Epoxy resin composition and electronic component device

Abstract

To provide an epoxy resin composition which has low viscosity and maintains good curability while having excellent thermal conductivity, and an electronic component device including an element sealed using the same.SOLUTION: The epoxy resin composition contains: an epoxy resin; a curing agent; alumina particles; and a silane compound which does not have a functional group reactive with an epoxy group but has a functional group unreactive with an epoxy group, and has a structure in which the functional group unreactive with an epoxy group is bonded to a silicon atom or is bonded to the silicon atom via a C1-5 chain hydrocarbon group.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present disclosure relates to an epoxy resin composition and an electronic component device. [Background technology]

[0002] BACKGROUND ART Conventionally, packages (electronic component devices) in which elements such as transistors and ICs are sealed with resin such as epoxy resin have been widely used in electronic devices.

[0003] In recent years, the amount of heat generated has tended to increase with the miniaturization and increased density of electronic component devices, making how to dissipate heat an important issue. To address this issue, inorganic fillers with high thermal conductivity have been mixed into sealing materials to increase thermal conductivity.

[0004] When an inorganic filler is mixed into an encapsulant, the viscosity of the encapsulant increases as the amount of the inorganic filler increases, reducing the fluidity, which may result in problems such as insufficient filling, wire sweep, etc. Therefore, a method has been proposed in which a specific phosphorus compound is used as a curing accelerator to increase the fluidity of the encapsulant (see, for example, Patent Document 1). [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Publication No. 9-157497 Summary of the Invention [Problem to be solved by the invention]

[0006] However, with the further progress in miniaturization and high density of electronic component devices, there is a demand for a resin composition that can be used as an encapsulant, which can suppress an increase in viscosity while maintaining a higher level of thermal conductivity. It is also required that the resin composition suppresses an increase in viscosity while not impairing curability during molding. In view of the above circumstances, an object of the present disclosure is to provide an epoxy resin composition that has excellent thermal conductivity, low viscosity, and good curability, and an electronic component device including an element encapsulated with the epoxy resin composition. [Means for solving the problem]

[0007] The means for solving the above problems include the following aspects. <1> The epoxy resin composition comprises an epoxy resin, a curing agent, alumina particles, and a silane compound having a structure in which the functional group that does not react with an epoxy group but does have a functional group that does not react with an epoxy group is bonded to a silicon atom or to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms. <2> The content of the silane compound is 0.01% by mass to 20% by mass with respect to the total amount of the epoxy resin. <1> The epoxy resin composition according to claim 1. <3> the functional group that does not react with an epoxy group is at least one selected from the group consisting of a (meth)acryloyl group, a (meth)acryloyloxy group, and a vinyl group; <1> or <2> The epoxy resin composition according to claim 1. <4> The silane compound includes 3-methacryloxypropyltrimethoxysilane. <1> ~ <3> 10. The epoxy resin composition according to claim 1, wherein the epoxy resin composition is <5> The content of the alumina particles is 50% by volume or more. <1> ~ <4> 10. The epoxy resin composition according to claim 1, wherein the epoxy resin composition is <6> Further containing silica particles, <1> ~ <5> 10. The epoxy resin composition according to claim 1, wherein the epoxy resin composition is <7> <1> ~ <6> 1. An electronic component device comprising an element encapsulated with the epoxy resin composition according to any one of claims 1 to 9. [Effects of the Invention]

[0008] According to the present disclosure, there are provided an epoxy resin composition that has excellent thermal conductivity, low viscosity, and maintains good curability, and an electronic component device including an element encapsulated with the epoxy resin composition. DETAILED DESCRIPTION OF THE INVENTION

[0009] Hereinafter, embodiments for carrying out the present invention will be described in detail. However, the present invention is not limited to the following embodiments. In the following embodiments, components (including element steps, etc.) are not essential unless otherwise specified. The same applies to numerical values ​​and their ranges, and do not limit the present invention. In the present disclosure, a numerical range indicated using "to" indicates a range that includes the numerical values ​​before and after "to" as the minimum and maximum values, respectively. In the numerical ranges described in stages in this disclosure, the upper or lower limit value described in one numerical range may be replaced with the upper or lower limit value of another numerical range described in stages. Furthermore, in the numerical ranges described in this disclosure, the upper or lower limit value of that numerical range may be replaced with a value shown in the examples. In the present disclosure, each component may contain multiple substances corresponding to the component. When multiple substances corresponding to each component are present in the composition, the content or amount of each component means the total content or amount of the multiple substances present in the composition, unless otherwise specified. In the present disclosure, multiple types of particles corresponding to each component may be contained. When multiple types of particles corresponding to each component are present in the composition, the particle size of each component means the value for a mixture of the multiple types of particles present in the composition, unless otherwise specified. In the present disclosure, a (meth)acryloyl group means at least one of an acryloyl group and a methacryloyl group, and a (meth)acryloyloxy group (also referred to as a (meth)acryloxy group) means at least one of an acryloyloxy group and a methacryloyloxy group.

[0010] <Epoxy resin composition> The epoxy resin composition of the present disclosure contains an epoxy resin, a curing agent, alumina particles, and a silane compound having a structure in which the silane compound does not have a functional group reactive with an epoxy group but has a functional group that does not react with an epoxy group, and the functional group that does not react with an epoxy group is bonded to a silicon atom or is bonded to the silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms. In the present disclosure, the "silane compound having a structure in which the silane compound does not have a functional group reactive with an epoxy group but has a functional group that does not react with an epoxy group, and the functional group that does not react with an epoxy group is bonded to a silicon atom or is bonded to the silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms" is also referred to as the "specific silane compound." The epoxy resin composition may contain other components as needed.

