Sealant film for retort food packaging containers

Abstract

To provide a sealant film for a retort food packaging container in which a wide processable temperature range and shock resistance at a low temperature are balanced at a high level beyond the limit of the conventional technique.SOLUTION: The problem is solved by a sealant film for a retort food packaging container, comprising (A) a seal layer, (B) a core layer, and (C) a laminate layer each containing straight-chain polyethylene, wherein (B) the core layer and (C) the laminate layer each have a thermal melting rate of 30-95 mass% at 121°C, and (A) the seal layer has a thermal melting rate of 5-50 mass% at 121°C.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to a sealant film for a retort food packaging container, and more specifically, to a sealant film for a retort food packaging container in which a wide processing temperature range and high impact resistance at low temperatures are balanced at a high level.

Background Art

[0002] In the field of packaging containers for retort foods, where demand has been increasing in recent years, there is a need for retort food packaging containers suitable not only for room temperature storage / distribution but also for low temperature storage / distribution (freezing to chilled). Therefore, for such sealant films for retort food packaging containers, in addition to the conventionally required heat sealability, high temperature heat resistance, etc., impact resistance at low temperatures is also required.

[0003] In order to achieve both low temperature impact resistance and high temperature heat resistance, etc., a laminate in which at least a first layer, a second layer, and a third layer are laminated in this order, the first layer contains a specific ethylene-α-olefin copolymer, and the second layer contains a specific ethylene-α-olefin copolymer, and the third layer contains a specific ethylene-α-olefin copolymer and high density polyethylene. A sealant film for retort foods composed of a laminate has been proposed (for example, see Patent Document 1).

[0004] Similarly, as a laminate suitable for films and sheets for packaging cooked foods, etc., which have both impact resistance and heat resistance, etc., a linear low density polyethylene (A) composed of a copolymer of ethylene and an α-olefin having 3 to 20 carbon atoms and a first layer containing high density polyethylene (B) which is a homopolymer of ethylene or a copolymer of ethylene and an α-olefin having 3 to 20 carbon atoms, and a second layer containing high density polyethylene (C) which is a homopolymer of ethylene or a copolymer of ethylene and an α-olefin having 3 to 20 carbon atoms and is produced by a metallocene catalyst or a single site catalyst. A laminate characterized by consisting of at least two layers has been proposed (for example, see Patent Document 2).

[0005] As described above, heretofore, heat sealability, high temperature heat resistance, etc. have been required for retort food packaging containers. In particular, from the viewpoints such as the retort treatment process and the degree of freedom of the food to be stored, after performing the retort treatment at a predetermined retort temperature, the temperature range (processable temperature) at which the packaging container can be easily opened without significant deformation has become increasingly important. From this viewpoint, there is a growing need for a sealant film for retort food packaging containers that has a wide processable temperature range and high-level balance with impact resistance at low temperatures. For example, a packaging container is formed such that the seal layers are in contact with each other, and after performing the retort treatment at a predetermined retort temperature, the temperature range (processable temperature) at which the packaging container can be easily opened without significant deformation is wide, and the packaging container does not easily burst even when the drop test at low temperature is repeated after the formation of the packaging container. A sealant film for retort food packaging containers is required.

[0006]

Patent Document 1

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0007] In view of the above technical background, an object of the present invention is to provide a sealant film for retort food packaging containers that has a wide processable temperature range and high-level balance with impact resistance at low temperatures beyond the limits of the prior art.

Means for Solving the Problems

[0008] As a result of diligent research, the inventors have discovered that in a sealant film for retort food packaging containers having (A) a seal layer, (B) a core layer, and (C) a laminate layer, each containing linear polyethylene, by setting the thermal melting rate of each layer at a predetermined temperature within a specific range, it is possible to achieve both a wide processing temperature range and low-temperature impact resistance at a high level that surpasses the limitations of the prior art, thus completing the present invention. In other words, the present invention is [1] A sealant film for retort food packaging containers having (A) a seal layer, (B) a core layer, and (C) a laminate layer, each containing linear polyethylene, (B) The core layer and (C) the laminate layer have a thermal melting rate of 30-95% by mass at 121°C. (A) The thermal melting rate of the seal layer at 121°C is 5 to 50% by mass. Sealant film for retort food packaging containers, That is the case.

[0009] Hereinafter, [2] to [5] are all preferred embodiments or models of the present invention. [2] (A) A sealant film for retort food packaging containers according to [1], wherein the thermal melting rate of the seal layer at 121°C is 5 to 35% by mass. [3] A sealant film for retort food packaging containers according to [1] or [2], wherein the linear polyethylene constituting (B) the core layer and (C) the laminate layer is polymerized using a metallocene catalyst. [4] A retort food packaging container film comprising a sealant film for retort food packaging containers and a base film as described in any one of [1] to [3], wherein the base film is laminated with the sealant film for retort food packaging containers in a (C) laminate layer. [5] A retort food packaging container, including the film for retort food packaging containers described in [4]. [Effects of the Invention]

[0010] The sealant film for retort food packaging containers of the present invention surpasses the limitations of conventional technology, achieving both a wide processing temperature range and impact resistance at low temperatures at a high level. For example, when a packaging container is formed so that the sealing layers are in contact with each other, and after retorting at a predetermined retort temperature, the packaging container can be easily opened without significant deformation (processing temperature) within a wide range of temperatures, and even after repeated drop tests at low temperatures after the packaging container is formed, it does not easily rupture, thus achieving remarkable technical effects. [Modes for carrying out the invention]

[0011] The present invention relates to a sealant film for retort food packaging containers having (A) a seal layer, (B) a core layer, and (C) a laminate layer, each containing linear polyethylene, (B) The core layer and (C) the laminate layer have a thermal melting rate of 30-95% by mass at 121°C. (A) The thermal melting rate of the seal layer at 121°C is 5 to 50% by mass. This is a sealant film for retort food packaging containers. In other words, the sealant film for retort food packaging containers of the present invention has a seal layer (A), a core layer (B), and a laminate layer (C).

[0012] sealing layer (A) The seal layer (A) constituting the sealant film for retort food packaging containers of the present invention contains linear polyethylene. Therefore, the seal layer (A) may consist only of linear polyethylene, or it may contain other components in addition to linear polyethylene, such as other resins, or various additives such as antiblocking agents and slipping agents. By containing linear polyethylene in the seal layer (A), the sealant film for retort food packaging containers of the present invention can balance a wide processing temperature range and impact resistance at low temperatures at a high level, and also appropriately possess physical properties generally required for sealant films such as heat sealability, flexibility, flexibility, airtightness, etc.

[0013] The seal layer (A) has a heat melting rate at 121 °C of 5 to 50% by mass. Since the heat melting rate of the seal layer (A) at 121 °C is within the range of 5 to 50% by mass, combined with other requirements of the present invention, the processable temperature range of the sealant film for retort food packaging containers of the present invention can be expanded. The melting rate of the seal layer (A) at 121 °C is more preferably 35% by mass or less, and particularly preferably 30% by mass or less. The heat melting rate of the seal layer (A) can be appropriately adjusted by adjusting the type and amount of the material constituting the seal layer (A), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention including the seal layer (A) or the seal layer (A).

