Method and apparatus for heating and self-heating batteries at low temperatures

Abstract

A heating circuit for an energy storage device having an internal surface capacitance between the inputs that stores electric field energy between internal electrodes coupled to the inputs, one of the internal electrodes coupled to one of the inputs having the characteristics of a resistor and an inductor coupled in series with a voltage source, the heating circuit including: a power supply coupleable to one of the inputs, the power supply providing a positive input current and a negative input current at the inputs, the positive input current flowing into one of the inputs and the negative input current flowing out of one of the inputs; and a controller for controlling the power supply, the controller providing an alternating current at one of the inputs between the positive and negative input currents at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device, generating heat and increasing the temperature of the electrolyte.

Description

Detailed description of the invention

[0001] [Cross-reference of related applications] This application claims priority under U.S. Provisional Patent Application No. 63 / 078,251, filed on 14 September 2020, the entire contents of which are incorporated herein by reference.

[0002] [background] [1. Field] The present invention generally relates to energy storage devices such as supercapacitors and lithium-ion batteries for rapid charging and operation at extremely low temperatures and high rates, and more specifically to methods and apparatus for rapid charging of energy storage devices such as supercapacitors and lithium-ion batteries, and to supercapacitors and lithium-ion batteries designed to be charged at high rates and, in addition, designed for high discharge rate operation at extremely low temperatures. In this specification, extremely low temperature means a temperature at which the electrolyte inside such an energy storage device is at least prevented from charging, for example, the temperature at which the electrolyte becomes nearly solid in the supercapacitor, usually around -45 degrees Celsius, but as low as -54 degrees Celsius or lower.

[0003] [2. Prior art] Supercapacitors (SCs), sometimes referred to as ultracapacitors and formerly as electric double-layer capacitors (EDLCs), are high-capacity electrochemical capacitors with capacitance values of up to 10,000 farads at 1.2 volts that bridge the gap between electrolytic capacitors and rechargeable batteries (collectively referred to herein as "supercapacitors"). Such supercapacitors typically store 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, receive and deliver charge much more rapidly than batteries, and withstand many more charge and discharge cycles than rechargeable batteries. However, for a given charge, a supercapacitor is approximately 10 times larger than a conventional battery. The construction and properties of many different types of supercapacitors are well known in the art.

[0004] In certain applications such as military hardware, supercapacitors may be required to charge and discharge at extremely low temperatures, sometimes as low as -40°F to -65°F or lower. Similar extremely low charging and operating temperatures can be faced by many commercial applications, such as supercapacitors used in vehicles for direct power supply or for regenerative circuits used during braking. At such extremely low temperatures, the electrolyte of a supercapacitor becomes solid, thereby inhibiting or impeding ion transport within the electrolyte. As a result, the charging and discharging rates of the supercapacitor are greatly diminished. As a result, the user may risk non-chargeability, or, if the temperature level is not so low and the supercapacitor is not sufficiently thermally insulated, the user may have to wait a relatively long time to charge the supercapacitor. It is recognized by those skilled in the art that this applies to all currently available supercapacitors.

[0005] Similarly, charging methods and devices for currently available rechargeable batteries, such as lithium-ion batteries, cannot be used for charging these batteries at low temperatures. Although applicable to any rechargeable battery having an electrolyte inside, a lithium-ion battery is referred to as an example below. However, such low temperatures for lithium-ion batteries can be even higher than the temperatures discussed above for supercapacitors, for example, around zero degrees Celsius, and still prevent charging, damage the battery, and even pose a fire hazard, because the components of lithium-ion batteries are very sensitive to temperature. At low temperatures, the "viscous" resistance of the electrolyte to the movement of lithium ions increases. This increase in resistance results in higher losses during the charging and discharging of lithium-ion batteries. Charging at low temperatures is known to pass a (relatively high) current through the components representing the electrochemical reaction of the battery, resulting in so-called lithium plating, which is essentially irreversible and interferes with battery charging and permanently damages the battery.

[0006] [Summary] Therefore, in military products such as military supplies where the charging rate is important to achieve the required system performance, and in commercial products such as electric vehicles and hybrid vehicles, vehicle regeneration circuit elements, and power tools, it is highly desirable to have methods and devices for rapid charging of energy storage devices available for storing electrical energy, such as supercapacitors and lithium-ion batteries.

[0007] It is also highly desirable to have energy storage devices, such as supercapacitors and lithium-ion batteries, that have the ability to charge and discharge at a significantly faster rate at the aforementioned extremely low temperatures.

[0008] Furthermore, it is highly desirable that energy storage devices such as supercapacitors and lithium-ion batteries can be easily implemented in almost any currently available design, minimizing the amount of changes and modifications that must be made to current manufacturing processes to produce them.

[0009] Therefore, there is a need for the development of methods and apparatus for rapidly charging and discharging energy storage devices of different types and designs, such as supercapacitors and lithium-ion batteries, at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or even lower.

[0010] Furthermore, there is a need for methods to design and build energy storage devices, such as supercapacitors and lithium-ion batteries, that can charge and discharge significantly faster than is currently possible at extremely low temperatures.

[0011] Such methods and apparatus for rapidly charging and discharging currently available energy storage devices, such as supercapacitors and lithium-ion batteries of different types and designs, at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or sometimes even lower, will enable military equipment, vehicles, or other devices to be charged and / or discharged significantly more rapidly and to be ready for operation. In commercial applications, such as vehicles, where supercapacitors and / or lithium-ion batteries are used, such methods and apparatus for rapidly charging them at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or sometimes even lower, will enable the operation of vehicles, etc., at such extremely low temperatures.

[0012] Such methods for designing and constructing energy storage devices, such as supercapacitors and lithium-ion batteries, that can charge and discharge significantly faster than possible, enable military equipment and / or vehicles using them to be charged and ready for operation significantly faster, sometimes at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or sometimes even lower.

[0013] This specification describes novel methods and apparatus for rapidly charging and discharging currently available energy storage devices, such as supercapacitors and lithium-ion batteries, of various types and designs, at extremely low temperatures, sometimes between -65 and -45 degrees Fahrenheit, or sometimes even lower.

[0014] Furthermore, this specification also describes novel methods and apparatus for designing and constructing energy storage devices, such as supercapacitors and lithium-ion batteries, that are designed to be able to charge and discharge very rapidly at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or sometimes even lower.

[0015] In addition, this specification also describes methods and apparatus for rapidly charging and / or discharging energy storage devices such as supercapacitors and lithium-ion batteries, which are designed to be charged and discharged very rapidly at extremely low temperatures, sometimes as low as -65 to -45 degrees Fahrenheit, or sometimes even lower.

[0016] Although the novel methods and apparatus are described for extremely low temperatures as low as -65 degrees Celsius, such methods and apparatus are applicable to all low-temperature environments, including temperatures slightly below 0 degrees Celsius, to provide enhanced charging and discharging performance.

[0017] Therefore, a method is provided for heating an energy storage device having a core having an electrolyte. The method includes: providing an energy storage device having an input, the characteristics of the capacitances at both ends of the electrolyte and the core, and the characteristics of the internal surface capacitance between the inputs, which can store electric field energy between the internal electrodes of the energy storage device coupled to the input; switching an input voltage provided at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device to one of the inputs and a ground input to generate heat and raise the temperature of the electrolyte; and ceasing the switching when the temperature of the electrolyte exceeds a predetermined temperature that is considered sufficient to increase the charging efficiency of the energy storage device.

[0018] The method may include providing an input voltage via a first switch and providing a ground input via a second switch, wherein the switching includes simultaneously coupling the input voltage to one input through the operation of the first switch and disconnecting the ground input from one input through the operation of the second switch during a first time interval, and then simultaneously disconnecting the input voltage from one input through the operation of the first switch and coupling the ground input to one input through the operation of the second switch during a second time interval, wherein the first and second intervals are subsequently repeated at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device. The first switch may be a normally closed switch that couples the input voltage to one input when the first switching voltage is below a first predetermined voltage, and / or the second switch may be a normally open switch that disconnects the ground voltage from one input when the second switching voltage is below a second predetermined voltage. Providing a ground input may involve coupling one input to circuit ground via a second switch and a sink resistor. This method may involve selecting the input voltage and the resistance of the sink resistor such that substantially the same charge of the energy storage device occurs during the first time interval as discharge from the energy storage device occurs during the second time interval.

[0019] The predetermined temperature may be a first predetermined temperature, where the method may include initiating switching when the electrolyte temperature falls below a second predetermined temperature, which is lower than the first predetermined temperature, and which is considered to at least reduce the charging efficiency of the energy storage device.

[0020] This method may include obtaining at least one measured and approximate value of the electrolyte temperature. Obtaining this may include directly measuring the electrolyte temperature using temperature sensors placed on one or more of the electrolyte and surfaces of the energy storage device. Obtaining this may include applying an initial charge input to the energy storage device, measuring the charge rate using the initial charge input, and identifying the charge rate at the initial charge input, and if it is determined that the charge rate is below a predetermined charge rate, the electrolyte temperature is estimated to be below the predetermined temperature.

[0021] This method may include providing a controller for controlling the switching and discontinuation of the switching. The method may include the controller obtaining at least one measured and approximate value of the electrolyte temperature. Obtaining the temperature may include directly measuring the electrolyte temperature using a temperature sensor coupled to the controller and located on one or more of the electrolyte and surfaces of the energy storage device. The acquisition may be performed periodically.

[0022] This method may involve generating the input voltage from an AC source provided via an AC-DC converter.

[0023] This method may include: obtaining the energy storage type for an energy storage device; and retrieving a predetermined temperature corresponding to the obtained energy storage type from a lookup table, where the lookup table correlates different energy storage types to their corresponding predetermined temperatures.

[0024] This method may involve charging an energy storage device by coupling an input voltage to one input while the electrolyte temperature is above a predetermined temperature.

[0025] The energy storage device may be a lithium-ion battery or a supercapacitor.

[0026] Also provided is a method for charging an energy storage device having a core having an electrolyte. This method includes: providing an energy storage device having an input, the capacitance characteristics of the electrolyte and the core, and the internal surface capacitance characteristics between the inputs, which can store electric field energy between the internal electrodes of the energy storage device coupled to the input; switching an input voltage provided to one of the inputs at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device and a ground input to generate heat and raise the temperature of the electrolyte; periodically acquiring measurements correlated with the temperature of the electrolyte, wherein the switching is initiated when the measurements indicate that the temperature of the electrolyte is below a low temperature threshold that is considered to at least reduce the charging efficiency of the energy storage device, and the switching is stopped when the measurements indicate that the temperature of the electrolyte is above a high temperature threshold that is considered sufficient to increase the charging efficiency of the energy storage device, and periodically acquiring measurements correlated with the temperature of the electrolyte, where the low temperature threshold is a temperature lower than the high temperature threshold; and charging the energy storage device by providing an input voltage to one of the inputs while the measurements indicate that the temperature of the electrolyte is above a high temperature threshold.

[0027] By applying a high-frequency current that directly heats the battery core, primarily the electrolyte, it becomes possible to use almost all currently available battery types, as well as supercapacitors, at temperatures as low as -60 degrees Celsius and even lower. The high-frequency current flowing through the battery causes corresponding high-frequency vibrations of ions in the electrolyte, which generates heat and thereby raises the temperature of the electrolyte and battery core. Typically, the applied current frequency can range from several hundred Hz to several MHz, depending on the type and chemical properties of the battery. To prevent any damage to the battery and supercapacitor, it is essential that the high-frequency current passed through the battery and supercapacitor is symmetrical, that is, it has no net DC component or its net DC component is negligibly small.

[0028] Therefore, methods and examples of such circuit implementations used to construct the aforementioned direct battery and supercapacitor heating devices for low temperatures, which pass a desired high-frequency current through a battery or supercapacitor while automatically maintaining the symmetry of the high-frequency current, in a state where the DC component is absent or negligibly small.

[0029] Furthermore, it is highly desirable to have a simple and highly efficient device that can be used to maintain batteries and supercapacitors at a temperature below which they can operate at their peak performance level when the ambient temperature falls below that temperature. For example, in extremely cold environments, a vehicle's battery may initially be heated by externally supplied power so that it can be charged or the vehicle can become operational. However, once the vehicle starts moving, external power is no longer available, and the battery may cool down below its maximum operating performance level, potentially becoming almost inoperable. Under such conditions, it is highly desirable to have a highly efficient device that can self-heat the vehicle battery as needed using its own power so that it can be kept operational at or near its peak performance level. It is also recognized that vehicles such as trucks, passenger cars, tractors, snowplows, and jet snowplow trucks are routinely parked outdoors for a certain period of time or even overnight, especially during winter when temperatures are extremely low. In such cases, external power is usually unavailable, and if the battery is very cold, it may not be able to supply enough power after being parked for several hours or overnight, making it impossible to start the engine. In such situations, the driver has two options: keep the engine running while parked, at the cost of wasting a considerable amount of fuel and causing unnecessary environmental pollution; or use a heating blanket to cover the battery and power the heating blanket with battery power. The former is not only costly but also environmentally problematic, and idling the engine is prohibited in many countries. The latter solution is very inefficient, as most of the heat generated is released into the environment, and therefore can only be used for a relatively short time, and can never heat the battery overnight. It is recognized that large lead-acid batteries are used in heavy machinery such as trucks, but when cooled below -10°C, they can only supply a fraction of their full ambient-temperature power. For this reason, if such heavy machinery needs to operate at temperatures that can reach -20°C to -30°C, or even lower, it may be necessary to install more batteries to supply sufficient power for starting the engine all at once. Therefore, it is highly desirable that such vehicles be equipped with a means to efficiently maintain the vehicle batteries above a certain temperature that can provide sufficient power to start the vehicle engine, after prolonged parking such as overnight parking, while minimizing the use of battery power. Such a battery self-heating method and apparatus is highly desirable because it can operate while the vehicle engine is running, ensuring that the battery temperature does not fall below a predetermined threshold and that the battery remains at or near its peak performance level.

[0030] Those skilled in the art will recognize that many other systems, too, can use such self-heating capabilities to keep themselves operational at low temperatures.

[0031] Therefore, we describe methods and examples of circuit implementations used to construct highly efficient and simple self-heating devices for batteries and supercapacitors. [Brief explanation of the drawing]

[0032] These and other features, aspects, and advantages of the apparatus of the present invention will be better understood with respect to the following description, accompanying claims, and accompanying drawings.

