Ester, base agent for cosmetic, and cosmetic

Abstract

The present invention provides an ester synthesized from a component A that is at least one selected from C2-8 divalent alcohols, a component B that is at least one selected from C2-10 divalent carboxylic acids, and a component C that is at least one selected from C4-6 hydroxycarboxylic acids having two or more carboxy groups.

Description

Esters, cosmetic bases and cosmetics

[0001] The present invention relates to an ester, a cosmetic base comprising the ester, and a cosmetic containing the cosmetic base.

[0002] Moisture retention is essential for maintaining healthy skin, and numerous cosmetics have been developed with the aim of moisturizing. In cosmetics, hydrocarbon oils such as petrolatum and liquid paraffin, and ester oils such as neopentyl glycol dicaprate and glyceryl tri-2-ethylhexanoate, are used to moisturize and soften the skin. However, some hydrocarbon oils, such as waxes, have issues with their feel during use, such as stickiness and oiliness, so ester oils with a less oily feel are preferred. Patent Document 1, for example, discloses an ester composed of a polyhydric alcohol, a fatty acid having 8 to 30 carbon atoms, and a dibasic carboxylic acid having 12 to 30 carbon atoms, such as an ester synthesized from glycerin, behenic acid, and eicosadioic acid (hereinafter referred to as "glyceryl behenate eicosadioate").

[0003] Recently, there has been a trend toward more environmentally friendly products, and bases used in these products are preferably made from natural materials. In particular, bases made from natural materials that have superior moisturizing effects and are not sticky are in demand. In particular, moisturizing ingredients that are soluble in oil and water while also having an emollient effect like oil and can be incorporated into formulations for a wide range of applications are desired. As a moisturizing base made from natural materials, for example, malic acid, a type of hydroxycarboxylic acid, is widely used in cosmetics due to its excellent safety and stability. Patent Document 2, for example, discloses diisostearyl malate as a derivative of malic acid.

[0004] However, although esters such as glyceryl behenate eicosanedioate and diisostearyl malate have oily properties and moisturizing properties, they are insoluble in water and therefore have limited application.

[0005] JP 2009-19049 A JP 2020-2055 A

[0006] The present invention has been made in view of the above circumstances, and an object of the present invention is to provide an ester which has good solubility in water and oil and is not sticky.

[0007] The present invention, which can achieve the above object, is as follows: [1] An ester synthesized from component A, which is at least one dihydric alcohol selected from dihydric alcohols having 2 to 8 carbon atoms, component B, which is at least one dicarboxylic acid selected from dicarboxylic acids having 2 to 10 carbon atoms, and component C, which is at least one hydroxycarboxylic acid selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and two or more carboxy groups. [2] A cosmetic base comprising the ester described in [1] above. [3] A cosmetic containing the cosmetic base described in [2] above.

[0008] According to the present invention, an ester having good solubility in water and oil and no sticky feeling can be obtained.

[0009] Preferred embodiments of the present invention will be described in detail below. The descriptions in this specification can be combined with each other unless it is clear that they cannot be combined. In this specification, a numerical range defined using "to" includes the numerical values ​​at both ends (upper and lower limits) of "to." For example, "2 to 8" means "2 or more and 8 or less."

[0010] <Ester> The ester of the present invention is synthesized from: Component A, which is at least one dihydric alcohol selected from dihydric alcohols having 2 to 8 carbon atoms; Component B, which is at least one dicarboxylic acid selected from dicarboxylic acids having 2 to 10 carbon atoms; and Component C, which is at least one hydroxycarboxylic acid selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and two or more carboxy groups.

[0011] Examples of component A include ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, neopentyl glycol, 1,2-octanediol, and 1,6-octanediol.

[0012] From the viewpoints of the solubility in water of the ester of the present invention and the feeling upon use, component A is preferably at least one selected from dihydric alcohols having 2 to 6 carbon atoms, more preferably at least one selected from dihydric alcohols having 2 to 4 carbon atoms, even more preferably at least one selected from linear dihydric alcohols having 3 to 4 carbon atoms, particularly preferably 1,3-propanediol and / or 1,4-butanediol, and most preferably 1,3-propanediol.

[0013] Examples of component B include oxalic acid, malonic acid, succinic acid, maleic acid, glutaric acid, adipic acid, sebacic acid, and azelaic acid.

[0014] From the viewpoints of the solubility of the ester of the present invention in water and oil and the feeling upon use, Component B is preferably at least one selected from dicarboxylic acids having 2 to 8 carbon atoms, more preferably at least one selected from dicarboxylic acids having 2 to 6 carbon atoms, even more preferably at least one selected from dicarboxylic saturated carboxylic acids having 4 to 6 carbon atoms, and particularly preferably succinic acid and / or adipic acid.

[0015] Examples of component C include malic acid, tartaric acid, citric acid, etc. The number of carboxy groups contained in one molecule of component C is preferably 2 or 3.

[0016] From the viewpoint of usability, component C is preferably at least one selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and one hydroxy group and two or more carboxy groups, more preferably at least one selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and one hydroxy group and two or three carboxy groups, even more preferably malic acid and / or citric acid, and particularly preferably malic acid.

[0017] From the viewpoint of suppressing stickiness and water solubility of the ester of the present invention, the ratio of the constituent component derived from component A (hereinafter referred to as "A ｍｏｌ％ ") is 50 to 65 mol %, and the proportion of the constituent component derived from component B (hereinafter referred to as "B ｍｏｌ％ ") is 1 to 25 mol %, and the proportion of the constituent component derived from component C (hereinafter referred to as "C ｍｏｌ％ ") is preferably 25 to 34 mol %. ｍｏｌ％ , B ｍｏｌ％ , and C ｍｏｌ％ The standard is the sum of the components derived from components A to C.

[0018] From the viewpoint of suppressing stickiness and water solubility of the ester of the present invention, A ｍｏｌ％ is more preferably 55 to 65 mol %. ｍｏｌ％ is more preferably 10 to 25 mol %, and further preferably 10 to 20 mol %. ｍｏｌ％ is more preferably 25 to 32 mol %, and further preferably 25 to 29 mol %. ｍｏｌ％ is 50 to 65 mol %, and B ｍｏｌ％ is 10 to 25 mol %, and C ｍｏｌ％ is more preferably 25 to 32 mol %, and A ｍｏｌ％ is 55 to 65 mol %, and B ｍｏｌ％ is 10 to 20 mol %, and C ｍｏｌ％ is more preferably 25 to 29 mol %.

[0019] A ｍｏｌ％ , B ｍｏｌ％ , C ｍｏｌ％ is the ester of the present invention １This value is calculated by analyzing a chart of H NMR (frequency: 400 MHz, solvent: deuterated methanol).

[0020] The hydroxyl value of the ester of the present invention is preferably 100 to 500 mgKOH / g, more preferably 200 to 450 mgKOH / g, and even more preferably 300 to 400 mgKOH / g, from the viewpoint of suppressing stickiness and water solubility. The kinematic viscosity of the ester of the present invention at 40°C is preferably 100 to 600 mm ２ / s, and more preferably 150 to 450 mm ２ / s, and more preferably 150 to 300 mm ２ / s.

[0021] The ester of the present invention can be produced by an esterification reaction of Components A, B, and C. Esterification reactions are well known to those skilled in the art, and those skilled in the art can produce the ester of the present invention by appropriately setting the conditions for the esterification reaction.

[0022] The esterification reaction is usually carried out while removing water from the system in order to promote the reaction. The esterification reaction may be carried out under normal pressure or under reduced pressure. The temperature of the esterification reaction is, for example, 100 to 200°C. In order to obtain an ester with excellent color, the temperature of the esterification reaction is preferably 100 to 160°C, more preferably 120 to 150°C.

