CONSUMER PRODUCTS AND DELIVERY SYSTEMS THAT USE ORGANOLEPTIC COMPOUNDS.

Abstract

This application relates to perfume delivery systems and consumer products comprising a novel organoleptic compound and / or perfume delivery systems having the novel organoleptic compound, as well as methods for using such perfume delivery systems and consumer products.

Description

CONSUMER PRODUCTS AND DELIVERY SYSTEMS THAT USE ORGANOLEPTIC COMPOUNDS FIELD OF DESCRIPTION This application relates to consumer products and perfume delivery systems that use organoleptic compounds, as well as processes for making and using such consumer products and perfume delivery systems. BACKGROUND OF THE INVENTION Consumer products may comprise one or more perfumes and / or perfume delivery systems that can mask an undesirable odor and / or provide a desired aroma to a product or an area in contact with such a product. While current perfumes and perfume delivery systems provide desirable fragrances, consumers continue to seek products with aromas that are longer-lasting and tailored to their individual preferences (see, for example, U.S. patent applications 2007 / 0275866 A1 and 2008 / 0305977 A1). Unfortunately, the available set of perfumery raw materials and perfume delivery systems is still too limited to fully meet the needs of the perfume-making community. Therefore, perfume producers require a much larger set of perfume raw materials and perfume delivery systems. BRIEF DESCRIPTION OF THE INVENTION Subcombinations: A. A consumer product comprising an organoleptic compound of the formula: IVIA / a / 1 / UU4 f 30 where R represents H; one of the dotted lines on the ring represents a carbon-carbon single bond, where the other represents a carbon-carbon double bond; and the dotted line on the chain represents either a carbon-carbon single bond or a carbon-carbon double bond, with the condition that if the dotted line on the chain represents a carbon-carbon double bond, R is absent. B. The consumer product according to Paragraph A, where the organoleptic compound is selected from the group consisting of: (E)-l-((lR,6R)-4,6-dimeth¡lc¡clohex-3-en-l-¡l)-2-methylpent-l-en-3-one; (E)-l-((lS,6S)-3,6-dimeth¡lc¡clohex-3-en-l-¡l)-2-methylpent-l-en-3-one; (E)-l-((lR,6S)-4,6-dimeth¡lc¡clohex-3-en-l-¡l)-2-methylpent-l-en-3-one; (E)-l-((lS,6R)-3,6-dimeth¡lc¡clohex-3-en-l-yl)-2-methylpent-l-en-3-one; (£)-l-((l / 2,6 / 2)-4,6-dimethylc¡clohex-3-en-l-yl)-2-meth¡lpent-l-en-3-ol; (£)-1-((15,65)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-ol; (£)-1-((1 / 2.65)-4,6-dimeth¡lc¡clohex-3-en-l-¡l)-2-methylpent-l-en-3-ol; (£)-1-((15,6 / 2)-3,6-dimeth¡lc¡clohex-3-en-l-¡l)-2-methylpent-l-en-3-ol; and a mixture of these. C. The consumer product according to paragraph B, wherein the organoleptic compound is the mixture of (E)-l-((lR,6R)-4,6-dimethylcyclohex-3-en-l-¡l)-2methylpent-l-en-3-one, (E)-l-((lS,6S)-3,6-dimeth¡lc¡chlohex-3-en-l-¡l)-2-meth¡lpentl-en-3-one, (E)-l-((lR,6S)-4,6-dimeth¡lc-clohex-3-en-l-meth-en-l-penthol-en-3-l-3-one) (E)-l-((lS,6R)-3,6-dimeth¡lc¡clohex-3-en-l-yl)-2-methylpent-l-en-3-one. D. The consumer product according to any of Paragraphs A to C, wherein the consumer product is a cleaning and / or treatment composition, such composition comprises, based on the total weight of the composition, from approximately 0.0001% to approximately 25% of the organoleptic compound. E. The consumer product according to any of Paragraphs A to D, wherein the consumer product is a cleaning and / or fabric and / or hard surface treatment composition, such composition comprises, based on the total weight of the composition, from approximately 0.00001% to approximately 25% of the organoleptic compound. F. The consumer product according to any of Paragraphs A to E, where the consumer product is a detergent, said detergent comprises, based on the total weight of the detergent, from approximately 0.00001% to approximately 25% of the organoleptic compound. G. The consumer product in accordance with any of Paragraphs A to F, in MA / a / ZUZ1 / UU4l30 where the consumer product is a highly compact consumer product, said highly compact consumer product comprises, based on the total weight of the highly compact consumer product, from approximately 0.00001% to approximately 25% of the organoleptic compound. H. A method for treating an area with the consumer product from any of Paragraphs A to I. A perfume delivery system comprising an organoleptic compound of the formula: IVIA / a / 1 / UU4l30 where R represents H; one of the dotted lines on the ring represents a carbon-carbon single bond, where the other represents a carbon-carbon double bond; and the dotted line on the chain represents either a carbon-carbon single bond or a carbon-carbon double bond, with the condition that if the dotted line on the chain represents a carbon-carbon double bond, R is absent. The perfume delivery system of Paragraph I, wherein the organoleptic compound is selected from the group consisting of: (E)-l-((lR,6R)-4,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one; (E)-l-((lS,6S)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one; (E)-l-((lR,6S)-4,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one; (E)-l-((lS,6R)-3,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one; (£)-l-((l / ?,6 / ?)-4,6-dimet¡lcyclohex-3-en-l-¡l)-2-met¡lpent-l-en-3-ol; (£)-1-((15.65)-3,6-dimethylcyclohex-3-en-l-íl)-2-methylpent-l-en-3-ol; (£)-l-((l / ?,65)-4,6-dimet¡lc¡clohex-3-en-l-yl)-2-met¡lpent-l-en-3-ol; (£)-1-((15,6 / ?)-3,6-dimethylcyclohex-3-en-1-1)-2-methylpent-1-en-3-ol; and a mixture thereof, wherein said perfume delivery system is selected from a polymer-assisted delivery system; a molecule-assisted delivery system; a fiber-assisted delivery system; an amine-assisted delivery system; a cyclodextrin delivery system; a starch-encapsulated accord; an inorganic carrier delivery system; or a perfume precursor. K. The perfume delivery system of Paragraph J, wherein the organoleptic compound is the mixture of (E)-l-((lR,6R)-4,6-dimethylcyclohex-3-en-l-íl)-2methylpent-l-en-3-one, and (E)-l-((lS,6R)-3,6-dimethylcyclohex-3-en-l-íl)-2-methylpent-l-en-3-one. L. The perfume delivery system in accordance with any of Paragraphs I to K, further comprising, based on the total weight of the perfume delivery system, from approximately 0.1% to approximately 99% of the organoleptic compound. M. A perfume delivery system according to any of Paragraphs I to L, wherein the perfume delivery system is a capsule. N. A perfume delivery system according to any of Paragraphs I to M, wherein the perfume delivery system is a starch-encapsulated accord. O. A method for treating an area with a consumer product comprising the perfume delivery system of any of Paragraphs I to N. DETAILED DESCRIPTION OF THE INVENTION The following definitions may be helpful in understanding the invention described herein. As used in the present description, consumer product means baby care, beauty care, fabric and home care, family care, feminine care or health care products generally intended to be used or consumed in the form in which they are sold. The term "baby care" includes such products as include, but are not limited to, products and / or methods relating to absorbent and / or non-absorbent disposable articles, including adult incontinence garments, bibs, diapers, training pants, wipes for the care of babies and toddlers; and personal care products, including hand soaps, shampoos, lotions, oral care implements, and clothing. The term hair care composition means products for and / or related methods for the treatment of hair (human, canine and / or feline), including, IVIA / a / 1 / UU4l30 bleaching, coloring, dyeing, conditioning, growth, removal, retarded growth, shampooing, styling; deodorants and antiperspirants; personal grooming products; color cosmetics; products, and / or related methods for treating the skin (of humans, dogs and / or cats) including the application of creams, lotions and other topically applied products for consumer use; and products and / or related methods to materials administered orally to improve the appearance of hair, skin and / or nails (of humans, dogs and / or cats); and shaving. The expression fabric and home care includes products and / or methods related to the treatment of fabrics, hard surfaces and any other surface in the area of ​​fabric and home care, including: air care, car care, dishwashing, fabric conditioning (which includes fabric softeners), laundry detergents, laundry care and / or rinse additives, hard surface cleaning and / or treatment and other cleaners for institutional or consumer use. The term "family care" includes products such as wet or dry toilet paper, facial wipes, tissues, disposable towels and / or wet wipes, as well as methods and equipment for manufacturing such products. The term feminine care includes products related to menstrual towels, incontinence pads, interlabial pads, panty liners, intrauterine devices, sanitary napkins, tampons and tampon applicators, and / or cleansing wipes. The term health care includes products and / or methods relating to: oral care which includes any composition for use with any soft and / or hard tissue of the oral cavity or conditions associated therewith (e.g., anticaries compositions, antimicrobial compositions, antiplaque chewing gum compositions, breath compositions, confectionery products, toothpastes, denture compositions, lozenges, mouthwashes and teeth whitening compositions), cleaning devices, dental floss and flossing devices, and toothbrushes;over-the-counter health care products, including cough and cold remedies and treatments for other respiratory conditions, pain relievers whether topical, oral or otherwise, gastrointestinal remedies including any composition suitable for relieving gastrointestinal diseases such as heartburn, upset stomach, diarrhea and irritable bowel syndrome, and nutrient supplementation such as calcium or fiber supplementation;Pharmaceutical care, which includes pharmacologically active molecular and / or biological entities, their use in the treatment and / or prevention of diseases and / or relief of symptoms in humans and / or animals, and formulations, regimens, kits and / or routes for delivering such entities to subjects in need of treatment and / or prevention and / or relief, discovery tools, which include detection methods, assays and receptors, and their use in the discovery of new molecular and / or biological entities; IVIA / a / 1 / UU4l30 pharmacologically active; pet health and nutrition, including food, pet treats, other products that can be administered orally, regardless of the distribution channel (including veterinary and over-the-counter products), as well as topical products, such as brushing aids, training aids, devices, toys