[0033] [Figure 1] This is a simplified schematic diagram of a supercapacitor, in which the supercapacitor is shown together with a condensed core, the condensed core having an equivalent condensed internal resistance element and an equivalent condensed internal inductance element. [Figure 2] A schematic diagram illustrating one embodiment of a supercapacitor rapid charging system for charging at extremely low temperatures and a supercapacitor to be charged at extremely low temperatures is shown. [Figure 3] This flowchart illustrates one embodiment of a method for charging a supercapacitor at extremely low temperatures. [Figure 4] This flowchart illustrates one embodiment of a method for charging a supercapacitor at extremely low temperatures. [Figure 5] This flowchart illustrates one embodiment of a method for charging a supercapacitor at extremely low temperatures. [Figure 6] This flowchart illustrates one embodiment of a method for charging a supercapacitor at extremely low temperatures. [Figure 7] This flowchart illustrates one embodiment of a method for charging a supercapacitor at extremely low temperatures. [Figure 8] This illustrates one embodiment of a supercapacitor that should be charged at extremely low temperatures. [Figure 9] A schematic diagram of a supercapacitor charging unit is shown as an example. [Figure 10] The circuit diagram for a 2-30MHz RF power amplifier is shown as an example. [Figure 11] This illustrates the equivalent circuit elements of a lithium-ion battery. [Figure 12] This diagram illustrates a block diagram of a structure for charging / discharging lithium-ion batteries at low temperatures. [Figure 13] This diagram illustrates the main components of one embodiment of a processor-controlled lithium-ion battery charging and discharging unit at low temperatures. [Figure 14] Figure 13 illustrates a block diagram of an alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for low temperatures, intended for use only as a lithium-ion battery charging unit for all temperatures, including low temperatures. [Figure 15] Figure 13 illustrates a block diagram of an alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for lower temperatures and for maintaining the battery core temperature during the charging and discharging process. [Figure 16] Figure 15 illustrates a block diagram of an alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for low temperatures, intended for use only as a lithium-ion battery charging unit for all temperatures, including low temperatures. [Figure 17] Figure 15 illustrates a block diagram of another alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for low temperatures, used to maintain the core temperature of the lithium-ion battery above a predetermined temperature for efficient discharge at all temperatures, including low temperatures. [Figure 18] Figure 17 illustrates a block diagram of an alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for low temperatures, used to maintain the core temperature of the lithium-ion battery above a predetermined temperature for efficient discharge at all temperatures, including low temperatures. [Figure 19]Figure 18 illustrates a block diagram of an alternative embodiment of a processor-controlled lithium-ion battery charging and discharging unit for low temperatures, used to maintain the core temperature of the lithium-ion battery above a predetermined temperature for efficient discharge at all temperatures, including low temperatures. [Figure 20] This flowchart illustrates how to charge a lithium-ion battery at low temperatures by maintaining the core temperature of the lithium-ion battery above a predetermined temperature for efficient charging at all temperatures, including low temperatures. [Figure 21] This flowchart illustrates how to discharge a lithium-ion battery at low temperatures by maintaining the core temperature of the lithium-ion battery above a predetermined temperature for efficient discharge at all temperatures, including low temperatures. [Figure 22] A circuit diagram illustrating one embodiment of a heating circuit for a battery or energy storage device is shown. [Figure 23] This is a schematic model of a supercapacitor with additional details compared to the model in Figure 1. [Figure 24] Figure 22 illustrates the implementation of the battery heating circuit embodiment. [Figure 25] Figure 22 illustrates a circuit diagram of an embodiment of a battery heating circuit, which includes a battery temperature sensor and a controller that activates the battery heating circuit when a predetermined low temperature threshold is detected. [Figure 26] Figure 25 illustrates an alternative circuit diagram for the embodiment of the battery heating circuit. [Figure 27] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 28] Figure 27 illustrates a circuit diagram of an embodiment of a battery heating circuit, which includes a battery temperature sensor and a controller that activates the battery heating circuit when a predetermined low temperature threshold is detected. [Figure 29] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 30]Figure 29 illustrates a circuit diagram of an embodiment of a battery heating circuit, which includes a battery temperature sensor and a controller that activates the battery heating circuit when a predetermined low temperature threshold is detected. [Figure 31] Figure 27 illustrates the heating of a Li-ion battery using the heating circuit of the embodiment, as a function of time, at temperatures ranging from -30 degrees Celsius to 20 degrees Celsius. [Figure 32] This example shows a plot of the internal resistance of a standard 18650 Li-ion cell (battery part number LGABB418650) in a temperature range of -55°C to 45°C. [Figure 33] This example shows a plot of the internal inductance of a standard 18650 cell Li-ion battery (battery part number LGABB418650) in a temperature range of -55°C to 45°C. [Figure 34] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 35] Figure 34 illustrates a circuit diagram of an embodiment modified to provide a sinusoidal high-frequency heating AC voltage. [Figure 36] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 37] Figure 36 illustrates a circuit diagram of an embodiment modified to provide a sinusoidal high-frequency heating AC voltage. [Figure 38] An alternative, modified circuit diagram of the embodiment shown in Figure 37 is illustrated. [Figure 39] For several battery types, the plot of available battery current at the rated voltage is shown as a function of temperature. [Figure 40] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 41] Figure 40 illustrates a modified circuit diagram of the battery heating circuit embodiment. [Figure 42] A circuit diagram illustrating another embodiment of the battery heating circuit is shown. [Figure 43] Figure 42 illustrates a modified circuit diagram of the battery heating circuit embodiment. [Figure 44] A block diagram illustrating another embodiment of the battery heating device is shown. [Figure 45] The block diagram of the embodiment of the battery heating device shown in Figure 44 illustrates the operation of the "heating engine". [Figure 46] Typical switching waveforms and battery current waveforms used in the embodiment of the battery heating device shown in Figure 44 are illustrated. [Figure 47] This illustrates one possible implementation of a hardware shutdown circuit for the embodiment of the battery heating device shown in Figure 44. [Figure 48] This shows an example of the current waveform during one heating cycle in the embodiment of the battery heating device shown in Figure 44. [Figure 49] This illustrates the actual measured current response during heating of a 12V Type 31 lead-acid battery, commonly used in trucks. [Figure 50] This diagram illustrates a basic circuit diagram of a first embodiment of the high-efficiency self-heating device of the present invention. [Figure 51] A block diagram illustrating an embodiment of the first high-efficiency self-heating device of the present invention is shown. [Figure 52] Figure 50 illustrates a circuit diagram of a first embodiment of the high-efficiency self-heating device of the present invention. [Figure 53] Figure 52 illustrates an example plot of battery temperature and ambient temperature during self-heating of a battery using the embodiment of the self-heating device shown. [Figure 54] Figure 52 illustrates a circuit diagram of an embodiment of a high-efficiency self-heating device, which includes an additional heating resistor to improve the overall heating efficiency of the self-heating system. [Figure 55] A circuit diagram illustrating another embodiment of the high-efficiency self-heating device of the present invention is shown. [Figure 56] Figure 55 illustrates typical current and voltage waveforms in the series resonant circuit of the self-heating circuit during one self-heating cycle. [Figure 57]Figure 55 illustrates a circuit diagram of a more efficient self-heating device embodiment of the present invention, resulting from modifications to the embodiment and its operating process. [Figure 58] Figure 57 illustrates typical current and voltage waveforms in the resonant circuit of the self-heating circuit. [Figure 59] Figure 57 illustrates typical current and voltage waveforms in the resonant circuit of the self-heating circuit, which is generated from the energy stored in the circuit capacitor. [Figure 60] Figure 57 illustrates typical current and voltage waveforms in the resonant circuit of the self-heating circuit for the entire cycle of highly efficient battery heating. [Figure 61] Figures 55 and 57 illustrate the operation flowcharts of the self-heating embodiments that have an automatic circuit parameter adjustment function. [Modes for carrying out the invention]

[0034] [Detailed explanation] All currently available types and designs of supercapacitors exhibit internal resistance and internal inductance, which can be modeled as being in series. Both the internal resistance and internal inductance of supercapacitors are relatively low. The inductance of supercapacitors is significantly higher in the case of wound supercapacitors compared to flat and multilayer types in terms of construction. Leakage current can be represented by a separate resistor in parallel with the capacitor. In general, the resistance of a supercapacitor can be ignored in short-term operation. The inductance of a supercapacitor can also be ignored in low-frequency operation.

[0035] In the schematic diagram of Figure 1, a simplified model of the supercapacitor 20 is shown together with a centrifugal capacitor core 21. Within the centrifugal capacitor core 21, the equivalent internal resistance and equivalent internal inductance are shown as two pairs of series resistors and inductors connected to the supercapacitor capacitance C. In Figure 1, the series resistor and inductor pairs are represented by resistors R1 and R2 and inductances L1 and L2. In most supercapacitors, the resistances of resistors R1 and R2 are extremely low. In this model, the centrifugal series resistor and inductor pairs are connected to the supercapacitor capacitance C at one end and to the supercapacitor terminal 22 at the other end. In Figure 1, the internal resistance of the supercapacitor is the source of leakage and is modeled as a centrifugal resistor R3. In Figure 1, for the sake of simplicity, and because this simplification does not affect the methods and apparatus for charging and discharging the supercapacitor that are to be described, the electrical model of the supercapacitor is considered to be as shown in Figure 1.

[0036] In the first embodiment schematically shown in Figures 2, 3, and 5, a supercapacitor charger unit 11 having an internal processor 11a first acquires the internal temperature of the supercapacitor core in step S1a or S1b. Such a processor may include hardware components such as a PLC or CPU, software, and a memory that stores such software and also stores data such as predetermined values ​​used in the methods described below. In applications such as munitions where the munitions are stored at ambient temperature, the supercapacitor core temperature may be acquired by measuring the ambient temperature in step S1a and estimating the internal temperature of the supercapacitor core using some function of the ambient temperature, such as equating the ambient temperature with the supercapacitor core temperature. Alternatively, the supercapacitor core temperature can be measured directly by an internal sensor 12 (e.g., a thermocouple-based sensor or other temperature measuring sensor known in the art), and the measured temperature signal is provided to the processor 11a via wiring 13 connected to the sensor capacitor terminal 14. Sensor 12 is used by processor 11a to determine whether the supercapacitor is able to charge at its normal rate, or whether the core temperature is so low that the supercapacitor electrolyte is solid or very close to solid, thereby inhibiting or interfering with ion transport within the electrolyte and preventing the supercapacitor from rapidly charging at its normal (liquid electrolyte) rate. As yet another alternative, a temperature sensor may be placed on the external surface of the supercapacitor, and the acquired temperature is used to estimate the internal temperature of the supercapacitor core using some function of the external surface temperature, such as equating the external surface temperature with the supercapacitor core temperature.

[0037] Alternatively, as shown in Figure 5, the supercapacitor core temperature may be obtained, on the assumption that, for example, in step S1b, by applying a normal charging voltage (or any appropriate initial voltage level) to the supercapacitor via the charging unit 11, and in step S2b, if the processor 11a determines that the supercapacitor is not being charged at its normal rate, i.e., for example, that the measured charging current is significantly lower than the known normal charging current rate, then the processor 11a may assume that the supercapacitor core temperature is extremely low and that the supercapacitor core is below the temperature at which it can be charged at its normal (liquid electrolyte) rate.

[0038] In the following, as discussed above, extremely low temperatures are used to indicate the temperature level at which the supercapacitor electrolyte becomes solid or where relatively free transport of its ions cannot be effectively enabled.

[0039] For safety reasons, as will be apparent to those skilled in the art, the processor 11a of the charger unit 11 can also determine the charge level of the supercapacitor before the start of the charge cycle. In addition, the temperature sensor 12 can be used, as previously described, to ensure that the reason for the low charge rate is indeed due to a low supercapacitor core electrolyte temperature level.

[0040] In the schematic diagram of Figure 2, it is shown that the charger unit 11 is powered internally, such as by a battery. However, in many applications, the charger unit 11 can be powered by an external source (not shown). The charger unit 11 functions similarly regardless of its power source.

[0041] Next, once the processor 11a determines in either step S2a or S2b that the supercapacitor core temperature is extremely low and that rapid charging of the supercapacitor (which may also be determined to be not fully charged) is not possible due to the extremely low temperature level, the charger unit 11 can begin charging the supercapacitor in step S5a. In the schematic diagram of Figure 2, the charger unit 11 is shown to be connected to the supercapacitor 20 via wires 15 that connect the terminals 22 of the supercapacitor 20 to the corresponding terminals 16 of the charger unit 11.

[0042] However, if in step S2a or S2b the processor 11a determines that the core temperature of the supercapacitor is not below a predetermined temperature (for example, the core is at a temperature above which normal charging can be performed) (the determination in step S2a or S2b is No), the charger unit charges the supercapacitor in the conventional manner in step S3 and continues this until the supercapacitor is determined to be fully charged in step S4, or until charging is terminated in any other manner.

[0043] On the other hand, if the determination in step S2a or S2b is Yes, the charger unit 11 may input one or more predetermined voltages and currents to the terminals 22 of the supercapacitor, such that one or more voltages and currents generate heat in the internal components of the energy storage device. As a first exemplary input, the charger unit 11 may apply a relatively high frequency voltage to the supercapacitor in step S5a. The high frequency voltage may be approximately the peak voltage of the maximum allowable charging supercapacitor voltage, or a voltage significantly higher than that. Here, high frequency means the frequency at which the capacitors of the supercapacitor effectively short-circuit, generating heat in the inductances L1 and L2 and resistors R1 and R2. Next, the processor 11a may continue to acquire the supercapacitor core temperature periodically, for example, at several predetermined intervals, by any of the methods discussed above (illustrated by line S6 in Figures 3 and 5). The periodic acquisition of the supercapacitor core temperature can be performed, as discussed above, by direct measurement or assumption, for example, by measuring the internal temperature using the temperature sensor 12 in step S1a, or by measuring the charge rate from the charge current by attempting to charge the capacitor at the normal charge voltage in step S1b. Alternatively, two or more methods can be used, such as both methods (S1a and S1b) for measuring the core temperature until the core (supercapacitor electrolyte) temperature reaches a desired level for proper charging of the supercapacitor, or until the nominal charge rate of the supercapacitor is reached. Upon reaching the desired level, the applied high-frequency voltage signal is terminated in steps S2a and / or S2b, and the processor 11a instructs the charging unit 11 to charge the supercapacitor to the desired level in the conventional manner in steps S3 and S4. Temperature level and / or charge rate measurements may be repeated as needed, such as at regular intervals, especially under extremely low ambient temperature conditions, to ensure that the charging process is not interrupted by the "refreezing" of the supercapacitor electrolyte.

[0044] Next, an alternative embodiment will be described using the schematic diagram in Figure 2 and the flowcharts in Figures 4 and 6, which number similarly to those illustrated in Figures 3 and 5, respectively, for similar steps. In the alternative embodiment, once it is determined in step S2a or S2b that the core 12 of the supercapacitor 20 (not fully charged) is at a very low temperature using one or a combination of the techniques described above, the processor 11a instructs the charging unit 11 in step S5b to heat the core 12 by passing a constant current through the equivalent internal resistance R3 via the supercapacitor terminals 22 and the two pairs of series-connected resistors and inductors described above. The current is generated by the charging unit 11 via the wiring 15. Generally, and depending on the type and design of the supercapacitor 20, its charge state and electrolyte temperature, the current may be applied at a voltage significantly higher than the voltage rating of the supercapacitor. This is usually possible because the frozen electrolyte of a capacitor with a low charge level can withstand a significantly higher voltage. When using a heating voltage exceeding the rated voltage of the supercapacitor, the processor 11a can periodically monitor the core temperature and charge state of the supercapacitor in S6 and appropriately reduce the heating voltage as the supercapacitor begins to charge at or near its nominal rate.

[0045] In general, due to the extremely high internal resistance level R3 of most supercapacitors, the method of supplying heat to the supercapacitor core via the equivalent inductances L1 and L2 of the supercapacitor, as illustrated in Figures 3 and 5, may be more effective. Such methods illustrated in Figures 3 and 5 may also be safer, because high-frequency currents may be applied at or above the rated voltage of the supercapacitor. However, as will be recognized by those skilled in the art, since the inductor core in this case is substantially a conductive supercapacitor electrolyte, the amount of heat that can be generated in many supercapacitors may be relatively small.

[0046] In the condensation model shown in Figure 1, the heat (P) generated per second by applying a constant voltage to the supercapacitor terminal is:

number

[0047] As can be seen from the equation above, because the leakage resistance R3 is extremely large, the amount of heat that can be generated per second for a relatively low voltage that can be applied to the supercapacitor (for example, using a rated voltage of 2.7 volts) is extremely small. For example, for a typical 100F supercapacitor with a rated voltage of 2.7V, a series resistance of R1+R2=50mΩ, and a leakage resistance of R3=10kΩ, according to equation (1) above,

number

[0048] In another alternative embodiment, to significantly increase the heat generation rate within the core 21 of a typical supercapacitor 20, such as the one schematically shown in Figure 1, the following method can be used instead of the constant voltage application described herein. In this method, as shown in Figure 7, once the charger unit 11 determines in steps S1c and S2c that the battery is not fully charged and the battery core is at a very low temperature, the charger unit 11 then, in step S5c, sets the peak voltage at high frequency f to V pAn alternating current (AC) is applied to the terminals. The behavior of the lumped circuit elements (consisting of resistors R1, R2, and R3 and inductors L1 and L2, as shown in Figures 1 and 2) is currently quite different from that shown by equation (1) above. At high frequencies f, capacitor C provides an extremely low impedance, effectively short-circuiting the leakage resistor R3 which is in parallel with it. As a result, the total resistance to the applied current is extremely small, because resistors R1 and R2 are extremely small. Consequently, the total heat generated per second is extremely large, and therefore the extremely cold supercapacitor core electrolyte can be heated very quickly to a temperature at which the supercapacitor can be charged at or near its nominal charge rate. It should be noted that at such extremely high frequencies, inductors L1 and L2 also provide high impedance, but in a supercapacitor environment they typically generate significantly less heat than those generated by the low resistances R1 and R2. The heat generated per second (output P) can be roughly calculated using the equation (2) below.

number

[0049] For the aforementioned 100F capacitor, which has a typical total inductance of L1+L2=0.06μH and R1+R2=50mΩ, and a leakage resistance of R3=10Ω, the applied AC voltage at a frequency f=1,000Hz is V p If the voltage is 1V, the heat generated per second can reach 9.3W. It should be noted that the above calculation is an approximation and does not take into account the change in capacitance of the supercapacitor under the applied high-frequency voltage at extremely low temperatures.