[0023] The esterification reaction may be carried out in the presence of a catalyst (for example, a Bronsted acid catalyst or a Lewis acid catalyst) or in the absence of a catalyst.

[0024] The progress of the esterification reaction can be monitored by measuring the acid value of the reaction mixture. The resulting ester is preferably purified by a known method. For example, free carboxylic acid remaining in the reaction mixture may be removed using an alkaline aqueous solution, or the reaction mixture may be distilled, deodorized with steam, or treated with activated carbon for the purpose of reducing odor and improving stability.

[0025] <Cosmetic base and cosmetic> The present invention provides a cosmetic base comprising the ester of the present invention. Here, "cosmetic base" refers to a base component constituting a cosmetic. The present invention also provides a cosmetic containing the cosmetic base of the present invention.

[0026] The content of the cosmetic base of the present invention in the cosmetic of the present invention is preferably 0.001 to 90% by mass, more preferably 0.1 to 50% by mass, even more preferably 0.1 to 20% by mass, and particularly preferably 0.1 to 10% by mass, based on the total mass of the cosmetic.

[0027] The cosmetic of the present invention may contain other components different from the cosmetic base of the present invention described above. Examples of other components include, but are not limited to, powder components, liquid oils and fats, solid oils and fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters different from the cosmetic base of the present invention, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, water-soluble polymers, thickeners, film-forming agents, UV absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, fragrances, and water. Each of the other components may be used alone, or two or more may be used in combination.

[0028] The form of the cosmetic of the present invention is not particularly limited, and may be, for example, any of a solution, emulsion, powder, water-oil two-layer, water-oil-powder three-layer, gel, paste, mist, spray, mousse, roll-on, or stick. The cosmetic of the present invention may also be used in the form of being impregnated into or coated on a sheet such as a nonwoven fabric.

[0029] Furthermore, the product form of the cosmetic of the present invention is not particularly limited, and examples thereof include facial cosmetics such as lotion, milky lotion, cream, gel, pack, and water balm; makeup cosmetics such as base cosmetics, foundation, lipstick, and eye shadow; sunscreen cosmetics (sunscreen agents); body cosmetics such as deodorant, deodorant spray, and deodorant sheet; aromatic cosmetics; skin cleansers or facial washes such as makeup removers, body shampoos, and cleansing lotions; hair cosmetics such as hair liquids, hair tonics, hair waxes, hair conditioners, hair treatments, shampoos, rinses, and hair growth agents; and ointments.

[0030] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

[0031] <Synthesis of Ester> (Example 1) 200 g (2.63 mol) of 1,3-propanediol, 34.9 g (0.24 mol) of adipic acid, and 134.1 g (0.56 mol) of malic acid were charged into a four-neck flask, and the reaction was continued under a nitrogen atmosphere at 130°C and atmospheric pressure while distilling off the reaction water. The acid value was measured every hour, and the reaction was continued until the rate of decrease in the acid value per hour reached 0.5 or less. Next, the acid value was measured every hour at the same temperature and under a reduced pressure of 1 to 5 kPa, and the reaction was continued until the rate of decrease in the acid value per hour reached 0.5 or less, thereby obtaining a crude ester. Thereafter, 350 g of ethyl acetate was charged, and the mixture was washed with water to remove excess 1,3-propanediol, and then the ethyl acetate was removed by distillation under reduced pressure. Next, acid clay and a silica-alumina-based adsorbent were added so that each amount was 1.0 mass% of the ester amount, and an adsorption treatment was carried out. The temperature, pressure, and time of the adsorption treatment were 100° C., 1 to 5 kPa, and 2 hours. Finally, filtration was carried out using a 1 micron filter to obtain ester 1.

[0032] Example 2 230 g (3.02 mol) of 1,3-propanediol, 59.5 g (0.50 mol) of succinic acid, and 64.5 g (0.34 mol) of citric acid were charged into a four-necked flask, and the subsequent steps were carried out in the same manner as in Example 1, to obtain ester 2.

[0033] Comparative Example 1 220 g (2.89 mol) of 1,3-propanediol and 129.2 g (0.96 mol) of malic acid were charged into a four-necked flask, and the subsequent steps were carried out in the same manner as in Example 1, to obtain ester 3.

[0034] Comparative Example 2 200 g (2.63 mol) of 1,3-propanediol and 129.1 g (0.88 mol) of adipic acid were charged into a four-necked flask, and the subsequent steps were carried out in the same manner as in Example 1, to obtain ester 4.

[0035] <Analysis of Ester> The obtained ester was analyzed according to the following method. The results are shown in Table 1.

[0036] (Composition) of the obtained ester １ H NMR measurement was performed, and A ｍｏｌ％ , B ｍｏｌ％ , and C ｍｏｌ％ was calculated.

[0037] (Hydroxyl Value) The hydroxyl value of the obtained ester was measured in accordance with JIS K0070.

[0038] (Kinematic Viscosity) The kinematic viscosity of the obtained ester was measured in accordance with JIS K2283.

[0039] (Solubility in Water) A 50% by mass aqueous solution of the obtained ester was prepared, and its appearance was visually confirmed. If the appearance was uniform, it was evaluated as ◯, and if it was non-uniform, it was evaluated as ×.

[0040] (Solubility in Olive Oil) A 1% by mass olive oil solution of the obtained ester was prepared, and the appearance thereof was visually confirmed. If the appearance was uniform, it was evaluated as ◯, and if it was non-uniform, it was evaluated as ×.

[0041] (Sticky Feeling) Twenty women (aged 22 to 40) served as panelists, and after blending the obtained ester (approximately 1 g) into their skin, they evaluated the sticky feeling using the following rating and criteria. Esters rated as "Good" or "Excellent" were judged to be cosmetic bases that do not have a sticky feeling. (Rating) 2 points: No sticky feeling after blending into skin 1 point: Slight sticky feeling after blending into skin 0 point: Sticky feeling after blending into skin (Criteria) Good: Total score is 30 points or more Good: Total score is 20 points or more and 29 points or less X: Total score is 19 points or less

[0042]

[0043] The results in Table 1 show that the ester of the present invention has good solubility in water and oil, is not sticky, and provides an excellent feel when used.

[0044] <Formulation Examples of Cosmetics> Formulation examples of cosmetics using the ester of the present invention (i.e., Ester 1 or 2) as a cosmetic base are described below. Note that the numerical value of each component below (e.g., "10" in "Glycerin: 10") indicates the amount (% by mass) of that component.

[0045] Formulation Example 1 Oil-in-water emulsion Water: balance Glycerin: 10 BG: 5 DPG: 5 Dimethicone: 3 Diglycerin: 1 (PEG-240 / Decyltetradeceth-20 / HDI) copolymer: 1 Sodium chloride: 0.5 Gellan gum: 0.2 Polyquaternium-51: 0.01 Aspartic acid: 0.1 Tea leaf extract: 0.01 Ester 1 or 2: 0.5 Sodium acetyl hyaluronate: 0.01 Trimethylsiloxysilicate: 0.1 Water-soluble collagen: 0.01 Sodium citrate: 0.1 Sodium metaphosphate: 0.1 (Acrylates / C10-30 alkyl acrylate) crosspolymer: 0.05 Ethanol: 0.5 Potassium hydroxide: 0.03 Citric acid: 0.1 Sodium metabisulfite: 0.1 BHT: 0.01 Phenoxyethanol: 0.6, Chlorphenesin: 0.2, Fragrance: 0.05

