent particles are further mixed together, and the resin particles and the release agent particles are further aggregated so as to adhere to the surfaces of the first aggregated particles, thereby forming second aggregated particles having a core and a coating layer. In the second aggregate particle formation step of forming a coating layer on the core-shell toner particles, for example, a surfactant having the same polarity as the surfactant contained in the resin particle dispersion is used as the surfactant contained in the release agent particle dispersion, thereby obtaining toner particles having many large-diameter domains in the coating layer of the toner particles.

[0120] -Fusion / unification process- Next, the second aggregate particle dispersion liquid in which the second aggregate particles are dispersed is heated, for example, to a temperature equal to or higher than the glass transition temperature of the resin particles (for example, a temperature 10 to 30°C higher than the glass transition temperature of the resin particles), to fuse and coalesce the second aggregate particles and form toner particles.

[0121] Through the above steps, toner particles are obtained. The toner particles may be produced through the following steps: after obtaining the second aggregate particle dispersion in which the second aggregate particles are dispersed, further mixing the second aggregate particle dispersion with a resin particle dispersion in which resin particles are dispersed, and aggregating the second aggregate particles so that the resin particles adhere to the surfaces of the second aggregate particles to form third aggregate particles; and heating the third aggregate particle dispersion in which the third aggregate particles are dispersed to fuse and coalesce the third aggregate particles to form toner particles having a core, a first coating layer, and a second coating layer.

[0122] After the fusion and coalescence process, the toner particles formed in the solution are subjected to a known washing process, a solid-liquid separation process, and a drying process to obtain dry toner particles. In the washing step, it is preferable to carry out sufficient replacement washing with ion-exchanged water from the viewpoint of electrostatic chargeability. Furthermore, the solid-liquid separation step is not particularly limited, but from the viewpoint of productivity, it is preferable to carry out suction filtration, pressure filtration, etc. Furthermore, in the drying step, there is no particular limitation on the method, but from the viewpoint of productivity, it is preferable to carry out freeze drying, flash drying, fluidized drying, vibration-type fluidized drying, etc.

[0123] The toner according to this embodiment is produced by, for example, adding an external additive to the obtained dry toner particles and mixing them. The mixing can be carried out using, for example, a V blender, a Henschel mixer, a Loedige mixer, or the like. Furthermore, if necessary, coarse particles may be removed from the toner using a vibrating sieve, an air sieve, or the like.

[0124] <Electrostatic image developer> The electrostatic image developer according to this embodiment contains at least the toner according to this embodiment. The electrostatic image developer according to this embodiment may be a one-component developer containing only the toner according to this embodiment, or may be a two-component developer containing the toner mixed with a carrier.

[0125] The carrier is not particularly limited, and examples thereof include known carriers, such as coated carriers in which the surface of a core material made of magnetic powder is coated with a coating resin, magnetic powder dispersion carriers in which magnetic powder is dispersed and blended in a matrix resin, and resin-impregnated carriers in which porous magnetic powder is impregnated with a resin. The magnetic powder dispersion type carrier and the resin impregnated type carrier may be a carrier in which the constituent particles of the carrier are used as a core material and are coated with a coating resin.

[0126] Examples of magnetic powder include magnetic metals such as iron, nickel, and cobalt, and magnetic oxides such as ferrite and magnetite.

[0127] Examples of coating resins and matrix resins include polyethylene, polypropylene, polystyrene, polyvinyl acetate, polyvinyl alcohol, polyvinyl butyral, polyvinyl chloride, polyvinyl ether, polyvinyl ketone, vinyl chloride-vinyl acetate copolymer, styrene-acrylic acid ester copolymer, straight silicone resins containing organosiloxane bonds or modified products thereof, fluororesins, polyesters, polycarbonates, phenolic resins, and epoxy resins. The coating resin and the matrix resin may contain other additives such as conductive particles. Examples of conductive particles include particles of metals such as gold, silver, and copper, carbon black, titanium oxide, zinc oxide, tin oxide, barium sulfate, aluminum borate, and potassium titanate.

[0128] Here, the method of coating the surface of the core material with a coating resin includes a method of coating with a solution for forming a coating layer in which the coating resin and, if necessary, various additives are dissolved in an appropriate solvent. The solvent is not particularly limited and may be selected taking into consideration the coating resin to be used, its applicability, etc. Specific resin coating methods include an immersion method in which the core material is immersed in a solution for forming a coating layer, a spray method in which the solution for forming a coating layer is sprayed onto the surface of the core material, a fluidized bed method in which the solution for forming a coating layer is sprayed onto the core material while it is suspended in flowing air, and a kneader coater method in which the core material of the carrier and the solution for forming a coating layer are mixed in a kneader coater and the solvent is removed.

[0129] In the two-component developer, the mixing ratio (mass ratio) of toner to carrier is preferably toner:carrier=1:100 to 30:100, and more preferably 3:100 to 20:100.

