Functional liquid carriers, functional sustained-release compositions, and molded articles

Abstract

To provide a functional liquid carrier that can maintain an excellent sustained-release effect for a long time, a functional sustained-release formulation, and a molded article.SOLUTION: A functional liquid carrier includes a porous coordination polymer including an organic ligand and a metal ion, and function sustained-release liquid. The organic ligand includes at least one kind selected from a group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole. If the organic ligand includes the fumaric acid, an amount of free fumaric acid in the porous coordination polymer is 0.7 mass% or less relative to 100 mass% of the porous coordination polymer; if the organic ligand includes the terephthalic acid, an amount of free terephthalic acid in the porous coordination polymer is 0.5 mass% or less relative to 100 mass% of the porous coordination polymer; if the organic ligand includes benzenetricarboxylic acid, an amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6 mass% or less relative to 100 mass% of the porous coordination polymer; and if the organic ligand includes methylimidazole, an amount of free methylimidazole in the porous coordination polymer is 0.7 mass% or less relative to 100 mass% of the porous coordination polymer.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to functional liquid carriers, functional sustained-release compositions, and molded articles. [Background technology]

[0002] In molded bodies containing functional components for small animal control, the duration of effectiveness can be expected to be improved by releasing a predetermined amount of the functional component from the molded body over a long period of time. As a method to enhance the duration of effectiveness of small animal control functional components, molded bodies using small animal control composite materials in which the small animal control functional component is deployed in a matrix resin have been devised (for example, Patent Documents 1 to 4). The molded bodies described in Patent Documents 1 to 4 can maintain the small animal control function on the surface of the molded body that comes into contact with small animals such as pests by gradually releasing the small animal control functional component onto the surface of the molded body (hereinafter referred to as "sustained release"). In order to maintain such sustained release over a long period of time, it is conceivable to increase the amount of functional sustained-release component deployed in the matrix resin. Increasing the amount of functional sustained-release component is also effective from the standpoint of further strengthening the function. [Prior art documents] [Patent Documents]

[0003] [Patent Document 1] Japanese Patent Publication No. 2001-73886 [Patent Document 2] Japanese Patent Publication No. 2000-212005 [Patent Document 3] Japanese Patent Publication No. 2008-206492 [Patent Document 4] Japanese Patent Publication No. 2012-6868 [Overview of the project] [Problems that the invention aims to solve]

[0004] However, porous coordination polymers that retain functional sustained-release components have a problem in that variations occur in the amount of functional sustained-release liquid adsorbed within a lot or between lots during the manufacturing process. Therefore, even if a certain amount of functional sustained-release liquid is blended into a porous coordination polymer for the purpose of expressing function, variations in the amount of functional sustained-release liquid adsorbed by the porous coordination polymer will result in variations in the function of the resulting molded product. Similarly, even if the amount of porous coordination polymer blended is kept constant when manufacturing a molded product, variations in the amount of functional sustained-release liquid adsorbed will result in variations in the function of the molded product.

[0005] Therefore, the object of the present invention is to provide a functional liquid carrier, a functional sustained-release composition, and a molded article that can maintain an excellent sustained-release effect over a long period of time. [Means for solving the problem]

[0006] The present inventors, through diligent research to solve the above problems, have discovered that the above problems can be solved by using a functional liquid support as a functional sustained-release component, which includes a porous coordination polymer having a specific organic ligand and a metal ion, and a specific functional sustained-release liquid, wherein free organic ligands derived from the specific organic ligand are contained in the porous coordination polymer in a specific amount or less. This has led to the completion of the present invention.

[0007] In other words, the present invention includes the following: [1] A porous coordination polymer having an organic ligand and a metal ion, and a functional sustained-release liquid, wherein the organic ligand includes one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, and if the organic ligand includes fumaric acid, the amount of free fumaric acid in the porous coordination polymer is 0.7% by mass or less with respect to 100% by mass of the porous coordination polymer, and if the organic ligand includes terephthalic acid, the amount of free terephthalic acid in the porous coordination polymer is 0.7% by mass or less. A functional liquid carrier wherein the amount of acid is 0.5% by mass or less per 100% by mass of the porous coordination polymer, and if the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6% by mass or less per 100% by mass of the porous coordination polymer, and if the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is 0.7% by mass or less per 100% by mass of the porous coordination polymer.

[0008] [2] The functional liquid carrier according to [1], wherein the metal ion comprises one or more selected from the group consisting of aluminum ions, zirconium ions, chromium ions, copper ions, iron ions, and zinc ions.

[0009] [3] The functional liquid carrier according to [1] or [2], wherein the molecular weight of the functional sustained-release liquid is 600 or less.

[0010] [4] The functional liquid carrier according to any one of [1] to [3], wherein the average pore size of the porous coordination polymer is equal to or greater than the molecular diameter of the functional sustained-release liquid.

[0011] A functional sustained-release composition comprising a functional liquid carrier described in any of [5][1] to [4] and a matrix resin.

[0012] [6] When compressed to 10 MPa or more, the surface concentration of the liquid component is 1.0 mg / cm³. 2 A functional sustained-release composition as described in [5], which is less than [5].

[0013] A molded article comprising the functional sustained-release composition described in [7], [5], or [6]. [Effects of the Invention]

[0014] The present invention aims to provide a functional liquid carrier, a functional sustained-release composition, and a molded article that can maintain an excellent sustained-release effect over a long period of time. [Modes for carrying out the invention]

[0015] Hereinafter, embodiments for carrying out the present invention (hereinafter simply referred to as "this embodiment") will be described with reference to the drawings as necessary. This embodiment is an example for explaining the present invention, and the present invention is not limited to this embodiment.

[0016] [Functional liquid carriers] The functional liquid support of this embodiment comprises a porous coordination polymer having an organic ligand and a metal ion, and a functional sustained-release liquid, wherein the organic ligand includes one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, and when the organic ligand includes fumaric acid, the amount of free fumaric acid in the porous coordination polymer is 0.7% by mass or less per 100% by mass of the porous coordination polymer, and when the organic ligand includes terephthalic acid, the porous coordination The amount of free terephthalic acid in the polymer is 0.5% by mass or less per 100% by mass of the porous coordination polymer. If the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6% by mass or less per 100% by mass of the porous coordination polymer. If the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is 0.7% by mass or less per 100% by mass of the porous coordination polymer.

[0017] Because the functional liquid carrier of this embodiment is configured in this way, the functional sustained-release composition and molded article containing the functional liquid carrier as a functional sustained-release component can maintain an excellent sustained-release effect for a long period of time. For this reason, the functional sustained-release composition of this embodiment offers advantages such as improved product performance and cost reduction through reduced maintenance frequency.

[0018] In this embodiment, the reason why a functional sustained-release composition and molded article containing a functional liquid carrier that can maintain an excellent sustained-release effect over a long period of time is obtained is not clear, but the inventors have the following hypothesis. First, in the porous coordination polymer according to this embodiment, organic ligands are adsorbed onto the surface of the porous coordination polymer even after undergoing the same washing process during its manufacturing. Therefore, free organic ligands that are not bound to metal ions may be present on the surface of the porous coordination polymer. In this case, the free organic ligands block the pores of the porous coordination polymer, which is thought to reduce the adsorption capacity of the functional sustained-release liquid to the porous coordination polymer, and consequently, reduce the amount of functional sustained-release liquid adsorbed. When the amount of functional sustained-release liquid adsorbed by a porous coordination polymer decreases, it becomes necessary to increase the amount of porous coordination polymer blended into the resin composition and molded product to compensate for the reduced adsorption. As a result, the apparent concentration of the porous coordination polymer in the resin composition and molded product increases, leading to an increase in the amount of functional sustained-release liquid released from the molded product, and also an increase in its release rate. Consequently, the sustained-release effect and lifespan of the molded product are significantly reduced. Therefore, in order to maintain a superior sustained-release effect over a long period, it is presumed that the concentration of free substances derived from organic ligands must be kept below a certain level, and that a porous coordination polymer with minimal adhesion of free substances must be used as the functional sustained-release liquid. However, this is not the only reason for this presumption.

[0019] Functional liquid carriers are preferably porous in order to maintain a superior sustained-release effect over a long period of time.

[0020] [Porous coordination polymer] The functional sustained-release support in this embodiment includes a porous coordination polymer. The porous coordination polymer according to this embodiment has an organic ligand and a metal ion.

[0021] Porous coordination polymers, for example, have a form in which metal ions are adsorbed onto organic ligands. Porous coordination polymers are also called MOFs (Metal-Organic Frameworks) or PCPs (Porous Coordination Polymers).

[0022] Porous coordination polymers, for example, have a large number of pores in the macropore or mesopore region, and have a uniform pore diameter because the pore size (diameter of the pore) is determined by the crystal structure.

[0023] Porous coordination polymers can increase the retention capacity of functional sustained-release liquids and enable dense packing by controlling the affinity based on the length and chemical structure of the organic ligands. From a similar viewpoint, it is preferable that the average pore diameter of the porous coordination polymer is greater than or equal to the molecular diameter of the functional sustained-release liquid described later.

[0024] The average pore size of the porous coordination polymer is preferably 0.1 nm to 5.0 nm, and more preferably 0.5 nm to 3.0 nm, from the viewpoint of effectively dispersing the functional sustained-release liquid through the matrix resin and further improving long-term sustained-release properties. In this specification, the average pore size is measured using the MP (micropore analysis) method. Specific measurement methods may be found in the examples.

[0025] The molecular diameter of the functional sustained-release liquid is preferably 0.1 nm or more and 5.0 nm or less, more preferably 0.5 nm or more and 3.0 nm or less, from the viewpoint of enabling effective deployment of the functional sustained-release liquid with the matrix resin and further improving long-term sustained release properties. In this specification, the molecular diameter of the functional sustained-release liquid is determined by the following procedure using the open-source "Mol-view". First, draw the molecule and measure the major axis and minor axis of the molecule within the software. Here, the major axis is the intermolecular distance of the long part when the molecule is stretched linearly, and the minor axis is the intermolecular distance of the short part when the molecule is stretched in the same manner. Here, the above "molecular diameter" corresponds to the minor axis.

[0026] The specific surface area of the porous coordination polymer is 900 m 2 / g or more and 10400 m 2 / g or less, preferably 900 m 2 / g or more and 9000 m 2 / g or less, more preferably 900 m 2 / g or more and 7000 m 2 / g or less, even more preferably 900 m 2 / g or more and 5000 m 2 / g or less, even more preferably. When the specific surface area is 900 m 2 / g or more, the porous coordination polymer tends to be able to effectively deploy the functional sustained-release liquid with the matrix resin as compared with the case of directly kneading the functional sustained-release liquid into the matrix resin to form a composite molded body. In this specification, the specific surface area is measured by the Brunauer-Emmett-Teller method (BET method). For the specific measurement method, reference may be made to the examples.

[0027] Since a sufficient pore volume is required to adsorb the functional sustained-release liquid, the gas adsorption amount of the porous coordination polymer is 50 cm 3 / g or more and 5000 cm 3 / g or less, preferably 100 cm 3 / g or more and 4000 cm 3 / g or less, more preferably 150 cm 3 / g or more and 3000 cm 3It is even more preferable that the amount is less than or equal to / g. In this specification, the amount of gas adsorbed is determined by creating an isothermal adsorption curve and taking the amount of nitrogen adsorbed at 0.99P / P0 on that curve. For specific measurement methods, please refer to the examples.

[0028] From the viewpoint of sustained release in the resin composition and molded article, the content of the porous coordination polymer in the functional sustained-release support is preferably 10 parts by mass or more and 75 parts by mass or less, and more preferably 20 parts by mass or more and 50 parts by mass or less, per 100 parts by mass of the functional sustained-release support.

[0029] (organic ligand) The porous coordination polymer of this embodiment includes an organic ligand. The organic ligand includes one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, due to its ability to readily bond with metal salts and metal ions. In this specification, these compounds include various isomers, such as stereoisomers (geometric isomers, enantiomers, diastereoisomers, etc.) and structural isomers (positional isomers, etc.), as well as solvates (hydrates, etc.). The same applies to other compounds described in this specification.

[0030] The porous coordination polymer may contain two or more organic ligands, such as fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, but it is preferable to contain only one of these compounds in order to more easily control the pore size.

[0031] As the benzenetricarboxylic acid, 1,3,5-benzenetricarboxylate is preferred because it allows for easier construction of the porous coordination polymer structure.

[0032] As the methylimidazole, 2-methylimidazole is preferred because it allows for easier construction of the porous coordination polymer structure.

[0033] In order to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains fumaric acid as an organic ligand, the amount of free fumaric acid (free substance) that is not bound to metal ions derived from fumaric acid is 0.7% by mass or less per 100% by mass of the porous coordination polymer. Preferably, the amount of free fumaric acid is 0.5% by mass or less per 100% by mass of the porous coordination polymer. The lower limit of the amount of free fumaric acid is 0% by mass or more, as it is preferable that no free fumaric acid is contained in the porous coordination polymer in order to control the amount of functional sustained-release liquid adsorbed. However, considering the manufacturing process of the porous coordination polymer, it may be 0.1% by mass or more.

[0034] In order to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains terephthalic acid as an organic ligand, the amount of free terephthalic acid (free substance) that is not bound to metal ions derived from terephthalic acid is 0.5% by mass or less per 100% by mass of the porous coordination polymer. Preferably, the amount of free terephthalic acid is 0.3% by mass or less per 100% by mass of the porous coordination polymer. The lower limit of the amount of free terephthalic acid is 0% by mass or more, as it is preferable that no free terephthalic acid is contained in the porous coordination polymer in order to control the amount of functional sustained-release liquid adsorbed. However, considering the manufacturing process of the porous coordination polymer, it may be 0.1% by mass or more.

[0035] In order to control the adsorption of functional sustained-release liquids onto porous coordination polymers, when a porous coordination polymer contains benzenetricarboxylic acid as an organic ligand, the amount of free benzenetricarboxylic acid (free substance) that is not bound to metal ions derived from benzenetricarboxylic acid is 0.6% by mass or less per 100% by mass of the porous coordination polymer. Preferably, the amount of free benzenetricarboxylic acid is 0.3% by mass or less per 100% by mass of the porous coordination polymer. The lower limit of the amount of free benzenetricarboxylic acid is 0% by mass or more, as it is preferable that no free benzenetricarboxylic acid is contained in the porous coordination polymer in order to control the amount of adsorption of functional sustained-release liquids, but considering the manufacturing process of the porous coordination polymer, it may be 0.1% by mass or more.

[0036] In order to control the amount of functional sustained-release liquid adsorbed onto the porous coordination polymer, when the porous coordination polymer contains methylimidazole as an organic ligand, the amount of free methylimidazole (free substance) that is not bound to metal ions derived from methylimidazole is 0.7% by mass or less per 100% by mass of the porous coordination polymer. Preferably, the amount of free methylimidazole is 0.5% by mass or less per 100% by mass of the porous coordination polymer. The lower limit of the amount of free methylimidazole is 0% by mass or more, as it is preferable that no free methylimidazole is contained in the porous coordination polymer in order to control the amount of functional sustained-release liquid adsorbed. However, considering the manufacturing process of the porous coordination polymer, it may be 0.1% by mass or more.

[0037] From the viewpoint of the adsorption amount of functional sustained-release liquid, in porous coordination polymers, the content of organic ligands is preferably 60% to 90% by mass in total, and more preferably 70% to 85% by mass, per 100% by mass of the porous coordination polymer.

[0038] (Other organic ligands) The porous coordination polymer of this embodiment may contain other organic ligands besides fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole, as long as it achieves the effects of the present invention.

[0039] Other organic ligands preferably include bridging ligands that can crosslink to metal ions. Examples of such bridging ligands include 2,5-dihydroxyterephthalic acid, 1,4-naphthalenedicarboxylic acid, 4,4'-biphenyldicarboxylic acid, 4,4''-p-terphenyldicarboxylic acid, isophthalic acid, 1,3,5-tri-4-carboxyphenylbenzene, 4,4'-biphenyldicarboxylic acid, naphthalenedicarboxylic acid, hexaazatriphenylene, 2,5-dihydroxybenzoic acid, 5-cyanobenzenedicarboxylic acid, 5-ethyl-1,3-benzodicarboxylic acid, terephenyl-3,3',5,5'-tetracarboxylic acid, and 9,10-anthracene Examples include dicarboxylic acids, imidazoles, 2,2'-diamino-4,4'-stilbenicarboxylic acid, 2,2'-dinitrostilbenicarboxylic acid, 2,5-dihydroxyterephthalic acid, 3,3',5,5'-tetracarboxydiphenylmethane, 1,2,4,5-tetrakis(4-carboxyphenyl)benzene, 4,4',4''-s-triazine-2,4,6-trail-tribenzoic acid, 2-hydroxyterephthalic acid, biphenyl-3,3',5,5'-tetracarboxylic acid, biphenyl-3,4,5-tricarboxylic acid, 5-bromoisophthalic acid, and malonic acid. These organic ligands may be used individually or in combination of two or more.

[0040] When a porous coordination polymer contains other organic ligands, it is preferable that the amount of free other organic ligands (free substances) that are not bound to metal ions derived from the other organic ligands is 1.0% by mass or less in total, relative to 100% by mass of the porous coordination polymer. The lower limit of the amount of free other organic ligands is 0% by mass or more, as it is preferable that no free other organic ligands are contained in the porous coordination polymer, in order to control the amount of adsorption of the functional sustained-release liquid. However, considering the manufacturing process of the porous coordination polymer, it may be 0.1% by mass or more.