[0046] Formulation Example 2: Water-in-oil cream Water: balance Glycerin: 10 Butylene Glycol: 6 Retinol: 1 Isododecane: 5 Isohexadecane: 5 Dimethicone: 5 Cetyl ethylhexanoate: 5 Hydrogenated polydecene: 4 Disteardimonium hectorite: 2 PEG-9 polydimethylsiloxyethyl dimethicone: 1.5 PEG-150: 0.5 Ester 1 or 2: 0.5 Macadamia nut fatty acid phytosteryl: 1 Stearyl glycyrrhetinate: 0.1 Tocopheryl acetate: 0.1 Hydroxyproline: 0.05 Sodium acetyl hyaluronate: 0.01 Saccharomyces culture lysate: 0.1 Rubus idaeus extract: 0.01 PEG-8 diisostearate: 0.5 Sodium citrate: 0.1 EDTA-3Na: 0.1 Citric acid: 0.05 Sodium metaphosphate: 0.02, Myrtus officinalis leaf extract: 0.01, Tocopherol: 0.01, Phenoxyethanol: 0.6, Methylparaben: 0.15, Ethylparaben: 0.15, Fragrance: 0.15, Iron oxide: 0.001

[0047] Formulation Example 3: Water-in-oil cream Water: balance Glycerin: 10 BG: 6 Isododecane: 5 Isohexadecane: 5 Dimethicone: 5 Cetyl ethylhexanoate: 5 Hydrogenated polydecene: 4 Disteardimonium hectorite: 0.5 PEG-9 polydimethylsiloxyethyl dimethicone: 0.5 PEG-150: 0.5 Ester 1 or 2: 0.5 Macadamia nut fatty acid phytosteryl: 1 Stearyl glycyrrhetinate: 0.1 Tocopheryl acetate: 0.1 Hydroxyproline: 0.05 Sodium acetyl hyaluronate: 0.01 Saccharomyces culture lysate: 0.1 Rubus idaeus (Raspberry) extract: 0.01 PEG-8 diisostearate: 0.2 Sodium citrate: 0.1 EDTA-3Na: 0.1 Citric acid: 0.05 Sodium metaphosphate: 0.02, Myrtus officinalis leaf extract: 0.01, Tocopherol: 0.01, Phenoxyethanol: 0.6, Methylparaben: 0.15, Ethylparaben: 0.15, Fragrance: 0.15, Iron oxide: 0.001

[0048] Formulation Example 4: Oil-in-water gel containing oily capsules Water: balance Glycerin: 10 DPG: 10 Ethanol: 3 Diglycerin: 1 PEG-20: 1.5 Pentaerythrityl tetraethylhexanoate: 2 Dimethicone: 2 (Sodium acrylate / Sodium acryloyldimethyltaurate) copolymer: 1 Ester 1 or 2:1 Candelilla wax: 0.6 Saccharomyces culture lysate: 0.01 Aspartic acid: 0.01 Squalane: 0.5 Lysine HCl: 0.01 Macadamia nut fatty acid phytosteryl: 0.1 Sesame oil: 0.1 Jojoba seed oil: 0.1 Sodium acetyl hyaluronate: 0.01 Betaine: 0.01 Soybean seed extract: 0.01 Water-soluble collagen: 0.01 Isohexadecane: 1 PEG-400: 0.5 Polysorbate 80: 0.2, Sorbitan Oleate: 0.05, Talc: 0.5, EDTA-2Na: 0.1, (Acrylates / C10-30 Alkyl Acrylate Crosspolymer): 0.01, Dextrin Palmitate: 0.002, Calcium Stearate: 0.01, Potassium Hydroxide: 0.001, PEG-9 Polydimethylsiloxyethyl Dimethicone: 0.01, Tetrahydrotetramethylcyclotetrasiloxane: 0.01, Citric Acid: 0.001, Sodium Phosphate: 0.001, Tetradecene: 0.001, Butylene Glycol: 1, Tocopherol: 0.01, Phenoxyethanol: 0.35, Fragrance: 0.05, Iron Oxide: 0.01

[0049] Formulation Example 5: Lotion Water: balance Ethanol: 5 Glycerin: 5 DPG: 5 Ester 1 or 2:5 Diglycerin: 1 PEG / PPG-17 / 4 dimethyl ether: 2 Crystalline cellulose (*1): 2 Betaine: 4 Aspartic acid: 0.1 Lysine HCl: 0.01 Sodium acetyl hyaluronate: 0.1 Soybean seed extract: 0.01 Water-soluble collagen: 0.1 PPG-13 decyltetradeceth-24:1 Carbomer: 0.05 Potassium hydroxide: 0.05 EDTA-2Na: 0.02 BG: 1 Tocopherol: 0.01 Phenoxyethanol: 0.6 (*1 Leocrysta C-2SP (Dai-ichi Kogyo Seiyaku Co., Ltd.))

[0050] Formulation Example 6 Liposome-Containing Lotion Water: balance DPG: 5 Glycerin: 5 Diglycerin: 3 Propanediol: 4 Ester 1 or 2:2 BG: 2 Diphenylsiloxyphenyl trimethicone: 1 PEG-60 Hydrogenated Castor Oil: 1 PCA-Na: 0.5 Erythritol: 0.5 Dipotassium Glycyrrhizate: 0.1 Sodium Polyacrylate: 0.02 Hydrogenated Lecithin: 0.01 Magnesium Chloride: 0.01 Angelica acutiloba Root Extract: 0.01 Olive Leaf Extract: 0.01 Calcium Chloride: 0.01 Serine: 0.01 Sodium Acetylated Hyaluronate: 0.01 Oryzanol: 0.001 Hamamelis Virginiana (Witch Hazel) Leaf Extract: 0.01 Quince Extract: 0.01 Lum Puyan Extract: 0.01 Rosa Rosa Extract: 0.01 Polyquaternium-51: 0.01 Bupleurum Root Extract: 0.01 Isostearyl Alcohol: 1 Polyglyceryl-2 Diisostearate: 0.5 PEG-20: 1 Sodium Citrate: 0.1 Ethanol: 1 EDTA-2Na: 0.05 Citric Acid: 0.05 Phenoxyethanol: 0.3 Fragrance: 0.1

[0051] Formulation Example 7: Water-in-oil cream Water: balance, ethanol: 3, glycerin: 3, DPG: 5, cyclohexasiloxane: 5, cetyl ethylhexanoate: 5, hydrogenated polydecene: 2, phytosteryl / octyldodecyl lauroyl glutamate: 2, dimethicone: 2, PPG-3 dipivalate: 2, myristyl myristate: 1, methyl methacrylate crosspolymer: 1, dimethicone / vinyl dimethicone crosspolymer: 0.6, erythritol: 0.5, ester 1 or 2: 0.5, PEG / PPG-17 / 4 dimethyl ether: 0.5, tocopheryl acetate: 0.2, caffeine: 0.1, soapberry peel extract: 0.01, angelica tree leaf / stem extract: 0.01, tea leaf extract: 0.01, yuzu seed extract: 0.01, jujube fruit extract: 0.01 Ingredients: Spiny Eucalyptus / Hijirimen / Mitsuishi Kelp / Usba Aonori / Wakame Extract: 0.01 Turmeric Rhizome Extract: 0.01 Mitsuishi Kelp / Wakame Extract: 0.01 Chlorella Extract: 0.01 Hydrogenated Palm Oil: 1 Behenyl Alcohol: 0.5 Polysorbate 60: 0.5 PEG-30 Phytosterol: 0.5 (Ammonium Acryloyldimethyltaurate / VP) Copolymer: 0.6 Batyl Alcohol: 0.3 Butylene Glycol: 1 Carbomer: 0.04 (Acrylates / C10-30 Alkyl Acrylate Crosspolymer): 0.05 Potassium Hydroxide: 0.03 EDTA-2Na: 0.01 Sodium Metaphosphate: 0.02 Tocopherol: 0.01 Sodium Metabisulfite: 0.1 (HDI / trimethylol hexyl lactone) crosspolymer: 0.01, silica: 0.1, phenoxyethanol: 0.3, fragrance: 0.05, iron oxide: 0.01