[0130] <Image forming device / image forming method> An image forming apparatus and an image forming method according to this embodiment will be described. The image forming apparatus according to the present embodiment includes an image carrier, a charging unit that charges the surface of the image carrier, an electrostatic image forming unit that forms an electrostatic image on the surface of the charged image carrier, a developing unit that contains an electrostatic image developer and develops the electrostatic image formed on the surface of the image carrier as a toner image using the electrostatic image developer, a transfer unit that transfers the toner image formed on the surface of the image carrier to the surface of a recording medium, and a fixing unit that fixes the toner image transferred to the surface of the recording medium. The electrostatic image developer according to the present embodiment is used as the electrostatic image developer.

[0131] The image forming apparatus according to this embodiment carries out an image forming method (the image forming method according to this embodiment) that includes a charging step of charging the surface of an image carrier, an electrostatic image forming step of forming an electrostatic image on the surface of the charged image carrier, a developing step of developing the electrostatic image formed on the surface of the image carrier as a toner image using the electrostatic image developer according to this embodiment, a transfer step of transferring the toner image formed on the surface of the image carrier to the surface of a recording medium, and a fixing step of fixing the toner image transferred to the surface of the recording medium.

[0132] The image forming apparatus according to the present embodiment may be any of known image forming apparatuses, such as a direct transfer type apparatus that directly transfers a toner image formed on the surface of an image carrier to a recording medium; an intermediate transfer type apparatus that primarily transfers a toner image formed on the surface of an image carrier to the surface of an intermediate transfer medium, and then secondarily transfers the toner image transferred to the surface of the intermediate transfer medium to the surface of a recording medium; an apparatus equipped with a cleaning means that cleans the surface of the image carrier after the transfer of the toner image but before charging; and an apparatus equipped with a discharging means that irradiates the surface of the image carrier with discharging light to discharge it after the transfer of the toner image but before charging. In the case of an intermediate transfer type device, the transfer means is configured to have, for example, an intermediate transfer body onto whose surface a toner image is transferred, a primary transfer means which primarily transfers the toner image formed on the surface of the image carrier onto the surface of the intermediate transfer body, and a secondary transfer means which secondarily transfers the toner image transferred onto the surface of the intermediate transfer body onto the surface of the recording medium.

[0133] In the image forming apparatus according to the present embodiment, for example, a portion including the developing means may have a cartridge structure (process cartridge) that is detachably attached to the image forming apparatus. As the process cartridge, for example, a process cartridge equipped with developing means that accommodates the electrostatic image developer according to the present embodiment is preferably used.

[0134] An example of an image forming apparatus according to the present embodiment will be described below, but the present invention is not limited to this. Note that only the main parts shown in the drawings will be described, and descriptions of other parts will be omitted.

[0135] FIG. 1 is a schematic diagram showing the configuration of an image forming apparatus according to this embodiment. The image forming apparatus shown in Figure 1 includes first through fourth electrophotographic image forming units 10Y, 10M, 10C, and 10K (image forming means) that output images in the colors yellow (Y), magenta (M), cyan (C), and black (K) based on color-separated image data. These image forming units (hereinafter sometimes simply referred to as "units") 10Y, 10M, 10C, and 10K are arranged side by side horizontally spaced a predetermined distance apart from one another. Note that these units 10Y, 10M, 10C, and 10K may also be process cartridges that are detachable from the image forming apparatus.

[0136] Above each of the units 10Y, 10M, 10C, and 10K in the drawing, an intermediate transfer belt 20 serving as an intermediate transfer body extends through each unit. The intermediate transfer belt 20 is wound around a drive roll 22 and a support roll 24 that are spaced apart from each other and arranged from left to right in the drawing, and is configured to run in a direction from the first unit 10Y to the fourth unit 10K. A force is applied to the support roll 24 in a direction away from the drive roll 22 by a spring or the like (not shown), thereby applying tension to the intermediate transfer belt 20 wound around them. In addition, an intermediate transfer body cleaning device 30 is provided on the image carrier side of the intermediate transfer belt 20, facing the drive roll 22. In addition, the developing devices (developing means) 4Y, 4M, 4C, and 4K of the units 10Y, 10M, 10C, and 10K are supplied with toner including four colors of toner, yellow, magenta, cyan, and black, contained in toner cartridges 8Y, 8M, 8C, and 8K, respectively.

[0137] Since the first to fourth units 10Y, 10M, 10C, and 10K have the same configuration, the first unit 10Y, which forms a yellow image and is disposed upstream in the direction of travel of the intermediate transfer belt, will be described here as a representative. Note that parts equivalent to those of the first unit 10Y are given reference numerals with magenta (M), cyan (C), and black (K) instead of yellow (Y), and descriptions of the second to fourth units 10M, 10C, and 10K will be omitted.