and diagnostic techniques; and types of water including purified, flavored or other types of treated water. As used in this description, the term "cleaning and / or treatment composition" refers to a subset of consumer products that includes, unless otherwise stated, beauty care, household care, and fabric care products. These products include, but are not limited to, hair care products (for humans, dogs, and / or cats), including bleaches, colorants, dyes, conditioners, shampoos, and styling products; deodorants and antiperspirants; personal grooming products; cosmetics; and skin care, including application creams, lotions, and other topical consumer products.and shaving products, products for the treatment of fabrics, hard surfaces and any other surface included within the field of fabric and home care, which include: environmental care including air modifiers and fragrance delivery systems, car care, dishwashing, fabric conditioning (including fabric renewers and / or softeners), laundry detergents, laundry and rinse care and / or additives, hard surface cleaning and / or treatment including floor and toilet cleaners, multipurpose or high-performance granular or powder washing agents, especially cleaning detergents; liquid, multipurpose gel or paste cleaning agents, especially liquid types called high-performance; liquid detergents for delicate fabrics;Agents for hand dishwashing or low-performance dishwashing agents, especially those of the high-foaming type; agents for automatic dishwashers, including the various types in tablet, granule, liquid form and rinse aid for institutional and domestic use; liquid cleaning agents and disinfectants, including antibacterial handwashing agents, cleaning bars, mouthwashes, denture cleaners, toothpaste, carpet or car shampoos, bathroom cleaners, including toilet cleaners; shampoos and conditioners for hair; shower gels and bath foams, and metal cleaners; as well as cleaning aids, such as bleaching additives and types of stain removers in bar or pretreatment form;Products loaded onto substrates, such as dryer sheets, dry and moist pads and cloths, non-woven fabric substrates and sponges; as well as sprays and vaporizers, all for domestic and / or institutional use; and / or methods related to oral care, including toothpastes, dental gels, mouthwashes, denture adhesives, and teeth whiteners. As used in this description, the term cleaning composition and / or IVIA / a / 1 / UU4l30 fabric and / or hard surface treatment refers to a subset of cleaning and treatment compositions which include, unless otherwise specified, high-performance or multi-purpose washing agents in granule or powder form, especially cleaning detergents; liquid, multi-purpose gel or paste cleaning agents, especially liquid types designated as high-performance; liquid detergents for fine fabrics; hand dishwashing agents or low-performance dishwashing agents, especially those of the high-foaming type; automatic dishwashing agents, including the various types in tablet, granule, liquid form and rinse aid for institutional and domestic use;Liquid cleaning agents and disinfectants, including antibacterial types not for hand washing, cleaning bars, carpet or car shampoos, bathroom cleaners, including toilet cleaners; and metal cleaners, fabric conditioning products including softeners and / or fabric restorers that may be in liquid, solid and / or dryer sheet form; as well as cleaning aids, such as bleaching additives and types of stain removers in bar or pretreatment form; products loaded onto substrates, such as dryer sheets, dry and wet pads and cloths, non-woven fabric substrates and sponges;as well as sprays and vaporizers. All applicable products may be in standard, concentrated, or even highly concentrated form, to the point of being, in some respects, non-aqueous. Cleaning and / or treatment compositions for fabrics and / or hard surfaces may be configured for spraying, pouring, dosing, and the like. As used herein, the articles a and a, when used in a claim, are to be construed as one or more of what is claimed or described. As used in this description, the terms include, encompass, and that include are understood to be non-limiting. As used in this description, the term solid includes granular, powder, bar, and tablet forms of the product. As used in this description, the term fluid includes liquid, gel, paste, and gaseous product forms. As used in this description, the term "area" refers to the location or space to be treated or cleaned with a consumer product. An area may be a substrate, paper product, fabric, garment, hard surface, hair, skin, air, and the like. Unless otherwise stated, all component or composition levels refer to the active portion of that component or composition and exclude impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions. All percentages and ratios are calculated by weight, unless otherwise stated IVIA / a / 1 / UU4l30 in any other way. All percentages and ratios are calculated based on the total composition, unless otherwise stated. Each maximum numerical limit given in this specification shall be understood to include all lower numerical limits, as if the lower numerical limits had been explicitly stated herein. All minimum numerical limits stated in this specification shall include all higher numerical limits, as if the higher numerical limits had been expressly stated herein. Any numerical range given throughout this specification includes any lower numerical range that falls within that broader numerical range, as if the lower numerical range were expressly stated herein. Organoleptic Compounds The consumer products and / or delivery systems of the present invention may benefit from the introduction of novel organoleptic compounds to enhance, improve and / or modify their fragrance. More specifically, the present invention relates to consumer products and delivery systems using an organoleptic compound, (dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-ones (ols), represented by Formula I shown below: OR(H3θ24 J T3 Formula I where R represents H and one of the dotted lines in the ring represents a carbon-carbon single bond, where the other represents a carbon-carbon double bond, and the dotted line in the chain represents either a carbon-carbon single bond or a carbon-carbon double bond; provided that the dotted line in the chain represents a carbon-carbon double bond, the R group is absent The compounds (dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one (ol) represented by Formula I of the present invention are illustrated by the following examples. (£)-!-((! / ?,6 / ?)-4,6-dimet¡lcyclohex-3-en-l-¡l)-2-methylpent-l-en-3-one Structure 1 IVIA / a / 1 / UU4l30 (£)-1-((15,65)-3,6-dimethylc¡clohex-3-en-l-¡l)-2-met¡lpent-l-en-3-one IVIA / a / 1 / UU4l30 (£)-1-((15,65)-4,6-dimethylc¡clohex-3-en-l-yl)-2-met¡lpent-l-en-3-one (£)-1-((15,65)-3,6-dimethylc¡clohex-3-en-l-¡l)-2-meth¡lpent-l-en-3-one (£)-l-((15,65)-4,6-dimeth¡lc¡clohex-3-en-l-yl)-2-meth¡lpent-l-en-3-ol (£)-1-((15,65)-3,6-dimethylc¡clohex-3-en-l-¡l)-2-meth¡lpent-l-en-3-ol Structure 6 IVIA / a / 1 / UU4l30 (£)-l-((l / ?,65)-4,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-ol (£)-1-((15,6 / ?)-3,6-dimethylc¡clohex-3-en-l-¡l)-2-meth¡lpent-l-en-3-ol Those skilled in the art will recognize that the compounds of the present invention may have a number of isomers, such as positional isomers, depending on the available raw materials. The compounds described herein are intended to include isomeric mixtures as well as single isomers that can be separated using techniques known to those skilled in the art. Suitable techniques include chromatography, such as high-performance liquid chromatography (HPLC), and in particular silica gel chromatography, and gas chromatography entrapment (GC). However, commercial products are mainly offered as isomeric mixtures. The term "an organoleptic compound" is understood to mean one or more of the (dimethylcyclohex-3-en-1-1)-2-methylpent-1-en-3-ones (ols) represented by Structures 1-8 as described herein.The preparation of the organoleptic compounds of the present invention is detailed in the Examples. Structures 5-8 can be readily prepared from the corresponding structures 1-4 by hydrogenation using lithium aluminum hydride (LIAIH4). The materials were purchased from Aldrich Chemical Company, unless otherwise stated. The organoleptic compounds of the present invention, for example, possess strong and complex, fresh, crisp, slightly green, resinous, coniferous, floral, ionic, amber, woody and diffuse notes. In these preparations, the organoleptic compounds of the present invention may be used alone or in combination with other perfume compositions, solvents, adjuvants, and the like. The nature and variety of the other ingredients that may also be employed are known to those skilled in the art. Many types of fragrances may be employed in the present invention, the only limitation being compatibility with the other components used. Suitable fragrances include, but are not limited to, fruits such as almond, apple, cherry, grape, pear, pineapple, orange, strawberry, and raspberry; musk; and floral aromas such as lavender, rose, iris, or carnation. Other pleasing aromas include herbal and woody aromas derived from pine, fir, and other forest scents. Fragrances may also be derived from various oils, such as essential oils, or from plant materials such as spearmint, peppermint, and the like. U.S. Patent No. 4,534,891, the contents of which are incorporated by reference as if set forth in full, provides a list of suitable fragrances. Another source of suitable fragrances is found in Perfumes, Cosmetics and Soaps, Second Edition, edited by W.A. Poucher, 1959. Among the fragrances offered in this treatise are acacia, cassie, chypre, cyclamen, fern, gardenia, hawthorn, heliotrope, honeysuckle, hyacinth, jasmine, lilac, lily, magnolia, mimosa, narcissus, fresh-cut hay, orange blossom, orchid, remora, sweet pea, tuberose, vanilla, violet, wallflower, and the like. The organoleptic compounds of the present invention may be used in combination with a complementary fragrance compound. As described herein, the term complementary fragrance compound is defined as a fragrance compound selected from the group consisting of 2-[(4-methylphenyl)methylene]heptanal (Acalea), isoamyl oxyacetic acid allyl ester (allylamyl glycolate), (3,3-dimethylcyclohexyl)ethylpropane-1,3-dioate (Applelida), (E / Z)-1-ethoxy-1-decene (Arctical), 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-1)-2-buten-1-ol (Bacdanol), 2-methyl-3-[(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)oxy]hexo-1-propanol (Bornafix), 1,2,3,5,6,7-hexahydro-l,1,2,3,3-pentamethyl4H-inden-4-one (Cashmeran), trimethylcyclopentenylmethyloxabicyclooctane (Cassiffix), l,l-dimethoxy-3,7dimethyl-2,6-octadiene (Citral DMA), 3,7-dimethyl-6-octen-l-ol (Citronellol), 3A,4,5,6,7,7A-hexahydro-4,7methane-l / ^inden-S / ó-yl acetate (Cyclacet), 3A,4,5,6,7,7A-hexahydro-4,7-methane-l / y-inden-5 / 6-¡l propinoate (Cyclaprop), 3A,4,5,6,7,7A-hexahydro-4,7-methane-lG-inden-5 / 6-¡l butyrate (cyclobutanate), 1(2,6,6-trimethyl-3-c¡clohexen-l-¡l)-2-buten-l-one (Delta damascona), 3-(4-ethylphenyl)-2,2-d¡meth¡l propanonitrile (Fleuranyl), 3-(O / P-ethylphenyl) 2,2-methyl propionyl (fluoroallozone), tetrahydro-4-methyl-2(2-methylpropyl)-2H-p¡ran-4-ol (Floriffol), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2benzopyran (Galaxolide), l-(5,5-dimet¡ll-cyclohexene-l-¡l)pent-4-en-l-one (Galbascona), E / Z-3,7-dimethyl2,6-octadien-l-yl acetate (geranyl acetate), a-methyl-l,3-benzodioxol-5-propanal), (Helional). 