[0011] The above-described configuration makes it possible to obtain an epoxy resin composition that has excellent thermal conductivity, suppresses an increase in viscosity, and maintains good curability. The detailed reasons why the epoxy resin composition of the present disclosure exhibits the above-described effects are not necessarily clear, but are presumed to be as follows. Generally, when a silane compound is used as a coupling agent in an epoxy resin composition, a silane compound having a functional group reactive with the epoxy resin is often used, with the main purpose being to increase the dispersibility of the inorganic filler in the epoxy resin and the fluidity of the composition by chemical bonding between the silanol group of the silane compound and the inorganic filler, and between the functional group of the silane compound and the epoxy resin. On the other hand, the specific silane compound in the epoxy resin composition of the present disclosure has a functional group that does not react with epoxy groups, but does not have a functional group that does react with epoxy groups, and is therefore believed to be present on the surface of the alumina particles without bonding to the epoxy resin. Due to the nature of their surface condition, alumina particles generally tend to reduce the fluidity of resin compositions. However, when the specific silane compound is present on the surface of the alumina particles, the specific silane compound functions as a lubricant, which is believed to improve the compatibility of the alumina particles with the resin. This is presumably to reduce the frictional resistance between the alumina particles and reduce the melt viscosity. Furthermore, since the increase in viscosity of the epoxy resin composition is suppressed, it is believed that it is possible to increase the amount of alumina particles incorporated, thereby further improving thermal conductivity. On the other hand, while an increase in components that do not contribute to curing generally poses a risk of reducing curability, the use of specific silane compounds does not significantly reduce the curability of epoxy resin compositions. The reason for this is unclear, but it is presumed that this is because the specific silane compounds have a structure in which a functional group that does not react with epoxy groups is bonded to the silicon atom, or is bonded to the silicon atom via a hydrocarbon group with a chain length of 5 or less carbon atoms, so the distance between the silicon and the functional group is relatively short and the curing reaction of the epoxy resin composition is unlikely to be hindered.

[0012] (epoxy resin) The epoxy resin composition contains an epoxy resin. The type of the epoxy resin is not particularly limited as long as it has an epoxy group in the molecule. Specific examples of epoxy resins include novolac epoxy resins (phenol novolac epoxy resins, orthocresol novolac epoxy resins, etc.) obtained by epoxidizing novolac resins obtained by condensing or co-condensing, under an acidic catalyst, at least one phenolic compound selected from the group consisting of phenolic compounds such as phenol, cresol, xylenol, resorcinol, catechol, bisphenol A, bisphenol F, etc., and naphthol compounds such as α-naphthol, β-naphthol, dihydroxynaphthalene, etc., with an aliphatic aldehyde compound such as formaldehyde, acetaldehyde, propionaldehyde, etc.; triphenylmethane epoxy resins obtained by epoxidizing triphenylmethane phenolic resins obtained by condensing or co-condensing, under an acidic catalyst, the above-mentioned phenolic compound with an aromatic aldehyde compound such as benzaldehyde, salicylaldehyde, etc.; and novolac resins obtained by co-condensing, under an acidic catalyst, the above-mentioned phenolic compound and naphthol compound with an aldehyde compound. diphenylmethane-type epoxy resins, which are diglycidyl ethers of bisphenol A, bisphenol F, etc.; biphenyl-type epoxy resins, which are diglycidyl ethers of alkyl-substituted or unsubstituted biphenols; stilbene-type epoxy resins, which are diglycidyl ethers of stilbene-based phenolic compounds; sulfur-containing epoxy resins, which are diglycidyl ethers of bisphenol S, etc.; epoxy resins, which are glycidyl ethers of alcohols such as butanediol, polyethylene glycol, and polypropylene glycol; glycidyl ester-type epoxy resins, which are glycidyl esters of polycarboxylic acids such as phthalic acid, isophthalic acid, and tetrahydrophthalic acid; glycidylamine-type epoxy resins, in which the active hydrogen bonded to the nitrogen atom of aniline, diaminodiphenylmethane, isocyanuric acid, etc. is substituted with a glycidyl group; and dicyclopentadiene-type epoxy resins, which are epoxidized co-condensation resins of dicyclopentadiene and phenolic compounds.Alicyclic epoxy resins such as vinylcyclohexene diepoxide, 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, and 2-(3,4-epoxy)cyclohexyl-5,5-spiro(3,4-epoxy)cyclohexane-m-dioxane, which are produced by epoxidizing the olefin bonds in the molecule; paraxylylene-modified epoxy resins, which are glycidyl ethers of paraxylylene-modified phenolic resins; metaxylylene-modified epoxy resins, which are glycidyl ethers of metaxylylene-modified phenolic resins; terpene-modified epoxy resins, which are glycidyl ethers of terpene-modified phenolic resins; and dicyclopentadiene-modified phenolic resins, which are glycidyl ethers of dicyclopentadiene-modified phenolic resins. Examples of suitable epoxy resins include pentadiene-modified epoxy resins, cyclopentadiene-modified epoxy resins, which are glycidyl ethers of cyclopentadiene-modified phenolic resins; polycyclic aromatic ring-modified epoxy resins, which are glycidyl ethers of polycyclic aromatic ring-modified phenolic resins; naphthalene-type epoxy resins, which are glycidyl ethers of naphthalene ring-containing phenolic resins; halogenated phenol novolac-type epoxy resins; hydroquinone-type epoxy resins; trimethylolpropane-type epoxy resins; linear aliphatic epoxy resins obtained by oxidizing olefin bonds with peracids such as peracetic acid; and aralkyl-type epoxy resins obtained by epoxidizing aralkyl-type phenolic resins such as phenol aralkyl resins and naphthol aralkyl resins. Further examples of suitable epoxy resins include epoxidized silicone resins and epoxidized acrylic resins. These epoxy resins may be used alone or in combination of two or more.

[0013] The epoxy equivalent (molecular weight / number of epoxy groups) of the epoxy resin is not particularly limited, but from the viewpoint of a balance of various properties such as moldability, reflow resistance, and electrical reliability, it is preferably 100 g / eq to 1000 g / eq, and more preferably 150 g / eq to 500 g / eq.

[0014] The epoxy equivalent of the epoxy resin is a value measured by a method in accordance with JIS K 7236:2009.

[0015] When the epoxy resin is solid, the softening point or melting point of the epoxy resin is not particularly limited, but is preferably 40°C to 180°C from the viewpoint of moldability and reflow resistance, and more preferably 50°C to 130°C from the viewpoint of handleability during preparation of the epoxy resin composition.

[0016] The melting point of the epoxy resin is a value measured by differential scanning calorimetry (DSC), and the softening point of the epoxy resin is a value measured by a method (ring and ball method) in accordance with JIS K 7234:1986.

[0017] The content of the epoxy resin in the epoxy resin composition is preferably 0.5% by mass to 50% by mass, more preferably 2% by mass to 30% by mass, and even more preferably 2% by mass to 20% by mass, from the viewpoints of strength, fluidity, heat resistance, moldability, etc.

