Method for producing solid biomass fuel

Abstract

The present invention relates to a method for producing solid biomass fuel from rice husk, alone or in combination with other materials such as Calliandra carotylus or wood, and to the solid biomass fuel produced by said method. Accordingly, the present invention relates to a combustion method comprising the step of combusting said solid biomass fuel to produce energy.

Description

Technical Field

[0001] The present invention relates to a method for producing solid biomass fuel and to the solid biomass fuel produced by said method. Furthermore, the present invention relates to a combustion method comprising the step of burning said solid biomass fuel so as to generate energy.

Background Art

[0002] Coal-fired power generation is used in power plants and industrial processes worldwide. Coal and other fossil fuels are non-renewable energy resources. Over the past few decades, it has been required to reduce the consumption of coal in coal-fired power plants and instead use renewable resources for energy.

[0003] Fuels derived from biomass are an example of renewable energy sources that can be used to replace or at least partially replace coal. Biomass-derived fuels can be burned in the presence of oxygen in a combustion method for generating energy in a power plant. Biomass-derived fuels can be burned in traditional power plants originally designed for coal combustion, or biomass-derived fuels can be burned in power plants built specifically for biomass combustion. Certain forms of biomass can be mixed with coal and burned in the same combustion method within a power plant. Such a method is known as co-firing of biomass with coal. In order to be suitable for co-firing with coal, biomass-derived combustion typically must have certain characteristics, such as a certain level of quality and homogeneity regarding properties. For example, biomass fuels containing particles of uniform size, density, moisture content, etc. are particularly desirable for co-firing methods. It is also desirable for the biomass fuel to contain a low level of ash. The level of ash in biomass-derived fuels is typically higher than the level found in coal.

[0004] Various methods for producing solid biomass fuel from biomass sources are known. International Publication No. 2014 / 087949 discloses a method for producing solid biomass fuel, which involves steam-exploding a biomass source, forming it into a biomass block, and then heating it to form biomass fuel. The aim of this method is to produce biomass fuel that is easy to handle during storage and has reduced chemical oxygen demand (COD) in the wastewater during storage. The biomass source used in this method is palm kernel shell.

[0005] International Publication No. 2016 / 056608, built upon the teachings of International Publication No. 2014 / 087949, discloses a method for producing solid biomass fuel that does not require a steam explosion step to generate the fuel. The method includes a molding step of crushing a biomass source, then compressing it into a biomass block, and then heating the biomass block. The biomass sources taught for use in the said method are trees such as Douglas fir, Western hemlock, Japanese cedar, Japanese cypress, Scots pine, old almond trees, almond husks, acacia wood, acacia bark, walnut husks, sago palm, hollow fruit clusters, meranti, and rubber.

[0006] International Publication No. 2017 / 175733 discloses a similar method comprising a molding step of crushing a biomass source, then compressing it to form a biomass block, and subsequently heating the biomass block. The method of International Publication No. 2017 / 175733 aims to provide a biomass fuel that exhibits low disintegration and achieves a reduction in COD in wastewater when exposed to rainwater. The biomass sources used in this method are selected from rubber trees, acacia, meranti, eucalyptus, teak, and mixtures of larch, spruce, and birch.

[0007] International Publication No. 2019 / 069849 aims to provide a biomass fuel that is easy to transport and store and resistant to spontaneous combustion during storage. The biomass fuel is produced by a method that includes a molding step, in which a biomass source is crushed and then compressed into a biomass block, and the biomass block is subsequently heated. Biomass sources for producing the fuel are selected from rubber trees, acacia trees, radiata pine, larch and a mixture of spruce and birch, as well as spruce, pine and fir.

[0008] International Publication No. 2019 / 069860 discloses an apparatus for producing biomass solid fuel. The apparatus includes a carbonizer for carbonizing molded biomass products to obtain biomass solid fuel. The apparatus further includes a yield calculation unit, a temperature measurement unit, and a control unit. The control unit controls the heat applied to the carbonizer based on the spontaneous combustion characteristics of the biomass fuel. The molded biomass products are formed by pulverizing a biomass source into pellets, and then molding the pellets into molded biomass fuel. The biomass source is selected from rubber tree, acacia, dipterocarp, radiata pine, a mixture of larch, spruce, and birch, or a mixture of spruce, pine, and fir.

[0009] International Publication No. 2018 / 181919 discloses a different method for producing solid biomass fuel than those discussed above. This method involves a hydrothermal carbonization step of biomass, in which the biomass source is pressurized in hot water so that the biomass is carbonized. This method has been reported to provide biomass fuel with high yield and reduced production costs and high pulverizability. Biomass sources can be selected from shells, palm kernel husks, coconuts, bamboo, empty fruit clusters, apricots, and eggplants.

[0010] International Publication No. 2017 / 175737 discloses a cooling apparatus for cooling carbonized biomass. This apparatus improves the cooling efficiency of semi-carbonized molded biomass. The apparatus cools the biomass by spraying water. The cooler includes a vibrating plate and a spraying section for spraying water onto the plate. Biomass fuel is produced by the same method as described above. Sources of biomass for producing biomass fuel include Douglas fir, Western hemlock, Japanese cedar, Japanese cypress, Scots pine, old almond trees, almond shells, acacia wood, acacia bark, walnut shells, sago palm, empty fruit clusters, meranti, and rubber trees.

[0011] Finally, International Publication No. 2014 / 050964 discloses a method for improving the pulverizability of biomass so that it can be pulverized together with coal. This method involves increasing the moisture content of the pulverized woody biomass to 10-50% and 0.55 g / cm³. 3 This process involves increasing the density of the biomass to the above-mentioned density, followed by roasting the biomass. Sources of biomass include wood chips, bark, wood veneer, and sawdust. [Prior art documents] [Patent Documents]

[0012] [Patent Document 1] International Publication No. 2014 / 087949 brochure [Patent Document 2] International Publication No. 2016 / 056608 Brochure [Patent Document 3] International Publication No. 2017 / 175733 brochure [Patent Document 4] International Publication No. 2019 / 069849 Brochure [Patent Document 5] International Publication No. 2019 / 069860 Brochure [Patent Document 6] International Publication No. 2018 / 181919 Pamphlet [Patent Document 7] International Publication No. 2017 / 175737 brochure [Patent Document 8] International Publication No. 2014 / 050964 Brochure [Overview of the Initiative] [Problems that the invention aims to solve]

[0013] The inventors of this invention recognize that the solid biomass fuels and methods for producing them discussed in the above-mentioned literature have various problems associated with them. For example, all of the biomass sources described in the above-mentioned literature are plants and trees that typically exist only in nature and are not easy to cultivate and harvest on a commercial scale. The inventors recognize that it is advantageous to have a biomass source that can be easily grown and harvested on a commercial scale. It is also advantageous to have a biomass source that can be grown and harvested so that the quality and specific characteristics of the biomass source can be controlled.

[0014] In addition, the inventors have found that the biomass sources described in the above literature, all of which contain woody materials or similar materials, form low-homogeneity particles when subjected to conventional micronization techniques known in the art. Furthermore, micronizing biomass sources is costly due to the difficulty in micronizing wood and wood-like materials. The inventors of the present invention recognize that it is advantageous to have a biomass source that can be more easily micronized by conventional micronization techniques known in the art and forms more homogeneous sized particles when micronized, or a biomass source that does not require micronization before conversion to solid biomass fuel.

