Water- and oil-repellent treatment agent for fabric, and fabric

Abstract

Provided is a water-repellent and oil-repellent treatment agent for fabric including a chlorinated polyolefin composite acrylic resin (A) having a chlorinated polyolefin resin (a1) and an acrylic polymer (a2), an aqueous medium (B), and a modified silicone oil (C), said treatment agent being characterized in that the modified silicone oil (C) includes an amino-modified silicone oil (c1) and a polyether-modified silicone oil (c2). The water-repellent and oil-repellent treatment agent for fabric can impart excellent water repellency and oil repellency to a base material, and therefore can be suitably used as a water-repellent and oil-repellent treatment agent for fabric comprising fibers such as cotton, silk, wool, hemp, polyethylene, nylon, polyester, polyurethane, and rayon.

Description

[Technical Field]

[0001] The present invention relates to a water- and oil-repellent treating agent for fabrics, and to fabrics. [Background technology]

[0002] Conventionally, textile products have been known in which water repellency has been imparted to the surface by treating the textile product with a fluorine-based water repellent agent. However, fluorine compounds have concerns about their environmental impact and require heat treatment at high temperatures during use, and therefore, treatment agents that do not contain fluorine compounds have been investigated.

[0003] In this situation, a water- and oil-repellent treating agent for fabrics has been proposed, which contains a polyolefin resin, a polyolefin-composite acrylic resin having an acrylic polymer, and an aqueous medium (see, for example, Patent Document 1).

[0004] However, although this water- and oil-repellent treatment agent has excellent water repellency, it has the problem of insufficient oil repellency. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Publication No. 2022-62389 Summary of the Invention [Problem to be solved by the invention]

[0006] The problem to be solved by the present invention is to provide a water- and oil-repellent treating agent for fabrics that does not contain fluorine compounds that are of concern for their environmental impact and that is capable of exhibiting excellent water- and oil-repellency. [Means for solving the problem]

[0007] As a result of intensive research conducted by the present inventors to solve the above-mentioned problems, they have found that a water- and oil-repellent treating agent for fabrics containing a chlorinated polyolefin-composite acrylic resin, an aqueous medium, and a specific modified silicone can solve the above-mentioned problems.

[0008] That is, the present invention relates to a water- and oil-repellent treatment agent for fabrics, which contains a chlorinated polyolefin composite acrylic resin (A) having a chlorinated polyolefin resin (a1) and an acrylic polymer (a2), an aqueous medium (B), and a modified silicone oil (C), wherein the modified silicone oil (C) contains an amino-modified silicone oil (c1) and a polyether-modified silicone oil (c2). [Effects of the Invention]

[0009] The water- and oil-repellent treating agent for fabrics of the present invention can impart excellent water and oil repellency to a substrate, and therefore can be suitably used as a water- and oil-repellent treating agent for fabrics made of fibers such as cotton, silk, wool, hemp, polyethylene, nylon, polyester, polyurethane, and rayon. DETAILED DESCRIPTION OF THE INVENTION

[0010] The water- and oil-repellent treatment agent for fabrics of the present invention comprises a chlorinated polyolefin composite acrylic resin (A) having a chlorinated polyolefin resin (a1) and an acrylic polymer (a2), an aqueous medium (B), and a modified silicone oil (C), wherein the modified silicone oil (C) comprises an amino-modified silicone oil (c1) and a polyether-modified silicone oil (c2).

[0011] The chlorinated polyolefin resin (a1) is a chlorinated polyolefin resin, and examples of the polyolefin resin include polypropylene, high-density polyethylene, ultra-high molecular weight polyethylene, linear low-density polyethylene, low-density polyethylene, very low-density polyethylene, ultra-ultra-low-density polyethylene, polymethylpentene, ethylene-propylene copolymer, propylene-1-butene random copolymer, propylene-ethylene-1-butene random copolymer, copolymers of propylene and an α-olefin having 5 to 12 carbon atoms, propylene-non-conjugated diene copolymer, ethylene-non-conjugated diene copolymer, ethylene-propylene-non-conjugated diene copolymer, polybutene, ethylene-vinyl acetate copolymer, ethylene-vinyltrimethoxysilane copolymer, ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methyl methacrylate copolymer, styrene-butadiene block copolymer, and hydrogenated products thereof. The chlorinated polyolefin resin (a1) may be partially modified with maleic acid.

[0012] The chlorinated polyolefin resin (a1) may be used alone or in combination of two or more kinds, but preferably contains a chlorinated polypropylene resin.