[0014] There is no particular limitation on the density of the seal layer (A), but it is preferably 915 kg / m 3 or more and 960 kg / m 3 or less. The density of the seal layer (A) being 915 kg / m 3 or more and 960 kg / m 3 or less is advantageous for achieving a high level of compatibility between the processable temperature range and impact resistance at low temperatures of the sealant film for food packaging containers of the present invention. The density of the seal layer (A) is preferably 925 kg / m 3 or more and 960 kg / m 3 or less, more preferably 930 kg / m 3 or more and 955 kg / m 3 or less, and particularly preferably 940 kg / m 3 or more and 95^{3} kg / m 3 or less. The density of the sealing layer (A) can be appropriately adjusted by adjusting the type and amount of material constituting the sealing layer (A), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the sealing layer (A). If the seal layer (A) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additives, the density of the seal layer (A) is largely determined by the density of the linear polyethylene. In such cases, the density is 915 kg / m³. 3 More than 960kg / m 3 Preferably 930 kg / m 3 More than 955kg / m 3 More preferably, 940 kg / m 3 More than 953kg / m 3 By using linear polyethylene as described below, the density of the sealing layer (A) can be kept within the above range.

[0015] There are no particular restrictions on the melting point of the sealing layer (A), and it can be set appropriately depending on the application and usage of the sealant film for retort food packaging containers, but it is preferably 120 to 135°C. By having the melting point of the sealing layer (A) within the above range, the processable temperature range of the sealant film for food packaging containers of the present invention can be further expanded. The melting point of the seal layer (A) is more preferably 122 to 134°C, and particularly preferably 125 to 133°C. The melting point of the seal layer (A) can be appropriately adjusted by adjusting the type and amount of material constituting the seal layer (A), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the seal layer (A). If the seal layer (A) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additive, the melting point of the seal layer (A) is largely determined by the melting point of the linear polyethylene. In such cases, the melting point of the seal layer (A) can be kept within the preferred range by using linear polyethylene having a melting point of 120 to 135°C, preferably 125 to 133°C.

[0016] There are no particular restrictions on the MFR (melt flow rate) of the seal layer (A). It can be set appropriately according to the manufacturing conditions of the seal layer (A) or the sealant film for retort food packaging containers containing the seal layer (A), and the physical properties required for the sealant film for retort food packaging containers. However, it is preferable that the MFR (190°C, 2160g load) is 0.1 to 15g / 10min. By having the MFR of the sealing layer (A) within the above range, the manufacturing of the sealant film for food packaging containers of the present invention becomes even easier, and desirable effects such as the resin pressure during extrusion being within an appropriate range can be achieved. The MFR (190°C, 2160g load) of the sealing layer (A) is more preferably 0.5 to 12 g / 10 min, and particularly preferably 0.7 to 11 g / 10 min. The MFR of the seal layer (A) can be adjusted as appropriate by selecting and adjusting the type and amount of materials that make up the seal layer (A). If the seal layer (A) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additive, the MFR of the seal layer (A) is largely determined by the melting point of the linear polyethylene. In such cases, the MFR of the seal layer (A) can be brought within the preferred range by using linear polyethylene with an MFR (190°C, 2160g load) of 0.1 to 15g / 10min, more preferably 0.5 to 12g / 10min.

[0017] Linear polyethylene The linear polyethylene constituting the seal layer (A) may be any homopolymer of ethylene having a substantially linear main chain, or a copolymer of ethylene and another monomer; there are no other restrictions. Typical forms of linear polyethylene include high-density polyethylene and linear low-density polyethylene. In the sealing layer (A), the density of the sealing layer (A) is set to a preferred range, for example, 915 kg / m³. 3 More than 960kg / m 3 It is preferable to use linear polyethylene which can be as follows: The linear polyethylene content of the sealing layer (A) is preferably 20% by mass or more, more preferably 25 to 100% by mass, and particularly preferably 30 to 100% by mass. In the sealing layer (A), only one type of linear polyethylene may be used, or two or more types of linear polyethylene may be used in combination. When two or more types of linear polyethylene are used in combination, the linear polyethylene content described above is calculated based on the total mass of the two or more types of linear polyethylene.

[0018] High-density polyethylene As a representative form of linear polyethylene, high-density polyethylene can be used as appropriate, which is generally known as high-density polyethylene in the relevant technical field. High-density polyethylene (HDPE) may be an ethylene homopolymer or a copolymer of ethylene and α-olefin.

[0019] The above-mentioned high-density polyethylene preferably has a melt flow rate (hereinafter referred to as MFR) of 0.1 to 15 g / 10 min, more preferably 0.5 to 12.0 g / 10 min, and even more preferably 0.7 to 11.0 g / 10 min, measured at 190°C and a load of 2160 g in accordance with JIS K6922-1. Having the MFR within the above range is preferable because it reduces the load on the extruder during molding and improves molding stability.

[0020] The high-density polyethylene preferably used in this embodiment has a density of 940 to 975 kg / m³ in accordance with JIS K6922-1. 3 Preferably, and more preferably, 945-965 kg / m 3 More preferably 950-960 kg / m 3 That is the case. By having a density within the above range, the density of the sealing layer (A) can be set to a preferred range, for example, 915 kg / m³. 3 More than 960kg / m 3This makes it easier to do the following:

[0021] The high-density polyethylene preferably used in this embodiment may be a commercially available product, for example, Nipolon Hard 5700, 8500, 8022 (product names) manufactured by Tosoh Corporation, and Hyzex® 3300F manufactured by Prime Polymer Co., Ltd.

[0022] Furthermore, the high-density polyethylene preferably used in this embodiment can be manufactured by methods such as the slurry method, solution method, or gas phase method. When manufacturing the high-density polyethylene, a Ziegler catalyst consisting of a solid catalyst component containing magnesium and titanium and an organoaluminum compound, a metallocene catalyst consisting of an organotransition metal compound containing a cyclopentadienyl derivative and a compound that reacts with it to form an ionic complex and / or an organometallic compound, or a vanadium-based catalyst can be used. The high-density polyethylene can be manufactured by homopolymerizing ethylene or copolymerizing ethylene with α-olefins using these catalysts. The α-olefin can be any α-olefin generally referred to as such, and is preferably an α-olefin having 3 to 12 carbon atoms, such as propylene, butene-1, hexene-1, octen-1, or 4-methyl-1-pentene. Examples of copolymers of ethylene and α-olefins include ethylene-hexene-1 copolymer, ethylene-butene-1 copolymer, and ethylene-octen-1 copolymer.

[0023] Linear low-density polyethylene As a typical form of linear polyethylene, linear low-density polyethylene can be any linear low-density polyethylene that is generally known in the art. Such linear low-density polyethylene can be a copolymer of ethylene and α-olefin, and can be synthesized using a production method that uses a known catalyst such as a Ziegler catalyst or a metallocene catalyst.