[0015] In addition, the inventors have found that solid biomass fuels prepared from the biomass sources discussed in the above literature, and prepared by the methods described in the above literature, do not possess sufficient water-resistant properties. Water resistance is important for solid biomass fuels because they need to be dry (or at least thoroughly dry) at the time of use in the combustion method (either alone or co-firing with coal). Biomass fuels are frequently exposed to moisture (e.g., rainwater) during storage or transport. Therefore, biomass fuels with increased water resistance are desirable.

[0016] The inventors also recognize that the biomass fuel production methods described in the above-mentioned literature do not provide fuel with sufficient quality and uniformity. In particular, the methods discussed above do not provide sufficient control over the biomass density during the molding step. [Means for solving the problem]

[0017] This invention addresses the problems discussed above in relation to prior methods. Surprisingly, we have found that a specific biomass source useful for providing solid biomass fuel can be grown and harvested on a commercial scale. In this way, a fixed and consistent biomass source can be provided throughout the growth cycle for fuel production. In addition, by growing and harvesting the biomass source on a commercial scale, the quality and uniformity of the biomass source can be controlled, for example, by cultivation and crossbreeding techniques.

[0018] In addition, advantageously, we found that certain biomass sources do not require pulverization before processing into solid biomass fuel, thus reducing processing-related costs.

[0019] In addition to the above, the inventors of the present invention have also found that by changing the molding step and / or the heating step in the method, a biomass fuel having improved waterproof characteristics can be provided. By adapting and controlling the molding step and the heating step in the method of the present invention, the quality and uniformity of the solid biomass fuel product are improved, and certain physical characteristics highly favorable for use in combustion methods are imparted to the solid biomass fuel product. Further, by adapting the molding step and the heating step, it has been found that the yield of the solid biomass fuel is increased and characteristics facilitating transportation and storage are imparted to the fuel. The inventors have found that the nature of the biomass source and the specific characteristics of the molding and heating steps act together to provide an excellent biomass fuel product for use in combustion methods that exceeds what is known in the art.

[0020] According to a first aspect of the present invention, a method for producing a solid biomass fuel, comprising: (i) preparing one or more biomass powders having a particle size of from 1000 μm to 10000 μm; (ii) heating the one or more biomass powders at a temperature of from 160°C to 420°C for a period of from 0.25 to 5 hours to provide a heated biomass product; and (iii) molding the heated biomass product to provide a solid biomass fuel. comprising One or more biomass powders are derived from one or more biomass sources, and the one or more biomass sources are: (i) composed of rice husks or consisting essentially of rice husks; (ii) containing a mixture of rice husks and wood such as mixed wood or consisting essentially of such a mixture; (iii) composed of a mixture of rice husks and calliandra callothyrsus or consisting essentially of such a mixture; or (iv) containing at least 15% by weight of rice husks and calliandra callothyrsus; and when the one or more biomass sources are composed of rice husks or consisting essentially of rice husks, the material derived from the biomass is present in the solid biomass fuel in an amount of at least 95% by weight of the total fuel content of the solid biomass fuel. A method is provided.

[0021] In an embodiment, the one or more biomass sources are composed of rice husks or consisting essentially of rice husks.

[0022] In another embodiment, the one or more biomass sources further comprise wood such as mixed wood, calliandra callothyrsus, or a combination thereof. Preferably, the one or more biomass sources include (i) rice husks and calliandra callothyrsus, or (ii) rice husks and wood such as mixed wood. In an embodiment, the one or more biomass sources are composed of a mixture of rice husks and wood such as mixed wood or consisting essentially of such a mixture. In another embodiment, the one or more biomass sources are composed of a mixture of rice husks and calliandra callothyrsus or consisting essentially of such a mixture. In another embodiment, the one or more biomass sources contain at least 15% by weight of rice husks and calliandra callothyrsus.

[0023] In one embodiment, one or more biomass sources include 20% to 80% by weight of rice husks. In one embodiment, one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of wood such as mixed wood. Preferably, one or more biomass sources do not include coconut shells or straw. In one embodiment, one or more biomass sources consist essentially of rice husks and wood such as mixed wood, and one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of wood such as mixed wood. In another embodiment, one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of Calliandra carotyrus. In the embodiment, one or more biomass sources consist essentially of rice husks and Calliandra carotyrus, and the one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of Calliandra carotyrus.

[0024] The step of heating one or more biomass powders is preferably carried out for a period of 0.4 to 3 hours, for example 0.4 to 2 hours, or 0.5 to 3 hours, for example 0.4 to 2 hours.

[0025] The step of heating one or more biomass powders includes heating one or more biomass powders to a temperature of 180°C to 350°C, preferably 210°C to 280°C.

[0026] Preferably, step (ii) of heating one or more biomass powders includes heating one or more biomass powders under conditions for inducing roasting of the molded biomass product.

[0027] Preferably, this method further includes a step of cooling the heated biomass product before step (iii) of shaping the heated biomass product.

[0028] Step (i) of preparing one or more biomass powders may include pulverizing one or more biomass sources and / or mixing one or more biomass powders.

[0029] Typically, this method may include a step of drying one or more biomass powders prior to step (ii) of heating one or more biomass powders.

[0030] Step (iii) of molding the heated biomass product may include adapting the molding step so that the density of the solid biomass fuel is controlled. Preferably, adapting the molding step so that the density of the solid biomass fuel is controlled includes controlling the compression ratio of the mold used in the molding step.

[0031] Preferably, this method includes the step of adding an additive to the heated biomass product before step (iii) of shaping the heated biomass product. Preferably, the additive is added in such a way as to increase the yield of the solid biomass fuel.

[0032] Step (ii), which involves heating one or more biomass powders, is typically adapted to control the uniformity of the heated biomass product. Preferably, adapting step (ii) to control the uniformity of the heated biomass product includes performing step (ii) in an apparatus that rotates one or more biomass powders while heating them. More preferably, adapting step (ii) to control the uniformity of the heated biomass product includes controlling the speed or direction of rotation of one or more biomass powders. Most preferably, one or more biomass powders are rotated in both counterclockwise and clockwise directions in the apparatus.

[0033] The bulk density of solid biomass fuel, as determined by DIN EN 15103, is typically 0.40 kg / l to 0.65 kg / l, preferably 0.45 kg / l to 0.60 kg / l, and most preferably 0.50 to 0.60 kg / l.

[0034] The mechanical durability of solid biomass fuels, as determined by DIN EN 15210-1, is typically 95% or higher, 96% or higher, 97% or higher, or 98% or higher.

[0035] In some embodiments of this method, one or more biomass sources and solid biomass fuels are as follows: (i) One or more biomass sources include or consist essentially of rice husks, the solid biomass fuel has a bulk density of 0.40 kg / L to 0.48 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. (ii) One or more biomass sources include a mixture of rice husks and wood such as mixed wood, the solid biomass fuel has a bulk density of 0.50 kg / L to 0.65 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more, (iii) The biomass source consists of one or more sources including a mixture of rice husks and Calliandra carotylus, the solid biomass fuel has a bulk density of 0.45 kg / L to 0.60 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. The bulk density is determined by DIN EN 15103, and the mechanical durability is determined by DIN EN 15210-1.

