Process for the production of hydrogen

Abstract

A process for the production of hydrogen is described, comprising: subjecting a gaseous mixture comprising hydrocarbons and steam, and having a steam to carbon ratio of at least 0.9:1, to adiabatic pre-reforming in a pre-reformer, followed by autothermal reforming with oxygen-enriched gas in an autothermal reformer to generate a reformed gas mixture; optionally adding steam to the reformed gas mixture; subjecting the reformed gas mixture to one or more water gas shift stages in a water gas shift unit to increase the hydrogen content of the reformed gas mixture to provide a hydrogen-enriched reformed gas; cooling the hydrogen-enriched reformed gas and separating condensed water therefrom; passing the resulting dehydrated hydrogen-enriched reformed gas to a carbon dioxide separation unit to provide a carbon dioxide gas stream and a crude hydrogen gas stream; and passing the crude hydrogen gas stream to a purification unit to provide purified hydrogen gas and a fuel gas, wherein the fuel gas is supplied to one or more combustion heaters used to heat one or more process streams in the process.

Description

[Technical Field]

[0001] The present invention relates to a process for converting hydrocarbons to hydrogen while minimizing carbon dioxide production. [Background technology]

[0002] Processes for generating hydrogen are well known and generally involve combustion steam methane reformers combined with water gas shift and carbon dioxide (CO2) removal. Such processes create significant volumes of carbon dioxide in the flue gas at pressures unsuitable for efficient CO2 capture. A need exists for a hydrogen production process that produces lower levels of carbon dioxide effluent and allows for more efficient CO2 capture.

[0003] WO2011077106A1 discloses a process for reducing CO2 emissions from a combined cycle power generation process utilizing a gaseous hydrocarbon feed, comprising splitting the hydrocarbon feed into two portions: a first smaller portion and a second larger portion, feeding the first smaller portion to an autothermal reforming process to generate a hydrogen-containing gas and a carbon dioxide stream, combining the hydrogen-containing stream with a second portion of the gaseous hydrocarbons, combusting the resulting hydrogen-containing fuel stream with an oxygen-containing gas in a gas turbine to generate electricity, and sending an exhaust gas mixture from the gas turbine to a heat recovery steam generation system (feeding one or more steam turbines) to generate additional electricity. The captured carbon dioxide stream can be stored or fed to an enhanced oil recovery process.

[0004] They have developed an improved process where the percentage of captured CO2 can be over 95%. Summary of the Invention

[0005] Accordingly, the present invention provides a process for the production of hydrogen, comprising: (i) subjecting a gaseous mixture comprising hydrocarbons and steam and having a steam to carbon ratio of at least 0.9:1 to adiabatic pre-reforming in a pre-reformer followed by autothermal reforming with an oxygen-enriched gas in an autothermal reformer to generate a reformed gas mixture; (ii) increasing the hydrogen content of the reformed gas mixture by subjecting the reformed gas mixture to one or more water gas shift stages in a water gas shift unit to provide a hydrogen-enriched reformed gas; (iii) cooling the hydrogen-enriched reformed gas and separating condensed water therefrom to provide a dehydrated hydrogen-enriched reformed gas; (iv) passing the dehydrated hydrogen-rich reformed gas to a carbon dioxide separation unit to provide a carbon dioxide gas stream and a crude hydrogen gas stream; (v) passing the crude hydrogen gas stream from the carbon dioxide removal unit to a purification unit to provide purified hydrogen gas and fuel gas; A process is provided in which fuel gas is supplied to one or more fired heaters that are used to heat one or more process streams within the process.

[0006] By using a pre-reformer coupled to an autothermal reformer and operating at a selected steam-to-carbon ratio, it is possible to use all of the fuel gas for one or more fired heaters, thereby minimizing CO2 emissions from the process. Further efficiency gains are possible, allowing for greater than 95% capture of CO2 from the process.

[0007] The gaseous mixture may comprise any gaseous or low-boiling hydrocarbon (such as natural gas, associated gas, LPG, petroleum distillates, diesel, naphtha, or mixtures thereof), or hydrocarbon-containing off-gas from a chemical process (such as refinery off-gas or pre-reformate gas). The gaseous mixture preferably comprises methane, associated gas, or natural gas (containing a substantial proportion of methane (e.g., greater than 50% v / v)). Natural gas is particularly preferred. The hydrocarbons may be compressed to a pressure in the range of 10 to 100 bar absolute. The pressure of the hydrocarbons may usefully govern the pressure throughout the process. The operating pressure is preferably in the range of 15 to 50 bar absolute, more preferably 25 to 50 bar absolute, thereby providing improved performance from the process.

[0008] Unlike WO2011077106A1, the hydrocarbons are not split.