[0024] As the α-olefin, compounds having 3 to 20 carbon atoms can be used, such as propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-dodecene, 4-methyl-1-pentene, 4-methyl-1-hexene, etc., and mixtures thereof may also be used. Preferably, the α-olefin is a compound having 4, 6, or 8 carbon atoms or a mixture thereof, such as 1-butene, 1-hexene, 1-octene, or a mixture thereof. However, it is also possible to increase the amount of ethylene during the polymerization process to produce α-olefins, in which case it is possible to manufacture them using virtually only ethylene as a raw material.

[0025] Linear low-density polyethylene can be a commercially available product, for example, 2040F (C6-LLDPE, MFR; 4.0, density; 0.918 g / cm³) manufactured by Ube Maruzen Polyethylene Co., Ltd. 3 ), or products such as Evolu® SP2040 manufactured by Prime Polymer Co., Ltd. can be used.

[0026] The density of linear low-density polyethylene is preferably 890-940 kg / m³. 3 And more preferably, 900-930 kg / m 3 The density of the sealing layer (A) is set to a preferred range, for example, 915 kg / m³. 3 More than 960kg / m 3 From the following perspectives, it is particularly preferable to use a relatively high density within the above density range. The density of linear low-density polyethylene can be adjusted as needed by adjusting the comonomer content, and also by selecting and adjusting polymerization conditions such as catalysts and polymerization temperature.

[0027] From the viewpoint of setting the MFR (190°C, 2160g load) of the sealing layer (A) to the above preferred range, the MFR (190°C, 2160g load) of linear low-density polyethylene is preferably 0.1 to 15 g / 10 min, more preferably 0.5 to 12 g / 10 min, and particularly preferably 0.7 to 11 g / 10 min. The molecular weight-free polymer (MFR) of linear low-density polyethylene (at 190°C and 2160g load) can be adjusted as appropriate by conventionally known methods, such as by adjusting polymerization conditions like polymerization temperature or by introducing molecular weight modifiers.

[0028] Linear low-density polyethylene can be produced by conventionally known manufacturing methods using conventionally known catalysts, including multi-site catalysts such as Ziegler catalysts and single-site catalysts such as metallocene catalysts. From the viewpoint of obtaining linear low-density polyethylene that can form a high-strength film with a narrow molecular weight distribution, it is preferable to use a single-site catalyst.

[0029] The single-site catalyst described above is a catalyst capable of forming a uniform active species, and is usually prepared by contacting a metallocene transition metal compound or a non-metallocene transition metal compound with an activation co-catalyst. Single-site catalysts are preferred over multi-site catalysts because they have a more uniform active site structure, allowing for the polymerization of polymers with high molecular weight and high uniformity. As a single-site catalyst, metallocene catalysts are particularly preferred. A metallocene catalyst is a catalyst comprising a transition metal compound of Group IV of the periodic table containing a ligand having a cyclopentadienyl skeleton, a co-catalyst, an organometallic compound if necessary, and each catalytic component of a support.

[0030] In the transition metal compounds of Group IV of the periodic table containing the ligand having the cyclopentadienyl skeleton described above, the cyclopentadienyl skeleton is a cyclopentadienyl group, a substituted cyclopentadienyl group, etc. The substituted cyclopentadienyl group has at least one substituent selected from hydrocarbon groups having 1 to 30 carbon atoms, silyl groups, silyl-substituted alkyl groups, silyl-substituted aryl groups, cyano groups, cyanoalkyl groups, cyanoaryl groups, halogen groups, haloalkyl groups, halosilyl groups, etc. The substituted cyclopentadienyl group may have two or more substituents, and the substituents may bond to each other to form a ring, forming an indenyl ring, a fluorenyl ring, an azlenyl ring, or a hydrogenated version thereof. The ring formed by the bonding of substituents may further have substituents on each other.

[0031] In a transition metal compound of Group IV of the periodic table containing a ligand having a cyclopentadienyl skeleton, examples of the transition metal include zirconium, titanium, and hafnium, with zirconium and hafnium being particularly preferred. The transition metal compound usually has two ligands having a cyclopentadienyl skeleton, and it is preferable that each ligand having a cyclopentadienyl skeleton is bonded to each other by a bridging group. Examples of bridging groups include alkylene groups having 1 to 4 carbon atoms, silylene groups, substituted silylene groups such as dialkylsilylene groups and diarylsilylene groups, and substituted germylene groups such as dialkylgermylene groups and diarylgermylene groups. A substituted silylene group is preferred.

[0032] In transition metal compounds of Group IV of the periodic table, typical ligands other than those having a cyclopentadienyl skeleton include hydrogen, hydrocarbon groups having 1 to 20 carbon atoms (alkyl groups, alkenyl groups, aryl groups, alkylaryl groups, aralkyl groups, polyenyl groups, etc.), halogens, metaalkyl groups, and metaaryl groups.

[0033] The transition metal compounds of Group IV of the periodic table containing the ligand having the cyclopentadienyl skeleton described above can be used as catalyst components, either individually or as a mixture of two or more.

[0034] Co-catalysts are those that can effectively utilize the transition metal compounds of Group IV of the periodic table mentioned above as polymerization catalysts, or that can balance the ionic charge of the catalytically activated state. Examples of co-catalysts include benzene-soluble aluminoxanes and benzene-insoluble organoaluminum oxy compounds, ion-exchangeable layered silicates, boron compounds, ionic compounds consisting of cations containing or not containing active hydrogen groups and non-coordinating anions, lanthanide salts such as lanthanum oxide, tin oxide, and phenoxy compounds containing fluoro groups.

[0035] Transition metal compounds of Group IV of the periodic table containing ligands having a cyclopentadienyl skeleton may be used by being supported on an inorganic or organic compound support. A porous oxide of an inorganic or organic compound is preferred as the support, specifically an ion-exchangeable material such as montmorillonite. Examples include layered silicates, SiO2, Al2O3, MgO, ZrO2, TiO2, B2O3, CaO, ZnO, BaO, ThO2, etc., or mixtures thereof.

[0036] Further organometallic compounds that may be used as needed include organoaluminum compounds, organomagnesium compounds, and organozinc compounds. Of these, organoaluminum compounds are preferred.