[0138] The first unit 10Y has a photoreceptor 1Y that acts as an image carrier. Around the photoreceptor 1Y, there are arranged in this order: a charging roll (an example of a charging means) 2Y that charges the surface of the photoreceptor 1Y to a predetermined potential; an exposure device (an example of an electrostatic image forming means) 3 that exposes the charged surface to a laser beam 3Y based on a color-separated image signal to form an electrostatic image; a developing device (an example of a developing means) 4Y that supplies charged toner to the electrostatic image to develop it; a primary transfer roll 5Y (an example of a primary transfer means) that transfers the developed toner image onto an intermediate transfer belt 20; and a photoreceptor cleaning device (an example of a cleaning means) 6Y that removes toner remaining on the surface of the photoreceptor 1Y after the primary transfer. The primary transfer roll 5Y is disposed inside the intermediate transfer belt 20 and is positioned opposite the photoreceptor 1Y. Furthermore, a bias power supply (not shown) that applies a primary transfer bias is connected to each of the primary transfer rolls 5Y, 5M, 5C, and 5K. Each bias power supply varies the transfer bias applied to each primary transfer roll under the control of a control unit (not shown).

[0139] The operation of forming a yellow image in first unit 10Y will be described below. First, prior to operation, the surface of the photosensitive member 1Y is charged to a potential of −600V to −800V by the charging roll 2Y. The photoconductor 1Y has conductivity (for example, volume resistivity at 20°C: 1×10 -6 The photosensitive layer is formed by laminating a photosensitive layer on a substrate with a resistivity of Ωcm or less. This photosensitive layer normally has a high resistance (the resistance of ordinary resins), but when irradiated with a laser beam 3Y, the resistivity of the irradiated portion changes. Therefore, a laser beam 3Y is output to the charged surface of the photosensitive element 1Y via an exposure device 3 in accordance with image data for yellow sent from a control unit (not shown). The laser beam 3Y is irradiated onto the photosensitive layer on the surface of the photosensitive element 1Y, thereby forming an electrostatic charge image of a yellow image pattern on the surface of the photosensitive element 1Y.

[0140] An electrostatic image is an image formed on the surface of the photosensitive element 1Y by charging it; the laser beam 3Y reduces the resistivity of the irradiated portion of the photosensitive layer, causing the charged charges on the surface of the photosensitive element 1Y to flow, while the charges remain in the portions not irradiated by the laser beam 3Y, forming a so-called negative latent image. The electrostatic image formed on the photoreceptor 1Y is rotated to a predetermined development position as the photoreceptor 1Y travels. At this development position, the electrostatic image on the photoreceptor 1Y is made visible as a toner image (developed image) by the developing device 4Y.

[0141] The developing device 4Y contains an electrostatic image developer containing, for example, at least yellow toner and a carrier. The yellow toner is frictionally charged by stirring inside the developing device 4Y and is held on a developer roll (an example of a developer holder) with a charge of the same polarity (negative polarity) as the charge on the photoreceptor 1Y. As the surface of the photoreceptor 1Y passes through the developing device 4Y, the yellow toner electrostatically adheres to the discharged latent image portion on the surface of the photoreceptor 1Y, and the latent image is developed with the yellow toner. The photoreceptor 1Y with the yellow toner image formed thereon continues to travel at a predetermined speed, and the toner image developed on the photoreceptor 1Y is transported to a predetermined primary transfer position.

[0142] When the yellow toner image on the photoreceptor 1Y is transported to the primary transfer, a primary transfer bias is applied to the primary transfer roll 5Y, and an electrostatic force from the photoreceptor 1Y to the primary transfer roll 5Y acts on the toner image, causing the toner image on the photoreceptor 1Y to be transferred onto the intermediate transfer belt 20. The transfer bias applied at this time has a (+) polarity opposite to the (-) polarity of the toner, and in the first unit 10Y, for example, it is controlled to +10 μA by a control unit (not shown). On the other hand, the toner remaining on the photoreceptor 1Y is removed and collected by the photoreceptor cleaning device 6Y.

[0143] Furthermore, the primary transfer bias applied to the primary transfer rolls 5M, 5C, and 5K of the second unit 10M and subsequent units is also controlled in accordance with the first unit. In this way, the intermediate transfer belt 20 onto which the yellow toner image has been transferred by the first unit 10Y is conveyed sequentially through the second to fourth units 10M, 10C, and 10K, and the toner images of each color are superimposed and transferred.

[0144] The intermediate transfer belt 20, onto which the four-color toner images have been multiplex-transferred through the first to fourth units, reaches a secondary transfer section composed of the intermediate transfer belt 20, a support roll 24 in contact with the inner surface of the intermediate transfer belt, and a secondary transfer roll (an example of a secondary transfer means) 26 arranged on the image bearing surface side of the intermediate transfer belt 20. Meanwhile, recording paper (an example of a recording medium) P is fed via a supply mechanism into the gap between the secondary transfer roll 26 and the intermediate transfer belt 20 at a predetermined timing, and a secondary transfer bias is applied to the support roll 24. The transfer bias applied at this time has a negative polarity, the same as the negative polarity of the toner. Electrostatic force from the intermediate transfer belt 20 toward the recording paper P acts on the toner image, transferring the toner image on the intermediate transfer belt 20 onto the recording paper P. The secondary transfer bias at this time is determined according to resistance detected by resistance detection means (not shown) that detects resistance in the secondary transfer section, and is voltage-controlled.