[0036] Typically, the total dry sulfur content of the resulting biomass solid fuel is 0.05% by weight or less, preferably 0.04% by weight or less, and most preferably 0.03% by weight or less, and the total dry sulfur content is determined according to DIN EN 15289.

[0037] Typically, the total dry hydrogen content of the biomass solid fuel produced is 5% by weight or more, preferably 5% to 10% by weight, and more preferably 5% to 7% by weight, and the total dry hydrogen content is determined according to DIN EN 15104.

[0038] Typically, the total dry oxygen content of the resulting biomass solid fuel is 34% by weight or more, preferably 34% to 40% by weight, and more preferably 34% to 38% by weight, with the total dry oxygen content determined by DIN EN 15296.

[0039] Typically, the total dry carbon content of the resulting biomass solid fuel is 40% by weight or more, preferably 45% to 55% by weight, and more preferably 50% to 52% by weight, with the total dry carbon content determined by DIN EN 15104.

[0040] Typically, the total dry nitrogen content of the resulting biomass solid fuel is less than 0.5% by weight, preferably less than 0.4% by weight, and more preferably less than 0.3% by weight, and the total dry nitrogen content is determined according to DIN EN 15104.

[0041] Typically, the solid biomass fuel produced is waterproof for up to 20 days, preferably up to 30 days, and more preferably up to 40 days.

[0042] Typically, the chemical oxygen demand (COD) of the solid biomass fuel produced is 5000 ppm or less, preferably 4000 ppm or less, and most preferably 3000 ppm or less, when immersed in water, and the chemical oxygen demand is determined by GB / 11914-89.

[0043] Typically, the fixed carbon content of solid biomass fuel is 28% by weight or more, preferably 28% to 35% by weight, and more preferably 30% to 33% by weight, and the fixed carbon content is determined according to DIN EN 51734.

[0044] Typically, the ash content of solid biomass fuel is less than 25% by weight, preferably less than 20% by weight, and most preferably less than 18% by weight, and the ash content is determined at 550°C according to EN 14775.

[0045] Typically, the volatile matter content of solid biomass fuel is 40% to 65% by weight, more preferably 45% to 60% by weight, and the volatile matter content is determined according to DIN EN 15148.

[0046] Typically, the moisture content of the solid biomass fuel produced is less than 8% by weight, preferably less than 6% by weight, and most preferably less than 5% by weight, and the moisture content is determined according to DIN EN 14774.

[0047] Typically, the calorific value of the solid biomass fuel produced is between 4300 kcal / kg dry mass and 6500 kcal / kg dry mass, and the calorific value is determined according to DIN EN 14918.

[0048] Typically, the bulk density of molded biomass products is A, the bulk density of solid biomass fuel is B, B / A is 0.55 to 1, and the bulk density is determined by DIN EN 15103.

[0049] Preferably, this method does not involve adding coal, an oxidizer, an igniter, or a combination thereof to the heated biomass product before the molding step, and the solid biomass fuel does not contain coal, an oxidizer, an igniter, or a combination thereof.

[0050] In the embodiment, step (ii) of heating one or more biomass powders includes heating one or more biomass powders for a period of 30 minutes to 5 hours, or optionally 1 hour to 5 hours.

[0051] A second aspect of the present invention provides a solid biomass fuel that can be obtained or obtained by the method according to the first aspect of the present invention.

[0052] According to a third aspect of the present invention, a solid biomass fuel is provided which is derived from one or more biomass sources, wherein one or more biomass sources consist of (i) rice husks or are essentially made of rice husks; (ii) rice husks and a mixture of wood such as mixed wood or are essentially made of a mixture; (iii) rice husks and Calliandra carotyrus or are essentially made of a mixture; or (iv) rice husks and Calliandra carotyrus in an amount of at least 15% by weight, and when one or more biomass sources consist of or are essentially made of rice husks, the biomass-derived material is present in the solid biomass fuel in an amount of at least 95% by weight of the total fuel content of the solid biomass fuel.

[0053] In the embodiment, one or more biomass sources include rice husks and wood such as mixed wood. Typically, one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of wood such as mixed wood. Preferably, one or more biomass sources do not include coconut husks or straw. In the embodiment, one or more biomass sources consist essentially of rice husks and wood such as mixed wood, and one or more biomass sources include 20% to 80% by weight of rice husks and 20% to 80% by weight of wood such as mixed wood.

[0054] In another embodiment, one or more biomass sources comprise a mixture of rice husks and Calliandra carotylus, with the rice husks present in an amount of at least 15% by weight of the total weight of the one or more biomass sources. Preferably, one or more biomass sources comprise 20% to 80% by weight of rice husks and 20% to 80% by weight of Calliandra carotylus. In an embodiment, one or more biomass sources consist essentially of rice husks and Calliandra carotylus, comprising 20% ​​to 80% by weight of rice husks and 20% to 80% by weight of Calliandra carotylus.

[0055] The bulk density of solid biomass fuel, as determined by DIN EN 15103, is typically 0.40 kg / l to 0.65 kg / l, preferably 0.45 kg / l to 0.60 kg / l, and most preferably 0.50 to 0.60 kg / l.

[0056] The mechanical durability of solid biomass fuels, as determined by DIN EN 15210-1, is typically 95% or higher, 96% or higher, 97% or higher, or 98% or higher.

[0057] In some embodiments of this method, one or more biomass sources and solid biomass fuels are as follows: (i) One or more biomass sources include or consist essentially of rice husks, the solid biomass fuel has a bulk density of 0.40 kg / L to 0.48 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. (ii) One or more biomass sources include a mixture of rice husks and wood such as mixed wood, the solid biomass fuel has a bulk density of 0.50 kg / L to 0.65 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more, (iii) The biomass source consists of one or more sources including a mixture of rice husks and Calliandra carotylus, the solid biomass fuel has a bulk density of 0.45 kg / L to 0.60 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. The bulk density is determined by DIN EN 15103, and the mechanical durability is determined by DIN EN 15210-1.

[0058] Typically, the total dry sulfur content of the resulting biomass solid fuel is 0.05% by weight or less, preferably 0.04% by weight or less, and most preferably 0.03% by weight or less, and the total dry sulfur content is determined according to DIN EN 15289.

[0059] Typically, the total dry hydrogen content of the biomass solid fuel produced is 5% by weight or more, preferably 5% to 10% by weight, and more preferably 5% to 7% by weight, and the total dry hydrogen content is determined according to DIN EN 15104.

[0060] Typically, the total dry oxygen content of the resulting biomass solid fuel is 34% by weight or more, preferably 34% to 40% by weight, and more preferably 34% to 38% by weight, with the total dry oxygen content determined by DIN EN 15296.

[0061] Typically, the total dry carbon content of the resulting biomass solid fuel is 40% by weight or more, preferably 45% to 55% by weight, and more preferably 50% to 52% by weight, with the total dry carbon content determined by DIN EN 15104.

[0062] Typically, the total dry nitrogen content of the resulting biomass solid fuel is less than 0.5% by weight, preferably less than 0.4% by weight, and more preferably less than 0.3% by weight, and the total dry nitrogen content is determined according to DIN EN 15104.

[0063] Typically, the solid biomass fuel produced is waterproof for up to 20 days, preferably up to 30 days, and more preferably up to 40 days.