[0041] (Metal ions) The porous coordination polymer of this embodiment contains metal ions. The metal ions are not particularly limited as long as they can bind suitably to the organic ligands. One type of metal ion may be used alone, or two or more types may be used in combination. The metal ions may also be present in the porous coordination polymer in the form of compounds such as salts.

[0042] From the standpoint of being able to bind more favorably with organic ligands, it is preferable that the metal ion is a metal ion other than an alkali metal ion. In this specification, alkali metal ions refer to lithium ions, sodium ions, potassium ions, rubidium ions, cesium ions, and francium ions.

[0043] From the standpoint of being able to bond even more favorably with organic ligands, silver ions, aluminum ions, beryllium ions, calcium ions, cadmium ions, cerium ions, cobalt ions, chromium ions, copper ions, dysprosium ions, erbium ions, europium ions, iron ions, gallium ions, gadolinium ions, holmium ions, indium ions, magnesium ions, manganese ions, molybdenum ions, neodymium ions, nickel ions, scandium ions, samarium ions, strontium ions, terbium ions, thulium ions, vanadium ions, tungsten ions, yttrium ions, ytterbium ions, zinc ions, and zirconium ions are more preferred as metal ions because they can bond even more favorably with organic ligands.

[0044] It is even more preferable that the metal ion includes one or more selected from the group consisting of aluminum ions, zirconium ions, chromium ions, copper ions, iron ions, and zinc ions, as this allows for easier bonding with organic ligands.

[0045] When a porous coordination polymer contains fumaric acid as an organic ligand, it is preferable that the metal ions include aluminum ions, iron ions, copper ions, and magnesium ions, and more preferably aluminum ions, because they can bind to the organic ligand more easily.

[0046] When the porous coordination polymer contains terephthalic acid as an organic ligand, it is preferable that the metal ions include zirconium ions, chromium ions, aluminum ions, iron ions, magnesium ions, and zinc ions, and more preferably zirconium ions and / or chromium ions, in order to further facilitate bonding with the organic ligand.

[0047] When the porous coordination polymer contains benzenetricarboxylic acid as an organic ligand, it is preferable that the metal ions include iron ions, copper ions, chromium ions, iron ions, molybdenum ions, and zinc ions, and more preferably iron ions and / or copper ions, because they can bond more easily with the organic ligand.

[0048] When a porous coordination polymer contains methylimidazole as an organic ligand, it is preferable that the metal ion contains zinc ions or cobalt ions, and more preferably zinc ions, because they can bind more easily to the organic ligand.

[0049] In order to more easily construct the structure of the porous coordination polymer, the content of metal ions in the porous coordination polymer is preferably 10% to 40% by mass in total, and more preferably 15% to 30% by mass, per 100% by mass of the porous coordination polymer.

[0050] [Method for producing porous coordination polymers] The method for producing porous coordination polymers is not particularly limited, and known methods can be used as appropriate. Examples of such production methods include solvent mixing methods such as room temperature and atmospheric pressure mixing, high temperature and atmospheric pressure mixing, high temperature and high pressure mixing, microwave, ultrasonic, and electrochemical synthesis methods, as well as flow reaction methods using column reactors, counterflow mixing reactors, continuous stirring tank reactors, tubular flow reactors, and microfluidic synthesis. Furthermore, mechanochemical synthesis methods such as mortar mixing, ball mill mixing, and twin-screw extruders can be used.

[0051] [Functional sustained release liquid] The functional sustained-release carrier of this embodiment includes a functional sustained-release liquid. In functional sustained-release liquids, "functional sustained-release" refers to properties that possess functions such as small animal control, plant growth control, antibacterial function, antifungal function, plasticity imparted to resins, sliding function, self-healing function, catalytic function, medical function, antiviral function, self-cleaning function, and fragrance function, and that exhibit sustained-release properties. Functional sustained-release liquids may be liquid components possessing functional sustained-release properties, solid components possessing functional sustained-release properties in a liquefied form, or solid components possessing functional sustained-release properties in a liquefied form obtained by dissolving them in a solvent.

[0052] Examples of functional sustained-release liquids having small animal control functions include, for example, agents or liquid forms of agents dissolved in a solvent that have control activity against various agricultural pests, sanitary pests, other insects, spiders, mites, rodents, and other small animals (hereinafter also referred to as "small animal control agents"). Examples include compounds with small animal repellent activity, compounds with small animal killing activity such as insecticidal activity, acaricidal activity, spidericidal activity, or rodenticidal activity, compounds with small animal feeding inhibition activity, and compounds with small animal growth control activity.

[0053] Specific examples of small animal control agents include metadiamide insecticides such as broflanilide, piperidine insecticides such as icaridin, chloronicotinyl insecticides such as imidacloprid, compounds consisting of neophyll radicals with silicon atoms such as silafluofen, carbamate compounds such as benfuracarb, alanicarb, methoxydiazone, carbosphan, phenobucarb, carbaryl, methomyl, propoxer, and phenoxycarb, pyrethrin, allethrin, dl,d-T80-allethrin, d-T80-resmethrin, bioallethrin, d-T80-phthalthrin, phthalthrin, resmethrin, flamethrin, and propas Examples include pyrethroid compounds such as phosphorus, permethrin, acrinatrin, etofenprox, tralomethrin, phenothrin, d-phenothrin, fenvalerate, empenthrin, prallethrin, tefluthrin, benfluthrin, transfluthrin, and metofluthrin; organophosphorus compounds such as dichlorovos, fenitrothion, diazinon, malathion, bromophos, fenthion, trichlorfon, nared, temephos, fenclophos, chlorpyrifos-methyl, siaphos, calclophos, azamethiphos, pyridaphenthion, propethamphos, and chlorpyrifos, as well as their isomers, derivatives, and analogues.

[0054] Examples of compounds that have growth control activity in small animals include methoprene, pyriproxyfen, quinoprene, hydroprene, deohenolan, NC-170, fluphenoroxurone, diflubenzuron, lufenuron, and chlorazurone.

[0055] Examples of compounds with small animal miticide activity include acaricides such as kelthane, chlorfenavir, debufenpyradpiridaben, milbemectin, and fenpyroximate, and rodenticides such as siriloside, norvomide, zinc phosphide, thallium sulfate, yellow phosphorus, Antzu, warfarin, endoside, coumarin, coumatetralin, promadiolone, and difethiaron.

[0056] Examples of small animal control agents include hinokitiol found in Taiwanese cypress, Japanese cypress, and Japanese cypress (Aomori cypress), cadinol derivatives (α-cadinol, T-cadinol) found in herbs and cypress, geraniol, pinene, caryophyllene, borneol, eugenol, and other known fragrant oils with small animal control properties found in fragrant plants such as cloves, nutmeg, coriander, and cumin.

[0057] As a pest control agent for small animals, pheromone agents for insects and other animals that have attractant effects and communication inhibiting effects are also used. Examples of pheromone agents include those used for fruit trees such as Shin-Etsu Chemical Co., Ltd.'s "Confuser R," "Confuser AA," "Confuser N," "Confuser MM," "Hamakikon-N," "Sukashibakon L," "Shinkuikon-L," "Nashihimekon," "Bokutokon-H," and "Hetamushikon"; pheromone agents used for vegetables such as Shin-Etsu Chemical Co., Ltd.'s "Confuser V," "Yotokon-H," "Yotokon-S," "Konagakon-Plus," and "Shin-Etsu Konagakon"; pheromone agents used for tea such as Shin-Etsu Chemical Co., Ltd.'s "Hamakikon-N"; and pheromone agents used for sugarcane such as Shin-Etsu Chemical Co., Ltd.'s "Okimerakon," "Yotokon-I," and "Kebukakon."

[0058] The small animal control agent may also be a repellent for wasps, and the wasp repellent may contain, for example, a compound represented by the following general formula (I) as an active ingredient.

[0059] [ka]

[0060] In formula (I), R 1 C may have a hydrogen atom and a substituent β. 1-4 C may have alkyl groups and substituent β. 2-4 C may have an alkenyl group or a substituent β. 1-4The molecule exhibits an alkyl-carbonyl group, and X may have a substituent γ. 1-4 C may have an alkylene group or a substituent γ. 2-4 The C group exhibits an alkenylene group, and α may have a substituent δ. 1-4 C may have alkyl groups and substituent δ. 2-4 C may have an alkenyl group and a substituent δ. 1-4 C may have an alkoxy group or a substituent δ. 1-4 C may have an alkyl-carbonyl group and a substituent δ. 1-4 It represents one or more substituents selected from alkyl-carbonyloxy groups, halogeno groups, and hydroxyl groups. Substituents β, γ, and δ are each independently C 1-4 Alkoxy group, C 1-4 Alkyl-carbonyl group, C 1-4 It represents one or more substituents selected from the group consisting of alkyl-carbonyloxy groups, halogeno groups, and hydroxyl groups, and n is an integer between 0 and 5.

[0061] Further specific examples of repellents for wasps include, for example, the repellent described in Japanese Patent Publication No. 2017-88548.

[0062] Examples of functional sustained-release liquids that control plant growth include plant hormones. Examples of plant hormones include natural or synthetic auxins such as indole-3-acetic acid, 2,4-dichlorophenoxyacetic acid, 2,6-dichlorobenzoic acid, and naphthaleneacetic acid; natural or synthetic cytokinins such as zeatin, kinetin, 4-benzylaminobenzimidazole, and benzyladenine; gibberellins; brassinosteroids such as brassinolide and castasterone; and abscisic acid. These plant hormones can be used individually or in combination of two or more.

[0063] Examples of functional sustained-release liquids having antibacterial and antifungal properties include known sustained-release antibacterial agents and sustained-release antifungal agents. Examples of antibacterial and antifungal agents include natural organic compounds such as hinokitiol compounds, chitosan compounds, mustard extract compounds, and eucalyptus compounds, as well as synthetic organic compounds and organic complexes. These compounds can be used individually or in combination of two or more. Among these, synthetic organic compounds are preferred from the viewpoint of effectively acting on both fungi and molds.

[0064] Examples of synthetic organic compounds include nitrogen-containing heterocyclic compounds, aldehyde compounds, phenolic compounds, biguanide compounds, nitrile compounds, halogenated compounds, anilide compounds, disulfide compounds, thiocarbamate compounds, organosilicon quaternary ammonium salt compounds, quaternary ammonium salt compounds, amino acid compounds, organometallic compounds, alcohol compounds, carboxylic acid compounds, ester compounds, thiazoline compounds, cationic polymers, and the like. These synthetic organic compounds can be used individually or in combination of two or more.

[0065] Examples of functional sustained-release liquids that impart plasticity to resins include carboxylic acid ester derivatives, phosphate ester derivatives, phosphazene derivatives, carboxylic acid amide derivatives, sulfonic acid ester derivatives, sulfonic acid amide derivatives, and sulfonamide derivatives. Plasticizers can be used individually or in combination of two or more.

[0066] Examples of carboxylic acid ester derivatives include alkyl esters and aromatic esters of various carboxylic acids, which may be substituted with hydroxyl groups, nitro groups, amino groups, epoxy groups, halogens, etc. Specific examples of carboxylic acid ester derivatives include, for example, dimethyl phthalate, diethyl phthalate, di-n-octyl phthalate, diphenyl phthalate, benzyl phthalate, dimethoxyethyl phthalate, 4,5-epoxyhexahydrophthalate di(2-ethylhexyl), 4,5-epoxycyclohexahydrophthalate di(7,8-epoxy-2-octenyl), 4,5-epoxycyclohexahydrophthalate di(9,10-epoxyoctadecyl), 4,5-epoxycyclohexahydrophthalate di(10,Phthalate ester derivatives such as 11-epoxyundecyl), di(tetrahydroflufryloxyethyl) phthalate, various phthalate mixed esters and ethylene oxide adducts of phthalate mixed esters, isophthalate ester derivatives, tetrahydrophthalate ester derivatives, butoxyethyl p-hydroxybenzoate, cyclohexyloxyethoxyethoxyethyl p-hydroxybenzoate, 2-ethylhexyl p-hydroxybenzoate, hydroxybenzoate esters of ω-alkyl oligoethylene oxide, Benzoate ester derivatives such as the parahydroxybenzoic acid adduct of undecylglycidyl ether, propionic acid ester derivatives such as thiodipropionate di(tetrahydroflufuroxyethyl), adipic acid ester derivatives, azelaic acid ester derivatives, sebacate acid ester derivatives, dodecane-2- acid ester derivatives, maleic acid ester derivatives, fumarate ester derivatives, trimet acid ester derivatives, tris(2-ethylhexyl) trimellitate, tri(butoxyethoxyethyl) citrate, Citrate ester derivatives such as di-n-octyl-mono(nonylphenoxyethyl) citrate, tri-n-octyl citrate, dioctyl citrate (tetrahydrofurfuroxyethyl), trimiristyl citrate, triethyl citrate, itaconic acid ester derivatives, oleic acid ester derivatives such as tetrahydrofurfuryl oleate, ricinoleic acid ester derivatives, lactate (n-butyl), lactate (2-ethylhexyl), lactate (n-butoxyethoxyethyl), lactate (n-octoxyethoxyethyl), Examples include lactic acid ester derivatives such as lactic acid (n-decyloxyethoxyethyl), tartaric acid ester derivatives such as di(octoxyethoxyethyl) tartrate, n-octyl tartaric acid (nonylphenoxyethyl), and di(octoxyethoxyethyl) tartrate, malic acid ester derivatives such as dibutoxyethyl malate, di(n-butoxyethoxyethyl) malate, distearyl malate, and octadecenylisononyl malate, and salicylic acid ester derivatives such as salicylic acid adducts of benzyl glycidyl ether.

[0067] Examples of phosphate ester derivatives include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tri-(2-ethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, cresyl diphenyl phosphate, isodecyl diphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tri(chloroethyl) phosphate, xylenyl diphenyl phosphate, and tetrakis(2,4-diter-butylphenyl)4,4'-biphenylenediphosphonate.

[0068] Examples of phosphazene derivatives include cyclic phosphazene compounds represented by the following general formula (1).

[0069] [ka]

[0070] In the formula, m represents an integer between 3 and 25, and R 1 , and R 2 These may be the same or different, and represent an alkyl group having 1 to 8 carbon atoms, or a phenyl group which may be substituted with an alkyl group having 1 to 8 carbon atoms and / or an allyl group. The phosphazene derivative may consist of one type of cyclic phosphazene compound represented by formula (1), or it may consist of a mixture of two or more types.

[0071] Examples of phosphazene derivatives include linear phosphazene compounds represented by the following general formula (2).

[0072] [ka]

[0073] In the formula, n represents an integer between 3 and 1000, and R 3 , and R 4These may be the same or different groups, and represent an alkyl group having 1 to 8 carbon atoms, or a phenyl group which may be substituted with an alkyl group having 1 to 8 carbon atoms and / or an allyl group, where X is the group -N=P(OR 3 )3, Base - N = P(OR 4 )3, Base - N = P(O)(OR 3 ) or base-N=P(O)(OR 4 ) indicates that Y is based on P(OR 3 )4, Base-P(OR 4 )4, base-P(O)(OR 3 )2 or base-P(O)(OR 4 )2 is shown. The phosphazene derivative may consist of one type of linear phosphazene compound represented by formula (2), or it may consist of a mixture of two or more types.

[0074] As a phosphazene derivative, the crosslinking group represented by formula (3) below allows R in formula (1) or formula (2) to be removed. 1 , R 2 , R 3 , R 4 It may also be a phosphazene compound in which an alkyl group is removed and the two oxygen atoms are bridged.

[0075] [ka]

[0076] In the formula, r represents 0 or 1, and A represents the group -SO2-, -S-, -O-, or -C(CH3)2-.

[0077] Specific examples of cyclic phosphazene compounds represented by formula (1) include hexaphenoxycyclotriphosphazene, octaphenoxycyclotetraphosphazene, decaffenoxycyclopentaphosphazene, hexapropoxycyclotriphosphazene, octapropoxycyclotetraphosphazene, and decapropoxycyclopentaphosphazene.

[0078] Specific examples of linear phosphazene compounds represented by formula (2) include linear phosphazene compounds obtained by substituting a propoxy group and / or a phenoxy group for a linear dichlorophosphazene.

[0079] Specific examples of the crosslinking structure represented by formula (3) include 4,4'-sulfonyldiphenylene (bisphenol-S residue), 4,4'-oxydiphenylene group, 4,4'-thiodiphenylene group, and 4,4'-diphenylene group.

[0080] These phosphazene derivatives may be substituted with amino groups and / or phenylamino groups at any position. These phosphazene derivatives can be used individually or in combination of two or more.

[0081] Examples of carboxylic acid amide derivatives include N-cyclohexylbenzoic acid amide.

[0082] Examples of sulfonamide derivatives include N-methylbenzenesulfonamide, N-ethylbenzenesulfonamide, N-butylbenzenesulfonamide, N-cyclohexylbenzenesulfonamide, N-ethyl-p-toluenesulfonamide, N-butyltoluenesulfonamide, and N-cyclohexyltoluenesulfonamide.

[0083] Examples of sulfonic acid ester derivatives include ethyl benzenesulfonate.

[0084] Examples of sulfonate amide derivatives include 2-methoxyethyl methanesulfonate, 2,2,2-trifluoroethyl methanesulfonate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, and n-propyl p-toluenesulfonate.

[0085] Examples of functional sustained-release liquids having sliding properties include known sustained-release lubricants. Examples of known lubricants include mineral oil, synthetic oil, wax, paraffin, and the like.

[0086] Examples of functional sustained-release liquids with self-healing properties include known sustained-release self-healing agents. Known self-healing agents include polyrotaxane and Self-Healing Clear (a product of Natco Trading Co., Ltd.).