[0009] If the hydrocarbon contains sulfur compounds, it can be subjected to desulfurization, including hydrodesulfurization using a CoMo or NiMo catalyst, and hydrogen sulfide absorption using a suitable hydrogen sulfide adsorbent (e.g., a zinc oxide adsorbent), before or preferably after compression. Ultra-purified adsorbents can be usefully used downstream of the hydrogen sulfide adsorbent to further protect the steam reforming catalyst. Suitable ultra-purified adsorbents can include copper-zinc oxide / alumina materials and copper-nickel-zinc oxide / alumina materials. Hydrogen is preferably added to the compressed hydrocarbon to facilitate hydrodesulfurization and / or reduce the risk of carbon laydown in the reforming process. The amount of hydrogen in the resulting mixed gas stream can range from 1 to 20% by volume, but is preferably in the range of 1 to 10% by volume, and more preferably in the range of 1 to 5% by volume, on a dry gas basis. In a preferred embodiment, a portion of the crude or purified hydrogen gas stream can be mixed with the compressed hydrocarbon. Hydrogen can be combined with the hydrocarbon upstream and / or downstream of any hydrodesulfurization stage.

[0010] If the hydrocarbons contain other contaminants, such as chlorides or heavy metal contaminants, these can be removed using conventional adsorbents, either upstream or downstream of the optional desulfurization and prior to upgrading. Adsorbents suitable for chloride removal are known and include alkalized alumina materials. Similarly, adsorbents for heavy metals such as mercury or arsenic are known and include copper sulfide materials.

[0011] The hydrocarbons may be preheated in one or more stages. They may be conveniently preheated after compression and before desulfurization. Various hot gas sources are provided in the process that may be used for this task. For example, the hydrocarbon feed stream may be heated by heat exchange with a shifted gas stream recovered from a water-gas shift stage, preferably a high-temperature shift stage. If the hydrocarbons have been desulfurized, they may be further heated after desulfurization and before being mixed with steam. The desulfurized hydrocarbons may be heated, for example, in a combustion heater fueled by fuel gas.

[0012] The hydrocarbons are mixed with steam. Steam introduction can be carried out by direct injection of steam and / or saturation of the hydrocarbons by contact with a heated water stream. In a preferred embodiment, a gaseous mixture containing hydrocarbons and steam is formed by directly mixing the hydrocarbons with steam, preferably steam generated in one or more combustion heaters, and / or by cooling the reformed gas mixture with water. The amount of steam introduced is sufficient to provide a steam-to-hydrocarbon carbon ratio (defined as the ratio of steam to hydrocarbon carbon at the inlet to the reforming unit operation) of at least 0.9:1, i.e., at least 0.9 moles of steam per gram of hydrocarbon carbon atom in the gaseous mixture, with a preferred range of 0.9:1 to 3.5:1. If the steam-to-carbon ratio at the inlet to the reforming unit operation is less than 0.9:1 to 2.4:1, additional steam must be added to the reformed gas upstream of the water-gas shift stage. Operating the reforming section at steam-to-carbon ratios in the range of 0.9:1 to less than 2.4:1 has the advantage that the heating requirements and oxygen demand of the reforming stage are reduced, and the front-end equipment (e.g., combustion heaters, pre-reformers, and autothermal reformers) is smaller and less costly. When the steam-to-carbon ratio is in the range of 2.4:1 to 3.5:1, no additional steam addition upstream of the water-gas shift unit is required, which can be useful in situations where adding steam to the reformed gas is impractical.

[0013] If preheating of the gaseous mixture comprising hydrocarbons and steam is carried out using one or more combustion heaters, no further heating step is required prior to the adiabatic pre-reforming step.

[0014] The gaseous mixture containing hydrocarbons and steam is subjected to a process of adiabatic steam reforming in a pre-reformer vessel followed by autothermal reforming in an autothermal reformer, the pre-reformer and the autothermal reformer being operated in series.

[0015] In pre-reforming, a gaseous mixture containing hydrocarbons and steam is passed adiabatically through a bed of steam reforming catalyst, e.g., a steam reforming catalyst having a high nickel content, typically greater than 40 wt. %, at an inlet temperature ranging from 400 to 650°C, preferably 500 to 550°C. During such an adiabatic pre-reforming step, any hydrocarbons higher than methane react with the steam to give a mixture of methane, carbon oxides, and hydrogen. The use of such an adiabatic steam reforming step, commonly referred to as pre-reforming, is desirable to ensure that the feed to the autothermal reformer does not contain hydrocarbons higher than methane and also contains some hydrogen.

[0016] In the present invention, a pre-reformed gas containing methane, hydrogen, steam, and carbon oxides is supplied to an autothermal reformer for autothermal reforming. In the current process, all of the pre-reformed gas is supplied to the autothermal reformer. If desired, the temperature and / or pressure of the pre-reformed gas can be adjusted before supplying it to the autothermal reformer. In a preferred embodiment, the pre-reformed gas mixture recovered from the adiabatic reforming step is heated and then supplied to the autothermal reformer by passing it through a combustion heater fueled by at least a portion of the fuel gas, particularly the same combustion heater used to preheat the hydrocarbons. Desirably, the pre-reformed gas is heated to 600-700°C, preferably 620-680°C.

[0017] An autothermal reformer may include a burner located at the top of the reformer to which the steam reformed gas and oxygen-enriched gas are supplied, a combustion zone below the burner through which the flame extends, and a fixed bed of particulate steam reforming catalyst located below the combustion zone. Thus, in autothermal reforming, heat for the endothermic steam reforming reaction is provided by burning a portion of the hydrocarbons in the pre-reforming feed gas. The pre-reformed gas is typically supplied to the top of the reformer, and the oxygen-enriched gas is supplied to the burner, where mixing and combustion occur downstream of the burner to generate a heated gas mixture, the composition of which is equilibrated as it passes through the steam reforming catalyst. The autothermal steam reforming catalyst may include nickel supported on a refractory support such as rings or pellets of calcium aluminate, magnesium aluminate, alumina, titania, zirconia, or the like. In a preferred embodiment, the autothermal steam reforming catalyst comprises a layer of catalyst comprising Ni and / or Ru on zirconia over a bed of Ni on alumina catalyst to reduce volatilization of the catalyst support which can lead to degradation of autothermal reformer performance.