[0145] Thereafter, the recording paper P is sent to the pressure contact portion (nip portion) of a pair of fixing rolls in a fixing device (an example of fixing means) 28, where the toner image is fixed onto the recording paper P, forming a fixed image.

[0146] Examples of the recording paper P onto which the toner image is transferred include plain paper used in electrophotographic copying machines, printers, etc. In addition to the recording paper P, examples of the recording medium include overhead projector sheets and the like. To further improve the smoothness of the image surface after fixing, it is preferable that the surface of the recording paper P is also smooth. For example, coated paper in which the surface of plain paper is coated with resin or the like, or art paper for printing, is preferably used.

[0147] The recording paper P on which the color image has been fixed is conveyed toward the discharge section, and the series of color image forming operations is completed.

[0148] <Process cartridges / toner cartridges> The process cartridge according to this embodiment will be described. The process cartridge according to this embodiment is a process cartridge that is detachably attached to an image forming apparatus and that contains the electrostatic image developer according to this embodiment and is equipped with a developing means that develops an electrostatic image formed on the surface of an image carrier using the electrostatic image developer into a toner image.

[0149] The process cartridge according to this embodiment is not limited to the above configuration, but may also be configured to include a developing device and, if necessary, at least one other means selected from an image carrier, a charging means, an electrostatic image forming means, and a transfer means.

[0150] An example of a process cartridge according to the present embodiment will be described below, but the present invention is not limited to this. Note that only the main parts shown in the drawings will be described, and descriptions of other parts will be omitted.

[0151] FIG. 2 is a schematic diagram showing the configuration of the process cartridge according to the present embodiment. The process cartridge 200 shown in FIG. 2 is configured to integrally combine and hold a photosensitive member 107 (an example of an image carrier), a charging roll 108 (an example of a charging means) provided around the photosensitive member 107, a developing device 111 (an example of a developing means), and a photosensitive member cleaning device 113 (an example of a cleaning means), which are held by a housing 117 provided with, for example, mounting rails 116 and an opening 118 for exposure, and is made into a cartridge. In FIG. 2, 109 denotes an exposure device (an example of an electrostatic image forming means), 112 denotes a transfer device (an example of a transfer means), 115 denotes a fixing device (an example of a fixing means), and 300 denotes recording paper (an example of a recording medium).

[0152] Next, the toner cartridge according to this embodiment will be described. The toner cartridge according to the present embodiment is a toner cartridge that contains the toner according to the present embodiment and is detachably attached to an image forming apparatus. The toner cartridge contains replenishment toner to be supplied to a developing unit provided in the image forming apparatus.

[0153] 1 is an image forming apparatus having a configuration in which toner cartridges 8Y, 8M, 8C, and 8K can be attached and detached, and developing devices 4Y, 4M, 4C, and 4K are connected to the toner cartridges corresponding to each developing device (color) by toner supply pipes (not shown). When the toner stored in a toner cartridge runs low, the toner cartridge is replaced. [Example]

[0154] Examples will be described below, but the present invention is not limited to these examples. In the following description, unless otherwise specified, all "parts" and "%" are by mass.

[0155] [Preparation of release agent particle dispersion] <Preparation of Release Agent Particle Dispersion 1> 500 parts of hydrocarbon wax (Fischer-Tropsch wax, manufactured by Nippon Seiro Co., Ltd., product name: FNP0090, melting temperature Tm: 91°C) Cationic surfactant (quaternary ammonium salts, chemical name: quaternary ammonium salts, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., product name: Catiogen™): 16 parts Ion-exchanged water: 1,700 parts The above materials were mixed and the release agent was heated to an internal liquid temperature of 120°C, and then dispersed in a pressure discharge homogenizer (Gaulin Homogenizer manufactured by Gaulin) at a dispersion pressure of 5 MPa for 120 minutes, then at 40 MPa until the volume average particle size of the release agent particles reached 225 nm, and then cooled to obtain a dispersion. Ion-exchanged water was added to adjust the solid content to 20 mass%, and this was named release agent particle dispersion 1. The volume average particle size of the release agent particles in release agent particle dispersion 1 was 225 nm.

[0156] <Preparation of Release Agent Particle Dispersions 2 and 3> Release agent particle dispersions 2 and 3 were obtained in the same manner as release agent particle dispersion 1, except that the amount of cationic surfactant added was changed as shown in Table 1. The volume average particle size of the release agent particles in release agent particle dispersions 2 and 3 was all 225 nm.

[0157] <Preparation of Release Agent Particle Dispersion 4> Release agent particle dispersion liquid 4 was obtained in the same manner as release agent particle dispersion liquid 1, except that 20 parts of an anionic surfactant (sulfonate salts, compound name: sodium dodecylbenzenesulfonate, manufactured by Dai-ichi Kogyo Seiyaku, product name: NEOGEN RK) was used instead of the cationic surfactant. The volume average particle size of the release agent particles in release agent particle dispersion liquid 4 was 225 nm.