[0087] Examples of functional sustained-release liquids having catalytic function include known sustained-release catalysts. Known catalysts include ionic liquids, tertiary amines (e.g., "PZETA" from Tosoh Corporation), and organotitanium compounds (e.g., tetra-i-propoxytitanium, tetra-n-butoxytitanium, tetrakis(2-ethylhexyloxine)titanium (e.g., products from Nippon Soda Co., Ltd.)).

[0088] Examples of functional sustained-release liquids with medical functions include known medical products that have sustained-release properties.

[0089] Examples of functional sustained-release liquids with antiviral properties include aromatic compounds (Amolden V-1000HP, manufactured by Yamato Chemical Industry Co., Ltd.) and cationic polymers (Amolden D-CL50, D-CLH, manufactured by Yamato Chemical Industry Co., Ltd.).

[0090] Examples of functional sustained-release liquids with self-cleaning properties include ionic surfactants (amino ion AS200, AS400, manufactured by Nippon Emulsifier Co., Ltd.), nonionic surfactants (Amite 102, 105, manufactured by Kao Corporation), and fluorinated surfactants (Surflon S-242, S-243, S-386, manufactured by AGC Seikamika).

[0091] The solvent is preferably one that has high compatibility with the matrix resin and has little effect on the shape stability of the molded product. Examples of solvents include water, methanol, ethanol, dimethyl sulfoxide, polyethylene glycol, sulfonamide derivatives, sulfonic acid ester derivatives, carboxylic acid amide derivatives, carboxylic acid ester derivatives, phosphate ester derivatives, hydrocarbon compounds, and silicone compounds.

[0092] Examples of sulfonamide derivatives include N-methylbenzenesulfonamide, N-ethylbenzenesulfonamide, N-butylbenzenesulfonamide, N-cyclohexylbenzenesulfonamide, N-ethyl-p-toluenesulfonamide, N-butyl-toluenesulfonamide, and N-cyclohexyl-toluenesulfonamide. Examples of sulfonic acid ester derivatives include 2-methoxyethyl methanesulfonate, 2,2,2-trifluoroethyl methanesulfonate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, and n-propyl p-toluenesulfonate.

[0093] An example of a carboxylic acid amide derivative is N-cyclohexylbenzoic acid amide.

[0094] Examples of carboxylic acid ester derivatives include dimethyl phthalate, diethyl phthalate, di-n-octyl phthalate, diphenyl phthalate, benzyl phthalate, dimethoxyethyl phthalate, 4,5-epoxyhexahydrophthalate di(2-ethylhexyl), 4,5-epoxycyclohexahydrophthalate di(7,8-epoxy-2-octenyl), 4,5-epoxycyclohexahydrophthalate di(9,10-epoxyoctadecyl), 4,5-epoxycyclohexahydrophthalate di(10,Phthalate ester derivatives such as 11-epoxyundecyl), di(tetrahydroflufuroxyethyl) phthalate, various phthalate mixed esters and ethylene oxide adducts of phthalate mixed esters, isophthalate ester derivatives, tetrahydrophthalate ester derivatives, butoxyethyl parahydroxybenzoate, cyclohexyloxyethoxyethoxyethyl parahydroxybenzoate, 2-ethylhexyl parahydroxybenzoate, hydroxybenzoate esters of ω-alkyloligoethylene oxide, benzoate ester derivatives such as parahydroxybenzoate adducts of undecylglycidyl ether, propionic acid ester derivatives such as di(tetrahydroflufuroxyethyl) thiodipropionate, adipic acid ester derivatives, azelaic acid ester derivatives, sebacate acid ester derivatives, dodecane-2 acid ester derivatives, maleic acid ester derivatives, fumarate ester derivatives, trimetic acid ester derivatives, tri(butoxyethoxyethyl) citrate, di-n-octyl citrate -Citrate ester derivatives such as mono(nonylphenoxyethyl), tri-n-octyl citrate, dioctyl citrate (tetrahydrofurfuroxyethyl), trimiristyl citrate, triethyl citrate, itaconic acid ester derivatives, oleic acid ester derivatives such as tetrahydrofurfuryl oleate, ricinoleic acid ester derivatives, lactic acid (n-butyl), lactic acid (2-ethylhexyl), lactic acid (n-butoxyethoxyethyl), lactic acid (n-octoxyethoxyethyl), lactic acid (n- Examples include lactic acid ester derivatives such as decyloxyethoxyethyl tartar, tartrate ester derivatives such as di(octoxyethoxyethyl) tartrate, n-octyl tartar (nonylphenoxyethyl) tartrate, malic acid ester derivatives such as dibutoxyethyl malate, di(n-butoxyethoxyethyl) malate, distearyl malate, octadecenylisononyl malate, and salicylic acid ester derivatives such as salicylic acid adducts of benzyl glycidyl ether.

[0095] Examples of phosphate ester derivatives include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tri-(2-ethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, tributoxyethyl phosphate, triphenyl phosphate, cresyl diphenyl phosphate, isodecyl diphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tri(chloroethyl) phosphate, xylenyl diphenyl phosphate, and tetrakis(2,4-diter-butylphenyl)4,4'-biphenylenediphosphate.

[0096] Examples of hydrocarbon compounds include chain-type saturated hydrocarbon compounds (paraffins), chain-type unsaturated hydrocarbon compounds (olefins), alicyclic hydrocarbon compounds (cycloalkanes, cycloalkenes, cycloalkynes, etc.), and aromatic hydrocarbon compounds. Among these hydrocarbon compounds, paraffin oil with a molecular weight of 330 to 530 and a kinematic viscosity of 10 cSt to 120 cSt is particularly preferred. Hydrocarbon compounds with a molecular weight of 330 to 530 are preferred from the viewpoint of easily penetrating the body of small animals through their pores. Hydrocarbon compounds with a kinematic viscosity of 10 cSt to 120 cSt are also preferred from the viewpoint of easily adhering to the body surface of small animals. Furthermore, the use of paraffin oil is preferred from the viewpoint of being inexpensive and readily available. Examples of silicone compounds include dimethyl silicone, methylphenyl silicone, polyether-modified silicone, long-chain alkyl-modified silicone, and higher fatty acid ester-modified silicone.

[0097] Examples of flame retardants include non-halogenated flame retardants such as trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, cresyl diphenyl phosphate, cresyl di2,6-xylenyl phosphate, aromatic condensed phosphate esters, aliphatic phosphate amides, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, melamine cyanurate, and ADEKA FP-600 (product name, manufactured by ADEKA). Examples of halogenated flame retardants include Adeka Stab PFR (product name, manufactured by ADEKA), Adeka Stab FP-900L (product name, manufactured by ADEKA), tris(chloropropyl) phosphate, tris(tribromoneopentyl) phosphate, halogenated condensed phosphate esters, tribromoneopentyl alcohol, dibromoneopentyl glycol, tribromophenol, pentabromobenzyl polyacrylate, decabromodiphenyl oxide, tetrabromobisphenol-A, and brominated epoxy.

[0098] Examples of fragrances include isothiocyanates, indoles and their derivatives, ethers, esters, ketones, fatty acids, aliphatic higher alcohols, aliphatic higher aldehydes, aliphatic higher hydrocarbons, thioethers, thiols, terpene hydrocarbons, phenol ethers, phenols, furfural and its derivatives, aromatic alcohols, aromatic aldehydes, lactones, and 4-nonanolides. These fragrances can be used individually or in combination of two or more.

[0099] When a functional sustained-release liquid is compounded with a resin, it is gradually released onto the surface of the molded product, and its excellent sustained-release effect can be maintained for a long period of time. Therefore, it is preferable that the functional sustained-release liquid has a molecular weight of 600 or less. There is no particular lower limit to the molecular weight, but for example, it is 30 or more.

[0100] The acid dissociation constant of a functional sustained-release liquid is preferably in the range of -10 to 40, given that it must be a liquid. The acid dissociation constant of a functional sustained-release liquid can be determined using the Henderson-Hasselbalch equation, known literature, and methods such as neutralization titration, spectrophotometric analysis, and capillary electrophoresis.

[0101] From the standpoint of facilitating the compounding of resins, the content of the functional sustained-release liquid in the functional sustained-release support is preferably 10 parts by mass or more and 90 parts by mass or less, and more preferably 25 parts by mass or more and 80 parts by mass or less, per 100 parts by mass of the functional sustained-release support.

[0102] The ratio of the content of the functional sustained-release liquid to the content of the porous coordination polymer is, for example, 0.10 to 9.00, and from the viewpoint of more effectively and reliably achieving the effects of the present invention, it is preferably 0.25 to 3.00.

[0103] [Method for manufacturing functional liquid carriers] The method for producing the functional sustained-release support is not particularly limited, and known methods can be used as appropriate. For example, the methods for producing such a product can be based on the Pigment Test Methods - Part 13: Oil Absorption JIS K5101-13-1 (2004) Section 1: Refined Linseed Oil Method and JIS K5101-13-2 (2004) Section 2: Boiled Linseed Oil Method.

[0104] In this embodiment, when manufacturing a functional liquid support, it is desirable to remove any free matter derived from organic ligands that is attached to or present on the surface and / or inside the pores of the porous coordination polymer before allowing the porous coordination polymer to hold the functional sustained-release liquid. If free matter is present, when compounding the porous coordination polymer and the functional sustained-release liquid, the pores may be narrowed or completely blocked by the free matter, making it difficult to inject the functional sustained-release liquid into the pores of the porous coordination polymer. Furthermore, since the free matter is mixed into the functional sustained-release liquid as an impurity, the physical properties of the functional sustained-release liquid change, and the desired effect cannot be obtained.

[0105] The method for removing free matter is not particularly limited, and known methods can be used as appropriate. Examples of such methods include washing the porous coordination polymer with a solvent. Examples of solvents used for washing include water, methanol, THF (tetrahydrofuran), and DMF (dimethylformamide). Among these solvents, water and / or methanol are preferred. When the solvent is water and / or methanol, the small molecular size of the solvent allows it to easily penetrate the pores of the porous coordination polymer, easily removing free matter from within the pores. Alternatively, the free matter may be removed by immersing the porous coordination polymer in the solvent for a long period of time. The immersion time is preferably 12 hours or more, and more preferably 24 hours or more. After washing with the solvent, it is preferable to completely remove the solvent by heat treatment.

[0106] As a method for removing free substances, they may be detached by heat treatment. Since the free substances originate from organic ligands and are organic matter, they can be easily removed by heat treatment in air or an oxygen atmosphere. If the free substances are volatile substances, they can also be removed by vacuum heat treatment. The heating temperature is preferably between 100°C and 300°C.

[0107] In the manufacture of functional liquid carriers, if impurities other than free matter are present, it is preferable to remove them, for example, by the washing and heat treatment described above.

[0108] [Functional sustained release composition] The functional sustained-release composition of this embodiment comprises a functional liquid carrier and a matrix resin. In the functional sustained-release composition, the functional liquid carrier may be used alone or in combination of two or more types, as long as the effects of the present invention are achieved.

[0109] The functional sustained-release composition has a surface concentration of liquid component of 1.0 mg / cm³ when compressed to 10 MPa or higher. 2 It is preferable that the surface concentration be less than 1.0 mg / cm³. 2As a result, when processing functional sustained-release compositions by injection molding or the like, there is a risk of problems such as material pellets becoming clogged due to the surface becoming sticky.

[0110] (Matrix resin) The functional sustained-release composition of this embodiment includes a matrix resin. Examples of matrix resins include thermoplastic resins and thermosetting resins. The matrix resin may be used alone or in combination of two or more types.

[0111] Examples of thermoplastic resins include polyethylene resin, polypropylene resin, polyvinyl chloride resin, polyvinylidene chloride resin, polyvinyl acetate resin, polystyrene resin, AS resin, ABS resin, methacrylic resin, polyvinyl alcohol resin, EVA resin, polyamide resin, polyacetal resin, polycarbonate resin, polyphenylene ether resin, polyethylene terephthalate resin, polybutylene terephthalate resin, fluororesin, polyphenylene sulfide resin, polysulfone resin, polyarylate resin, polyetherimide resin, polyethersulfone resin, polyetherketone resin, liquid crystal polyester resin, thermoplastic polyimide resin, and thermoplastic polyurethane resin.

[0112] Examples of thermosetting resins include epoxy resins, unsaturated polyester resins, phenolic resins, urea resins, melamine resins, alkyd resins, silicone resins, polyimide resins, polyurethane resins, vinyl ester resins, diallyl phthalate resins, furan resins, polyaminobismaleimide resins, casein resins, epoxy acrylate resins, urethane acrylate resins, polyurea resins, benzoxazine resins, oxetane resins, xylene resins, dicyclopentadiene resins, and episulfide resins.

[0113] From the standpoint of easy processing, in a functional sustained-release composition, the content of the functional liquid carrier is preferably 1% by mass or more and 95% by mass in total per 100% by mass of the functional sustained-release composition. In a functional sustained-release composition, the content of the matrix resin is preferably 5% by mass or more and 99% by mass in total per 100% by mass of the functional sustained-release composition.

[0114] (Inorganic filler) Functional sustained-release compositions may contain inorganic fillers from the viewpoint of improving their mechanical properties. Known inorganic fillers can be used as such inorganic fillers. Examples include particulate inorganic fillers, fibrous inorganic fillers, and flake-shaped or plate-shaped inorganic fillers. One type of inorganic filler may be used alone, or two or more types may be used in combination.

[0115] The particulate inorganic filler may be, for example, a particulate inorganic filler having a micron size, or a particulate inorganic filler having a nano size.

[0116] Examples of particulate inorganic fillers having a micron size include calcium carbonate particles, silica particles, glass beads, titanium oxide particles, zinc oxide particles, potassium titanate particles, titania particles, monoclinic titania particles, calcium phosphate particles, wollastonite, vermiculite, shirasu balloons, and glass balloons.

[0117] Examples of particulate inorganic fillers having nano-size include nano-titanium dioxide, nano-silica, carbon black, and carbon fillers.

[0118] Among these, particulate inorganic fillers are preferable because they offer even better sustained release properties for functional sustained-release liquids (especially small animal control agents), and therefore contain potassium titanate particles.

[0119] From the viewpoint of not adversely affecting the appearance of the molded article, the fibrous inorganic filler preferably includes a fibrous inorganic filler having an average fiber diameter of 0.05 μm to 10 μm and an average fiber length of 3 μm to 150 μm, and more preferably includes a fibrous inorganic filler having an average fiber diameter of 0.1 μm to 7 μm and an average fiber length of 5 μm to 50 μm.

[0120] The fibrous inorganic filler may be, for example, a fibrous inorganic filler having a micron size, or a fibrous inorganic filler having a nano size.

[0121] Examples of fibrous inorganic fillers having a micron size include glass fibers, carbon fibers, graphite fibers, aramid fibers, vinylon fibers, polyamide fibers, polyester fibers, cotton, hemp fibers, kenaf fibers, bamboo fibers, rayon, steel fibers, aluminum fibers, gypsum fibers, potassium tetratitanate fibers, potassium hexatitanate fibers, potassium octatanate fibers, titania fibers, monoclinic titania fibers, silica fibers, wollastonite, and xonotlite.

[0122] Examples of fibrous inorganic fillers having nanoscale dimensions include carbon fibers, carbon nanotubes, fullerenes, cotton fibrils, silicon nitride whiskers, alumina whiskers, silicon carbide whiskers, and nickel whiskers.

[0123] These fibrous inorganic fillers may be used individually or in combination of two or more types.

[0124] The flake-shaped or plate-shaped inorganic filler may be, for example, a flake-shaped or plate-shaped inorganic filler having a micron size, or a flake-shaped or plate-shaped inorganic filler having a nano size.

[0125] Examples of flake-shaped or plate-shaped inorganic fillers having a micron size include talc, kaolin clay, mica (synthetic mica or natural mica), glass flakes, aragonite, calcium sulfate, aluminum hydroxide, potassium titanate, lithium potassium titanate, magnesium potassium titanate, sericite, plate-shaped alumina, and boron nitride.

[0126] Examples of nanoscale flake-like or plate-like inorganic fillers include organic montmorillonite, swellable synthetic mica, graphite, and the like.

[0127] The flake-shaped inorganic filler may be used individually or in combination of two or more types.

[0128] The inorganic filler may be used as is, or it may be used in a form that has been surface-treated with a silane coupling agent such as aminosilane, epoxysilane, or acrylicsilane, or a surface treatment agent such as a titanate coupling agent, from the viewpoint of improving interfacial adhesion with the resin or further improving mechanical properties.

[0129] In functional sustained-release compositions, if an inorganic filler is included, the amount of the inorganic filler is usually 0.01% by mass or more and 70% by mass or less per 100% by mass of the functional sustained-release composition.

[0130] (Weather-resistant additive) Functional sustained-release compositions may contain weather-resistant additives to further improve weather resistance when left outdoors. Examples of weather-resistance-improving additives include hindered phenol antioxidants, phosphorus antioxidants, UV-absorbing light stabilizers, hindered amine light stabilizers, and carbon. These weather-resistance-improving additives may be used individually or in combination of two or more.

[0131] Examples of hindered phenol antioxidants include pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], N,N'-hexane-1,6-diylbis[3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)], bis-[3,3-bis-(4'-hydroxy-3'-tert-butylphenyl)-butanoic acid]-glycol ester, tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, and thiodiethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl] Examples include [nyl)propionate], octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 3,3',3'',5,5',5''-hexa-tert-butyl-a,a',a''-(methylene-2,4,6-triyl)tri-p-cresol, hexamethylenebis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], tetrakis[methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]methane, and methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate.