[0050] As will be apparent to those skilled in the art, the charger unit 11 requires not only the processor 11a but also any electronic and logic circuit elements to measure the core temperature and provide the indicated current and voltage inputs for safe charging of the supercapacitor, in addition to the described supercapacitor heating process. These techniques are widely used in practice and are considered well known in the art.

[0051] In the embodiments described above, the inductance or internal resistance of the supercapacitor is used by the charging unit described to heat the supercapacitor core (primarily its electrolyte) to a temperature that provides sufficient mobility for the electrolyte ions to rapidly charge the supercapacitor. The supercapacitor consists of series resistance and inductance, and leakage current is represented in Figure 1 by a resistor in parallel with the capacitor. The series resistance (R1 and R2 in Figure 1) ranges from a few milliohms to tens of milliohms. The inductance (L1 and L2 in Figure 1) is structurally dependent and can be ignored for low-frequency operation. The leakage resistance can also be ignored for short-term operation. The electrolyte in the supercapacitor forms a conductive connection between two electrodes, which distinguishes the supercapacitor from an electrolytic capacitor where the electrolyte is the second electrode (cathode). The supercapacitor electrodes are generally a thin coating applied to and electrically connected to a conductive metal current collector. The electrodes must possess good conductivity, high-temperature stability, long-term chemical stability, high corrosion resistance, and a high surface area per unit volume and mass. Other requirements include environmental compatibility and low cost.

[0052] Referring to Figure 8, another embodiment relates to additional resistive and / or inductive elements added to the surface of a supercapacitor electrode, regardless of the type and design of the superconductor and its electrodes, or to dispersing such resistive and / or inductive elements throughout the supercapacitor core. Similarly, such additional resistive and / or inductive elements can also be added to rechargeable batteries such as lithium-ion batteries. These additional resistive and / or inductive elements can be electrically insulated by a dielectric material to prevent interference with the operation of their energy storage devices. The additional resistive elements R4 and / or inductive elements L3 can be dispersed throughout the core and as close as possible to the electrolyte material. Next, as previously described, if the core temperature is determined to be low, current is passed through the added resistors to generate heat and raise the electrolyte temperature, thereby enabling charging at its nominal rate once the core temperature rises above some predetermined temperature or charging capacity. When inductive elements are added, a sufficiently high frequency alternating current can be used to heat the electrolyte, thereby facilitating a rapid charging process at extremely low temperatures. When using such a supercapacitor 20a, an additional terminal 14a can be provided to input the electrical input required for core heating via an independent wiring 13a from the charger unit, or an electronic logic can be provided using only one set of terminals 22 to perform both charging of the supercapacitor 20a and input to an additional inductor L3 and resistor R4 for core heating.

[0053] Figure 9 shows a block diagram of the supercapacitor test unit 100. A function generator 102, such as a 25 MHz arbitrary waveform generator, is provided. A power amplifier 104 is also provided, which can be constructed by modifying an available 2-30 MHz RF power amplifier by matching the supercapacitor impedance with the required output range, as described below. A DC power supply 106 is provided by an adjustment source with limit settings for output voltage and output current. The test load or user device 108 may be a high-power resistor, which is used to measure the available energy stored in the supercapacitor.

[0054] The frequency of the function generator and the voltage amplitude of the power amplifier can be set manually. A host computer 110 equipped with a DAQ and DSP board is a means of controlling the process and can provide means for data acquisition, online analysis, and feedback. A DSP board clock can be used to accommodate rapid input / output operation and sampling time. The provided system allows for continuous measurement of voltage and current across the load, power consumption, and thereby load impedance. A DC power supply 106 is also controllable by the DSP-based controller 110 to achieve a desired charge profile. A test load can be used to measure the amount of energy that a charged supercapacitor can provide after charging. A switch 112, controlled by the DSP controller 110, can be used to connect the supercapacitor 114 to a desired circuit element. A set of voltage sensors 116 and current sensors 118 report their values ​​to the DSP A / D converter via the DAQ. The controller 110 can communicate with the host computer to exchange commands and status of each device. The DSP controller 110 can also generate charging pulses.

[0055] A supercapacitor test unit can be designed to apply a high-frequency sinusoidal AC voltage signal to a supercapacitor load, with or without DC bias. The voltage and frequency of the AC signal can be controlled manually or automatically. The voltage across the load, the current through the supercapacitor load, and their phases are measured. Then, the power applied to the load and the load impedance can be calculated.

[0056] The high-frequency 25MHz function generator 102 can be used as the input to the power amplifier 104. The power amplifier 104 can be constructed by modifying the input and output impedances of an existing RF power amplifier. Figure 10 shows a circuit diagram of an existing 2-30MHz RF power amplifier design. The nominal power output of this device can be 30 watts, which is suitable for charging superconductors.

[0057] Existing host computers are equipped with DAQ and DSP boards for this purpose. The software required to operate the system with proper data communication, acquisition and processing of sensor data, and generation of necessary control signals can be stored in memory (not shown) accessible by the controller 110.

[0058] The charging unit 100 can measure the impedance of the supercapacitor 114 at different AC frequencies, temperatures, and voltages. A function generator 102 can be used to generate a sine wave using an adjustable voltage signal, for example, up to 25 MHz. The power amplifier 104 then generates an AC voltage at a predetermined (pre-set) voltage level and applies it to the supercapacitor. A switch 112, controlled by a pulse generator, applies the AC voltage to the supercapacitor 114 for a predetermined time period, such as an adjustable short duration of 10 to 100 microseconds, depending on the AC voltage frequency. The short duration of input power ensures that the total input energy is negligibly small. The waveforms of the input voltage and input current are then measured and used to calculate the impedance of the supercapacitor.

[0059] Superconductor charging tests can be performed at various temperatures, including -20°C, -25°C, -35°C, -45°C, -48°C, -54°C, and -65°C. These tests can also utilize various AC voltage amplitudes, such as 2.7V, 3.2V, 4.5V, 6V, 8V, and 10V. The AC voltage frequency range can be from 2MHz to 25MHz, and tests can be performed in 0.5MHz increments.

[0060] As previously described, the purpose of applying a high-frequency AC voltage to a supercapacitor is to heat the supercapacitor core, particularly its electrolyte, at a low temperature before charging the supercapacitor with the applied DC voltage.

[0061] The purpose of testing the device is to determine at what point the AC voltage should be stopped and DC charging should be started, in order to build a database for use in the method described above. At extremely low temperatures, approximately -45°C to below 48°C, the electrolyte is almost a frozen solid, and the impedance of the supercapacitor is extremely high. However, as the electrolyte becomes active (melts), the effective capacitance of the supercapacitor rapidly increases, causing a rapid drop in impedance, thereby increasing the level of current flowing through it accordingly. In the test, the AC current level is measured, and after this AC current level has increased by 10, 25, 50, 75, and 100 times, the AC voltage can be switched off and the DC charging voltage can be applied to the supercapacitor. In the test, for example, the supercapacitor can be charged at 3.2V until the charging current drops to 20mA, at which point the supercapacitor is considered fully charged. Next, the available stored energy is measured by discharging the stored energy in the supercapacitor through the test load 108.

[0062] The AC current and voltage profiles, as well as the DC charging time, are recorded. The test can be performed while the supercapacitor is inside the temperature chamber 120. The test can be performed with the capacitor wrapped in a typical insulating jacket, and in an uninsulated state to simulate a mounted supercapacitor, each of the following: within an enclosure that provides a certain level of insulation against heat loss, and outside any enclosure.

[0063] During testing, if the stored energy is less than 95% of the expected available stored energy, the supercapacitor 114 is considered to be damaged.

[0064] Using such tests, the above methods for charging supercapacitors at low temperatures can be optimized to achieve full charge in the shortest possible time, and an overall time-optimized strategy for charging supercapacitors at low temperatures can be formulated.

[0065] The AC voltage and frequency range for preheating the supercapacitor and subsequent DC charging, as well as the expected optimal AC-DC switching timing, can be determined for different lower temperature levels, which can be tested and fine-tuned to obtain the desired time-optimal strategy for implementation.

[0066] Therefore, using the above test devices and methods, statistics can be obtained regarding the time required to fully charge supercapacitors of various sizes and configurations at various low temperatures. The generated statistics may include the average time required to charge the capacitor at a given temperature and its standard deviation at a specific confidence level, such as 95%.

[0067] As will be apparent to those skilled in the art, the disclosed test device and method for charging supercapacitors at low temperatures can be applied to other methods described above (e.g., those shown in Figures 3 to 6), and / or to different types of commonly known supercapacitors, ultracapacitors, and so-called hybrid capacitors, in addition to rechargeable batteries such as lithium-ion batteries.

[0068] Using the methods and devices described above for rapidly charging supercapacitors at low temperatures, it is also possible to similarly enable, and / or significantly increase, the charging rates of lithium-ion batteries and other similar rechargeable batteries at low temperatures. As discussed above, charging at low temperatures is generally a greater problem for lithium-ion batteries and other similar rechargeable batteries because their charging rates are low even at temperatures higher than those of supercapacitors, typically even at temperatures a few degrees below zero degrees Celsius.

[0069] In the case of lithium-ion batteries and other similar rechargeable batteries, the charging process includes similar steps as those previously described for supercapacitors. After it is determined that a lithium-ion battery requires charging and its core is at a low temperature that prevents / minimizes charging, the battery's electrolyte and electrodes are heated in a similar manner to those described with respect to Figures 3 to 7, by applying one or more predetermined voltage and current inputs to the battery's terminals, causing its internal components to generate heat, for example, by applying an AC high-frequency voltage, usually on the order of 1 to 10 MHz, and sometimes higher, depending on the size and structure of the battery. Next, once the battery core, particularly its electrolyte, has reached a desired predetermined temperature or charging capacity, the battery can be charged in a conventional manner using a DC voltage in accordance with well-known electronic and logic circuit elements and procedures for ensuring safe and rapid charging. The arrival of the desired predetermined temperature or charging capacity can be directly detected using a temperature sensor as described above, or, for example, can be assumed by detecting the charging rate using an AC voltage and / or DC voltage, also as described above.

[0070] As will be recognized by those skilled in the art, in many cases of charging lithium-ion batteries and other similar rechargeable batteries (including supercapacitors), the optimal charging time can usually be achieved by overlapping AC voltage and DC voltage charging for a portion of the time before switching from AC voltage to DC voltage.

[0071] The basic operation of a lithium-ion battery can be roughly modeled using the equivalent (centralized) circuit elements shown in Figure 11. In this model, resistor R e This is considered to be the electrical resistance that resists the free movement of electrons within the conductive material in which the electrodes and wiring are fabricated. Equivalent resistor R I This represents the (essentially viscous) resistance of the battery electrolyte to the free movement of lithium ions. Equivalent inductor L Irepresents the resistance to the change in its state of motion (which is "essentially inertial"), and this resistance does not become a problem until the frequency of the required motion becomes extremely high. Capacitor C s is the surface capacitance, which can store electric field energy between the electrodes and acts like the parallel plates of a capacitor. Resistor R c and capacitor C c represent the electrochemical mechanism of the battery, where in the battery, C c is intended to represent the electrical energy that can be stored as chemical energy during battery charging and discharged again as electrical energy during battery discharging, and R c represents an equivalent resistor, in which part of the discharged electrical energy is consumed (lost) and essentially converted to heat. Terminals A and B are intended to represent the terminals of a lithium-ion battery, and terminals C and D are other internal points within the circuit element.

[0072] As will be recognized by those skilled in the art, many different lithium-ion types and designs, as well as different chemical compositions, are currently available. Also as will be recognized by those skilled in the art, other models of lithium-ion batteries have also been developed. However, the model presented in the schematic of FIG. 11 represents the basic components of a lithium-ion battery insofar as it relates to the disclosed methods and apparatus for charging such a battery at low temperatures. Accordingly, the methods and apparatus described herein apply not only to those having the configuration represented by FIG. 11, but also to all different types and designs of lithium-ion batteries having all different design structures and chemical properties. The reasons why currently available methods and devices for charging lithium-ion batteries cannot be used for charging these batteries even at low temperatures near zero degrees Celsius have been briefly described above and are well documented in the prior art, and it has been shown that if used, they can damage the battery and even pose a fire hazard.

[0073] In the approximate equivalent (centralized) circuit element model of the lithium-ion battery shown in Figure 11, the three components of the battery are, namely, R I , R c , and C c However, it is highly sensitive to temperature. At low temperatures, the resistor R I The resistance increases due to the increased "viscous" resistance of the electrolyte to the movement of lithium ions. This increase in resistance results in higher losses during the charging and discharging of lithium-ion batteries. Charging at low temperatures represents the electrochemical reaction of the battery, as indicated by component R. c and C c It is well known that passing a (relatively high) current through it results in so-called lithium plating, which is essentially irreversible, interferes with battery charging, and permanently damages the battery.

[0074] One embodiment of a method for charging a lithium-ion battery at low temperatures can be described as follows. Consider the circuit model shown in Figure 11. When an AC current with a sufficiently high frequency is applied to the battery, capacitor C s Due to the low impedance, there is no significant voltage drop across the capacitor, that is, between the junction C and D, and the circuit is such that capacitor C s It behaves effectively as if it were short-circuited. As a result, the applied high-frequency AC current essentially acts as a resistor R. e and R I Passing through R c and C c The branch does not damage the electrochemical components of the battery. c and C c Any residual current passing through the branch will not damage the battery, due to the high frequency and zero DC component of the applied current. Next, resistor R e and R I The high-frequency AC current passing through the battery heats the battery core, thereby raising its temperature. If the high-frequency AC current is applied for a sufficiently long period of time, the battery core temperature will rise to a degree sufficient to make charging using the commonly used DC charging method safe.

[0075] Furthermore, as the required frequency of the AC current increases, the inductance L I This indicates a high AC voltage potential requirement from the charging device. In other words, although there is an AC voltage limit from the charging device, the inductance L I It becomes dominant when the frequency becomes high enough, thereby reducing all voltage potential drops across its terminals. Although some of the energy is still being converted into heat from this inductor, it becomes dominant. I It is far less than that from. Therefore, the high-frequency AC current is inducted L I You can make a selection considering these factors.

[0076] In a device designed to provide the aforementioned high-frequency AC current to raise the battery core temperature to a safe charging temperature, measures can be taken to periodically assess the temperature status of the battery core and determine whether the safe charging temperature level has been reached.

[0077] In a method and apparatus for charging a lithium-ion battery at low temperatures, a temperature sensor can be used, as discussed above with respect to the supercapacitor in Figure 12. However, two basic methods can be used to assess the battery core temperature without the need for a temperature sensor (and thus, no special configuration of the lithium-ion battery is required for use in such a method or with such apparatus). In one method, the battery impedance is measured periodically as the aforementioned high-frequency AC current is applied to the battery. Resistor R I Since the resistance is high at low temperatures, the level of battery impedance indicates whether the battery core temperature is low or at a temperature that is nearly safe for charging. Using this method, the battery impedance can be measured in advance for the charger to be used to determine when the battery core has reached a safe charging temperature.

[0078] A second method for determining whether the battery core temperature has reached a safe charging temperature level while applying the aforementioned high-frequency AC current is as follows: In this method, the high-frequency AC current is periodically interrupted, and current is discharged from the battery through a resistive load for a very short duration. If the battery core is still cold, the voltage across the load is low.

[0079] As will be apparent to those skilled in the art, both of the above methods can be readily incorporated into a battery charging unit. In fact, one and / or both of the above methods for assessing the lithium-ion battery core temperature for safe charging, in addition to the electrical and electronic circuit elements required for the application of the aforementioned high-frequency AC current, can be readily incorporated into a single charging unit. Such a unit can also charge the battery using commonly known methods once the battery core temperature has risen to a safe charging level.