[0064] Typically, the chemical oxygen demand (COD) of the solid biomass fuel produced is 5000 ppm or less, preferably 4000 ppm or less, and most preferably 3000 ppm or less, when immersed in water, and the chemical oxygen demand is determined by GB / 11914-89.

[0065] Typically, the fixed carbon content of solid biomass fuel is 28% by weight or more, preferably 28% to 35% by weight, and more preferably 30% to 33% by weight, and the fixed carbon content is determined according to DIN EN 51734.

[0066] Typically, the ash content of solid biomass fuel is less than 25% by weight, preferably less than 20% by weight, and most preferably less than 18% by weight, and the ash content is determined at 550°C according to EN 14775.

[0067] Typically, the volatile matter content of solid biomass fuel is 40% to 65% by weight, more preferably 45% to 60% by weight, and the volatile matter content is determined according to DIN EN 15148.

[0068] Typically, the moisture content of the solid biomass fuel produced is less than 8% by weight, preferably less than 6% by weight, and most preferably less than 5% by weight, and the moisture content is determined according to DIN EN 14774.

[0069] Typically, the calorific value of the solid biomass fuel produced is between 4300 kcal / kg dry mass and 6500 kcal / kg dry mass, and the calorific value is determined according to DIN EN 14918.

[0070] A fourth aspect of the present invention provides a combustion method comprising the step of burning a solid biomass fuel according to the second and third aspects of the present invention to generate energy.

[0071] In one embodiment, solid biomass fuel is simultaneously fired and burned together with fossil fuel. Preferably, the fossil fuel includes coal.

[0072] In one embodiment, the PM1.0 emissions in the method are less than 175 mg / kg, preferably less than 150 mg / kg.

[0073] According to a fifth aspect of the present invention, the use of solid biomass fuel according to the second and third aspects of the present invention as fuel in a combustion method is provided.

[0074] Preferably, the combustion method includes the step of co-firing solid biomass fuel together with fossil fuel. Preferably, the fossil fuel is coal.

[0075] In one embodiment, the PM1.0 emissions in the method are less than 175 mg / kg, preferably less than 150 mg / kg.

[0076] According to a sixth aspect of the present invention, a use is provided for one or more biomass sources for producing solid biomass fuel, wherein one or more biomass sources consist of (i) rice husks or are essentially made of rice husks; (ii) rice husks and a mixture of wood such as mixed wood or are essentially made of a mixture; (iii) rice husks and Calliandra carotyrus or are essentially made of a mixture; or (iv) rice husks and Calliandra carotyrus in an amount of at least 15% by weight, and if one or more biomass sources consist of or are essentially made of rice husks, biomass-derived material is present in the solid biomass fuel in an amount of at least 95% by weight of the total fuel content of the solid biomass fuel.

[0077] Preferably, one or more biomass sources are as described above according to the first and third aspects of the present invention.

[0078] Preferably, use involves using one or more biomass sources in the method according to the first aspect of the present invention.

[0079] Preferably, the solid biomass fuel is as described above according to the first and third aspects of the present invention. [Brief explanation of the drawing]

[0080] The present invention is described herein with reference to the attached diagram as an example. [Figure 1] This is a photograph of rice husks. [Figure 2] This graph illustrates the difference in production yield during the molding process. The biomass source is rice husks. [Figure 3]This graph shows the productivity (Y-axis) as a function of the compression ratio (X-axis) for molded biomass products produced according to the method of the present invention. The biomass source here is rice husks. [Figure 4] This graph shows the density (kg / L) on the y-axis against the compression ratio (x-axis) for molded biomass products produced according to the method of the present invention. The biomass source is rice husks. [Figure 5] This is a photograph of the biomass fuel product of the present invention. [Figure 6] This graph illustrates the bulk densities of multiple products of the present invention. [Figure 7] This graph illustrates the durability of multiple products of the present invention. [Figure 8] This is a graph illustrating the sulfur content of several products of the present invention. [Figure 9] This is a graph illustrating the oxygen content of multiple products of the present invention. [Figure 10] This is a graph illustrating the carbon content of several products of the present invention. [Figure 11] This is a graph illustrating the nitrogen content of several products of the present invention. [Figure 12] This is a graph illustrating the fixed carbon content of multiple products of the present invention. [Figure 13] This is a graph illustrating the ash content of several products of the present invention. [Figure 14] This is a graph illustrating the water content of multiple products of the present invention. [Figure 15] This graph illustrates the volatile substance content of multiple products of the present invention. [Figure 16] This graph illustrates the PM1.0 emissions of multiple products of the present invention. [Figure 17] This graph shows the results of testing the product of the present invention in an artificial climate chamber. [Figure 18] This graph shows the results of another test of the product of the present invention in an artificial climate chamber. [Figure 19]This graph shows the results of another test of the product of the present invention in an artificial climate chamber. [Figure 20] This graph shows the surface moisture content of several products of the present invention after testing in a climate chamber. [Figure 21] This is a schematic diagram of a compression mold that can be used in the molding step of the method of the present invention. [Modes for carrying out the invention]

[0081] Biomass supply source One or more biomass sources used in accordance with the present invention may be any of those described above. In a preferred embodiment, one or more biomass sources include, consist of, or comprise rice hulls. If one or more biomass sources include rice hulls and one or more additional biomass sources, one or more biomass sources may contain any specific amount of rice hulls, such as 5% to 95% by weight. Typically, if one or more biomass sources include rice hulls and one or more additional biomass sources, the rice hulls are present in amounts of 10% to 90% by weight, 20% to 80% by weight, 30% to 70% by weight, or 40% to 60% by weight of the total amount of the one or more biomass sources.

[0082] If one or more biomass sources include or consist of a mixture of rice husks and Calliandra carotylus, the rice husks typically constitute at least 15% by weight of the total weight of the one or more biomass sources. Preferably, the rice husks constitute 20% to 80% by weight of the total amount of the one or more biomass sources present. If one or more biomass sources include or consist of a mixture of rice husks and wood such as mixed wood, the rice husks typically constitute at least 15% by weight of the total weight of the one or more biomass sources. Preferably, the rice husks constitute 20% to 80% by weight of the total amount of the one or more biomass sources present.

[0083] Each of the one or more biomass sources described above can be obtained or harvested by conventional methods known in the art.

[0084] As used herein, the term “wood” typically refers to a hard, fibrous material consisting of the wood beneath the bark, which constitutes the majority of the trunk, branches, and roots of trees or shrubs. In foliaceous plants, wood is found only to a limited extent. This definition of the term “wood” is consistent with the definition commonly understood in the art. As used herein, the term “mixed wood” refers to a mixture of two or more types of wood. Two or more types of wood may be present in the mixed wood in any amount, as long as the mixed wood contains at least two types of wood.

[0085] As used herein, the term “comprising” is used to mean that any further indefinite components may be present. As used herein, the term “consisting” is used to mean that no further components other than those specifically listed should be present. As used herein, the term “consisting essentially of” is used to mean that further indefinite components may be present, but these components do not substantially affect the essential characteristics of the composition.

[0086] As described above, the one or more biomass sources used in the present invention can be grown and harvested on a commercial scale and have been found to provide improved control over the quality and specific properties of the biomass sources compared to materials used in the prior art. The use of the said materials also avoids environmental damage associated with using trees, such as necessary logging. The above advantages are particularly related to the use of rice husks and Calliandra carotylus.