[0013] The degree of chlorination of the polyolefin resin (a1) is preferably from 15 to 35%, more preferably from 25 to 35%, since this further improves the balance between water dispersibility and oil repellency.

[0014] The softening point of the chlorinated polyolefin resin (a1) is preferably 50 to 75°C for ease of synthesis, and more preferably 50 to 70°C for improved water dispersibility of the resin.

[0015] The acrylic polymer (a2) can be obtained by polymerizing a (meth)acrylic monomer and, if necessary, other unsaturated monomers.

[0016] Examples of the (meth)acrylic monomer include (meth)acrylates having 3 or less carbon atoms, such as methyl (meth)acrylate, ethyl (meth)acrylate, and propyl (meth)acrylate; (meth)acrylates having a cyclic or linear alkyl group having 4 or more carbon atoms, such as n-butyl (meth)acrylate, isobutyl (meth)acrylate, t-butyl (meth)acrylate, cyclohexyl (meth)acrylate, hexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isobornyl (meth)acrylate, lauryl (meth)acrylate, and stearyl (meth)acrylate; (meth)acrylamide, glycidyl (meth)acrylate, 2-methyl (meth)acrylate, and the like. Examples of the (meth)acrylate include (meth)acrylates having functional groups such as aminoethyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, γ-methacryloxypropyltrimethoxysilane, benzyl (meth)acrylate, diethylene glycol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, and glycerin di(meth)acrylate; (meth)acrylic acid, etc. These (meth)acrylic monomers can be used alone or in combination of two or more, but it is preferable to use the (meth)acrylates having 3 or less carbon atoms and the (meth)acrylates having a cyclic or linear alkyl group having 4 or more carbon atoms in combination. It is also preferable to use a monomer having a carboxyl group, such as the above-mentioned (meth)acrylic acid or an unsaturated carboxylic acid described below.

[0017] Examples of the other unsaturated monomer include styrene compounds such as styrene, α-methylstyrene, paramethylstyrene, and chloromethylstyrene; and unsaturated carboxylic acids such as maleic acid (anhydride), fumaric acid, citraconic acid (anhydride), mesaconic acid (anhydride), itaconic acid (anhydride), and aconitic acid (anhydride). These other monomers can be used alone or in combination of two or more.

[0018] The acid value of the acrylic polymer (a2) may be from 1 to 15 mgKOH / g, or may be from 3 to 12 mgKOH / g.

[0019] In the present invention, "(meth)acrylate" refers to either or both of methacrylate and acrylate, "(meth)acrylic acid" refers to either or both of methacrylic acid and acrylic acid, and "(meth)maleic anhydride" refers to either or both of maleic anhydride and maleic acid.

[0020] In the chlorinated polyolefin composite acrylic resin (A), the mass ratio (a1 / a2) of the chlorinated polyolefin resin (a1) to the acrylic polymer (a2) is preferably 5 / 95 to 40 / 60, more preferably 5 / 95 to 30 / 70, since this further improves the balance between water repellency and oil repellency.

[0021] As a method for producing the chlorinated polyolefin composite acrylic resin (A), the underwater polymerization method or emulsion polymerization method is preferred because the chlorinated polyolefin composite acrylic resin (A) can be easily obtained.

[0022] An example of a method for obtaining the chlorinated polyolefin composite acrylic resin (A) by emulsion polymerization is a method in which the monomer raw materials for the acrylic polymer (a2) are radically polymerized in an aqueous medium in the presence of the chlorinated polyolefin resin (a1), an emulsifier, and a polymerization initiator at a temperature of 50 to 100°C.

[0023] Examples of the emulsifier include sulfate esters of higher alcohols and their salts, alkylbenzene sulfonates, polyoxyethylene alkylphenyl sulfonates, polyoxyethylene alkyl diphenyl ether ... Examples of emulsifiers include anionic emulsifiers such as sulfuric acid half ester salts of alkyl ethers, alkyl diphenyl ether disulfonates, and dialkyl succinate sulfonates; nonionic emulsifiers such as polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene diphenyl ethers, polyoxyethylene-polyoxypropylene block copolymers, and acetylene diols; cationic emulsifiers such as alkyl ammonium salts; and amphoteric emulsifiers such as alkyl (amido) betaines and alkyl dimethyl amine oxides. These emulsifiers can be used alone or in combination of two or more.