[0080] Furthermore, once DC charging begins, the charging unit may be programmed to periodically assess the battery core temperature, and if it detects that the temperature is approaching an unsafe (low) temperature, a high-frequency AC current is switched on and the DC charging current is cut off. Alternatively, the high-frequency AC current may be superimposed on the DC charging current.

[0081] Lithium-ion batteries may also be equipped with temperature sensors, such as those used in some currently available lithium-ion batteries, to measure their temperature. The temperature sensor input may then be used to determine the battery's safe charging temperature, in addition to one or both of the methods described above.

[0082] The aforementioned high-frequency AC current can also be used to raise the lithium-ion battery core temperature at low temperatures to achieve a higher discharge rate. In this way, the method provides a means for charging lithium-ion batteries at low temperatures, and in addition, a means for improving the performance of lithium-ion batteries at low temperatures, i.e., for increasing their discharge rate.

[0083] Figure 12 shows a block diagram of an apparatus using the novel method for charging and / or discharging a lithium-ion battery 206 having an electrolyte battery core 208 at a low temperature. The charge / discharge unit 200 (collectively referred to herein as the "charge unit") is provided with electrical and electronic circuit elements that provide the aforementioned high-frequency AC current and charging DC current, both with voltage control, and may include a processor 202, such as a microprocessor or CPU, for controlling the process of measuring the battery core temperature, raising the core temperature if the core temperature is below the battery's safe charging temperature, and charging the battery when the battery core temperature exceeds the safe charging temperature, as previously described. The charge unit 200 has wiring for connecting to the terminals 210 of the battery 206. The process steps for performing such a method can be stored as software on a memory device accessible by the processor 202. The charging unit 200 guides the charging process appropriately by using one or both of the aforementioned methods based on the battery impedance, and / or alternatively, by periodically checking the temperature from an external or internal battery temperature sensor source 204.

[0084] Alternatively, the charging unit in Figure 12 may function as a charge and discharge control unit, and if the battery core temperature is below the safe charging temperature for charging as described above, it may raise the battery core temperature by applying an appropriate high-frequency AC current to the battery, followed by a DC charging current. If the battery temperature is low enough to significantly reduce its performance, i.e., its desired discharge rate, the charging unit 200 will also apply a high-frequency AC current to the battery 206 to raise its core temperature and increase its discharge rate.

[0085] The block diagram in Figure 13 shows one embodiment 300 of a lithium-ion charging and discharging unit. Unit 300 can be used exclusively for charging lithium-ion batteries at low temperatures, but is intended for use as a lithium-ion battery charging and discharging unit at all temperatures, including low temperatures.

[0086] It should be understood here that, in the context of lithium battery charging, "low temperature" is intended to refer to the battery core temperature at which a DC current (continuous current or pulsed current, or other variations known in the art) would damage the battery or prevent it from being effectively charged. In the lithium-ion battery discharge process, "low temperature" is intended to refer to the temperature at which the lithium-ion battery discharge rate is significantly lower than its normal rate. In lithium-ion batteries, the latter temperature is generally lower than the temperature at which the battery can be safely charged.

[0087] Unit 300 is powered by an external power source, as schematically indicated by arrow 302, which may be, for example, an outdoor outlet for charging the lithium-ion battery of an electric vehicle. As discussed above, a microprocessor-based controller 304 (alternatively referred to as the “control unit” in this specification and Figure 13) is used to determine the status of the battery 301, which may or may not have an internal or external temperature sensor 303, while it is being charged. If the battery 301 determines that its battery core is below a safe charging temperature, it instructs the AC and DC current generator 306 to output a high-frequency AC current, as schematically indicated by arrow AC307, and if the battery 301 is safe to charge, it instructs the AC and DC current generator 306 to output a DC current, as schematically indicated by arrow DC308, using the switching element 310 shown. The control unit 304 can be programmed to raise the internal temperature of the battery 301 by a safe amount to enable charging of the battery 301 at a faster rate (the instructions can be stored in memory provided in unit 300 and accessible by the control unit 304). High-frequency AC and DC currents are generated by the indicated AC and DC current generator 306, which is powered by the unit input power 302 and communicates directly with the control unit 306, as indicated by arrow 312. The control unit 304 also constantly communicates with the AC and DC current switching element 310 and can determine whether one or the other of the AC or DC current needs to be switched on or off. In this embodiment, it is possible to turn on only one of the AC or DC current at a time.

[0088] In the embodiment 300 of Figure 13, when either AC or DC current is applied, current is passed to the charging voltage, current, and impedance measurement and charge and discharge adjustment unit 314, as indicated by arrow 316a. The charging voltage, current, and impedance measurement and charge and discharge adjustment unit 314 is used to identify the aforementioned current, voltage, and impedance measurements required by the control unit 304 and to control the charging process as described above. The charging voltage, current, and impedance measurement and charge and discharge adjustment unit 314 also adjusts the charging current during the charging cycle and the discharge current during the discharge cycle, as induced by the control unit 304, to ensure the proper and safe operation of the battery 301 and the charge and discharge unit 300. The charging and discharging connections between the charging voltage, current, and impedance measurement and charge and discharge adjustment unit 314 and the lithium-ion battery 301 are schematically shown by arrow 316b. Battery discharge is routed via AC and DC current switching elements 310, as schematically indicated by arrow 318. The control unit 304 communicates with all system units as shown in Figure 13, as well as with a battery temperature sensor 303, if one is provided. The charging voltage, current, and impedance measurement and charging and discharging adjustment unit 314 are shown separately, but can be integrated into the control unit 304.

[0089] Once the battery core temperature reaches a safe charging level, the battery can be charged using DC current, or using any other currently available technique known in the art and used for efficient and safe charging of lithium-ion batteries, such as using or not using charging pulses. Any of the known methods for protecting the discharge process may also be used. Similarly, different hardware designs, also known in the art and used in the charge and discharge circuit element designs of this and the following embodiments, may be used to charge the battery after reaching the aforementioned safe core temperature level (measured directly or via the aforementioned impedance-related techniques), and when reaching a desired core temperature (measured directly or via the aforementioned impedance-related techniques) for efficient discharge (typically in terms of a rapid discharge rate and a reduction in internal losses that is higher at lower temperatures).

[0090] Figure 14 shows a block diagram of an alternative embodiment, a microprocessor-controlled lithium-ion battery charging and discharging unit 320 for low temperatures. Embodiment 320 is intended to be used as a means of simply charging a lithium-ion battery at all temperatures, including low temperatures, once the battery core temperature falls below its safe charging temperature level. All components of Embodiment 320 are the same as those of Embodiment 300 in Figure 13, except that Embodiment 320 is modified so that the charging voltage, current, and impedance measurement, as well as the charge and discharge adjustment unit 314a, eliminates its discharge adjustment function. The lithium-ion charging unit 320 functions to charge the battery using a DC current (continuous current or pulsed current, or other modifications known in the art, etc.) while the battery core temperature, as measured using one or more of the methods described herein, is above its safe charging temperature. If the battery core temperature is determined to be below or approaching the battery's safe charging temperature, the charging DC current is disconnected, and a high-frequency AC current is applied as previously described for the embodiment in Figure 13 to raise the battery core temperature above its safe charging temperature. The core temperature can be measured either continuously or at sufficiently short time intervals to ensure that the battery core temperature does not drop below its safe charging temperature during charging.

[0091] Figure 15 shows a block diagram of another alternative embodiment, a microprocessor-controlled lithium-ion battery charging and discharging unit 340 for lower temperatures. All components of embodiment 340 are the same as those of embodiment 300 in Figure 13, except that the AC and DC current switching element 310 in Figure 13 is replaced by an AC and DC current mixing element 342. Depending on the measurement of charging voltage, current, and impedance, and the detailed design of the charging and discharging adjustment unit 314b, some conventional modifications may be made to the design to adapt to the mixed AC and DC current signals.

[0092] The operation of the microprocessor-controlled lithium-ion battery charging and discharging unit 340 in Figure 5 is similar to that of the embodiment 300 in Figure 13, but differs in the following respects. In the embodiment 300 in Figure 13, during a battery charging cycle, the unit 300 can apply either a high-frequency AC current or a DC current to the battery. During charging at a low temperature, the unit 300 applied a high-frequency AC current until a safe battery core temperature was reached. Next, a charging DC current (continuous current or pulsed current, or other modifications known in the art, etc.) was applied to charge the battery 301. In the embodiment 340 in Figure 15, when the battery core temperature falls below its safe charging temperature, the unit similarly applies a high-frequency voltage to the battery to raise its core temperature to a safe charging level. However, in embodiment 340, by providing an AC current and DC current mixing element, when it is detected that the battery core temperature has dropped to near the safe charging temperature, it is possible to maintain the battery core temperature at the safe charging temperature level. Whenever such conditions are detected, the core temperature is raised above its safe charging temperature by adding a high-frequency AC current to the charging DC current. By continuously or frequently measuring the battery core temperature, it is possible to maintain the temperature above the battery's safe charging temperature and to continue charging. This situation is frequently encountered when lithium-ion batteries are exposed to extremely cold environments, and especially when the battery has a relatively small size and a geometric shape with a relatively high surface area-to-volume ratio, for example, in batteries that are relatively thin and have a large surface area.

[0093] A high-frequency AC current may be applied to the battery 301 during the discharge cycle when the battery core temperature falls below or near a predetermined optimal level for efficient discharge (typically determined in terms of the achievable discharge rate and the reduction in internal losses, which increases at lower temperatures). In this embodiment, the battery core temperature can be measured at least periodically via a temperature sensor, if one is provided, and / or using the impedance-related measurement techniques described above.

[0094] Figure 16 shows a block diagram of an alternative embodiment, a microprocessor-controlled lithium-ion battery charging and discharging unit 360 for low temperatures. Embodiment 360 is intended to be used as a means of simply charging a lithium-ion battery at all temperatures, including low temperatures, once the battery core temperature falls below its safe charging temperature level. All components of Embodiment 360 are the same as those of Embodiment 340 in Figure 15, except that Embodiment 360 is modified so that the charging voltage, current, and impedance measurement, as well as the charge and discharge adjustment unit 314c, are eliminated to remove their discharge adjustment function. The lithium-ion charging unit 360 functions to raise the battery core temperature to the safe charging temperature level, as described for Embodiment 340 in Figure 15, and thereafter charging using a DC current (continuous current or pulsed current, or other modifications known in the art, etc.) continues while the battery core temperature, as measured using one or more of the methods described herein, remains above its safe charging temperature. Next, whenever the control unit 304 detects that the battery core temperature has dropped to near its safe charging temperature, it instructs the AC and DC current generators to add a high-frequency AC current to the charging DC current, thereby raising the battery core temperature above the safe charging temperature. By continuously or frequently measuring the battery core temperature, the core temperature can be maintained above the battery's safe charging temperature while the battery is being continuously charged.

[0095] Figure 17 shows a block diagram of another alternative embodiment, a novel, microprocessor-controlled lithium-ion battery charging and discharging unit 380 for low temperatures. Embodiment 380 is intended to be used as a means of maintaining the core temperature of a lithium-ion battery above a predetermined level for efficient discharge at all temperatures, including low temperatures. All components of Embodiment 380 are the same as those of Embodiment 360 in Figure 15, except that Embodiment 380 is modified so that the charging voltage, current, and impedance measurement, and the charge and discharge adjustment unit 314d, provide only the functionality of discharge adjustment and voltage, current, and battery impedance measurement. While the battery 301 is being used to power a particular load, i.e., while electrical energy is being discharged from the battery, a high-frequency AC current may be applied to the battery whenever the battery core temperature is measured to be below, or near, a predetermined level that is optimal for efficient battery discharge (usually determined in terms of an achievable discharge rate and a reduction in internal losses that is higher at lower temperatures). In this embodiment, the battery core temperature can be measured at least periodically, if a temperature sensor 303 is provided, via the temperature sensor 303, or using the impedance-related measurement techniques described above.

[0096] In the embodiment 380 of Figure 17, the generator element 306a that generates high-frequency AC current is powered by an external source 302. External power supply to the AC current generator 306a may be necessary in certain situations, for example, when the charged battery core is at too low a temperature to provide sufficient power to the AC current generator 306a, or when it cannot provide enough power to raise the core temperature to the required operating temperature within a sufficiently short period of time. If such situations are not expected to occur, the AC current generator 306a may be powered directly by the lithium-ion battery 301 itself, or after an initial external power supply period. The embodiment in Figure 18 illustrates such a discharge control unit 400 in which the AC current generator 306a of the discharge control unit is powered by the battery 301 itself.

[0097] Embodiment 400, shown in Figure 18, is similar in functionality and design to Embodiment 380 in Figure 17, but differs in the power supply for the AC current generator. In Embodiment 400, the AC current generator 306a is powered by the device discharge power and AC generator power supply control unit 402, as indicated by arrow 404. The AC current generator 306a communicates directly with the system control unit 304, as shown in Figure 18. The discharge power and AC generator power supply control unit 402 obtains its power from the battery via voltage, current, and impedance measurement and discharge adjustment unit 314a, as indicated by arrow 406. The input and output currents to the battery 301 are via the connection indicated by the bidirectional arrow 316a. Battery discharge is via the discharge power and AC generator power supply control unit 402, as indicated by the discharge power arrow 318. When the battery core temperature falls below a predetermined temperature level, or is about to fall below a predetermined temperature level, the generated AC current is supplied to the voltage, current, and impedance measuring and discharge adjustment unit 314a, which communicates with the system control unit 304, in order to raise the battery core temperature.

[0098] Embodiment 400 in Figure 18 may be provided with an external power supply for its high-frequency AC current generator, similar to that in Embodiment 380 in Figure 17. The device then has the capability to use this external power supply, as shown in the Embodiment of Figure 18, as an initial power supply to bring the battery core temperature to a predetermined level, particularly before switching to the internal power supply mode. Such a configuration is shown in Embodiment 420 in Figure 19, which is similar in functionality and design to Embodiment 400 in Figure 18, but with a different power source for the AC current generator 306a. In Embodiment 400 in Figure 18, the AC current generator 306a is powered only by arrow 404. However, in Embodiment 420 in Figure 19, the AC current generator 306a can also obtain energy from an external input power 302, and depending on the situation, one or both of these power sources can be selected to heat the battery 301.

[0099] Figures 20 and 21 show flowcharts for charging and discharging a lithium-ion battery at any given temperature. As discussed above, if it is determined that the battery needs to be charged, in step S10, a measurement of the internal temperature of the lithium-ion battery is taken. Next, in step S12, it is determined whether the taken temperature is lower than some predetermined threshold temperature at which the battery cannot be charged or efficiently charged. If the determination in step S12 is No, the method proceeds to steps S14 and S16, and the battery is charged in the conventional manner. However, if the determination in step S12 is Yes, the method proceeds to step S18, where a high-frequency AC voltage current is input to the lithium-ion battery to heat its interior. Such a process can loop back to step S10 along path S20 periodically or at some regular intervals until the determination in step S12 is negative (No). When the determination in step S12 is negative (No), the battery is charged in the conventional manner in steps S14 and S16 until it is fully charged or until the process is terminated in any other way. Thus, in Figure 20, a heating procedure is performed until the core temperature rises sufficiently high in order to avoid damaging the battery while the battery core temperature is detected to be below a predetermined temperature.

[0100] In Figure 21, a measurement is taken in step S10 to obtain a measurement of the internal temperature of the battery. Similar to Figure 20, if in step S12 it is determined that the core temperature is below a predetermined temperature, in step S18 a high-frequency AC voltage current is input to the battery to heat the inside of the battery. As discussed above with respect to Figure 20, this process loops back to step S10 via S20 until it is determined in step S12 that the core temperature exceeds the predetermined threshold temperature. When it is determined in step S12 that the temperature has exceeded the threshold temperature, the process proceeds to step S22, where the lithium-ion battery is discharged to the load in the conventional manner. Thus, as can be seen in loop S24, the heating procedure is also performed until the core temperature rises above the predetermined temperature, while the core temperature of the battery is low and the discharge efficiency is decreasing. Therefore, the discharge in step S22 is not interrupted during the heating procedure in step S18.