[0018] The oxygen-enriched gas may contain at least 50% O by volume and may be an oxygen-enriched air mixture. However, in the present invention, the oxygen-enriched gas preferably contains at least 90% O by volume, more preferably at least 95% O by volume, and most preferably at least 98% O by volume, or at least 99% O by volume (e.g., a pure oxygen gas stream that may be obtained using a vacuum pressure swing adsorption (VPSA) unit or an air separation unit (ASU)). The ASU may be electrically powered, desirably using renewable electricity, to further improve the efficiency of the process and minimize CO2 emissions.

[0019] The amount of oxygen-enriched gas added preferably adds 45 to 65 moles of oxygen per 100 moles of carbon in the hydrocarbons fed to the process. Preferably, the amount of oxygen added is such that the autothermal reforming gas leaves the autothermal reforming catalyst at a temperature in the range of 800 to 1100°C. In a preferred embodiment, a small purge of steam may be added to the oxygen-enriched gas to protect against backflow in the event of a plant trip.

[0020] After leaving the autothermal reformer, the reformed gas is then typically cooled in one or more steps of heat exchange. These may include at least a first stage of steam raising, for example, using a boiler with a connected steam drum. In one embodiment, at least a portion of the steam generated by cooling the reformed gas, optionally after heating in one or more fired heaters, is mixed with hydrocarbons to form a gaseous mixture containing hydrocarbons and steam. In another embodiment, the oxygen-rich gas supplied to the autothermal reformer is heated by heat exchange with the steam generated by cooling the reformed gas before being supplied to the autothermal reformer. For safety reasons, the reformed gas is preferably not used to directly heat the oxygen-containing gas supplied to the autothermal reformer. One or more additional cooling steps may be performed, but these are generally not required in this process.

[0021] The reformate gas recovered from the autothermal reformer contains hydrogen, carbon monoxide, carbon dioxide, steam, and small amounts of unreacted methane, and may also contain small amounts of inert gases such as nitrogen and argon. For example, in processes where all process steam is added upstream of the reforming unit operation, the hydrogen content of the autothermal reformate gas may range from 35 to 45% by volume, and the CO content may range from 10 to 20% by volume. In current processes, the hydrogen content of the reformate gas mixture is increased by subjecting it to one or more water-gas shift stages in a water-gas shift unit, thereby producing a hydrogen-enriched reformate gas stream and simultaneously converting carbon monoxide to carbon dioxide. The reaction can be depicted as follows:

[0022]

number

[0023] Optionally, if the steam-to-carbon ratio of the gaseous mixture fed to the pre-reformer is less than 2.4:1, additional process steam may be added to the reformed gas to improve the equilibrium position of the water-gas shift stage. Thus, in some embodiments, the process optionally includes adding steam to the reformed gas. Steam may be added to the reformed gas upstream of the water-gas shift unit, e.g., upstream of the high-temperature shift stage. The amount of steam added will vary depending on the amount of steam in the hydrocarbon-containing gaseous mixture fed to the reforming stage. The amount of steam added is desirably commensurate with maximizing carbon capture from the assisted process by minimizing carbon monoxide slip. Thus, if steam is added to the reformed gas, the molar ratio of dry gas to steam in the reformed gas is preferably at least 0.7:1, more preferably in the range of 0.7:1 to 0.9:1.

[0024] However, if reforming is carried out with excess steam, it is generally not necessary to add steam to the reformed gas mixture recovered from the autothermal reformer.

[0025] Although the water-gas shift unit may include one shift stage using a suitably stable active shift catalyst, the reformate gas is preferably subjected to two or more water-gas shift stages, including a high-temperature shift, a medium-temperature shift, an isothermal shift, and a low-temperature shift. In this way, favorable equilibria at low temperatures can be used to maximize hydrogen formation along with the conversion of carbon monoxide to carbon dioxide. By using two or more shift stages, very low CO levels in the shifted gas are possible.

[0026] The high temperature shift is operated adiabatically in a shift vessel having an inlet temperature in the range of 300-400° C., preferably 320-360° C., over a bed of reduced iron catalyst such as chromia-promoted magnetite. Alternatively, a promoted zinc aluminate catalyst may be used.