[0087] The use of one or more biomass sources in the present invention has been found to be surprisingly easier to pulverize than the previously used materials. For some materials, pulverization is even unnecessary. This reduces the cost of the pulverization process. In particular, rice husks generally do not require pulverization. While Calliandra carrotylus does require pulverization, it has been found to be easier to pulverize than the previously used materials.

[0088] The use of the materials of the present invention also provides a more homogeneous particle size mix than previously used materials when finely ground. While not limited by theory, this is thought to impart favorable properties to the final solid fuel product, such as greater uniformity and continuity of the biomass fuel product. This is desirable in combustion methods for several reasons.

[0089] Rice hulls are considered particularly useful as a source of biomass in certain regions of the world due to the abundance of rice in those areas. Currently, the area used for rice cultivation worldwide is approximately 155 million hectares, with China alone using 31 million hectares, accounting for about 20% of the world's surface area used for rice cultivation. China is the world's largest rice producer, accounting for 31% of global production. Rice hulls (shown in Figure 1) are the main by-product generated during rice processing. Rice hulls are a clean, renewable resource with abundant reserves. They are also inexpensive because they are a plentiful by-product of the rice production process.

[0090] However, rice hulls have a low packing density, and for this reason at least, they are inconvenient to transport. Furthermore, when rice hulls are directly incinerated in agriculture and forestry, the dust can cause air pollution. An advantage of using rice hulls compared to other previously used biomass raw materials is that they do not require expensive micronization processing. However, a disadvantage of rice hulls is that when fuel is produced from rice hulls using conventional biomass fuel production methods, the resulting fuel does not produce sufficient energy per unit volume. Therefore, in the art, there is a need for a method for producing solid biomass fuel from rice hulls that mitigates the disadvantages described above. The method of the present invention has been found to mitigate the aforementioned disadvantages.

[0091] Other advantages associated with the use of rice husks include the uniformity in size and density of the husks as a starting material, which means that the husks can be roasted directly without prior shaping, as will be described in more detail below. Solid biomass fuel produced from rice husks has also been found to have enhanced water resistance when compared to solid biomass fuels derived from different starting materials.

[0092] As used herein, the term "rice husk" is used interchangeably with the term "rice hull."

[0093] Biomass mixing and micronization Step (i) of preparing one or more biomass powders having particle sizes of 1000 μm to 10000 μm may include micronizing one or more biomass sources.

[0094] Biomass sources can be pulverized into biomass powder by standard techniques known in the art. The biomass sources can be pulverized such that the biomass powder has an average particle diameter (D50) of 1,000 μm to 10,000 μm. Typically, one or more biomass sources are pulverized to have average particle diameters of 1,000 μm to 8,000 μm, 2,000 μm to 8,000 μm, or 2,000 μm to 6,000 μm. As described above, it has been found that pulverizing specific biomass sources for use in the present invention provides a biomass powder with a more favorable particle size distribution than that provided by pulverizing previously known biomass sources. This is particularly true for Calliandra carotyrusus.

[0095] In one embodiment, the method includes the step of pulverizing the rice husks. In an alternative embodiment, the method does not include the step of pulverizing the rice husks. As described above, the advantage of using rice husks is that pulverization is not necessarily required due to the naturally occurring particle size.

[0096] Step (i) of preparing one or more biomass powders may also include mixing the rice hulls with one or more other biomass sources. The mixing can be carried out using standard techniques known in the art. In one embodiment, one or more biomass sources in addition to the rice hulls are pulverized to have a particle size of 1,000 μm to 10,000 μm. In another embodiment, one or more additional biomass sources do not need to be pulverized because they may have a naturally occurring particle size of 1,000 μm to 10,000 μm.

[0097] Heating of biomass powder One or more biomass powders are heated to produce a heated biomass product. The heating is carried out at a temperature of 160°C to 420°C for a period of 0.25 to 5 hours. Preferably, the step of heating the molded biomass product is carried out for a period of 0.4 to 2 hours. Preferably, the step of heating one or more biomass powders includes heating one or more biomass powders to a temperature of 180°C to 350°C, more preferably to a temperature of 210°C to 280°C.

[0098] Preferably, step (ii) heating one or more biomass powders includes heating one or more biomass powders under conditions for inducing roasting of the one or more biomass powders. Roasting is a mild pyrolysis process carried out in a low-oxygen atmosphere, such as an atmosphere with an oxygen content of less than 10%. Suitable conditions and processes for roasting are known in the art. Therefore, preferably, step (ii) heating one or more biomass powders includes roasting.

[0099] The heating step can be carried out in any apparatus known in the art that is suitable for heating one or more biomass powders. For example, the heating step can be carried out in the apparatus disclosed in European Patent Application Publication No. 3287509(A1) using the disclosed process conditions.

[0100] Preferably, step (ii) of heating one or more biomass powders is adapted to control the uniformity of the heated biomass product, and optionally, adapting step (ii) to control the uniformity of the heated biomass product includes performing step (ii) in a device that rotates one or more biomass powders while heating them, and optionally, adapting step (ii) to control the uniformity of the heated biomass product includes controlling the speed or direction of rotation of one or more biomass powders, and optionally, rotating one or more biomass powders in both counterclockwise and clockwise directions in the device. The uniformity of the heated biomass product is also optimized by the heating temperature and duration described above. Although not limited by theory, it is believed that higher uniformity in the heated biomass product is transferred to the solid biomass fuel product once molded, resulting in the production of a more uniform solid biomass fuel.

[0101] If the method of the present invention includes a step of cooling after a step of heating biomass, the cooling step may include rotating the biomass. The biomass may be rotated in a suitable apparatus, such as that disclosed in European Patent Application Publication No. 3287509(A1). Preferably, both the heating step (ii) and the cooling step of the biomass include rotating the biomass. If the biomass is rotated in either the cooling step or the heating step, the biomass may be rotated in different directions, such as both clockwise and counterclockwise in a continuous cycle.

[0102] The term "uniformity" of a solid biomass product is used to refer to a solid biomass fuel or heated biomass product that has consistent or similar properties down to each particle of the solid biomass fuel or heated biomass product, and down to multiple particles within a bulk sample of the solid biomass fuel or heated biomass product. Examples, but not limited to, particle density, ease of combustion, chemical composition, and water resistance. Uniformity is a highly desirable property for biomass fuels intended for use in combustion methods.

[0103] The inventors have also found that controlling the heating step as described above further helps to provide a solid biomass fuel product with enhanced water-repellent properties compared to prior art biomass fuels. During the heating step, water-absorbing hydrophilic compounds present in the biomass powder are decomposed. Furthermore, the heating step causes oil present in the biomass powder to move to the outside of the biomass powder particles, increasing the hydrophobicity of the particles.

[0104] Molding of heated biomass products Biomass powder is molded to provide solid biomass fuel. The molding step may be carried out in any molding apparatus known in the art, in accordance with biomass molding techniques known in the art, and may include an extrusion molding system. Preferably, the molding step is carried out in a compression mold. Preferably, the compression mold includes a molded product escape hole. The molding step may be carried out using the apparatus described in Chinese Patent No. 105435708.

[0105] Preferably, the molding step includes molding the biomass powder into pellets. Therefore, in a preferred embodiment, the solid biomass fuel product includes biomass pellets.