[0037] From the viewpoint of obtaining linear low-density polyethylene with a broad molecular weight distribution and excellent flexibility and moldability, it is preferable to use multi-site catalysts such as Ziegler catalysts and Phillips catalysts. Preferred Ziegler catalysts are those commonly known as Ziegler catalysts used in the coordination polymerization of ethylene and α-olefins, such as catalysts containing titanium compounds and organoaluminum compounds. Examples include catalysts composed of titanium halide compounds and organoaluminum compounds, and catalysts composed of solid catalyst components such as titanium, magnesium, and chlorine, and organoaluminum compounds. Examples of such catalysts include catalysts comprising a catalyst component (ai) obtained by reacting an alcohol pretreatment product of an anhydrous magnesium dihalide with an organometallic compound, and an organometallic compound (bi); catalysts comprising a catalyst component (aii) obtained by reacting magnesium metal with an organic hydroxide or oxygen-containing organic compound such as magnesium, an oxygen-containing organic compound of a transition metal, and an aluminum halide, and an organometallic compound catalyst component (bii); and catalysts comprising (i) metallic magnesium and at least one selected from organic hydroxides, oxygen-containing organic compounds of magnesium, and halogen-containing compounds; (ii) at least one selected from oxygen-containing organic compounds of transition metals and halogen-containing compounds; (iii) a reaction product obtained by reacting a silicon compound with (iv) an aluminum halide compound, and an organometallic compound catalyst component (biii).

[0038] Furthermore, the Phillips catalyst can be any generally known Phillips catalyst used in the coordination polymerization of ethylene and α-olefins, such as a catalyst system containing chromium compounds like chromium oxide. Specifically, examples include catalysts in which chromium compounds such as chromium trioxide and chromate esters are supported on solid oxides such as silica, alumina, silica-alumina, and silica-titania.

[0039] The sealing layer (A) may contain components other than the linear polyethylene described above. For example, polymers other than linear polyethylene, oligomers, antiblocking agents, slip agents, heat stabilizers (antioxidants), weather stabilizers, ultraviolet absorbers, lubricants, nucleating agents, antistatic agents, antifogging agents, pigments, dyes, and various fillers such as talc, silica, and diatomaceous earth may be blended as needed, or insofar as they do not contradict the purpose of the present invention. These additive components may be incorporated into the linear polyethylene beforehand, or they may be added when forming the intermediate layer (A) from the linear polyethylene.

[0040] There are no particular restrictions on the thickness of the sealing layer (A), but from the viewpoint of good sealing characteristics, it is preferable that it be 3 μm or more, more preferably 4 μm or more, and particularly preferably 5 μm or more. On the other hand, from the viewpoint of flexibility and economic efficiency, the thickness of the seal layer (A) is preferably 30 μm or less, more preferably 25 μm or less, and particularly preferably 20 μm or less. When stretching is performed in the manufacturing of the laminated film of the present invention, the stretching ratio is preferably 1 to 100 times in terms of area, and particularly preferably 4 to 80 times. The thickness of the layer corresponding to the sealing layer (A) before stretching is preferably 0.3 to 12 mm, and particularly preferably 0.5 to 4 mm. The thickness of the seal layer (A) can be appropriately adjusted by adjusting the stretching conditions such as the stretching ratio, the thickness of the layer before stretching, and the lip spacing of the die when forming the layer before stretching.

[0041] Core layer (B) The core layer (B) is a layer containing linear polyethylene, the thermal melting coefficient at 121°C being 30 to 95 mass. Because the melting rate of the core layer (B) at 121°C is within the above range, and in conjunction with the other requirements of the present invention, the sealant film for food packaging containers of the present invention can achieve a high level of balance between a wide processable temperature range and impact resistance at low temperatures. The melting rate of the core layer (B) at 121°C is more preferably 45 to 95% by mass, and particularly preferably 47 to 93% by mass. The melting rate of the core layer (B) at 121°C can be appropriately adjusted by adjusting the type and amount of material constituting the core layer (B), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the core layer (B).

[0042] The core layer (B) constituting the sealant film for retort food packaging containers of the present invention preferably contains linear polyethylene polymerized using a metallocene catalyst. Therefore, the core layer (B) may consist only of linear polyethylene polymerized using a metallocene catalyst, or it may contain other components in addition to linear polyethylene polymerized using a metallocene catalyst, such as other resins or various additives such as antiblocking agents and slipping agents. Since linear polyethylene polymerized using a metallocene catalyst has excellent impact resistance, the core layer (B) contains linear polyethylene polymerized using a metallocene catalyst. As a result, the sealant film for retort food packaging containers of this embodiment can achieve a high level of balance between the processable temperature range and impact resistance at low temperatures, and can also appropriately possess physical properties generally required for sealant films, such as heat sealability, flexibility, pliability, and airtightness.

[0043] There are no particular restrictions on the density of the core layer (B), but 932 kg / m³ is acceptable. 3 More than 940kg / m 3 It is preferable that the density of the core layer (B) is less than 932 kg / m³. 3 More than 940kg / m 3 The following is advantageous for achieving a high level of balance between the processable temperature range and low-temperature impact resistance of the sealant film for food packaging containers of the present invention. The density of the core layer (B) is 934 kg / m³ 3 More than 940kg / m 3 It is more preferable that it be less than 936 kg / m 3 More than 940kg / m 3It is especially preferable that it be less than [a certain value]. The density of the core layer (B) can be appropriately adjusted by adjusting the type and amount of material constituting the core layer (B), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the core layer (B). If the core layer (B) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additives, the density of the core layer (B) is largely determined by the density of the linear polyethylene. In such cases, the density is 932 kg / m³. 3 More than 940kg / m 3 Less than 934 kg / m³ 3 More than 940kg / m 3 By using linear polyethylene with a density of less than 1 / 2, the density of the core layer (B) can be kept within the preferred range described above.

[0044] There are no particular restrictions on the melting point of the core layer (B), and it can be set appropriately depending on the application and usage of the sealant film for retort food packaging containers, but it is preferably 120 to 135°C. By having the melting point of the core layer (B) within the above range, the processable temperature range of the sealant film for food packaging containers of the present invention can be further expanded. The melting point of the core layer (B) is more preferably 122 to 134°C, and particularly preferably 125 to 133°C. The melting point of the core layer (B) can be appropriately adjusted by adjusting the type and amount of material constituting the core layer (B), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the core layer (B) or the core layer (B). If the core layer (B) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additives, the melting point of the core layer (B) is largely determined by the melting point of the linear polyethylene. In such cases, the melting point of the core layer (B) can be kept within the preferred range by using linear polyethylene having a melting point of 120 to 135°C, preferably 122 to 134°C.

[0045] There are no particular restrictions on the MFR (melt flow rate) of the core layer (B). It can be set appropriately according to the manufacturing conditions of the core layer (B) or the sealant film for retort food packaging containers containing the core layer (B), and the physical properties required for the sealant film for retort food packaging containers. However, it is preferable that the MFR (190°C, 2160g load) is 6.0g / 10min or less. By having a core layer (B) with an MFR of 6.0 g / 10 min or less, the sealant film for food packaging containers of the present invention can achieve an even higher level of balance between its processable temperature range and impact resistance at low temperatures, thereby realizing desirable effects such as improved impact resistance. The MFR (190°C, 2160g load) of the core layer (B) is more preferably 0.1 to 15g / 10min, and particularly preferably 0.7 to 11g / 10min. The MFR of the core layer (B) can be adjusted as needed by selecting and adjusting the type and amount of materials that make up the core layer (B). If the core layer (B) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additive, the MFR of the core layer (B) is largely determined by the melting point of the linear polyethylene. In such cases, the core layer (B) MFR can be kept within the preferred range by using linear polyethylene with an MFR (190°C, 2160g load) of 0.1 to 15g / 10min, more preferably 0.7 to 11g / 10min.