[0101] In both Figures 20 and 21, the alternative steps discussed above can also be used to determine (without using a temperature sensor) whether the battery core temperature is too low to charge in the conventional manner. In this case, step S12 determines whether the core temperature is too cold based on this determination rather than on direct temperature measurement. Naturally, both determination methods can be used, and this method may include logic for making the determination in step S12 based on multiple inputs (for example, for the first method, the temperature measurement and battery impedance as described above, and / or for the second method discussed above, the voltage across a small load).

[0102] As will be apparent to those skilled in the art, numerous modifications of the described design, as shown in the block diagrams of Figures 13 to 19, are also possible to perform the functions shown. The disclosure of the shown embodiments is not intended to limit their implementation to the described modes, but rather to illustrate the various combinations of functionalities that can be incorporated into a given design, and their general purposes.

[0103] It is also recognized that the means for controlling the operation of the disclosed embodiments may involve the use of a microprocessor-based control unit. However, it is also recognized that the general functions performed by the microprocessor can also be performed by appropriate electronic and logic circuit elements. Similar circuit element designs have been developed industrially and commercially for controlling various processes and may be designed for controlling the disclosed lithium-ion battery charging and discharging device for operation at all temperatures, including low temperatures.

[0104] Finally, none of the above methods can be performed without initial determination of the core temperature of the energy storage device. That is, a conventional charging input can be used regardless of the core temperature of the energy storage device, and such determination can be performed while the charging input is applied. In this case, core temperature determination can be performed periodically, and if the acquired (directly measured or assumed) core temperature is below a predetermined threshold that would prevent further charging, or is approaching some limit of the predetermined threshold, then the alternative inputs discussed above can be superimposed on the charging input to heat the internal components of the energy storage device, for example, until the predetermined threshold is reached, until the charging input can be restarted, or the charging input can be stopped and the alternative input applied. The same may apply to the discharge methods discussed above.

[0105] Figure 22 illustrates one embodiment of a heating circuit for a battery or energy storage device 450, for example, a lithium-ion battery, a nickel-metal hydride battery, a lead-acid battery, or other rechargeable or non-rechargeable battery, and for various types of supercapacitors. In the diagram of Figure 22, the device 450 is shown as a single battery, but it may be a single supercapacitor, or two or more batteries or supercapacitors connected in series or parallel.

[0106] As can be seen in Figure 22, an external power supply is used to apply a positive current flow (indicated by a positive voltage V+) into the battery 450 via switch SW1. Resistor R sink is used to draw current from the battery via switch SW2. Signals for opening and closing switches SW1 and SW2 are provided by the controller.

[0107] In this embodiment, the high-frequency AC voltage described above, which is applied to the battery 450 to heat its electrolyte, is brought about by the proper on / off switching of switches SW1 and SW2, as follows. This process consists of applying current to the battery and drawing current from the battery at a desired (sufficiently high) frequency, and is equivalent to the capacitor C in the case of a lithium-ion battery as illustrated by the model in Figure 11. s (Figure 11) effectively short-circuits the equivalent capacitance between electrodes of other types of batteries and supercapacitors. For supercapacitors, the total capacitance C in Figure 1 is essentially a capacitor C that describes the electrical energy stored as chemical energy, and a parallel capacitor C that essentially shows the capacitance between the device electrodes. s By separating it into these two components, the model in Figure 1 can be created in more detail.

[0108] In the process shown in Figure 21, where high-frequency AC current is passed through battery 450, when switch SW1 is closed, switch SW2 is opened, and vice versa. Switching signals to enable or disable SW1 and SW2 are transmitted by a controller. The controller may be a microcontroller, combinational logic circuit, or a circuit based on an FPGA, etc. The current flow into the battery during a positive cycle is controlled by varying the voltage level of the voltage source "V+". By increasing the voltage level, "V+" increases the current flow into battery 450. The amount of voltage drop and current flow from the battery is controlled by changing the resistance value of "R sink", i.e., by reducing the resistance of the resistor "R sink", thereby increasing the current flow from battery 450. Therefore, as will be recognized by those skilled in the art, the resulting effective high-frequency AC voltage will be close to a square wave. Generally, the voltage level "V+" needs to be balanced so that approximately the same charge and discharge are obtained from the battery during each cycle of AC voltage application. In addition, as described below in this disclosure, since the characteristics of the battery change with temperature, it is desirable that the provided controller vary the characteristics of the applied AC voltage in order to obtain an optimal rate for heating the battery.

[0109] Figure 24 illustrates a schematic implementation of the battery heating circuit embodiment shown in Figure 22. In the circuit of Figure 22, switch SW1 is implemented by a P-channel MOSFET "M1", and switch SW2 is implemented by an N-channel MOSFET "M2". Resistors R1 and R2 are pull-up and pull-down resistors, respectively, which are required to properly bias the gate inputs of the MOSFETs. When the voltage levels of both control signals VG1 and VG2 are 0V, MOSFET M1 acts as a closed switch and M2 acts as an open switch. When the voltage level of control signal VG1 is above the gate-source threshold voltage of M1 and VG2 is above the gate-source threshold voltage of M2, MOSFET M1 acts as an open switch and M2 acts as a closed switch. To disable both switches when the heating circuit is not in use, VG1 is set above the gate-source threshold voltage of M1 and VGS is set to 0V. Alternatively, the switches can also be disabled by disconnecting the circuit from the voltage source V+.

[0110] As will be apparent to those skilled in the art, the implementation of the circuit diagram of Figure 22, as shown in Figure 24, is not unique, and many other circuits with the same functionality may be designed. The example of the circuit in Figure 24 is not intended to exclude any other circuits that may be capable of providing the same functionality.

[0111] Figure 25 illustrates a circuit diagram of an embodiment of Figure 24, which includes a controller that uses a temperature sensor input to activate a battery heating circuit element when a predetermined low temperature threshold is detected. The device is shown to include a temperature sensor, which is used to detect the battery temperature. The controller consists of a microcontroller. The output voltage level of the temperature sensor is typically designed to be proportional to the measured battery temperature. The microcontroller monitors the output voltage of the temperature sensor using one of the internal ADC channels, "A1," in Figure 25. When the temperature voltage output falls below a certain preset threshold, the microcontroller applies drive signals to M1 and M2, as previously described for the embodiment of Figure 24, and thus initiates the battery heating process. The drive signals are transmitted to the gate terminals of M1 and M2 via two digital output pins D1 and D2, respectively. The microcontroller can be programmed to change the switching frequency of M1 and M2, i.e., the frequency of the heating current, depending on the measured battery temperature, as described later in this disclosure.

[0112] The temperature sensor may be a low-voltage temperature sensor IC such as a TMP35, thermocouple module, resistance temperature detector (RTD), or thermistor. The battery temperature is generally measured at the battery surface, and in this case, during the described heating process, the battery core temperature is generally higher than the measured surface temperature. For relatively small batteries, e.g., those with a maximum diameter of 1 inch, this difference may not pose any problem because the difference may be only a few degrees Celsius, and the temperature threshold for the lower temperature may be set a few degrees lower than the desired threshold to account for this difference. Alternatively, especially for larger batteries and supercapacitors, a thermal model of the battery may be used, along with the time history of heating energy input into the battery, to estimate the average (or peak-high or peak-low) internal temperature of the battery core, and this may be used to set the controller's low-temperature threshold for switching the heating circuit on and off. Thermal modeling of batteries and supercapacitors is well known in the art, and for these embodiments, a very simplified model is generally sufficient. Modeling techniques specifically tailored for use in lithium-ion batteries and other similar batteries, and supercapacitors, are described later in this disclosure.

[0113] As will be recognized by those skilled in the art, the usual practice for setting a temperature threshold is to set a temperature range below which the heating process is turned on and above which it is turned off.

[0114] When an external AC power supply is used to power the circuits in Figure 24 or Figure 25, an AC-DC converter and voltage regulator, shown in the dashed box in Figure 25, may be used to supply voltage V+ to the circuit in Figure 24, and in addition, to power the microcontroller and temperature sensor for the circuit in Figure 25. The AC-DC converter and voltage regulator may be integrated into the same circuit board as the other components of the circuit, or they may be designed as external components.

[0115] Figure 26 illustrates the circuit diagram shown in Figure 25 with a temperature sensor implemented using a thermistor or RTD. The thermistor can be either an NTC or PTC type thermistor. The resistance of the thermistor and RTD is proportional to the temperature. Therefore, resistor R3 in series with either the thermistor or RTD forms a voltage divider. Thus, the voltage measured by the ADC channel A1 of the microcontroller is proportional to the measured temperature. The resistance value of R3 can be adjusted to obtain different sensitivities.

[0116] Figure 27 illustrates another embodiment of a battery heating circuit that applies both positive and negative current flows to a battery using bipolar power supplies V+ and V-. When the P-channel MOSFET M1 is enabled and the N-channel MOSFET M2 is disabled, a positive voltage source V+ is connected to the positive terminal of the battery, and current flows from the source into the battery. The voltage level of V+ must be greater than the voltage across the battery. When M2 is enabled and M1 is disabled, a negative voltage source V- is connected to the positive terminal of the battery, and current flows from the battery into the source. The voltage level of V- is preferably lower than the voltage across the battery to balance the current flow. Resistors R1 and R4 are used to ensure that both M1 and M2 are disabled when the control signal voltage is 0V. Resistors R2 and R3 can be used to adjust the output DC offset voltage value. The control signal from the controller is AC coupled via capacitor C1. When the control signal voltage is positive, M2 is enabled and M1 is disabled. When the control signal voltage is negative, M1 is enabled and M2 is disabled.

[0117] Figure 28 illustrates the circuit diagram of the controller, along with the circuit diagram shown in Figure 27. The controller consists of a temperature sensor and a microcontroller. The temperature sensor is used to monitor the temperature of battery 450, which may be heated if it falls below a predetermined temperature threshold. The output voltage level of the temperature sensor is proportional to the battery temperature. The temperature sensor may be a low-voltage temperature sensor IC such as a TMP35, thermocouple module, resistance thermometer (RTD), or thermistor. The microcontroller monitors the output voltage of the temperature sensor using one of its internal ADC channels, "A1". When the temperature voltage output falls below a certain preset threshold, the microcontroller applies control signals to M1 and M2, and thus initiates the heating process as previously described. The control signals are transmitted to the gate terminals of M1 and M2 via digital output pin D1. The AC coupled via capacitor C1 allows the control signal voltage levels at the gate terminals of M1 and M2 to be both positive and negative, while digital pin D1 outputs a voltage value between 0V and a positive preset value. The microcontroller can change the switching frequencies of M1 and M2 at different battery temperatures, in particular when the battery is intended to operate at extremely low temperatures, e.g., below -40 degrees Celsius, as described below. AC-DC converters 1 and 2 are used to supply positive and negative voltage sources for the heating process, and in addition, to power the microcontroller and temperature sensor via a voltage regulator. The AC-DC converters and voltage regulator can be integrated on the same circuit board along with the other components, or they can be external components.

[0118] Figure 29 illustrates a block diagram of another embodiment of a heating circuit for a battery 450, which applies both positive and negative current flows into the battery 450 using a single power source. For this purpose, four switches SW1A, SW1B, SW2A, and SW2B are used. These switches can be implemented by relays, semiconductor switch ICs, or MOSFETs. When SW1A and SW1B are closed and SW2A and SW2B are open, a positive voltage source V+ is connected to the positive terminal of the battery 450 and circuit ground is connected to the negative terminal of the battery. Then, current flows from the source into the battery 450. When SW1A and SW1B are open and SW2A and SW2B are closed, a positive voltage source V+ is connected to the negative terminal of the battery 450 and circuit ground is connected to the positive terminal of the battery. Then, current flows from the battery 450 into the source. The voltage level V+ is preferably greater than the voltage across the battery 450. The controller is used to drive all four switches in the correct sequence and frequency.

[0119] Figure 30 illustrates a circuit diagram of a battery heating controller having the circuit of the embodiment shown in Figure 29. The switches are implemented by MOSFETs M1A, M1B, M2A, and M2B, representing SW1A, SW1B, SW2A, and SW2B, respectively. The controller is a microcontroller, and the controller is equipped with a temperature sensor. The temperature sensor is used to monitor the temperature of the battery 450. The output voltage level of the temperature sensor is proportional to the battery temperature. The temperature sensor may be a low-voltage temperature sensor IC such as a TMP35, thermocouple module, resistance thermometer (RTD), or thermistor. The microcontroller monitors the output voltage of the temperature sensor using one of its internal ADC channels, "A1". When the temperature voltage output falls below a predetermined threshold, the microcontroller initiates the battery heating process by applying a control signal to the MOSFETs via a driver circuit consisting of resistors R1 to R4 and MOSFETs M3 and M4, through digital pins D1 and D2. The driver circuit ensures that M1A, M1B, M2A, and M2B can be fully driven to either cutoff mode (open) or saturation mode (closed), regardless of the differential voltage level between the control signal voltage and the power supply voltage V+. When digital pin D1 is logic high and D2 is logic low, M1A and M1B act as closed switches, and M2A and M2B act as open switches. Therefore, current flows from the source into battery 450. When digital pin D1 is logic low and D2 is logic high, M1A and M1B act as open switches, and M2A and M2B act as closed switches. Therefore, current flows from battery 450 into the source. Thus, the switching frequency, i.e., the frequency of the applied current (AC heating current), is set and controlled by the controller and may vary as a function of battery temperature, as described hereafter in this disclosure. The AC-DC converter is used to supply a voltage source for the heating process, and also to power the microcontroller and temperature sensor via a voltage regulator.The AC-DC converter and voltage regulator can be integrated onto the same circuit board along with the other components, or they can be external components.

[0120] Figure 31 shows an example of raising the temperature of a standard Model 18650 Li-ion cell battery from -30°C to 20°C using a circuit based on the design shown in Figure 27. The temperature of the battery was measured on its outer surface. The battery part number is LGABB418650.

[0121] As previously described in this disclosure, the internal resistance and internal inductance of lithium-ion-based batteries, and indeed all rechargeable and primary batteries, and supercapacitors, vary with temperature, and this change becomes extremely significant at lower temperatures. As an example, Figures 32 and 33 plot the measured internal resistance and internal inductance of a standard 18650 cell lithium-ion battery (battery part number LGABB418650) in the temperature range of -55°C to 45°C, respectively.

[0122] As is recognized, as shown in Figure 32 and the plots in Figure 33, the internal resistance and internal inductance of batteries and supercapacitors to be heated by the application of the described high-frequency voltage (current) vary significantly as a function of temperature, especially at very low temperatures where achieving a higher heating rate is highly desirable. Therefore, the amplitude and frequency of the applied high-frequency voltage (current) must be adjusted to obtain the optimal heating rate in response to temperature variations. In various embodiments of the present invention, this is easily accomplished by providing the controllers and microcontrollers of the embodiments in Figures 22 and 24-30 with stored data, for example, in the form of a table. As will be recognized to those skilled in the art, examining the typical plots in Figures 32 and 33 shows that such lookup tables require only a very limited size because the plotted curves have a simple shape. In more general-purpose devices, such lookup table data can also be stored in the memory of controllers and microcontrollers for a wide range of batteries and supercapacitors that are commonly used. Alternatively, users may be given the option of inputting relevant lookup table data by using some data communication methods known in the technology.

[0123] Figure 34 illustrates another embodiment of a battery heating circuit utilizing a push-pull amplifier consisting of PNP bipolar junction transistors Q1 and Q2. The base terminals of both transistors are driven by the same control signal voltage. When the signal voltage is positive, Q1 is activated and Q2 is in cutoff mode, acting as an open switch. Current flows from the positive voltage source V+ into the battery. When the signal voltage is negative, Q2 is activated and Q1 is in cutoff mode, acting as an open switch. Current flows from the battery into the negative voltage source V-. The control signal is transmitted from a controller similar to the control circuit shown in Figure 28. The controller outputs a digital pulse via an AC-coupled capacitor C1. The AC-coupled control signal is then amplified by a device such as an operational amplifier U1. The ratio of resistors R1 and R2 is used to determine the voltage level of the output signal of U1. The AC-coupled and amplified control signal is then transmitted to drive transistors Q1 and Q2.