[0024] Examples of the polymerization initiator include azo compounds such as 2,2'-azobis(isobutyronitrile), 2,2'-azobis(2-methylbutyronitrile), and azobiscyanovaleric acid; organic peroxides such as tert-butyl peroxypivalate, tert-butyl peroxybenzoate, tert-butylperoxy-2-ethylhexanoate, di-tert-butyl peroxide, cumene hydroperoxide, benzoyl peroxide, and tert-butyl hydroperoxide; and inorganic peroxides such as hydrogen peroxide, ammonium persulfate, potassium persulfate, and sodium persulfate. These polymerization initiators can be used alone or in combination. These polymerization initiators are preferably used in an amount of 0.1 to 10% by mass relative to the total amount of the monomers used as raw materials for the polymer.

[0025] Since the dispersion stability of the chlorinated polyolefin-composite acrylic resin (A) is further improved, it is preferable to adjust the pH with a basic compound and / or an acidic compound. Examples of the basic compound include organic amines such as methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, 2-aminoethanol, and 2-dimethylaminoethanol; inorganic basic compounds such as ammonia (water), sodium hydroxide, and potassium hydroxide; and quaternary ammonium hydroxides such as tetramethylammonium hydroxide, tetra-n-butylammonium hydroxide, and trimethylbenzylammonium hydroxide. These basic compounds can be used alone or in combination of two or more.

[0026] Examples of the acidic compound include carboxylic acid compounds such as formic acid, acetic acid, propionic acid, and lactic acid; monoesters or diesters of phosphoric acid such as monomethyl phosphate and dimethyl phosphate; organic sulfonic acid compounds such as methanesulfonic acid, benzenesulfonic acid, and dodecylbenzenesulfonic acid; and inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid, and phosphoric acid. Among these, carboxylic acid compounds are preferred. These acidic compounds can be used alone or in combination of two or more.

[0027] Examples of the aqueous medium (B) include water, organic solvents miscible with water, and mixtures thereof. Examples of water-miscible organic solvents include alcohols such as methanol, ethanol, n-propanol, and isopropanol; ketones such as acetone and methyl ethyl ketone; polyalkylene glycols such as ethylene glycol, diethylene glycol, and propylene glycol; alkyl ethers of polyalkylene glycols; and lactams such as N-methyl-2-pyrrolidone. In the present invention, water alone may be used, or a mixture of water and an organic solvent miscible with water may be used, or a water-miscible organic solvent alone may be used. From the standpoints of safety and environmental impact, water alone or a mixture of water and an organic solvent miscible with water is preferred, and using water alone is particularly preferred.

[0028] As the aqueous medium (B), it is simple and preferable to use the aqueous medium used when producing the chlorinated polyolefin composite acrylic resin (A) by the in-water polymerization method and emulsion polymerization method as it is.

[0029] The water- and oil-repellent treating agent for fabrics of the present invention contains the chlorinated polyolefin-composite acrylic resin (A) and the aqueous medium (B). Preferably, the water- and oil-repellent treating agent is obtained by diluting with water an aqueous dispersion in which the chlorinated polyolefin-composite acrylic resin (A) is dispersed in the aqueous medium (B), the aqueous dispersion being obtained by an emulsion polymerization method or the like.

[0030] Furthermore, if necessary, the amount of organic solvent in the water- and oil-repellent treating agent for fabric of the present invention can be reduced by carrying out a solvent removal step.

[0031] The modified silicone oil (C) includes an amino-modified silicone oil (c1) and a polyether-modified silicone oil (c2).

[0032] The amino-modified silicone oil (c1) is a silicone having an amino group, and is preferably a silicone oil having an aminopropyl group or an iminopropyl group, more preferably a silicone oil having an iminopropyl group.

[0033] The functional group equivalent weight of the amino-modified silicone oil (c1) is preferably 1,000 to 7,000.

[0034] The polyether-modified silicone oil (c2) is a silicone having a polyether structure, and the HLB of the polyether-modified silicone oil (c2) is preferably 5-13.

[0035] In the modified silicone oil (C), the mass ratio (c1 / c2) of the amino-modified silicone oil (c1) to the polyether-modified silicone oil (c2) is preferably 10 / 90 to 90 / 10, more preferably 20 / 80 to 80 / 20.

[0036] The content of the amino-modified silicone oil (c1) is preferably 0.5 to 25 mass %, more preferably 2 to 20 mass %, relative to 100 mass of the acrylic polymer (A), because this further improves the balance between water repellency and oil repellency.

