Silane compound

Abstract

The present invention provides a compound represented by formula (1), wherein RS is a monovalent group containing one or more Si atoms which respectively do not directly bind to a hydroxyl group or a hydrolyzable group; X1 is a 2-10 valent group containing two or more ether bonds; RSi is a monovalent group containing a Si atom bound to a hydroxyl group or a hydrolyzable group; and α is an integer of 1-9.

Description

Silane Compounds

[0001] The present disclosure relates to silane compounds.

[0002] It is known that certain silane compounds can provide excellent water and oil repellency when used in the surface treatment of a substrate (Patent Document 1).

[0003] Japanese Patent Application Laid-Open No. 2019-44179

[0004] An object of the present disclosure is to provide a silane compound capable of forming a surface treatment layer having higher weather resistance.

[0005] The present disclosure includes the following aspects: [1] A compound represented by the following formula (1): [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ is a divalent to decavalent group containing two or more ether bonds, R Ｓｉ is a monovalent group containing a Si atom to which a hydroxyl group or a hydrolyzable group is bonded, and α is an integer of 1 to 9. Ｓ is R １ -R Ｓ１ -(SiR ２ ２ ) ｓ - and R １ is a hydrocarbon group, or R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ -: R １ａ are each independently R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ -, and R １ｃ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently a hydrocarbon group or R １ａ’ and R １ａ’ is R １ａEach ma is independently an integer of 1 to 5, provided that R １ａ Medium, R １ａ’ The number of is 20 or less, and R １ｂ are each independently a hydrocarbon group, na is an integer of 1 to 3, z is 0 or 1, and R Ｓ１ are each independently a single bond or a group represented by the following formula: (In the formula: R ３ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - and R ４ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R７ -R ９ -R ６ -R ９ - and R ６ are each independently C １－６ is an alkylene group, R ７ are each independently an optionally substituted arylene group, R ８ are each independently a single bond or C １－６ is an alkylene group, R ９ are each independently a single bond or an oxygen atom, ５ are each independently a hydrocarbon group, x is an integer of 0 to 200, y is an integer of 0 to 200, z is an integer of 0 to 200, x + y + z is 1 or more, and the order of occurrence of the respective repeating units enclosed in parentheses with x, y, or z is arbitrary in the formula. ２ are each independently a hydrocarbon group, and s is 0 or 1. [3] The compound according to the above [1]. １ is R １ａ ｎａ R １ｂ ３－ｎａ Si—O—, and R １ａ are each independently -(R １ｃ -SiR １ｄ ２ ) ｍａ -R １ｄ R is a group represented by １ｃ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently a hydrocarbon group or R １ａ’ and R １ａ’ is R １ａ Each ma is independently an integer of 1 to 5, provided that R １ａ Medium, R １ａ’ The number of is 20 or less, and R １ｂ are each independently a hydrocarbon group, na is an integer of 1 to 3, and is a group represented by the formula: [4] R１ａ are each independently -(OSiR １ｄ ２ ) ｍａ -R １ｄ R is a group represented by １ｄ are each independently a hydrocarbon group or R １ａ’ Each ma is independently 1 or 2; １ｂ are each independently a hydrocarbon group, and na is an integer of 1 to 3. [5] The compound according to [2] or [3] above. １ｄ is C １－４ The compound according to any one of the above items [2] to [4], wherein X is an alkyl group. １ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ The compound according to any one of the above [1] to [5], which contains a group represented by the formula: - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1). [7] X １ is -(O) ｚ１ - [CH ２ CH ２ O] ｎｃ The compound according to any one of the above items [1] to [6], which contains a group represented by - (wherein nc is an integer of 1 to 30, and z1 is 0 or 1). [8] X １ can further include alkylene, phenylene, —CO—, —COO—, —NR ｘ１ --, --CONR ｘ１ --, --OCONR ｘ１ -, -NR ｘ１ -CO-NR ｘ１ -, -O-, -S-, -O-(CH ２ ) ｘ１ -CONR ｘ１ -, or -O-(CH ２ ) ｘ１ is a divalent organic group containing —CO—, ｘ１ is a hydrogen atom or C １－６ The compound according to any one of the above items [1] to [7], wherein X is an alkyl group, and x1 is an integer of 1 to 20. [9] X １is represented by the following formula: -X １１ -X １２ -X １３ - [In the formula: X １１ is a single bond or a divalent group, １２ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1), １３ is a single bond or a divalent group.].

[10] The compound according to any one of the above [1] to [8], wherein R is a group represented by the formula: Ｓｉ is represented by the following formula (S1), (S2), (S3), (S4), or (S5): [In the formula: R １１ are each independently a hydroxyl group or a hydrolyzable group, R １２ are each independently a monovalent organic group, and n1 is (SiR １１ ｎ１ R １２ ３－ｎ１ ) units are each independently an integer of 0 to 3, １１ are each independently a single bond or a divalent organic group, １３ are each independently a hydrogen atom or a monovalent organic group, each t is independently an integer of 2 or more, R １４ are each independently a hydrogen atom, a halogen atom or -X １１ -SiR １１ ｎ１ R １２ ３－ｎ１ and R １５ are each independently a single bond, an oxygen atom, an alkylene group having 1 to 6 carbon atoms, or an alkyleneoxy group having 1 to 6 carbon atoms; R ａ１ are each independently -Z １ -SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ and Z １are each independently a divalent organic group, ２１ are each independently -Z １’ -SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ and R ２２ are each independently a hydroxyl group or a hydrolyzable group, R ２３ are each independently a monovalent organic group, p1 is each independently an integer of 0 to 3, q1 is each independently an integer of 0 to 3, r1 is each independently an integer of 0 to 3, the sum of p1, q1 and r1 is 3, and Z １’ are each independently a divalent organic group, ２１’ are each independently -Z １” -SiR ２２” ｑ１” R ２３” ｒ１” and R ２２’ are each independently a hydroxyl group or a hydrolyzable group, R ２３’ are each independently a monovalent organic group, p1' is each independently an integer of 0 to 3, q1' is each independently an integer of 0 to 3, r1' is each independently an integer of 0 to 3, the sum of p1', q1' and r1' is 3, and Z １” are each independently a divalent organic group, ２２” are each independently a hydroxyl group or a hydrolyzable group, R ２３” are each independently a monovalent organic group, q1" is each independently an integer of 0 to 3, r1" is each independently an integer of 0 to 3, the sum of q1" and r1" is 3, and R ｂ１ are each independently a hydroxyl group or a hydrolyzable group, R ｃ１are each independently a monovalent organic group, k1 is each independently an integer of 0 to 3, l1 is each independently an integer of 0 to 3, m1 is each independently an integer of 0 to 3, the sum of k1, l1 and m1 is 3, provided that in formula (S3), there are at least two Si atoms bonded to a hydroxyl group or a hydrolyzable group, and R ｄ１ are each independently -Z ２ -CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ and Z ２ are each independently a single bond, an oxygen atom, or a divalent organic group, and R ３１ are each independently -Z ２’ -CR ３２’ ｑ２’ R ３３’ ｒ２’ and R ３２ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ３３ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group; p2 is each independently an integer of 0 to 3; q2 is each independently an integer of 0 to 3; r2 is each independently an integer of 0 to 3; the sum of p2, q2, and r2 is 3; Z ２’ are each independently a single bond, an oxygen atom, or a divalent organic group, and R ３２’ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ３３’ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group; q2' are each independently an integer of 0 to 3; r2' are each independently an integer of 0 to 3; the sum of q2' and r2' is 3; Z ３are each independently a single bond, an oxygen atom, or a divalent organic group; R ３４ are each independently a hydroxyl group or a hydrolyzable group, R ３５ are each independently a monovalent organic group, n2 is each independently an integer of 0 to 3, R ｅ１ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ｆ１ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group, k2 is each independently an integer of 0 to 3, l2 is each independently an integer of 0 to 3, and m2 is each independently an integer of 0 to 3. The sum of k2, l2, and m2 is 3, provided that in formula (S4), there are at least two Si atoms bonded to a hydroxyl group or a hydrolyzable group, and R ｇ１ and R ｈ１ are each independently -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ , -Z ４ -SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ , or -Z ４ -CR ｄ１ ｋ２ R ｅ１ ｌ２ R ｆ１ ｍ２ and Z ４ are each independently a single bond, an oxygen atom, or a divalent organic group, with the proviso that in formula (S5), there are at least two Si atoms bonded to hydroxyl groups or hydrolyzable groups. Ｓ is represented by the following formula: １ -[Si(CH ３ ) ２ -O] ｘ -Si(CH ３ ) ２- [wherein, R １ is an alkyl group having 1 to 6 carbon atoms or R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ - and R １ａ is (CH ３ ) ３ SiO—, R １ｂ is an alkyl group having 1 to 4 carbon atoms, na is 2 or 3, and x is an integer of 5 to 50. １ is represented by the following formula: -X １１ -X １２ -X １３ - [In the formula: X １１ is C １－６ is an alkylene group or a phenylene group, １２ is -O-[(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 2 to 4, nc is an integer of 1 to 5, and z1 is 0 or 1), and X １３ is C １－１２ is an alkylene group.], and R Ｓｉ is represented by the following formula: １１ ３ [In the formula, R １１ is -OR ｈ and R ｈ is an alkyl group having 1 to 4 carbon atoms.] and α is 1.