[0158] <Preparation of Release Agent Particle Dispersion 5> Release agent particle dispersion liquid 5 was obtained in the same manner as release agent particle dispersion liquid 2, except that 500 parts of an ester wax (manufactured by NOF Corporation, product name: WEP-5, melting temperature Tm: 85°C) was used instead of paraffin wax FNP0090. The volume average particle size of the release agent particles in release agent particle dispersion liquid 5 was 225 nm.

[0159] <Preparation of Release Agent Particle Dispersion 6> Release agent particle dispersion liquid 6 was obtained in the same manner as release agent particle dispersion liquid 5, except that 20 parts of an anionic surfactant (sulfonate salts, compound name: sodium dodecylbenzenesulfonate, manufactured by Dai-ichi Kogyo Seiyaku, product name: NEOGEN RK) was used instead of the cationic surfactant. The volume average particle size of the release agent particles in release agent particle dispersion liquid 6 was 225 nm.

[0160] [Table 1]

[0161] [Preparation of resin particle dispersion] <Styrene acrylic resin particle dispersion A> (Preparation of styrene acrylic resin particle dispersion A) A surfactant solution was prepared by dissolving 7 parts by mass of an anionic surfactant (sodium dodecyl sulfate) in 3,000 parts of ion-exchanged water in a reaction vessel equipped with a stirrer, temperature control, cooling tube, and nitrogen introduction device. The temperature inside the reaction vessel was raised to 80°C while stirring this surfactant solution at a stirring speed of 230 rpm under a nitrogen stream. Next, a polymerization initiator solution prepared by dissolving 9.2 parts of a polymerization initiator (potassium persulfate (KSP)) in 200 parts of ion-exchanged water was added to the surfactant solution, and the temperature inside the reaction vessel was raised to 75°C. Then, a mixed solution (1) containing the following components was added dropwise over 1 hour. Styrene: 69.4 parts n-Butyl acrylate: 28.3 parts Methacrylic acid: 2.3 parts Furthermore, the solution after dropwise addition of the mixed liquid (1) was stirred at 75°C for 5 hours to polymerize, thereby preparing a styrene-acrylic resin particle dispersion liquid A in which the styrene-acrylic resin particles A were dispersed, and ion-exchanged water was added to adjust the solid content to 20 mass%. The styrene acrylic resin particles A had a weight average molecular weight of 5,500 and a volume average particle size of 105 nm.

[0162] <Amorphous polyester resin particle dispersion B> (Preparation of amorphous polyester resin B) Terephthalic acid: 70 parts Fumaric acid: 30 parts Ethylene glycol: 41 parts 1,5-pentanediol: 48 parts The above materials were placed in a 5-liter flask equipped with a stirrer, nitrogen inlet tube, temperature sensor, and distillation column. The temperature was raised to 220°C over 1 hour under a nitrogen gas stream, and 1 part of titanium tetraethoxide was added for every 100 parts of the above materials. The temperature was raised to 240°C over 0.5 hours while distilling off the resulting water. The dehydration condensation reaction was continued at that temperature for 1 hour, and then the reaction mixture was cooled. In this way, amorphous polyester resin B with a weight-average molecular weight of 96,000 and a glass transition temperature of 61°C was synthesized.

[0163] (Preparation of amorphous polyester resin particle dispersion B) A vessel equipped with a temperature control device and a nitrogen purge device was charged with 40 parts of ethyl acetate and 25 parts of 2-butanol to form a mixed solvent. Then, 100 parts of amorphous polyester resin B was gradually added and dissolved. A 10% by mass aqueous ammonia solution (equivalent to three times the molar amount of the resin's acid value) was added and stirred for 30 minutes. The atmosphere inside the vessel was then purged with dry nitrogen, the temperature was maintained at 40°C, and 400 parts of ion-exchanged water was added dropwise at a rate of 2 parts / min while stirring the mixed solution, resulting in emulsification. After the addition was completed, the emulsion was returned to 25°C, yielding a resin particle dispersion in which amorphous polyester resin particles B with a volume average particle size of 190 nm were dispersed. Ion-exchanged water was added to the resin particle dispersion to adjust the solids content to 20% by mass, yielding amorphous polyester resin particle dispersion B.

[0164] <Crystalline polyester resin particle dispersion C> (Preparation of Crystalline Polyester Resin C) 1,10-decanedicarboxylic acid: 265 parts 1,6-Hexanediol: 168 parts Dibutyltin oxide (catalyst): 0.3 parts by mass The above ingredients were placed in a heated and dried three-necked flask, and the air inside the vessel was evacuated to an inert atmosphere with nitrogen gas. The mixture was then mechanically stirred and refluxed at 180°C for 5 hours. The temperature was then gradually increased to 230°C under reduced pressure and stirred for 2 hours. When the mixture became viscous, it was air-cooled to terminate the reaction. Molecular weight measurement (polystyrene equivalent) showed that the weight-average molecular weight (Mw) of the resulting "Crystalline Polyester Resin C" was 12,700, and the melting temperature was 73°C.