[0037] The content of the polyether-modified silicone oil (c2) is preferably 100% by mass of the acrylic polymer (A) because the balance between water repellency and oil repellency is further improved. department The content is preferably 0.5 to 25 mass %, more preferably 2 to 20 mass %.

[0038] The water- and oil-repellent treating agent for fabric of the present invention may also contain silicone oils other than the modified silicone oil (C).

[0039] The content of the chlorinated polyolefin composite acrylic resin (A) in the water- and oil-repellent treating agent for fabric of the present invention is preferably less than 10% by mass, more preferably less than 3% by mass, and more preferably 0.05% by mass. quality % or more is preferable, and 0.1 quality % or more is more preferable.

[0040] The aqueous medium (B) in the water / oil repellent treatment agent for fabric of the present invention is preferably 90% by mass or more, more preferably 97% or more, and is preferably less than 99.95% by mass, more preferably less than 99.9%.

[0041] Furthermore, the water- and oil-repellent treating agent for fabrics of the present invention may be used in combination with additives such as water repellents, oil repellents, dispersants, curing catalysts, lubricants, fillers, thixotropy-imparting agents, tackifiers, waxes, heat stabilizers, light-resistant stabilizers, fluorescent brighteners, and foaming agents, pH adjusters, leveling agents, antigelling agents, dispersion stabilizers, antioxidants, radical scavengers, heat-resistance-imparting agents, inorganic fillers, organic fillers, plasticizers, reinforcing agents, catalysts, antibacterial agents, mildew inhibitors, rust inhibitors, thermoplastic resins, thermosetting resins, pigments, dyes, conductivity-imparting agents, antistatic agents, moisture permeability improvers, oil repellents, hollow foams, compounds containing crystal water, flame retardants, water absorbents, moisture absorbents, deodorizers, foam stabilizers, antifoaming agents, antifungal agents, preservatives, antialgae agents, pigment dispersants, antiblocking agents, and hydrolysis inhibitors, as needed.

[0042] The water- and oil-repellent treating agent for fabrics of the present invention preferably contains a nonionic dispersant such as polyoxyalkylene alkyl ether, since this makes it possible to make the dispersion state of each component more uniform. These nonionic dispersants can be used alone or in combination of two or more kinds.

[0043] The content of the nonionic dispersant in the water- and oil-repellent treatment agent for fabrics is preferably 0.1 to 10 mass %, more preferably 0.2 to 5 mass %, relative to 100 parts by mass of the chlorinated polyolefin-composite acrylic resin (A), because this makes the dispersion state of each component more uniform.

[0044] Examples of fabrics that can be treated with the water- and oil-repellent treatment agent for fabrics of the present invention include fabrics made of chemical fibers such as nylon, polyester, polyurethane, polypropylene, and rayon, and fabrics made from a blend of two or more of the above chemical fibers. [Example]

[0045] The present invention will be described in more detail below with reference to specific examples.

[0046] (Synthesis Example 1: Synthesis of Water Dispersion (1) of Chlorinated Polyolefin Composite Acrylic Resin) Into a four-necked flask equipped with a stirrer, a reflux condenser, a thermometer, and a nitrogen inlet tube, 138 parts by mass of ion-exchanged water was placed, and the temperature was raised to 70°C. In a separate vessel, 6 parts by mass of a nonionic emulsifier (Dai-ichi Kogyo Seiyaku Co., Ltd. "TDS-200D") and 4 parts by mass of an anionic emulsifier (Dai-ichi Kogyo Seiyaku Co., Ltd. "Hitenol LA-12") were dissolved in 120 parts by mass of ion-exchanged water to prepare an emulsifier aqueous solution. To this was added a mixture of 34 parts by mass of chlorinated polyolefin resin (a1-1) (Nippon Paper Industries Co., Ltd. "Superchlor 836S"; chlorination degree 27-29%, softening point 60-70 ° C), 116 parts by mass of methylcyclohexane, 111 parts by mass of cyclohexyl methacrylate, 31 parts by mass of methyl methacrylate, and 1.5 parts by mass of methacrylic acid. The mixture was stirred and emulsified, and then further stirred in a homogenizer at 8000 rpm for 15 min to micro-emulsify the mixture. This micro-emulsion and a solution of 0.8 parts by mass of ammonium persulfate in 34 parts by mass of ion-exchanged water were added dropwise over 2 hours, and the reaction was carried out at 67-73 ° C. After holding the temperature at 70°C for 120 minutes, 2 parts by mass of 25% aqueous ammonia and 300 parts by mass of ion-exchanged water were added at the same temperature for neutralization. The solvent was removed at 90°C under reduced pressure (0.080-0.095 MPa) and then cooled to obtain an aqueous dispersion of chlorinated polyolefin composite acrylic resin (1). The properties of this aqueous dispersion were 40% by mass of nonvolatile content, pH 7.4, and viscosity 9 mPa s.