[12] The compound according to any one of the above [1] to

[11] , which is the following compound: CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (Wherein TMSO is (CH ３ ) ３ SiO—, and n is 3 to 100.

[13] The compound according to any one of the above [1] to

[11] , which is the following compound: CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２ OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (Wherein TMSO is (CH ３ ) ３SiO—, and n is 10 to 30.)

[14] A surface treatment agent comprising the compound according to any one of [1] to

[13] above.

[15] The surface treatment agent according to

[11] above, further comprising a condensate of the compound according to any one of [1] to

[13] above.

[16] The surface treatment agent according to

[14] or

[15] above, which is for vacuum deposition.

[17] The surface treatment agent according to

[14] or

[15] above, which is for wet coating.

[18] A pellet containing the surface treatment agent according to any one of

[14] to

[17] above.

[19] An article comprising a substrate and, on the substrate, a layer formed from the compound according to any one of [1] to

[13] above.

[20] The article according to

[19] above, which comprises an intermediate layer containing silicon oxide between the substrate and the layer.

[21] The article according to

[19] or

[20] above, in which the intermediate layer contains an alkali metal atom.

[22] The article according to the above

[21] , wherein at least a part of the alkali metal atoms is a sodium atom.

[23] The article according to any one of the above

[19] to

[22] , which is an optical element.

[24] The article according to any one of the above

[19] to

[23] , which is a display.

[25] A compound represented by the formula: R Ｓ -X １ａ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ａ is a divalent group containing two or more ether bonds.]

[26] A compound represented by the formula: R Ｓ -X １ａ -CONR ５１ - (CH ２ ) ｘ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ａ is a divalent group containing two or more ether bonds, and R ５１ represents a hydrogen atom or a monovalent hydrocarbon group, and x represents an integer of 0 to 30.

[0006] According to the present disclosure, it is possible to provide a silane compound capable of forming a surface treatment layer having higher weather resistance.

[0007] As used herein, the term "monovalent organic group" refers to a monovalent group containing carbon. The monovalent organic group is not particularly limited, but may be a hydrocarbon group or a derivative thereof. A hydrocarbon group derivative refers to a group having one or more N, O, S, Si, amide, sulfonyl, siloxane, carbonyl, carbonyloxy, etc. at the end or in the molecular chain of the hydrocarbon group. Note that when simply referring to an "organic group," it refers to a monovalent organic group. Furthermore, the term "divalent organic group" refers to a divalent group containing carbon. Examples of such divalent organic groups include divalent groups in which one more hydrogen atom has been eliminated from an organic group. Similarly, a trivalent or higher organic group refers to a group in which a predetermined number of hydrogen atoms have been eliminated from an organic group.

[0008] As used herein, the term "hydrocarbon group" refers to a group containing carbon and hydrogen, which is obtained by removing a hydrogen atom from a hydrocarbon. Such hydrocarbon groups include, but are not limited to, C １－２０ Examples of hydrocarbon groups include aliphatic hydrocarbon groups and aromatic hydrocarbon groups. The "aliphatic hydrocarbon group" may be linear, branched, or cyclic, and may be saturated or unsaturated. The hydrocarbon group may contain one or more ring structures. The hydrocarbon group may be substituted with one or more substituents.

[0009] As used herein, the substituent of the "hydrocarbon group" is not particularly limited, but examples thereof include a halogen atom, a C １－６ Alkyl group, C ２－６ Alkenyl group, C ２－６ Alkynyl group, C ３－１０ Cycloalkyl group, C ３－１０ Unsaturated cycloalkyl groups, 5- to 10-membered heterocyclyl groups, 5- to 10-membered unsaturated heterocyclyl groups, C ６－１０Examples include one or more groups selected from aryl groups and 5- to 10-membered heteroaryl groups.

[0010] As used herein, the term "hydrolyzable group" refers to a group that can undergo a hydrolysis reaction, i.e., a group that can be removed from the main skeleton of a compound by a hydrolysis reaction. Examples of hydrolyzable groups include -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ or —NCO (wherein R ｈ represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms), and preferably —OR ｈ (i.e., an alkoxy group). ｈ Examples of the alkyl group include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, with methyl and ethyl groups being more preferred.

[0011] The silane compound of the present disclosure is represented by the following formula (1): [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ is a divalent to decavalent group containing two or more ether bonds, R Ｓｉ is a monovalent group containing a Si atom to which a hydroxyl group or a hydrolyzable group is bonded, and α is an integer of 1 to 9.

[0012] The compounds of the present disclosure are １ Since the compound contains two or more ether bonds, the surface treatment layer obtained from the compound of the present disclosure can be imparted with excellent ultraviolet (UV) resistance.

[0013] R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded.

[0014] In one embodiment, RＳ is R １ -R Ｓ１ -(SiR ２ ２ ) ｓ - is a group represented by the formula:

[0015] R １ is a hydrocarbon group, or R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ - is.

[0016] In one embodiment, R １ is a hydrocarbon group. １ The hydrocarbon group in the formula (I) may preferably be an alkyl group or an aryl group.

[0017] The alkyl group may be linear or branched. The alkyl group is preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms. The alkyl group is particularly preferably a methyl group, an ethyl group, an n-propyl group, an isopropyl group, or a tert-butyl group.

[0018] The aryl group may be monocyclic or polycyclic. The aryl is preferably an aryl group having 6 to 20 carbon atoms, more preferably an aryl group having 6 to 10 carbon atoms. The aryl group is particularly preferably a phenyl group.

[0019] R １ The hydrocarbon group in is preferably an alkyl group, more preferably an alkyl group having 1 to 4 carbon atoms.

[0020] In one embodiment, R １ is R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ - is.

[0021] R １ａ are each independently R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ - is a group represented by the formula:

[0022] R １ｃ are each independently an oxygen atom or C １－６ It is an alkylene group.

[0023] R １ｃ C in １－６ The alkylene group may be a straight chain or a branched chain. １－６ The alkylene group is preferably C １－４ Alkylene group, more preferably C ２－４ It may be an alkylene group.

[0024] In one embodiment, R １ｃ is O.

[0025] In one embodiment, some R １ｃ is O, and other R １ｃ is C １－６ It is an alkylene group.

[0026] R １ｄ are each independently a hydrocarbon group or R １ａ’ is.

[0027] In one embodiment, R １ｄ is a hydrocarbon group.

[0028] R １ｄ The hydrocarbon group in the formula (I) may preferably be an alkyl group or an aryl group.

[0029] The alkyl group may be linear or branched. The alkyl group is preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms. The alkyl group is particularly preferably a methyl group, an ethyl group, an n-propyl group, an isopropyl group, or a tert-butyl group.

[0030] The aryl group may be monocyclic or polycyclic. The aryl is preferably an aryl group having 6 to 20 carbon atoms, more preferably an aryl group having 6 to 10 carbon atoms. The aryl group is particularly preferably a phenyl group.

[0031] R １ｄThe hydrocarbon group in the formula (I) is preferably an alkyl group, more preferably an alkyl group having 1 to 4 carbon atoms.

[0032] In one embodiment, R １ｄ is R １ａ’ is.

[0033] R １ａ’ is R １ａ That is, R １ａ’ is R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ -. However, R １ａ Medium, R １ａ’ The number is 20 or less, preferably 10 or less, more preferably 6 or less, and further preferably 3 or less.

[0034] In one embodiment, R １ｄ is R １ｄ’ -(SiR １ｄ’ ２ -R １ｃ’ ) ｍａ’ - [In the formula: R １ｄ’ are each independently a hydrocarbon group or R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ - and at least one R １ｄ’ is R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ - and R １ｃ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently an integer of 1 to 5, or a hydrocarbon group; １ｃ’ are each independently an oxygen atom or C １－６ is an alkylene group, and each m a ' is independently an integer of 1 to 5.

[0035] In another embodiment, in one embodiment, R １ｄ is R １ｄ’-(SiR １ｄ’ ２ -R １ｃ’ ) ｍａ’ - [In the formula: R １ｃ’ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ’ are each independently a hydrocarbon group or R １ｄ” -(SiR １ｄ” ２ -R １ｃ” ) ｍａ” - and at least one R １ｄ’ is R １ｄ” -(SiR １ｄ” ２ -R １ｃ” ) ｍａ” - and R １ｄ” are each independently a hydrocarbon group or R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ - and at least one R １ｄ” is -(R １ｃ -SiR １ｄ ２ ) ｍａ -R １ｄ and R １ｃ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently an integer of 1 to 5, or a hydrocarbon group; １ｃ” are each independently an oxygen atom or C １－６ an alkylene group; each m a ″ is independently an integer of 1 to 5; and each m a ′ is independently an integer of 1 to 5.