[0106] While it is known that molded biomass products are produced by molding biomass powder, the inventors of this invention have surprisingly discovered that by adapting the molding step so that the density of the molded biomass product produced from the step is controlled within a certain range, certain advantageous properties can be imparted to the final solid biomass fuel product. In particular, it was found that by controlling the molding step so that the density of the molded biomass product is in the range of 0.60 to 1.30 kg / L, advantageous properties can be imparted to the final biomass fuel product. Preferably, the molding step is controlled so that the density of the molded biomass product is in the range of 0.70 kg / L to 1.25 kg / L.

[0107] The molding step can be controlled in various ways. When the molding process involves the use of a compression mold, density is controlled by using a compression ratio between 3.8 and 6.5. Typically, a lower compression ratio results in a lower density of the molded biomass product. However, a higher compression ratio results in a lower yield of the molded biomass product.

[0108] For a compression mold having a molded product escape hole, the compression ratio can be defined as the ratio of the length to the diameter of the molded product escape hole.

[0109] Figure 21 shows an example of a compression mold that can be used according to the present invention. After the heated biomass product is inserted into the mold, it is pushed out from the inside of the mold by pressure so that it exits through the molded product exit hole shown in the figure. The pressure ratio is shown in the figure as the ratio of the length to the diameter of the molded product exit hole.

[0110] In the method of the present invention, preferably, step (iii) of molding the biomass powder includes adapting the molding step so that the density of the molded biomass product is controlled to be within the range of 0.70 kg / L to 1.25 kg / L. Preferably, the density is controlled by using a compression mold and controlling the compression ratio of the compression mold. More preferably, the compression ratio is 3.8 to 6.5.

[0111] It has been found that, surprisingly, controlling the density of the molded biomass product during the molding step provides an increase in the water-resistant capacity of the final biomass fuel product. Preferably, solid biomass fuel products produced from molded biomass products having a density in the range of 0.70 kg / L to 1.25 kg / L are sufficiently water-resistant for up to 20 days, preferably up to 30 days.

[0112] Preferably, an additive is added to the heated biomass product before step (iii) of molding the heated biomass product. The additive is thought to improve the molding process and increase the yield of the molded biomass product produced from the molding step. Suitable additives include, but are not limited to, starch or starch derivatives, which are known in the art.

[0113] Figure 2 shows the difference in yield after the molding step when additives are included during the molding step compared to when additives are not included, with one or more biomass sources consisting of rice husks. It can be seen that a higher yield is obtained when additives are added to the heated biomass product before molding.

[0114] Figure 3 is a graph illustrating the productivity (Y-axis) against the compression ratio (X-axis) for molded biomass products produced according to the method of the present invention. The biomass source here consists of rice husks.

[0115] Figure 4 is a graph illustrating the density (kg / L) on the y-axis against the compression ratio (x-axis) for molded biomass products produced according to the method of the present invention, where the biomass source is rice husks.

[0116] In the method of the present invention, once step (iii) is performed, in some embodiments the direct product of the molding step (referred to herein as the molded biomass product) may be used directly as solid biomass fuel in a combustion method. In alternative embodiments, the molded biomass product may be further processed so as to provide a solid biomass fuel product. Thus, in some embodiments, the method of the present invention further includes a step of processing the direct product of the molding step (molded biomass product) to form a solid biomass fuel.

[0117] The present invention involves heating the biomass powder before molding it into heated biomass particles. This is in contrast to known methods in which molding is performed before roasting the biomass. The advantage of roasting before molding is that the roasting process is easier and requires less energy compared to larger molded pellets, due to the smaller particle size and larger surface area of ​​the biomass powder. In methods in which roasting is performed after molding, in some cases only the outside of the molded pellet is effectively roasted, while the inside is not effectively roasted. Furthermore, roasting molded pellets can lead to crack formation during the heating step. Therefore, it has been found that molding after roasting is advantageous.

[0118] However, known methods require molding to provide a uniform and homogeneous shaped pellet product, and therefore involve molding before roasting. It is highly desirable that the biomass particles subjected to roasting be of uniform size. For previously known biomass starting materials such as various types of wood, the pulverization process used to break down the wood into small particles does not provide a sufficiently uniform pulverized product, and therefore molding before roasting is necessary. Thus, molding of the pulverized particles is necessary to provide a uniform product for roasting. In contrast, when using rice husks as a biomass starting material, roasting may be performed before molding, which is advantageous because the rice husk particles naturally exist in a small and uniform size, and either pulverization is not necessary to produce a uniform product with a large surface area, or only minimal pulverization is required. The product can be roasted without molding, and therefore the advantages described above are provided.

[0119] Typically, other than the additives described above, no other fuel sources are added to the heated biomass product during the molding step. Therefore, the molded biomass product (i.e., solid biomass fuel) in the molding step contains only biomass-derived materials as fuel sources in the solid biomass fuel. For example, when molding the heated biomass product into pellets, typically, no other fuel sources are added to the heated biomass product before molding so that the solid biomass fuel pellets produced by the molding step contain only biomass-derived fuel sources. Therefore, in a preferred embodiment, the solid biomass fuel constitutes at least 50% by weight of the total fuel content of the fuel, for example, at least 60% by weight, at least 70% by weight, at least 80% by weight, at least 90% by weight, preferably at least 95% by weight of biomass-derived materials. If one or more biomass sources consist of or are essentially made of rice husks, the biomass solid fuel constitutes at least 95% by weight of biomass-derived materials of the total fuel content of the fuel.

[0120] This is in contrast to certain methods known in the art, in which solid fuel pellets are produced in a molding step, during which biomass-derived material is mixed with an alternative fuel source such as coal. Thus, the pellets will contain both biomass-derived material and an additional fuel source such as coal.

[0121] Where the term "total fuel content of a solid fuel" is used herein, it is intended to refer to the components of a solid fuel that are combustible materials, such as biomass-derived materials and coal. The term "fuel content of a solid fuel" is not intended to include additives that may be present in solid fuel pellets that do not produce energy through their own combustion.

[0122] The molding step has also been found to enhance the watertight properties of the final biomass solid fuel product. The increase in density that occurs during the molding step means that the denser molded biomass product particles are less permeable to water. Furthermore, as the product becomes denser, more biomass is concentrated inside the molded material, preventing direct contact with water.

[0123] Solid biomass fuel products Solid biomass fuel products may possess any of the physical properties described above.

[0124] As described above, the biomass solid fuel of the present invention preferably comprises pellets. The pellets may be of any suitable size. Preferably, the pellets have a diameter of 3 mm to 100 mm, more preferably 5 mm to 8 mm. Preferably, the pellets have a length of 20 mm to 60 mm, more preferably 30 mm to 50 mm. Surprisingly, as discussed above, the solid biomass fuel product of the present invention has been found to have enhanced waterproofing characteristics compared to solid biomass fuel products produced by prior art methods. This is thought to be due to the molding and / or heating steps being controlled as described above. The inventors have found that prior art biomass fuels are only sufficiently waterproof for a maximum of 10 days. In contrast, the solid biomass fuel product of the present invention has been found to be sufficiently waterproof for a maximum of 20 days, preferably 30 days, and more preferably 40 days.

[0125] The waterproofing properties of solid biomass fuels are determined by standard tests conducted by the Energy Research Centre of the Netherlands (ECN), which are described in more detail below.