[0132] Examples of phosphorus-based antioxidants include tris(2,4-di-tert-butylphenyl) phosphite, tris[2-[[2,4,8,10-tetra-tert-butylbenzo[d,f][1,3,2]dioxaphosphefin-6-yl]oxy]ethyl]amine, tetrakis(2,4-di-tert-butylphenyl)[1,1-biphenyl]-4,4'-diylbisphosphonate, distearyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol phosphite, bis(2,6-di-tert-butyl-4-phenyl) pentaerythritol phosphite, and bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite.

[0133] Examples of UV absorbers include 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol, propanedioc acid, and [(4-methoxyphenyl)-methylene]-dimethyl ester.

[0134] Examples of hindered amine-based light stabilizers include N,N',N'',N'''-tetrakis-(4,6-bis-(butyl-(N-methyl-2,2,6,6-tetramethylpiperidine-4-yl)amino)-triazine-2-yl)-4,7-diazadecane-1,10-diamine, poly[(6-(1,1,3,3-tetramethylbutyl)amino-1,3,5-triazine-2,4-diyl)(2,2,6,6-tetramethyl-4-piperidyl)imino]hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino) Examples include bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, 2,2,4,4-tetramethyl-7-oxa-3,20-diaza-dispiro-[5.1.11.2]-heneicosan-21-one, propanedioic acid, [(4-methoxyphenyl)-methylene]-,bis(1,2,2,6,6-pentamethyl-4-piperidinyl) ester, 1,3-benzenedicaramide, N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl), and 2-ethyl,2'-ethoxy-oxalanilide.

[0135] Among these, the weather-resistant additives are pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate], N,N'-hexane-1,6-diylbis[3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)], tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, tris(2,4-di-tert-butylphenyl)phosphite, tetrakis(2,4-di-tert-butylphenyl)[1,1-biphenyl]-4,4'-diylbisphosphonate, bis(2,4-di-tert-butylphenyl)pentaerythritol phosphite, and 2-(2H-benzotriazole-2-yl)-4,6 -Bis(1-methyl-1-phenylethyl)phenol, 2-ethyl,2'-ethoxy-oxalanilide, N,N',N'',N'''-tetrakis-(4,6-bis-(butyl-(N-methyl-2,2,6,6-tetramethylpiperidine-4-yl)amino)-triazine-2-yl)-4,7-diazadecane-1,10-diamine, poly[(6-(1,1,3,3-tetramethylbutyl)amino-1,3,5-triazine-2,4-diyl)(2,2,6,6-tetramethyl-4-piperidyl)imino]hexamethylene((2,2,6,6-tetramethyl-4-piperidyl)imino)), 1,3-benzenedicaramide, and N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl) are preferred.

[0136] In functional sustained-release compositions, if a weather-resistance-imparting additive is included, the content of the weather-resistance-imparting additive is usually 0.01% by mass or more and 20% by mass or less per 100% by mass of the functional sustained-release composition.

[0137] [Method for producing a functional sustained-release composition] The method for producing the functional sustained-release composition is not particularly limited, and known methods can be used as appropriate. Examples of such production methods include batch-type compounding using rolls, Banburys, kneaders, etc.; screw-type compounding using single-screw extruders, twin-screw extruders, multi-screw extruders, etc.; rotor-type compounding using single-screw compounders, multi-screw compounders, etc.; and millstone-type compounding using KCK compounding extruders, etc.

[0138] [Molded body] The molded article of this embodiment contains a functional sustained-release composition. Functional sustained-release compositions can be used as is, for example, as paints, sealants, cushioning materials, or fillers, but they may also be used after being processed into molded bodies having a predetermined shape.

[0139] In a functional sustained-release composition, for example, by selecting an appropriate functional liquid carrier and a matrix resin and adjusting them as appropriate, a molded article having fluidity, semi-fluidity, or rubber-like elasticity can be produced.

[0140] Examples of molded products that have fluidity include paints.

[0141] Examples of semi-fluid molded bodies include sealants.

[0142] Examples of molded bodies having rubber-like elasticity include cushioning materials and stuffing materials.

[0143] When using a functional sustained-release composition as a paint, sealant, cushioning material, or filler, colorants such as colorants or pigments may be added to the matrix resin as needed.

[0144] When molding functional sustained-release compositions, appropriate known molding methods such as injection molding, compression molding, transfer molding, extrusion molding, blow molding, calendering, FRP molding, lamination molding, casting, solution casting, vacuum / pressure molding, extrusion composite molding, foam molding, thermoforming, insert molding, melt impregnation, and melt spinning can be applied. Furthermore, the shape of the molded product is not particularly limited and can be any shape, such as flat, rod-shaped, cylindrical, comb-shaped, or spherical. In addition to molding the functional sustained-release composition alone, it can also be molded in two or more colors by combining it with metal or other materials. [Examples]

[0145] The present invention will be described in more detail below using examples and comparative examples, but the present invention is not limited in any way by these examples. Also, unless otherwise specified, "parts" and "%" are based on mass.

[0146] [Amount of free organic ligands] The amounts of free fumaric acid, free terephthalic acid, free 1,3,5-benzenetricarboxylic acid, and free 2-methylimidazole in the porous coordination polymer were measured by the following method. Specifically, 1 g of each porous coordination polymer obtained in the synthesis example and 20 ml of solvent were added to a 100 ml Erlenmeyer flask. Then, extraction was performed for 30 minutes at 50°C and 120 rpm using a constant temperature shaker (Tokyo Rikakikai Co., Ltd.). The obtained extract was filtered through a 0.2 μm filter and measured using a high-performance liquid chromatograph (GL Sciences, SH-Stabilwax 30 m × 0.25 mm ID × 0.25 μm). From the measurement results, the amount of free organic ligands was calculated as the amount (mass%) relative to 100 mass% of the porous coordination polymer.

[0147] [Specific surface area] Specific surface area (m²) of porous coordination polymers 2 The specific surface area / g) was measured by the following method. Specifically, nitrogen adsorption and desorption were performed on each of the porous coordination polymers obtained in the examples and comparative examples using a specific surface area / pore size distribution analyzer (BELSORP-maxII (product name) manufactured by Microtrac-Bel Co., Ltd.). The adsorption temperature was liquid nitrogen temperature (-196°C, 77K). Pretreatment was performed under vacuum, 200°C, and 5 hours. The measurement range was 5 × 10⁻⁶. -5 The relative pressure was between P / P0 and 0.995P / P0.

[0148] [Average pore diameter] The average pore size (nm) of the porous coordination polymer was measured by the following method. Specifically, nitrogen adsorption and desorption were performed on each of the porous coordination polymers obtained in the examples and comparative examples using a specific surface area / pore size distribution analyzer (BELSORP-maxII (product name) manufactured by Microtrac-Bel Co., Ltd.). The adsorption temperature was liquid nitrogen temperature (-196°C, 77K). Pretreatment was performed under vacuum, 200°C, and 5 hours. The measurement range was 5 × 10⁻⁶. -5 The relative pressure was between P / P0 and 0.995P / P0. The MP method was used for the analysis.

[0149] [Gas adsorption amount] The amount of gas adsorbed was determined from the nitrogen adsorbed amount at 0.99 P / P0 using an isothermal adsorption curve. Specifically, for each of the porous coordination polymers obtained in the examples and comparative examples, nitrogen adsorption and desorption were performed using a specific surface area / pore size distribution analyzer (BELSORP-maxII (product name) manufactured by Microtrac-Bel Co., Ltd.) to determine the amount of gas adsorbed by the porous coordination polymer (cm³). 3 The saturation (STP) per g (standard conditions) was measured. The adsorption temperature was set to liquid nitrogen temperature (-196°C, 77K). Pretreatment was performed under vacuum, 200°C, and for 5 hours. The measurement range was 5 × 10⁻⁶. -5 The relative pressure was between P / P0 and 0.995P / P0.

[0150] [Amount of functional sustained-release liquid adsorbed in a functional liquid carrier] The adsorption amounts (mass%) of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoids, and trimellitic acid esters in the functional liquid carrier were measured by the following method. Specifically, 1 g of the porous coordination polymer obtained in Synthesis Examples 1-30 was weighed into a glass petri dish, and a functional liquid-supported material was prepared by adding one drop of the functional sustained-release liquid to the porous coordination polymer while kneading it with a glass rod to ensure proper mixing of the polymer and the liquid. During this process, the amount of liquid added at that point was visually confirmed to be the amount of functional sustained-release liquid adsorbed, and this amount was defined as the adsorbed amount of the functional liquid. From these measurement results, the amount of functional sustained-release liquid adsorbed in the functional liquid-supported material was calculated as the amount relative to 100% by mass of the porous coordination polymer (mass%).

[0151] [Measurement of surface amount of functional sustained-release liquid in molded bodies] The amounts of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoid, and trimellitic acid ester in the molded articles were measured by the following method. Specifically, for each of the molded articles prepared in the examples and comparative examples, the surface amounts (surface concentration of the functional sustained-release liquid) of etofenprox, 2-n-octyl-4-isothiazolin-3-one, 4-nonanoid, and trimellitic acid ester in the molded articles were measured by the following method. First, each molded body was immersed in 50 mL of tetrahydrofuran at 20°C to wash away the functional sustained-release liquid precipitated on its surface. Next, using a high-performance liquid chromatograph (LUNA, column: Luna® 3 μm C18(2) 100 Å, LC Column 150 × 4.6 mm, Ea), the surface amount (surface concentration) of the functional sustained-release liquid per unit area of ​​the molded body in the washed solution was determined (μg / cm³). 2 ) was measured.

[0152] [Synthesis Examples 1-5] Synthesis of porous coordination polymers A1-A5 Aluminum sulfate-18 hydrated water (Al2(SO4)3·18H2O), fumaric acid, and sodium hydroxide were introduced into a Henschel mixer in a ratio of 1:3:6 (by mass) and blended. The blend was then fed into a twin-screw extruder (HAAKE Process 11 (product name), Thermo Fisher Scientific Co., Ltd.), and extruded while kneading at a cylinder and die temperature of 150°C and an extrusion rate of 0.6 kg / hour to obtain a powder sample. 1 g of the powder sample and 10 mL of pure water were added to a 100 mL Erlenmeyer flask and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed powder sample was vacuum-dried at 200°C to obtain a porous coordination polymer A1 having aluminum ions as metal ions and fumaric acid as an organic ligand. Porous coordination polymers A2 to A5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer A1.

[0153] [Synthesis Examples 6-10] Synthesis of porous coordination polymers B1-B5 In a Teflon® container, 1 mmol of chromium nitrate-9-hydrated water (Cr(NO3)3·9H2O), 1 mmol of nitric acid, 1 mmol of terephthalic acid, and 5 mL of ultrapure water were added and dissolved. The resulting solution was then heated at 220°C for 8 hours and cooled to room temperature (25°C) over 6 hours. The solution was then filtered to obtain the product (filter). 1 g of the product (filter) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed product was vacuum-dried at 200°C to obtain porous coordination polymer B1 having chromium ions as metal ions and terephthalic acid as an organic ligand. Porous coordination polymers B2 to B5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer B1.

[0154] [Synthesis Examples 11-15] Synthesis of Porous Coordination Polymers C1-C5 0.2 mmol of zirconium chloride (ZrCl4), 0.4 mmol of terephthalic acid, 0.2 mmol of hydrochloric acid, and 25 mL of N,N-dimethylformaldehyde (DMF) were placed in a Teflon container and stirred at 120°C for 24 hours. The mixture was then filtered to obtain the product (filter). 1 g of the product (filter) and 10 mL of pure water were added to a 100 mL Erlenmeyer flask and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed product was vacuum-dried at 200°C to obtain a porous coordination polymer C1 having zirconium ions as metal ions and terephthalic acid as an organic ligand. Porous coordination polymers C2 to C5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer C1.

[0155] [Synthesis Examples 16-20] Synthesis of porous coordination polymers D1-D5 In a 100 ml round-bottom flask, iron nitrate 9-hydrate ([Fe(H2O)6](NO3)3·3H2O), 1,3,5-benzenetricarboxylic acid, hydrogen fluoride, nitric acid, and ultrapure water were added in a ratio of 1:1:2:0.5:100 (mass ratio) and refluxed at 95°C for 12 hours. The mixture was then allowed to stand at room temperature. The solution was then filtered to obtain the product (filter). In a 100 ml Erlenmeyer flask, 1 g of the product (filter) and 10 ml of pure water were added and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed product was vacuum-dried at 200°C to obtain a porous coordination polymer D1 containing iron ions as metal ions and 1,3,5-benzenetricarboxylic acid as an organic ligand. Porous coordination polymers D2 to D5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer D1.

[0156] [Synthesis Examples 21-25] Synthesis of Porous Coordination Polymers E1-E5 In a 200 ml Erlenmeyer flask, copper nitrate (Cu(NO3)2), 1,3,5-benzenetricarboxylic acid, and ultrapure water were added in a ratio of 1:2:2222 (mass ratio) and stirred at room temperature for 1 hour. The mixture was then left to stand at room temperature for 23 hours. The solution was then filtered to obtain the product (filter). In a 100 ml Erlenmeyer flask, 1 g of the product (filter) and 10 ml of pure water were added and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed product was vacuum-dried at 200 °C to obtain a porous coordination polymer E1 containing copper ions as metal ions and 1,3,5-benzenetricarboxylic acid as an organic ligand. Porous coordination polymers E2 to E5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer E1.

[0157] [Synthesis Examples 26-30] Synthesis of Porous Coordination Polymers F1-F5 In a 200 ml Erlenmeyer flask, zinc nitrate (Zn(NO3)2), 2-methylimidazole, triethylamine, and ultrapure water were added in a ratio of 1:6:2.5:500 (mass ratio) and mixed at room temperature for 30 minutes. The solution was filtered to obtain the product (filter). In a 100 ml Erlenmeyer flask, 1 g of the product (filter) and 10 ml of pure water were added and washed by stirring at 120 rpm for 20 hours using a magnetic stirrer (AS ONE). The washed product was vacuum-dried at 200 °C to obtain a porous coordination polymer F1 having zinc ions as metal ions and 2-methylimidazole as an organic ligand. Porous coordination polymers F2 to F5 were obtained by synthesizing them using the same method as described above for the synthesis of porous coordination polymer F1.

[0158] [Example 1-A1] When the amount of free fumaric acid in porous coordination polymer A1(W) was measured using the above method, it was found to be 0.4% by mass relative to 100% by mass of porous coordination polymer A1(W). Furthermore, the specific surface area of ​​porous coordination polymer A1(W) measured by the BET method was 904 m². 2The values ​​are per gram, the average pore size is 0.6 nm, and the gas adsorption capacity is 451 cm³. 3 It was / g. Next, etofenprox (melting point 37°C, boiling point 200°C, molecular weight 376.49, molecular diameter (major axis) 1.748 nm, molecular diameter (minor axis) 0.5 nm, Mitsui Chemicals Agro, Inc.) was adsorbed onto the porous coordination polymer A1(W) to obtain a functional liquid support 1-A1 with adsorbed etofenprox. The adsorption method involved placing the porous coordination polymer A1 in a vacuum bell jar and dropping etofenprox onto it under reduced pressure of 0.01 MPa or less to adsorb the etofenprox onto the porous coordination polymer A1. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in the functional liquid support 1-A1 was 300% by mass relative to 100% by mass of the porous coordination polymer A1(W). Next, functional liquid carrier 1-A1 was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to produce a functional sustained-release composition (molded body material). The mixture was formulated so that functional liquid carrier 1-A1 was 6.7% by mass and the matrix resin (polyethylene resin) was 93.3% by mass, based on 100% by mass of the functional sustained-release composition. For the compounding process, a laboplast mill (Toyo Seiki Seisakusho Co., Ltd.) was used, and the mixture was compounded at a processing temperature of 120°C for 10 minutes. Next, using a heated press (IMC180C model (product name), Imoto Seisakusho Co., Ltd.), the functional sustained-release composition was pressurized at 120°C with a pressure of 10 tons to produce a plate-shaped molded body measuring 50 mm x 50 mm and 1.0 mm in thickness. The amount of functional sustained-release liquid on the surface of the produced plate-shaped molded body was measured to be 8 μg / cm³. 2 That was the case.

[0159] [Example 1-A2] When the amount of free fumaric acid in porous coordination polymer A2(W) was measured using the above method, it was found to be 0.7% by mass relative to 100% by mass of porous coordination polymer A2(W). Furthermore, the specific surface area of ​​porous coordination polymer A2(W) measured by the BET method was 903 m².2 The values ​​are per gram, the average pore size is 0.6 nm, and the gas adsorption capacity is 452 cm³. 3 It was / g. Next, using the same method as in Example 1-A1, etofenprox was adsorbed onto the porous coordination polymer A2(W) as a functional sustained-release liquid to obtain functional liquid support 1-A2 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-A2 was 250% by mass relative to 100% by mass of the porous coordination polymer A2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.0% by mass of the functional liquid carrier 1-A2, and 93.0% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0160] [Comparative example 1-A3] When the amount of free fumaric acid in porous coordination polymer A3(W) was measured using the above method, it was found to be 0.9% by mass relative to 100% by mass of porous coordination polymer A3(W). Furthermore, the specific surface area of ​​porous coordination polymer A3(W) measured by the BET method was 907 m². 2 The values ​​are per gram, the average pore size is 0.6 nm, and the gas adsorption capacity is 449 cm³. 3 It was / g. Next, using the same method as in Example 1-A1, etofenprox was adsorbed onto the porous coordination polymer A3(W) as a functional sustained-release liquid to obtain functional liquid support 1-A3 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-A3 was 200% by mass relative to 100% by mass of the porous coordination polymer A3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.5% by mass of the functional liquid carrier 1-A3, and 92.5% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 23 μg / cm³. 2 That was the case.