1-(2,6,6tr¡methyl-2-c¡chlohexen-l-¡l)-l,6-heptad¡en-3-one (Hexalon), (Z)-3-hexenyl-2-hydroxybenzoate (hexenyl salicylate, CIS-3), 4-(2,6,6-trimet¡l-2-c¡chlohexen-l-yl)-3-buten-2-one (lonone a), 1-(1,2,3,4,5,6,7,8octahydro-2,3,8,8-tetramethyl-2-naphthalene¡l)-ethane-l-E-one, (Iso-E- 3-oxo-2-pentylcyclopentanoacetate methyl (Kharismal), 2,2,4-tr¡met¡l-4-phen¡l-butanone¡tr¡lo (Khusinil), 3,4,5,6,6-pentamethylhept-3-en-2-one, IVIA / a / 1 / UU4l30 (Koavona), 3 / 4-(4-hydrox¡-4-met¡l-pent¡l) cyclohexene-1-carboxaldehyde (Lyral), 3-meth¡l-4-(2,6,6-tr¡met¡l-2cyclohexyl-3-butene) (3-methyl-butene) lonone y), l-(2,6,6-tr¡meth¡l-2-c¡chlohexeno-l-¡l) pent-l-en-3-one (Methyl lonone a Extra, Methyl lonone N), 3-methyl-4-phen¡lbutan-2-ol (Muguesia), cyclopentadec-4-en-l-one (Muscle-Zone), 3,3,4,5,5-pentameth¡l·ll,13-dioxatri¡c¡chlo[7.4.0.0<2,6>]tr¡dec-2(6)-eno (Nebulona), 3,7-dimethyl2,6-octadien-1-yl acetate (Acetato de Nerilo), 3,7-dimethyl,3,6-octat¡treno (Ocimeno), ortho-tolylethanol (Peomosa), 3-methyl-5-phen¡lpentanol (Fenoxanol), l-methyl-4-(4-methyl-3-pentenyl)cyclohex-3-eno-lcarboxaldehyde (Preciclemona B), 4-methyl-8-methyllen-2-adamantanol (Prismantol), 2-ethyl 1-4-(2,2,3-trimethyl 1-3cyclopenten-1-yl)-2-buten-1-ol (Sanjinol), 2-met¡l·4-(2,2,3-tr¡met¡l-3-c¡clopenten-l-¡l)-2-buten-l-ol (Santaliff), Terpineol, 2,4-dimetil-3-c¡clohexeno-l-carboxaldehído (Triplal), decahidro-2,6,6,7,8,8hexametil-2H-indeno[4,5-B]furano (Trisamber), acetato de 2-terc-butilciclohexilo (Verdox), acetato de 4terc-butilciclohexilo (Vertenex), cedreno de acetilo (Vertofix), 3,6 / 4,6-dimetilciclohex-3-eno-lcarboxaldehído (Vertoliff / Isovertoliff) y (3 Z)-l-[(2-methyl-2-propenyl)ox¡]-3-hexene (Vivaldie). The complexity of scent notes refers to the presence of multiple and / or blended but distinct odors, rather than a single note or a few easily identifiable notes. High levels of complexity are also assigned to compounds that possess ambiguous and somewhat difficult-to-define notes due to the direct contribution or numerous olfactory combinations that occur. Fragrance materials with a high level of complexity are considered to be of exceptional and unusual quality. The term alkyl means a linear or branched saturated monovalent hydrocarbon, e.g., methyl, ethyl, propyl, 2-propyl, butyl (including all isomeric forms), pentyl (including all isomeric forms), hexyl (including all isomeric forms), and the like. The term alkenyl means a linear or branched unsaturated aliphatic hydrocarbon containing at least one carbon-carbon double bond. The term alkylene refers to a divalent alkyl. Examples include -CH2-CH2CH2-CH2CH2CH2-, -CH2(CH3)CH2-, -CH2CH2CH2CH2-, and the like. The term "enhances" in the phrase "enhances," "potentiates," or "modifies" a fragrance formulation is understood to mean elevating the fragrance formulation to a more desirable character. The term "potentiates" is understood to mean making the fragrance formulation more effective or providing it with an improved character. The term "modifies" is understood to mean giving the fragrance formulation a change in character. Consumer Products The use of the organoleptic compounds of the present invention is widely applicable in current consumer products, including personal care products such as soaps, shower gels, and hair care products, fabric care products, air fresheners, and cosmetic preparations. The present invention can also be used with cleaning agents, such as, but not limited to, detergents and washing materials. ML / a / ZUZ1 / UU4l30 dishes, scouring compositions, window cleaners and the like. The organoleptic compounds of Formula I and their stereoisomers are suitable for use in consumer products at levels, based on the total weight of the consumer product, of approximately 0.0001% to approximately 25%, approximately 0.0005% to approximately 10%, approximately 0.001% to approximately 5%, approximately 0.005% to approximately 2.5%, or even 0.01% to approximately 1%. These organoleptic compounds of Formula I and their stereoisomers may be used in various combinations in the aforementioned consumer products. A consumer product may comprise one or more organoleptic compounds of Formula I and their stereoisomers selected from Structures 1–8 and their stereoisomers. The organoleptic compounds of Formula I and their stereoisomers are suitable for use in cleaning and / or treatment compositions at levels, based on the total weight of the cleaning and treatment products, of approximately 0.0001% to approximately 25%, approximately 0.0005% to approximately 10%, approximately 0.001% to approximately 5%, approximately 0.005% to approximately 2.5%, or even 0.01% to approximately 1%. Such organoleptic compounds of Formula I and their stereoisomers may be used in various combinations in the aforementioned cleaning and / or treatment compositions. A cleaning and / or treatment composition may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof selected from Structures 1-8 and stereoisomers thereof. The organoleptic compounds of Formula I and their stereoisomers are suitable for use in cleaning and / or treating compositions for fabrics and / or hard surfaces at levels, based on the total weight of the cleaning and / or treating composition, of approximately 0.00001% to approximately 25%, 0.00005% to approximately 10%, 0.0001% to approximately 5%, 0.0005% to approximately 1.0%, or even 0.001% to approximately 0.5%. Such PRMs and their stereoisomers may be used in various combinations in the aforementioned cleaning and / or treating compositions for fabrics and / or hard surfaces. A cleaning and / or treatment composition for fabrics and / or hard surfaces may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof selected from Structures 1-8 and stereoisomers thereof. A detergent that may comprise the same level of organoleptic compounds of Formula I as described for the cleaning and / or treatment compositions for fabrics and hard surfaces mentioned above. A detergent may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof selected from Structures 1-8 and stereoisomers thereof. The organoleptic compounds of Formula I and their stereoisomers are suitable for IVIA / a / 1 / UU4l30 their use in highly compact consumer products, including highly compact cleaning and / or treatment compositions for fabrics and hard surfaces. For example, the organoleptic compounds of Formula I and their stereoisomers can be used in highly compact solid or liquid detergents at levels of approximately 0.00001% to approximately 25%, 0.00005% to approximately 10%, 0.0001% to approximately 5%, 0.0005% to approximately 1.0%, or even 0.001% to approximately 0.5%, based on the total weight of the composition. Such organoleptic compounds of Formula I and their stereoisomers can be used in various combinations in the aforementioned highly compact detergent compositions. Such highly compact detergents typically comprise a higher percentage of active ingredients than normal.A highly compact detergent may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof. More specifically, a highly compact detergent may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof selected from Structures 1-8 and stereoisomers thereof. Furthermore, and surprisingly, the organoleptic compounds of the present invention have also been found to provide superior ingredient performance and unexpected advantages in applications that counteract unpleasant odors such as body perspiration, ambient odors such as mold and mildew, bathroom odors, etc. The organoleptic compounds of the present invention substantially eliminate the perception of unpleasant odors and / or prevent the formation of such odors; therefore, they can be used with a wide range of functional products. The effective odor-counteracting amount refers to the quantity of the odor neutralizer of the invention employed in a functional product that is organoleptically effective in diminishing a specific odor while reducing the combined intensity of the odor level, where the specific odor is present in the ambient space or deposited on a substrate. The exact quantity of odor-neutralizing agent employed may vary depending on the type of odor neutralizer, the type of carrier employed, and the desired odor-neutralizing level. Generally, the quantity of odor-neutralizing agent present is the normal dosage required to obtain the desired result. Such dosage is known to those skilled in the art. In a preferred embodiment, when used in combination with solid or liquid odor-containing functional products, e.g.In soap and detergent, the organoleptic compounds of the present invention may be present in an amount ranging from approximately 0.005 to approximately 50 percent by weight, preferably from approximately 0.01 to approximately 20 percent by weight, and more preferably from approximately 0.05 to approximately 5 percent by weight, and when used in combination with gaseous functional products with bad odor, the organoleptic compounds of the present invention may be present in an amount ranging from approximately 0.1 to 10 mg per cubic meter of air. IVIA / a / 1 / UU4l30 Perfume delivery systems The organoleptic compounds of the present invention may be further incorporated into a perfume delivery system. Perfume delivery systems, methods for preparing perfume delivery systems, and uses of perfume delivery systems are described in U.S. Patent Application No. 2007 / 0275866 A1. The organoleptic compounds of Formula I and their stereoisomers are suitable for use in perfume delivery systems at levels, based on the total weight of the perfume delivery system, of approximately 1% to approximately 99%, approximately 2.5% to approximately 75%, 5% to approximately 60%, approximately 5% to approximately 50%, and approximately 5% to approximately 25%. A perfume delivery system may comprise one or more compounds of Formula I, and their stereoisomers, selected from Structures 1-8, and mixtures thereof. The perfume delivery technologies (also known as perfume delivery systems) described herein can be used in any combination in any type of consumer product, cleaning and / or treatment composition, cleaning and / or treatment composition for fabrics and hard surfaces, detergent, and / or highly compacted detergent. The perfume delivery systems described herein are suitable for use in consumer products, cleaning and treatment compositions, cleaning and / or treatment compositions for fabrics and hard surfaces, detergents, and highly compacted consumer products, including highly compacted compositions for cleaning and / or treating fabrics and hard surfaces (e.g., highly compacted solid or liquid detergents) at levels, based on the total weight of the consumer product, from approximately 0.001% to approximately 20%.0.1% to approximately 10%, from approximately 0.05% to approximately 5%, from approximately 0.1% to approximately 0.5%. These perfume delivery systems include: I. Polymer-Assisted Delivery (PAD): This perfume delivery technology uses polymeric materials to deliver the organoleptic compounds of Formula I, stereoisomers of these compounds, and additional perfume materials. Examples of PAD include the use of classical coacervation, soluble or partially soluble to insoluble charged or neutral polymers, liquid crystals, heat melts, hydrogels, scented plastics, capsules, nano- and microlatex, polymer film formers, and polymer absorbents, etc. PAD systems include, but are not limited to: a.) Matrix systems: The organoleptic compounds of Formula I, their stereoisomers, and additional perfume materials are dissolved or dispersed in a polymeric matrix or particle. Additional perfume particles may be 1) dispersed in the polymer prior to product formulation or 2) added separately from the polymer during or after product formulation. Suitable organic latex particles include a wide variety of materials including, but not limited to, polyacetal, polyacrylate, polyamide, polybutadiene, polychloroprene, polyethylene, cyclohexylene polycarbonate, polyhydroxyalkanoate, polyketone, polyester, polyetherimide, polyethersulfone, polyethylene chlorinated compounds, polyimide, polyisoprene, polylactic acid, polyphenylene, polypropylene, polystyrene, polysulfone, polyvinyl acetate, polyvinyl chloride, as well as amine-based polymers or copolymers, acrylonitrile-butadiene, cellulose acetate, ethylene-vinyl acetate, ethylene vinyl alcohol, styrene-butadiene, ethylene vinyl acetate, and mixtures thereof.All these matrix systems include, for example, polysaccharides and nanolatex, which can be combined with other perfume delivery technologies, including other PAD systems such as receptacle PAD systems in the form of a perfume capsule (PC). Silicone-assisted delivery (SAD) can also be used. Examples of silicones include polydimethylsiloxane and polyalkyldimethylsiloxanes. Other examples include those with amine functionality, which can be used to provide benefits associated with amine-assisted delivery (AAD), polymer-assisted delivery (PAD), or amine reaction products (ARPs). b.) Receptacle systems: Receptacle systems are also known as shell-core systems (e.g., perfume capsules). In this system, the beneficial agent is surrounded by a beneficial agent release-control membrane, which may serve as a protective cover. The capsules may comprise one or more organoleptic compounds of Formula I and stereoisomers thereof, selected from Structures 1–8, and mixtures thereof. Suitable coating materials include reaction products of one or more amines with one or more aldehydes, such as urea crosslinked with formaldehyde or glutaraldehyde, melamine crosslinked with formaldehyde, gelatin-polyphosphate coacervates optionally crosslinked with gluteraldehyde, gelatin-gum arabic coacervates, crosslinked silicone fluids, polyamines reacted with polyisocyanates, polyamines reacted with epoxides, polyvinyl alcohol crosslinked with gluteraldehyde, polydivinyl chloride, polyesters, polyamides, polyacrylates, and mixtures thereof. Polyacrylate-based materials may comprise polyacrylate formed from methyl methacrylate / dimethylaminomethyl IVIA / a / 1 / UU4l30 methacrylate, polyacrylate formed from acrylate and / or amine methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and / or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and / or methacrylate monomer and a carboxylic acid acrylate and / or carboxylic acid methacrylate monomer, and mixtures thereof. Core materials include Formula I organoleptic compounds and stereoisomers thereof, perfume compositions, perfume raw materials, silicone oils, waxes, hydrocarbons, higher fatty acids, essential oils, lipids, skin coolants, vitamins, sunscreens, antioxidants, glycerin, catalysts, bleaching particles, silicon dioxide particles, odor-reducing agents, odor control materials, chelating agents, antistatic agents, softening agents, insect and moth repellents, colorants, antioxidants, chelating agents, body-giving agents, fall-control and shape-control agents, softening agents, wrinkle-control agents, disinfecting agents, germ-control agents, mold-control agents, fungal-control agents, antiviral agents, drying agents, and stain-resistant agents.Soil release agents, fabric refreshing agents and freshness prolonging agents, chlorine odor control agents, dye fixatives, dye transfer inhibitors, color maintenance agents, optical brighteners, color restoration / rejuvenation agents, anti-fading agents, whiteness enhancers, anti-abrasion agents, wear resistance agents, fabric integrity agents, anti-pilling agents, antifoaming and defoaming agents, fabric and skin UV protection agents, sun fade inhibitors, anti-allergy agents, enzymes, waterproofing agents, fabric comfort agents, shrink resistance agents, stretch resistance agents, stretch recovery agents, skin care agentsGlycerin and natural active ingredients such as aloe vera, vitamin E, shea butter, cocoa butter, and the like; brighteners; antibacterial agents; antiperspirant agents; cationic polymers; dyes; and mixtures thereof. Suitable perfume compositions may include long-lasting perfumes, such as perfume raw materials having a logP greater than approximately 2.5 and a boiling point greater than approximately 250 °C. Furthermore, suitable perfume compositions may include floral perfumes comprising perfume raw materials having a logP greater than approximately 3 and a boiling point less than approximately 260 °C. Suitable core materials can be stabilized and / or emulsified in solvent systems with organic or inorganic materials (organic materials can be polymers of anionic, non-ionic, or cationic nature, such as polyacrylates and polyvinyl alcohol). Suitable processes for preparing core-shell systems include coating, extrusion, spray drying, IVIA / a / 1 / UU4l30 interfacial polymerization, polycondensation, simple coacervation, complex coacervation, free radical polymerization, in situ emulsion polymerization, matrix polymerization and combinations thereof. Suitable characteristics for core-deck systems include: a) a coating thickness of approximately 20 nm to approximately 500 nm, approximately 40 nm to approximately 250 nm, or approximately 60 nm to approximately 150 nm; b) a core-to-cover ratio of approximately 5:95 to approximately 50:50, from approximately 10:90 to approximately 30:70, or from approximately 10:90 to approximately 15:85; c) a fracture strength of approximately 0.1 MPa to approximately 16 MPa, from approximately 0.5 MPa to approximately 8 MPa, or even from approximately 1 MPa to approximately 3 MPa; and d) an average particle size of approximately 1 micron to approximately 100 microns, from approximately 5 microns to approximately 80 microns, or even from approximately 15 microns to approximately 50 microns. Suitable coatings to improve deposition and / or retention can be applied to core-shell systems and include non-ionic polymers, anionic polymers, cationic polymers such as polysaccharides including, but not limited to, cationicly modified starch, cationicly modified guar gum, chitosan, polysiloxanes, polydiallyldimethylammonium halides, polydiallyldimethylammonium chloride and vinylpyrrolidone copolymers, acrylamides, imidazoles, imidazolinium halides, imidazolium halides, polyvinylamine, polyvinylamine and N-vinylformamide copolymers, and mixtures thereof. Suitable coatings can be selected from the group consisting of polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinyl alcohol, polyacrylates, and combinations thereof. Suitable methods, such as centrifugation, can be used to reduce and / or physically remove any residual material from the core-shell manufacturing process.Suitable methods can also be employed to chemically reduce any type of residual material, such as the use of scrubbers, for example, formaldehyde scrubbers that include sodium bisulfite, melamine, urea, ethyleneurea, cysteine, cysteamine, lysine, glycine, serine, carnosine, histidine, glutathione, 3,4-diaminobenzoic acid, allantoin, glycouryl, anthranilic acid, methyl anthranilate, methyl 4-aminobenzoate, ethyl acetoacetate, acetoacetamide, malonamide, ascorbic acid, 1,3-dihydroxyacetone dimer, biuret, oxamide, benzoguanamine, pyroglutamic acid, pyrogallol, methyl gallate, ethyl gallate, propyl gallate, triethanolamine, succinamide, thiabendazole, benzotriazole, triazole, indoline, acid sulfanilic, oxamide, sorbitol, glucose, cellulose, poly(vinyl alcohol), partially hydrolyzed poly(vinyl formamide), poly(vinyl amine), poly(ethylene imine),. IVIA / a / 1 / UU4l30 poly(oxyalkylenamine), poly(vinyl alcohol)-co-pol¡(vinyl amine), poly(4-aminoest¡rene), poly(l-lysine), chitosan, hexane diol, ethylenediamine-N,N'-b¡sacetoacetam¡da, N-(2-ethylhexyl)acetoacetamide, 2benzoylacetoacetamide, N-(3-phenylpropyl)acetoacetamide, lilial, helional, melonal, triplal, 5,5-dimethyl-l, 3-cyclohexanedione, 2,4-dimethyl-3-c¡clohexenecarboxaldehyde, 2,2-dimeth¡ll,3-dioxan-4,6-d¡one, 2pentanone, dibutyl amine, triethylenthetramine, ammonium hydroxide, benzylamine, hydroxycitronellol, cyclohexanone, 2-butanone, pentane dione, dehydroacetic acid, or mixtures thereof. Polyacrylate capsules Polyacrylate capsules comprise a core and an outer shell encapsulating the core, wherein the shell comprises polyacrylate polymer. The shell may include from approximately 50% to approximately 100%, or from approximately 70% to approximately 100%, or from approximately 80% to approximately 100% of a polyacrylate polymer. The polyacrylate may include a crosslinked polyacrylate polymer. Polyacrylate capsules comprise an outer covering that defines a core in which a beneficial agent is held until the covering is broken. The cover material may include a material selected from the group consisting of a polyacrylate, a polyethylene glycol acrylate, a polyurethane acrylate, an epoxy