[0126] The moisture content of the biomass solid fuel of the present invention can also be determined by the standard ECN test method. The moisture content of the solid biomass fuel of the present invention is typically 5-9% by weight, preferably 6-8% by weight, and more preferably 6-7% by weight.

[0127] The solid biomass fuel of the present invention has also been found to possess unexpectedly high mechanical durability. Mechanical durability is typically over 95%. This is advantageous because biomass pellets with mechanical durability of 95% or more have been found to be able to be stored outdoors without damage for as long as two months. In contrast, biomass pellets with mechanical durability of less than 95% are typically damaged by rainfall and cannot be stored outdoors. Therefore, high mechanical durability is a further advantage of the biomass pellets of the present invention.

[0128] A further advantage associated with the high durability of solid biomass fuel particles is that if the pellets are broken in any way by force, they will break into larger pieces than pellets with lower mechanical durability. This minimizes the risk of dust explosions, if any.

[0129] As described above, in preferred embodiments, typically no other fuel sources are added to the heated biomass product during the molding step, other than the additives described above. Therefore, the solid biomass fuel typically contains only biomass-derived materials as fuel sources. For example, when molding the heated biomass product into pellets, typically, no other fuel sources are added to the heated biomass product before molding, so that the solid biomass fuel pellets produced by the molding step contain only biomass-derived fuel sources.

[0130] Therefore, in a preferred embodiment, the solid biomass fuel constitutes at least 50% by weight of the total fuel content, for example, at least 60% by weight, at least 70% by weight, at least 80% by weight, at least 90% by weight, preferably at least 95% by weight of biomass-derived materials. If one or more biomass sources consist of or are essentially made of rice husks, the biomass solid fuel constitutes at least 95% by weight of the total fuel content of biomass-derived materials.

[0131] Typically, solid biomass fuels do not contain oxidizers, igniters, or any combination thereof. For example, when formed into pellets, solid biomass fuel pellets preferably do not contain igniters or oxidizers, and examples of igniters and oxidizers are known in the art, such as potassium permanganate. An advantage related to the present invention is that solid biomass fuel does not require the igniter and oxidizer to burn effectively. Previously, when rice husks were used as a source of biomass in fuel products, it was necessary to include an igniter or oxidizer in the fuel for it to burn properly.

[0132] In addition, as described above, preferably, the solid biomass fuel product of the present invention does not contain an additional fuel source such as fossil fuels, e.g., coal. Previously, when rice husks were used as a biomass source for fuel, the rice husks were combined with coal to burn effectively and provide sufficient energy during the combustion method. An unexpected advantage of the present invention is that the solid biomass fuel product does not need to contain coal or any other additives to burn effectively or to provide sufficient energy during the combustion method.

[0133] Although not limited by theory, it is believed that by controlling the density during the molding step and the uniformity during the heating step as discussed above, the biomass solid fuel product of the present invention can be given excellent performance characteristics. As a result, the product can be effectively burned without the need to add an oxidizer or ignition compound and coal during the molding step, so that the final biomass solid fuel pellets contain coal and an oxidizer or ignition compound together with the biomass.

[0134] Combustion method The products of the present invention can be used in a variety of different combustion methods. The suitability of the products for use in specific methods will be apparent to those skilled in the art. For example, the biomass fuel of the present invention may be used alone in combustion methods in power plants or in industrial processes. Alternatively, the biomass products of the present invention may be used in combustion methods in co-firing with additional fuels such as coal.

[0135] Advantageously, the products of the present invention have been found to produce significantly lower PM1.0 emissions compared to other biomass fuels known in the art. In addition, the PM1.0 emissions of this method are lower than those of methods involving the combustion of coal.

[0136] Advantageously, the improved physical properties of the biomass fuel of the present invention have been found to make the biomass particularly suitable for co-firing with coal. For example, the improved quality and uniformity of the product allows the biomass fuel of the present invention to be co-fired with coal particularly well. The improved waterproof properties of the biomass fuel of the present invention also mean that the biomass is particularly suitable for co-firing with coal, and due to its waterproof properties, storage and transportation are made easier. [Examples]

[0137] The method according to the present invention was carried out. The only source of biomass was rice husks. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated rice husks were cooled and then molded to obtain solid biomass fuel.

[0138] A photograph of the solid product is shown in Figure 5. [Examples]

[0139] The method according to the present invention was carried out. The biomass source consisted of 75% by weight of rice husks and 25% by weight of mixed wood. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel. [Examples]

[0140] The method according to the present invention was carried out. The biomass source consisted of 50% by weight of rice husks and 50% by weight of mixed wood. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel. [Examples]

[0141] The method according to the present invention was carried out. The biomass source consisted of 25% by weight of rice husks and 75% by weight of mixed wood. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel. [Examples]

[0142] The method according to the present invention was carried out. The biomass source consisted of 75% by weight of rice husks and 25% by weight of Calliandra carotyrus. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel. [Examples]

[0143] The method according to the present invention was carried out. The biomass source consisted of 50% by weight of rice husks and 50% by weight of Calliandra carotyrus. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel. [Examples]

[0144] The method according to the present invention was carried out. The biomass source consisted of 25% by weight of rice husks and 75% by weight of Calliandra carotyrus. The temperature during the heating step was 220°C to 280°C for a period of 0.4 to 2 hours. After the heating step, the heated biomass product was cooled and then molded to obtain solid biomass fuel.

[0145] Characterization of solid biomass fuels produced in Examples 1-7 The bulk density (kg / L) of the solid biomass fuels prepared in Examples 1 to 7 was measured using DIN EN 15103 and is shown in Figure 6.

[0146] The durability of the solid biomass fuels prepared in Examples 1 to 7 was determined according to DIN EN 15210-1 and is shown in Figure 7.

[0147] Figure 8 shows the sulfur content of the solid biomass fuels prepared in Examples 1 to 7. The sulfur content is determined according to DIN EN 15289.

[0148] Figure 9 shows the oxygen content of the solid biomass fuels prepared in Examples 1 to 7. The oxygen content was determined according to DIN EN 15296.

[0149] Figure 10 shows the carbon content of the biomass solid fuels prepared in Examples 1 to 7. The carbon content is determined according to DIN EN 15104.

[0150] Figure 11 shows the nitrogen content of the biomass solid fuels prepared in Examples 1 to 7. The nitrogen content is determined according to DIN EN 15104.

[0151] Figure 12 shows the fixed carbon content of the biomass solid fuels prepared in Examples 1 to 7. The fixed carbon content is determined according to DIN EN 51734.

[0152] Figure 13 shows the ash content of the biomass solid fuels prepared in Examples 1 to 7. The ash content was determined at 550°C according to DIN EN 14775.

[0153] The moisture content of the biomass solid fuels prepared in Examples 1 to 7 is shown in Figure 14. The water content was determined according to DIN EN 14774-2.

[0154] Figure 15 shows the volatile substance content of the solid biomass fuels prepared in Examples 1 to 7. Figure 16 shows the PM1.0 emissions from the biomass solid fuels produced in Examples 1 to 7. PM1.0 emissions were determined by the standard method of the German ECN Testing Laboratory.