[0161] [Comparative example 1-A4] When the amount of free fumaric acid in porous coordination polymer A4(W) was measured using the method described above, it was found to be 1.1% by mass relative to 100% by mass of porous coordination polymer A4(W). Furthermore, the specific surface area of ​​porous coordination polymer A4(W) measured by the BET method was 908 m². 2 The values ​​are per gram, the average pore size is 0.6 nm, and the gas adsorption capacity is 453 cm³. 3 It was / g. Next, using the same method as in Example 1-A1, etofenprox was adsorbed onto the porous coordination polymer A4(W) as a functional sustained-release liquid to obtain functional liquid support 1-A4 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-A4 was 180% by mass relative to 100% by mass of the porous coordination polymer A4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.8% by mass of the functional liquid carrier 1-A4, and 92.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 28 μg / cm³. 2 That was the case.

[0162] [Comparative Example 1-A5] When the amount of free fumaric acid in porous coordination polymer A5(W) was measured using the above method, it was found to be 1.2% by mass relative to 100% by mass of porous coordination polymer A5(W). Furthermore, the specific surface area of ​​porous coordination polymer A5(W) measured by BET was 904 m². 2The values ​​are per gram, the average pore size is 0.6 nm, and the gas adsorption capacity is 454 cm³. 3 It was / g. Next, using the same method as in Example 1-A1, etofenprox was adsorbed onto the porous coordination polymer A5(W) as a functional sustained-release liquid to obtain functional liquid support 1-A5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-A5 was 170% by mass relative to 100% by mass of the porous coordination polymer A5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 1-A5, and 92.1% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 31 μg / cm³. 2 That was the case.

[0163] [Comparative Examples 1-6] Etofenprox was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as a matrix resin to prepare a functional sustained-release composition (molded body material). Next, a plate-shaped molded body was prepared in the same manner as in Example 1A-1. The mixture was formulated to consist of 5.0% by mass of the functional sustained-release liquid and 95.0% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured to be 21 μg / cm³. 2 That was the case.

[0164] Table 1 shows the adsorption amounts of etofenprox in functional liquid carriers 1-A1 to 1-A5 and the surface amount of etofenprox on the plate-shaped molded bodies. Table 1 also shows the relative change, with the adsorption amount of etofenprox in functional liquid carrier 1-A1 set to 100 and the adsorption amount of etofenprox in functional liquid carrier 1-A5 set to 0. Furthermore, the relative changes for functional liquid carriers 1-A2 to 1-A4 are shown as relative amounts, with the adsorption amount of etofenprox in functional liquid carrier 1-A5 set to 0 and the adsorption amount of etofenprox in functional liquid carrier 1-A1 set to 100. For example, the relative change for functional liquid carrier 1-A2 is calculated as 62 (≒(250-170) / (300-170)x100). In Table 1, EP represents etofenprox.

[0165] [Table 1]

[0166] [Example 2-A1] Functional liquid carrier 2-A1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one (molecular weight 213, Tokyo Chemical Industry Co., Ltd.) as a functional sustained-release liquid, instead of etofenprox, onto the porous coordination polymer A1(W) in Example 1-A1. The adsorption method was the same as in Example 1-A1. When the amount of 2-n-octyl-4-isothiazolin-3-one adsorbed was measured using the above measurement method, the amount of 2-n-octyl-4-isothiazolin-3-one adsorbed on functional liquid carrier 2-A1 was 210% by mass relative to 100% by mass of porous coordination polymer A1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 3.0% by mass of functional liquid carrier 1-A1 and 97.0% by mass of matrix resin (polyethylene resin) per 100% by mass of the functional sustained-release composition. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0167] [Example 2-A2] Functional liquid carrier 2-A2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer A2(W) in Example 1-A2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A2 was 160% by mass relative to 100% by mass of porous coordination polymer A2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.3% by mass of the functional liquid carrier 1-A2, and 96.7% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 11 μg / cm³. 2 That was the case.

[0168] [Comparative example 2-A3] Functional liquid carrier 2-A3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer A3(W) in Example 1-A3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A3 was 140% by mass relative to 100% by mass of porous coordination polymer A3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.4% by mass of the functional liquid carrier 1-A3, and 96.6% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0169] [Comparative example 2-A4] Functional liquid carrier 2-A4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer A4(W) in Example 1-A4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A4 was 110% by mass relative to 100% by mass of porous coordination polymer A4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.8% by mass of the functional liquid carrier 1-A4, and 96.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 17 μg / cm³. 2 That was the case.

[0170] [Comparative Example 2-A5] Functional liquid carrier 2-A5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer A5(W) in Example 1-A5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A5 was 107% by mass relative to 100% by mass of porous coordination polymer A5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.9% by mass of the functional liquid carrier 1-A5, and 96.1% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 18 μg / cm³. 2 That was the case.

[0171] [Comparative Example 2-6] A functional sustained-release composition (molded body material) was prepared by compounding and mixing 2-n-octyl-4-isothiazolin-3-one as a functional sustained-release liquid with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as a matrix resin. Next, a plate-shaped molded body was prepared in the same manner as in Example 2A-1. The mixture was formulated to consist of 2.0% by mass of the functional sustained-release liquid and 98.0% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured to be 12 μg / cm³. 2 That was the case.

[0172] Table 2 shows the adsorption amounts of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-A1 to 2-A5 and the surface amount of 2-n-octyl-4-isothiazolin-3-one on the plate-shaped molded bodies. In addition, Table 2 also shows the relative change, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A5 set to 0. Furthermore, the relative changes in functional liquid carriers 2-A2 to 2-A4 are shown as relative amounts, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A5 being 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-A1 being 100, where 100 is set as the baseline. In Table 2, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0173] [Table 2]

[0174] [Example 3-A1] In Example 1-A1, 4-nonanolide (molecular weight 156, Fujifilm Wako Pure Chemical Industries, Ltd.) was adsorbed onto the porous coordination polymer A1(W) as a functional sustained-release liquid, instead of etofenprox, to obtain a functional liquid carrier 3-A1 with adsorbed 4-nonanolide. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in the functional liquid carrier 3-A1 was 220% by mass relative to 100% by mass of the porous coordination polymer A1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.3% by mass of the functional sustained-release liquid carrier 3-A1, and 92.7% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 5 μg / cm³. 2 That was the case.

[0175] [Example 3-A2] Functional liquid support 3-A2 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer A2(W) in Example 1-A2, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-A2 was 170% by mass relative to 100% by mass of the porous coordination polymer A2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 3-A2, and 92.1% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0176] [Comparative example 3-A3] For the porous coordination polymer A3(W) in Example 1-A3, a functional liquid carrier 3-A3 adsorbed with 4-nonanolide was obtained as a functional slow-release liquid instead of etofenprox. The adsorption method used was the same as that in Example 1-A1. When the adsorption amount of 4-nonanolide was measured by the said measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A3 was 140% by mass with respect to 100% by mass of the porous coordination polymer A3(W). Next, in the same manner as in Example 1-A1, a plate-shaped molded body was produced. For the mixing, with respect to 100% by mass of the functional slow-release composition, 8.6% by mass of the functional liquid carrier 3-A3 and 91.4% by mass of the matrix resin (polyethylene resin) were blended. As a result of measuring the surface amount of the functional slow-release liquid of the produced plate-shaped molded body, it was 8 μg / cm 2 It was.

[0177] [Comparative Example 3-A4] For the porous coordination polymer A4(W) in Example 1-A4, a functional liquid carrier 3-A4 adsorbed with 4-nonanolide was obtained as a functional slow-release liquid instead of etofenprox. The adsorption method used was the same as that in Example 1-A1. When the adsorption amount of 4-nonanolide was measured by the said measurement method, the adsorption amount of 4-nonanolide in the functional liquid carrier 3-A4 was 120% by mass with respect to 100% by mass of the porous coordination polymer A4(W). Next, in the same manner as in Example 1-A1, a plate-shaped molded body was produced. For the mixing, with respect to 100% by mass of the functional slow-release composition, 9.2% by mass of the functional liquid carrier 4-A4 and 90.8% by mass of the matrix resin (polyethylene resin) were blended. As a result of measuring the surface amount of the functional slow-release liquid of the produced plate-shaped molded body, it was 9 μg / cm 2 It was.

[0178] [Comparative Example 3-A5] For the porous coordination polymer A5(W) in Example 1-A5, a functional liquid carrier 3-A5 adsorbed with 4-nonanolid was obtained as a functional sustained-release liquid instead of etofenprox. The adsorption method used was the same as in Example 1-A1. When the adsorption amount of 4-nonanolid was measured by the above measurement method, the adsorption amount of 4-nonanolid in the functional liquid carrier 3-A5 was 90% by mass with respect to 100% by mass of the porous coordination polymer A5(W). Next, a plate-shaped molded body was produced in the same manner as in Example 1-A1. The mixing was carried out by blending 10.6% by mass of the functional liquid carrier 3-A5 and 89.4% by mass of the matrix resin (polyethylene resin) with respect to 100% by mass of the functional sustained-release composition. As a result of measuring the surface amount of the functional sustained-release liquid of the produced plate-shaped molded body, it was 12 μg / cm 2 It was.

[0179] [Comparative Example 3-6] 4-Nonanolid was used as the functional sustained-release liquid, and it was compounded and mixed with a polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to produce a functional sustained-release composition (molded body material). Next, a plate-shaped molded body was produced in the same manner as in Example 3A-1. The mixing was carried out by blending 5.0% by mass of the functional sustained-release liquid and 95.0% by mass of the matrix resin (polyethylene resin). As a result of measuring the surface amount of the functional sustained-release liquid of the produced plate-shaped molded body, it was 8 μg / cm 2 It was.

[0180] Table 3 shows the adsorption amount of 4-nonanolid in the functional liquid carriers 3-A1 to 3-A5 and the surface amount of 4-nonanolid in the plate-shaped molded body. In Table 3, the relative change amount is also shown, with the adsorption amount of 4-nonanolid in the functional liquid carrier 3-A1 taken as 100 and the adsorption amount of 4-nonanolid in the functional liquid carrier 3-A5 taken as 0. The relative change amounts in the functional liquid carriers 3-A2 to 3-A4 are shown as relative amounts when the adsorption amount of 4-nonanolid in the functional liquid carrier 3-A5 is taken as 0 and the adsorption amount of 4-nonanolid in the functional liquid carrier 3-A1 is taken as 100.

[0181] [Table 3]

[0182] [Example 4-A1] Functional liquid support 4-A1 was obtained by adsorbing trimellitic acid ester (molecular weight 547, Tokyo Chemical Industry Co., Ltd.) as a functional sustained-release liquid instead of etofenprox onto the porous coordination polymer A1(W) in Example 1-A1. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-A1 was 290% by mass relative to 100% by mass of the porous coordination polymer A1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.7% by mass of the functional liquid carrier 4-A1, and 92.3% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 11 μg / cm³. 2 That was the case.

[0183] [Example 4-A2] Functional liquid support 4-A2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer A2(W) in Example 1-A2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-A2 was 250% by mass relative to 100% by mass of the porous coordination polymer A2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.0% by mass of the functional liquid carrier 4-A2, and 93.0% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 15 μg / cm³. 2 That was the case.

[0184] [Comparative example 4-A3] Functional liquid support 4-A3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer A3(W) in Example 1-A3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-A3 was 210% by mass relative to 100% by mass of the porous coordination polymer A3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.4% by mass of the functional liquid carrier 4-A3, and 92.6% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 21 μg / cm³. 2 That was the case.

[0185] [Comparative example 4-A4] Functional liquid support 4-A4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer A4(W) in Example 1-A4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-A4 was 160% by mass relative to 100% by mass of the porous coordination polymer A4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 4-A4, and 91.9% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 36 μg / cm³. 2 That was the case.

[0186] [Comparative Example 4-A5] Functional liquid support 4-A5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer A5(W) in Example 1-A5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-A5 was 140% by mass relative to 100% by mass of the porous coordination polymer A5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-A1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.6% by mass of the functional liquid carrier 4-A5, and 91.4% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 47 μg / cm³. 2 That was the case.

[0187] [Comparative Examples 4-6] A functional sustained-release composition (molded body material) was prepared by compounding and mixing trimellitic acid ester as a functional sustained-release liquid with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as a matrix resin. Next, a plate-shaped molded body was prepared in the same manner as in Example 4A-1. The mixture was formulated to consist of 5% by mass of the functional sustained-release liquid and 95% by mass of the matrix resin (polyethylene resin). The surface amount of the functional sustained-release liquid in the prepared plate-shaped molded body was measured to be 18 μg / cm³. 2 That was the case.

[0188] Table 4 shows the adsorption amount of trimellitic acid ester in the functional liquid carriers 4-A1 to 4-A5 and the surface amount in the plate-shaped molded body. In Table 4, the relative change amount is also shown, where the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A1 is taken as 100, and the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A5 is taken as 0. The relative change amounts in the functional liquid carriers 4-A2 to 4-A4 are shown as relative amounts when the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A5 ranges from 0 to the adsorption amount of trimellitic acid ester in the functional liquid carrier 4-A1, which is 100, and is set to 100. In Table 4, TOTM represents trimellitic acid ester.

[0189] [Table 4]

[0190] [Example 1-B1] When the amount of free terephthalic acid in the porous coordination polymer B1(W) was measured by the above method, it was 0.1% by mass based on 100% by mass of the porous coordination polymer B1(W). The specific surface area of the porous coordination polymer B1(W) by the BET method was 2210 m 2 / g, the average pore diameter was 2.5 nm, and the gas adsorption amount was 1001 cm 3 / g. Next, a functional liquid carrier 1-B1 in which etofenprox was adsorbed as a functional sustained-release liquid was obtained on the porous coordination polymer B1(W). The adsorption method used was the same as in Example 1-A1. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-B1 was 320% by mass based on 100% by mass of the porous coordination polymer B1(W). Next, the functional liquid carrier 1-B1 was compounded and mixed with a polyethylene resin ("Novatic UJ310" of Nippon Polyethylene products) as a matrix resin to produce a functional sustained-release composition (molding material). In the mixing, based on 100% by mass of the functional sustained-release composition, the functional liquid carrier 1-B1 was blended at 6.6% by mass and the matrix resin (polyethylene resin) was blended at 93.4% by mass. Also, the compounding process and the method for producing the plate-shaped molded body were carried out in the same manner as A-1. As a result of measuring the surface amount of the functional sustained-release liquid of the produced plate-shaped molded body, it was 10 μg / cm 2 It was.

[0191] [Example 1-B2] When the amount of free terephthalic acid in the porous coordination polymer B2(W) was measured by the above method, it was 0.3% by mass based on 100% by mass of the porous coordination polymer B2(W). Also, the specific surface area of the porous coordination polymer B2(W) by the BET method was 2220 m 2 / g, the average pore diameter was 2.5 nm, and the gas adsorption amount was 1010 cm 3 / g, STP. Next, in the same manner as in Example 1-B1, etofenprox was adsorbed on the porous coordination polymer B2(W) to obtain a functional liquid carrier 1-B2 adsorbed with etofenprox. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid carrier 1-B2 was 260% by mass based on 100% by mass of the porous coordination polymer B2(W). Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In the mixing, based on 100% by mass of the functional sustained-release composition, the functional liquid carrier 1-B2 was blended at 6.9% by mass and the matrix resin (polyethylene resin) was blended at 93.1% by mass. As a result of measuring the surface amount of the functional sustained-release liquid of the produced plate-shaped molded body, it was 15 μg / cm 2 It was.

[0192] [Example 1-B3] When the amount of free terephthalic acid in the porous coordination polymer B3(W) was measured by the above method, it was 0.6% by mass with respect to 100% by mass of the porous coordination polymer B3(W). Also, the specific surface area of the porous coordination polymer B3(W) by the BET method was 2214 m 2 / g, the average pore diameter was 2.5 nm, and the gas adsorption amount was 990 cm 3 / g. Next, in the same manner as in Example 1-B1, etofenprox was adsorbed onto the porous coordination polymer B3(W) as a functional slow-release liquid to obtain a functional liquid-supported material 1-B3 adsorbed with etofenprox. When the adsorption amount of etofenprox was measured by the above measurement method, the adsorption amount of etofenprox in the functional liquid-supported material 1-B3 was 240% by mass with respect to 100% by mass of the porous coordination polymer B3(W). Next, a plate-shaped molded body was produced in the same manner as in Example 1-B1. In the mixing, 7.1% by mass of the functional liquid-supported material 1-B3 and 92.9% by mass of a matrix resin (polyethylene resin) were blended with respect to 100% by mass of the functional slow-release composition. As a result of measuring the surface amount of the functional slow-release liquid of the produced plate-shaped molded body, it was 18 μg / cm 2 .

[0193] [Comparative Example 1-B4] When the amount of free terephthalic acid in the porous coordination polymer B4(W) was measured by the above method, it was 0.8% by mass with respect to 100% by mass of the porous coordination polymer B4(W). Also, the specific surface area of the porous coordination polymer B4(W) by the BET method was 2221 m 2 / g, the average pore diameter was 2.5 nm, and the gas adsorption amount was 995 cm 3 . Next, using the same method as in Example 1-B1, etofenprox was adsorbed onto the porous coordination polymer B4(W) as a functional sustained-release liquid to obtain functional liquid support 1-B4 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-B4 was 170% by mass relative to 100% by mass of the porous coordination polymer B4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 1-B4, and 92.1% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 24 μg / cm³. 2 That was the case.