acrylate, a polymethacrylate, a polyethylene glycol methacrylate, a polyurethane methacrylate, an epoxy methacrylate, and mixtures thereof. The capsule shell material may include a polymer derived from a material comprising one or more polyfunctional acrylate entities. The polyfunctional acrylate entity may be selected from the group consisting of trifunctional acrylate, tetrafunctional acrylate, pentafunctional acrylate, hexafunctional acrylate, heptafunctional acrylate, and mixtures thereof. The polyfunctional acrylate entity is preferably hexafunctional acrylate. The shell material may include a polyacrylate comprising an entity selected from the group consisting of an acrylate entity, a methacrylate entity, an amine acrylate entity, an amine methacrylate entity, a carboxylic acid acrylate entity, a carboxylic acid methacrylate entity, and combinations thereof, preferably an amine methacrylate or carboxylic acid acrylate entity. The cover material may include a material comprising one or more multifunctional entities of acrylate and / or methacrylate. The ratio of material comprising one or more multifunctional acrylate entities to material comprising one or more methacrylate entities may be from approximately 999:1 to approximately 6:4, preferably from approximately 99:1 to approximately 8:1, most preferably from approximately 99:1 to approximately 8.5:1. The core / cap may comprise an emulsifier, wherein the emulsifier is preferably selected from anionic emulsifiers, non-ionic emulsifiers, cationic emulsifiers or mixtures thereof, preferably non-ionic emulsifiers. The core / cladding material may comprise from 0.01% to 20%, with higher IVIA / a / 1 / UU4l30 preference of 0.05% to 10%, even with a higher preference of 0.1% to 5%, with the highest preference of 0.1% to 2% by weight of the polyvinyl alcohol core / shell capsule. Preferably, the polyvinyl alcohol has at least one of the following properties, or a mixture thereof: (i) a degree of hydrolysis of 55% to 99%, preferably 75% to 98%, with greater preference of 80% to 96%, with greater preference of 82% to 96%, with the highest preference of 86% to 94%; (i) a viscosity of 2 mPa.s 150 mPa.s, preferably 3 mPa.s 70 mPa.s, more preferably 4 mPa.s 60 mPa.s, even more preferably 5 mPa.s 55 mPa.s in 4% aqueous solution at 20 °C; (iii) a degree of polymerization of 1500 to 2500; (iv) an average molecular weight of 65,000 Da to 110,000 Da. Los materiales de alcohol polivinílico adecuados pueden seleccionarse de Selvol 540 PVA (Sekisui Specialty Chemicals, Dallas, TX), Mowiol 18-88 = Poval 18-88, Mowiol 3-83, Mowiol 4-98 = Poval 4-98 (Kuraray), Poval KL-506 = Poval 6-77 KL (Kuraray), Poval R-1130 = Poval 25-98 R (Kuraray), Gohsenx K-434 (Nippon Gohsei). II. Molecularly Assisted Delivery (MAD): Non-polymeric materials or molecules can also enhance the delivery of the organoleptic compounds of Formula I, their stereoisomers, and additional perfume materials, as these materials can interact non-covalently with organic materials, resulting in altered deposition and / or release. Non-limiting examples of such organic materials include, but are not limited to, hydrophobic materials such as organic oils, waxes, mineral oils, petrolatum, fatty acids or esters, sugars, surfactants, liposomes, and even other perfume raw materials (perfume oils), as well as natural oils, including body oils and / or other oils. III. Fiber-Assisted Delivery (FAD): The choice or use of an area can enhance the delivery of the organoleptic compounds of Formula I, their stereoisomers, and additional perfume materials. In fact, the area itself can be a perfume delivery technology. For example, different types of fabrics, such as cotton or polyester, will have different properties regarding their ability to attract, retain, and / or release perfume. The amount of perfume deposited in the fibers can be altered by the choice of fiber, as well as by the fiber's history or treatment, and by any coating or treatment applied to the fiber. Fibers can be pre-loaded with perfume and then added to a product that may or may not contain free perfume or one or more perfume delivery technologies. IV. Amine-Assisted Delivery (AAD): The amine-assisted delivery technology methodology uses materials containing an amine group to IVIA / a / 1 / UU4l30 to increase the deposition or modify the release of the organoleptic compounds of Formula I, stereoisomers thereof, and additional perfume materials during product use. There are no requirements in this methodology to pre-complex or pre-react the perfume raw material(s) and the amine before addition to the product. Suitable AAD materials containing amine for use in this description may be non-aromatic, for example, polyalkylimine, such as polyethyleneimine (PEI) or polyvinylamine (PVAm); or aromatic, for example, anthranilates. The materials may also be polymeric or non-polymeric. Such materials contain at least one primary amine. A material containing a heteroatom other than nitrogen, for example, sulfur, phosphorus, or selenium, may be used as an alternative to amine compounds.In another respect, the alternative organoleptic compounds mentioned above can be used in combination with amine compounds. Furthermore, a single molecule could comprise an amine moiety and one or more alternative heteroatom entities, such as thiols, phosphines, and selenols. V. Cyclodextrin (CD) Delivery System: This technological methodology uses a cyclic oligosaccharide, or cyclodextrin, to enhance the delivery of the organoleptic compounds of Formula I, their stereoisomers, and additional perfume materials. Typically, the organoleptic compounds of Formula I, their stereoisomers, and / or additional perfume materials form a complex with the cyclodextrin complex (CD). Such complexes may be preformed, formed on-site, or formed on or within the area. VI. Starch-Encapsulated Accord (SEA): SEAs are perfume materials encapsulated in starch. Suitable starches include modified starches such as hydrolyzed starch, acid-diluted starch, starch with hydrophobic groups such as starch esters of long-chain hydrocarbons (C5 or higher), starch acetates, starch octenyl succinate, and mixtures thereof. Starch esters such as starch octenyl succinate may also be used. Perfumes suitable for encapsulation include HIA perfumes, which are those with a boiling point at standard normal pressure of approximately 760 mmHg of 275°C or lower, an octanol / water dissociation coefficient (P) of approximately 2000 or higher, and an odor detection threshold (ODT) of 50 parts per billion (ppb) or less. The perfume may have a logP of 2 or higher. VII. Inorganic Carrier Delivery System (ZIC): This technology relates to the use of porous zeolites or other inorganic materials to deliver perfumes. Perfume-loaded zeolite can be used with or without additional ingredients, for example, to coat the perfume-loaded zeolite (PLZ) to change its perfume release properties during product storage, use, or from the dry area. Another example of a suitable inorganic carrier includes inorganic tubes. IVIA / a / 1 / UU4l30 where the perfume or other active material is contained within the lumen of the nano- or microtubules. Monomeric and / or polymeric materials, including starch encapsulation, may be used to coat, plug, seal, or otherwise encapsulate the PLZ. VIII. Perfume Precursor (PP): This technology refers to perfume technologies resulting from the reaction of organoleptic compounds of Formula I, stereoisomers thereof, and additional perfume materials with other substrates or chemicals to form materials having a covalent bond between one or more PRMs and one or more carriers. The PRM is converted into a new material called a PRM precursor (i.e., perfume precursor) which could then release the original PRM upon exposure to an activator, such as water or light. Non-limiting examples of perfume precursors include Michael adducts (e.g., beta-amino ketones), aromatic or non-aromatic imines (Schiff bases), oxazolidines, beta-keto esters, and orthoesters. Another aspect includes compounds comprising one or more beta-oxy or beta-thio carbonyl entities capable of releasing a PRM, for example, an alpha, beta-unsaturated ketone, aldehyde, or carboxylic ester.Silicone compounds, including aminosilicones, may be suitable and even preferred for forming perfume precursor materials with PRMs; therefore, the perfume precursor may be a silicone-based perfume precursor, preferably an aminosilicone-based perfume precursor. The PRMs may be covalently bonded to the silicone compound, for example, by preferably forming an imine linkage with a primary amine group of an aminosilicone, in one or more terminal or non-terminal positions, including pendant positions of a silicone backbone structure. Silicones, in particular, may be preferred as perfume precursor carriers because they can facilitate improved deposition of the PRM fragments onto a target surface, such as a fabric, prior to PRM release. These silicone-based delivery technologies are further described in U.S. Patent Application No.2016 / 0137674A1 (assigned to The Procter & Gamble Company), incorporated in this description by reference. a) Amine Reaction Product (ARP): For the purposes of this application, ARP is a subclass or species of PP. Reactive polymeric amines may also be used in which the amine functionality is pre-reacted with one or more PRMs, typically PRMs containing a ketone and / or aldehyde entity, to form the ARP. Typically, the reactive amines are primary and / or secondary amines and may be part of a polymer or a (non-polymeric) monomer. Such ARPs could be further blended with additional PRMs to provide polymer-assisted delivery and / or amine-assisted delivery benefits. Non-limiting examples of polymeric amines include polyalkylimine-based polymers such as polyethyleneimine (PEI) or polyvinylamine (PVAm). IVIA / a / 1 / UU4l30 Monomeric (non-polymeric) aromatic amines include hydroxylamines, such as 2-aminoethanol and its alkyl-substituted derivatives, and aromatic amines, such as anthranilates. These aromatic amines could be premixed with perfume or added separately in leave-in or rinse-out applications. A material containing a non-nitrogen heteroatom, such as oxygen, sulfur, phosphorus, or selenium, can be used as an alternative to amine compounds. Alternatively, the aforementioned alternative compounds can be used in conjunction with amine compounds. A single molecule could comprise an amine moiety and one or more alternative heteroatom entities, such as thiols, phosphines, and selenols. Methods of use Some consumer products described herein may be used to clean or treat an area, such as a surface or fabric. In one example, at least a portion of the area is brought into contact with a consumer product, either neat or diluted in a