[0124] As will be apparent to those skilled in the art, the switching circuits in the embodiments of Figures 22 and 24-30 generate a substantially square-wave voltage input for heating batteries and supercapacitors. Such a square-wave high-frequency voltage, when generated at sufficiently high frequencies as previously shown, is effective for heating various shown batteries, including lithium-ion batteries, lead-acid batteries, and supercapacitors. In certain applications, particularly when the inductance of the battery or supercapacitor to be heated is high, it may be desirable to use a heating AC voltage that is closer to a pure sine wave. For this purpose, for example, the heating circuit of the embodiment in Figure 34 may be modified as illustrated in Figure 35. In this circuit, resistor R3 and capacitors C3 and C1 together form a filter that converts the square-wave signal generated by the controller into an essentially sinusoidal signal.

[0125] Figure 36 illustrates another embodiment of a battery heating circuit utilizing a power operational amplifier integrated circuit U1. The power operational amplifier integrated circuit U1 can be configured as an inverting or non-inverting amplifier. Figure 36 illustrates an example of U1 configured as an inverting amplifier. In this embodiment, a control signal is transmitted from a controller, which may be similar to the control circuit shown in the embodiment of Figure 28. The control signal is transmitted to the input of U1 via an AC-coupled capacitor C1. The ratio of resistors R1 and R2 is used to configure the voltage level at the output of U1. Next, the output power of U1 is used to apply heating for the battery via an AC-coupled capacitor C2. Capacitor C2 is required to prevent damage to the output terminals of U1.

[0126] Figure 37 illustrates a modified alternative example of the battery heating circuit embodiment shown in Figure 36. In this circuit, resistor R3 and capacitors C3 and C1 together form a filter that essentially converts the square wave signal generated by the controller into a sinusoidal wave signal.

[0127] Figure 38 illustrates a modified alternative example of the battery heating circuit in the embodiment of Figure 37. In this circuit, a transformer T1 is used to provide impedance matching between the battery and the output of the power operational amplifier integrated circuit U1. The transformer T1 is necessary when the battery impedance is even lower than the output impedance of the power operational amplifier integrated circuit U1. The coil resistance N1 inside T1 should be sufficiently high to maintain the output efficiency of U1 and, in addition, to reduce power dissipation within U1. The AC coupling capacitor C2 is also required to prevent the coil resistance N2 from loading the battery.

[0128] It is recognized that the battery heating circuit embodiments in Figures 22, 24-30, and 34-38 use an external power source for their operation. In certain applications, it is desirable for the battery heating circuit to operate using power supplied by the battery itself. For battery types such as Li-ion, NiMH, and lead-acid, the maximum output current available at the rated voltage decreases as the battery temperature decreases. Figure 39 is a typical plot showing the maximum output current level of Li-ion, NiMH, and VRLA (Valve-Regulated Lead-Acid) batteries as a function of temperature. As can be seen in Figure 39, the available current decreases significantly as the temperature decreases. For this reason, the following embodiments of the battery heating circuit of the present invention can be classified into those for applications where the battery can still provide sufficient current to directly power the heating circuit, and those where the available current level is not sufficiently high and an intermediate storage device is required. These two circuit types are desired to operate together to achieve optimal performance; that is, once the battery is sufficiently heated and capable of providing the required current level, the heating circuit switches to direct power supply mode.

[0129] Figure 40 illustrates another embodiment of the heating circuit for battery 450, which uses power directly from the battery being heated, and therefore does not require an external power supply. The circuit embodiment in Figure 40 is a modification of the basic heating circuit of the embodiment in Figure 22. In the circuit of Figure 40, the voltage source V+ is provided by a step-up voltage regulator that obtains the input voltage from the terminals of battery 450 via an LC filter consisting of an inductor L1 and a capacitor C1. The step-up voltage regulator outputs a voltage level that is an increased voltage level of the input voltage. The LC filter allows the input voltage level of the voltage regulator to be kept stable during the heating process, which involves either an inflow of current into the battery or an outflow of the battery. The voltage regulator requires a minimum amount of input current to maintain the output voltage level and provide sufficient current for the heating process. Figure 39 shows the available currents at rated voltages for typical Li-ion, NiMH, and lead-acid batteries. The circuit in Figure 40 is ideal for operation at a battery temperature above a certain value that allows sufficient current for the heating process while maintaining the V+ voltage level. For example, with the circuit in Figure 40, a 28V Li-ion battery pack is used, and the minimum current required for the circuit in Figure 40 to operate properly is approximately 5A. Therefore, as shown in Figure 39, the minimum operating temperature for this example is -20°C.

[0130] It is recognized that in the embodiment of the heating circuit in Figure 40, which is powered by the battery 450 itself, an external power supply may be provided. As a result, the user can use external power to heat the battery 450 when such an external power supply is available, thereby saving battery charge and accelerating the battery heating process. In this case, an optional terminal of V+ and circuit ground can be connected to the external power supply. It is recognized that once the battery temperature has risen to a maximum appropriate value, the external power supply can be disconnected, and the subsequent heating process can be powered by the battery itself. In many such applications, the external power supply is used to bring the battery temperature to room temperature, or a temperature at which the battery performance is nearly optimal or at a desired level, or near thereto, and then the external power supply is terminated, and battery power is used to maintain the battery temperature at the desired level.

[0131] An example of such an application is a battery for a vehicle or power tool, where the vehicle or power tool is stored in an unheated garage or storage area with access to external power. The user then first heats the battery in cold temperatures, and once the battery reaches the desired temperature level, disconnects the external power and maintains the battery temperature at the desired level using battery power. The user can then use the vehicle and power tools in extremely cold weather without losing battery performance. As will be recognized by those skilled in the art, such applications are numerous and include most devices and systems used occasionally in low-temperature environments.

[0132] Figure 41 illustrates an embodiment of the battery heating circuit of Figure 40, modified to enable operation at extremely low temperatures where the battery cannot directly provide a sufficiently high current for the circuit's operation. The embodiment of the battery heating circuit in Figure 41 operates without external power. The voltage source V+ is provided by a step-up voltage regulator that obtains an input voltage from capacitor C2 via an LC filter consisting of an inductor L1 and a capacitor C1. Capacitor C2 is charged when switch SW3 is switched to position A. Once the capacitor is fully charged, the controller switches SW3 to position B, and the voltage regulator draws energy from C2 to provide energy for the heating process. Once the voltage across C2 drops to a certain level that can no longer sustain the operation of the voltage regulator, SW3 is switched to position A, and the capacitor is fully charged again. This process is repeated until the controller detects that the battery temperature has exceeded a predetermined threshold for direct self-powering. Then, as previously described for the embodiment of Figure 40, the battery can be used to directly power the heating circuit.

[0133] Figure 42 illustrates another embodiment of the heating circuit for battery 450, which uses power directly from the battery being heated, and therefore does not require an external power supply. The circuit embodiment in Figure 42 is a modification of the basic heating circuit of the embodiment in Figure 29. The voltage source V+ is provided by a step-up voltage regulator that obtains an input voltage from the terminals of battery 450 via an LC filter consisting of an inductor L1 and a capacitor C1. The step-up voltage regulator outputs a voltage level higher than the input voltage level. The LC filter allows the input voltage level of the voltage regulator to be kept stable during the heating process, which alternately allows current to flow into and out of battery 450. The voltage regulator requires a minimum amount of input current to maintain the output voltage level and provide sufficient current for the heating process. Figure 39 shows the available currents at rated voltages for typical Li-ion, NiMH, and lead-acid batteries. The circuit in Figure 42 is ideal for operation at a battery temperature of 450°C, above a level where the battery can provide sufficient current for the heating process while maintaining the required V+ voltage level. For example, with the circuit in Figure 42, a 28V Li-ion battery pack is used, and the minimum required current for the circuit in Figure 42 to operate properly is approximately 5A. Therefore, as shown in Figure 39, the minimum operating temperature for this example is -20°C.

[0134] It is recognized that in the embodiment of the heating circuit in Figure 42, which is powered by the battery 450 itself, an external power supply may be provided. As a result, the user can use external power to heat the battery 450 when such an external power supply is available, thereby saving battery charge and accelerating the battery heating process. In this case, an optional terminal of V+ can be connected to circuit ground to the external power supply. It is recognized that once the battery temperature has risen to a maximum appropriate value, the external power supply can be disconnected, and the subsequent heating process can be powered by the battery itself. In many such applications, the external power supply is used to bring the battery temperature to room temperature, or a temperature at which the battery performance is nearly optimal or at a desired level, or near thereto, and then the external power supply is terminated, and battery power is used to maintain the battery temperature at the desired level. Examples of such applications as batteries for vehicles or power tools, and other similar applications, have been discussed so far.

[0135] Figure 43 illustrates an embodiment of the battery heating circuit of Figure 42, modified to enable operation at extremely low temperatures where the battery cannot directly provide a sufficiently high current for the circuit's operation. The embodiment of the battery heating circuit in Figure 43 operates without external power. The voltage source V+ is provided by a step-up voltage regulator that obtains an input voltage from capacitor C2 via an LC filter consisting of an inductor L1 and a capacitor C1. Capacitor C2 is charged when switch SW3 is switched to position A. Once the capacitor is fully charged, the controller switches SW3 to position B, and the voltage regulator draws energy from C2 to provide energy for the heating process. Once the voltage across C2 drops to a certain level that can no longer sustain the operation of the voltage regulator, SW3 is switched to position A, and C2 is fully charged again. This process is repeated until the controller detects that the battery temperature has exceeded a certain value. This process is repeated until the controller detects that the battery temperature has exceeded a predetermined threshold for direct self-powering. As described above with respect to the embodiment shown in Figure 42, the battery can be used to directly supply power to the heating circuit.

[0136] As will be recognized by those skilled in the art, in most applications, batteries and supercapacitors are housed in a closed environment, such as a battery pack. In some applications, such as a lead-acid battery case, the battery may not be housed in a relatively closed enclosure. In all of these applications, when a battery or supercapacitor is heated using one of the embodiments of the present invention, the temperature measured by a sensor attached to the outer surface of the battery or supercapacitor is generally lower than the temperature of the battery and supercapacitor core. In all of these applications, a thermal model of the battery or supercapacitor core, its housing (including the insulating layer and / or paint), and other coating layers can be used to predict the core temperature by measuring the temperature of the outer surface of the battery and supercapacitor. In these models, the amount of input heating energy and the measured outer surface temperature as a function of time, along with the initial temperature of the battery (usually the same as the temperature measured on the battery surface), are used to predict the core temperature of the battery or supercapacitor. As will also be recognized by those skilled in the art, such models can be readily programmed within the processor of the controller of various embodiments of the present invention.

[0137] Several methods and related circuits for generating high-frequency currents to directly heat the cores of batteries and supercapacitors have been described. However, it is highly desirable that the device used to pass a high-frequency current through a battery be able to automatically maintain the symmetry of the high-frequency current while having no DC component or having a DC component that is negligibly small. Thus, such low-temperature direct heating devices for batteries and supercapacitors can be used for any voltage and internal impedance that fluctuates with temperature, and moreover, the user, or a separate circuit element with a sensing device, does not need to perform the task of making the necessary adjustments to achieve the required, negligibly small DC component of the high-frequency heating current passed through the battery or supercapacitor.

[0138] The methods to be disclosed are described herein by an example of one of their possible circuit designs. As will be apparent to those skilled in the art, the described methods may be implemented using other similar circuit designs.

[0139] Figure 44 illustrates a block diagram of one embodiment of such a direct battery heating system. The heating system in Figure 44 consists of a "heating engine" 501, which carries an oscillating current 502 through a battery 503. The "heating engine" is powered by a bipolar high-current source 504, for example, a source providing 50-150 amps. A "slave" microcontroller 505 is programmed to provide voltage pulses for alternating operation of the "heating engine" 501, such as a push-pull MOSFET switch, an example of which is shown in Figure 45 and described further in this disclosure. The "slave" microcontroller 505 is made available by a "master" microcontroller 506, which utilizes a sensing input 507 from the battery to provide digital control of the "heating engine" 501. The functions of the "master" and "slave" microcontrollers may be performed by a single microcontroller.

[0140] Typically, one or more temperature sensors 508, such as NTC thermistors, monitor the battery temperature. A current sensor 509 may be provided to measure the RMS value of the heating current. A heating cycle is initiated whenever the battery temperature drops below a desired operating temperature and disabled whenever the battery temperature exceeds a set upper limit. Normal operation of the heating system maintains the battery temperature within the desired limits.

[0141] It is recognized that potentially dangerous conditions may be detected, such as the battery temperature exceeding a certain preset threshold due to unpredictable events. In addition to the normal control of the "heating engine," a software-generated signal may be provided to disable the "heating engine" whenever the measured temperature falls outside the normal operating range, or whenever a command is received from some external source (not shown). The system may be programmed to automatically recover when the temperature drops below the dangerous condition. However, in the event of a software failure, a hardware shutdown circuit 510 may be provided to detect when the temperature exceeds a preset threshold and to disable the high-current power supply. The "heating engine" remains in the off position until the system is restarted.

[0142] Figure 45 illustrates the operation of the "heating engine" 501, which consists of a gate driver module 511, a voltage-controlled toggle switch 512 (e.g., a solid-state relay), multiple N-type MOSFETs 513 arranged in parallel, multiple P-type MOSFETs 514 arranged in parallel, and multiple capacitors 515 arranged in parallel. The circuit operation is independent of the battery voltage and chemical properties. The slave microcontroller 505 in Figure 44 generates a control waveform 516 for the N-MOSFET 513 bank and a control waveform 517 for the P-MOSFET 514 bank. Control waveforms 516 and 517 are converted into positive gate-source voltage requirements 518 and negative gate-source voltage requirements 519 for the N-type MOSFETs 513 and P-type MOSFETs 514, respectively. These switching pulses are passed to the respective gate terminals 520 and 521. The N-type MOSFET 513 provides current flow into the positive terminal of the battery. While the P-type MOSFET 514 is conducting (on), current flows out from the positive terminal. Figure 46 illustrates typical switching waveforms 516 and 517 and the battery current waveform 521. Furthermore, an important and innovative feature of the heating cycle is the off period 523 when both channel MOSFETs are in off mode. This added feature eliminates a potentially dangerous condition that forces both the P-type and N-type MOSFETs to be on simultaneously.

[0143] Referring to Figure 45, the parallel bank of capacitors 515 offers a clear functional advantage to the heating system. Without the capacitor bank, the positive and negative supply voltages must be adjusted independently to obtain a symmetric heating current flow through the battery. Subsequently, the power supply voltage requirement becomes dependent on the battery open-circuit voltage, significantly complicating the design of the heating system. However, using the novel design, as illustrated in Figure 48 and expressed in equation (4), and described in detail thereafter in this disclosure, by including the capacitor bank 515, a symmetric current flow through any battery is promised by this design, as described below. Using this novel design, the disclosed “heating engine” can be used to heat a single cell or cell pack of various battery chemical properties, such as lead acid, Li ions, and Li polymers.

[0144] Another important consideration for disclosed high-frequency direct heating of batteries and supercapacitors is the efficiency of the heating circuit. Poor efficiency, in other words, is the generation of excess heat by the electronic components, requiring means to transport and dissipate a significant amount of heat from the circuit components.

[0145] The heating efficiency of the circuit is given by the ratio of the effective battery resistance to the total resistance of the circuit at the operating frequency.

number

[0146] The efficiency calculations above are based on conduction losses, but it should be noted that at higher operating frequencies (on the order of MHz), switching losses also become higher.

[0147] Figure 47 shows a schematic diagram of one possible implementation of the hardware shutdown circuit 510 in Figure 44, which is designed to cut off power to the “heating engine” 501 in Figure 44 when it is detected that the temperature is higher than a preset temperature threshold. The output 524 from the battery temperature sensor is compared to setpoint 525 for this condition. The output of comparator 526 is switched to a high level, indicating that it has been detected that the temperature is higher than the preset condition. Two AND gates 527 and 528 generate outputs 529 and 530 according to truth table 531. The two outputs 529 and 530 drive an exclusive OR gate 532, which generates a logic low at output 533 for normal operation. The hardware shutdown circuit ensures that the “heating engine” is powered only when it is false that the temperature is higher than the preset temperature signal. It should be recognized that the hardware shutdown circuit 510 may be implemented by a circuit designed to have or not have a programmable microprocessor.