[0194] [Comparative Example 1-B5] When the amount of free terephthalic acid in porous coordination polymer B5(W) was measured using the above method, it was found to be 0.9% by mass relative to 100% by mass of porous coordination polymer B5(W). Furthermore, the specific surface area of ​​porous coordination polymer B5(W) measured by the BET method was 2224 m². 2 The values ​​are per gram, the average pore size is 2.5 nm, and the gas adsorption capacity is 1003 cm³. 3 It was / g. Next, using the same method as in Example 1-B1, etofenprox was adsorbed onto the porous coordination polymer B5(W) as a functional sustained-release liquid to obtain functional liquid support 1-B5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-B5 was 130% by mass relative to 100% by mass of the porous coordination polymer B5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 1-B5, and 91.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 33 μg / cm³. 2That was the case.

[0195] Table 5 shows the amount of etofenprox adsorbed in functional liquid carriers 1-B1 to 1-B5 and the surface amount of etofenprox on the sheet-like molded body. In addition, Table 5 also shows the relative change, with the amount of etofenprox adsorbed in functional liquid carrier 1-B1 set to 100 and the amount of etofenprox adsorbed in functional liquid carrier 1-B5 set to 0. Furthermore, the relative change for functional liquid carriers 1-B2 to 1-B4 is shown as a relative amount, with the amount of etofenprox adsorbed in functional liquid carrier 1-B5 (0) and the amount of etofenprox adsorbed in functional liquid carrier 1-B1 (100) set to 100.

[0196] [Table 5]

[0197] [Example 2-B1] Functional liquid carrier 2-B1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer B1(W) in Example 1-B1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B1 was 280% by mass relative to 100% by mass of porous coordination polymer B1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 2.7% by mass of the functional liquid carrier 2-B1, and 97.3% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0198] [Example 2-B2] Functional liquid carrier 2-B2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer B2(W) in Example 1-B2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B2 was 240% by mass relative to 100% by mass of porous coordination polymer B2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 2.8% by mass of the functional liquid carrier 2-B2, and 97.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0199] [Example 2-B3] Functional liquid carrier 2-B3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer B3(W) in Example 1-B3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B3 was 210% by mass relative to 100% by mass of porous coordination polymer B3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.0% by mass of the functional liquid carrier 2-B3, and 97.0% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0200] [Comparative example 2-B4] Functional liquid carrier 2-B4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer B4(W) in Example 1-B4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B4 was 150% by mass relative to 100% by mass of porous coordination polymer B4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.3% by mass of the functional liquid carrier 2-B4, and 96.7% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 13 μg / cm³. 2 That was the case.

[0201] [Comparative Example 2-B5] Functional liquid carrier 2-B5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer B5(W) in Example 1-B5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B5 was 120% by mass relative to 100% by mass of porous coordination polymer B5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.7% by mass of the functional liquid carrier 2-B5, and 96.3% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 μg / cm³. 2 That was the case.

[0202] Table 6 shows the adsorption amounts of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-B1 to 2-B5 and the OIT surface area of ​​the plate-shaped molded body. In addition, Table 6 also shows the relative change amount, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 2-B2 to 2-B4 are shown as relative amounts, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B5 set to 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-B1 set to 100. In Table 6, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0203] [Table 6]

[0204] [Example 3-B1] Functional liquid support 3-B1 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid instead of etofenprox onto the porous coordination polymer B1(W) in Example 1-B1. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-B1 was 210% by mass relative to 100% by mass of the porous coordination polymer B1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 7.4% by mass of functional liquid carrier 3-B1 and 92.6% by mass of matrix resin (polyethylene resin) per 100% by mass of the functional sustained-release composition. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0205] [Example 3-B2] Functional liquid support 3-B2 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer B2(W) in Example 1-B2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-B2 was 160% by mass relative to 100% by mass of the porous coordination polymer B2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 3-B2, and 91.9% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0206] [Example 3-B3] Functional liquid carrier 3-B3 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer B3(W) in Example 1-B3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid carrier 3-B3 was 150% by mass relative to 100% by mass of the porous coordination polymer B3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 3-B3, and 91.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0207] [Comparative example 3-B4] Functional liquid support 3-B4 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer B4(W) in Example 1-B4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-B4 was 120% by mass relative to 100% by mass of the porous coordination polymer B4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.2% by mass of the functional liquid carrier 3-B4, and 90.8% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0208] [Comparative Example 3-B5] Functional liquid support 3-B5 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer B5(W) in Example 1-B5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-B5 was 90% by mass relative to 100% by mass of the porous coordination polymer B5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 10.6% by mass of functional liquid carrier 3-B5 and 89.4% by mass of matrix resin (polyethylene resin) relative to 100% by mass of the functional sustained-release composition. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured to be 12 g / cm³. 2 That was the case.

[0209] Table 7 shows the adsorption amounts of 4-nonanolide in functional liquid carriers 3-B1 to 3-B5 and the OIT surface area in the plate-shaped molded bodies. In addition, Table 7 also shows the relative change amount, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-B1 set to 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-B5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 3-B2 to 3-B4 are shown as relative amounts, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-B5 (0) and the adsorption amount of 4-nonanolide in functional liquid carrier 3-B1 (100) set to 100.

[0210] [Table 7]

[0211] [Example 4-B1] Functional liquid support 4-B1 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer B1(W) in Example 1-B1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-B1 was 280% by mass relative to 100% by mass of the porous coordination polymer B1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.8% by mass of the functional liquid carrier 4-B1, and 93.2% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 13 g / cm³. 2 That was the case.

[0212] [Example 4-B2] Functional liquid support 4-B2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer B2(W) in Example 1-B2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-B2 was 230% by mass relative to 100% by mass of the porous coordination polymer B2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.2% by mass of the functional liquid carrier 4-B2, and 92.8% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 15 g / cm³. 2 That was the case.

[0213] [Example 4-B3] Functional liquid support 4-B3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer B3(W) in Example 1-B3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-B3 was 200% by mass relative to 100% by mass of the porous coordination polymer B3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.5% by mass of the functional liquid carrier 4-B3, and 92.5% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 g / cm³. 2 That was the case.

[0214] [Comparative example 4-B4] Functional liquid support 4-B4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer B4(W) in Example 1-B4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-B4 was 160% by mass relative to 100% by mass of the porous coordination polymer B4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 4-B4, and 91.9% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 19 g / cm³. 2 That was the case.

[0215] [Comparative Example 4-B5] Functional liquid support 4-B5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer B5(W) in Example 1-B5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-B5 was 110% by mass relative to 100% by mass of the porous coordination polymer B5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-B1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.5% by mass of the functional liquid carrier 4-B5, and 90.5% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 25 g / cm³. 2 That was the case.

[0216] Table 8 shows the adsorption amounts of trimellitic acid ester in functional liquid carriers 4-B1 to 4-B5 and the surface amount of trimellitic acid ester on the plate-shaped molded bodies. Table 8 also shows the relative change, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-B1 set to 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-B5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 4-B2 to 4-B4 are shown as relative amounts, with the adsorption amount from 0 in functional liquid carrier 4-B5 to 100 in functional liquid carrier 4-B1 set to 100. In Table 8, TOTM represents trimellitic acid ester.

[0217] [Table 8]

[0218] [Example 1-C1] When the amount of free terephthalic acid in porous coordination polymer C1(W) was measured by the above method, it was found to be 0.1% by mass relative to 100% by mass of porous coordination polymer C1(W). Furthermore, the specific surface area of ​​porous coordination polymer C1(W) by the BET method was 1004 m². 2 The values ​​are per g, the average pore size is 0.9 nm, and the gas adsorption capacity is 644 cm³. 3 It was / g. Next, a functional liquid support 1-C1 was obtained by adsorbing etofenprox as a functional sustained-release liquid onto the porous coordination polymer C1(W). The adsorption method was the same as in Example 1-A1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed on the functional liquid support 1-C1 was 280% by mass relative to 100% by mass of the porous coordination polymer C1(W). Next, functional liquid carrier 1-C1 was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to prepare a functional sustained-release composition (molded body material). The mixing was performed so that the functional liquid carrier 1-C1 was 6.8% by mass and the matrix resin (polyethylene resin) was 93.2% by mass, based on 100% by mass of the functional sustained-release composition. The compounding process and the preparation of the plate-shaped molded body were carried out in the same manner as in A-1. The surface amount of the functional sustained-release liquid in the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0219] [Example 1-C2] When the amount of free terephthalic acid in porous coordination polymer C2(W) was measured using the method described above, it was found to be 0.3% by mass relative to 100% by mass of porous coordination polymer C2(W). Furthermore, the specific surface area of ​​porous coordination polymer C2(W) measured by the BET method was 1006 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 656 cm³. 3 It was / g. Next, using the same method as in Example 1-C1, etofenprox was adsorbed onto the porous coordination polymer C2(W) as a functional sustained-release liquid to obtain functional liquid support 1-C2 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-C2 was 270% by mass relative to 100% by mass of the porous coordination polymer C2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.9% by mass of the functional liquid carrier 1-C2, and 93.1% by mass of the matrix resin (polyethylene resin). The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 13 μg / cm³. 2 That was the case.

[0220] [Example 1-C3] When the amount of free terephthalic acid in porous coordination polymer C3(W) was measured using the method described above, it was found to be 0.5% by mass relative to 100% by mass of porous coordination polymer C3(W). Furthermore, the specific surface area of ​​porous coordination polymer C3(W) measured by the BET method was 1043 m². 2 The values ​​are per g, the average pore size is 0.9 nm, and the gas adsorption capacity is 643 cm³. 3 It was / g. Next, using the same method as in Example 1-C1, etofenprox was adsorbed onto the porous coordination polymer C3(W) as a functional sustained-release liquid to obtain functional liquid support 1-C3 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-C3 was 240% by mass relative to 100% by mass of the porous coordination polymer C3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.1% by mass of the functional liquid carrier 1-C3, and 92.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 μg / cm³. 2 That was the case.

[0221] [Comparative example 1-C4] When the amount of free terephthalic acid in porous coordination polymer C4(W) was measured by the above method, it was found to be 0.8% by mass relative to 100% by mass of porous coordination polymer C4(W). Furthermore, the specific surface area of ​​porous coordination polymer C4(W) by the BET method was 1050 m². 2 The values ​​are per g, the average pore size is 0.9 nm, and the gas adsorption capacity is 650 cm³. 3 There was / g. Next, using the same method as in Example 1-C1, etofenprox was adsorbed onto the porous coordination polymer C4(W) as a functional sustained-release liquid to obtain functional liquid support 1-C4 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-C4 was 190% by mass relative to 100% by mass of the porous coordination polymer C4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.6% by mass of the functional liquid carrier 1-C4, and 92.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 26 μg / cm³. 2 That was the case.

[0222] [Comparative example 1-C5] When the amount of free terephthalic acid in porous coordination polymer C5(W) was measured by the above method, it was found to be 0.9% by mass relative to 100% by mass of porous coordination polymer C5(W). Furthermore, the specific surface area of ​​porous coordination polymer C5(W) measured by the BET method was 1051 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 651 cm³. 3 It was / g. Next, using the same method as in Example 1-C1, etofenprox was adsorbed onto the porous coordination polymer C5(W) as a functional sustained-release liquid to obtain functional liquid support 1-C5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-C5 was 170% by mass relative to 100% by mass of the porous coordination polymer C5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 1-C5, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 33 μg / cm³. 2 That was the case.

[0223] Table 9 shows the amount of etofenprox adsorbed in functional liquid carriers 1-C1 to 1-C5 and the amount of etofenprox on the plate-shaped molded body. In addition, Table 9 also shows the relative change, with the amount of etofenprox adsorbed in functional liquid carrier 1-C1 set to 100 and the amount of etofenprox adsorbed in functional liquid carrier 1-C5 set to 0. Furthermore, the relative change for functional liquid carriers 1-C2 to 1-C4 is shown as a relative amount, with the amount of etofenprox adsorbed in functional liquid carrier 1-C5 (0) and the amount of etofenprox adsorbed in functional liquid carrier 1-C1 (100) set to 100.

[0224] [Table 9]

[0225] [Example 2-C1] Functional liquid carrier 2-C1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer C1(W) in Example 1-C1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C1 was 200% by mass relative to 100% by mass of the porous coordination polymer C1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 2-C1, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0226] [Example 2-C2] Functional liquid carrier 2-C2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer C2(W) in Example 1-C2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C2 was 190% by mass relative to 100% by mass of porous coordination polymer C2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 2-C2, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0227] [Example 2-C3] Functional liquid carrier 2-C3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer C3(W) in Example 1-C3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C3 was 160% by mass relative to 100% by mass of porous coordination polymer C3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.3% by mass of the functional liquid carrier 2-C3, and 96.7% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 11 μg / cm³. 2 That was the case.

[0228] [Comparative example 2-C4] Functional liquid carrier 2-C4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer C4(W) in Example 1-C4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C4 was 140% by mass relative to 100% by mass of the porous coordination polymer C4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.4% by mass of the functional liquid carrier 2-C4, and 96.6% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 13 μg / cm³.2 That was the case.

[0229] [Comparative example 2-C5] Functional liquid carrier 2-C5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer C5(W) in Example 1-C5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C5 was 120% by mass relative to 100% by mass of porous coordination polymer C5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.7% by mass of the functional liquid carrier 2-C5, and 96.3% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 15 μg / cm³. 2 That was the case.

[0230] Table 10 shows the adsorption amounts of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-C1 to 2-C5 and the surface amount of 2-n-octyl-4-isothiazolin-3-one in the plate-shaped molded product. In addition, Table 10 also shows the relative change, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C5 set to 0. Furthermore, the relative change in functional liquid carriers 2-C2 to 2-C4 is shown as a relative amount, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C5 being 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-C1 being 100. In Table 10, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0231] [Table 10]

[0232] [Example 3-C1] In Example 1-C1, 4-nonanolide was adsorbed onto the porous coordination polymer C1(W) instead of etofenprox as the functional sustained-release liquid to obtain a functional liquid support 3-C1 with adsorbed 4-nonanolide. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in the functional liquid support 3-C1 was 170% by mass relative to 100% by mass of the porous coordination polymer C1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 3-C1, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0233] [Example 3-C2] In Example 1-C2, 4-nonanolide was adsorbed onto the porous coordination polymer C2(W) instead of etofenprox as the functional sustained-release liquid to obtain a functional liquid carrier 3-C2 with adsorbed 4-nonanolide. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in the functional liquid carrier 3-C2 was 160% by mass relative to 100% by mass of the porous coordination polymer C2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 3-C2, and 91.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0234] [Example 3-C3] Functional liquid support 3-C3 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer C3(W) in Example 1-C3, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-C3 was 140% by mass relative to 100% by mass of the porous coordination polymer C3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.6% by mass of the functional liquid carrier 3-C3, and 91.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0235] [Comparative example 3-C4] Functional liquid support 3-C4 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer C4(W) in Example 1-C4, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-C4 was 120% by mass relative to 100% by mass of the porous coordination polymer C4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.2% by mass of the functional liquid carrier 3-C4, and 90.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0236] [Comparative example 3-C5] Functional liquid support 3-C5 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer C5(W) in Example 1-C5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-C5 was 100% by mass relative to 100% by mass of the porous coordination polymer C5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 10.0% by mass of the functional liquid carrier 3-C5, and 90.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0237] Table 11 shows the adsorption amounts of 4-nonanolide in functional liquid carriers 3-C1 to 3-C5 and the surface amount of 4-nonanolide in the plate-shaped molded product. In addition, Table 11 also shows the relative change amount, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-C1 set to 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-C5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 3-C2 to 3-C4 are shown as relative amounts, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-C5 (0) to the adsorption amount of 4-nonanolide in functional liquid carrier 3-C1 (100) set to 100.

[0238] [Table 11]

[0239] [Example 4-C1] Functional liquid support 4-C1 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer C1(W) in Example 1-C1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-C1 was 240% by mass relative to 100% by mass of the porous coordination polymer C1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.1% by mass of the functional liquid carrier 4-C1, and 92.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0240] [Example 4-C2] Functional liquid support 4-C2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer C2(W) in Example 1-C2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-C2 was 220% by mass relative to 100% by mass of the porous coordination polymer C2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.3% by mass of the functional liquid carrier 4-C2, and 92.7% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³. 2 That was the case.

[0241] [Example 4-C3] Functional liquid support 4-C3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer C3(W) in Example 1-C3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-C3 was 200% by mass relative to 100% by mass of the porous coordination polymer C3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.5% by mass of the functional liquid carrier 4-C3, and 92.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 17 μg / cm³. 2 That was the case.

[0242] [Comparative example 4-C4] Functional liquid support 4-C4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer C4(W) in Example 1-C4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-C4 was 170% by mass relative to 100% by mass of the porous coordination polymer C4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 4-C4, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 22 μg / cm³. 2 That was the case.

[0243] [Comparative Example 4-C5] Functional liquid support 4-C5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer C5(W) in Example 1-C5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-C5 was 150% by mass relative to 100% by mass of the porous coordination polymer C5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-C1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 4-C5, and 91.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 27 μg / cm³. 2 That was the case.

[0244] Table 12 shows the adsorption amounts of trimellitic acid ester in functional liquid carriers 4-C1 to 4-C5 and the surface amount of trimellitic acid ester in the plate-shaped molded product. Table 12 also shows the relative change, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-C1 set to 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-C5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 4-C2 to 4-C4 are shown as relative amounts, with the adsorption amount from 0 in functional liquid carrier 4-C5 to 100 in functional liquid carrier 4-C1 set to 100. In Table 12, TOTM represents trimellitic acid ester.