[0046] For the core layer (B), linear polyethylene polymerized using a metallocene catalyst is preferred. In this case, the linear polyethylene is basically the same type of resin as the linear polyethylene constituting the seal layer (A) described above. However, the description above regarding the production of linear polyethylene using catalysts other than metallocene catalysts does not apply to linear polyethylene polymerized using a metallocene catalyst.

[0047] The density of the linear polyethylene constituting the core layer (B) is within a preferred range for the density of the core layer (B), for example, 932 kg / m³. 3 More than 940kg / m3 It is preferable to set it so that it is less than [a certain value]. More specifically, the density of the linear polyethylene that makes up the core layer (B) is 932 kg / m³. 3 More than 940kg / m 3 Preferably, it should be within the range of less than 934 kg / m 3 More than 940kg / m 3 It is more preferable that it be within the range of less than 936 kg / m 3 More than 940kg / m 3 It is especially preferable that the value be within the range of less than or equal to. From this perspective, linear low-density polyethylene (LLDPE) is preferred over high-density polyethylene (HDPE) as the linear polyethylene constituting the core layer (B), and it is preferable to use only linear low-density polyethylene or a combination in which linear low-density polyethylene makes up the majority.

[0048] The linear polyethylene content of the core layer (B) is preferably 70% by mass or more, more preferably 80-100% by mass, and particularly preferably 90-98% by mass. In the core layer (B), only one type of linear polyethylene may be used, or two or more types of linear polyethylene may be used in combination. When two or more types of linear polyethylene are used in combination, the linear polyethylene content described above is calculated based on the total mass of the two or more types of linear polyethylene.

[0049] There are no particular limitations on the thickness of the core layer (B), but it is preferable that it be greater than the thickness of the seal layer (A) and the laminate layer (C), and it is particularly preferable that it be greater than the sum of the thicknesses of the seal layer (A) and the laminate layer (C). More specifically, the thickness of the core layer (B) is preferably 9 μm or more, and particularly preferably 15 μm or more. On the other hand, from the viewpoint of raw material costs, the thickness of the core layer (B) is preferably 90 μm or less, and particularly preferably 60 μm or less.

[0050] Laminate layer (C) The laminate layer (C) is a layer containing linear polyethylene, and its thermal melting coefficient at 121°C is 30 to 95 by mass. Because the melting rate of the laminate layer (C) at 121°C is within the above range, and in conjunction with the other requirements of the present invention, the sealant film for food packaging containers of the present invention can achieve a high level of balance between a wide processable temperature range and impact resistance at low temperatures. The melting rate of the laminate layer (C) at 121°C is more preferably 45 to 95% by mass, and particularly preferably 47 to 93% by mass. The melting rate of the laminate layer (C) at 121°C can be appropriately adjusted by adjusting the type and amount of materials constituting the laminate layer (C), and the manufacturing conditions of the sealant film for retort food packaging containers of the present invention, which includes the laminate layer (C) or the core layer laminate layer (C).

[0051] The laminate layer (C) constituting the sealant film for retort food packaging containers of the present invention preferably contains linear polyethylene polymerized using a metallocene catalyst. Therefore, the laminate layer (C) may consist only of linear polyethylene polymerized using a metallocene catalyst, or it may contain other components in addition to linear polyethylene polymerized using a metallocene catalyst, such as other resins or various additives such as antiblocking agents and slipping agents. Since linear polyethylene polymerized using a metallocene catalyst has excellent impact resistance, the inclusion of linear polyethylene polymerized using a metallocene catalyst in the laminate layer (C) allows the sealant film for retort food packaging containers of this embodiment to achieve a high level of balance between the processable temperature range and impact resistance at low temperatures, and to appropriately possess physical properties generally required of sealant films, such as heat sealability, flexibility, pliability, and airtightness.

[0052] There are no particular restrictions on the density load of the laminate layer (C), but 932 kg / m 3 More than 940kg / m3 It is less than 932 kg / m³. The density of the laminate layer (C) is 932 kg / m³. 3 More than 940kg / m 3 The following is advantageous in achieving a high level of balance between the processable temperature range and low-temperature impact resistance of the sealant film for food packaging containers of the present invention. The density of the laminate layer (C) is 934 kg / m³ 3 More than 940kg / m 3 It is more preferable that it be less than 936 kg / m 3 More than 940kg / m 3 It is especially preferable that it be less than [a certain value]. The density of the laminate layer (C) can be appropriately adjusted by adjusting the type and amount of materials constituting the laminate layer (C), and the manufacturing conditions of the laminate layer (C) or the sealant film for retort food packaging containers of the present invention that includes the laminate layer (C). If the laminate layer (C) is composed solely of linear polyethylene, or linear polyethylene with a small amount of additives, the density of the laminate layer (C) is largely determined by the density of the linear polyethylene. In such cases, the density is 932 kg / m³. 3 More than 940kg / m 3 Less than 934 kg / m³ 3 More than 940kg / m 3 By using linear polyethylene with a density of less than 1, the density of the laminate layer (C) can be kept within the preferred range described above.

[0053] There are no particular restrictions on the melting point of the laminate layer (C), and it can be set appropriately depending on the application and usage of the sealant film for retort food packaging containers, but it is preferably 120 to 135°C. By having the melting point of the laminate layer (C) within the above range, the processable temperature range of the sealant film for food packaging containers of the present invention can be further expanded. The melting point of the laminate layer (C) is more preferably 122 to 134°C, and particularly preferably 125 to 133°C. The melting point of the laminate layer (C) can be appropriately adjusted by adjusting the type and amount of materials constituting the laminate layer (C), and the manufacturing conditions of the laminate layer (C) or the sealant film for retort food packaging containers of the present invention that includes the laminate layer (C). If the laminate layer (C) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additives, the melting point of the laminate layer (C) is largely determined by the melting point of the linear polyethylene. In such cases, the melting point of the laminate layer (C) can be kept within the preferred range by using linear polyethylene having a melting point of 120-135°C, preferably 122-134°C.