[0036] Each ma is independently an integer of 1 to 5, preferably 1 or 2.

[0037] R １ｂ are each independently a hydrocarbon group.

[0038] R １ｂThe hydrocarbon group in the formula (I) may preferably be an alkyl group or an aryl group.

[0039] The alkyl group may be linear or branched. The alkyl group is preferably an alkyl group having 1 to 6 carbon atoms, more preferably an alkyl group having 1 to 4 carbon atoms. The alkyl group is particularly preferably a methyl group, an ethyl group, an n-propyl group, an isopropyl group, or a tert-butyl group.

[0040] The aryl group may be monocyclic or polycyclic. The aryl is preferably an aryl group having 6 to 20 carbon atoms, more preferably an aryl group having 6 to 10 carbon atoms. The aryl group is particularly preferably a phenyl group.

[0041] R １ｂ is preferably an alkyl group, more preferably an alkyl group having 1 to 4 carbon atoms.

[0042] n a is 1 to 3. In one embodiment, n a is 2. In another embodiment, n a is 3. １ａ’ When there is a １ｄ ２ -R １ｃ ) ｍａ are selected independently.

[0043] z is 0 or 1. In one embodiment, z is 0. In another embodiment, z is 1.

[0044] R １ａ There are two or more, preferably three or more, more preferably four or more, and even more preferably six or more, for example, eight or more, nine or more, ten or more, or twelve or more Si—O bonds.

[0045] In a preferred embodiment, R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ -In R １ａ are each independently R １ｄ -(Si １ｄ ２ -R １ｃ ) ｍａ-, and R １ｃ are each independently an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently a hydrocarbon group (preferably an alkyl group having 1 to 4 carbon atoms), or R １ａ’ is preferably a hydrocarbon group (preferably an alkyl group having 1 to 4 carbon atoms), and R １ａ’ is R １ａ ma is 1 or 2; R １ｂ are each independently a hydrocarbon group, preferably an alkyl group having 1 to 4 carbon atoms; na is 1 to 3; and z is 0 or 1, preferably 0.

[0046] R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ Examples of groups represented by - include, but are not limited to, the following groups:

[0047]

[0048]

[0049] In one embodiment, R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ The group represented by - is the following group.

[0050] In one embodiment, R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ The group represented by - is the following group.

[0051] R Ｓ１ are each independently a single bond or the following formula: (In the formula: R ３ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - and R ４ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - and R ６ are each independently C １－６ is an alkylene group, R ７ are each independently an optionally substituted arylene group, R ８ are each independently a single bond or C １－６ is an alkylene group, R ９ are each independently a single bond or an oxygen atom, ５are each independently a hydrocarbon group, x is an integer of 0 to 200, y is an integer of 0 to 200, z is an integer of 0 to 200, x + y + z is 1 or more, and the order of occurrence of the respective repeating units enclosed in parentheses with x, y, or z is arbitrary in the formula. ２ are each independently a hydrocarbon group, and s is 0 or 1.

[0052] In one embodiment, R Ｓ１ is a single bond.

[0053] In another embodiment, R Ｓ１ teeth, It is a group represented by the formula:

[0054] R ３ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ -, preferably C １－１２ Alkylene group, or -R ６ -O-R ６ - is.

[0055] R ４ are each independently C １－１２ alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - is.

[0056] In one embodiment, R ４ are each independently C １－１２ Alkylene group, or -R ６ -O-R ６ - is.

[0057] In another embodiment, R ４ are each independently -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - is.

[0058] In one embodiment, R ３ are each independently C １－１２ Alkylene group, or -R ６ -O-R ６ - and R ４ are each independently C １－１２Alkylene group, or -R ６ -O-R ６ - is.

[0059] In another embodiment, R ３ are each independently C １－１２ Alkylene group, or -R ６ -O-R ６ - and R ４ are each independently -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - is.

[0060] Above C １－１２ The alkylene group may be a straight chain or a branched chain. １－１２ The alkylene group is preferably straight-chain.

[0061] Above C １－１２ The alkylene group is preferably C ２－８ Alkylene group, more preferably C ２－６ It is an alkylene group.

[0062] R ６ are each independently C １－６ The above C is an alkylene group. １－６ The alkylene group may be a straight chain or a branched chain. １－６ The alkylene group is preferably straight-chain.

[0063] Above C １－６ The alkylene group is preferably C ２－４ Alkylene group, more preferably C ２－３It is an alkylene group.

[0064] In a preferred embodiment, multiple R ６ In a group containing ６ are the same group.

[0065] R ７ are each independently an optionally substituted arylene group.

[0066] In one embodiment, R ７ are each independently is.

[0067] In one embodiment, R ７ is a phenylene group.

[0068] In another embodiment, R ７ is a naphthylene group.

[0069] The arylene group may have a substituent. The number of the substituents is not particularly limited and is, for example, 1 to 4, preferably 1 or 2.

[0070] In one embodiment, the phenylene group and naphthylene group may have a substituent. The number of substituents is not particularly limited and is, for example, 1 to 4, preferably 1 or 2. The substituted phenylene group is preferably a 2,5-substituted phenylene.

[0071] The substituents on the arylene group are each independently —R ４１ -R ４２ is.

[0072] R ４１ represents a single bond, an oxygen atom, or a sulfur atom, preferably a single bond or an oxygen atom, more preferably an oxygen atom.

[0073] R ４２ is C optionally substituted by halogen １－１２ alkyl group, -(O-R ４３ ) ｐ , -R ４４ -R ４５ , -R ４４ -OR ４６ is.

[0074] The halogen is fluorine, chlorine, bromine or iodine, preferably fluorine.

[0075] R ４２ C in １－１２ The alkyl group may be straight or branched.

[0076] R ４３ is C １－６ Alkylene group, preferably C ２－４ It is an alkylene group. Such an alkylene group may be a straight chain or a branched chain.

[0077] R ４４ is C １－１２ Alkylene group, preferably C １－６ It is an alkylene group. Such an alkylene group may be a straight chain or a branched chain.

[0078] R ４５ is -CH=CH ２ or -OCOCH=CH ２ is.

[0079] R ４６ is a hydrogen atom or C １－６ The alkyl group may be a straight chain or a branched chain. １－６ The alkyl group is preferably C １－３ alkyl group, more preferably C １－２ It is preferably an alkyl group, more preferably a methyl group.

[0080] R ８ are each independently a single bond or C １－６ It is an alkylene group. １－６ The alkylene group may be straight-chain or branched.

[0081] In one embodiment, R ８ is a single bond.

[0082] In another embodiment, R ８ is C １－６ It is an alkylene group.

[0083] R ９ are each independently a single bond or an oxygen atom.

[0084] In one embodiment, R ９ is a single bond.

[0085] In another embodiment, R ９ is an oxygen atom.

[0086] R ５ are each independently a hydrocarbon group. Such hydrocarbon groups may be substituted.

[0087] R ５ are each independently preferably an unsubstituted hydrocarbon group or a hydrocarbon group substituted with a halogen atom. Such a halogen atom is preferably a fluorine atom.

[0088] R ５ are each independently preferably C optionally substituted by a halogen atom. １－１８ an alkyl group or an aryl group, more preferably C １－１８ It is an alkyl group or an aryl group.

[0089] Above C １－１８ The alkyl group may be straight-chain or branched, but is preferably straight-chain. １－１８ The alkyl group is preferably C １－１０ alkyl group, more preferably C １－６ alkyl group, more preferably C １－４ It is preferably an alkyl group, and even more preferably a methyl group.

[0090] The aryl group is preferably a phenyl group.

[0091] In one embodiment, R ５ are each independently C １－６ Alkyl group, preferably C １－４ It is preferably an alkyl group, more preferably a methyl group.

[0092] In another embodiment, R ５ is a phenyl group.

[0093] In another embodiment, R ５ are each independently a methyl group or a phenyl group, preferably a methyl group.

[0094] x is an integer of 0 to 200, preferably an integer of 0 to 100, more preferably an integer of 1 to 100, even more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0095] In one embodiment, x is 0.

[0096] In one embodiment, x is an integer of 1 to 200, preferably an integer of 1 to 100, more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0097] y is an integer of 0 to 200, preferably an integer of 0 to 100, more preferably an integer of 1 to 100, even more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0098] In one embodiment, y is 0.

[0099] In one embodiment, y is an integer of 1 to 200, preferably an integer of 1 to 100, more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0100] z is an integer of 0 to 200, preferably an integer of 0 to 100, more preferably an integer of 1 to 100, even more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0101] In one embodiment, z is 0.

[0102] In one embodiment, z is an integer of 1 to 200, preferably an integer of 1 to 100, more preferably an integer of 5 to 50, and even more preferably an integer of 10 to 30.