[0027] The intermediate-temperature and low-temperature shift stages can be carried out using a shift vessel containing a supported copper catalyst, particularly a copper / zinc oxide / alumina composition. In the low-temperature shift, gas containing carbon monoxide (preferably not more than 6% CO by volume on a dry basis) and steam (with a steam to total dry gas ratio ranging from 0.3:1 to 1.5:1) can be passed over the catalyst in an adiabatic fixed bed at an outlet temperature ranging from 200 to 300°C. Typically, the inlet gas is the product of a "high-temperature shift" in which the carbon monoxide content is reduced by reaction over an iron-chromia catalyst with an outlet temperature ranging from 400 to 500°C, followed by cooling by indirect heat exchange. The outlet carbon monoxide content from the low-temperature water-gas shift stage is generally in the range of 0.1 to 1.0% by volume on a dry basis, particularly less than 0.5% by volume. Alternatively, in a medium temperature shift, gas containing carbon monoxide and steam is fed to the catalyst at a pressure in the range of 15-50 bar (absolute) and an inlet temperature generally in the range of 200-240°C, although the inlet temperature can be as high as 280°C and the outlet temperature is typically up to 300°C, but can be as high as 360°C.

[0028] A shift unit comprising a combination of high temperature and low temperature shift stages, each stage operated adiabatically, is preferred in the present process.

[0029] Adiabatic operation of the shift stage results in an increase in the temperature of the shifted gas mixture, subsequent heat exchange with one or more process streams is generally desirable. When the shift unit includes a high-temperature shift stage, two stages of heat exchange are preferred, and the heat-shifted gas mixture can be cooled by heat exchange with water under pressure and together with hydrocarbons. In a preferred arrangement, the heat-shifted gas from the high-temperature shift stage is cooled in a first stage of heat exchange with hydrocarbons and a second stage of heat exchange with water under pressure.

[0030] While the low-temperature and intermediate-temperature shift reactions can be operated adiabatically, they can also be operated isothermally, i.e., with heat exchange within the shift vessel, whereby the reaction within the catalyst bed occurs in contact with the heat exchange surfaces. Conveniently, the coolant can be water under pressure to cause partial or complete boiling. The resulting steam can be used, for example, to drive a turbine for power or to provide process steam for a water-gas shift or steam reforming reaction. The water can be in tubes surrounded by the catalyst, or vice versa. Although the term "isothermal" is used, the temperature of the gas between the inlet and outlet can be small, and thus the temperature of the hydrogen-rich reformate stream at the outlet of the isothermal shift converter can be 1 to 25 degrees Celsius higher than the inlet temperature.

[0031] Following one or more shift stages, the hydrogen-rich reformed gas is cooled to a temperature below the dew point so that the steam condenses. The liquid water condensate can then be separated using one or more gas-liquid separators, which can have one or more additional cooling stages between them. Any coolant can be used. Preferably, cooling of the hydrogen-rich reformed gas stream is first carried out by heat exchange with water. In a preferred arrangement, the hydrogen-rich reformed gas mixture is cooled by heat exchange with water, and the resulting heated water is supplied to a steam drum coupled to a boiler used to cool the reformed gas mixture. One or more additional stages of cooling are desirable. Cooling can be carried out by heat exchange in one or more stages using demineralized water, air, or a combination thereof.

[0032] Two or three stages of condensate separation are preferred. If desired, some or all of the condensate can be used to generate steam for the adiabatic pre-reforming step or to generate steam that is added to the oxygen-enriched gas supplied to the autothermal reformer. In this way, organic compounds in the condensate can be returned to the process, thereby reducing the burden of any aqueous effluent treatment. Any condensate not used to generate steam can be sent as effluent to water treatment.

[0033] Typically, the hydrogen-rich reformed gas stream contains 20-30% by volume of carbon dioxide (on a dry basis). In the present invention, after separation of the condensed water, carbon dioxide is separated from the resulting dehydrated hydrogen-rich reformed gas stream.

[0034] The carbon dioxide separation step can be carried out using a physical or reactive scrubbing system, preferably a reactive scrubbing system, in particular an amine scrubbing system. Carbon dioxide can be separated by an acid gas recovery (AGR) process. In the AGR process, the dehydrated hydrogen-rich reformed gas stream (i.e., the dehydrated shifted gas) is contacted with a suitable absorbing liquid stream, such as an amine, in particular a methyl diethanolamine (MDEA) solution, so that the carbon dioxide is absorbed by the liquid to provide an absorbent liquid and a gas stream (having a reduced carbon dioxide content). The absorbent liquid is then regenerated by heating and / or reducing the pressure to desorb the carbon dioxide and provide a regenerated absorbent liquid, which is then recycled to the carbon dioxide absorption step. Alternatively, methanol or glycol can be used to capture carbon dioxide in a manner similar to that of amines. In a preferred arrangement, at least a portion of the heating to regenerate the absorbent liquid is carried out using steam generated in one or more fired heaters. If the carbon dioxide separation step is operated as a single pressure process, i.e., essentially the same pressure is used in the absorption and regeneration steps, only a small amount of recompression of the recycled carbon dioxide is required.

[0035] For example, recovered carbon dioxide from AGR can be compressed and used to manufacture chemicals, sent to storage or sequestration, used in enhanced oil recovery (EOR) processes, or used to generate other chemicals. Compression can be achieved using an electrically driven compressor powered by renewable electricity. If the CO2 is to be compressed for storage, transportation, or use in an EOR process, the CO2 can be dried to prevent traces of liquid water from condensing. For example, the CO2 can be dried to a dew point of -10°C or below by passing it through a bed of a suitable desiccant, such as zeolite, or by contacting it with glycol in a glycol drying unit.

[0036] Upon separation of the carbon dioxide, the process provides a crude hydrogen gas stream.