[0052] Formulation Example 8 Oil-in-water emulsion Water: balance Dipotassium glycyrrhizinate: 0.1 DL-α-tocopherol acetate: 0.1 Seaweed extract: 0.01 Magnesium chloride: 0.01 Calcium chloride: 0.01 Lemon extract: 0.05 Glycerin: 5 Dipropylene glycol: 5 Ethanol: 4 1,3-butylene glycol: 3 Methylpolysiloxane: 3 Behenyl alcohol: 1.5 α-olefin oligomer: 1 Diisostearyl malate: 2 Pentaerythritol tetra-2-ethylhexanoate: 1 Ester 1 or 2:1 Stearyl alcohol: 0.5 Sodium N-stearoyl-N-methyl taurate: 0.3 Disodium edetate: 0.02 Xanthan gum: 0.1 Sodium citrate: 0.1 Distearyldimethylammonium chloride: 0.05 Citric acid: 0.02 L-arginine hydrochloride: 0.01 Isopropanol: 0.01 Angelica acutiloba extract: 0.01 dl-α-tocopherol 2-L-ascorbic acid phosphate diester potassium salt: 0.01 Acetylated sodium hyaluronate: 0.01 Scutellaria baicalensis extract: 0.01 Perilla frutescens extract: 0.01 Job's tears extract: 0.01 Phenoxyethanol: 0.5

[0053] Formulation Example 9: Oil-in-water cream Water: balance Cetyl ethylhexanoate: 7 Glycerin: 5 Ethanol: 1 Nylon-12: 5 Cetearyl alcohol: 5 DPG: 5 Caprylic / capric triglyceride: 5 Phytosteryl macadamiate: 3 Glyceryl stearate: 1.5 Dimethicone: 1 Diisostearyl malate: 1 Erythritol: 1 Ester 1 or 2:1 PEG / PPG-17 / 4 dimethyl ether: 1 Tocopheryl acetate: 0.2 Caffeine: 0.1 Xanthan gum: 0.02 Soapberry peel extract: 0.01 Angelica keiskei leaf / stem extract: 0.01 Tea leaf extract: 0.01 Yuzu seed extract: 0.01 Jujube fruit extract: 0.01 Ingredients: Spiny Eucalyptus / Hidirimen / Komatsuna / Usbaonori / Wakame Extract: 0.01 Turmeric Rhizome Extract: 0.01 Komatsuna / Wakame Extract: 0.01 Chlorella Extract: 0.01 Beheneth-20: 0.5 (HDI / Trimethylolhexyllactone) Crosspolymer: 0.1 Carbomer: 0.07 Butylene Glycol: 1 Sodium Citrate: 0.07 EDTA-3Na: 0.05 Potassium Hydroxide: 0.06 Citric Acid: 0.05 Sodium Metabisulfite: 0.01 Sodium Metaphosphate: 0.02 PPG-3 Dipivalate: 0.1 Tocopherol: 0.1 Silica: 0.1 Phenoxyethanol: 0.7 Fragrance: 0.1 Iron Oxide: 0.01

[0054] Formulation Example 10 Oil-in-water emulsion Water: balance Dipotassium glycyrrhizinate: 0.1 Glucosyl hesperidin: 0.01 Hawthorn extract: 0.01 Turmeric extract: 0.01 Soapberry extract: 0.001 Inositol: 0.01 Iris root extract: 0.01 Ginkgo extract: 0.01 Watercress extract: 0.01 Water-soluble collagen (F): 0.01 Glycerin: 6 1,3-butylene glycol: 6 α-olefin oligomer: 4 Ethanol: 3 Cetyl 2-ethylhexanoate: 3 Methylpolysiloxane: 3 Dipropylene glycol: 2 Polyoxyethylene glyceryl isostearate: 1.5 Polyethylene glycol 1000: 1 Polyoxyethylene glyceryl monostearate: 1 Behenyl alcohol: 0.5 Petrolatum: 0.5 Polyethylene glycol 20000: 0.5 Stearic acid: 0.4, Isostearic acid: 0.3, Behenic acid: 0.3, Batyl alcohol: 0.2, Carboxyvinyl polymer: 0.2, Potassium hydroxide: 0.2, Ester 1 or 2: 0.5, Succinoglucan: 0.04, Disodium edetate: 0.03, Lauroyl glutamate di (phytosteryl / octyldodecyl): 0.1, Sodium metabisulfite: 0.01, Phenoxyethanol: 0.6, Fragrance: 0.05

[0055] Formulation Example 11 Oil-in-water lotion Water: balance Ethanol: 4 DPG: 4 BG: 3.5 Glycerin: 3 Diglycerin: 1.5 Ester 1 or 2:1 Lactobacillus / rice fermentation product: 1 PEG-60 hydrogenated castor oil: 0.3 Diphenylsiloxyphenyl trimethicone: 0.3 Erythritol: 0.1 Glycyrrhizinate 2K: 0.1 Xanthan gum: 0.05 Sodium polyacrylate: 0.005 Yuzu fruit extract: 0.01 Sodium acetyl hyaluronate: 0.01 Hamamelis virginiana (witch hazel) leaf extract: 0.01 Carbomer: 0.15 Polyglyceryl-2 diisostearate: 0.12 Potassium hydroxide: 0.12 EDTA-2Na: 0.12 Isostearyl alcohol: 0.1 Isostearic acid: 0.1 Sodium citrate: 0.1g, Citric acid: 0.02g, Sodium pyrosulfite: 0.01g, Phenoxyethanol: 0.6g, Fragrance: 0.01g

[0056] Formulation Example 12: Lotion Water: balance, watercress extract: 0.01, inositol: 0.01, water-soluble collagen (F): 0.01, lysine hydrochloride: 0.01, dipropylene glycol: 5, glycerin: 5, ethanol: 3, maltitol: 1.5, 1,3-butylene glycol: 1, ester 1 or 2:3, polyoxyethylene polyoxypropylene decyl tetradecyl ether: 0.2, carboxyvinyl polymer: 0.1, erythritol: 1, disodium edetate: 0.02, magnesium L-ascorbyl phosphate: 0.1, sodium polyacrylate: 0.01, sodium metabisulfite: 0.01, rosemary oil: 0.01, yeast extract (3): 0.01, L-arginine hydrochloride: 0.01, phenoxyethanol: 0.5, fragrance: 0.02

[0057] Formulation Example 13: Water-in-oil cream Water: balance Hydrogenated polydecene: 12 Glycerin: 6 Mineral oil: 7 Petrolatum: 6 BG: 5 Paraffin: 4 Polyglyceryl-2 diisostearate: 2 Squalane: 3 Glyceryl oleate: 2 PCA-Na: 1.5 DPG: 1 Beeswax: 2 Carnosine: 1.2 Polyethylene: 0.5 Tocopheryl acetate: 0.2 Phytosteryl / octyldodecyl lauroyl glutamate: 0.1 Caffeine: 0.1 Ester 1 or 2: 0.5 Soapberry peel extract: 0.1 Acacia extract: 0.1 Angelica keiskei leaf / stem extract: 0.1 Sanguisorba officinalis extract: 0.1 Hawthorn flower extract: 0.1 Tea leaf extract: 0.1 Sodium acetyl hyaluronate: 0.01 Hydroxyproline: 0.1, Yuzu seed extract: 0.1, Jujube fruit extract: 0.1, Chlorella extract: 0.1, Toge Kirinsai / Hijirimen / Mitsuishi Kelp / Usba Aonori / Wakame extract: 0.1, Sodium lactate: 0.1, Turmeric rhizome extract: 0.1 Mitsuishi Kelp / Wakame extract: 0.1, Microcrystalline wax: 1, Sodium hydroxide: 0.5, Ethanol: 1, EDTA-3Na: 0.1, Tocopherol: 0.1, Sodium pyrosulfite: 0.1, PPG-3 dipivalate: 0.1, Cassia bark extract: 0.1, Carbomer: 0.01, BHT: 0.01, Polysorbate 20: 0.1, Palmitoyl tripeptide-1: 0.1, Palmitoyl tetrapeptide-7: 0.1, Methylparaben: 0.01 Ethylparaben: 0.01 Fragrance: 0.01 Iron oxide: 0.01