liquid, for example, a laundry liquid, and then the fabric may be washed and / or rinsed optionally. In another aspect, an area is brought into contact with a consumer product and then washed and / or rinsed, optionally. For the purposes of the present invention, washing includes, but is not limited to, scrubbing and mechanical agitation. The fabric may comprise, in general, any fabric that can be washed or treated under normal consumer use conditions. The liquids comprising the described compositions may have a pH of approximately 3 to approximately 11.5.The compositions are typically used in concentrations of approximately 500 ppm to approximately 15,000 ppm in solution. When the washing solvent is water, the temperature typically ranges from approximately 5 °C to approximately 90 °C, and when the area comprises a fabric, the water-to-fabric ratio is typically from approximately 1:1 to approximately 30:1. The product can also be sprayed onto the area to be treated. In some applications, after spraying, the product can be wiped off with a cleaning implement, such as a sponge, cloth, towel, or scouring pad. In some applications, after spraying the area with the product, the area can be rinsed with water. Examples The following are provided as specific embodiments of the present invention. Other modifications of this invention will be readily apparent to those skilled in the art. Such modifications are included within the scope of this invention. As used herein, all percentages are weight percentages unless otherwise stated, ppm represents parts per million, L represents liter, mL represents milliliters, g represents IVIA / a / ZUZ1 / UU4l30 grams, Kg represents kilograms, mol represents mole, mmol represents millimole, psig represents pounds-force per square inch gauge, and mmHg is millimeters (mm) of mercury (Hg). IFF as used in the examples represents International Flavors & Fragrances Inc., New York, NY, USA. Example 1 Structure 1 Structure 2 Structure 3 Structure 4 Preparation of (£)-1-((1 / ζ6 / ?)-4,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 1), (£)-1-((1^65)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 2), (£)-1-((1^65)-4,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 3) and (£)-1-((1^6 / 7)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 4): Potassium hydroxide (KOH) (32.5 g, 0.58 mol) was dissolved in methanol (CH3OH) (800 mL). A slight exothermic reaction was observed. The reaction mixture was cooled to room temperature. 3-pentanone ((CH3CH2CO) (299 g, 3.5 mol) was slowly added to the mixture while the temperature was maintained at 20-25 °C. An isomeric mixture of (6 / 7)-4,6-dimethylcyclohex-3-ene-1-carbaldehyde, (15,65)-3,6-dimethylcyclohex-3-ene-1-carbaldehyde, (1 / 7,65)4,6-dimethylcyclohex-3-ene-1-carbaldehyde and (1S,6 / ?)-3,6-dimethylcyclohex-3-ene-1-carbaldehyde (400 g, 2.9 mol) (commercially available at IFF) was fed to the reaction mixture for 56 hours while the reaction mixture was exothermic at 30–35 °C. After feeding was complete, the reaction mixture was heated and then held at 50–55 °C for 3–4 hours. The reaction mixture was cooled to room temperature, inactivated with glacial acetic acid (CH3COOH) (30 g, 0.5 mol), and then heated to 80 °C to distill MeOH. Subsequently, the reaction mixture was washed with brine (500 mL).The aqueous layer was removed and the organic layer was distilled to provide the mixture of (£)-1-((1 / 7,6 / 7)-4,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one, (£)-1-((15)65)-3,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one, (£)-1-((1 / 7,65)4,6-dimethylcyclohex-3-en-l-l)-2-methylpent-l-en-3-one and (£)-l-((15,6 / ?)-3,6-dimethylcyclohex-3-en-l il)-2-methylpent-l-en-3-one (396 g) with a weight ratio of approximately 13:21:26: 37 and has a boiling point of 122 °C at a pressure of 5 mmHg. NMR (m, 3H), 1.65 (m, 3H), 1.07 (m, 3H), 0.84 (m, 3H) The blend of Structures 1-4 was described as having fresh, crisp, light green, resinous, coniferous, floral, ionone-like, amber, and woody notes. These desirable notes were also diffusive and bloomy. Example 2 IVIA / a / 1 / UU4 f 30 Preparation of (£)-1-(( 1^25)-2,4-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 9) and (£)-1-((1^25)-2,4-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one (Structure 10): The mixture of (£)-1-((1 / ?,25)-2,4-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one and (^-1-((15)25)-2,4-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one with a weight ratio of approximately 69:28 was prepared similarly to that in EXAMPLE I from an isomeric mixture of (l / ?,2 / ?)-2,4-dimethylcyclohex-3-ene-l-carbaldehyde and (15)2 / ?)-2,4-dimethylcyclohex-3-ene-l-carbaldehyde (commercially available from IFF). (5) -1-((7R, 25)-2,4-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one had the following NMR spectral characteristics: XH NMR (400 MHz, CDCb) δ: 6.44 (dd, J = 9.7, 1.3 Hz, 1H), 5.18-5.25 (m, 1H), 2.68 (q, J = 7.4 Hz, 2H), 2.11-2.2-3 (m 1. 1, 10). 1.79 (d, J=1.4 Hz, 3H), 1.63–1.71 (m, 1H), 1.67 (s, 3H), 1.41–1.55 (m, 1H), 1.08 (t, J=7.4 Hz, 3H), 0.88 (d, J=6) Hz (J= -1-((7S,25)-2,4-dimet¡lc¡clohex-3-en-l-¡l)-2-met¡lpent-ren-3-one had the following NMR spectral features: XH NMR (400 MHz, CDCb) δ: 6.60 (dd, J=9.7, 1.3 Hz, 1H), 5.25–5.29 (m, 1H), 2.70–2.80 (m, 1H), 2.62 (q, J=7.2 (2 Hz), 1H 2H), 1.85–2.10 (m, 2H), 1.80 (d, J=1.4 Hz, 3H), 1.63–1.71 (m, 2H), 1.67 (s, 3H), 1.07 (t, J=7.4 Hz, 3H), 0.87 (H) 3, J= 6 The blend of Structures 9 and 10 was described as having green, floral and woody notes. Compared to the two blends obtained from EXAMPLE I and EXAMPLE II, respectively, the blend of Structures 1-4 exhibited significantly stronger, longer-lasting, and more complex notes. In contrast, the blend of Structures 9 and 10 sounded weak, thin, less natural, and harsh. Furthermore, the resinous and coniferous notes present in the blend of Structures 1-4 were absent from the blend of Structures 9 and 10. Example 3 The mixture of (£)-1-((1 / 2,6 / ?)-4,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one, (£)-1-((15)65)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one, (£)-1-((1 R, 65)-4,6dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one and (£)-1-((15)6 / 2)-3,6-dimethylcyclohex-3-en-l-yl)-2methylpent-l-en-3-one (25.0 g, 121 mmol) is dissolved in tetrahydrofuran (250 ml, 0.5M). Cool the mixture to 0 °C and add lithium aluminum hydride in small portions (2.3 g, 60.5 mmol). Then, allow the mixture to warm to room temperature. Stirring continued for 50 minutes at this temperature to achieve complete conversion of the starting material. The mixture was cooled to 0 °C. Subsequently, water (2.3 mL), aqueous sodium hydroxide (15%) (2.3 mL), and water (4.6 mL) were added to the mixture, and the mixture was stirred at room temperature overnight. The mixture was filtered over a layer of Celite, and the filter cake was washed with tetrahydrofuran (50 mL). The filtrate was evaporated under reduced pressure and dried under high vacuum to obtain 20 g of product. (79% yield) Example 4: Preformed product from amine reaction The following ingredients are weighed into a glass jar: 1. 50% of a perfume composition comprising one or more organoleptic compounds of Structures 1, 2, 3, 4, or isomers thereof; 2. Place 50% of BASF's Lupasol WF (CAS No. 09002-98-6) in a warm water bath at 60°C for 1 hour before use. The two ingredients are mixed using the UltraTurraxT25 basic equipment (from IKA) for 5 minutes. Once mixing is complete, the sample is placed in a warm water bath at 60 °C for approximately 12 hours. A viscous and homogeneous material is obtained. In the same way as described above, different relationships between the components can be used: IVIA / a / 1 / UU4 í 30 % by weight Perfume composition 40 50 60 70 80 Lupasol WF 60 50 40 30 20 Example 5: Melamine formaldehyde PAD capsule deposition system (IMF) with 84% core and 16% wall 25 grams of butylacrylate and acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pka 4.5-4.7, Kemira Chemicals, Inc. Kennesaw, Georgia, USA) are dissolved and mixed in 200 grams of deionized water. The pH of the solution is adjusted to 4.0 with a sodium hydroxide solution. Eight grams of partially methylated melamine methylol resin (CIMEL 385, 80% solids (CITEC Industries, West Paterson, New Jersey, USA)) are added to the emulsifier solution. Two hundred grams of perfume oil comprising Structures 1, 2, 3, 4, or isomers thereof of Formula I are added to the mixture with mechanical stirring, and the temperature is raised to 50°C. After mixing at a higher speed until a stable emulsion is obtained, the second solution and four grams of sodium sulfate salt are added to the emulsion.This second solution contains 10 grams of butylacrylate-acrylic acid copolymer emulsifier (Colloid C351, 25% solids, pKa 4.5–4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to adjust the pH to 4.8, and 25 grams of partially methylated melamine methylol resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 70 °C and held overnight with continuous stirring to complete the encapsulation process. Twenty-three grams of acetoacetamide (Sigma-Aldrich, Saint Louis, Missouri, USA) are added to the suspension. An average capsule size of 30 µm is obtained, as analyzed using an Accusizer model 780. Example 6: Polyacrylate-based PAD capsule deposition system Suitable perfume capsules can be purchased from Encapsys (825 East Wisconsin Ave, Appleton, WI 54911) and are prepared as follows: A first oil phase, consisting of 37.5 g of perfume, 0.2 g of ethyl tert-butylamine methacrylate, and 0.2 g of beta-hydroxyethyl acrylate, is mixed for approximately 1 hour before the addition of 18 g of CN975 (Sartomer, Exter, PA). The solution is mixed as required for the subsequent process. A second oil phase, consisting of 65 g of the organoleptic compound of Formula I and stereoisomers thereof, 84 g of isopropyl myristate, 1 g of 2,2'-azobis(2-methylbutyronitrile), and 0.8 g of 4,4'-azobis[4-cyanovaleric acid], is added to a lined steel reactor. The reactor is maintained at 35 °C, and the oil solution is mixed at 500 rpm using a 2-inch flat paddle mixer. A nitrogen blanket is applied to the reactor at a rate of 300 cc / min. The solution is heated to 70 °C in 45 minutes and held at 70 °C for 45 minutes before being cooled to 50 °C in 75 minutes. The first oil phase at 50 °C is added, and the combined oils are mixed for a further 10 minutes at 50 °C. An aqueous phase, containing 85 g of Celvol 540 PVA (Sekisui Specialty Chemicals, Dallas, TX) at 5% solids, 268 g of water, 1.2 g of 4,4'-azobis[4-cyanovaleric acid], 1.1 g of 21.5% NaOH, was prepared and mixed until the 4,4'-AZOBIS[4-cyanovaleric acid] IVIA / a / 1 / UU4l30 dissolves. The pH of the aqueous phase for this was 4.90. Once the temperature of the