[0018] (hardening agent) The epoxy resin composition contains a curing agent. The type of curing agent is not particularly limited and can be selected depending on the type of resin, the desired properties of the epoxy resin composition, and the like. Examples of the curing agent include a phenol curing agent, an amine curing agent, an acid anhydride curing agent, a polymercaptan curing agent, a polyaminoamide curing agent, an isocyanate curing agent, a blocked isocyanate curing agent, etc. From the viewpoint of improving heat resistance, the curing agent is preferably one having a phenolic hydroxyl group in the molecule (phenol curing agent).

[0019] Specific examples of phenolic curing agents include polyhydric phenolic compounds such as resorcinol, catechol, bisphenol A, bisphenol F, and substituted or unsubstituted biphenols; novolak-type phenolic resins obtained by condensing or co-condensing at least one phenolic compound selected from the group consisting of phenolic compounds such as phenol, cresol, xylenol, resorcinol, catechol, bisphenol A, bisphenol F, phenylphenol, and aminophenol, and naphthol compounds such as α-naphthol, β-naphthol, and dihydroxynaphthalene, with an aldehyde compound such as formaldehyde, acetaldehyde, propionaldehyde, benzaldehyde, and salicylaldehyde, under an acidic catalyst; and copolymers of the above phenolic compounds with dimethoxyparaxylene, bis(methoxymethyl)bis(benzoyl)methyl ... Examples of suitable phenol curing agents include aralkyl phenolic resins such as phenol aralkyl resins and naphthol aralkyl resins synthesized from phenyl, etc.; paraxylylene and / or metaxylylene-modified phenolic resins; melamine-modified phenolic resins; terpene-modified phenolic resins; dicyclopentadiene-type phenolic resins and dicyclopentadiene-type naphthol resins synthesized by copolymerization of the above phenolic compounds with dicyclopentadiene; cyclopentadiene-modified phenolic resins; polycyclic aromatic ring-modified phenolic resins; biphenyl-type phenolic resins; triphenylmethane-type phenolic resins obtained by condensing or co-condensing the above phenolic compounds with aromatic aldehyde compounds such as benzaldehyde and salicylaldehyde under an acidic catalyst; and phenolic resins obtained by copolymerizing two or more of these. These phenolic curing agents may be used alone or in combination of two or more.

[0020] Among these, biphenyl-type phenolic resins are preferred from the viewpoint of flame retardancy, aralkyl-type phenolic resins are preferred from the viewpoint of reflow resistance and curability, dicyclopentadiene-type phenolic resins are preferred from the viewpoint of low moisture absorption, triphenylmethane-type phenolic resins are preferred from the viewpoint of heat resistance, low expansion coefficient, and low warpage, and novolac-type phenolic resins are preferred from the viewpoint of curability. The epoxy resin composition preferably contains at least one of these phenolic resins.

[0021] The functional group equivalent of the curing agent (hydroxyl group equivalent in the case of a phenolic curing agent) is not particularly limited, but from the viewpoint of the balance of various properties such as moldability, reflow resistance, and electrical reliability, it is preferably 70 g / eq to 1000 g / eq, and more preferably 80 g / eq to 500 g / eq.

[0022] The functional group equivalent of the curing agent (hydroxyl group equivalent in the case of a phenolic curing agent) is a value measured by a method in accordance with JIS K 0070:1992.

[0023] When the curing agent is solid, the softening point or melting point of the curing agent is not particularly limited, but is preferably 40°C to 180°C from the viewpoint of moldability and reflow resistance, and more preferably 50°C to 130°C from the viewpoint of handleability during production of the epoxy resin composition.

[0024] The melting point or softening point of the curing agent is a value measured in the same manner as the melting point or softening point of the epoxy resin.

[0025] The equivalent ratio between the epoxy resin and the curing agent, i.e., the ratio of the number of functional groups in the curing agent to the number of epoxy groups in the epoxy resin (number of functional groups in the curing agent / number of epoxy groups in the epoxy resin), is not particularly limited. From the viewpoint of minimizing unreacted components, the equivalent ratio between the epoxy resin and the curing agent is preferably set in the range of 0.5 to 2.0, more preferably in the range of 0.6 to 1.3. From the viewpoints of moldability and reflow resistance, the equivalent ratio between the epoxy resin and the curing agent is more preferably set in the range of 0.8 to 1.2.

[0026] (alumina particles) The epoxy resin composition contains alumina particles as an inorganic filler. The epoxy resin composition may contain an inorganic filler other than alumina particles.

[0027] The content of alumina particles in the epoxy resin composition is not particularly limited. From the viewpoint of thermal conductivity of the cured product, the content of alumina particles is preferably 30% by volume or more, more preferably 35% by volume or more, even more preferably 40% by volume or more, particularly preferably 45% by volume or more, and extremely preferably 50% by volume or more, based on the total amount of the epoxy resin composition. The upper limit of the alumina particle content is not particularly limited, and from the viewpoint of improving fluidity and reducing viscosity, it is preferably less than 100% by volume, more preferably 99% by volume or less, and even more preferably 98% by volume or less. The content of alumina particles in the epoxy resin composition is preferably 30% by volume or more but less than 100% by volume, more preferably 35% to 99% by volume, even more preferably 40% to 98% by volume, particularly preferably 45% to 98% by volume, and extremely preferably 50% to 98% by volume. The content of alumina particles in the epoxy resin composition can be measured, for example, by the method for measuring the content of inorganic fillers described below.

[0028] The volume average particle diameter of the alumina particles is not particularly limited. The volume average particle diameter of the alumina particles is preferably 0.1 μm or more, more preferably 0.3 μm or more. Furthermore, the volume average particle diameter of the alumina particles is preferably 80 μm or less, more preferably 50 μm or less. When the volume average particle diameter of the alumina particles is 0.1 μm or more, an increase in the viscosity of the epoxy resin composition is easily suppressed. Furthermore, when the volume average particle diameter of the alumina particles is 80 μm or less, the mixing of the alumina particles in the epoxy resin composition is improved, uneven distribution of the alumina particles is suppressed, and variations in thermal conductivity in the cured product tend to be suppressed. Furthermore, even when used to seal a narrow area, the alumina particles tend to have excellent packing properties. The volume average particle diameter of the alumina particles can be measured, for example, using a laser scattering diffraction particle size distribution analyzer. In the present disclosure, the volume average particle diameter can be measured as the particle diameter (D50) at which the cumulative amount from the small diameter side reaches 50% in a volume-based particle size distribution measured by a laser scattering diffraction particle size distribution measuring device.