[0047] (Synthesis Example 2: Synthesis of aqueous dispersion (2) of chlorinated polyolefin composite acrylic resin) A water dispersion (2) of chlorinated polyolefin composite acrylic resin was obtained in the same manner as in Synthesis Example 1, except that the chlorinated polyolefin resin (a1-1) used in Synthesis Example 1 was changed to a chlorinated polyolefin resin (a1-2) (Superchlorine 2030S manufactured by Nippon Paper Industries Co., Ltd.; chlorination degree 29 to 31%, softening point 55 to 65°C). The property values ​​of this water dispersion were nonvolatile content 40 mass%, pH 7.2, and viscosity 7 mPa s.

[0048] (Synthesis Example 3: Synthesis of aqueous dispersion (r1) of polyolefin composite acrylic resin) An aqueous dispersion of polyolefin-composite acrylic resin (R1) was obtained in the same manner as in Synthesis Example 1, except that the chlorinated polyolefin resin (a1-1) used in Synthesis Example 1 was changed to a polyolefin resin ("ELMODU S-400" manufactured by Idemitsu Petrochemical Co., Ltd.) The properties of this aqueous dispersion were: nonvolatile content 40% by mass, pH 7.0, and viscosity 11 mPa s.

[0049] (Example 1: Production and evaluation of water- and oil-repellent treatment agent for fabric (1)) To 64.1 parts by mass of the aqueous dispersion (1) of the chlorinated polyolefin composite acrylic resin obtained in Synthesis Example 1, 0.15 parts by mass of a dispersant ("Noigen XL-41" manufactured by Daiichi Kogyo Seiyaku Co., Ltd.; polyoxyalkylene branched decyl ether), 3 parts by mass of amino-modified silicone oil ("DOWSIL SF-8417" manufactured by Dow Toray Industries, Inc.), and 1 part by mass of polyether-modified silicone oil ("DOWSIL SF-8410" manufactured by Dow Toray Industries, Inc.) were added, and the nonvolatile content was then adjusted to 0.6% by mass with ion-exchanged water to obtain a water- and oil-repellent treatment agent (1) for fabrics.

[0050] (Example 2: Production and evaluation of water- and oil-repellent treatment agent for fabric (2)) A water- and oil-repellent treatment agent for fabrics (2) with a non-volatile content of 0.6% by mass was obtained in the same manner as in Example 1, except that the amino-modified silicone oil used in Example 1 was changed from 3 parts by mass to 2 parts by mass, and the polyether-modified silicone oil was changed from 1 part by mass to 2 parts by mass.

[0051] (Example 3: Production and evaluation of water- and oil-repellent treatment agent for fabric (3)) A water- and oil-repellent treatment agent for fabrics (3) with a non-volatile content of 0.6% by mass was obtained in the same manner as in Example 1, except that the amino-modified silicone oil used in Example 1 was changed from 3 parts by mass to 1 part by mass, and the polyether-modified silicone oil was changed from 1 part by mass to 3 parts by mass.

[0052] (Example 4: Production and evaluation of water- and oil-repellent treatment agent for fabric (4)) A water- and oil-repellent treatment agent for fabrics (4) having a nonvolatile content of 0.6 mass % was obtained in the same manner as in Example 1, except that the aqueous dispersion of chlorinated polyolefin-composite acrylic resin (1) used in Example 1 was changed to an aqueous dispersion of chlorinated polyolefin-composite acrylic resin (2).

[0053] (Example 5: Production and evaluation of water- and oil-repellent treatment agent for fabric (5)) A water- and oil-repellent treatment agent for fabrics (5) having a nonvolatile content of 0.6% by mass was obtained in the same manner as in Example 1, except that the aqueous dispersion of chlorinated polyolefin-composite acrylic resin (1) used in Example 1 was changed to an aqueous dispersion of chlorinated polyolefin-composite acrylic resin (2), the amount of amino-modified silicone oil was changed from 3 parts by mass to 1 part by mass, and the amount of polyether-modified silicone oil was changed from 1 part by mass to 3 parts by mass.