[0054] There are no particular restrictions on the MFR (melt flow rate) of the laminate layer (C). It can be set appropriately according to the manufacturing conditions of the laminate layer (C) or the sealant film for retort food packaging containers containing the laminate layer (C), and the physical properties required for the sealant film for retort food packaging containers. However, it is preferable that the MFR (190°C, 2160g load) is 6.0g / 10min or less. By having a MFR of 6.0 g / 10 min or less in the laminate layer (C), it is possible to achieve an even higher level of balance between the processable temperature range and low-temperature impact resistance of the sealant film for food packaging containers of the present invention, thereby realizing desirable effects such as improved impact resistance. The MFR (190°C, 2160g load) of the laminate layer (C) is more preferably 0.1 to 15g / 10min, and particularly preferably 0.7 to 11g / 10min. The MFR of the laminate layer (C) can be adjusted as needed by selecting and adjusting the type and amount of materials that make up the laminate layer (C). If the laminate layer (C) is composed solely of linear polyethylene, or linear polyethylene and a small amount of additive, the MFR of the laminate layer (C) is largely determined by the melting point of the linear polyethylene. In such cases, the MFR of the laminate layer (C) can be brought within the preferred range by using linear polyethylene with an MFR (190°C, 2160g load) of 0.1 to 15g / 10min, more preferably 0.7 to 11g / 10min.

[0055] For the laminate layer (C), linear polyethylene polymerized using a metallocene catalyst is preferred. In this case, the linear polyethylene is basically the same type of resin as the linear polyethylene constituting the seal layer (A) described above. However, the description above regarding the production of linear polyethylene using catalysts other than metallocene catalysts does not apply to linear polyethylene polymerized using a metallocene catalyst.

[0056] The density of the linear polyethylene constituting the laminate layer (C) is within a preferred range for the density of the laminate layer (C), for example, 932 kg / m³. 3 More than 940kg / m 3 It is preferable to set it so that it is less than [a certain value]. More specifically, the density of the linear polyethylene constituting the laminate layer (C) is 932 kg / m³. 3 More than 940kg / m 3 Preferably, it should be within the range of less than 934 kg / m 3 More than 940kg / m 3 It is more preferable that it be within the range of less than 936 kg / m 3 More than 940kg / m 3 It is especially preferable that the value be within the range of less than or equal to. From this perspective, linear low-density polyethylene (LLDPE) is preferred over high-density polyethylene (HDPE) as the linear polyethylene constituting the laminate layer (C), and it is preferable to use only linear low-density polyethylene or a combination in which linear low-density polyethylene makes up the majority.

[0057] The linear polyethylene content of the laminate layer (C) is preferably 70% by mass or more, more preferably 80-100% by mass, and particularly preferably 90-98% by mass. In the laminate layer (C), only one type of linear polyethylene may be used, or two or more types of linear polyethylene may be used in combination. When two or more types of linear polyethylene are used in combination, the linear polyethylene content described above is calculated based on the total mass of the two or more types of linear polyethylene.

[0058] The laminate layer (C) can be laminated with other layers, including the base layer (D) described later, as necessary or desired. Therefore, it is preferable to design the laminate layer (C) taking into consideration the lamination strength between it and other layers, including the base layer (D). The laminate layer (C) may be subjected to surface treatments such as corona treatment to improve its adhesion to other layers.

[0059] From the viewpoint of preventing blocking when storing the sealant film for retort food packaging containers of the present invention, the laminate layer (C) may contain a blocking inhibitor. As an anti-blocking agent, powdered silica, preferably synthetic silica, etc., can be suitably used. From the viewpoint of uniformly dispersing the powdered silica in the laminate layer (C), the powdered silica may be dispersed in a resin that has excellent miscibility with the resin constituting the laminate layer (C) to form a masterbatch, and then the masterbatch may be added to the laminate layer (C).

[0060] There are no particular restrictions on the thickness of the laminate layer (C), but from the viewpoint of suppressing film curling, it is preferable that it be 3 μm or more, and particularly preferable that it be 5 μm or more. On the other hand, from the viewpoint of raw material costs, etc., it is preferable that the particle size be 30 μm or less, and particularly preferable that it be 20 μm or less.

[0061] Any of the seal layer (A), core layer (B), and laminate layer (C) may contain various additives and fillers other than those mentioned above, as long as they do not contradict the objectives of the present invention. For example, heat stabilizers, antioxidants, light stabilizers, antistatic agents, antiblocking agents, lubricants, nucleating agents, flame retardants, pigments, dyes, calcium carbonate, barium sulfate, magnesium hydroxide, mica, talc, clay, antibacterial agents, antifogging agents, etc. Furthermore, other thermoplastic resins, thermoplastic elastomers, rubbers, etc. (other than those described above) may be blended in as long as they do not contradict the objectives of the present invention. Various additives may be added in masterbatch form.

[0062] Sealant film (laminated film) for retort food packaging containers The sealant film for retort food packaging containers of the present invention comprises a seal layer (A), a core layer (B), and a laminate layer (C). In the sealant film for retort food packaging containers of the present invention, the laminate layer (C) and the seal layer (A) are preferably directly laminated via the core layer (B), but other layers may be present in between.

[0063] The sealant film for retort food packaging containers of the present invention can be manufactured using various known film molding methods. For example, one method may involve first molding films to form a laminate layer (C), a core layer (B), and a seal layer (A), and then laminating these films together to form a sealant film for retort food packaging containers; obtaining a multilayer film consisting of a core layer (B) and a seal layer (A) using a multilayer die, and then extruding the laminate layer (C) onto the surface of the core layer (B) to form a sealant film for retort food packaging containers; obtaining a multilayer film consisting of a laminate layer (C) and a core layer (B) using a multilayer die, and then extruding the seal layer (A) onto the surface of the core layer (B) to form a sealant film for retort food packaging containers; or obtaining a sealant film for retort food packaging containers consisting of a laminate layer (C), a core layer (B), and a seal layer (A) using a multilayer die.

[0064] Furthermore, various known film forming methods can be employed as the film forming method, specifically, T-die-cast film forming methods, inflation film forming methods, etc.

[0065] The thickness of the sealant film for retort food packaging containers of the present invention is not particularly limited, but from the viewpoint of ensuring practical strength, it is usually 20 μm or more, preferably 30 μm or more, and more preferably 40 μm or more. On the other hand, from the viewpoint of having practical flexibility even after being laminated with a base layer (D), for example, it is usually 200 μm or less, preferably 170 μm or less, and more preferably 150 μm or less.

[0066] The sealant film for retort food packaging containers of the present invention may be a stretched film or an unstretched film, but an unstretched film is preferred from the viewpoint of ease of manufacture and flexibility. On the other hand, from the viewpoint of improving mechanical properties, it is preferable that the film be stretched, and particularly preferable that it be a biaxially oriented film. Biaxial stretching can be performed using methods such as sequential biaxial stretching, simultaneous biaxial stretching, or multi-stage stretching, as appropriate. As for the conditions for biaxial stretching, known manufacturing conditions for biaxially oriented films include, for example, in the sequential biaxial stretching method, the longitudinal stretching temperature is in the range of 100°C to 145°C, the stretching ratio is in the range of 4 to 7 times, the transverse stretching temperature is in the range of 150 to 190°C, and the stretching ratio is in the range of 8 to 11 times.

[0067] The sealant film for retort food packaging containers of the present invention has a predetermined thermal melting rate for each of its (A) seal layer, (B) core layer, and (C) laminate layer, thereby achieving a wide processing temperature range and impact resistance at low temperatures at a high level that surpasses the limitations of conventional technology. Here, the processing temperature range refers to the range of retort temperatures in which, after forming the packaging container so that the sealing layers (A) are in contact with each other and performing retort processing at a predetermined retort temperature, the packaging container can be easily opened without significant deformation.