[0029] The shape of the alumina particles is not limited, and examples include spherical and angular shapes. From the viewpoint of flowability, the particle shape of the alumina particles is preferably spherical, and the particle size distribution of the alumina particles is preferably wide. For example, when the alumina particles are blended in an epoxy resin composition at 75% by volume or more, it is preferable that 70% by mass or more of the total amount of alumina particles be spherical particles, and that the particle diameter of the spherical particles be distributed over a wide range of 0.1 μm to 80 μm. Such alumina particles tend to have a close-packed structure, so even if the blending amount is increased, there is little increase in the viscosity of the material, and an epoxy resin composition with excellent flowability tends to be obtained.

[0030] The epoxy resin composition may contain an inorganic filler other than alumina particles. The inorganic filler other than alumina particles is not particularly limited, and examples thereof include inorganic particles such as fused silica, crystalline silica, glass, calcium carbonate, zirconium silicate, calcium silicate, silicon nitride, aluminum nitride, boron nitride, magnesium oxide, silicon carbide, beryllia, zirconia, zircon, fosterite, steatite, spinel, mullite, titania, talc, clay, and mica. An inorganic filler having a flame-retardant effect may also be used. Examples of the inorganic filler having a flame-retardant effect include aluminum hydroxide, magnesium hydroxide, composite metal hydroxides such as magnesium-zinc composite hydroxide, and zinc borate. One type of inorganic filler may be used alone, or two or more types may be used in combination. In particular, from the viewpoint of the balance of various properties such as the thermal conductivity and thermal expansion coefficient of the cured product, it is preferable to use alumina particles and silica particles in combination. Furthermore, from the viewpoint of thermal conductivity, it is also preferable to use magnesium oxide in combination.

[0031] The inorganic fillers other than alumina particles may be used singly or in combination of two or more. The term "use of two or more inorganic fillers" refers to, for example, the use of two or more inorganic fillers having the same components but different volume average particle sizes, the use of two or more inorganic fillers having the same volume average particle size but different components, and the use of two or more inorganic fillers having different volume average particle sizes and types.

[0032] The content of the inorganic filler in the total mass of the epoxy resin composition is not particularly limited. From the viewpoint of the thermal conductivity of the cured product, the content of the inorganic filler is preferably 30% by volume or more, more preferably 35% by volume or more, even more preferably 40% by volume or more, particularly preferably 45% by volume or more, and extremely preferably 50% by volume or more, relative to the total amount of the epoxy resin composition. The upper limit of the content of the inorganic filler is not particularly limited, and from the viewpoint of improving fluidity and reducing viscosity, it is preferably less than 100% by volume, more preferably 99% by volume or less, and even more preferably 98% by volume or less. The content of the inorganic filler in the epoxy resin composition is preferably 30% by volume or more but less than 100% by volume, more preferably 35 to 99% by volume, even more preferably 40 to 98% by volume, particularly preferably 45 to 98% by volume, and extremely preferably 50 to 98% by volume.

[0033] The content of inorganic filler in the total mass of an epoxy resin composition is measured as follows. First, the total mass of a cured product of the epoxy resin composition (also referred to as an epoxy resin molded product) is measured, and the epoxy resin molded product is baked at 400°C for 2 hours and then at 700°C for 3 hours to evaporate the resin components, and the mass of the remaining inorganic filler is measured. The volume is calculated from the obtained mass and specific gravity, and the ratio of the volume of the inorganic filler to the total volume of the cured product of the epoxy resin composition (epoxy resin molded product) is determined as the inorganic filler content.

[0034] The inorganic filler may have a controlled maximum particle size (also referred to as cut point) in order to improve filling properties into narrow gaps when the epoxy resin composition is used for mold underfill, etc. The maximum particle size of the inorganic filler may be adjusted as appropriate, and from the viewpoint of filling properties, it is preferably 105 μm or less, more preferably 75 μm or less, and may be 60 μm or less, or may be 40 μm or less. The maximum particle size can be measured using a laser diffraction particle size distribution analyzer (manufactured by Horiba, Ltd., product name: LA920).

[0035] When the epoxy resin composition contains alumina particles and inorganic fillers other than alumina particles as inorganic fillers, the content of the alumina particles relative to the total amount of the inorganic fillers is preferably 30% by mass or more, more preferably 35% by mass or more, and even more preferably 40% by mass or more. The upper limit of the content of the alumina particles relative to the total amount of the inorganic fillers is not particularly limited, and may be 100% by mass or less, 90% by mass or less, or 85% by mass or less.

[0036] (Specific silane compounds) The epoxy resin composition contains a specific silane compound. The specific silane compound does not have a functional group that reacts with an epoxy group, but does have a functional group that does not react with an epoxy group, and has a structure in which the functional group that does not react with an epoxy group is bonded to a silicon atom or is bonded to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms. Hereinafter, the functional group in the specific silane compound that does not react with an epoxy group will also be referred to as the "specific functional group."

[0037] A "functional group that does not react with an epoxy group" refers to a functional group that does not undergo a chemical reaction with an epoxy group or that reacts so slowly that the change in the properties of the epoxy resin composition due to the reaction is negligible in practical terms. A "functional group that reacts with an epoxy group" refers to a functional group other than a functional group that does not react with an epoxy group. A "functional group" of a silane compound refers to an atom or atomic group that is present in the molecule of the silane compound and that causes the reactivity of the silane compound. The fact that the functional group of a silane compound does not react with an epoxy group can be confirmed, for example, by differential scanning calorimetry (DSC). In the above-mentioned "structure in which a functional group that does not react with an epoxy group is bonded to a silicon atom, or is bonded to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms," the "structure in which a functional group that does not react with an epoxy group is bonded to a silicon atom" refers to a structure in which a specific functional group is directly bonded to a silicon atom.

[0038] Examples of the specific functional group include a (meth)acryloyl group, a (meth)acryloyloxy group, a vinyl group, and a styryl group. On the other hand, examples of the "functional group that reacts with an epoxy group" include an amino group, a group having an amine structure such as a phenylamino group, an epoxy group, a thiol group, an isocyanate group, an isocyanurate group, and a ureido group. The specific functional group is preferably at least one selected from the group consisting of a (meth)acryloyl group, a (meth)acryloyloxy group, and a vinyl group, and more preferably a (meth)acryloyloxy group.

[0039] The specific silane compound may have one or more specific functional groups per molecule. The number of specific functional groups per molecule of the specific silane compound is preferably 1 to 4, more preferably 1 to 3, even more preferably 1 or 2, and particularly preferably 1.