[0103] In one embodiment, y is 0 and z is 0.

[0104] R Ｓ１ may be a random polymer or a block polymer.

[0105] X １ is a divalent to decavalent group containing two or more ether bonds.

[0106] X １The number of ether bonds in the formula (I) may be preferably 2 to 50, more preferably 2 to 40, even more preferably 2 to 30, still more preferably 2 to 20, and particularly preferably 2 to 9, for example, 2 to 6, or 2 to 5.

[0107] In one embodiment, X １ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ -(wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1).

[0108] nb is preferably an integer of 1 to 6, more preferably an integer of 2 to 4, and even more preferably 2 or 3.

[0109] n c is preferably an integer of 1 to 25, for example, an integer of 3 to 25, an integer of 3 to 20, an integer of 3 to 10, an integer of 4 to 25, an integer of 5 to 20, an integer of 4 to 15, an integer of 5 to 15, an integer of 3 to 6, an integer of 1 to 10, an integer of 1 to 5, an integer of 1 to 4, or an integer of 1 to 3.

[0110] In one embodiment, z1 is 0. In another embodiment, z1 is 1.

[0111] In a preferred embodiment, X １ is -(O) ｚ１ - [CH ２ CH ２ O] ｎｃ - (wherein nc is an integer of 1 to 30, and z1 is 0 or 1).

[0112] In a preferred embodiment, X １ represents two or more ether bonds and an alkylene, phenylene, —CO—, —COO—, —NR ｘ１ --, --CONR ｘ１ --, --OCONR ｘ１ -, -NR ｘ１ -CO-NR ｘ１ -, -O-, -S-, -O-(CH ２ ) ｘ１ -CONR ｘ１ -, and -O-(CH ２ ) ｘ１R is a group containing at least one group selected from —CO—, and is preferably a divalent group. ｘ１ is a hydrogen atom or C １－６ It is an alkyl group, and x1 is an integer of 1 to 20.

[0113] X １ is preferably represented by the following formula: １１ -X １２ -X １３ - [In the formula: X １１ is a single bond or a divalent group, １２ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1), １３ is a single bond or a divalent group.

[0114] X １１ is a single bond or a divalent group.

[0115] In one embodiment, X １１ is a single bond.

[0116] In one embodiment, X １１ is a divalent group.

[0117] X １１ The divalent group in the formula (I) is an alkylene, a phenylene, —CO—, —COO—, or —NR ｘ１ --, --CONR ｘ１ --, --OCONR ｘ１ -, -NR ｘ１ -CO-NR ｘ１ -, -O-, -S-, -O-(CH ２ ) ｘ１ -CONR ｘ１ -, and -O-(CH ２ ) ｘ１ R may be a group containing at least one group selected from —CO—. ｘ１ is a hydrogen atom or C １－６It is an alkyl group, and x1 is an integer of 1 to 20. The alkylene preferably has 1 to 30 carbon atoms, more preferably 1 to 20 carbon atoms, for example, 1 to 10, 1 to 6, 2 to 30, 5 to 25, 10 to 25, or 12 to 20 carbon atoms.

[0118] X １１ is preferably C １－６ Alkylene group, -(CH ２ ) ｆ１ -O-(CH ２ ) ｆ２ - (wherein f1 is an integer of 0 to 6, for example, an integer of 1 to 6, and f2 is an integer of 0 to 6, for example, an integer of 1 to 6), or -(CH ２ ) ｆ３ -phenylene-(CH ２ ) ｆ４ - (wherein f3 is an integer of 0 to 6, for example, an integer of 1 to 6, and f4 is an integer of 0 to 6, for example, an integer of 1 to 6). １－６ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0119] X １１ is more preferably C １－６ In one embodiment, X is an alkylene group or a phenylene group. １１ is C １－６ In another embodiment, X is an alkylene group. １１ is a phenylene group.

[0120] X １３ is a single bond or a divalent group.

[0121] In one embodiment, X １３ is a single bond.

[0122] In one embodiment, X １３ is a divalent group.

[0123] X １３The divalent group in the formula (I) is an alkylene, a phenylene, —CO—, —COO—, or —NR ｘ１ --, --CONR ｘ１ --, --OCONR ｘ１ -, -NR ｘ１ -CO-NR ｘ１ -, -O-, -S-, -O-(CH ２ ) ｘ１ -CONR ｘ１ -, and -O-(CH ２ ) ｘ１ R may be a group containing at least one group selected from —CO—. ｘ１ is a hydrogen atom or C １－６ It is an alkyl group, and x1 is an integer of 1 to 20. The alkylene preferably has 1 to 30 carbon atoms, more preferably 6 to 26 carbon atoms, for example, 8 to 24, 10 to 22, 12 to 20, 1 to 20, 1 to 10, or 1 to 6 carbon atoms.

[0124] X １３ is preferably C １－３０ Alkylene groups (e.g., C １－１２ an alkylene group, or C １－６ alkylene group), -(CH ２ ) ｆ５ -O-(CH ２ ) ｆ６ - (wherein f5 is an integer of 0 to 30, for example, an integer of 1 to 30, and f6 is an integer of 0 to 30, for example, an integer of 1 to 30), or -(CH ２ ) ｆ７ -phenylene-(CH ２ ) ｆ８ - (wherein f7 is an integer of 0 to 30, for example, an integer of 1 to 30, and f8 is an integer of 0 to 30, for example, an integer of 1 to 30). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0125] X １is preferably represented by the following formula: １１ -X １２ -X １３ - [In the formula: X １１ is C １－６ is an alkylene group or a phenylene group, １２ is -O-[(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 2 to 4, nc is an integer of 1 to 5, and z1 is 0 or 1), and X １３ is C １－１２ It is an alkylene group.]

[0126] R Ｓｉ is a monovalent group containing a Si atom to which a hydroxyl group or a hydrolyzable group is bonded.

[0127] In a preferred embodiment, R Ｓｉ is represented by the following formula (S1), (S2), (S3), (S4) or (S5): [In the formula: R １１ are each independently a hydroxyl group or a hydrolyzable group, R １２ are each independently a monovalent organic group, and n1 is (SiR １１ ｎ１ R １２ ３－ｎ１ ) units are each independently an integer of 0 to 3, １１ are each independently a single bond or a divalent organic group, １３ are each independently a hydrogen atom or a monovalent organic group, each t is independently an integer of 2 or more, R １４ are each independently a hydrogen atom, a halogen atom or -X １１ -SiR １１ ｎ１ R １２ ３－ｎ１ and R １５ are each independently a single bond, an oxygen atom, an alkylene group having 1 to 6 carbon atoms, or an alkyleneoxy group having 1 to 6 carbon atoms; R ａ１ are each independently -Z １ -SiR ２１ｐ１ R ２２ ｑ１ R ２３ ｒ１ and Z １ are each independently a divalent organic group, ２１ are each independently -Z １’ -SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ and R ２２ are each independently a hydroxyl group or a hydrolyzable group, R ２３ are each independently a monovalent organic group, p1 is each independently an integer of 0 to 3, q1 is each independently an integer of 0 to 3, r1 is each independently an integer of 0 to 3, the sum of p1, q1 and r1 is 3, and Z １’ are each independently a divalent organic group, ２１’ are each independently -Z １” -SiR ２２” ｑ１” R ２３” ｒ１” and R ２２’ are each independently a hydroxyl group or a hydrolyzable group, R ２３’ are each independently a monovalent organic group, p1' is each independently an integer of 0 to 3, q1' is each independently an integer of 0 to 3, r1' is each independently an integer of 0 to 3, the sum of p1', q1' and r1' is 3, and Z １” are each independently a divalent organic group, ２２” are each independently a hydroxyl group or a hydrolyzable group, R ２３” are each independently a monovalent organic group, q1" is each independently an integer of 0 to 3, r1" is each independently an integer of 0 to 3, the sum of q1" and r1" is 3, and R ｂ１ are each independently a hydroxyl group or a hydrolyzable group, R ｃ１are each independently a monovalent organic group, k1 is each independently an integer of 0 to 3, l1 is each independently an integer of 0 to 3, m1 is each independently an integer of 0 to 3, the sum of k1, l1 and m1 is 3, provided that in formula (S3), there are at least two Si atoms bonded to a hydroxyl group or a hydrolyzable group, and R ｄ１ are each independently -Z ２ -CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ and Z ２ are each independently a single bond, an oxygen atom, or a divalent organic group, and R ３１ are each independently -Z ２’ -CR ３２’ ｑ２’ R ３３’ ｒ２’ and R ３２ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ３３ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group; p2 is each independently an integer of 0 to 3; q2 is each independently an integer of 0 to 3; r2 is each independently an integer of 0 to 3; the sum of p2, q2, and r2 is 3; Z ２’ are each independently a single bond, an oxygen atom, or a divalent organic group, and R ３２’ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ３３’ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group; q2' are each independently an integer of 0 to 3; r2' are each independently an integer of 0 to 3; the sum of q2' and r2' is 3; Z ３are each independently a single bond, an oxygen atom, or a divalent organic group; R ３４ are each independently a hydroxyl group or a hydrolyzable group, R ３５ are each independently a monovalent organic group, n2 is each independently an integer of 0 to 3, R ｅ１ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and R ｆ１ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group, k2 is each independently an integer of 0 to 3, l2 is each independently an integer of 0 to 3, and m2 is each independently an integer of 0 to 3. The sum of k2, l2, and m2 is 3, provided that in formula (S4), there are at least two Si atoms bonded to a hydroxyl group or a hydrolyzable group, and R ｇ１ and R ｈ１ are each independently -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ , -Z ４ -SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ , or -Z ４ -CR ｄ１ ｋ２ R ｅ１ ｌ２ R ｆ１ ｍ２ and Z ４ are each independently a single bond, an oxygen atom, or a divalent organic group, with the proviso that in formula (S5), there are at least two Si atoms bonded to hydroxyl groups or hydrolyzable groups.