[0054] (Comparative Example 1: Production and Evaluation of Water- and Oil-Repellent Treatment Agent for Fabric (R1)) To 64.1 parts by mass of the aqueous dispersion of polyolefin-composite acrylic resin obtained in Synthesis Example 3, 0.15 parts by mass of a dispersant ("Noigen XL-41" manufactured by Daiichi Kogyo Seiyaku Co., Ltd.; polyoxyalkylene branched decyl ether) and 4 parts by mass of amino-modified silicone oil ("DOWSIL SF-8417" manufactured by Dow Toray Industries, Inc.) were added, and then the nonvolatile content was adjusted to 0.6% by mass with ion-exchanged water, followed by dilution to obtain a water- and oil-repellent treatment agent for fabrics (R1).

[0055] [Preparation of test cloth] The water and oil repellent treatment agent for fabric obtained above was applied to the base fabric (high density nylon fabric) using a mangle coater at a wet rate of 15.6 g / m 2 The coating was applied by the dip-nip method at a coating weight of 130°C for 5 minutes and then dried at 160°C for 5 minutes to obtain a test cloth.

[0056] [Water repellency evaluation] In accordance with Method A of JIS L1092:2009, a water repellency test was conducted in which the test cloth obtained above was stretched out so as to be smooth, placed at an angle of 45 degrees, and several drops of water were dropped on it with a dropper to check the state of the water on the surface of the test cloth. The water repellency was evaluated according to the following criteria. G5: Water droplets do not separate and there are no marks left after wiping. G4: Water droplet separation, no traces after wiping G3: No bleeding when dripping, traces after wiping G2: Seepage mark after dripping G1: Full immersion

[0057] [Evaluation of oil repellency] In accordance with AATCC118, the test cloth obtained above was placed on a pin-embossed paper wiper, and one drop of n-hexadecane (oil repellency test grade 3) was dropped onto it, and the time until the n-hexadecane penetrated into the fabric was measured. The longer the time until the n-hexadecane penetrated, the higher the oil repellency. 60 seconds after dropping one drop of n-hexadecane onto the test cloth, the spread of the n-hexadecane along the warp and weft of the test cloth was measured with a ruler, and the area (mm) was calculated using the formula for the area of ​​an ellipse. 2 The smaller the area of ​​the stain spread, the higher the oil repellency.

[0058] Table 1 shows the compositions and evaluation results of Examples 1 to 5 and Comparative Example 1.

[0059] [Table 1]

[0060] It was confirmed that the water- and oil-repellent treating agents for fabrics of the present invention in Examples 1 to 5 were able to impart water and oil repellency.

[0061] Comparative Example 1 is an example in which chlorinated polyolefin resin, which is an essential raw material of the present invention, was not used, and it was confirmed that the oil repellency was insufficient.

Claims

1. a chlorinated polyolefin composite acrylic resin (A) having a chlorinated polyolefin resin (a1) and an acrylic polymer (a2); an aqueous medium (B); A water- and oil-repellent treatment agent for fabrics containing a modified silicone oil (C), the modified silicone oil (C) contains an amino-modified silicone oil (c1) and a polyether-modified silicone oil (c2), The content of the chlorinated polyolefin composite acrylic resin (A) is 0.05% by mass or more and less than 10% by mass, The water- and oil-repellent treatment agent for fabrics, characterized in that the content of the polyether-modified silicone oil (c2) is 0.5 to 25 mass% based on 100 parts by mass of the chlorinated polyolefin-composite acrylic polymer (A).

2. 2. The water- and oil-repellent treating agent for fabric according to claim 1, wherein the mass ratio (a1 / a2) of the chlorinated polyolefin resin (a1) to the acrylic polymer (a2) is 5 / 95 to 40 / 60.

3. 2. The water- and oil-repellent treating agent for fabric according to claim 1, wherein the softening point of the chlorinated polyolefin resin (a1) is 50 to 75°C.

4. 2. The water- and oil-repellent treating agent for fabric according to claim 1, wherein the chlorinated polyolefin resin (a1) has a degree of chlorination of 15 to 35%.

5. The water- and oil-repellent treating agent for fabrics according to claim 1, which contains a nonionic dispersant.

6. A fabric treated with the water- and oil-repellent treating agent for fabrics according to any one of claims 1 to 5.

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