[0040] In the specific silane compound, the specific functional group is bonded to a silicon atom or bonded to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms. When the specific functional group is bonded to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms, from the viewpoints of viscosity reduction and moldability, the number of carbon atoms in the chain hydrocarbon group is preferably 2 to 4, and more preferably 3. In the present disclosure, the number of carbon atoms in the chain hydrocarbon group means the number of carbon atoms excluding carbon atoms in branches or substituents. When the specific functional group is bonded to the silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms, the specific functional group may be present at the end of the chain hydrocarbon group or on a side chain of the chain hydrocarbon group. From the viewpoint of suppressing viscosity, the specific functional group is preferably present at the end of the chain hydrocarbon group.

[0041] The chain hydrocarbon group may have a branched chain. When the chain hydrocarbon group has a branched chain, the number of carbon atoms in the branched chain is preferably 1 or 2. It is preferable that the chain hydrocarbon group does not have a branched chain. The chain hydrocarbon group may have a substituent in addition to the specific functional group. When the chain hydrocarbon group has a substituent, the substituent is not particularly limited and may be an alkoxy group, an aryl group, an aryloxy group, or the like. It is preferable that the chain hydrocarbon group does not have a substituent in addition to the specific functional group. The chain hydrocarbon group may or may not contain an unsaturated bond, and preferably does not contain an unsaturated bond.

[0042] Hereinafter, a specific functional group directly bonded to a silicon atom, or a group bonded to a silicon atom and having the chain hydrocarbon group having 1 to 5 carbon atoms and a specific functional group, will be referred to as a "group containing a specific functional group." The number of groups containing a specific functional group in the specific silane compound may be 1 to 4, preferably 1 to 3, more preferably 1 or 2, and even more preferably 1. When the number of groups containing a specific functional group is 1 to 3, the other groups bonded to the silicon atom are not particularly limited and may each independently be a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an aryl group, an aryloxy group, etc., preferably an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, and more preferably a methyl group, ethyl group, methoxy group, or ethoxy group. Among these, it is preferable that one group containing a specific functional group is bonded to the silicon atom, and that the other three bonds are each independently bonded to an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms. It is more preferable that one group containing a specific functional group is bonded to the silicon atom, and that the other three bonds are each independently bonded to a methyl group, ethyl group, methoxy group, or ethoxy group.

[0043] Examples of the specific silane compound include 3-(meth)acryloxypropylmethyldimethoxysilane, 3-(meth)acryloxypropyltrimethoxysilane, 3-(meth)acryloxypropylmethyldiethoxysilane, 3-(meth)acryloxypropyltriethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, and p-styryltrimethoxysilane. Among these, 3-(meth)acryloxypropyltrimethoxysilane is preferred from the viewpoints of inhibiting an increase in the viscosity of the epoxy resin composition and of curing properties. The specific silane compounds may be used alone or in combination of two or more.

[0044] The specific silane compound may be synthesized or may be commercially available. Examples of commercially available specific silane compounds include KBM-502 (3-methacryloxypropylmethyldimethoxysilane), KBM-503 (3-methacryloxypropyltrimethoxysilane), KBE-502 (3-methacryloxypropylmethyldiethoxysilane), KBE-503 (3-methacryloxypropyltriethoxysilane), and KBM-5103 (3-acryloxypropyltrimethoxysilane), all of which are manufactured by Shin-Etsu Chemical Co., Ltd.

[0045] The content of the specific silane compound in the epoxy resin composition is not particularly limited. The content of the specific silane compound is preferably 0.01% by mass to 20% by mass relative to the total amount of epoxy resin. For example, from the viewpoint of the balance between the viscosity and curability of the composition, the content of the specific silane compound may be 0.01% by mass to 10% by mass relative to the total amount of epoxy resin. Furthermore, from the viewpoint of further suppressing an increase in viscosity, the content of the specific silane compound may be 10% by mass to 20% by mass, or even 15% by mass to 20% by mass, relative to the total amount of epoxy resin.

[0046] The epoxy resin composition may further contain other silane compounds in addition to the specific silane compound. The other silane compounds are not particularly limited as long as they are commonly used in epoxy resin compositions, and may be silane compounds that react with epoxy groups or silane compounds that do not react with epoxy groups. Examples of other silane compounds include epoxy silanes, mercaptosilanes, aminosilanes, alkylsilanes, ureidosilanes, (meth)acrylic silanes (excluding the specific silane compounds), and vinylsilanes (excluding the specific silane compounds). The other silane compounds may be used alone or in combination of two or more.

[0047] From the viewpoint of effectively exerting the effect of the specific silane compound, the content of the other silane compounds relative to the total amount of the specific silane compound and the other silane compounds is preferably 30% by mass or less, more preferably 20% by mass or less, and even more preferably 10% by mass or less.

[0048] The epoxy resin composition may contain a coupling agent other than a silane compound. Examples of the coupling agent other than a silane compound include known coupling agents such as titanium compounds, aluminum chelate compounds, and aluminum / zirconium compounds. The other coupling agents may be used alone or in combination of two or more.