oil phase has been reduced to 50 °C, mixing is stopped and the aqueous phase is added to the blended oils. High shear agitation is applied to produce an emulsion with the desired size characteristics (1900 rpm for 60 minutes). The temperature was then increased to 75°C in 30 minutes, held at 75°C for 4 hours, heated to 95°C in 30 minutes, and held at 95°C for 6 hours. The batch was then allowed to cool to room temperature. Example 7: Process for developing a polymer-assisted delivery array (PAD) system A mixture comprising 50% of a perfume composition comprising one or more of Structures 1, 2, 3, 4, or isomers thereof of Formula 1, 40% of carboxyl-terminated Hycar® 1300X18 (CAS No. 0068891-50-9) from Noveon (placed in a warm water bath at 60°C for 1 hour before mixing), and 10% of Lupasol® WF (CAS No. 09002-98-6) from BASF (placed in a warm water bath at 60°C for 1 hour before mixing). Mixing is achieved by blending for five minutes using an IKA Ultra-Turrax T25 Basic Mixer. After blending, the mixture is placed in a warm water bath at 60°C for approximately 12 hours. A homogeneous, viscous, and sticky material is obtained. In the same way as described above, different relationships between the components can be used: IVIA / a / 1 / UU4l30 % by weight Perfume composition 40 50 60 70 80 Lupasol® WF 12 10 8 6 4 Hycar® CTBN1300X18 48 40 32 24 16 % by weight Perfume compositions 50 50 50 50 50 50 50 50 Lupasol® WF 2.5 5 7.5 10 12.5 15 17.5 20 Hycar® CTBN 1300X18 47.5 45 42.5 40 37.5 35 32.5 30 Example 8: Product Formulation Non-limiting examples of product formulations containing PRM in the present specification of perfumes and amines presented in the following table. IVIA / a / 1 / UU4l30 EXAMPLES (percent by weight) XI XII 0.81 0.81 Isopropyl alcohol - — — — — - 0.33 1.22 — - Starch d 1.25 1.47 2.00 1.25 — 2.30 0.5 0.70 0.71 0.42 Amine* 0.6 0.75 0.6 0.75 0.37 0.60 0.37 0.6 0.37 0.37 Perfume Xe 0.40 0.13 0.065 0.25 0.03 0.030 0.030 0.065 0.03 0.03 Stabilizing phase polymer f 0.21 0.25 0.21 0.21 0.14 — — 0.14 — — Foam suppressant g — - — — — — — 0.1 — - Calcium chloride 0.15 0.176 0.15 0.15 0.30 0.176 — 0.1-0.15 — - DTPAh 0.017 0.017 0.017 0.017 0.007 0.007 0.20 — 0.002 0.002 Preservative (ppm) H 5 5 5 5 5 5 — 250 j 5 5 Antifoam 0.015 0.018 0.015 0.015 0.015 0.015 — — 0.015 0.015 Dye (ppm) 40 40 40 40 40 40 11 30-300 30 30 Ammonium chloride 0.100 0.118 0.100 0.100 0.115 0.115 — HCl 0.012 0.014 0.012 0.012 0.028 0.028 0.016 0.025 0.011 0.011 Structuring agent 1 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 Additional pure perfume 0.8 0.7 0.9 0.5 1.2 0.5 1.1 0.6 1.0 0.9 Deionized water + + + + + + + + + +. aN,N-di(tallow¡lox¡ethyl)-N,Ndimethylammonium chloride. 10Methyl bis(tallowam¡doethyl)2-hydroxy¡ethylammonium methylsulfate. Fatty acid reaction product with methyldiethanolamine in a molar ratio of 1.5:1, quaternized with methyl chloride, which produces a 1:1 molar mixture of N,N-bis(stearoyl-oxy-ethyl) N,N-dimethylammonium chloride and N-(stearoyl-oxy-ethyl) N,N-hydroxyethyl N,N-dimethylammonium chloride. 01 High amylose cationic corn starch, available from National Starch under the trade name CATO®. ePerfume comprising one or more of Structures 1,2,3,4, and isomers thereof of Formula I above.fEthylene oxide and terephthalate copolymer with the formula described in U.S. Patent No. 5,574,179, column 15, lines 1 to 5, wherein each X is methyl, each n is 40, u is 4, each R1 is essentially 1,4-phenylene entities, each R2 is essentially 1,2-propylene, ethylene, or mixtures of these entities. 9 SE39 of Wacker h Diethylenetriaminepentaacetic acid. ' KATHON® CG, available from Rohm and Haas Co. PPM is parts per million. j Gluteraldehydek Silicone antifoaming agent, available from Dow Corning Corp. under the trade name DC2310. 1Hydrophobically modified ethoxylated urethane, available from Rohm and Haas under the trade name of Aculan 44. * One or more materials comprising an amine portion as described in this specification. + Balance IVIA / a / 1 / UU4l30 Example 9: Dry formulations for laundry Component % w / w of granular composition of laundry detergent ABCDEFG Brightener 0.1 0.1 0.1 0.2 0.1 0.2 0.1 Soap 0.6 0.6 0.6 0.6 0.6 0.6 0.6 Ethylenediaminedisuccinic acid 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Acrylate / maleate copolymer 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Hydroxyethanedi(methylenephosphonic) acid 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Quaternary monoalkyl chloride Ciz-h, dimethyl, monohydroxyethyl ammonium 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Linear alkylbenzene 0.1 0.1 0.2 0.1 0.1 0.2 0.1 Linear alkylbenzene sulfonate 10.3 10.1 19.9 14.7 10.3 17 10.5 Magnesium sulfate 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Sodium carbonate 19.5 19.2 10.1 18.5 29.9 10.1 16.8 Sodium sulfate 29.6 29.8 38.8 15.1 24.4 19.7 19.1 Sodium chloride 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Zeolite 9.6 9.4 8.1 18 10 13.2 17.3 Photobleaching particle 0.1 0.1 0.2 0.1 0.2 0.1 0.2 Blue and red carbonate specks 1.8 1.8 1.8 1.8 1.8 1.8 1.8 Ethoxylated alcohol AE7 1 1 1 1 1 1 1 Tetraacetylethylenediamine agglomerate 0.9 0.9 0.9 0.9 0.9 0.9 0.9. (92% by weight active) Citric acid 1.4 1.4 1.4 1.4 1.4 1.4 1.4 PDMS / clay agglomerates (9.5% by weight active PDMS) 10.5 10.3 5 15 5.1 7.3 10.2 Polyethylene oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Enzymes, for example, protease (84 mg / g active), amylase (22 mg / g active) 0.2 0.3 0.2 0.1 0.2 0.1 0.2 Foam suppressant agglomerate (12.4% by weight active) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Sodium percarbonate (having 12% to 15% active AvOx) 7.2 7.1 4.9 5.4 6.9 19.3 13.1 Additional pure perfume** 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Amine* 0.1 0.5 0.0 0.01 0.02 0.00 0.07 Perfume delivery system as described herein including Examples 3-5 0.05 0.0 0.1 0.0 0.2 0.4 0.0 Perfume comprising one or more of Structures 1, 2, 3, 4, and isomers thereof of Formula I above 0.3 0.4 0.01 0.02 0.04 0.1 0.1 Water 1.4 1.4 1.4 1.4 1.4 1.4 1.4 Mise. 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Total parts 100 100 100 100 100 100 100 One or more materials comprising an amine portion as described in this specification. ** Optional Example 10: Liquid formulations for laundry (HDL) Ingredient HDL 1 HDL 2 HDL 3 HDL 4 HDL 5 HDL 6 Alkyl ether sulfate 0.00 0.50 12.0 12.0 6.0 7.0 Dodecylbenzene sulfonic acid 8.0 8.0 1.0 1.0 2.0 3.0 Ethoxylated alcohol 8.0 6.0 5.0 7.0 5.0 3.0 Citric acid 5.0 3.0 3.0 5.0 2.0 3.0 Fatty acid 3.0 5.0 5.0 3.0 6.0 5.0 Quaternized hexamethylenediamine ethoxysulfate 1.9 1.2 1.5 2.0 1.0 1.0 Diethylenetriaminepenta(methylenephosphonic acid) 0.3 0.2 0.2 0.3 0.1 0.2 Enzymes 1.20 0.80 0 1.2 0 0.8 Brightener (FWA based on diaminostilbene disulfonate) 0.14 0.09 0 0.14 0.01 0.09 Cationic hydroxyethylcellulose 0 0 0.10 0 0.200 0.30 Poly(acrylamide-co-diallyldimethylammonium chloride) 0 0 0 0.50 0.10 0 Hydrogenated castor oil bulking agent 0.50 0.44 0.2 0.2 0.3 0.3 Boric acid 2.4 1.5 1.0 2.4 1.0 1.5 Ethanol 0.50 1.0 2.0 2.0 1.0 1.0 1,2 Propanediol 2.0 3.0 1.0 1.0 0.01 0.01 Glutaraldehyde 0 0 19 ppm 0 13 ppm 0 Diethylene glycol (DEG) 1.6 0 0 0 0 0 2,3-Methyl-1,3-propanediol (M pdiol) 1.0 1.0 0 0 0 0 Monoethanolamine 1.0 0.5 0 0 0 0 NaOH sufficient to provide a Formulation pH of: pH 8 pH 8 pH 8 pH 8 pH 8 pH 8 Sodium cumenesulfonate (NaCS) 2.00 0 0 0 0 0 Silicone emulsion (PDMS) 0.003 0.003 0.003 0.003 0.003 0.003 Additional pure perfume** 0.7 0.5 0.8 0.8 0.6 0.6 Amine* 0.01 0.10 0.0 0.10 0.20 0.05 Perfume comprising one or more of Structures 1, 2, 3, 4, and isomers thereof of Formula I above 0.02 0.15 0.0 0.2 0.3 0.1 Perfume delivery system as described in this specification including Examples 3-4 0.2 0.02 0.4 0.0 0.0 0.0 Water Balance Balance Balance Balance Balance Balance. One or more materials comprising an amine portion as described in this specification. ** Optional. Example 11: Shampoo formulations Ingredient Ammonium laureth sulfate (P&G, 3 EO) 6.00 Ammonium laureth sulfate 10.00 IVIA / a / 1 / UU4l30 Laureth-4 alcohol 0.90 Trihydroxystearin (7) 0.10 Perfume comprising one or more of Structures 1, 2, 3, 4, and isomers thereof of Formula I above 0.60 Sodium chloride 0.40 Citric acid 0.04 Sodium citrate 0.40 Sodium benzoate 0.25 Ethylenediaminetetraacetic acid 0.10 Dimethicone (9'10'11] 1.00 (9) Water and minor components (QS at 100%) Equilibrium IVIA / a / ZUZ1 / UU4l30 Example 12: Preparation of an illustrative silicone-based perfume precursor comprising an organoleptic compound according to the present description To form a silicone-based perfume precursor, 50.0 g of an aminosilicone (silicone KF-8003, commercially available from Shin-Etsu Silicones; 0.0264 mol) and 5.45 g of an organoleptic compound as described herein (0.0264 mol) are weighed into a 250 mL three-necked flask containing a magnetic stir bar. The reaction mixture is stirred for 24 hours at 80°C under nitrogen scavenging (to remove water). The formation of ion bonds is analyzed using 13C-NMR. The overall reaction is represented by the equation below, where R-NH2 represents the starting aminosilicone. It is understood that the starting aminosilicone includes a plurality of -NH2 entities, and that the reaction described below can occur on more than one -NH2 entity within the aminosilicone. This advantageously results in a plurality of organoleptic compounds being charged on the aminosilicone. The reaction product of the perfume precursor may be suitable for formulation in a consumer product, such as a fabric care product (e.g., a liquid fabric improver). It is also understood that different aminosilicones can be substituted for the illustrated aminosilicon KF-8003, but that the reaction shown above may remain substantially the same. The dimensions and values ​​described herein should not be understood as strictly limited to the exact numerical values ​​stated. Instead, unless otherwise specified, each such dimension shall mean the stated value and a functionally equivalent range encompassing that value. For example, a dimension described as 40 mm refers to approximately 40 mm. All documents mentioned in the Detailed Description of the Invention are incorporated herein, in their relevant parts, by reference; the citation of any document shall not be construed as an admission that it is a prior art with respect to the present invention. To the extent that any meaning or definition of a term herein conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to the term herein shall prevail. Although particular embodiments of the present invention have been illustrated and described, it will be evident to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended that the appended claims encompass all changes and modifications within the scope of this invention.