[0037] The crude hydrogen stream may comprise 85-99% hydrogen by volume, preferably 90-99% hydrogen by volume, more preferably 95-99% hydrogen by volume, with the remainder comprising methane, carbon monoxide, carbon dioxide, and inert gases. While this hydrogen gas stream is sufficiently pure for many operational duties, in the present invention the crude hydrogen gas stream is sent to a purification unit to provide purified hydrogen gas and fuel gas so that the fuel gas can be used in the process as an alternative to an external fuel source.

[0038] The purification unit may suitably include a membrane system, a temperature swing adsorption system, or a pressure swing adsorption system. Such systems are commercially available. The purification unit is preferably a pressure swing adsorption unit. Such a unit includes a regenerable porous adsorbent material that selectively captures and purifies gases other than hydrogen. The purification unit produces a pure hydrogen stream, preferably greater than 99.5% volumetric purity, more preferably greater than 99.9% volumetric purity, that can be compressed and used in downstream power or heating processes, for example, by using it as fuel in a gas turbine (GT) or by injection into a domestic or industrial networked gas distribution system. The pure hydrogen can also be used in downstream chemical synthesis processes. Thus, the pure hydrogen stream can be used to produce ammonia by reaction with nitrogen in an ammonia synthesis unit. Alternatively, pure hydrogen can be used with carbon dioxide-containing gas to produce methanol in a methanol production unit. Alternatively, pure hydrogen can be used with carbon monoxide-containing gas to synthesize hydrocarbons in a Fischer-Tropsch production unit. Any known ammonia, methanol, or Fischer-Tropsch production technology can be used. Alternatively, the hydrogen can be used to upgrade hydrocarbons, for example, by hydrotreating or hydrocracking hydrocarbons in a hydrocarbon refinery, or in any other process where pure hydrogen can be used. Compression can again be achieved using an electrically driven compressor powered by renewable electricity.

[0039] A portion of the crude hydrogen or a portion of the pure hydrogen may be recycled to the hydrocarbon feed stream as needed for desulfurization to reduce the possibility of carbon formation on the catalyst in the pre-reformer.

[0040] The purification unit desirably operates with continuous separation of fuel gas from the crude hydrogen stream. The fuel gas composition depends on the degree of purification of the crude hydrogen stream. The fuel gas may contain 80-90% hydrogen by volume, with the remainder comprising methane, carbon monoxide, carbon dioxide, and inert gases. The methane content may range from 1-5% by volume, preferably 2-5% by volume. The carbon monoxide content may range from 2-10% by volume, preferably 2-8% by volume. The carbon dioxide content may range from 0-1.5% by volume. Trace amounts of steam and nitrogen may also be present, ranging from 0-5% by volume.

[0041] The combination of pre-reforming, autothermal reforming, and water gas shift, operated as described herein, provides sufficient fuel gas to heat the process streams used in the process without significant additional fuel during normal operation. The volume of auxiliary fuel in the process is desirably kept to a minimum to maximize CO2 capture efficiency. The amount of auxiliary fuel, such as natural gas, supplied to one or more combustion heaters along with the fuel gas is preferably less than 5% by volume of the total fuel provided, more preferably less than 3% by volume of the total fuel provided, and most preferably less than 2% by volume of the total fuel provided.

[0042] In some situations, such as during start-up of the process, it may be necessary to temporarily supplement the fuel gas with hydrocarbon fuel, but this should not significantly reduce the efficiency of the process; however, during normal operation, the fuel gas recovered from the refinery unit is the primary source of fuel provided to one or more fired heaters.

[0043] In some embodiments, a single combustion heater fueled at least in part by fuel gas recovered from refining is sufficient to heat the hydrocarbons, the reformed gas recovered from a pre-reforming stage upstream of the autothermal reforming stage, and water to generate at least a portion of the steam for the process.

[0044] While all process streams requiring heating can be heated in a single fired heater, a preferred arrangement involves one fired heater being used for the hydrocarbon- and / or hydrogen-containing process gas stream and another being used solely to boil water for steam generation. The latter could therefore also be described as a boiler. Thus, fuel gas can be split between the first fired heater, used to heat the hydrocarbon- and / or hydrogen-containing stream, and the second fired heater, used to boil water to generate steam. Using two fired heaters in this manner offers several distinct advantages. It allows steam to be raised in the second fired heater, thereby being used as part of plant startup. It allows steam to be generated in the second fired heater while the plant is shut down and supplied to the plant during the shutdown process, which facilitates startup. Because the first and second fired heaters can be operated independently, eliminating the need for coil heating in a non-flowing regime, isolating the first fired heater allows nitrogen to be warmed as part of the startup procedure while the second fired heater is being brought into service or started up. The fuel gas split between the first combustion heater and the second combustion heater can be in the range of 10-90% by volume to 90-10% by volume, respectively, but is preferably in the range of 60-80% by volume for the first combustion heater and 40-20% by volume for the second combustion heater.