[0068] The processable temperature range of a sealant film for retort food packaging containers can be evaluated by forming a packaging container using the sealant film so that the seal layers (A) are in contact with each other, performing a retort process at a predetermined number of retort temperatures, and then determining the presence and degree of fusion between the seal layers (A). More specifically, it can be evaluated by, for example, the method described in the embodiment of this application. When evaluated by the method described in the embodiments of this application, it is preferable that a packaging container formed using the sealant film for retort food packaging containers of the present invention effectively prevents fusion, such as by not fusion occurring or by very slight fusion that can be easily peeled off when retorted at at least 115°C to 117°C for 45 minutes, i.e., has a processable temperature range of 115 to 117°C. In this case, the processable temperature range is more preferably 115 to 120°C, and even more preferably 115 to 121°C. In the present invention, the processable temperature range can be further expanded by further optimizing the resin composition. For example, the processable temperature range can be further expanded by setting a higher density for each layer, particularly the density of the sealing layer (A), or by setting a lower melting rate.

[0069] Here, impact resistance at low temperatures can be evaluated by the drop-and-break resistance, more specifically by forming a bag-shaped packaging container filled with water using a sealant film for retort food packaging containers, cooling it to 5°C, and then repeatedly dropping it from a predetermined height until it breaks, and more specifically by the method described in the embodiment of this application. When evaluated by the method described in the embodiments of this application, a packaging container formed using the sealant film for retort food packaging containers of the present invention typically requires 15 or more drops, preferably 20 or more drops, and more preferably 25 or more drops to break. In this invention, impact resistance at low temperatures can be further improved by further optimizing the resin composition. For example, impact resistance at low temperatures can be further improved by setting the density of each layer to a lower level.

[0070] Base material layer (D) If desired, the sealant film for retort food packaging containers of the present invention can be laminated with a base layer (D) in its laminate layer (C).

[0071] There are no particular restrictions on the base layer (D), but a film with excellent heat resistance and gas barrier properties, commonly used for retort food packaging containers, can be suitably used. Preferred materials for the base layer (D) include, for example, plastic films made from thermoplastic resins such as polyamides like nylon 6, nylon 66, para- or metaxylylene adipamide; polyolefins such as crystalline polypropylene, crystalline propylene-ethylene copolymer, crystalline polybutene-1, crystalline poly-methylpentene-1, low-, medium-, or high-density polyethylene, ethylene-vinyl acetate copolymer (EVA), ethylene-ethyl acrylate copolymer (EEA), and ion-crosslinked olefin copolymer (ionomer); aromatic vinyl copolymers such as polystyrene and styrene-butadiene copolymer; halogenated vinyl polymers such as polyvinyl chloride and vinylidene chloride resin; nitrile polymers such as acrylonitrile-styrene copolymer and acrylonitrile-styrene-butadiene copolymer; polyesters such as polyethylene terephthalate (PET) and polytetramethylene terephthalate; various polycarbonates; and polyacetals such as polyoxymethylene. Furthermore, if the contents to be packaged are sensitive to oxygen, the above-mentioned film may be provided with a film coated with metal, metal oxide, etc., or a film coated with an organic compound, or a layer made of ethylene vinyl alcohol copolymer (EVOH) resin. Plastic films made from these materials may be used in an unstretched state, or they may be used after being uniaxially stretched or biaxially stretched.

[0072] These plastic films can be used as a base layer (D) in a single layer or as a laminate of two or more types. Alternatively, one or more of these plastic films can be laminated with metal foil such as aluminum, paper, cellophane, etc. Preferred base layer (D) includes, for example, a single-layer film made of stretched nylon film or stretched polyester film, a two-layer film made by laminating a polyolefin film such as low-density polyethylene or polypropylene with PET, and a three-layer film made by laminating PET / nylon / polyethylene. When manufacturing these laminated films, adhesives and anchoring agents may be interposed between each layer as needed. An ink layer for expressing the design may also be provided.

[0073] There are no particular restrictions on the method of laminating the base layer (D) onto the laminate layer (C), but for example, the base layer (D) can be directly laminated onto the laminate layer (C) by extrusion lamination or the like. Alternatively, the base layer (D) can be laminated onto the laminate layer (C) via an adhesive layer by dry lamination or the like. As the adhesive, ordinary adhesives such as urethane adhesives, acid-modified polyolefin adhesives, polyester adhesives, polyether adhesives, and polyamide adhesives can be used. The thickness of the substrate layer (D) can be set arbitrarily, but is usually selected from the range of 5 to 1000 μm, preferably 9 to 100 μm.

[0074] The sealant film for retort food packaging containers of the present invention, and the laminated film obtained by laminating a base layer (D) onto a laminate layer (C) of the sealant film for retort food packaging containers of the present invention, are suitable films for constituting all or part of a retort food packaging container. There are no particular restrictions on the shape of the retort food packaging container, but suitable examples include bag-shaped packaging containers and packaging containers consisting of a lid and a cup or similar body. When using the sealant film for retort food packaging containers of the present invention in a retort food packaging container, for example, the sealant film for retort food packaging containers itself or a laminated film obtained by laminating it with a base layer (D) may be folded and sealed on three sides, or two sheets of sealant film for retort food packaging containers or the laminated film may be sealed on all four sides to form a bag-shaped packaging container. Alternatively, the sealant film for retort food packaging containers or a lid material made by laminating it with a base layer (D) may be heat-sealed to a container body such as a cup to form a packaging container. A suitable example of such a packaging container is one comprising the lid material and a container body containing at least one of polypropylene, polyethylene terephthalate, and polybutylene terephthalate.

[0075] The sealant film for retort food packaging containers of the present invention, or a lid material laminated thereto with a base layer (D), can form a heat seal by heat-sealing it to various container bodies at the seal layer (A). Examples of materials for such container bodies include propylene polymers, polystyrene, polyester, polycarbonate, and polyvinyl chloride. These container bodies can be in various shapes, such as films, sheets, trays, cups, and bottles.

[0076] There are no particular restrictions on the types of food that can be stored in the retort food packaging containers; various foods that have traditionally been offered as retort foods can be stored in them. The sealant film for retort food packaging containers of the present invention possesses a wide processing temperature range and impact resistance at low temperatures at a high level that surpasses the limitations of conventional technology. Therefore, retort food packaging containers using this film offer greater flexibility in the retort processing process and the types of food that can be stored. For example, it can be suitably used for heat and pressure sterilization processing at 100 to 135°C, preferably 121°C or lower. Furthermore, by utilizing its impact resistance at low temperatures, it can be suitably used in low-temperature storage and distribution (frozen to chilled). [Examples]

[0077] The present invention will be described in detail below with reference to examples and comparative examples. However, the present invention is not limited in any way to the following examples.