[0128] In the above formula, R １１ are each independently a hydroxyl group or a hydrolyzable group.

[0129] R １１ are preferably each independently a hydrolyzable group.

[0130] R １１ are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ , —NCO, or halogen (wherein R ｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈ Examples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈ is a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0131] In the above formula, R １２ are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0132] R １２ In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0133] In the above formula, n1 is (SiR １１ ｎ１ R １２ ３－ｎ１ ) units are each independently an integer of 0 to 3. However, in formula (S1), n1 is 1 to 3 (SiR １１ ｎ１ R １２ ３－ｎ１ In other words, in formula (S1), there are at least two Si atoms to which a hydroxyl group or a hydrolyzable group is bonded.

[0134] n1 is (SiR １１ ｎ１ R １２ ３－ｎ１ ) units are each independently an integer of preferably 1 to 3, more preferably 2 to 3, and even more preferably 3.

[0135] In the above formula, X １１ are each independently a single bond or a divalent organic group. Such a divalent organic group is preferably -R ２８ -O ｘ -R ２９ - (wherein, R ２８ and R ２９ are each independently a single bond or C １－２０ is an alkylene group, and x is 0 or 1. １－２０ The alkylene group may be a straight chain or a branched chain, but is preferably a straight chain. １－２０ The alkylene group is preferably C １－１０ Alkylene group, more preferably C １－６ Alkylene group, more preferably C １－３ It is an alkylene group.

[0136] In one embodiment, X １１ are each independently -C １－６ Alkylene -O-C １－６ Alkylene- or -O-C １－６ It is alkylene-.

[0137] In a preferred embodiment, X １１ are each independently a single bond or a linear C １－６ an alkylene group, preferably a single bond or a straight-chain C １－３ Alkylene group, more preferably a single bond or a straight chain C １－２ It is preferably a linear C alkylene group. １－２ It is an alkylene group.

[0138] In the above formula, R １３ are each independently a hydrogen atom or a monovalent organic group. Such a monovalent organic group is preferably C １－２０ It is an alkyl group.

[0139] In a preferred embodiment, R１３ are each independently a hydrogen atom or a straight-chain C １－６ is an alkyl group, preferably a hydrogen atom or a straight-chain C １－３ It is an alkyl group, preferably a hydrogen atom or a methyl group.

[0140] In the above formula, R １５ are each independently a single bond, an oxygen atom, an alkylene group having 1 to 6 carbon atoms, or an alkyleneoxy group having 1 to 6 carbon atoms.

[0141] In one embodiment, R １５ are each independently an oxygen atom, an alkylene group having 1 to 6 carbon atoms, or an alkyleneoxy group having 1 to 6 carbon atoms.

[0142] In a preferred embodiment, R １５ is a single bond.

[0143] In the above formula, each t is independently an integer of 2 or more.

[0144] In a preferred embodiment, each t is independently an integer of 2 to 10, preferably an integer of 2 to 6.

[0145] In the above formula, R １４ are each independently a hydrogen atom, a halogen atom or -X １１ -SiR １１ ｎ１ R １２ ３－ｎ１ Such a halogen atom is preferably an iodine atom, a chlorine atom or a fluorine atom, more preferably a fluorine atom. In a preferred embodiment, R １４ is a hydrogen atom.

[0146] In one embodiment, formula (S1) is the following formula (S1-a): [In the formula, R １１ , R １２ , R １３ , X １１and n1 are defined as in formula (S1) above, t1 and t2 are each independently an integer of 1 or more, preferably an integer of 1 to 10, more preferably an integer of 2 to 10, for example, an integer of 1 to 5 or an integer of 2 to 5, and the order of the repeating units enclosed in parentheses with t1 and t2 is arbitrary in the formula.]

[0147] In a preferred embodiment, formula (S1) is the following formula (S1-b): [In the formula, R １１ , R １２ , R １３ , X １１ , n1 and t are defined as in formula (S1) above.

[0148] R ａ１ are each independently -Z １ -SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ is.

[0149] Z １ are each independently an oxygen atom or a divalent organic group. １ The structure written as ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ )

[0150] In a preferred embodiment, Z １ is a divalent organic group.

[0151] In a preferred embodiment, Z １ Is Z １ Preferably, in formula (S3), (Si-Z １ —Si) does not contain a siloxane bond.

[0152] Z １ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ１ -O-(CH ２ )ｚ２ - (wherein z1 is an integer of 0 to 6, for example, an integer of 1 to 6, and z2 is an integer of 0 to 6, for example, an integer of 1 to 6), or -(CH ２ ) ｚ３ -phenylene-(CH ２ ) ｚ４ - (wherein z3 is an integer of 0 to 6, for example, an integer of 1 to 6, and z4 is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0153] In a preferred embodiment, Z １ is C １－３０ Alkylene group or -(CH ２ ) ｚ３ -phenylene-(CH ２ ) ｚ４ -, preferably -phenylene-(CH ２ ) ｚ４ - is.

[0154] In another preferred embodiment, Z １ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. １ is -CH ２ CH ２ CH ２ In another embodiment, Z １ is -CH ２ CH ２ In yet another embodiment, Z １ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２CH ２ CH ２ -It can be.

[0155] R ２１ are each independently -Z １’ -SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ is.

[0156] Z １’ are each independently an oxygen atom or a divalent organic group. １’ The structure written as ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ )

[0157] In a preferred embodiment, Z １’ is a divalent organic group.

[0158] In a preferred embodiment, Z １’ Is Z １’ Preferably, in formula (S3), (Si-Z １’ —Si) does not contain a siloxane bond.

[0159] Z １’ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ１’ -O-(CH ２ ) ｚ２’ - (wherein z1' is an integer of 0 to 6, for example, an integer of 1 to 6, and z2' is an integer of 0 to 6, for example, an integer of 1 to 6), or -(CH ２ ) ｚ３’ -phenylene-(CH ２ ) ｚ４’ - (wherein z3' is an integer of 0 to 6, for example, an integer of 1 to 6, and z4' is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C１－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0160] In a preferred embodiment, Z １’ is C １－３０ Alkylene group or -(CH ２ ) ｚ３’ -phenylene-(CH ２ ) ｚ４’ -, preferably -phenylene-(CH ２ ) ｚ４’ - is.

[0161] In another preferred embodiment, Z １’ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. １’ is -CH ２ CH ２ CH ２ In another embodiment, Z １’ is -CH ２ CH ２ In yet another embodiment, Z １’ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0162] The above R ２１’ are each independently -Z １” -SiR ２２” ｑ１” R ２３” ｒ１” is.

[0163] Above Z １” are each independently an oxygen atom or a divalent organic group. １”The structure written as ２２” ｑ１” R ２３” ｒ１” )

[0164] In a preferred embodiment, Z １” is a divalent organic group.

[0165] In a preferred embodiment, Z １” Is Z １” Preferably, in formula (S3), (Si-Z １” —Si) does not contain a siloxane bond.

[0166] Z １” is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ１” -O-(CH ２ ) ｚ２” - (wherein z1" is an integer of 0 to 6, for example, an integer of 1 to 6, and z2" is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ３” -phenylene-(CH ２ ) ｚ４” - (wherein z3" is an integer of 0 to 6, for example, an integer of 1 to 6, and z4" is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0167] In a preferred embodiment, Z １” is C １－３０ Alkylene group or -(CH ２ ) ｚ３” -phenylene-(CH ２ ) ｚ４” -, preferably -phenylene-(CH ２ ) ｚ４” - is. Z１” is such a group, the light resistance, particularly the ultraviolet resistance, can be improved.

[0168] In another preferred embodiment, Z １” is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. １” is -CH ２ CH ２ CH ２ In another embodiment, Z １” is -CH ２ CH ２ In yet another embodiment, Z １” is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0169] The above R ２２” are each independently a hydroxyl group or a hydrolyzable group.

[0170] The above R ２２” are preferably each independently a hydrolyzable group.