[0148] The operation of the "heating engine" 501 (Figure 44) can be analyzed in three distinct time domains: 1) when the N-type MOSFET is on and the P-type MOSFET is off (positive current); 2) when both MOSFETs are off; and 3) when the N-type MOSFET is off and the P-type MOSFET is on (negative current). The operation in domains (1) and (3) is similar except that the current polarity is reversed. Therefore, the analysis can be performed in either domain (1) or (3). During the positive cycle, the N-type MOSFET has an equivalent resistance R ON It is ON. Referring to Figure 45, the current i(t) that flows through the battery during conduction time T is,

number

[0149] Figure 48 shows R=50mΩ, C=2mF, and V sFigure 48 shows the complete current waveform 534 over one cycle at ±3.3V. T is the on-time for both MOSFETs, and τ=RC is the time constant of the heating circuit. The transition between positive and negative current flows is separated by the off-state 535 of both MOSFETs. Figure 48 shows the current waveforms for three conditions, namely: 1) the dashed line 536 is the response when τ=0.1T (R=50mΩ, C=0.2mF); 2) the solid line 534 is the response when τ=T (R=50mΩ, C=2mF); and 3) the dashed line 537 is the response when τ=10T (R=50mΩ, C=20mF). It should be noted that although the shape of the response differs for these three conditions, the average current through the battery is zero. From a practical standpoint, it is desirable to operate the heating engine around the last condition, τ=10T.

[0150] Figure 49 shows the actual measured current response during heating of a 12V Type 31 lead-acid battery 538, commonly used in trucks. A peak current of 70A was measured in this circuit.

[0151] The above description of the heating system has focused solely on rechargeable batteries for convenience. It should be recognized that the same heating system can be used to heat charged or uncharged supercapacitors, and all primary batteries, including liquid storage batteries and thermal storage batteries, at low temperatures.

[0152] Figure 50 illustrates a circuit diagram of a first embodiment of the high-efficiency self-heating device of the present invention. This device is designed to maintain a battery at a desired operating temperature when the ambient temperature drops by a predetermined amount below the desired operating temperature.

[0153] As can be seen in Figure 50, the battery (providing voltage VB) is arranged in series with an external capacitor C and an inductor L to form a series resonant circuit, loop "A". In the circuit of Figure 50, resistor RB indicates the internal resistance of the battery to high-frequency current, as previously described for high-frequency heating of batteries and supercapacitors. With switch S2 open, switch S1 is suddenly closed. The resonant circuit of loop "A" then passes an oscillating current through the battery resistor at the resonant frequency of the circuit, thereby heating the battery core, mainly by heating its electrolyte, as previously described for the embodiments of high-frequency battery heating. The amplitude of the oscillating current gradually decreases as the oscillating energy is converted into heat and as the resonant circuit reaches a steady-state condition where the heating current becomes zero as the capacitor is charged to the battery potential. At this time, switch S1 is opened and switch S2 is closed. The electrical energy stored in capacitor C is discharged to ground. Next, switch S2 is opened, and the heating cycle is repeated as needed until a predetermined battery temperature is reached.

[0154] The steady-state time constant of the circuit is the effective series resistance of the battery (R hereafter). tot It is a function of (shown as) and all other resistances arising from the reactive component and other parasitic resistances (which are expected to be significantly lower than RB in a properly designed circuit and are therefore not shown in Figure 50). The peak current and resonant frequency of the loop "A" circuit are a function of the on-switching time of switch S1 and C, L, and R tot It is determined by the value and .

[0155] Figure 51 shows a block diagram of such a high-efficiency self-heating device for batteries and supercapacitors. The elements in box 539, indicated by the dashed line, represent the battery and its series internal resistance to high-frequency current. The battery is shown to be equipped with a temperature sensor (a thermistor in Figure 51), whose output provides a means for the microcontroller to initiate a heating cycle as described above when the battery temperature drops below a preset temperature level, and to stop the heating process when the battery reaches a preset upper temperature. The switching network block in Figure 51 represents the components of switches S1 and S2 in Figure 50, which are operated by the device microcontroller.

[0156] Figure 52 shows one implementation of a block diagram of a high-efficiency self-heating device for a battery and supercapacitor shown in Figure 51, as used for self-heating of a battery, indicated by a dashed box 540. In box 540, VB indicates the battery as a voltage source with an internal resistance RB to high-frequency current. The self-heating device is intended to heat the battery in a cold environment to keep it within a predetermined temperature range defined as an upper and lower temperature limit. As described for the circuit in Figure 51, the battery is provided with a temperature sensor 541 that measures the battery temperature using a "temperature sensor circuit," which provides a measured temperature signal 542 to the device microcontroller. A series resonant circuit is formed by the battery's internal resistance RB to high-frequency current, an external inductor L, and a capacitor C. The battery 540 powers the microcontroller and the temperature sensor circuit.

[0157] In the embodiment of the battery self-heating device shown in Figure 52, the temperature sensor circuit generates a controller signal 542 for starting and stopping the self-heating cycle by comparing the measured temperature with the desired operating temperature range. When the battery is to be heated, the microcontroller generates a control signal V for switches S1 and S2. s1 and V s2The toggling heating cycle is initiated by generating each of the following. The switching function is achieved by using N-MOSFETs S1 and S2, etc. Resistors R1 and R2 are used for the proper action of the N-MOSFET switches. When a heating request is received from the temperature sensor circuit, that is, when the measured temperature falls below a set threshold, the microcontroller sends a control signal V S1 Send the signal to turn on (close) switch S1, and the control signal V S2 The switch S2 is turned off (opened) by sending a signal. Using this configuration of the switch, the battery 540 and the series combination of components RB, L, and C form a series resonant circuit under a forced response and operate in an attenuated state. The flow of high-frequency sinusoidal current through the series RB, L, and C resonant circuit, in particular through the internal resistance RB, results in the generation of heat within the battery core, as described in the embodiment of high-frequency battery heating, thereby raising the battery core temperature. Once capacitor C is charged to near the battery voltage VB, switch S2 is closed and switch S1 is opened. The charge collected in capacitor C1 is discharged to ground, and the heating cycle is repeated. Next, as the battery core temperature rises to the upper limit temperature set for the battery, the temperature sensor circuit sends a control signal 542 to the microcontroller to stop the heating cycle. In summary, the self-heating cycle consists of a series of controlled switching (toggle) cycles, which include closing switch S1 and opening switch S2 during resonant charging of capacitor C, and rapidly discharging capacitor C by instantaneously closing switch S2 and opening switch S1. The switching sequence is repeated until the battery core reaches a predetermined temperature, typically at or near a predetermined upper temperature limit.

[0158] The heating efficiency η of the self-heating device circuit in Figure 52 is the ratio of the effective battery resistance RB at the (high-frequency) resonant frequency (loop "A" in Figure 50) to the total resistance of the circuit (not shown in Figures 50-52), i.e.,

number

[0159] As an example, the heating efficiency of the self-heating device embodiment shown in Figure 52 was used for a lithium-ion cell (model LGABB418650) placed in an environmental chamber set to lower its temperature from 20°C to -40°C. The cell was wrapped in a 1 mm thick battery insulation layer. The cell temperature was set to be maintained between 20°C and 25°C.

[0160] In the embodiment of the self-heating device shown in Figure 52, a switching frequency of 2 kHz was used for switch S2, and the discharge pulse width was 100 μs. Instantaneous voltage and instantaneous current measurements were used to estimate the total resistance of the circuit during the heating cycle. In this example, the resistance is R. L =7mΩ, and R C = 4mΩ, and using the RMS values ​​of the voltage and current waveforms, the resistor R tot The peak value was calculated to be 169 mΩ. These parameters result in a circuit heating efficiency of 93%, which includes capacitor discharge losses.

[0161] At the end of each 500 μs (2 kHz) resonant heating cycle, the stored energy in the capacitor is dissipated through a short circuit over 100 μs. In the above test example, the stored energy in the capacitor was 0.68 mJ after 400 μs of heating. During the heating time, the battery supplied a total of 34.8 mJ. This means that at the end of the heating pulse, approximately 2% of the supplied energy is stored in the capacitor.

[0162] Figure 53 shows a plot of the temperature 545 of the environmental chamber in which the battery in this example is placed, as a function of time. set This is indicated by a dashed line. The measured temperatures of the battery are also shown in the self-heating section 543 and the cooling section 544 (when the self-heating device is turned off). Plot 546 is an oscilloscope image of the actual, measured high-frequency current passed through the battery, i.e., the current heating the battery core, against the battery high-frequency resistance RB.

[0163] In the embodiments of the self-heating device shown in Figures 50-52, the stored energy in capacitor C is lost, thereby reducing the aforementioned circuit heating efficiency from 93% to approximately 91%. However, the electrical energy stored in capacitor C can be used to supplement the heating of a battery, in particular most lithium-ion batteries or lithium-polymer batteries, etc., in which several cells are connected in series, parallel, or a combination thereof to obtain a desired battery voltage or operating current. As will be recognized to those skilled in the art, in such a battery, a temperature sensor is placed between the battery packs for measuring the battery temperature for thermal control purposes or for battery heating purposes, using one of the disclosed embodiments of the present invention, including the embodiments of the self-heating device shown in Figures 50-52.

[0164] It is recognized that the battery cells within a battery pack are never strictly identical, and therefore, they generally need to be monitored individually (or in pairs or in a particular configuration) for thermal control purposes, in addition to heating, using one of the disclosed embodiments of the present invention, including the self-heating device embodiments shown in Figures 50-52. For this reason, once the switch S2 is closed, the charge accumulated in capacitor C is monitored by a resistor R provided, as shown in Figure 54. H It can be dissipated within. The circuit in Figure 54 has a resistor R H The circuit is identical to that in Figure 52 except for the addition of a resistor R, and operates in the same way as the embodiment in Figure 52, as previously described, with the only difference being that the electrical energy stored in capacitor C during each battery heating cycle is instead wasted by a resistor R placed between the battery cells of the battery pack. H This is the point used for heating. The heat generated is then used to heat the battery (even from its outer shell). As is recognized, generally thin and flat resistors (similar in thickness to the temperature sensor used) are used, but resistor R H It is preferable to use it for this purpose, so as not to increase the total volume of the battery pack. In the above embodiment of the self-heating device of the present invention, the high-frequency heating current applied to the battery is generated by the described switching circuit, which is powered by the battery. In subsequent embodiments of the present invention, a novel method is described that can be used to design a self-heating device for almost all batteries, such as Li-ion, Li-polymer, lead-acid, NiMH, and other primary batteries and rechargeable batteries. The resulting self-heating device has a simpler design, significantly fewer components, and can efficiently heat the battery core while minimizing electrical energy loss.

[0165] Figure 55 shows a circuit diagram of such a self-heating device, which has a significantly simplified design and consists of fewer elements. This self-heating device is designed to maintain the battery core operating temperature near a predetermined temperature in a low-temperature environment using battery power. In the circuit diagram of Figure 54, the battery 601 (as shown within the dashed rectangle) has an open-circuit voltage V B , internal resistance 603(R B ) and internal inductance 604(L B It is embodied as an ideal voltage source 602 having ). The self-heating circuit is started by a control signal 605, which is generated by the temperature sensor circuit 606 when the measurement of the temperature sensor 607 is below a set operating temperature. The heating circuit is shut off when the measured temperature exceeds the set operating temperature. The illustrated self-heating circuit has three operating stages, which are described with reference to Figures 55 to 59. Signal 605 initiates the execution of a programmed sequence of timing waveforms that control the operation of electronic switches 608 (S1) and 609 (S2). Signal 610 controls the opening and closing of electronic switch 608, and signal 611 controls the opening of electronic switch 609. The correct timing of these control signals is essential for the proper operation of the battery self-heating system. The microcontroller 612 processes the heat on / off signal 605 to generate timing waveforms for electronic switches 608 and 609. The self-heating system is designed to operate autonomously without requiring any external power supply or external control signals. Furthermore, the self-heating system can provide heat to the battery while the vehicle engine and / or other electrical and electronic equipment are operating, while it is installed in the vehicle.

[0166] The self-heating circuit in Figure 54 generates heat in the battery core by a high-frequency oscillating current flowing through a forced series resonant circuit. The forced series resonant circuit consists of a battery voltage source 602 and an internal resistance 603(R B ), internal inductance 604(L BThe circuit is formed by the battery and an external capacitor 613(C). At the start of the heating cycle, switch 608 is opened and switch 609 is momentarily closed to discharge capacitor 613. The heating stage is started by opening switch 609 and closing switch 608. The resonant heating described below continues until capacitor 613 is charged to the battery open-circuit voltage, at which point the current i1 becomes zero and heating stops. The duration of heating is determined by the component values. For example, plot (a) in Figure 56 shows the predicted current waveform 614 flowing through the series resonant circuit, and plot (b) in Figure 56 shows the voltage waveform 615. These plots are R B =2mΩ, L B This is generated for a 12V lead-acid battery with a current of 7mH and a capacitance of 226μF. After several oscillations, the current (i1) becomes zero, indicating that the capacitor has been fully charged to a voltage level of 616, depending on the open-circuit voltage of the battery. Referring to Figure 55, continuous heating of the battery is achieved by opening switch 608 and resistor shunt 617(R d It is recognized that this requires the discharge of capacitor 613, which can be achieved by closing switch 609 via ). However, this method of removing stored energy from capacitor 613 is wasteful, causing about 50% of the battery energy to dissipate into the environment as heat. A relatively small portion of the electrical energy stored in capacitor 613 can be recovered by mounting a shunt resistor 617 in the battery body to transfer heat to the core region through the case. However, the majority of the electrical energy stored in capacitor 613 can be used to generate another battery heating cycle after each of the aforementioned heating cycles, in which case the method and circuit design described in the following embodiments of the present invention, shown in Figure 57, is used.

[0167] The embodiment of the battery self-heating circuit in Figure 57 is the same as the embodiment of the battery self-heating circuit in Figure 55, but with the resistor 617(R dThe difference lies in the fact that the ) is replaced by inductor 640(L). The embodiment of the battery self-heating circuit in Figure 57 also operates with significantly higher efficiency, i.e., a significantly larger portion of the battery power is used by the self-heating circuit to heat the battery core, as described below. Referring to Figure 57, the battery self-heating circuit, while switch 609 (S2) is closed, following the closing of switch 608 (S1), the capacitor 613 (C) is heated to substantially the battery voltage level V B The device operates as described in the embodiment of Figure 55 until it is fully charged. In the embodiment of Figure 57, the electrical energy stored in capacitor 613(C) is then recovered by closing switch 609 and opening switch 608 using a tank circuit formed by inductor 640(L) and capacitor 613(C). In the case of an ideal capacitor and inductor, once switch 609(S2) is closed, the energy stored in capacitor 613(C) oscillates between the capacitor and the inductor (Figure 57). Figure 58(a) shows a plot of the current waveform 618(i2) flowing through the LC tank circuit, and Figure 58(b) shows a plot of the inductor voltage waveform 619(v2). Referring to Figure 58(a), time position 620(P) indicates the fully charged state of capacitor 613(C), indicated by current i2=0 and the maximum voltage v2 at point 621(P) in Figure 58(b). As voltage 619 decreases from its maximum value at 621(P) in Figure 58(b), current 618(i2) increases. The maximum current point 622(Q) indicates that all the energy from capacitor 613(C) has been transferred to inductor 640(L). At point 622(Q), the voltage across the inductor 623 is zero. At this time mark (622 and 623 in Figures 58(a) and (b), respectively), the capacitor energy has been fully transferred to the inductor 640(L) in Figure 57. Subsequently, the energy in the inductor is returned to the capacitor until point R (time marks 625 and 624 in Figures 58(a) and (b), respectively). However, it should be noted that the voltage across the capacitor undergoes a polarity reversal. At the start of the cycle, the voltage at point 621(P) is positive, and at point 624(R), the polarity is negative. The stored electrical energy returns to the capacitor by resonant transfer. This polarity reversal allows the electrical energy stored in the capacitor to be returned to the battery and used in the next heating cycle. Referring to Figure 58, at time mark (R), switch 609 is opened and switch 608 is closed, as shown in Figure 57, initiating a second heating cycle as illustrated in Figure 59. These current waveforms 626 and voltage waveforms 627 are similar to those in Figure 56, except that the current and voltage peaks are significantly increased. Point 628(S) indicates a polarity reversal of the voltage across the capacitor. Following the battery heating cycle in Figure 56, the battery heating cycle in Figure 59 continues until a heating stop control signal is received from the temperature sensor control circuit 606 in Figure 57.