[0045] The steam generated in the second fired heater can be used to heat the CO2 absorption liquid in the carbon dioxide separation unit. The second fired heater can also be used to superheat steam recovered from a steam drum coupled to a waste heat boiler heated by the reformed gas. The waste heat boiler is also preferably used to generate steam used to preheat the oxygen-enriched gas and / or to provide process steam added upstream of the water-gas shift unit to maximize the conversion to hydrogen and carbon dioxide. A portion of the steam from the waste heat boiler can also be sent to a steam expander to generate electricity. [Brief explanation of the drawings]

[0046] The present invention will now be illustrated by way of example with reference to the accompanying drawings. [Figure 1] 1 is a schematic flowsheet of one embodiment of the present invention in which all process steam is added upstream of the reforming unit operation.

[0047] The drawings are schematic and those skilled in the art will understand that in a commercial plant additional items of equipment may be required, such as reflux drums, pumps, vacuum pumps, temperature sensors, pressure sensors, pressure relief valves, control valves, flow controllers, level controllers, holding tanks, storage tanks, etc. Providing such equipment accessories does not form part of the present invention and is in accordance with conventional chemical engineering practice. DETAILED DESCRIPTION OF THE INVENTION

[0048] In Figure 1, a natural gas stream containing greater than 85% methane by volume provided via line 10 is mixed with a hydrogen-containing stream 12 so that the resulting mixture contains 1-5% hydrogen by volume. The hydrogen-containing natural gas stream is provided via line 14 to heat exchanger 16, where it is heated by high-temperature shifted gas 18. The heated natural gas mixture is then desulfurized by passing it via line 20 to a hydrodesulfurization (HDS) vessel 22 containing a bed of hydrodesulfurization catalyst, where organic sulfur compounds are converted to hydrogen sulfide with hydrogen, and then passed via line 24 to vessel 26 containing a bed of zinc oxide adsorbent and a bed of copper-zinc-alumina ultra-purified adsorbent, which remove hydrogen sulfide.

[0049] The desulfurized natural gas is supplied from vessel 26 via line 28 to a first fired heater 30 where it is heated by combustion of fuel gas supplied to the heater via line 32. The heated natural gas is removed from heater 30 via line 34 and combined with steam supplied via line 36 to provide a natural gas and steam mixture having a steam to carbon ratio of about 2.5:1.

[0050] The natural gas and steam mixture is supplied via line 38 to an adiabatic pre-reformer 40 containing a bed of pelletized nickel-based steam reforming catalyst. Higher hydrocarbons are converted to methane and partially steam reformed to produce a pre-reformed gas mixture containing hydrogen as the mixture passes through the pre-reformer catalyst. The pre-reformed gas mixture is then supplied via line 42 from the pre-reformer 40 to the first fired heater 30 where it is heated to the autothermal reformer inlet temperature.

[0051] The heated pre-reformed gas mixture is supplied from the combustion heater 30 via line 44 to the burner region of the autothermal reformer 46, where it is partially combusted with oxygen produced in the air separation unit 50 and supplied via line 48, which has been preheated in a heat exchanger 52. The hot combustion gas mixture is equilibrated over a fixed bed of pelletized nickel-based secondary reforming catalyst 54 located below the combustion zone in the autothermal reformer 46. The resulting thermal reformed gas mixture is supplied from the autothermal reformer 46 via line 56 to the tube side of a steam lift boiler 58 coupled to a steam drum 60. The thermal reformed gas mixture boils water, which is supplied from the steam drum 60 via line 62 to the shell side of the boiler, and returns steam from the boiler to the steam drum 60 via line 64. The steam drum 60 coupled to the boiler 58 generates high-pressure steam, which is recovered from the steam drum 60, split, and used in the process. The thermal reformed gas mixture is cooled as it passes through the boiler 58.

[0052] The resulting cooled reformed gas mixture is fed from the tube side of boiler 58 via line 66 to a first shift vessel 68 containing a fixed bed of particulate iron-based high-temperature shift catalyst. A water-gas shift reaction occurs, increasing the hydrogen content of the reformed gas and producing carbon monoxide, which is converted to carbon dioxide as the gas passes through the bed. The partially shifted reformed gas is fed from the first shift reactor via line 18 to heat exchanger 16 to preheat the natural gas and then to a further heat exchanger 70, where it is cooled with water under pressure. The cooled partially shifted gas mixture is fed from heat exchanger 70 via line 72 to a second shift vessel 74 containing a fixed bed of particulate copper-based low-temperature shift catalyst. As the gas passes through the bed, the water-gas shift reaction proceeds further to completion. The resulting hydrogen-rich reformed gas mixture is then cooled in heat exchanger 76 and fed with cold, pressurized, demineralized, deaerated water, which is provided to the process via line 78. A portion of the water recovered from heat exchanger 76 in line 80 is supplied to heat exchanger 70 where it is used to cool the partially shifted gas mixture. The heated water recovered from heat exchanger 70 is supplied via line 82 to steam drum 60 to provide coolant for the reformed gas mixture in boiler 58.

[0053] The cooled hydrogen-enriched reformed gas is fed from heat exchanger 76 via line 84 to a further heat exchanger 86 where it is further cooled with water. The cooling reduces the temperature of the gas mixture below the dew point so that the water condenses. The cooled stream is fed from heat exchanger 86 to a gas-liquid separator 88 where the condensate is separated from the hydrogen-enriched reformed gas mixture. The condensate is recovered from separator 88 via line 90. In this embodiment, the partially dehydrated hydrogen-enriched reformed gas mixture is recovered from separator 88 via line 92 and further cooled by heat exchange with water in heat exchanger 94. The cooled gas is sent to a second gas-liquid separator 96 to recover a further condensate stream 98. The condensate streams 90 and 98 are combined and sent as effluent 100 for water treatment.