[0171] The above R ２２” are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ or —NCO (wherein R ｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈExamples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈ is a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0172] R ２３” are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0173] R ２３” In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0174] Each q1" is independently an integer of 0 to 3, and each r1" is independently an integer of 0 to 3. The sum of q1" and r1" is (SiR ２２” ｑ１” R ２３” ｒ１” ) units, it is 3.

[0175] q1″ is (SiR ２２” ｑ１” R ２３” ｒ１” ) units are each independently an integer of preferably 1 to 3, more preferably 2 to 3, and even more preferably 3.

[0176] R ２２’ are each independently a hydroxyl group or a hydrolyzable group.

[0177] R ２２’ are preferably each independently a hydrolyzable group.

[0178] R ２２’ are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ２ , -NHR ｈ or —NCO (wherein R ｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈ Examples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈ is a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0179] R ２３’ are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0180] R ２３’ In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0181] Each p1' is independently an integer of 0 to 3, each q1' is independently an integer of 0 to 3, and each r1' is independently an integer of 0 to 3. The sum of p', q1', and r1' is (SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ ) units, it is 3.

[0182] In one embodiment, p1′ is 0.

[0183] In one embodiment, p1′ is (SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’) units may each independently be an integer from 1 to 3, an integer from 2 to 3, or 3. In a preferred embodiment, p1′ is 3.

[0184] In one embodiment, q1′ is (SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ ) units are each independently an integer of 1 to 3, preferably an integer of 2 or 3, and more preferably 3.

[0185] In one embodiment, p1′ is 0 and q1′ is (SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ ) units are each independently an integer of 1 to 3, preferably an integer of 2 to 3, and more preferably 3.

[0186] R ２２ are each independently a hydroxyl group or a hydrolyzable group.

[0187] R ２２ are preferably each independently a hydrolyzable group.

[0188] R ２２ are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ or —NCO (wherein R ｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈ Examples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈis a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0189] The above R ２３ are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0190] R ２３ In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0191] Each of the above p1's is independently an integer of 0 to 3, each of the q1's is independently an integer of 0 to 3, and each of the r1's is independently an integer of 0 to 3. The sum of p1, q1, and r1 is (SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ ) units, it is 3.

[0192] In one embodiment, p1 is 0.

[0193] In one embodiment, p1 is (SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ ) units may each independently be an integer from 1 to 3, an integer from 2 to 3, or 3. In a preferred embodiment, p1 is 3.

[0194] In one embodiment, q1 is (SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ ) units are each independently an integer of 1 to 3, preferably an integer of 2 or 3, and more preferably 3.

[0195] In one embodiment, p1 is 0 and q1 is (SiR ２１ ｐ１ R ２２ ｑ１ R ２３ｒ１ ) units are each independently an integer of 1 to 3, preferably an integer of 2 to 3, and more preferably 3.

[0196] In the formula, R ｂ１ are each independently a hydroxyl group or a hydrolyzable group.

[0197] R ｂ１ are preferably each independently a hydrolyzable group.

[0198] R ｂ１ are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ or —NCO (wherein R ｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈ Examples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈ is a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0199] In the formula, R ｃ１ are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0200] R ｃ１ In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0201] Each k1 is independently an integer of 0 to 3, each l1 is independently an integer of 0 to 3, and each m1 is independently an integer of 0 to 3. The sum of k1, l1, and m1 is (SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ ) units, it is 3.

[0202] In one embodiment, k1 is (SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ ) units are each independently an integer of 1 to 3, preferably 2 or 3, more preferably 3. In a preferred embodiment, k1 is 3.

[0203] In formula (S3), there are at least two Si atoms to which hydroxyl groups or hydrolyzable groups are bonded.

[0204] In a preferred embodiment, there are at least two Si atoms to which hydroxyl groups or hydrolyzable groups are bonded in the terminal portion of formula (S3).

[0205] In a preferred embodiment, the group represented by formula (S3) is -Z １ -SiR ２２ ｑ１ R ２３ ｒ１ (wherein q1 is an integer of 1 to 3, preferably 2 or 3, more preferably 3, and r1 is an integer of 0 to 2), -Z １’ -SiR ２２’ ｑ１’ R ２３’ ｒ１’ (wherein q1' is an integer of 1 to 3, preferably 2 or 3, more preferably 3, and r1' is an integer of 0 to 2), or -Z １” -SiR ２２” ｑ１” R ２３” ｒ１” (wherein q1″ is an integer of 1 to 3, preferably 2 or 3, more preferably 3, and r1″ is an integer of 0 to 2). Z １ , Z１’ , Z １” , R ２２ , R ２３ , R ２２’ , R ２３’ , R ２２” , and R ２３” has the same meaning as above.

[0206] In a preferred embodiment, in formula (S3), R ２１’ When present, at least one, preferably all, R ２１’ In the formula, q1″ is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0207] In a preferred embodiment, in formula (S3), R ２１ When present, at least one, preferably all, R ２１ In the formula (I), p1' is 0, and q1' is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0208] In a preferred embodiment, in formula (S3), R ａ１ When present, at least one, preferably all, R ａ１ In the formula (I), p1 is 0, and q1 is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0209] In a preferred embodiment, in formula (S3), k1 is 2 or 3, preferably 3; p1 is 0; and q1 is 2 or 3, preferably 3.

[0210] R ｄ１ are each independently -Z ２ -CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ is.

[0211] Z ２ are each independently a single bond, an oxygen atom, or a divalent organic group. ２ The structure written as follows is (CR ３１ ｐ２ R ３２ ｑ２ R ３３ｒ２ )

[0212] In a preferred embodiment, Z ２ is a divalent organic group.

[0213] In a preferred embodiment, Z ２ does not contain siloxane bonds.

[0214] Z ２ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ５ -O-(CH ２ ) ｚ６ - (wherein z5 is an integer of 0 to 6, for example, an integer of 1 to 6, and z6 is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７ -phenylene-(CH ２ ) ｚ８ - (wherein z7 is an integer of 0 to 6, for example, an integer of 1 to 6, and z8 is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0215] In a preferred embodiment, Z ２ is C １－３０ Alkylene group or -(CH ２ ) ｚ７ -phenylene-(CH ２ ) ｚ８ -, preferably -phenylene-(CH ２ ) ｚ８ - is. Z ２ is such a group, the light resistance, particularly the ultraviolet resistance, can be improved.

[0216] In another preferred embodiment, the Z ２ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C１－３ In one embodiment, Z is an alkylene group. ２ is -CH ２ CH ２ CH ２ In another embodiment, Z ２ is -CH ２ CH ２ In yet another embodiment, Z ２ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0217] R ３１ are each independently -Z ２’ -CR ３２’ ｑ２’ R ３３’ ｒ２’ is.

[0218] Z ２’ are each independently a single bond, an oxygen atom, or a divalent organic group. ２’ The structure written as follows is (CR ３２’ ｑ２’ R ３３’ ｒ２’ )

[0219] In a preferred embodiment, Z ２’ does not contain siloxane bonds.

[0220] Z ２’ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ５’ -O-(CH ２ ) ｚ６’ - (wherein z5' is an integer of 0 to 6, for example, an integer of 1 to 6, and z6' is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７’ -phenylene-(CH ２ ) ｚ８’- (wherein z7' is an integer of 0 to 6, for example, an integer of 1 to 6, and z8' is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0221] In a preferred embodiment, Z ２’ is C １－３０ Alkylene group or -(CH ２ ) ｚ７’ -phenylene-(CH ２ ) ｚ８’ -, preferably -phenylene-(CH ２ ) ｚ８’ - is. Z ２’ is such a group, the light resistance, particularly the ultraviolet resistance, can be improved.

[0222] In another preferred embodiment, the Z ２’ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. ２’ is -CH ２ CH ２ CH ２ In another embodiment, Z ２’ is -CH ２ CH ２ In yet another embodiment, Z ２’ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0223] R ３２’are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ is.

[0224] Z ３ are each independently a single bond, an oxygen atom, or a divalent organic group. ３ The structure written as ３４ ｎ２ R ３５ ３－ｎ２ )

[0225] In one embodiment, Z ３ is an oxygen atom.

[0226] In one embodiment, Z ３ is a divalent organic group.

[0227] In a preferred embodiment, Z ３ does not contain siloxane bonds.

[0228] Z ３ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ５” -O-(CH ２ ) ｚ６” - (wherein z5" is an integer of 0 to 6, for example, an integer of 1 to 6, and z6" is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８” - (wherein z7" is an integer of 0 to 6, for example, an integer of 1 to 6, and z8" is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0229] In a preferred embodiment, Z ３is C １－３０ Alkylene group or -(CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８” -, preferably -phenylene-(CH ２ ) ｚ８” - is. Z ３ is such a group, the light resistance, particularly the ultraviolet resistance, can be improved.

[0230] In another preferred embodiment, the Z ３ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. ３ is -CH ２ CH ２ CH ２ In another embodiment, Z ３ is -CH ２ CH ２ In yet another embodiment, Z ３ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0231] R ３４ are each independently a hydroxyl group or a hydrolyzable group.