[0049] (curing accelerator) The epoxy resin composition may contain a curing accelerator. The type of curing accelerator is not particularly limited and can be selected depending on the type of epoxy resin, the desired properties of the epoxy resin composition, and the like. Examples of the curing accelerator include diazabicycloalkenes such as 1,5-diazabicyclo[4.3.0]nonene-5 (DBN) and 1,8-diazabicyclo[5.4.0]undecene-7 (DBU), cyclic amidine compounds such as 2-methylimidazole, 2-phenylimidazole, 2-phenyl-4-methylimidazole, and 2-heptadecylimidazole; derivatives of the cyclic amidine compounds; phenol novolac salts of the cyclic amidine compounds or their derivatives; and the addition of maleic anhydride, 1,4-benzoquinone, 2,5-toluquinone, 1,4-naphthoquinone, or the like to these compounds. quinone compounds such as quinone, 2,3-dimethylbenzoquinone, 2,6-dimethylbenzoquinone, 2,3-dimethoxy-5-methyl-1,4-benzoquinone, 2,3-dimethoxy-1,4-benzoquinone, and phenyl-1,4-benzoquinone; compounds with intramolecular polarization obtained by adding compounds with π bonds such as diazophenylmethane; cyclic amidines such as tetraphenylborate salt of DBU, tetraphenylborate salt of DBN, tetraphenylborate salt of 2-ethyl-4-methylimidazole, and tetraphenylborate salt of N-methylmorpholine; ammonium compounds; tertiary amine compounds such as pyridine, triethylamine, triethylenediamine, benzyldimethylamine, triethanolamine, dimethylaminoethanol, and tris(dimethylaminomethyl)phenol; derivatives of the above tertiary amine compounds; ammonium salt compounds such as tetra-n-butylammonium acetate, tetra-n-butylammonium phosphate, tetraethylammonium acetate, tetra-n-hexylammonium benzoate, and tetrapropylammonium hydroxide; tertiary phosphines such as triphenylphosphine, diphenyl(p-tolyl)phosphine, tris(alkylphenyl)phosphine, tris(alkoxyphenyl)phosphine, tris(alkylalkoxyphenyl)phosphine, tris(dialkylphenyl)phosphine, tris(trialkylphenyl)phosphine, tris(tetraalkylphenyl)phosphine, tris(dialkoxyphenyl)phosphine, tris(trialkoxyphenyl)phosphine, tris(tetraalkoxyphenyl)phosphine, trialkylphosphine, dialkylarylphosphine, and alkyldiarylphosphine;Phosphine compounds such as complexes of the above-mentioned tertiary phosphines and organoborons; compounds having intramolecular polarization obtained by adding the above-mentioned tertiary phosphines or the above-mentioned phosphine compounds to maleic anhydride, quinone compounds such as 1,4-benzoquinone, 2,5-toluquinone, 1,4-naphthoquinone, 2,3-dimethylbenzoquinone, 2,6-dimethylbenzoquinone, 2,3-dimethoxy-5-methyl-1,4-benzoquinone, 2,3-dimethoxy-1,4-benzoquinone, and phenyl-1,4-benzoquinone, and compounds having a π bond such as diazophenylmethane; compounds having intramolecular polarization obtained by adding the above-mentioned tertiary phosphines or the above-mentioned phosphine compounds to 4-bromophenol, 3-bromophenol, 2-bromophenol, 4-chlorophenol, 3-chlorophenol, 2-chlorophenol, 4-iodophenol, and 3-iodophenol; Examples of the curing accelerator include compounds with intramolecular polarization obtained by reacting a halogenated phenol compound such as phenol, 2-iodophenol, 4-bromo-2-methylphenol, 4-bromo-3-methylphenol, 4-bromo-2,6-dimethylphenol, 4-bromo-3,5-dimethylphenol, 4-bromo-2,6-di-t-butylphenol, 4-chloro-1-naphthol, 1-bromo-2-naphthol, 6-bromo-2-naphthol, or 4-bromo-4'-hydroxybiphenyl with a dehydrohalogenation process; tetra-substituted phosphonium compounds such as tetraphenylphosphonium; tetra-substituted phosphonium compounds and tetra-substituted borates without a phenyl group bonded to the boron atom, such as tetra-p-tolylborate; and salts of tetraphenylphosphonium compounds with phenol compounds. The curing accelerator may be used alone or in combination of two or more.

[0050] When the epoxy resin composition contains a curing accelerator, the content thereof is preferably 0.1 to 30 parts by mass, and more preferably 1 to 15 parts by mass, per 100 parts by mass of the resin component (i.e., the total of the resin and curing agent). When the amount of the curing accelerator is 0.1 part by mass or more per 100 parts by mass of the resin component, good curing tends to occur in a short time. When the amount of the curing accelerator is 30 parts by mass or less per 100 parts by mass of the resin component, the curing speed is not too fast, and good molded products tend to be obtained.

[0051] [Various additives] In addition to the above components, the epoxy resin composition may contain various additives such as ion exchangers, mold release agents, flame retardants, colorants, stress relaxants, etc. exemplified below. The epoxy resin composition may contain various additives well-known in the art as needed in addition to the additives exemplified below.

[0052] (Ion exchanger) The epoxy resin composition may contain an ion exchanger. In particular, when the epoxy resin composition is used as a molding material for encapsulation, it is preferable to contain an ion exchanger from the viewpoint of improving the moisture resistance and high-temperature storage characteristics of an electronic component device provided with the element to be encapsulated. The ion exchanger is not particularly limited, and conventionally known ones can be used. Specifically, hydrotalcite compounds, and hydrated oxides of at least one element selected from the group consisting of magnesium, aluminum, titanium, zirconium, and bismuth can be mentioned. The ion exchanger may be used alone or in combination of two or more. Among them, hydrotalcite represented by the following general formula (A) is preferable.

[0053] Mg (1-X) Al X (OH)2(CO3) X / 2 ·mH2O ……(A) (0 < X ≦ 0.5, m is a positive number)

[0054] When the epoxy resin composition contains an ion exchanger, its content is not particularly limited as long as it is sufficient to capture ions such as halogen ions. For example, it is preferably 0.1 part by mass to 30 parts by mass, and more preferably 1 part by mass to 10 parts by mass with respect to 100 parts by mass of the resin component.

[0055] (Mold release agent) The epoxy resin composition may contain a mold release agent from the viewpoint of obtaining good releasability from the mold during molding. There are no particular limitations on the mold release agent, and conventionally known ones can be used. Specific examples include carnauba wax, higher fatty acids such as montanic acid and stearic acid, higher fatty acid metal salts, ester waxes such as montanic acid esters, and polyolefin waxes such as oxidized polyethylene and non-oxidized polyethylene. One type of mold release agent may be used alone, or two or more types may be used in combination.

[0056] When the epoxy resin composition contains a release agent, the content thereof is preferably 0.01 to 10 parts by mass, more preferably 0.1 to 5 parts by mass, per 100 parts by mass of the resin component. When the amount of the release agent is 0.01 part by mass or more per 100 parts by mass of the resin component, sufficient release properties tend to be obtained. When the amount is 10 parts by mass or less, better adhesion and curability tend to be obtained.

[0057] (Flame retardant) The epoxy resin composition may contain a flame retardant. There are no particular limitations on the flame retardant, and conventionally known flame retardants can be used. Specific examples include organic or inorganic compounds containing halogen atoms, antimony atoms, nitrogen atoms, or phosphorus atoms, and metal hydroxides. The flame retardants may be used alone or in combination of two or more.

[0058] When the epoxy resin composition contains a flame retardant, the content is not particularly limited as long as it is an amount sufficient to obtain the desired flame retardant effect. For example, the content is preferably 1 to 30 parts by mass, more preferably 2 to 20 parts by mass, per 100 parts by mass of the resin component.