[0054] The dehydrated hydrogen-enriched reformed gas mixture is supplied from separator 96 via line 102 to a CO2 removal unit 104 (such as an acid gas recovery unit operating with a liquid absorption scrubbing system that absorbs CO2 and any remaining H2O from the gas). The absorbed CO2 is recovered from the CO2-laden absorption liquid in unit 104 by heating it and reducing the pressure using steam supplied to unit 104 via line 106. The CO2-recovered water is separated and sent for water treatment (not shown). Steam condensate is recovered from CO2 removal unit 104 via line 108. The recovered CO2 from CO2 removal unit 104 is sent via line 110 for compression and storage.

[0055] A crude hydrogen gas stream is withdrawn from CO2 removal unit 104 and fed via line 112 to pressure swing adsorption unit 114, which contains a porous adsorbent that captures carbon oxides and methane in the crude hydrogen, thereby producing a purified hydrogen stream. Purified hydrogen gas is withdrawn from pressure swing adsorption unit 114 via line 116. A portion of the purified hydrogen is removed via line 118 and compressed to form recycle hydrogen stream 12. The remaining purified hydrogen in line 120 is compressed and sent either for storage, for power or heat generation, or for chemical production or conversion.

[0056] Pressure swing adsorption unit 114 adjusts the pressure to desorb the carbon oxides and methane trapped in the porous adsorbent, thereby generating fuel gas. The fuel gas is recovered from pressure swing adsorption unit 114 via line 122. A portion of the fuel gas in line 122 is provided via line 32 to first fired heater 30 as the sole fuel for that heater. A second portion of the fuel gas in line 122 is provided via line 126 to second fired heater 124 as the sole fuel.

[0057] A second fired heater 124 raises steam for the process by combustion of fuel gas provided via line 126 .

[0058] High pressure steam is withdrawn from steam drum 60 via line 128. A first portion, optionally after pressure reduction, is fed from line 128 via line 130 to heat the oxygen-enriched gas in heat exchanger 52. Condensate is withdrawn from heat exchanger 52 via line 132. A second portion is withdrawn from the remaining high pressure steam via lines 134 and 136 to second fired heater 124 for further heating to produce superheated steam that is fed to desulfurized natural gas stream 34 via line 36. A third portion is withdrawn from the remaining high pressure steam via line 138 to steam turbine 140 to generate electricity for processes, such as for driving air separation unit 50 and / or electrically driven compressors 144, 146, and 148.

[0059] A hot water stream may be taken from the preheated demineralized water in line 80 as shown, or from the preheated demineralized water in line 82, and supplied via line 150 to steam drum 152, where the heated water is circulated through second fired heater 124 via lines 154 and 156 to generate a stream at low pressure. Steam from steam drum 152 is recovered via line 106 and used to heat the CO2 absorbing solution in CO2 removal unit 104.

[0060] Efficient use of fuel gas to provide the heated natural gas feed stream(s) for the process minimizes CO2 emissions from the process.

[0061] Example 1 The present invention is further illustrated by the following calculated process example according to the flowsheet depicted in FIG.

[0062] [Table 1]

[0063] [Table 2]

[0064] [Table 3]

[0065] [Table 4]

[0066] [Table 5]

[0067] The flowsheet allows for 95% capture of CO2 at a steam to carbon ratio of 2.5:1.

[0068] Example 2 The present invention is further illustrated by the following calculated process example according to the flowsheet depicted in FIG. 1, with the following modifications: a) the operating pressure of the reforming unit operation is reduced to 26 barg; b) the steam to carbon ratio in the gaseous mixture comprising natural gas and steam fed to the pre-reformer 40 is 0.95:1; c) adding oxygen to the autothermal reformer to achieve an outlet temperature of 1065°C; d) steam raised in the steam lift boiler 58 is added to the cooled reformed gas 66, so that the feed at the inlet to the hot water gas shift has a steam to dry gas ratio of 0.72:1; e) the product gas from the high temperature water gas shift reactor 68 is cooled so that the feed gas to the low temperature water gas shift reactor 74 has an inlet temperature of 190°C; f) Adjusting the remaining combustion heater operating duties in the two combustion heaters 30 and 124 to provide for distribution of process steam addition both upstream and downstream of the reforming unit operation.

[0069] This configuration flowsheet also allows for 95% capture of CO2 at a steam to carbon ratio of 0.95:1, which reduces the heat demand and oxygen consumption in the autothermal reformer.

Claims

1. 1. A process for the production of hydrogen, comprising: (i) subjecting a gaseous mixture comprising hydrocarbons and steam and having a steam to carbon ratio of at least 0.9:1 to adiabatic pre-reforming in a pre-reformer followed by autothermal reforming with an oxygen-enriched gas in an autothermal reformer to generate a reformed gas mixture; (ii) increasing the hydrogen content of the reformed gas mixture by subjecting the reformed gas mixture to one or more water gas shift stages in a water gas shift unit to provide a hydrogen-enriched reformed gas; (iii) cooling the hydrogen-rich reformed gas and separating condensed water therefrom to provide a dehydrated hydrogen-rich reformed gas; (iv) passing the dehydrated hydrogen-rich reformed gas to a carbon dioxide separation unit to provide a carbon dioxide gas stream and a crude hydrogen gas stream; (v) passing the crude hydrogen gas stream from the carbon dioxide separation unit to a purification unit to provide purified hydrogen gas and a fuel gas; A process wherein all of said fuel gas is supplied to one or more fired heaters that are used to heat one or more process streams within said process.