[0058] Formulation Example 14: Paste Facial Cleanser Ethanol: 5 Glycerin: 5 1,3-Butylene Glycol: 5 PEG-8: 10 Stearic Acid: 15 Lauric Acid: 5 Myristic Acid: 10 Glyceryl Stearate (SE): 5 Ester 1 or 2: 0.5 Sodium Cocoyl Methyl Taurate: 1 Polyquaternium-7: 15 Potassium Hydroxide: appropriate amount EDTA-2Na: appropriate amount Fragrance: appropriate amount Water: balance

[0059] Formulation Example 15 Pump Foamer Facial Cleanser Glycerin: 10 Dipropylene glycol: 10 Sorbitol: 10 Lauric acid: 5 Myristic acid: 1 Coconut fatty acid arginine: 2 Methyl taurate Na: 3 Lauryl betaine: 5 Polyquaternium-7: 0.5 Ester 1 or 2: 0.5 Antioxidant: appropriate amount Chelating agent: appropriate amount Fragrance: appropriate amount Water: balance

[0060] Formulation Example 16 Liquid Facial Cleanser Glycerin: 25 Dipropylene glycol: 10 Lauric acid: 5 Myristic acid: 1 Palmitic acid: 1 Coconut fatty acid arginine: 10 Methyl taurate Na: 10 Lauryl betaine: 5 Xanthan gum: 0.5 Ester 1 or 2: 0.5 Antioxidant: appropriate amount Chelating agent: appropriate amount Fragrance: appropriate amount Water: balance

[0061] Formulation Example 17: Paste cleanser Glycerin: 40 PEG-400: 0.5 Ethylene glycol distearate: 1.5 Sodium lauryl glycol acetate: 1 Sodium cocoyl glycinate: 20 Arginine coconut fatty acid: 5 Cocamidopropyl betaine: 5 Ester 1 or 2: 0.5 Potassium hydroxide: appropriate amount Polyethylene: 1 Coloring material: appropriate amount EDTA-2Na: appropriate amount Water: remainder Fragrance: appropriate amount

[0062] Formulation Example 18: Facial cleanser PEG-10 dimethicone: 0.5 Glycerin: 10 PEG-8 dioleate: 5 PEG-2 laurate: 1 Sodium lauryl glycol acetate: 5 Sodium laureth sulfate: 10 Sodium cocoyl methyl taurate: 1 Cocamidopropyl betaine: 10 Ester 1 or 2: 0.5 pH adjuster: appropriate amount Stabilizer: appropriate amount Preservative: appropriate amount Fragrance: appropriate amount Water: balance

[0063] Formulation Example 19: Pump-former skin cleanser Glycerin: 10 1,3-butylene glycol: 10 PPG-9 diglyceryl / PPG-9: 5 ester 1 or 2: 0.5 Triethylhexanoin: 1 PEG-60 hydrogenated castor oil: 1 PEG-60 glyceryl isostearate: 1 Potassium cocoyl glutamate: 10 Sodium cocoamphoacetate: 5 pH adjuster: appropriate amount Preservative: appropriate amount Water: balance

[0064] Formulation Example 20 Makeup Remover Ethanol: 5 Decamethylcyclopentasiloxane: 5 1,3-Butylene glycol: 10 Glyceryl 2-ethylhexanoate: 5 POE (8) Glyceryl monoisostearate: 25 POE (20) Glyceryl monoisostearate: 5 Ester 1 or 2: 0.5 Dipotassium glycyrrhizinate: 0.05 Citric acid: appropriate amount Sodium citrate: appropriate amount Phenoxyethanol: appropriate amount Purified water: balance

[0065] Formulation Example 21 Makeup Remover Purified water: 5 Glycerin: 10 Sorbitol: 10 Sucrose stearate: 2 Sodium methyl cocoyl taurate: 1 PEG-60 hydrogenated castor oil: 1 PEG / PPG-35 / 40 dimethyl ether: 2 Ester 1 or 2: 0.5 Mineral oil: balance Cetyl ethylhexanoate: 10 Dimethicone: 5 Diphenylsiloxyphenyl trimethicone: 5 Sodium alginate: appropriate amount Sodium citrate: appropriate amount Citric acid: appropriate amount EDTA-2Na: appropriate amount

[0066] Formulation Example 22 Makeup Remover Purified water: balance, PEG-400: 5, butylene glycol: 10, mineral oil: 20, dimethicone: 5, triethylhexanoin: 5, stearyl alcohol: 0.5, behenyl alcohol: 0.5, ester 1 or 2: 0.5, PEG-60 glyceryl isostearate: 1, potassium hydroxide: appropriate amount, phenoxyethanol: appropriate amount, EDTA-2Na: appropriate amount, (acrylates / alkyl acrylate (C10-30)) crosspolymer: 0.05, carbomer: 0.5, fragrance: appropriate amount

[0067] Formulation Example 23 Cleansing Lotion Ethanol: 10 Glycerin: 1 Dipropylene glycol: 5 PEG-8: 5 PEG / PPG-35 / 40 dimethyl ether: 1 Ester 1 or 2: 0.5 PPG-13 decyltetradeceth-24: 1 pH adjuster: appropriate amount Fragrance: appropriate amount Chelating agent: appropriate amount Water: balance

[0068] Formulation Example 24 Two-layer makeup remover (oil layer) Isododecane: 10 Dimethicone: 25 Decyltetradecylamine oxide: 1.5 Ethylhexylglycerin: 1 (water layer) Ethanol: 10 1,3-butylene glycol: 10 Ester 1 or 2: 0.5 Lauryl betaine Sodium chloride: appropriate amount Preservative: appropriate amount pH adjuster: appropriate amount Chelating agent: appropriate amount Water: balance

[0069] Formulation Example 25 Deodorant PEG-11 methyl ether dimethicone: 0.5, alcohol: 60, butylene glycol: 0.5, ester 1 or 2: 0.5, PPG-20 decyltetradeceth-10: 0.5, chlorohydroxy aluminum: 10, sodium metaphosphate: 0.01, tocopherol: appropriate amount, fragrance: appropriate amount, menthol: appropriate amount, benzalkonium chloride: 0.05, hydroxypropyl methylcellulose: 0.1, polyvinylpyrrolidone: 0.05, purified water: balance

[0070] Formulation Example 26 Deodorant Spray LPG: 75 (undiluted solution) Ethanol: balance Ester 1 or 2: 0.5 Zinc oxide: 0.5 PEG-10 dimethicone: 0.05 Diphenylsiloxyphenyl trimethicone: 5 Ethylhexyl palmitate: 0.5 Calcium stearate: appropriate amount Silica: 1 Sulfate (Al / K): 1 Tricalcium phosphate, silver mixture: 0.05 Glycerin: 0.5 Menthol: appropriate amount Menthoxypropanediol: appropriate amount Cymen-5-ol: 0.01 Fragrance: appropriate amount