[0245] [Table 12]

[0246] [Example 1-D1] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer D1(W) using the method described above, it was found to be 0.2% by mass relative to 100% by mass of the porous coordination polymer D1(W). Furthermore, the specific surface area of ​​the porous coordination polymer D1(W) measured by the BET method was 1607 m². 2 The values ​​are per g, the average pore size is 2.6 nm, and the gas adsorption capacity is 703 cm³. 3 It was / g. Next, a functional liquid support 1-D1 was obtained by adsorbing etofenprox as a functional sustained-release liquid onto the porous coordination polymer D1(W). The adsorption method was the same as in Example 1-A1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed on the functional liquid support 1-D1 was 320% by mass relative to 100% by mass of the porous coordination polymer D1(W). Next, functional liquid carrier 1-D1 was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to prepare a functional sustained-release composition (molded body material). The mixing was performed so that the functional liquid carrier 1-D1 comprised 6.6% by mass and the matrix resin (polyethylene resin) comprised 93.4% by mass, based on 100% by mass of the functional sustained-release composition. The compounding process and the preparation of the plate-shaped molded body were carried out in the same manner as in A-1. The surface amount of the functional sustained-release liquid in the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0247] [Example 1-D2] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer D2(W) using the method described above, it was found to be 0.3% by mass relative to 100% by mass of the porous coordination polymer D2(W). Furthermore, the specific surface area of ​​the porous coordination polymer D2(W) measured by the BET method was 1610 m². 2 The values ​​are per gram, the average pore size is 2.6 nm, and the gas adsorption capacity is 710 cm³. 3 It was / g. Next, functional liquid support 1-D2 was obtained by adsorbing etofenprox onto porous coordination polymer D2(W) using the same method as in Example 1-D1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-D2 was 280% by mass relative to 100% by mass of porous coordination polymer D2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.6% by mass of the functional liquid carrier 1-D2, and 93.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³. 2 That was the case.

[0248] [Example 1-D3] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer D3(W) using the method described above, it was found to be 0.6% by mass relative to 100% by mass of the porous coordination polymer D3(W). Furthermore, the specific surface area of ​​the porous coordination polymer D3(W) measured by the BET method was 1619 m². 2 The values ​​are per gram, the average pore size is 2.6 nm, and the gas adsorption capacity is 689 cm³. 3 It was / g. Next, using the same method as in Example 1-D1, etofenprox was adsorbed onto the porous coordination polymer D3(W) as a functional sustained-release liquid to obtain functional liquid carrier 1-D3 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid carrier 1-D3 was 250% by mass relative to 100% by mass of the porous coordination polymer D3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.8% by mass of the functional liquid carrier 1-D3, and 93.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³. 2 That was the case.

[0249] [Comparative Example 1-D4] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer D4(W) using the method described above, it was found to be 0.8% by mass relative to 100% by mass of the porous coordination polymer D4(W). Furthermore, the specific surface area of ​​the porous coordination polymer D4(W) measured by the BET method was 1625 m². 2 The values ​​are per gram, the average pore size is 2.6 nm, and the gas adsorption capacity is 695 cm³. 3 It was / g. Next, functional liquid support 1-D4 was obtained by adsorbing etofenprox onto porous coordination polymer D4(W) using the same method as in Example 1-D1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-D4 was 180% by mass relative to 100% by mass of porous coordination polymer D4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.0% by mass of the functional liquid carrier 1-D4, and 93.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 23 μg / cm³. 2 That was the case.

[0250] [Comparative Example 1-D5] When the amount of free 1,3,5-benzenetricarboxylic acid relative to the porous coordination polymer D5(W) was measured by the above method, it was found to be 0.9% by mass relative to 100% by mass of the porous coordination polymer D5(W). Furthermore, the specific surface area of ​​the porous coordination polymer D5(W) measured by the BET method was 1624 m². 2 The values ​​are per gram, the average pore size is 2.6 nm, and the gas adsorption capacity is 694 cm³. 3 It was / g. Next, using the same method as in Example 1-D1, etofenprox was adsorbed onto the porous coordination polymer D5(W) as a functional sustained-release liquid to obtain functional liquid support 1-D5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-D5 was 160% by mass relative to 100% by mass of the porous coordination polymer D5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.8% by mass of the functional liquid carrier 1-D5, and 92.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 37 μg / cm³. 2 That was the case.

[0251] Table 13 shows the amount of etofenprox adsorbed in functional liquid carriers 1-D1 to 1-D5 and the surface area of ​​the plate-shaped molded composition. In addition, Table 13 also shows the relative change, with the amount of etofenprox adsorbed in functional liquid carrier 1-D1 set to 100 and the amount of etofenprox adsorbed in functional liquid carrier 1-D5 set to 0. Furthermore, the relative change for functional liquid carriers 1-D2 to 1-D4 is shown as a relative amount, with the amount of etofenprox adsorbed in functional liquid carrier 1-D5 (0) and the amount of etofenprox adsorbed in functional liquid carrier 1-D1 (100) set to 100.

[0252] [Table 13]

[0253] [Example 2-D1] Functional liquid carrier 2-D1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer D1(W) in Example 1-D1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D1 was 240% by mass relative to 100% by mass of the porous coordination polymer D1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 2.8% by mass of the functional liquid carrier 2-D1, and 97.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0254] [Example 2-D2] Functional liquid carrier 2-D2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer D2(W) in Example 1-D2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D2 was 220% by mass relative to 100% by mass of the porous coordination polymer D2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.0% by mass of the functional liquid carrier 2-D2, and 97.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0255] [Example 2-D3] Functional liquid carrier 2-D3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer D3(W) in Example 1-D3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D3 was 180% by mass relative to 100% by mass of the porous coordination polymer D3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.1% by mass of the functional liquid carrier 2-D3, and 96.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0256] [Comparative Example 2-D4] Functional liquid carrier 2-D4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer D4(W) in Example 1-D4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D4 was 120% by mass relative to 100% by mass of the porous coordination polymer D4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.7% by mass of the functional liquid carrier 2-D4, and 96.3% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 15 μg / cm³.2 That was the case.

[0257] [Comparative Example 2-D5] Functional liquid carrier 2-D5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer D5(W) in Example 1-D5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D5 was 110% by mass relative to 100% by mass of the porous coordination polymer D5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.8% by mass of the functional liquid carrier 2-D5, and 96.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 18 μg / cm³. 2 That was the case.

[0258] Table 14 shows the adsorption amounts of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-D1 to 2-D5 and the surface amount of 2-n-octyl-4-isothiazolin-3-one in the plate-shaped molded products. In addition, Table 14 also shows the relative change, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D5 set to 0. Furthermore, the relative changes in functional liquid carriers 2-D2 to 2-D4 are shown as relative amounts, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D5 being 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-D1 being 100, where 100 is set as the baseline. In Table 14, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0259] [Table 14]

[0260] [Example 3-D1] Functional liquid carrier 3-D1 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer D1(W) in Example 1-D1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid carrier 3-D1 was 230% by mass relative to 100% by mass of the porous coordination polymer D1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.2% by mass of the functional liquid carrier 3-D1, and 92.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0261] [Example 3-D2] Functional liquid carrier 3-D2 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer D2(W) in Example 1-D2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid carrier 3-D2 was 210% by mass relative to 100% by mass of the porous coordination polymer D2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.4% by mass of the functional liquid carrier 3-D2, and 92.6% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0262] [Example 3-D3] Functional liquid support 3-D3 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid instead of etofenprox onto the porous coordination polymer D3(W) in Example 1-D3. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-D3 was 170% by mass relative to 100% by mass of the porous coordination polymer D3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 3-D3, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0263] [Comparative Example 3-D4] Functional liquid support 3-D4 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer D4(W) in Example 1-D4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-D4 was 130% by mass relative to 100% by mass of the porous coordination polymer D4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 3-D4, and 91.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0264] [Comparative Example 3-D5] Functional liquid support 3-D5 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer D5(W) in Example 1-D5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-D5 was 110% by mass relative to 100% by mass of the porous coordination polymer D5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.5% by mass of the functional liquid carrier 3-D5, and 90.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0265] Table 15 shows the adsorption amounts of 4-nonanolide in functional liquid carriers 3-D1 to 3-D5 and the surface area of ​​the plate-shaped molded product. In addition, Table 15 also shows the relative change amount, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-D1 set to 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-D5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 3-D2 to 3-D4 are shown as relative amounts, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-D5 (0) and the adsorption amount of 4-nonanolide in functional liquid carrier 3-D1 (100) set to 100.

[0266] [Table 15]

[0267] [Example 4-D1] Functional liquid support 4-D1 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer D1(W) in Example 1-D1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-D1 was 330% by mass relative to 100% by mass of the porous coordination polymer D1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.5% by mass of the functional liquid carrier 4-D1, and 93.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0268] [Example 4-D2] Functional liquid support 4-D2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer D2(W) in Example 1-D2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-D2 was 310% by mass relative to 100% by mass of the porous coordination polymer D2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.6% by mass of the functional liquid carrier 4-D2, and 93.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0269] [Example 4-D3] Functional liquid support 4-D3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer D3(W) in Example 1-D3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-D3 was 260% by mass relative to 100% by mass of the porous coordination polymer D3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 6.9% by mass of the functional liquid carrier 4-D3, and 93.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 18 μg / cm³. 2 That was the case.

[0270] [Comparative Example 4-D4] Functional liquid support 4-D4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer D4(W) in Example 1-D4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-D4 was 190% by mass relative to 100% by mass of the porous coordination polymer D4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.6% by mass of the functional liquid carrier 4-D4, and 92.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 33 μg / cm³. 2 That was the case.

[0271] [Comparative Example 4-D5] Functional liquid support 4-D5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer D5(W) in Example 1-D5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-D5 was 160% by mass relative to 100% by mass of the porous coordination polymer D5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-D1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 4-D5, and 91.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 58 μg / cm³. 2 That was the case.

[0272] Table 16 shows the adsorption amounts of trimellitic acid ester in functional liquid carriers 4-D1 to 4-D5 and the surface area of ​​the plate-shaped molded product. In addition, Table 16 also shows the relative change amount, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D1 set to 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 4-D2 to 4-D4 are shown as relative amounts, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D5 (0) and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-D1 (100) set to 100. In Table 16, TOTM represents trimellitic acid ester.

[0273] [Table 16]

[0274] [Example 1-E1] When the amount of free 1,3,5-benzenetricarboxylic acid relative to the porous coordination polymer E1(W) was measured by the above method, it was found to be 0.1% by mass relative to 100% by mass of the porous coordination polymer E1(W). Furthermore, the specific surface area of ​​the porous coordination polymer E1(W) by the BET method was 1534 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 346 cm³. 3 It was / g. Next, a functional liquid support 1-E1 was obtained by adsorbing etofenprox onto the porous coordination polymer E1(W). The adsorption method was the same as in Example 1-A1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in the functional liquid support 1-E1 was 270% by mass relative to 100% by mass of the porous coordination polymer E1(W). Next, functional liquid carrier 1-E1 was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to prepare a functional sustained-release composition (molded body material). The mixing was performed so that the functional liquid carrier 1-E1 was 6.9% by mass and the matrix resin (polyethylene resin) was 93.1% by mass per 100% by mass of the functional sustained-release composition. The compounding process and the preparation of the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0275] [Example 1-E2] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer E2(W) using the method described above, it was found to be 0.3% by mass relative to 100% by mass of the porous coordination polymer E2(W). Furthermore, the specific surface area of ​​the porous coordination polymer E2(W) measured by the BET method was 1531 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 361 cm³. 3 It was / g. Next, using the same method as in Example 1-E1, etofenprox was adsorbed onto the porous coordination polymer E2(W) as a functional sustained-release liquid to obtain functional liquid support 1-E2 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-E2 was 230% by mass relative to 100% by mass of the porous coordination polymer E2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.2% by mass of the functional liquid carrier 1-E2, and 92.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³. 2 That was the case.

[0276] [Example 1-E3] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer E3(W) using the method described above, it was found to be 0.6% by mass relative to 100% by mass of the porous coordination polymer E3(W). Furthermore, the specific surface area of ​​the porous coordination polymer E3(W) measured by the BET method was 1623 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 352 cm³. 3 It was / g. Next, using the same method as in Example 1-E1, etofenprox was adsorbed onto the porous coordination polymer E3(W) as a functional sustained-release liquid to obtain functional liquid support 1-E3 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-E3 was 210% by mass relative to 100% by mass of the porous coordination polymer E3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.4% by mass of the functional liquid carrier 1-E3, and 92.6% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 17 μg / cm³. 2 That was the case.

[0277] [Comparative Example 1-E4] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer E4(W) using the method described above, it was found to be 0.7% by mass relative to 100% by mass of the porous coordination polymer E4(W). Furthermore, the specific surface area of ​​the porous coordination polymer E4(W) measured by the BET method was 1536 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 356 cm³. 3 It was / g. Next, functional liquid support 1-E4 was obtained by adsorbing etofenprox onto porous coordination polymer E4(W) using the same method as in Example 1-E1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-E4 was 160% by mass relative to 100% by mass of porous coordination polymer E4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 1-E4, and 91.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 28 μg / cm³. 2 That was the case.

[0278] [Comparative Example 1-E5] When the amount of free 1,3,5-benzenetricarboxylic acid was measured relative to the porous coordination polymer E5(W) using the method described above, it was found to be 0.9% by mass relative to 100% by mass of the porous coordination polymer E5(W). Furthermore, the specific surface area of ​​the porous coordination polymer E5(W) measured by the BET method was 1534 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 349 cm³. 3 It was / g. Next, using the same method as in Example 1-E1, etofenprox was adsorbed onto the porous coordination polymer E5(W) as a functional sustained-release liquid to obtain functional liquid support 1-E5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-E5 was 150% by mass relative to 100% by mass of the porous coordination polymer E5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.3% by mass of the functional liquid carrier 1-E5, and 91.7% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 32 μg / cm³. 2 That was the case.

[0279] Table 17 shows the amount of etofenprox adsorbed in functional liquid carriers 1-E1 to 1-E5 and the amount of etofenprox on the surface of the plate-shaped molded body. In addition, Table 17 also shows the relative change, with the amount of etofenprox adsorbed in functional liquid carrier 1-E1 set to 100 and the amount of etofenprox adsorbed in functional liquid carrier 1-E5 set to 0. Furthermore, the relative change for functional liquid carriers 1-E2 to 1-E4 is shown as a relative amount, with the amount of etofenprox adsorbed in functional liquid carrier 1-E5 (0) and the amount of etofenprox adsorbed in functional liquid carrier 1-E1 (100) set to 100.

[0280] [Table 17]

[0281] [Example 2-E1] Functional liquid carrier 2-E1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer E1(W) in Example 1-E1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E1 was 230% by mass relative to 100% by mass of the porous coordination polymer E1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 2.9% by mass of the functional liquid carrier 2-E1, and 97.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0282] [Example 2-E2] Functional liquid carrier 2-E2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer E2(W) in Example 1-E2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E2 was 210% by mass relative to 100% by mass of the porous coordination polymer E2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.0% by mass of the functional liquid carrier 2-E2, and 97.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0283] [Example 2-E3] Functional liquid carrier 2-E3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer E3(W) in Example 1-E3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E3 was 180% by mass relative to 100% by mass of the porous coordination polymer E3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.3% by mass of the functional liquid carrier 2-E3, and 96.7% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 11 μg / cm³. 2 That was the case.

[0284] [Comparative Example 2-E4] Functional liquid carrier 2-E4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer E4(W) in Example 1-E4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E4 was 130% by mass relative to 100% by mass of the porous coordination polymer E4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.5% by mass of the functional liquid carrier 2-E4, and 96.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³.2 That was the case.

[0285] [Comparative Example 2-E5] Functional liquid carrier 2-E5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer E5(W) in Example 1-E5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E5 was 120% by mass relative to 100% by mass of the porous coordination polymer E5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.7% by mass of the functional liquid carrier 2-E5, and 96.3% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 μg / cm³. 2 That was the case.

[0286] Table 18 shows the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carriers 2-E1 to 2-E5 and the surface amount in the plate-shaped molded product. In addition, Table 18 also shows the relative change amount, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 2-E2 to 2-E4 are shown as relative amounts, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E5 set to 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-E1 set to 100. In Table 18, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0287] [Table 18]

[0288] [Example 3-E1] Functional liquid support 3-E1 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid instead of etofenprox onto the porous coordination polymer E1(W) in Example 1-E1. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-E1 was 210% by mass relative to 100% by mass of the porous coordination polymer E1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.4% by mass of the functional liquid carrier 3-E1, and 92.6% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0289] [Example 3-E2] Functional liquid support 3-E2 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer E2(W) in Example 1-E2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-E2 was 180% by mass relative to 100% by mass of the porous coordination polymer E2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.8% by mass of the functional liquid carrier 3-E2, and 92.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0290] [Example 3-E3] Functional liquid support 3-E3 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer E3(W) in Example 1-E3, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-E3 was 160% by mass relative to 100% by mass of the porous coordination polymer E3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 3-E3, and 91.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0291] [Comparative Example 3-E4] Functional liquid support 3-E4 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer E4(W) in Example 1-E4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-E4 was 130% by mass relative to 100% by mass of the porous coordination polymer E4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 3-E4, and 91.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0292] [Comparative Example 3-E5] Functional liquid support 3-E5 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer E5(W) in Example 1-E5, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-E5 was 100% by mass relative to 100% by mass of the porous coordination polymer E5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 10.0% by mass of the functional liquid carrier 3-E5, and 90.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0293] Table 19 shows the adsorption amounts of 4-nonanolide in functional liquid carriers 3-E1 to 3-E5 and the surface area of ​​the plate-shaped molded product. In addition, Table 19 also shows the relative change amount, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-E1 set to 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-E5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 3-E2 to 3-E4 are shown as relative amounts, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-E5 (0) and the adsorption amount of 4-nonanolide in functional liquid carrier 3-E1 (100) set to 100.