[0168] Figure 60 illustrates the combined current and voltage waveforms between both phases of the entire battery heating cycle, i.e., the initial heating cycle while capacitor 613(C) is being charged in Figure 57, and the subsequent use of the electrical energy stored in the capacitor to heat the battery core, as described above. During the first stages 629 and 630 (Figures 60(a) and (b) respectively), capacitor 613(C) has no initial energy, and the voltage and current waveforms have lower peak values. Energy transfer stages 631 and 632 (Figures 60(a) and (b) respectively) require precise timing requirements at points 633 and 634 (Figures 60(a) and (b) respectively) and points 635 and 636 (Figures 60(a) and (b) respectively). The second heating resonance stages 637 and 638 (Figures 60(a) and (b) respectively) have higher peak currents and voltages. However, the subsequent heating cycles will all be identical. As will be apparent to those skilled in the art, switches 608 and 609 in Figures 55 and 57 are electronic, voltage-controlled single-throw switches, such as N-MOSFETs. As a practical way to increase heating efficiency, it is important to select elements with low series resistance, typically less than 1 mW. Even lower resistance values ​​can be achieved by using multiple switches in a parallel configuration. As will be apparent to those skilled in the art, the internal resistance and inductance of a battery typically fluctuate with temperature, and even between different batteries within the same battery set. Therefore, self-heating may comprise a microprocessor with various battery parameters and means for measuring these parameters while connected to the battery. Furthermore, as described above for embodiments in Figures 55 and 57, the device settings may be modified to ensure a proper battery self-heating process. As an example, a block diagram of such an addition to the self-heating method and an example of an embodiment of the device is provided in Figure 61.

[0169] Figure 61 illustrates an operational flowchart relating to the self-heating embodiment of Figure 57 (and similarly applies to the embodiment in Figure 55). The first step 700 enables the self-heating circuit. The enabled function may be a physical toggle switch or a digital signal applied directly to the microcontroller 701. The microcontroller 701 starts the self-heating circuit 702 (the embodiment in Figure 57 of 55) for a short enough time to capture the voltage and current waveforms described above, which drive the battery heating. Referring to Figures 55 (or 57) and 56, the current waveform 614 and voltage waveform 615 are captured and compared with data held in the microcontroller's memory to determine battery parameters such as the series resistance 603 and inductance 604 of the battery. These, along with the capacitor 113, determine the optimal current waveform 114 for efficient self-heating. The capacitor 613 typically consists of multiple parallel capacitors, which, when combined, give the desired capacitor value. Even within the same family, to adapt to variations between different batteries, for example, in a Type 31 track battery, each capacitor shunting in a large number of parallel capacitors has its own electronic toggle switch, which can be used by a control signal from the microcontroller 701. This switching capability allows the measured battery parameters 703 to make the correct number of capacitors available and give the capacitor 613 the desired net capacitance value. Similarly, the inductor 640 in Figure 57, which is essential for recovering the energy stored in capacitor C as described above, may also require some adjustment. For this reason, inductor 640 may be constructed from an electronically available bank of shunting inductors, thereby providing the desired value determined from the measured voltage waveforms performed. By correctly selecting the inductor, a match with the critical switching point 624, shown in Figure 58, can be achieved. After the circuit is thus adjusted, the self-heating circuit is ready to operate as required. Before activating the self-heating circuit, the remaining battery capacity may be measured by the battery capacity sensor 704. The battery capacity is measured using an established method based on conductance. If the measured battery capacity 705 is lower than a predetermined minimum, the circuit stops operating and issues a warning 706. Otherwise, the circuit heating flag 707 is set to high, enabling the normal heating function. This is driven by the output of the temperature sensor 708, which is processed via the microcontroller 701. Before issuing the heating on signal 609, the microcontroller performs a battery capacity test. The circuit continues heating until the measured temperature exceeds the setpoint. The heating off signal 710 stops the heating operation. The self-heating circuit described above maintains the battery core temperature at the desired temperature and stops functioning if the battery capacity falls below the setpoint or if the available function at the start of the battery heating operation is toggled to the off position.

[0170] While preferred embodiments of this invention have been shown and described, it will naturally be understood that various modifications and alterations to the shape or details can be easily made without departing from the spirit of this invention. Therefore, this invention is not intended to be limited to the exact form described and illustrated, but rather should be constructed to encompass all modifications that may fall within the scope of the accompanying claims.

Claims

1. A heating circuit for generating heat when coupled with an energy storage device having a core having an electrolyte, wherein the energy storage device has an input and an internal surface capacitance between the inputs that can store electric field energy between the internal electrodes of the energy storage device coupled to the input, and one of the internal electrodes is coupled to a first input of the inputs having the characteristics of a resistor and an inductor coupled in series with a voltage source, wherein the heating circuit is At least one power supply that can be coupled to the first input of the energy storage device, wherein when the at least one power supply is coupled to the first input of the input, it is configured to provide a positive input current and a negative input current to the first input of the input, the positive input current flows into the first input of the input, and the negative input current flows out from the first input of the input, The controller comprises hardware configured to control the at least one power supply to supply alternating current in a stepwise manner between a positive input current and a negative input current at the first input of the inputs, wherein between the positive input current and the negative input current there is a step in which neither a positive nor a negative input current is provided, the step occurring multiple times, with multiple positive current transitions and multiple negative current transitions between each step, and the controller is configured to control the at least one power supply to provide alternating positive and negative input currents at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device, thereby generating heat and raising the temperature of the electrolyte, A heating circuit equipped with this.

2. The controller is configured to control at least one power supply to stop the alternating positive and negative input currents when the temperature of the electrolyte and / or the energy storage device is within the operating temperature range of the energy storage device. The heating circuit described in claim 1.

3. The heating circuit according to claim 1, wherein when the temperature of the electrolyte and / or the energy storage device is lower than the operating temperature range of the energy storage device, the controller is configured to start the at least one power supply to provide the alternating positive input current and negative input current at the first input of the inputs.

4. The heating circuit according to claim 1, further comprising a temperature sensor configured to provide a signal to the controller, the signal being based on a detected temperature of the electrolyte and / or surface of the energy storage device, and the controller being configured to start and stop the at least one power supply in response to the signal to provide the alternatingly repeating positive and negative input currents at the first input of the inputs.

5. A heating circuit according to claim 1, comprising a switch formed from a plurality of first parallel-connected field-effect transistors (FETs), wherein the plurality of first parallel-connected FETs are connected in parallel with one another, and comprising components configured such that the at least one power supply is charged by the energy storage device via the operation of the resistor and inductor of the energy storage device and the switch, wherein the inductor and the components are configured to operate as a series resonant circuit having the voltage source through the operation of the switch, and the controller is configured to control the switch to start and stop heating the electrolyte.

6. The heating circuit according to claim 5, wherein the switch is a first switch, the heating circuit comprises a second switch formed from a plurality of second parallel-connected FETs and connected to a component, the plurality of second parallel-connected FETs are connected in parallel, the second switch is configured to start the discharge of the component, and the controller is configured to control the second switch to start and stop the discharge of the component, the plurality of first FETs are a first type of FET, and the plurality of second FETs are a second type of FET different from the first type of FET.

7. The heating circuit according to claim 6, comprising a plurality of capacitors arranged in parallel with each other, wherein the alternating inputs of a positive input current and a negative input current can be coupled to the first input among the inputs via the plurality of capacitors.

8. The heating circuit according to claim 6, wherein the controller is configured to control the first switch to stop charging the component when the component is charged to the potential of the voltage source, and then to control the second switch to start discharging the component.

9. The heating circuit according to claim 6, wherein the resistor of the energy storage device is a first resistor, the heating circuit comprises a second resistor coupled between the second switch and the component, and the heating circuit is configured such that when the second switch is controlled and discharge of the component begins, the discharge occurs via the second resistor.

10. The heating circuit according to claim 9, wherein the second resistor is configured to be located in close proximity to the energy storage device so that the heat generated by the second resistor heats the energy storage device during the discharge of the components through the second resistor.

11. The heating circuit according to claim 6, wherein the inductor of the energy storage device is a first inductor, the heating circuit comprises a second inductor coupled between the second switch and the component, and the heating circuit is configured such that when the second switch is controlled and the discharge of the component begins, the discharge transmits charge to the second inductor.

12. A first switch comprising a component configured such that at least one power source is charged by an energy storage device via a resistor and inductor of the energy storage device, wherein the inductor and the component are configured to operate as a series resonant circuit with the voltage source via operation of the first switch, and the controller is configured to control the first switch to start and stop heating of the electrolyte, The system comprises a second switch coupled to the aforementioned component, the second switch being configured to initiate the discharge of the component, and the controller being configured to control the second switch to initiate and stop the discharge of the component, The heating circuit according to claim 11, wherein at least one of the first switch and the second switch comprises a plurality of transistors, and the plurality of transistors are arranged in a parallel configuration with respect to each other.

13. The heating circuit according to claim 11, wherein the controller is configured to control the discharge of the component by closing the second switch, and is configured to open the second switch when the charge from the component is transmitted to the second inductor, and the charge from the second inductor is transmitted back to the component by resonant transfer.

14. The heating circuit according to claim 6, wherein the controller is configured to close the first switch to capture information indicating the voltage waveform and current waveform of the energy storage device, and the controller is configured to determine at least one of the resistance of the resistor and the inductance of the inductor from the captured information.

15. The heating circuit according to claim 14, wherein the controller is configured to adjust the capacitance of the component based on at least one of the determined resistance and inductance.

16. The heating circuit according to claim 14, wherein the inductor of the energy storage device is a first inductor, and the heating circuit comprises a second inductor coupled between the second switch and the component, and when the second switch is coupled to control the discharge of the component, the discharge transfers charge to the second inductor, and the controller is configured to adjust the inductance of the second inductor based on at least one of the determined resistance and inductance.

17. The heating circuit according to claim 1, comprising a capacity sensor configured to provide a capacity indication of the energy storage device, wherein the controller is configured to enable and disable heating based on the indication of the capacity.

18. The heating circuit according to claim 17, wherein when heating is available, the controller is configured to start the at least one power supply according to a predetermined temperature lower than the operating temperature range of the energy storage device, to provide the alternating positive input current and negative input current at the first input of the inputs.

19. A heating circuit for generating heat when coupled with an energy storage device having a core having an electrolyte, wherein the energy storage device has an input and an internal surface capacitance between the inputs that can store electric field energy between the internal electrodes of the energy storage device coupled to the input, and one of the internal electrodes is coupled to the first input of the inputs having the characteristics of a resistor and a first inductor coupled in series with a voltage source, wherein the heating circuit is A power supply capable of being coupled to a first input of an energy storage device, wherein the power supply, when coupled to the first input, is configured to provide a positive input current and a negative input current to the first input, the positive input current flowing into the first input and the negative input current flowing out of the first input, and A controller configured to periodically acquire a measurement value correlated with the temperature of the electrolyte, wherein the controller controls the at least one power supply to provide alternating positive and negative input currents provided at one of the inputs at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device when the measurement value indicates that the temperature of the electrolyte is below the operating temperature of the energy storage device, thereby generating heat and raising the temperature of the electrolyte, A first switch comprising a component configured such that at least one power source is charged by an energy storage device via a resistor and inductor of the energy storage device, wherein the inductor and the component are configured to operate as a series resonant circuit with the voltage source via operation of the first switch, and the controller is configured to control the first switch to start and stop heating of the electrolyte, The system comprises a second switch coupled to the aforementioned component, the second switch being configured to initiate the discharge of the component, and the controller being configured to control the second switch to initiate and stop the discharge of the component, The controller is configured to close the first switch and acquire information indicating the voltage and current waveforms of the energy storage device, and the controller is configured to determine at least one of the resistance of the resistor and the inductance of the inductor from the acquired information, and A second inductor coupled between the second switch and the component, wherein when the second switch is coupled, it controls the discharge of the component so that charge is transferred to the second inductor by the discharge, and the controller is configured to adjust the inductance of the second inductor based on at least one of the determined resistance and inductance of the first inductor. heating circuit.

20. The heating circuit according to claim 19, wherein the controller is configured to discontinue the alternating positive and negative input currents when the temperature of the electrolyte and / or the energy storage device is within the operating temperature range of the energy storage device.

21. The heating circuit according to claim 19, wherein when a rechargeable component is charged to the voltage of the voltage source as a result of the alternatingly repeated positive and negative input currents, the controller is configured to control the discharge of the rechargeable component.

22. A heating circuit that generates heat when coupled to an energy storage device having an electrolyte core, wherein the energy storage device has an input and an internal surface capacitance between the inputs that can store electric field energy between the internal electrodes of the energy storage device coupled to the input, and one of the internal electrodes coupled to a first input of the input has the characteristics of a resistor and an inductor coupled in series with a voltage source, and the heating circuit, At least one power supply capable of being coupled to a first input of the inputs of the energy storage device, wherein when the at least one power supply is coupled to the first input of the inputs, it is configured to provide a positive input current and a negative input current to the first input of the inputs, the positive input current flows into the first input of the inputs, and the negative input current flows out from the first input of the inputs, A controller is configured to control the at least one power supply and provide alternating positive and negative input currents at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device, thereby generating heat and raising the temperature of the electrolyte. A switch comprising a component configured such that at least one power supply is charged by the energy storage device via the resistor and inductor of the energy storage device by the operation of the switch, The controller is configured to close the switch and acquire information indicating the voltage and current waveforms of the energy storage device, and the controller is configured to determine at least one of the resistance of the resistor and the inductance of the inductor from the acquired information. The controller is configured to adjust the capacitance of the component based on at least one of the determined resistance and inductance. heating circuit.

23. A heating circuit that generates heat when coupled to an energy storage device having an electrolyte core, wherein the energy storage device has an input and an internal surface capacitance between the inputs that can store electric field energy between the internal electrodes of the energy storage device coupled to the input, and one of the internal electrodes coupled to a first input of the input has the characteristics of a resistor and an inductor coupled in series with a voltage source, and the heating circuit, At least one power supply capable of being coupled to a first input of the inputs of the energy storage device, wherein when the at least one power supply is coupled to the first input of the inputs, it is configured to provide a positive input current and a negative input current to the first input of the inputs, the positive input current flows into the first input of the inputs, and the negative input current flows out from the first input of the inputs, A controller comprising hardware, configured to control the at least one power supply to supply an alternating current between the positive input current and the negative input current, wherein the controller is configured to control the at least one power supply to provide alternating positive and negative input currents at a frequency sufficient to effectively short-circuit the internal surface capacitance of the energy storage device, thereby generating heat and raising the temperature of the electrolyte, The heating circuit comprises a first switch and a second switch, and the at least one power supply is configured to be charged by the energy storage device via the operation of the switch, through the resistor and inductor of the energy storage device. The inductor and the components are configured to operate as a series resonant circuit with the voltage source via the operation of the switch. The controller is configured to control the first switch to start and stop heating the electrolyte. The second switch is configured to initiate the discharge of the components, The controller is configured to control the second switch to start and stop the discharge of the components. The controller is configured to close the first switch in order to obtain information indicating the voltage and current waveforms of the energy storage device. The controller is configured to determine at least one of the resistance of the resistor and the inductance of the inductor from the acquired information. Here, The controller is configured to adjust the capacitance of the component based on at least one of the determined resistance and inductance. The inductor of the energy storage device is a first inductor, the heating circuit comprises a second inductor coupled between the second switch and the component, and when the second switch is coupled, controls the discharge of the component, thereby transferring charge to the second inductor, and the controller is configured to adjust the inductance of the second inductor based on at least one of the determined resistance and inductance of the first inductor, heating circuit.

24. The heating circuit according to claim 23, wherein the first switch is formed from a first plurality of parallel-connected field-effect transistors (FETs), and the second switch is formed from a second plurality of parallel-connected FETs coupled to the constituent, wherein the plurality of first FETs are of a first type, and the plurality of second FETs are of a second type different from the first type.

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