[0059] (coloring agent) The epoxy resin composition may further contain a colorant. Examples of the colorant include known colorants such as carbon black, organic dyes, organic pigments, titanium oxide, red lead, and red iron oxide. The content of the colorant can be appropriately selected depending on the purpose, etc. The colorant may be used alone or in combination of two or more.

[0060] (Stress reliever) The epoxy resin composition may contain a stress relaxation agent such as silicone oil or silicone rubber particles. The use of a stress relaxation agent can further reduce package warpage and package cracking. Examples of stress relaxation agents include commonly used known stress relaxation agents (also known as flexible agents). Specific examples include thermoplastic elastomers such as silicone, styrene, olefin, urethane, polyester, polyether, polyamide, and polybutadiene elastomers; rubber particles such as NR (natural rubber), NBR (acrylonitrile-butadiene rubber), acrylic rubber, urethane rubber, and silicone powder; and rubber particles having a core-shell structure such as methyl methacrylate-styrene-butadiene copolymer (MBS), methyl methacrylate-silicone copolymer, and methyl methacrylate-butyl acrylate copolymer. The stress relaxation agents may be used alone or in combination of two or more.

[0061] [Physical properties of epoxy resin composition] (Viscosity of epoxy resin composition) The viscosity of the epoxy resin composition is not particularly limited, and is preferably adjusted to a desired viscosity depending on the molding method, the composition of the epoxy resin composition, and the like. For example, when molding an epoxy resin composition by compression molding, from the viewpoint of reducing wire sweep, the viscosity of the epoxy resin composition at 175°C is preferably 200 Pa s or less, more preferably 150 Pa s or less, and even more preferably 100 Pa s or less. The lower limit of the viscosity is not particularly limited, and may be, for example, 10 Pa s or more. Furthermore, for example, when the epoxy resin composition is molded by transfer molding, from the viewpoint of reducing wire sweep, the viscosity of the epoxy resin composition at 175°C is preferably 200 Pa s or less, more preferably 150 Pa s or less, and even more preferably 100 Pa s or less. The lower limit of the viscosity is not particularly limited, and may be, for example, 10 Pa s or more. The viscosity of the epoxy resin composition can be measured using a Koka type flow tester (for example, manufactured by Shimadzu Corporation).

[0062] The viscosity of the epoxy resin composition may also be confirmed by spiral flow. For example, the viscosity may be measured by using a spiral flow measurement mold conforming to the standard (EMMI-1-66) to measure the viscosity of the epoxy resin composition at a hydraulic pressure of 70 kgf / cm, which is the converted value of the plunger bottom pressure. 2 The flowability can be evaluated by measuring the flow distance, which is the length of the molded product when the molded product is injected under a pressure of approximately 6.86 MPa (approximately 6.86 MPa) and molded at 175°C for 120 seconds. The flow distance measured under the above conditions is preferably 67 inches (170 cm) or more, more preferably 70 inches (178 cm) or more, even more preferably 75 inches (191 cm) or more, particularly preferably 80 inches (203 cm) or more, and extremely preferably 85 inches (216 cm) or more. The values ​​in parentheses (cm) are converted values.

[0063] (Thermal conductivity when cured) The thermal conductivity of the epoxy resin composition when cured is not particularly limited. From the viewpoint of obtaining the desired heat dissipation properties, the thermal conductivity may be 3.0 W / (m·K) or more, 4.0 W / (m·K) or more, 5.0 W / (m·K) or more, 6.0 W / (m·K) or more, 7.0 W / (m·K) or more, or 8.0 W / (m·K) or more at room temperature (25°C). The upper limit of the thermal conductivity is not particularly limited, and may be 9.0 W / (m·K). The thermal conductivity of the cured product can be measured by the xenon flash (Xe-flash) method (for example, using a Hyper Flash device manufactured by NETZSCH, trade name: LFA467).

[0064] (Hot hardness when cured) The hot hardness of the epoxy resin composition when cured is not particularly limited. For example, when the epoxy resin composition is molded under conditions of 175°C, 120 seconds, and a pressure of 7 MPa, the hot hardness measured using a Shore D hardness tester is preferably 60 or more, more preferably 65 or more, and even more preferably 70 or more.

[0065] [Method for preparing epoxy resin composition] The method for preparing the epoxy resin composition is not particularly limited. A typical method includes thoroughly mixing the components using a mixer or the like, melt-kneading the mixture using a mixing roll, extruder, or the like, cooling, and pulverizing the mixture. More specifically, the method includes mixing and stirring the components described above, kneading the mixture using a kneader, roll, extruder, or the like that has been preheated to 70°C to 140°C, cooling, and pulverizing the mixture.

[0066] The epoxy resin composition may be solid or liquid at room temperature and normal pressure (e.g., 25°C, atmospheric pressure), and is preferably solid. When the epoxy resin composition is solid, its shape is not particularly limited, and examples include powder, granules, and tablets. When the epoxy resin composition is in tablet form, it is preferable that the dimensions and mass of the tablet be set to suit the molding conditions of the package, from the viewpoint of handleability.

[0067] <Electronic component equipment> An electronic component device according to one embodiment of the present disclosure includes an element encapsulated with the above-described epoxy resin composition. Examples of electronic component devices include devices obtained by mounting elements (active elements such as semiconductor chips, transistors, diodes, and thyristors, and passive elements such as capacitors, resistors, and coils) on a support member such as a lead frame, a pre-wired tape carrier, a wiring board, glass, a silicon wafer, or an organic substrate, and then sealing the resulting element part with an epoxy resin composition. More specifically, DIP (Dual Inline Package), PLCC (Plastic Leaded Chip Carrier), QFP (Quad Flat Package), SOP (Small Outline Package), SOJ (Small Outline J-lead), etc., have a structure in which an element is fixed on a lead frame, and the terminals of the element, such as bonding pads, are connected to the lead portions by wire bonding, bumps, etc., and then sealed using an epoxy resin composition by transfer molding, etc. Examples of resin-sealed ICs include general resin-sealed ICs such as thin small outline packages (TSOPs), thin quad flat packages (TQFPs), and the like; tape carrier packages (TCPs) in which elements connected to a tape carrier via bumps are sealed with an epoxy resin composition; chip-on-board (COB) modules, hybrid ICs, and multi-chip modules in which elements connected to wiring formed on a support member via wire bonding, flip-chip bonding, solder, or the like are sealed with an epoxy resin composition; and ball grid arrays (BGAs), chip size packages (CSPs), and multi-chip packages (MCPs) in which elements are mounted on the surface of a support member having terminals for connecting a wiring board formed on the back side, connected to the wiring formed on the support member via bumps or wire bonding, and then sealed with an epoxy resin composition. Epoxy resin compositions can also be suitably used in printed wiring boards.