Claims

1. A consumer product comprising a compound selected from the group comprising: (E)-l-((IR,6R)-4,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one; (E)-l((15,65)-3,6-dimethylc¡clohex-3-en-l-¡l)-2-meth¡lpent-l-en-3-one; (E)-l-((lR,6S)-4,6-dimethylcyclohex-3en-l-yl)-2-methylpent-l-en-3-one; (E)-l-((lC,6R)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3ona; and a mixture of these.

2. The consumer product of claim 1, wherein the organoleptic compound is the mixture of (E)-l-(lR,6R)-4,6-dimethylcyclohex-3-en-l-¡l)-2methylpent-l-en-3-one, (E)-l-((lS,6S)-3,6-dimethylcyclohex-3-en-l-yl)-2-methylpent-l-en-3-one, (E)-l((lR,6S)-4,6-d¡methylc¡chlohex-3-en-l-¡l)-2-methlpent-en-3-en-3-one (E)-l-((lC,6R)-3,6-dimethylcyclohex3-en-l-yl)-2-methylpent-l-en-3-one.

3. The consumer product according to any of the preceding claims, further comprising, based on the total weight of the composition, from approximately 0.0001% to approximately 25% of the organoleptic compound.

4. The consumer product according to any of the preceding claims, characterized in that the consumer product is a cleaning and / or treatment composition, the composition comprising, based on the total weight of the composition, from approximately 0.0001% to approximately 25% of the organoleptic compound.

5. The consumer product according to any of the preceding claims, characterized in that the consumer product is a cleaning and / or treatment composition for fabrics and / or hard surfaces, the composition comprising, based on the total weight of the composition, from approximately 0.00001% to approximately 25% of the organoleptic compound.

6. The consumer product according to any of the preceding claims, characterized in that the consumer product is a detergent, the detergent comprising, based on the total weight of the detergent, from approximately 0.00001% to approximately 25% of the organoleptic compound.

7. The consumer product according to any of the preceding claims, characterized in that the consumer product is a highly compact consumer product, the highly compact consumer product comprising, based on the total weight of the highly compact consumer product, from approximately 0.00001% to approximately 25% of the organoleptic compound.

8. A method for treating an area with the consumer product of any of the preceding claims.

9. A perfume delivery system comprising a compound selected from the group consisting of: (E)-1-((1R,6R)-4,6-dimethylcyclohex-3-en-1-yl)-2-methylpent-len-3-one; (E)-1-((1S,65)-3,6-dimethylcyclohex-3-en-1-1)-2-methylpent-1-en-3-one; (E)-1-((1R,6S)-4,6-dimethylcyclohex-3-en-1-1)-2-methylpent-1-en-3-one; (E)-1-((1S,6R)-3,6-dimethylcyclohex-3-en-1-yl)-2-methylpent-1-en-3-one; and a mixture thereof, characterized in that the perfume delivery system is selected from a polymer-assisted delivery system; a molecule-assisted delivery system; a fiber-assisted delivery system; an amine-assisted delivery system; a cyclodextrin delivery system; a starch-encapsulated accord; an inorganic carrier delivery system; or a perfume precursor.

10. The perfume delivery system of claim 9, characterized in that the organoleptic compound is the mixture of (E)-l-(lR,6R)-4,6-dimethylcyclohex-3-en-l-yl)-2methylpent-l-en-3-one, and (E)-l-((lS,6R)-3,6-dimethylcyclohex3-en-l-yl)-2-methylpent-l-en-3-one.

11. The perfume delivery system of claim 9 or claim 10, further comprising, based on the total weight of the perfume delivery system, from approximately 0.1% to approximately 99% of the organoleptic compound.

12. A perfume delivery system according to any of claims 9-11, characterized in that the perfume delivery system is a capsule.

13. A perfume delivery system according to any of claims 9-12, characterized in that the perfume delivery system is a starch-encapsulated accord.

14. A method for treating an area with a consumer product comprising the perfume delivery system of any of claims 9-13.