[0155] In the figure above, the product of Example 1 is represented as A, the product of Example 2 as B, the product of Example 3 as C, the product of Example 4 as D, the product of Example 5 as E, the product of Example 6 as F, and the product of Example 7 as G. [Examples]

[0156] The solid biomass fuel from Example 1 was tested in an artificial climate experiment and exposed to an artificial climate chamber for 10 days. This test is an ECN standard test for evaluating the moisture content of biomass fuel particles.

[0157] The results of this test are shown in Figure 17. The results in Figure 17 show that the equilibrium moisture uptake of the biomass particles stabilized at 6-7% by weight after approximately 14 days of exposure at 27°C and 90% relative humidity. This indicates a low moisture content for biomass fuel particles, suggesting that the biomass particles are highly hydrophobic and water-resistant compared to biomass solid fuels known in the art.

[0158] In the second experiment in the climate chamber, biomass solid fuel was immersed in water at 27°C for 15 minutes and then exposed to the climate chamber. After immersion in water, the moisture content of the sample was 90% by weight. After 10 days of exposure in the climate chamber, the moisture content of the fuel stabilized at around 7.6%. The results are shown in Figures 18 and 19. Particle immersion had no effect on the equilibrium moisture content achieved after 10 days. [Examples]

[0159] The products from Examples 1 to 7 were subjected to repeated climate chamber experiments.

[0160] Figure 20 shows the surface moisture content of the products from Examples 1 to 7. It can be seen that the surface moisture content of the biomass particles and the actual moisture content are very close.

[0161] In Figures 17-20, the values ​​on the y-axis represent the weight percentage of water content in the biomass particles.

Claims

1. A method for producing solid biomass fuel, (i) A step of preparing one or more biomass powders having particle sizes of 1000 μm to 10000 μm, (ii) The step of heating one or more of the biomass powders to a temperature of 160°C to 420°C for a period of 0.25 to 5 hours to provide a heated biomass product, and (iii) The step of molding the heated biomass product to provide a solid biomass fuel, Step (i) of preparing the one or more biomass powders includes pulverizing one or more biomass sources and / or mixing the one or more biomass powders, Step (iii) of molding the heated biomass product includes adapting the molding step so that the density of the solid biomass fuel is controlled, and adapting the molding step so that the density of the solid biomass fuel is controlled includes controlling the compression ratio of the mold used in the molding step to 3.8 to 6.

5. The one or more biomass powders are derived from one or more biomass sources; the one or more biomass sources are (i) consisting of or essentially consisting of rice husks; (ii) containing or essentially consisting of a mixture of rice husks and wood such as mixed wood; or (iii) consisting of a mixture of rice husks and Calliandra carotyrus. or essentially consisting of a mixture; or (iv) comprising at least 15% by weight of rice husks and Calliandra carotylus; if the one or more biomass sources consist of or essentially consist of rice husks, biomass-derived material is present in the solid biomass fuel in an amount of at least 95% by weight of the total fuel content of the solid biomass fuel; The method wherein the solid biomass fuel has a mechanical durability of 95% or more as determined by DIN EN 15210-1, and, when immersed in water, a chemical oxygen demand (COD) of 5000 ppm or less as determined by GB / 11914-89.

2. (a) One or more sources of biomass consist of or are essentially made from rice husks; (b) One or more sources of biomass further include wood such as mixed wood, Calliandra carotylus, or a combination thereof; or (c) One or more sources of biomass include (i) rice husks and Calliandra carotyrus, or (ii) rice husks and wood such as mixed wood; The method according to claim 1.

3. One or more biomass sources comprising 20% ​​to 80% by weight of rice husks and optionally (a) 20% to 80% by weight of wood such as mixed wood; or (b) 20% to 80% by weight of Calliandra carotylus. The method according to claim 1.

4. The method according to claim 1, wherein step (ii) of heating one or more biomass powders is performed for a period of 0.5 to 3 hours, and / or step of heating one or more biomass powders includes heating the one or more biomass powders to a temperature of 180°C to 350°C, optionally 210°C to 280°C.

5. The step of cooling the heated biomass product is further included prior to the step of molding the heated biomass product, and / or, step (i) of preparing one or more biomass powders includes pulverizing one or more biomass sources and / or mixing the one or more biomass powders, The method according to claim 1.

6. The method according to claim 1, wherein step (ii) of heating one or more biomass powders is adapted so as to control the uniformity of the heated biomass product, and adapting step (ii) so as to control the uniformity of the heated biomass product is performed in an apparatus that rotates the one or more biomass powders while heating them; optionally adapting step (ii) so as to control the uniformity of the heated biomass product is performed by controlling the speed or direction of rotation of the one or more biomass powders, and optionally rotating the one or more biomass powders in both counterclockwise and clockwise directions in the apparatus.

7. The method according to claim 1, wherein the bulk density of the solid biomass fuel as determined by DIN EN 15103 is 0.40 kg / l to 0.65 kg / l, and / or the mechanical durability of the solid biomass fuel as determined by DIN EN 15210-1 is 95% or more.

8. (i) One or more biomass sources contain or consist essentially of rice husks, the solid biomass fuel has a bulk density of 0.40 kg / L to 0.48 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. (ii) The one or more biomass sources include a mixture of rice husks and wood such as mixed wood, the solid biomass fuel has a bulk density of 0.50 kg / L to 0.65 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more, (iii) The one or more biomass sources include a mixture of rice husks and Calliandra carotylus, the solid biomass fuel has a bulk density of 0.45 kg / L to 0.60 kg / L, and the mechanical durability of the solid biomass fuel is 95% or more. The bulk density is determined by DIN EN 15103, and the mechanical durability is determined by DIN EN 15210-1. The method according to claim 1.

9. The method according to claim 1, wherein (i) the total dry sulfur content of the biomass solid fuel is 0.05% by weight or less, and the total dry sulfur content is determined by DIN EN 15289; (ii) the total dry hydrogen content of the biomass solid fuel is 5% by weight or more, and the total dry hydrogen content is determined by DIN EN 15104; (iii) the total dry oxygen content of the biomass solid fuel is 34% by weight or more, and the total dry oxygen content is determined by DIN EN 15296; (iv) the total dry carbon content of the biomass solid fuel is 40% by weight or more, and the total dry carbon content is determined by DIN EN 15104; and / or (v) the total dry nitrogen content of the biomass solid fuel is less than 0.5% by weight, and the total dry nitrogen content is determined by DIN EN 15104.

10. The method according to claim 1, wherein (i) the chemical oxygen demand (COD) of the solid biomass fuel is 5000 ppm or less when immersed in water, and the chemical oxygen demand is determined by GB / 11914-89; (ii) the fixed carbon content of the solid biomass fuel is 28% by weight or more, and the fixed carbon content is determined by DIN EN 51734; (iii) the ash content of the solid biomass fuel is less than 25% by weight, and the ash content at 550°C is determined by EN 14775; and / or (iv) the volatile matter content of the solid biomass fuel is 40% by weight to 65% by weight, and the volatile matter content is determined by DIN EN 15148.

11. The method according to claim 1, wherein the solid biomass fuel does not include adding coal, an oxidizer, an igniter, or a combination thereof to the heated biomass product before the molding step, and the solid biomass fuel does not include coal, an oxidizer, an igniter, or a combination thereof.

12. The method according to claim 1, wherein step (ii) of heating one or more biomass powders comprises heating the one or more biomass powders for a period of 30 minutes to 5 hours, or optionally 1 hour to 5 hours.

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