[0294] [Table 19]

[0295] [Example 4-E1] Functional liquid support 4-E1 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer E1(W) in Example 1-E1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-E1 was 250% by mass relative to 100% by mass of the porous coordination polymer E1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.0% by mass of the functional liquid carrier 4-E1, and 93.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0296] [Example 4-E2] Functional liquid support 4-E2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer E2(W) in Example 1-E2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-E2 was 210% by mass relative to 100% by mass of the porous coordination polymer E2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.4% by mass of the functional liquid carrier 4-E2, and 92.6% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 14 μg / cm³. 2 That was the case.

[0297] [Example 4-E3] Functional liquid support 4-E3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer E3(W) in Example 1-E3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-E3 was 200% by mass relative to 100% by mass of the porous coordination polymer E3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.5% by mass of the functional liquid carrier 4-E3, and 92.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 μg / cm³. 2 That was the case.

[0298] [Comparative Example 4-E4] Functional liquid support 4-E4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer E4(W) in Example 1-E4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-E4 was 170% by mass relative to 100% by mass of the porous coordination polymer E4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 4-E4, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 22 μg / cm³. 2 That was the case.

[0299] [Comparative Example 4-E5] Functional liquid support 4-E5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer E5(W) in Example 1-E5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-E5 was 130% by mass relative to 100% by mass of the porous coordination polymer E5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-E1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.8% by mass of the functional liquid carrier 4-E5, and 91.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 46 μg / cm³. 2 That was the case.

[0300] Table 20 shows the adsorption amounts of trimellitic acid ester in functional liquid carriers 4-E1 to 4-E5 and the surface area of ​​the plate-shaped molded body. In addition, Table 20 also shows the relative change amount, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E1 set to 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 4-E2 to 4-E4 are shown as relative amounts, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E5 (0) to the adsorption amount of trimellitic acid ester in functional liquid carrier 4-E1 (100) set to 100. In Table 20, TOTM represents trimellitic acid ester.

[0301] [Table 20]

[0302] [Example 1-F1] When the amount of free 2-methylimidazole in porous coordination polymer F1(W) was measured by the above method, it was found to be 0.3% by mass relative to 100% by mass of porous coordination polymer F1(W). Furthermore, the specific surface area of ​​porous coordination polymer F1(W) measured by BET was 1404 m². 2 The values ​​are per gram, the average pore size is 0.8 nm, and the gas adsorption capacity is 170 cm³. 3 It was / g. Next, a functional liquid support 1-F1 was obtained by adsorbing etofenprox as a functional sustained-release liquid onto a porous coordination polymer F1(W). The adsorption method was the same as in Example 1-A1. When the amount of etofenprox adsorbed was measured using the above measurement method, the amount of etofenprox adsorbed on functional liquid support 1-F1 was 260% by mass relative to 100% by mass of the porous coordination polymer F1(W). Next, functional liquid carrier 1-F1 was compounded and mixed with polyethylene resin (Novatic UJ310, a product of Nippon Polyethylene) as the matrix resin to produce a functional sustained-release composition (molded body material). The mixing was performed so that the functional liquid carrier 1-F1 comprised 6.9% by mass and the matrix resin (polyethylene resin) comprised 93.1% by mass per 100% by mass of the functional sustained-release composition. The compounding process and the production of the plate-shaped molded body were carried out in the same manner as in A-1. The surface volume of the functional sustained-release liquid in the produced plate-shaped molded body was measured and found to be 11 μg / cm³. 2 That was the case.

[0303] [Example 1-F2] When the amount of free 2-methylimidazole in porous coordination polymer F2(W) was measured by the above method, it was found to be 0.5% by mass relative to 100% by mass of porous coordination polymer F2(W). Furthermore, the specific surface area of ​​porous coordination polymer F2(W) by the BET method was 1410 m². 2 The values ​​are per gram, the average pore size is 0.8 nm, and the gas adsorption capacity is 171 cm³. 3 It was / g. Next, using the same method as in Example 1-F1, etofenprox was adsorbed onto the porous coordination polymer F2(W) as a functional sustained-release liquid to obtain functional liquid support 1-F2 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-F2 was 240% by mass relative to 100% by mass of the porous coordination polymer F2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.1% by mass of the functional liquid carrier 1-F2, and 92.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 12 μg / cm³. 2 That was the case.

[0304] [Example 1-F3] When the amount of free 2-methylimidazole in porous coordination polymer F3(W) was measured by the above method, it was found to be 0.7% by mass relative to 100% by mass of porous coordination polymer F3(W). Furthermore, the specific surface area of ​​porous coordination polymer F3(W) measured by BET was 1413 m². 2 The values ​​are per gram, the average pore size is 0.9 nm, and the gas adsorption capacity is 173 cm³. 3 It was / g. Next, using the same method as in Example 1-F1, etofenprox was adsorbed onto the porous coordination polymer F3(W) as a functional sustained-release liquid to obtain functional liquid support 1-F3 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-F3 was 190% by mass relative to 100% by mass of the porous coordination polymer F3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.6% by mass of the functional liquid carrier 1-F3, and 92.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 20 μg / cm³. 2 That was the case.

[0305] [Comparative Example 1-F4] When the amount of free 2-methylimidazole in porous coordination polymer F4(W) was measured by the above method, it was found to be 0.9% by mass relative to 100% by mass of porous coordination polymer F4(W). Furthermore, the specific surface area of ​​porous coordination polymer F4(W) measured by BET was 1404 m². 2 The values ​​are per gram, the average pore size is 0.8 nm, and the gas adsorption capacity is 174 cm³. 3 It was / g. Next, using the same method as in Example 1-F1, etofenprox was adsorbed onto the porous coordination polymer F4(W) as a functional sustained-release liquid to obtain functional liquid support 1-F4 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-F4 was 110% by mass relative to 100% by mass of the porous coordination polymer F4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.5% by mass of the functional liquid carrier 1-F4, and 90.5% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 59 μg / cm³. 2 That was the case.

[0306] [Comparative Example 1-F5] When the amount of free 2-methylimidazole in porous coordination polymer F5(W) was measured by the above method, it was found to be 1.0% by mass relative to 100% by mass of porous coordination polymer F5(W). Furthermore, the specific surface area of ​​porous coordination polymer F5(W) measured by BET was 1412 m². 2 The values ​​are per gram, the average pore size is 0.8 nm, and the gas adsorption capacity is 162 cm³. 3 It was / g. Next, using the same method as in Example 1-F1, etofenprox was adsorbed onto the porous coordination polymer F5(W) as a functional sustained-release liquid to obtain functional liquid support 1-F5 with adsorbed etofenprox. When the amount of adsorbed etofenprox was measured using the above measurement method, the amount of etofenprox adsorbed in functional liquid support 1-F5 was 100% by mass relative to 100% by mass of the porous coordination polymer F5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 10.0% by mass of the functional liquid carrier 1-F5, and 90.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 37 μg / cm³. 2 That was the case.

[0307] Table 21 shows the amount of etofenprox adsorbed in functional liquid carriers 1-F1 to 1-F5 and the surface area of ​​the plate-shaped molded body. In addition, Table 21 also shows the relative change, with the amount of etofenprox adsorbed in functional liquid carrier 1-F1 set to 100 and the amount of etofenprox adsorbed in functional liquid carrier 1-F5 set to 0. Furthermore, the relative change for functional liquid carriers 1-F2 to 1-F4 is shown as a relative amount, with the amount of etofenprox adsorbed in functional liquid carrier 1-F5 (0) and the amount of etofenprox adsorbed in functional liquid carrier 1-F1 (100) set to 100.

[0308] [Table 21]

[0309] [Example 2-F1] Functional liquid carrier 2-F1 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer F1(W) in Example 1-F1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F1 was 230% by mass relative to 100% by mass of the porous coordination polymer F1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 2.9% by mass of the functional liquid carrier 2-F1, and 97.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0310] [Example 2-F2] Functional liquid carrier 2-F2 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer F2(W) in Example 1-F2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F2 was 210% by mass relative to 100% by mass of the porous coordination polymer F2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.0% by mass of the functional liquid carrier 2-F2, and 97.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0311] [Example 2-F3] Functional liquid carrier 2-F3 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer F3(W) in Example 1-F3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F3 was 170% by mass relative to 100% by mass of the porous coordination polymer F3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 3.2% by mass of the functional liquid carrier 2-F3, and 96.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0312] [Comparative Example 2-F4] Functional liquid carrier 2-F4 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer F4(W) in Example 1-F4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F4 was 100% by mass relative to 100% by mass of the porous coordination polymer F4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 4.0% by mass of the functional liquid carrier 2-F4, and 96.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 16 μg / cm³.2 That was the case.

[0313] [Comparative Example 2-F5] Functional liquid carrier 2-F5 was obtained by adsorbing 2-n-octyl-4-isothiazolin-3-one onto the porous coordination polymer F5(W) in Example 1-F5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one was measured using the above measurement method, the amount of adsorbed 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F5 was 90% by mass relative to 100% by mass of the porous coordination polymer F5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 4.2% by mass of the functional liquid carrier 2-F5, and 95.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 20 μg / cm³. 2 That was the case.

[0314] Table 22 shows the adsorption amount of 2-n-octyl-4-isothiazolin-3-one and the surface area of ​​the plate-shaped molded body in functional liquid carriers 2-F1 to 2-F5. In addition, Table 22 also shows the relative change amount, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F1 set to 100 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 2-F2 to 2-F4 are shown as relative amounts, with the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F5 set to 0 and the adsorption amount of 2-n-octyl-4-isothiazolin-3-one in functional liquid carrier 2-F1 set to 100. In Table 22, OIT represents 2-n-octyl-4-isothiazolin-3-one.

[0315] [Table 22]

[0316] [Example 3-F1] Functional liquid support 3-F1 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid instead of etofenprox onto the porous coordination polymer F1(W) in Example 1-F1. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-F1 was 170% by mass relative to 100% by mass of the porous coordination polymer F1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.9% by mass of the functional liquid carrier 3-F1, and 92.1% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0317] [Example 3-F2] Functional liquid support 3-F2 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer F2(W) in Example 1-F2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-F2 was 160% by mass relative to 100% by mass of the porous coordination polymer F2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.1% by mass of the functional liquid carrier 3-F2, and 91.9% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional liquid on the surface of the prepared plate-shaped molded body was measured and found to be 6 μg / cm³. 2 That was the case.

[0318] [Example 3-F3] Functional liquid support 3-F3 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer F3(W) in Example 1-F3, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-F3 was 140% by mass relative to 100% by mass of the porous coordination polymer F3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 8.6% by mass of the functional liquid carrier 3-F3, and 91.4% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 7 μg / cm³. 2 That was the case.

[0319] [Comparative Example 3-F4] Functional liquid support 3-F4 was obtained by adsorbing 4-nonanolide as a functional sustained-release liquid to the porous coordination polymer F4(W) in Example 1-F4, instead of etofenprox. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-F4 was 120% by mass relative to 100% by mass of the porous coordination polymer F4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 9.2% by mass of the functional liquid carrier 3-F4, and 90.8% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 9 μg / cm³. 2 That was the case.

[0320] [Comparative Example 3-F5] Functional liquid support 3-F5 was obtained by adsorbing 4-nonanolide onto the porous coordination polymer F5(W) in Example 1-F5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed 4-nonanolide was measured using the above measurement method, the amount of adsorbed 4-nonanolide in functional liquid support 3-F5 was 100% by mass relative to 100% by mass of the porous coordination polymer F5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 10.0% by mass of the functional liquid carrier 3-F5, and 90.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0321] Table 23 shows the adsorption amount of 4-nonanolide in functional liquid carriers 3-F1 to 3-F5 and the surface area of ​​the plate-shaped molded body. In addition, Table 23 also shows the relative change amount, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-F1 set to 100 and the adsorption amount of 4-nonanolide in functional liquid carrier 3-F5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 3-F2 to 3-F4 are shown as relative amounts, with the adsorption amount of 4-nonanolide in functional liquid carrier 3-F5 (0) and the adsorption amount of 4-nonanolide in functional liquid carrier 3-F1 (100) set to 100.

[0322] [Table 23]

[0323] [Example 4-F1] Functional liquid support 4-F1 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer F1(W) in Example 1-F1, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-F1 was 250% by mass relative to 100% by mass of the porous coordination polymer F1(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.0% by mass of the functional liquid carrier 4-F1, and 93.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 8 μg / cm³. 2 That was the case.

[0324] [Example 4-F2] Functional liquid support 4-F2 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer F2(W) in Example 1-F2, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-F2 was 220% by mass relative to 100% by mass of the porous coordination polymer F2(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.3% by mass of the functional liquid carrier 4-F2, and 92.7% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 10 μg / cm³. 2 That was the case.

[0325] [Example 4-F3] Functional liquid support 4-F3 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer F3(W) in Example 1-F3, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-F3 was 180% by mass relative to 100% by mass of the porous coordination polymer F3(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 7.8% by mass of the functional liquid carrier 4-F3, and 92.2% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 15 μg / cm³. 2 That was the case.

[0326] [Comparative Example 4-F4] Functional liquid support 4-F4 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer F4(W) in Example 1-F4, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-F4 was 100% by mass relative to 100% by mass of the porous coordination polymer F4(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 100% by mass of the functional sustained-release composition, 10.0% by mass of the functional liquid carrier 4-F4, and 90.0% by mass of the matrix resin (polyethylene resin). The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 26 μg / cm³. 2 That was the case.

[0327] [Comparative Example 4-F5] Functional liquid support 4-F5 was obtained by adsorbing trimellitic acid ester onto the porous coordination polymer F5(W) in Example 1-F5, instead of etofenprox as the functional sustained-release liquid. The adsorption method was the same as in Example 1-A1. When the amount of adsorbed trimellitic acid ester was measured using the above measurement method, the amount of adsorbed trimellitic acid ester in functional liquid support 4-F5 was 90% by mass relative to 100% by mass of the porous coordination polymer F5(W). Next, a plate-shaped molded body was prepared in the same manner as in Example 1-F1. The mixture consisted of 10.6% by mass of functional liquid carrier 4-F5 and 89.4% by mass of matrix resin (polyethylene resin) relative to 100% by mass of the functional sustained-release composition. The compounding process and the method for preparing the plate-shaped molded body were carried out in the same manner as in A-1. The amount of functional sustained-release liquid on the surface of the prepared plate-shaped molded body was measured and found to be 37 μg / cm³. 2 That was the case.

[0328] Table 24 shows the adsorption amounts of trimellitic acid ester in functional liquid carriers 4-F1 to 4-F5 and the surface area of ​​the plate-shaped molded body. In addition, Table 24 also shows the relative change amount, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F1 set to 100 and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F5 set to 0. Furthermore, the relative change amounts for functional liquid carriers 4-F2 to 4-F4 are shown as relative amounts, with the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F5 (0) and the adsorption amount of trimellitic acid ester in functional liquid carrier 4-F1 (100) set to 100. In Table 24, TOTM represents trimellitic acid ester.

[0329] [Table 24] [Industrial applicability]

[0330] The functional liquid carrier of this embodiment can be used in functional sustained-release compositions and molded articles that are imparted with functional components such as small animal control, sliding function, antibacterial function, antifungal function, self-healing function, catalytic function, and medical function. Specifically, the functional liquid carrier of this embodiment can be used in industrial fields such as automobiles and electrical products, amenity fields such as hygiene services, and medical fields such as pharmaceuticals.

Claims

1. A porous coordination polymer having an organic ligand and a metal ion, A functional sustained-release liquid, The organic ligand comprises one or more selected from the group consisting of fumaric acid, terephthalic acid, benzenetricarboxylic acid, and methylimidazole. When the organic ligand contains fumaric acid, the amount of free fumaric acid in the porous coordination polymer is 0.7% by mass or less relative to 100% by mass of the porous coordination polymer. When the organic ligand contains terephthalic acid, the amount of free terephthalic acid in the porous coordination polymer is 0.5% by mass or less relative to 100% by mass of the porous coordination polymer. When the organic ligand contains benzenetricarboxylic acid, the amount of free benzenetricarboxylic acid in the porous coordination polymer is 0.6% by mass or less relative to 100% by mass of the porous coordination polymer. When the organic ligand contains methylimidazole, the amount of free methylimidazole in the porous coordination polymer is 0.7% by mass or less relative to 100% by mass of the porous coordination polymer. Functional liquid carrier.

2. The functional liquid carrier according to claim 1, wherein the metal ion comprises one or more selected from the group consisting of aluminum ions, zirconium ions, chromium ions, copper ions, iron ions, and zinc ions.

3. The functional liquid carrier according to claim 1 or 2, wherein the molecular weight of the functional sustained-release liquid is 600 or less.

4. The functional liquid carrier according to any one of claims 1 to 3, wherein the average pore diameter of the porous coordination polymer is greater than or equal to the molecular diameter of the functional sustained-release liquid.

5. A functional liquid carrier according to any one of claims 1 to 4, A functional sustained-release composition comprising a matrix resin.

6. A molded article comprising the functional sustained-release composition described in claim 5.

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