[0071] Formulation Example 27: Deodorant Sheet A nonwoven fabric is impregnated with the following stock solution: (Stock solution) Alcohol: 40, Ester 1 or 2: 0.5, PPG-20 decyltetradeceth-10: 0.05, Talc: 3, Zinc phenolsulfonate: 2, Lactic acid: appropriate amount, Sodium lactate: appropriate amount, Menthol: appropriate amount, Benzalkonium chloride: 0.05, Purified water: balance, Fragrance: appropriate amount

[0072] Formulation Example 28 Hair Treatment Water: balance, Alcohol: 15, Glycerin: 5, PG: 5, Ester 1 or 2: 0.5, Dimethicone: 12, Aminopropyl Dimethicone: 0.6, (Acrylates / C10-30 Alkyl Acrylate) Crosspolymer: 0.1, PEG-10 Dimethicone: 0.1, Carbomer: 0.35, Xanthan Gum: 0.1, Hydroxyethyl Urea: 0.2, AMP: appropriate amount, EDTA-2Na: appropriate amount, Fragrance: appropriate amount

[0073] Formulation Example 29 Hair Wax Water: balance PG: 5 Maltitol: 5 Carbomer: 0.1 (PEG-240 / decyltetradeceth-20 / HDI) copolymer: 0.5 Ceteth-25: 3 Glyceryl stearate (SE): 0.5 Hydrogenated polyisobutene: 5 Microcrystalline wax: 5 Paraffin: 0.5 Stearic acid: 3 Cetyl alcohol: 3 Ester 1 or 2: 0.5 Candelilla wax: 10 Carnauba wax: 1 Cetyl ethylhexanoate: 3 Pentaerythrityl tetraethylhexanoate: 0.5 (Methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer: 2 (VP / VA) copolymer: 0.5 TEA: appropriate amount Phenoxyethanol: appropriate amount EDTA-2Na: appropriate amount Tocopherol: appropriate amount Fragrance: appropriate amount

[0074] Formulation Example 30 Oil-in-water sunscreen cosmetic Purified water: balance Glycerin: 2.5 DPG: 5 Ester 1 or 2: 0.5 PEG-60 glyceryl isostearate: 0.3 PEG-10 dimethicone: 0.3 TEA: 0.3 Behenyl alcohol: 1 Batyl alcohol: 1.5 Behenic acid: 0.6 Pentaerythritol tetra-2-ethylhexanoate: 2 Polypropylene glycol (17): 1 Cyclopentasiloxane: 4 Dimethicone (6 cst): 1 Ethylhexyl methoxycinnamate: 7.5 Bis-ethylhexyloxyphenol methoxyphenyl triazine: 2 Xanthan gum: 0.2 Phenoxyethanol: 0.35 Chlorphenesin: 0.2 Thiotaurine: 0.1 Aminoethanesulfinic acid: 0.1 Rosa multiflora fruit extract: 0.1 Rosa centifolia flower extract: 0.1 Titanium oxide: 0.05 Mica: 0.05 Chelating agent: appropriate amount pH adjuster: appropriate amount

[0075] Formulation Example 31 Oil-in-water sunscreen cosmetic Purified water: balance Glycerin: 4 BG (butylene glycol): 7 PEG / PPG-9 / 2 dimethyl ether: 5 Compound 1 or Compound 2: 0.5 Polyethylene glycol 300: 1 Succinoglycan: 0.3 (Dimethylacrylamide / Sodium acryloyldimethyltaurate) crosspolymer: 0.3 Sucrose fatty acid ester: 3 PEG-60 hydrogenated castor oil: 2 Diisopropyl sebacate: 2 Non-volatile dimethicone: 2 Cyclomethicone: 12 Triethylhexanoin: 5 Isostearic acid: 1 Sorbitan sesquiisostearate: 0.5 Hydrophobized zinc oxide fine particles: 10 Ethylhexyl methoxycinnamate: 10 Diethylamino hydroxybenzoyl hexyl benzoate: 1 Bis-ethylhexyloxyphenol methoxyphenyl triazine: 1 Spherical urethane resin powder: 3 Chlorphenesin: 0.2g pH adjuster: appropriate amount Chelating agent: appropriate amount

[0076] Formulation Example 32 Oil-in-water sunscreen cosmetic Purified water: balance Diisopropyl sebacate: 8 Bisethylhexyloxyphenol methoxyphenyl triazine: 1 Methyl bis(trimethylsiloxy)silylisopentyl trimethoxycinnamate: 1 Hydrophobized zinc oxide: 5 Succinoglycan: 1 (Dimethylacrylamide / Sodium acryloyldimethyltaurate) crosspolymer: 0.3 Stearoxyhydroxypropylmethylcellulose: 0.2 Chlorphenesin: 0.2 BG (butylene glycol): 4 Ethanol: 4 Ester 1 or 2: 0.5

[0077] Formulation Example 33 Water-in-oil sunscreen cosmetic Purified water: balance, ethanol: 3, ester 1 or 2: 0.5, cellulose gum: 0.1, glycerin: 2, isododecane: 5, isopropyl myrstate: 5, diisopropyl sebacate: 10, PBG / PPG-9 / 1 copolymer: 1, dimethicone (1.5 cs): 10, dimethicone (6 cs): 5, trimethylsiloxysilicate: 1, dextrin palmitate: 1, ethylhexyl methoxycinnamate: 5, diethylamino hydroxybenzoyl hexyl benzoate: 1, bis-ethylhexyloxyphenol methoxyphenyl triazine: 1, ethylhexyl salicylate: 3, hydrophobized titanium dioxide microparticles: 5, hydrophobized zinc oxide microparticles: 10, PEG-9 polydimethylpolysiloxyethyl dimethicone: 1, cetyl PEG / PPG-10 / 1 dimethicone: 1 Dimethyl distearyl ammonium hectorite: 0.2g, chlorphenesin: 0.1g, isostearic acid: 0.1g, chelating agent: appropriate amount, thiotaurine: 0.1g, aminoethanesulfinic acid: 0.1g, Rosa multiflora fruit extract: 0.1g, Rosa centifolia flower extract: 0.1g, titanium dioxide: 0.05g, mica: 0.05g

[0078] Formulation Example 34 Oil-in-water sunscreen cosmetic Purified water: balance Ethanol: 10 EDTA-2Na.H2O: appropriate amount Carbomer: 0.2 (Acrylates / C10-30 alkyl acrylate) crosspolymer: 0.1 Xanthan gum: 0.1 Agar: 0.1 Glycerin: 3 Butylene glycol: 5 Ester 1 or 2:1 Core-corona type microgel emulsifier (Acrylates / Methoxy PEG-90 methacrylate) crosspolymer (Production Example 9 of WO2013 / 094298): 1.5 Lauryl dimethylaminoacetic acid betaine 35% by mass aqueous solution: 0.1 Ethylhexyl methoxycinnamate: 7 Ethylhexyl triazine: 1 Diethylamino hydroxybenzoyl hexyl benzoate: 1 Bis-ethylhexyloxyphenol methoxyphenyl triazine: 1 Distearyldimethylammonium chloride-treated silica-treated titanium dioxide: 4 Dimethicone: 5 Caprylyl methicone: 2 Diisopropyl sebacate: 5 Alkyl benzoate (C12-15): 3 Dextrin (palmitate / ethylhexanoate): 1 Alumina-treated titanium dioxide: 1 Fragrance: appropriate amount Potassium hydroxide: 0.15 Phenoxyethanol: 0.5 Silica: 1