[0078] The physical properties and characteristics of the examples / comparative examples were evaluated by the following methods. (1) Processing temperature range Laminated films were prepared by laminating the sealant film laminate layer (C) of each example / comparative example onto a base material (15 μm thick nylon film). Two of the laminated films described above were placed with their sealing layer (A) sides overlapped, and the three sides were heat-sealed to create a three-sided bag. After degassing the three-sided bag so that the insides were in contact, the remaining side of the bag was heat-sealed, and then it was retorted for 45 minutes at a predetermined temperature selected within the range of 115°C to 121°C. The presence and degree of fusion inside the three-sided seal bag was evaluated by sensory testing based on the following criteria. A score of 4 or higher was judged as passing (〇), and the temperature range in which passing (〇) was achieved was defined as the processing temperature range. 5: No fusion 4: Very light fusion allows for easy removal. 3: Partially fused, but detachable. 2: The entire structure is fused together and difficult to separate. 1: Fusion occurs to a level that makes separation impossible.

[0079] (2) Low temperature impact resistance (dropping and rupturing of the bag) Laminated films were prepared by laminating the sealant film laminate layer (C) of each example / comparative example onto a base material (15 μm thick nylon film). Two of the laminated films described above were placed with their sealing layer (A) sides overlapped, and the three sides were heat-sealed to create a three-sided bag. 300 ml of water was filled into the three-sided bag described above, and the remaining side was heat-sealed to form a sealed bag, which was then retorted at 121°C. Next, the bags were stored in a 5°C refrigerator for 24 hours, and then repeatedly dropped in the 5°C refrigerator until they burst. The number of drops until the bag burst was recorded. A 1.0 kg weight was placed on top of the bag, and it was dropped from a height of 60 cm along with the weight. The sample size N was set to 10, and the average number of drops when the bag broke was used as the evaluation value for the example / comparative example.

[0080] (3) Melting point The melting point was measured using a differential scanning calorimeter (DSC) (TA Instruments, "Q200", software: "TA Universal Analysis") at a heating rate of 10°C / min.

[0081] (4) Melting rate at 121°C The heat of fusion (J / g) was measured using a differential scanning calorimeter (DSC) (TA Instruments, "Q200", software: "TA Universal Analysis") at a heating rate of 10°C / min, and this heat of fusion was defined as the heat of fusion specific to the raw material. The ratio obtained by dividing the heat of fusion from the melting start temperature to 121°C by the heat of fusion specific to the raw material was defined as the melting rate at 121°C [%].

[0082] Details of each component of the resins used in the examples / comparative examples are as follows. ·LLDPE-1 Metallocene LLDPE (linear low-density polyethylene) Composition: Ethylene-C6 copolymer Melting point: 130℃ Density: 937kg / m 3 Melting rate (121℃): 50% by mass MFR (2.16kg, 190℃): 1.8g / 10min ·LLDPE-2 Metallocene LLDPE (linear low-density polyethylene) Composition: Ethylene-C6 copolymer Melting point: 129℃ Density: 938kg / m 3 Melting rate (121℃): 39% by mass MFR (2.16kg, 190℃): 3.8g / 10min LLDPE-3 Non-metallocene LLDPE (linear low-density polyethylene) Composition: Ethylene-α-olefin copolymer Melting point: 127℃ Density: 941kg / m 3 Melting rate (121℃): 28% by mass MFR (2.16kg, 190℃): 4.0g / 10min ·LLDPE-4 Metallocene LLDPE (linear low-density polyethylene) Composition: Ethylene-C6 copolymer Melting point: 94℃ Density: 904kg / m 3 Melting rate (121℃): 98% by mass MFR (2.16kg, 190℃): 1.2g / 10min LLDPE-5 Metallocene LLDPE (linear low-density polyethylene) Composition: Ethylene-α-olefin copolymer Melting point: 130℃ Density: 946kg / m 3 Melting rate (121℃): 9% by mass MFR (2.16kg, 190℃): 2.8g / 10min • HDPE-1 HDPE (High-Density Polyethylene) Composition: Ethylene copolymer Melting point: 131℃ Density: 949kg / m 3 Melting rate (121℃): 22% by mass MFR (2.16kg, 190℃): 1.1g / 10min • Antiblocking agent masterbatch (Product name: EAZ-30, manufactured by Prime Polymer Co., Ltd.) A composition containing 30% by mass of synthetic zeolite as an antiblocking agent and 70% by mass of low-density polyethylene as a base resin. • Slippery agent masterbatch (Product name: ESQ-4, manufactured by Prime Polymer Co., Ltd.) A composition containing 4% by mass of erucic acid amide as a slipping agent and 96% by mass of low-density polyethylene as a base resin.

[0083] (Example 1) Each layer of resin listed in Table 1 was supplied to a separate extruder, and a sealant film for retort food packaging containers was formed by the T-die method. This film consisted of a three-layer co-extruded film with a total thickness of 50 μm, comprising a seal layer (A), a core layer (B), and a laminate layer (C), with a thickness ratio of 15:65:20. In addition to the resins for each layer listed in Table 1, 6% by mass of antiblocking agent masterbatch and 1.5% by mass of slipping agent masterbatch were added to the seal layer (A), and 1% by mass of antiblocking agent masterbatch was added to the laminate layer (C). The obtained sealant films for retort food packaging containers were evaluated according to the method described above for their processable temperature range, low-temperature impact resistance (dropping and rupture of the bag), and impact strength. The results are shown in Table 1.

[0084] (Examples 2 to 5, and Comparative Examples 1 to 2) Except for changing the resin of each layer as shown in Table 1, sealant films for retort food packaging containers were prepared and evaluated in the same manner as in Example 1. The results are shown in Table 1.

[0085] [Table 1] [Industrial applicability]

[0086] The sealant film for retort food packaging containers of the present invention combines a wide processing temperature range and impact resistance at low temperatures at a high level that surpasses the limitations of conventional technology. Therefore, it can provide retort food packaging containers that can be suitably used not only for room temperature storage but also for low-temperature distribution (frozen to chilled), and thus has high applicability in various fields of industry such as food processing, distribution, food service, tourism, and healthcare.

Claims

1. A sealant film for retort food packaging containers having (A) a seal layer, (B) a core layer, and (C) a laminate layer, each containing linear polyethylene, (B) The thermal melting rate of the core layer at 121°C, and (C) the thermal melting rate of the laminate layer at 121°C, are each 39 to 50% by mass. (A) The thermal melting rate of the seal layer at 121°C is 5 to 35% by mass. (B) The core layer and (C) the laminate layer are both composed of linear polyethylene polymerized using a metallocene catalyst. Sealant film for retort food packaging containers.

2. A film for retort food packaging containers, comprising a sealant film for retort food packaging containers and a base film as described in claim 1, wherein the base film is laminated with the sealant film for retort food packaging containers in a (C) laminate layer.

3. A retort food packaging container comprising the film for retort food packaging containers described in claim 2.

Images