2. 2. The process of claim 1, wherein the hydrocarbon is a methane-containing gas stream, preferably containing more than 50% methane by volume.

3. 3. The process of claim 1 or 2, wherein the hydrocarbon is desulfurized.

4. 4. The process of any one of claims 1 to 3, wherein the steam to carbon ratio is in the range of 0.9:1 to 3.5:

1.

5. 5. The process of any one of claims 1 to 4, wherein the steam to carbon ratio is in the range of 0.9:1 to 2.4:1, and the process comprises adding steam to the reformulated gas mixture.

6. 6. The process of any one of claims 1 to 5, wherein the gaseous mixture comprising the hydrocarbons and steam is formed by mixing the hydrocarbons with steam generated by the one or more combustion heaters and / or by cooling the reformed gas mixture with water.

7. The oxygen-enriched gas is at least 90% by volume O ２ , preferably at least 95% by volume O ２ , more preferably at least 98% by volume O ２ The process according to any one of claims 1 to 6, comprising:

8. A process according to any one of claims 1 to 7, wherein the oxygen-enriched gas is heated by heat exchange with steam generated by cooling the reformed gas before being supplied to the autothermal reformer.

9. The process of any one of claims 1 to 8, wherein the water gas shift stage comprises a high temperature shift stage and a downstream low temperature shift stage.

10. 10. The process of claim 9, wherein the hydrocarbon is heated by heat exchange with a shifted gas stream recovered from the high temperature shift stage.

11. 11. The process of any one of claims 1 to 10, wherein steam generated in the one or more fired heaters is used to generate power for the process.

12. A process as claimed in any one of claims 1 to 11, in which there are at least two stages of cooling and separation of the process condensate prior to the carbon dioxide separation stage.

13. A process according to any one of claims 1 to 12, wherein the carbon dioxide separation step is carried out using a physical or reactive scrubbing system, preferably a reactive scrubbing system, in particular an amine scrubbing system.

14. A process described in any one of claims 1 to 13, wherein one or more of the carbon dioxide separation unit streams are heated by heat exchange with steam generated in the one or more combustion heaters.

15. The process of any one of claims 1 to 14, wherein the purification unit is a pressure swing adsorption unit or a temperature swing adsorption unit, preferably a pressure swing adsorption unit.

16. 16. The process of any one of claims 1 to 15, wherein the carbon dioxide recovered from the carbon dioxide separation unit and the purified hydrogen gas recovered from the purification unit are each compressed in an electrically driven compressor.

17. The process of any one of claims 1 to 16, wherein a portion of the crude or purified hydrogen is fed to the hydrocarbon.

18. 18. A process according to any preceding claim, wherein supplemental fuel is added to the fuel gas supplied to the one or more fired heaters, the amount of supplemental fuel being less than 5% by volume of the total fuel provided, preferably less than 3% by volume, more preferably less than 2%.

19. 19. The process of any one of claims 1 to 18, wherein there is a single combustion heater at least partially fueled by the fuel gas recovered from the purification unit, said single combustion heater being used to heat the hydrocarbons, the reformed gas recovered from the pre-reforming stage upstream of the autothermal reforming stage, and water to generate at least a portion of the steam for the process.

20. 19. The process of any one of claims 1 to 18, wherein there are two fired heaters at least partially fueled by the fuel gas recovered from the refinery unit: a first fired heater that heats the hydrocarbon feed stream and a reformed gas stream recovered from the pre-reforming stage upstream of the autothermal reforming stage, and a second fired heater that functions as a boiler to generate steam for the process.

21. 21. The process of claim 20, wherein the fuel gas is split between the first and second fired heaters in the range of 10-90% by volume to 90-10% by volume, preferably 60-80% by volume to the first fired heater and 40-20% by volume to the second fired heater, respectively.

22. A portion of the steam generated in the second combustion heater is used to separate CO in a carbon dioxide separation unit. ２ 22. The process of claim 20 or 21, wherein the process is used to heat the absorption liquid.

23. 23. The process of any one of claims 20 to 22, wherein steam generated in the second fired heater is used to superheat steam recovered from a steam drum coupled to a waste heat boiler heated by the reformed gas.

24. 24. The process of claim 23, wherein the waste heat boiler is also used to generate steam used to preheat the oxygen-enriched gas.

25. 25. The process of claim 23 or 24, wherein a portion of the steam from the waste heat boiler is routed to a steam expander to generate electricity.

26. 26. The process of any one of claims 23 to 25, wherein a portion of the steam from the waste heat boiler is added to the reformed gas if the steam to carbon ratio is less than 2.4:

1.

27. 27. A process according to any one of claims 1 to 26, wherein the pure hydrogen stream is used in a downstream power process, a heating process, a downstream chemical synthesis process or for upgrading hydrocarbons.

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