[0232] R ３４ are preferably each independently a hydrolyzable group.

[0233] R ３４ are preferably each independently -OR ｈ , -OCOR ｈ , —O—N═CR ｈ ２ , -NR ｈ ２ , -NHR ｈ , —NCO, or halogen (wherein Rｈ is a substituted or unsubstituted C １－４ alkyl group), and more preferably -OR ｈ (i.e., an alkoxy group). ｈ Examples of R include unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, n-butyl, and isobutyl; and substituted alkyl groups such as chloromethyl. Among these, alkyl groups, particularly unsubstituted alkyl groups, are preferred, and methyl or ethyl groups are more preferred. In one embodiment, R ｈ is a methyl group, and in another embodiment, R ｈ is an ethyl group.

[0234] R ３５ are each independently a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0235] R ３５ In the formula (I), the monovalent organic group is preferably C １－２０ alkyl group, more preferably C １－６ It is preferably an alkyl group, more preferably a methyl group.

[0236] n2 is (SiR ３４ ｎ２ R ３５ ３－ｎ２ ) units are each independently an integer of 0 to 3. However, in the terminal portion of formula (S4), n2 is 1 to 3 (SiR ３４ ｎ２ R ３５ ３－ｎ２ In other words, there are at least two Si atoms to which hydroxyl groups or hydrolyzable groups are bonded in the terminal portion of formula (S4).

[0237] n2 is (SiR ３４ ｎ２ R ３５ ３－ｎ２ ) units are each independently an integer of preferably 1 to 3, more preferably 2 to 3, and even more preferably 3.

[0238] R ３３’are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0239] R ３３’ In the formula (I), the monovalent organic group is preferably C １－２０ Alkyl group or -(C ｓ H ２ｓ ) ｔ１ -(O-C ｓ H ２ｓ ) ｔ２ (wherein s is an integer of 1 to 6, preferably an integer of 2 to 4; t1 is 1 or 0, preferably 0; t2 is an integer of 1 to 20, preferably an integer of 2 to 10, more preferably an integer of 2 to 6), and more preferably C １－２０ alkyl group, more preferably C １－６ An alkyl group, particularly preferably a methyl group.

[0240] In one embodiment, R ３３’ is a hydroxyl group.

[0241] In another embodiment, R ３３’ is a monovalent organic group, preferably C １－２０ alkyl group, more preferably C １－６ It is an alkyl group.

[0242] Each of the q2's is independently an integer of 0 to 3, and each of the r2's is independently an integer of 0 to 3. The sum of q2' and r2' is (CR ３２’ ｑ２’ R ３３’ ｒ２’ ) units, it is 3.

[0243] q2' is (CR ３２’ ｑ２’ R ３３’ ｒ２’ ) units are each independently an integer of preferably 1 to 3, more preferably 2 to 3, and even more preferably 3.

[0244] R ３２ are each independently -Z ３ -SiR ３４ ｎ２ R ３５３－ｎ２ This is -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ is the above R ３２’ This has the same meaning as the description in

[0245] R ３３ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0246] R ３３ In the formula (I), the monovalent organic group is preferably C １－２０ Alkyl group or -(C ｓ H ２ｓ ) ｔ１ -(O-C ｓ H ２ｓ ) ｔ２ (wherein s is an integer of 1 to 6, preferably an integer of 2 to 4; t1 is 1 or 0, preferably 0; t2 is an integer of 1 to 20, preferably an integer of 2 to 10, more preferably an integer of 2 to 6), and more preferably C １－２０ alkyl group, more preferably C １－６ An alkyl group, particularly preferably a methyl group.

[0247] In one embodiment, R ３３ is a hydroxyl group.

[0248] In another embodiment, R ３３ is a monovalent organic group, preferably C １－２０ alkyl group, more preferably C １－６ It is an alkyl group.

[0249] Each p2 is independently an integer of 0 to 3, each q2 is independently an integer of 0 to 3, and each r2 is independently an integer of 0 to 3. The sum of p2, q2, and r2 is (CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ ) units, it is 3.

[0250] In one embodiment, p2 is 0.

[0251] In one embodiment, p2 is (CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ ) units may each independently be an integer from 1 to 3, an integer from 2 to 3, or 3. In a preferred embodiment, p2 is 3.

[0252] In one embodiment, q2 is (CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ ) units are each independently an integer of 1 to 3, preferably an integer of 2 or 3, and more preferably 3.

[0253] In one embodiment, p2 is 0 and q2 is (CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ ) units are each independently an integer of 1 to 3, preferably an integer of 2 to 3, and more preferably 3.

[0254] R ｅ１ are each independently -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ This is -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ is the above R ３２’ This has the same meaning as the description in

[0255] R ｆ１ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group. Such monovalent organic groups are monovalent organic groups excluding the above-mentioned hydrolyzable groups.

[0256] R ｆ１ In the formula (I), the monovalent organic group is preferably C １－２０ Alkyl group or -(C ｓ H ２ｓ ) ｔ１-(O-C ｓ H ２ｓ ) ｔ２ (wherein s is an integer of 1 to 6, preferably an integer of 2 to 4; t1 is 1 or 0, preferably 0; t2 is an integer of 1 to 20, preferably an integer of 2 to 10, more preferably an integer of 2 to 6), and more preferably C １－２０ alkyl group, more preferably C １－６ An alkyl group, particularly preferably a methyl group.

[0257] In one embodiment, R ｆ１ is a hydroxyl group.

[0258] In another embodiment, R ｆ１ is a monovalent organic group, preferably C １－２０ alkyl group, more preferably C １－６ It is an alkyl group.

[0259] Each k2 is independently an integer of 0 to 3, each l2 is independently an integer of 0 to 3, and each m2 is independently an integer of 0 to 3. The sum of k2, l2, and m2 is (CR ｄ１ ｋ２ R ｅ１ ｌ２ R ｆ１ ｍ２ ) units, it is 3.

[0260] In one embodiment, n2 is 1 to 3, preferably 2 or 3, more preferably 3 (SiR ３４ ｎ２ R ３５ ３－ｎ２ ) units are present at each terminal portion of formula (S3) in an amount of 2 or more, for example, 2 to 27, preferably 2 to 9, more preferably 2 to 6, even more preferably 2 to 3, and particularly preferably 3.

[0261] In a preferred embodiment, in formula (S4), R ３２’ When present, at least one, preferably all, R ３２’ In the formula, n2 is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0262] In a preferred embodiment, in formula (S4), R３２ When present, at least one, preferably all, R ３２ In the formula, n2 is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0263] In a preferred embodiment, in formula (S4), R ｅ１ When present, at least one, preferably all, R ａ１ In the formula, n2 is an integer of 1 to 3, preferably 2 or 3, and more preferably 3.

[0264] In a preferred embodiment, in formula (S4), k2 is 0, l2 is 2 or 3, preferably 3, and n2 is 2 or 3, preferably 3.

[0265] R ｇ１ and R ｈ１ are each independently -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ , -Z ４ -SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ , -Z ４ -CR ｄ１ ｋ２ R ｅ１ ｌ２ R ｆ１ ｍ２ Here, R １１ , R １２ , R ａ１ , R ｂ２ , R ｃ１ , R ｄ１ , R ｅ１ , R ｆ１ , n1, k1, l1, m1, k2, l2, and m2 have the same meanings as above.

[0266] In a preferred embodiment, R ｇ１ and R ｈ１ are each independently -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ is.

[0267] Above Z ４ are each independently a single bond, an oxygen atom, or a divalent organic group. ４ The structure written as １１ ｎ１ R １２ ３－ｎ１ )

[0268] In one embodiment, Z ４ is an oxygen atom.

[0269] In one embodiment, Z ４ is a divalent organic group.

[0270] In a preferred embodiment, Z ４ does not contain siloxane bonds.

[0271] Z ４ is preferably C １－３０ Alkylene group, -(CH ２ ) ｚ５” -O-(CH ２ ) ｚ６” - (wherein z5" is an integer of 0 to 6, for example, an integer of 1 to 6, and z6" is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８” - (wherein z7" is an integer of 0 to 6, for example, an integer of 1 to 6, and z8" is an integer of 0 to 6, for example, an integer of 1 to 6). １－３０ The alkylene group may be linear or branched, but is preferably linear. These groups may contain, for example, a fluorine atom, a C １－６ Alkyl group, C ２－６ Alkenyl groups, and C ２－６ It may be substituted by one or more substituents selected from alkynyl groups, but is preferably unsubstituted.

[0272] In a preferred embodiment, Z ４ is C １－３０ Alkylene group or -(CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８”-, preferably -phenylene-(CH ２ ) ｚ８” - is. Z ３ is such a group, the light resistance, particularly the ultraviolet resistance, can be improved.