[0165] (Preparation of Crystalline Polyester Resin Particle Dispersion C) 90 parts by mass of crystalline polyester resin C, 1.8 parts by mass of ionic surfactant Neogen RK (Dai-ichi Kogyo Seiyaku), and 210 parts by mass of ion-exchanged water were heated to 120°C and thoroughly dispersed using an IKA Ultra-Turrax T50.Then, a dispersion process was carried out for 1 hour using a pressure discharge Gaulin homogenizer to obtain crystalline polyester resin particle dispersion C having a volume average particle size of 190 nm and a solid content of 20% by mass.

[0166] [Preparation of colorant particle dispersion] Carbon black (Cabot, Regal 330): 50 parts Ionic surfactant Neogen RK (Dai-ichi Kogyo Seiyaku): 5 parts Ion-exchanged water: 193 parts The above components were mixed and treated for 60 minutes at 240 MPa using an Ultimizer (manufactured by Sugino Machine Co., Ltd.) to prepare a colorant particle dispersion (solid content concentration: 20% by mass).

[0167] [Toner particle production] Example 1 Styrene acrylic resin particle dispersion A: 360 parts Amorphous polyester resin particle dispersion B: 40 parts Crystalline polyester resin particle dispersion C: 40 parts Colorant particle dispersion: 250 parts Ion-exchanged water: 1,100 parts The above components and 350 parts of release agent particle dispersion 3 were thoroughly mixed and dispersed in a round stainless steel flask using an Ultra-Turrax T50 to obtain a solution. Next, 50 parts by mass of a 1% by mass aqueous solution of aluminum sulfate was added to this solution to prepare first agglomerated particles, which are core agglomerated particles, and the first agglomerated particles were dispersed using an Ultra-Turrax at 7,000 rpm for 5 minutes. The solution in the flask was further heated to 52°C while stirring in a heating oil bath, and after maintaining at 52°C for 60 minutes, a mixture of 130 parts of amorphous polyester resin particle dispersion B, 150 parts of release agent particle dispersion 4, and 100 parts of ion-exchanged water was added thereto over 10 minutes to produce secondary aggregated particles having a core-shell structure. Subsequently, a 0.5 Mol / L aqueous solution of sodium hydroxide was added to adjust the pH of the solution to 8.5, and the stainless steel flask was then sealed. The mixture was heated to 98°C with continuous stirring using a magnetic seal, held for 30 minutes, and then cooled to 90°C over 15 minutes. The temperature was then lowered to 30°C in cold water at a rate of 8°C / min, yielding black toner particles with a volume average particle size of 6.1 μm. The styrene content ("styrene amount" in the table) and Tm-Tg of the obtained toner particles are shown in Table 2.

[0168] <Examples 2 to 6> Black toner particles were obtained in the same manner as in Example 1, except that the type and amount of release agent particle dispersion used in preparing the first aggregated particles were changed from 3 and 350 parts of release agent particle dispersion to the type and amount shown in Table 2 ("WAX (core)" in the table), and the type and amount of release agent particle dispersion used in preparing the second aggregated particles was changed from 4 and 5 parts of release agent particle dispersion to the type and amount shown in Table 2 ("WAX (shell)" in the table). Table 2 shows the volume average particle size ("toner particle size" in the table), styrene content ("styrene amount" in the table), and Tm-Tg of the obtained toner particles.

[0169] Example 7 A black toner was obtained in the same manner as in Example 4, except that the amount of styrene acrylic resin particle dispersion A added was changed from 360 parts to 400 parts, the amount of amorphous polyester resin particle dispersion B added was changed from 40 parts to 20 parts, and the amount of crystalline polyester resin particle dispersion C added was changed from 40 parts to 20 parts. Table 2 shows the volume average particle size ("toner particle size" in the table), styrene content ("styrene amount" in the table), and Tm-Tg of the obtained toner particles.

[0170] Example 8 A black toner was obtained in the same manner as in Example 4, except that the amount of styrene acrylic resin particle dispersion A added was changed from 360 parts to 320 parts, the amount of amorphous polyester resin particle dispersion B added was changed from 40 parts to 60 parts, and the amount of crystalline polyester resin particle dispersion C added was changed from 40 parts to 60 parts. Table 2 shows the volume average particle size ("toner particle size" in the table), styrene content ("styrene amount" in the table) and Tm-Tg of the obtained toner particles.

[0171] <Comparative Examples 1 to 3> Black toner particles were obtained in the same manner as in Example 1, except that the type and amount of release agent particle dispersion used in preparing the first aggregated particles were changed from 3 and 350 parts of release agent particle dispersion to the type and amount shown in Table 2 ("WAX (core)" in the table), and the type and amount of release agent particle dispersion used in preparing the second aggregated particles was changed from 4 and 5 parts of release agent particle dispersion to the type and amount shown in Table 2 ("WAX (shell)" in the table). Table 2 shows the volume average particle size ("toner particle size" in the table), styrene content ("styrene amount" in the table), and Tm-Tg of the obtained toner particles.