[0068] Examples of methods for encapsulating electronic component devices using epoxy resin compositions include low-pressure transfer molding, injection molding, and compression molding. [Example]

[0069] The above-described embodiment will be specifically described below using examples, but the scope of the above-described embodiment is not limited to these examples.

[0070] <Preparation of Epoxy Resin Composition> First, the following components were prepared.

[0071] [Epoxy resin] Epoxy resin A: Bisphenol F epoxy resin with an epoxy equivalent weight of 187g / eq to 197g / eq and a melting point of 61°C to 71°C (manufactured by Nippon Steel Chemical & Material Co., Ltd., product name: YSLV-80XY) Epoxy resin B: Epoxy resin with an epoxy equivalent of 192 g / eq and a melting point of 106°C (Mitsubishi Chemical Corporation, product name: YX-4000)

[0072] [Curing agent] Triphenylmethane-type phenolic resin with a hydroxyl equivalent of 102 g / eq and a softening point of 70°C (Air Water Inc., product name: HE910)

[0073] [Curing accelerator] Phosphorus-based curing accelerator

[0074] [Silane Compound] Silane compound A: 3-methacryloxypropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KBM-503) Silane compound B: N-phenyl-3-aminopropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KBM-573) Silane compound C: 3-mercaptopropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KBM-803)

[0075] [Inorganic filler] Silica particles: Volume average particle size 0.2 μm Alumina particle A: Volume average particle diameter 10 μm, cut point 55 μm Alumina particle B: Volume average particle diameter 1 μm, cut point 25 μm Magnesium oxide: Volume average particle size: approx. 2 μm

[0076] [Additives] Release agent: Hoechst wax (Clariant, product name: HW-E) Pigment: Carbon black (manufactured by Mitsubishi Chemical Corporation, product name: MA-600MJ-S) Ion exchanger: Hydrotalcite (manufactured by Sakai Chemical Industry Co., Ltd., product name: STABIACE HT-P)

[0077] Epoxy resin compositions were prepared by blending the components shown in Table 1 in the amounts shown in the table, kneading, cooling, and pulverizing. In the table, unless otherwise specified, the blending amount of each component is expressed in parts by mass. In the table, "-" indicates that the component was not blended.

[0078] <Viscosity evaluation (spiral flow evaluation)> Using a spiral flow measurement mold conforming to the standard (EMMI-1-66), the epoxy resin composition was subjected to a hydraulic pressure of 70 kgf / cm, which is the converted value of the plunger bottom pressure. 2 The mixture was poured at a pressure of approximately 6.86 MPa and molded at 175°C for 120 seconds. The length of the molded product was evaluated as the flow distance.

[0079] <Evaluation of thermal conductivity> The epoxy resin composition was molded in a high-temperature vacuum molding machine under conditions of 175°C, 120 seconds, and a pressure of 7 MPa, and processed into a 1 mm thick, 10 mm square test piece. The test piece was measured at room temperature (25°C) using a NETZSCH Hyper Flash device (trade name: LFA467), and the value calculated by the xenon flash method was used as the thermal conductivity.

[0080] <Evaluation of hot hardness> The epoxy resin composition was molded in a high-temperature vacuum molding machine under conditions of 175°C, 120 seconds, and a pressure of 7 MPa, and the value measured using a Shore D hardness tester was taken as the hardness.

[0081] [Table 1]

[0082] As a result of the evaluation, in Examples 1 and 2, which contained silane compound A, the viscosity was reduced and the thermal conductivity of the cured product was good. In addition, the hot hardness was not significantly reduced compared to the comparative example, and good curability was maintained.

[0083] The disclosure of Japanese Patent Application No. 2018-049153 is incorporated herein by reference in its entirety. All documents, patent applications, and technical standards described herein are incorporated by reference into this specification to the same extent as if each individual document, patent application, and technical standard was specifically and individually indicated to be incorporated by reference.

Claims

1. epoxy resin, a curing agent containing a triphenylmethane-type phenolic resin; alumina particles, A silane compound having a structure in which, while having no functional group reactive with an epoxy group, it has a functional group that does not react with an epoxy group, and the functional group that does not react with an epoxy group is bonded to a silicon atom or to a silicon atom via a chain hydrocarbon group having 1 to 5 carbon atoms; Curing accelerator containing an adduct of a tertiary phosphine and a quinone compound Contains the content of the alumina particles is 50% by volume or more based on the total amount of the epoxy resin composition, the functional group that does not react with an epoxy group includes a (meth)acryloyloxy group, The epoxy resin composition is injected into a spiral flow measurement mold conforming to EMMI-1-66 at a hydraulic pressure of 70 kgf / cm2, which is the plunger bottom pressure converted value, and molded under conditions of 175°C and 120 seconds, and the flow distance measured as the length of the molded product is 170 cm or more, An epoxy resin composition that is a solid composition at 25°C and atmospheric pressure, for encapsulating elements of electronic device components by low-pressure transfer molding, injection molding, or compression molding.

2. 2. The epoxy resin composition according to claim 1, wherein the content of the silane compound is 0.01% by mass to 20% by mass based on the total amount of the epoxy resin.

3. 3. The epoxy resin composition according to claim 1, wherein the silane compound comprises 3-methacryloxypropyltrimethoxysilane.

4. The epoxy resin composition according to any one of claims 1 to 3, further comprising silica particles.

5. An epoxy resin composition described in any one of claims 1 to 4, wherein the epoxy resin comprises a biphenyl type epoxy resin and a bisphenol F type epoxy resin.

6. The epoxy resin composition according to any one of claims 1 to 5, wherein the epoxy resin composition is molded under conditions of 175°C, 120 seconds, and a pressure of 7 MPa, and the measured thermal conductivity of a test piece processed into a 1 mm thick, 10 mm square piece at 25°C calculated by the xenon flash method is 4.0 W / (m / k) or more.

7. An electronic component device comprising an element encapsulated with the epoxy resin composition according to any one of claims 1 to 6.

Images