[0079] Formulation Example 35 Oil-in-water sunscreen cosmetic Purified water: balance, Ethanol: 8, EDTA-2Na: appropriate amount, Sodium hexametaphosphate: appropriate amount, Citric acid: appropriate amount, Sodium citrate: appropriate amount, Cherry leaf extract: 1, V-E acetate: 1, Witch hazel: 1, Green tea extract: 1, (Dimethylacrylamide / Sodium acryloyldimethyltaurate) copolymer: 0.3, Succinoglucan: 0.1, Stearoxyhydroxypropylmethylcellulose: 0.1, Glycerin: 3, Butylene glycol: 5, Ester 1 or 2:1, Polyoxyethylene hydrogenated castor oil (60 mol): 1.5, Ethylhexyl methoxycinnamate: 5, Ethylhexyl triazine: 2, Diethylamino hydroxybenzoyl hexyl benzoate: 2, Bis-ethylhexyloxyphenol methoxyphenyl triazine: 1, Dimethicone: 6, Isododecane: 3 Dextrin (palmitic acid / ethylhexanoic acid): 1, Hydrophobized silica-coated zinc oxide fine particles: 15, Alumina-treated titanium dioxide: 1, Isostearic acid: 0.3, Sorbitan sesquiisostearate: 0.3, Fragrance: appropriate amount, Silica: 1

[0080] Formulation Example 36 Water-in-oil sunscreen cosmetic Purified water: balance Ethanol: 8 EDTA.3Na: appropriate amount Salt: appropriate amount Sodium metabisulfite: appropriate amount Glycerin: 2 Ester 1 or 2: 0.5 Isododecane: 3 Glyceryl tri-2-ethylhexanoate: 5 Isopropyl myrstate: 5 Diisopropyl sebacate: 5 Dimethicone: 6 Trisiloxysilicate: 1 Dextrin palmitate: 0.5 Homosalate: 5 Diethylaminohydroxybenzoylhexyl benzoate: 0.5 Bisethylhexyloxyphenol methoxyphenyl triazine: 1 t-Butyl methoxydibenzoylmethane: 2 Ethylhexyl salicylate: 5 Hydrophobized titanium dioxide microparticles: 3 Hydrophobized zinc oxide microparticles: 7 Methyl methacrylate crosspolymer: 3 Silica: 2 Hydrophobized silica: 5 PEG-9 polydimethylpolysiloxyethyl dimethicone: 1, Lauryl PEG-9 polydimethylpolysiloxyethyl dimethicone: 2, Dimethyl distearyl ammonium hectorite: 0.5, Isostearic acid: 0.5, Sorbitan sesquiisostearate: 0.5, Tocopherol: appropriate amount, Fragrance: appropriate amount

[0081] Formulation Example 37 Lipstick Polyethylene: 7 Microcrystalline wax: 1 Candelilla wax: 1 Petrolatum: 5 Macadamia nut oil: 21.92 Glyceryl triisostearate: 12 Diisostearyl malate: 10 Phytosteryl / octyldodecyl lauroyl glutamate: 10 Hydrogenated polyisobutene: 18.5 Diphenylsiloxyphenyl trimethicone: 5 Shea butter: 0.1 Ethylhexyl methoxycinnamate: 7.5 Pentaerythrityl tetraethylhexanoate: 0.2 Ester 1 or 2: 0.5 Colorant: 0.05 Dibromfluorescein (Sun Chemical): 0.1 Tetrabromfluorescein (Constam): 0.1 Tetrachlorotetrabromfluorescein: 0.1 Tocopheryl acetate: 0.05 Dimethicone / vinyl dimethicone crosspolymer: 0.01 Royal jelly extract: 0.05 Mica titanium: 0.03 Silica anhydride: 0.01 Titanium oxide: 0.01 Tocopherol: 0.05 Simethicone: 0.02

[0082] Formulation Example 38 Lipstick Polyethylene: 7 Microcrystalline wax: 1 Candelilla wax: 1 Petrolatum: 5 Macadamia nut oil: 21.72 Glyceryl triisostearate: 11 Diisostearyl malate: 9 Phytosteryl / octyldodecyl lauroyl glutamate: 9 Hydrogenated polyisobutene: 17.3 Diphenylsiloxyphenyl trimethicone: 4.5 Shea butter: 0.1 Ethylhexyl methoxycinnamate: 7.5 Pentaerythrityl tetraethylhexanoate: 0.2 Ester 1 or 2: 0.5 Colorant: 0.05 Dibromfluorescein (Sun Chemical): 0.1 Tetrabromfluorescein (Constam): 0.1 Tetrachlorotetrabromfluorescein: 0.1 Tocopheryl acetate: 0.05 Dimethicone / vinyl dimethicone crosspolymer: 0.01 Royal jelly extract: 0.05 Mica titanium: 0.03 Silica anhydride: 0.01 Titanium oxide: 0.01 Tocopherol: 0.05 Simethicone: 0.02

[0083] Formulation Example 39 Lipstick Polyethylene: 7 Microcrystalline wax: 1 Candelilla wax: 1 Petrolatum: 5 Macadamia nut oil: 17.39 Glyceryl triisostearate: 9.3 Diisostearyl malate: 7.8 Phytosteryl / octyldodecyl lauroyl glutamate: 7.8 Hydrogenated polyisobutene: 14.4 Diphenylsiloxyphenyl trimethicone: 4 Shea butter: 0.1 Ethylhexyl methoxycinnamate: 7.5 Pentaerythrityl tetraethylhexanoate: 5 Ester 1 or 2: 0.5 Colorant: 12 Dibromfluorescein (Sun Chemical): 0.1 Tetrabromfluorescein (Constam): 0.1 Tetrachlorotetrabromfluorescein: 0.1 Tocopheryl acetate: 0.05 Dimethicone / vinyl dimethicone crosspolymer: 0.01 Royal jelly extract: 0.05 Mica titanium: 0.01 Silica anhydride: 0.01 Titanium oxide: 0.01 Tocopherol: 0.05 Simethicone: 0.02

[0084] Formulation Example 40 Lipstick Polyethylene: 7 Microcrystalline wax: 1 Candelilla wax: 1 Petrolatum: 5 Macadamia nut oil: 16.29 Glyceryl triisostearate: 8.5 Diisostearyl malate: 7.1 Phytosteryl / octyldodecyl lauroyl glutamate: 7.1 Hydrogenated polyisobutene: 13.2 Diphenylsiloxyphenyl trimethicone: 3.6 Shea butter: 0.1 Ethylhexyl methoxycinnamate: 7.5 Pentaerythrityl tetraethylhexanoate: 5 Ester 1 or 2: 0.5 Colorant: 12 Dibromfluorescein (Sun Chemical): 0.1 Tetrabromfluorescein (Constam): 0.1 Tetrachlorotetrabromfluorescein: 0.1 Tocopheryl acetate: 0.05 Dimethicone / vinyl dimethicone crosspolymer: 0.01 Royal jelly extract: 0.05 Mica titanium: 0.01 Silica anhydride: 0.01 Titanium oxide: 0.01 Tocopherol: 0.05 Simethicone: 0.02

[0085] Formulation Example 41: Cosmetic base: Water: balance, Ethanol: 5, Glycerin: 3, Butylene Glycol: 5, Ester 1 or 2: 0.5, Succinoglycan: 0.3, Cellulose gum: 0.3, Dimethylacrylamide / Sodium acryloyldimethyltaurate crosspolymer: 0.3, Polyglyceryl-10 stearate: 3, Sorbitan sesquiisostearate: 1, Polyglyceryl-6 polyricinoleate: 0.5, C9-12 alkane / Coco-(caprylic / capric acid): 10, Isopropyl myristate: 8, Caprylic / capric triglyceride: 8, Zinc oxide / Dextrin palmitate: 15, Titanium oxide / Aluminum hydroxide / Stearic acid: 5, Silica: 1, Phenoxyethanol: appropriate amount, Citric acid: appropriate amount, Sodium citrate: appropriate amount, EDTA-2Na: appropriate amount