[0172] <Measurement of release agent domain> The area fraction Sa / St, area fraction Sb / St, area fraction Sc / St, area fraction Sw / St, Na, Nb, Nc, and average circularity of the large diameter domains ("Circularity" in the table) of the obtained toner particles were determined using the above-mentioned methods. The results are shown in Table 3.

[0173] [Toner production] 100 parts of the obtained toner particles and 0.7 parts of dimethylsilicone oil-treated silica particles (RY200 manufactured by Nippon Aerosil Co., Ltd.) were mixed in a Henschel mixer to obtain a toner.

[0174] [Preparation of developer] 8 parts of the obtained toner and 100 parts of the following carrier were mixed to obtain a developer.

[0175] -Creating a carrier- Ferrite particles (average particle size 50 μm) 100 parts Toluene 14 parts Styrene / methyl methacrylate copolymer (copolymerization ratio 15 / 85) 3 parts Carbon black 0.2 parts The above components except for the ferrite particles were dispersed in a sand mill to prepare a dispersion liquid, and this dispersion liquid was placed in a vacuum degassing kneader together with the ferrite particles, and the mixture was stirred under reduced pressure and dried to obtain a carrier.

[0176] [evaluation] <Evaluation of image density> Using the resulting developer, 50,000 test chart images with 5% area coverage were printed on A4-size coated paper in a modified DocuCentre Color 400 (manufactured by Fujifilm Business Innovation Co., Ltd.) under a low-temperature, low-humidity environment (room temperature 10°C, relative humidity 15%). The difference in image density between the 1,000th and 50,000th prints was calculated and evaluated. Specifically, a spectrophotometer (X-Rite Ci62, manufactured by X-Rite) was used to measure the L*, a*, and b* values ​​at three random locations in the image. The color difference ΔE was calculated and evaluated as follows: A through D were considered acceptable. The results are shown in Table 3. -Evaluation criteria- A: Color difference ΔE is 1 or less, so there is no problem. B: Color difference ΔE is greater than 1 and less than 2. The density difference is slight and poses no problem. C: Color difference ΔE is more than 2 and not more than 3. There is a density difference, but it is acceptable. D: Color difference ΔE is more than 3 and not more than 5. There is a density difference, but it is acceptable. E: Color difference ΔE is more than 5. Problematic.

[0177] <Evaluation of fixation> Using the obtained developer, 10,000 images with an image density of 20% were printed on A4 size J paper (manufactured by Fuji Xerox Co., Ltd.) in an environment of 28°C and 85% RH using a modified DocuCentre Color 400 manufactured by Fujifilm Business Innovation Co., Ltd. The fixing temperature was 180°C. The image on the 10,000th sheet was visually inspected, and the presence or absence of offset was evaluated according to the following evaluation criteria. A to C were considered to be within the acceptable range. The results are shown in Table 3. -Evaluation criteria- A: It cannot be confirmed. B: Offset of less than 1% of the image area. C: Offset of 1% or more but less than 10% of the image area. D: Offset of 10% or more but less than 15% of the image area. E: There is an offset of 15% or more of the image area.

[0178] [Table 2]

[0179] [Table 3]

[0180] From the above results, it can be seen that the toner of this example achieves both good releasability of fixed images and suppression of a decrease in image density when images are continuously formed in a low-temperature, low-humidity environment. [Explanation of symbols]

[0181] 1Y, 1M, 1C, 1K Photoconductor (an example of an image carrier) 2Y, 2M, 2C, 2K Charging roll (an example of charging means) 3. Exposure device (an example of an electrostatic image forming means) 3Y, 3M, 3C, 3K laser beam 4Y, 4M, 4C, 4K developing device (an example of developing means) 5Y, 5M, 5C, 5K Primary transfer roll (an example of a primary transfer means) 6Y, 6M, 6C, 6K: Photoconductor cleaning device (an example of a cleaning means) 8Y, 8M, 8C, 8K toner cartridges 10Y, 10M, 10C, 10K image forming units 20 Intermediate transfer belt (an example of an intermediate transfer body) 22 Drive Roll 24 Support Roll 26 Secondary transfer roll (an example of a secondary transfer means) 28 Fixing device (an example of fixing means) 30 Intermediate transfer body cleaning device 107 Photosensitive body (an example of an image carrier) 108 Charging roll (an example of charging means) 109 Exposure device (an example of electrostatic image forming means) 111 Developing device (an example of developing means) 112 Transfer device (an example of transfer means) 113 Photosensitive drum cleaning device (an example of cleaning means) 115 Fixing device (an example of fixing means) 116 Mounting Rail 117 Cabinet 118 Exposure opening 200 Process Cartridge 300 Recording paper (an example of a recording medium) P Recording paper (an example of a recording medium)

Claims

1. Toner particles containing a binder resin and a release agent, the binder resin contains a styrene (meth)acrylic resin, a content of units derived from a monomer having a styrene skeleton relative to the total amount of the toner particles is 15% by mass or more and 25% by mass or less; the toner particles have an area fraction Sa / St of 2% or more and an area fraction Sb / St of 20% or more, where St is the area of ​​the entire cross section of the toner particle, Sa is the total area of ​​the cross sections of domains of the release agent whose major axes are 10 nm or more and 500 nm or less, and Sb is the total area of ​​the cross sections of domains of the release agent whose major axes are 1500 nm or more and 3000 nm or less, the toner particles have a core-shell structure, the core portion contains a domain having a major axis of 10 nm or more and 500 nm or less, and the shell portion contains a domain having a major axis of 1500 nm or more and 3000 nm or less, The toner for developing electrostatic images satisfies the condition that the area fraction Sa / St is equal to or less than the area fraction Sb / St.