[0086] Formulation Example 42: Cosmetic base PEG-10 dimethicone: 3.5, Lauryl PEG-9 polydimethylsiloxyethyl dimethicone: 2, PEG-10 hydrogenated castor oil: 2, Ethylhexyl salicylate: 10, Isohexadecane: 10, Hydrogenated didecene: 20, Disteardimonium hectorite: 2, Fatty acid-treated titanium oxide: 4.5, Silica: 5, Silicone-treated titanium oxide: 4.5, Silicone-treated red iron oxide: 0.35, Silicone-treated yellow iron oxide: 0.75, Silicone-treated black iron oxide: 0.015, Water: balance, EDTA-3Na: 0.2, Glycerin: 2.5, DPG: 7, BG: 2, Ester 1 or 2: 0.5, Ethanol: 1, Phenoxyethanol: appropriate amount

[0087] Formulation Example 43 Mask spray Sugarcane extract: 1 Hydroxypropyl cyclodextrin: 2 Citric acid (food): appropriate amount Sodium citrate: appropriate amount Salt: 0.5 Sodium pyrosulfite: appropriate amount Ethanol: 54 1,3-butylene glycol: 3 Ester 1 or 2: 0.5 Phenoxyethanol: 0.5 Glycerin: 1 Orange oil: 0.2

[0088] Formulation Example 44 Cushion Foundation Cyclopentasiloxane: 27, Pentaerythrityl tetraethylhexanoate: 4, PEG-10 dimethicone: 3, PEG-9 polydimethylsiloxyethyl dimethicone: 1.5, Bis-butyldimethicone polyglyceryl-3:1, Disteardimonium hectorite: 0.5, Octyl methoxycinnamate: 6.5, Hydrophobized fine particle titanium dioxide: 11, Hydrophobized titanium dioxide: 7, Hydrophobized iron oxide red: 0.4, Hydrophobized iron oxide yellow: 0.8, Hydrophobized iron oxide black: 0.01, Spherical powder: 3, Water: balance, Glycerin: 10, Ester 1 or 2: 0.5, Paraben: appropriate amount, Phenoxyethanol: appropriate amount

[0089] Formulation Example 45 Water Balm Agar: 0.1 Tamarind gum: 1.2 Paraffin wax: 1 (Dimethylacrylamide / Sodium acryloyldimethyltaurate) crosspolymer: 0.4 Polyethylene glycol monostearate (40EO): 0.5 Polysorbate 60: 0.5 Sorbitan tristearate: 0.1 Stearyl alcohol: 0.1 Behenyl alcohol: 1.5 Glycerin: 15 Pearlizing agent: 10 Citric acid: Appropriate amount Sodium citrate: Appropriate amount Preservative: Appropriate amount Sodium metabisulfite: Appropriate amount Propanediol: 3 Butylene glycol: 3 Ester 1 or 2: 0.5 Spherical porous silica (average particle size: about 5 μm): 1 Nonporous silica (average particle size: about 7 μm): 1.5 PEG 60 hydrogenated castor oil: 0.1 Ethylhexyl methoxycinnamate: 4 Sorbitan sesquiisostearate: 1 Isostearic acid: 1 Glyceryl stearate: 1 BHT: 0.05 Isohexadecane: 2.5 Water: balance

[0090] Formulation Example 46 Eye Shadow Talc: balance Synthetic phlogopite: 10 Zinc oxide: 1 Barium sulfate: 1 Magnesium myristate: 1 Chlorphenesin: appropriate amount (vinyl dimethicone / methicone silsesquioxane) crosspolymer: 4 Boron nitride: 8 Jojoba ester: 3 Red 226 / mica: 1 Synthetic phlogopite / titanium oxide / tin oxide: 20 Petrolatum / tocopherol: 2 Diisostearyl malate: 6 Triethylhexanoin: 2 Ester 1 or 2: 0.5

[0091] Formulation Example 47 Oil-in-water foundation Water: balance Ethanol: 5 Glycerin: 2.5 1,3-butylene glycol: 7 Ester 1 or 2: 0.5 Stearoxyhydroxypropylmethylcellulose: 0.05 Succinoglycan: 0.15 (Dimethylacrylamide / Acryloyldimethyltaurate Na) Crosspolymer: 0.25 PEG-100 Hydrogenated Castor Oil: 0.2 PEG-60 Hydrogenated Castor Oil: 1.5 PPG-17: 1 Dimethicone: 2 Triethylhexanoin: 3 Dimethicone: 17 Isostearic acid: 0.8 Sorbitan sesquiisostearate: 0.2 Distearyldimonium chloride: 0.15 Zinc oxide: 14 Ethylhexyl methoxycinnamate: 7 Ethylhexyl triazone: 0.5 Diethylaminohydroxybenzoylhexyl benzoate: 0.5 Bisethylhexyloxyphenol methoxyphenyl triazine: 2g Titanium oxide: 0.5g Sodium metaphosphate: appropriate amount Phenoxyethanol: appropriate amount

[0092] Formulation Example 48 Make-up Cosmetic (Solid Water-in-Oil Emulsion) Decamethylcyclopentasiloxane: 16 Dimethylpolysiloxane (6 cps): 10 Polyoxyalkylene-modified organopolysiloxane: 5 Paraffin wax (165°F): 10 BisPEG-18 methyl ether dimethylsilane: 0.5 Silicone-treated talc: 16 Silicone-treated spherical silica powder: 5 Calcium stearate-treated zinc oxide: 3 Silicone-treated titanium dioxide: 10 Silicone-treated iron oxide (yellow): 3 Silicone-treated iron oxide (red): 1 Silicone-treated iron oxide (black): 0.1 Ion-exchanged water: balance Glycerin: 5 Ester 1 or 2: 0.5 Preservative: appropriate amount Fragrance: appropriate amount

[0093] Formulation Example 49 Oil-based liquid foundation Dimethylpolysiloxane: 10 Decamethylcyclopentasiloxane: balance Isohexadecane: 10 Polyether-modified silicone: 2 Isostearic acid: 0.5 Polyoxyethylene (10) isostearyl ether (HLB 12.4): 0.5 Organically modified bentonite: 0.1 Polymethyl methacrylate spherical powder: 5 Hydrophobized yellow iron oxide: 3 Hydrophobized red iron oxide: 1.5 Hydrophobized black iron oxide: 0.3 Hydrophobized titanium dioxide: 12 Ester 1 or 2: 0.5

[0094] Formulation Example 50 Facial Cosmetic (Aqueous Composition) Water: Balance (PEG-240 / Decyltetradeceth-20 / HDI) Copolymer: 0.9 (Ammonium Acryloyldimethyltaurate / VP) Copolymer: 0.3 Phenoxyethanol: 0.5 DPG: 8 BG: 5 Glycerin: 2 Ester 1 or 2: 0.5 Synthetic phlogopite, distearyldimonium chloride: 15 Iron oxide, triethoxycaprylylsilane: 0.4 Iron oxide, triethoxycaprylylsilane: 0.8 Iron oxide, triethoxycaprylylsilane: 0.01

[0095] The ester of the present invention has good solubility in water and oil, is not sticky, and is useful as a base for cosmetics.

[0096] This application is based on Japanese Patent Application No. 2023-121077, the contents of which are incorporated in their entirety herein.

Claims

1. An ester synthesized from component A, which is at least one selected from dihydric alcohols having 2 to 8 carbon atoms; component B, which is at least one selected from divalent carboxylic acids having 2 to 10 carbon atoms; and component C, which is at least one selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and two or more carboxy groups.

2. A cosmetic base comprising the ester according to claim 1.

3. A cosmetic comprising the cosmetic base according to claim 2.

Images