2. 2. The toner for developing electrostatic images according to claim 1, wherein the ratio Sb / Sa of Sb to Sa is 1 or more and 20 or less.

3. 3. The toner for developing electrostatic images according to claim 1, wherein the area ratio Sa / St is 20% or less and the area ratio Sb / St is 40% or less.

4. Toner particles containing a binder resin and a release agent, the binder resin contains a styrene (meth)acrylic resin, a content of units derived from a monomer having a styrene skeleton relative to the total amount of the toner particles is 15% by mass or more and 25% by mass or less; the number of domain cross sections of the release agent having a major axis of 10 nm or more and 500 nm or less is defined as Na, and the number of domain cross sections of the release agent having a major axis of 1500 nm or more and 3000 nm or less is defined as Nb, the number of Na is 15 or more and the number of Nb is 3 or more, the toner particles have a core-shell structure, the core portion contains a domain having a major axis of 10 nm or more and 500 nm or less, and the shell portion contains a domain having a major axis of 1500 nm or more and 3000 nm or less, In the cross section of the toner particle, when the area of ​​the entire cross section of the toner particle is St, the total area of ​​the cross sections of the domains of the release agent whose major axis is 10 nm or more and 500 nm or less is Sa, and the total area of ​​the cross sections of the domains whose major axis is 1500 nm or more and 3000 nm or less is Sb, The toner for developing electrostatic images satisfies the condition that the area fraction Sa / St is equal to or less than the area fraction Sb / St.

5. 5. The toner for developing electrostatic images according to claim 4, wherein the ratio of said Nb to said Na, Nb / Na, is 0.05 or more and 0.30 or less.

6. 6. The toner for developing electrostatic images according to claim 4, wherein the number of Na atoms is 45 or less and the number of Nb atoms is 5 or less.

7. 7. The toner for developing electrostatic images according to claim 1, wherein, in a cross section of the toner particle, an area fraction Sw / St is 30% or more and 50% or less, where St is an area of ​​the entire cross section of the toner particle and Sw is a total area of ​​the cross sections of the domains of the release agent.

8. 8. The toner for developing electrostatic images according to claim 1, wherein the average circularity of cross sections of the domains having a major axis of 1500 nm or more and 3000 nm or less is 0.6 or more.

9. 9. The toner for developing electrostatic images according to claim 1, wherein the release agent has a melting temperature Tm of 65° C. or higher and 95° C. or lower.

10. 10. The toner for developing electrostatic images according to claim 9, wherein the release agent is an ester wax.

11. 11. The toner for developing electrostatic images according to claim 1, wherein a difference Tm-Tg between a melting temperature Tm of the release agent and a glass transition temperature Tg of the binder resin is 15° C. or more and 30° C. or less.

12. 12. The toner for developing electrostatic images according to claim 1, wherein the toner particles contain a cationic surfactant and an anionic surfactant.

13. 13. The toner for developing electrostatic images according to claim 12, wherein the cationic surfactant is a quaternary ammonium salt, and the anionic surfactant is a sulfonate.

14. An electrostatic image developer comprising the toner for developing electrostatic images according to any one of claims 1 to 13.

15. A toner for developing electrostatic images according to any one of claims 1 to 13 is contained therein, A toner cartridge that is detachably attached to an image forming device.

16. a developing unit containing the electrostatic image developer according to claim 14 and developing an electrostatic image formed on the surface of an image carrier into a toner image by using the electrostatic image developer, A process cartridge is detachably mounted in an image forming apparatus.

17. an image carrier; a charging means for charging the surface of the image carrier; an electrostatic image forming means for forming an electrostatic image on the charged surface of the image carrier; a developing unit containing the electrostatic image developer according to claim 14 and developing the electrostatic image formed on the surface of the image carrier into a toner image by using the electrostatic image developer; a transfer means for transferring the toner image formed on the surface of the image carrier to the surface of a recording medium; a fixing means for fixing the toner image transferred onto the surface of the recording medium; An image forming apparatus comprising:

18. a charging step of charging the surface of the image carrier; an electrostatic image forming step of forming an electrostatic image on the charged surface of the image carrier; a developing step of developing the electrostatic image formed on the surface of the image carrier into a toner image by using the electrostatic image developer according to claim 14; a transfer step of transferring the toner image formed on the surface of the image carrier to the surface of a recording medium; a fixing step of fixing the toner image transferred onto the surface of the recording medium; An image forming method comprising the steps of:

Images