[0273] In another preferred embodiment, the Z ４ is C １－３０ Alkylene groups, for example, C １－６ Alkylene group or C １－３ In one embodiment, Z is an alkylene group. ４ is -CH ２ CH ２ CH ２ In another embodiment, Z ４ is -CH ２ CH ２ In yet another embodiment, Z ４ is -CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ -It can be.

[0274] In one embodiment, formulas (S1), (S2), (S3), and (S4) do not contain siloxane bonds.

[0275] In one embodiment, R Ｓｉ is a group represented by formula (S2), (S3), (S4), or (S5).

[0276] In one embodiment, R Ｓｉ is a group represented by formula (S2), (S3), or (S4).

[0277] In one embodiment, R Ｓｉ is a group represented by formula (S3), (S4) or (S5).

[0278] In one embodiment, R Ｓｉ is a group represented by formula (S3) or (S4).

[0279] In one embodiment, RＳｉ is a group represented by formula (S4) or (S5).

[0280] In one embodiment, R Ｓｉ is a group represented by formula (S1). In a preferred embodiment, formula (S1) is a group represented by formula (S1-b). In a preferred embodiment, in the formula, R １３ is a hydrogen atom, and X １１ is a single bond or -R ２８ -O ｘ -R ２９ - (wherein, R ２８ and R ２９ is, in each occurrence, independently a single bond or C １－２０ an alkylene group, and x is 0 or 1; and n1 is 1 to 3, preferably 2 to 3, and more preferably 3.

[0281] In one embodiment, R Ｓｉ is a group represented by formula (S2): In a preferred embodiment, n1 is 1 to 3, preferably 2 to 3, and more preferably 3.

[0282] In one embodiment, R Ｓｉ is a group represented by formula (S3). In a preferred embodiment, formula (S2) is -SiR ａ１ ２ R ｃ１ , or -SiR ａ１ ３ and R ａ１ Is, -Z １ -SiR ２２ ｑ１ R ２３ ｒ１ and Z １ is C １－６ Alkylene group, -(CH ２ ) ｚ１ -O-(CH ２ ) ｚ２ - (wherein z1 is an integer of 0 to 6, for example, an integer of 1 to 6, and z2 is an integer of 0 to 6, for example, an integer of 1 to 6), or -(CH ２ ) ｚ３ -phenylene-(CH ２ ) ｚ４- (wherein z3 is an integer of 0 to 6, for example, an integer of 1 to 6, and z4 is an integer of 0 to 6, for example, an integer of 1 to 6), preferably C １－６ It is an alkylene group, and q1 is 1 to 3, preferably 2 to 3, and more preferably 3.

[0283] In one embodiment, R Ｓｉ is a group represented by formula (S4). In a preferred embodiment, formula (S3) is -CR ｅ１ ２ R ｆ１ , or -CR ｅ１ ３ and R ｅ１ Is, -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ and Z ３ is C １－６ Alkylene group, -(CH ２ ) ｚ５” -O-(CH ２ ) ｚ６” - (wherein z5" is an integer of 0 to 6, for example, an integer of 1 to 6, and z6" is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８” - (wherein z7" is an integer of 0 to 6, for example an integer of 1 to 6, and z8" is an integer of 0 to 6, for example an integer of 1 to 6), preferably C １－６ It is an alkylene group, and n2 is 1 to 3, preferably 2 to 3, and more preferably 3.

[0284] In one embodiment, R Ｓｉ is a group represented by formula (S5). ｇ１ and R ｈ１ Is, -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ and Z ４ is C １－６ Alkylene group, -(CH ２ ) ｚ５” -O-(CH ２ ) ｚ６”- (wherein z5" is an integer of 0 to 6, for example, an integer of 1 to 6, and z6" is an integer of 0 to 6, for example, an integer of 1 to 6), or - (CH ２ ) ｚ７” -phenylene-(CH ２ ) ｚ８” - (wherein z7" is an integer of 0 to 6, for example an integer of 1 to 6, and z8" is an integer of 0 to 6, for example an integer of 1 to 6), preferably C １－６ It is an alkylene group, and n1 is 1 to 3, preferably 2 to 3, and more preferably 3.

[0285] In a preferred embodiment, formula (S2) is the following formula: In the following formula, * represents X １ Represents the point of attachment to

[0286] In a preferred embodiment, formula (S3) is the following formula: In the following formula, * represents X １ Represents the point of attachment to

[0287] In a preferred embodiment, formula (S4) is the following formula: In the following formula, * represents X １ Represents the point of attachment to

[0288] In a preferred embodiment, formula (S5) is the following formula: In the following formula, * represents X １ Represents the point of attachment to

[0289] In a preferred embodiment, the compounds of the present disclosure are Ｓ is represented by the following formula: １ -[Si(CH ３ ) ２ -O] ｘ -Si(CH ３ ) ２ - [wherein, R １ is an alkyl group having 1 to 6 carbon atoms or R １ａ ｎａ R １ｂ ３－ｎａ Si—(O) ｚ - and R １ａ is (CH ３ ) ３ SiO—, R １ｂis an alkyl group having 1 to 4 carbon atoms, na is 2 or 3, and x is an integer of 5 to 50. １ is represented by the following formula: -X １１ -X １２ -X １３ - [In the formula: X １１ is C １－６ is an alkylene group or a phenylene group, １２ is -O-[(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 2 to 4, nc is an integer of 1 to 5, and z1 is 0 or 1), and X １３ is C １－１２ is an alkylene group.], and R Ｓｉ is represented by the following formula: １１ ３ [In the formula, R １１ is -OR ｈ and R ｈ is an alkyl group having 1 to 4 carbon atoms.] and α is 1.

[0290] In one embodiment, suitable silane compounds of the present disclosure include, but are not limited to, the following compounds:

[0291] In the following formula, n is preferably 0 or more, more preferably 3 or more, and particularly preferably 6 or more. Furthermore, n is preferably 500 or less, more preferably 300 or less, and particularly preferably 200 or less. Furthermore, n is preferably 3 or more and 300 or less, more preferably 3 or more and 200 or less, particularly preferably 3 or more and 100 or less, and most preferably 10 or more and 30 or less. p is preferably 1 or more. Furthermore, p is preferably 50 or less, more preferably 30 or less, and particularly preferably 10 or less. p is preferably 1 or more and 50 or less, more preferably 1 or more and 30 or less, and particularly preferably 1 or more and 10 or less. q is preferably 1 or more and more preferably 2 or more. Furthermore, q is preferably 80 or less, more preferably 60 or less, and particularly preferably 50 or less. q is preferably 1 or more and 80 or less, more preferably 1 or more and 60 or less, and particularly preferably 1 or more and 50 or less. Ph represents a phenylene group.

[0292] CH ３ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ O (CH ２ CH ２ O)p(CH ２ ) ｑ Si(OCH ３ ) ３ CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ O (CH ２ CH ２ O)p(CH ２ ) ｑ Si(OCH ３ ) ３ [(CH ３）３ SiO] ３ SiO[Si(CH ３ ) ２ O] ｎH ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） H.E. ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３

[0293] CH ３ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ P.S. ２ ) ｑH. ３ ) ３ [(CH ３）３ SiO] ３ H.E. ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） H.E. ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３

[0294] CH ３ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O]ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ３ H.E. ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） H.E. ３ ) ２ O] ｎ H ３ ) ２ CH ２ CH ２ CH ２ O(CH ２ CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３

[0295] CH ３ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ P.S. ２ ) ｑH. ３ ) ３ CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ３ H.E. ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） H.E. ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３

[0296] CH ３ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ CH ３ CH ２ CH２ CH ２ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ３ H.E. ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） H.E. ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３

[0297] CH ３ [Si(CH ３ ) ２ O] ｎ H ３ ) ２ P.S. ２ CH ２ CH ２ CH ２ P.S. ２ ) ｑ H. ３ ) ３ CH ３ CH ２ CH ２CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ PhO(CH ２ CH ２ CH ２ CH ２ O)p(CH ２ ) ｑ Si(OCH ３ ) ３ [(CH ３）３ SiO] ３ SiO[Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ PhO(CH ２ CH ２ CH ２ CH ２ O)p(CH ２ ) ｑ Si(OCH ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） SiO[Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ PhO(CH ２ CH ２ CH ２ CH ２ O)p(CH ２ ) ｑ Si(OCH ３ ) ３

[0298] Specific examples of the compounds of the present disclosure include the following compounds: CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ ] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH２ OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ [(CH ３）３ SiO] ２ (CH ３） SiO[Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ PhO(CH ２ CH ２ O) ５ (CH ２ ) １１ Si(OCH ３ ) ３

[0299] [Production Method] A method for producing the silane compound of the present disclosure will be described below, but the method for producing the silane compound of the present disclosure is not limited to the following method.

[0300] (Production Method 1) In this production method, an olefin compound having a halogen atom at its terminal is reacted with a carbinol to produce an olefin compound containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and the olefin group of this aromatic compound is converted into a compound represented by the following formula: HSiR ｊ２７ ｍ３ R ｊ２８ ３－ｍ３ [In the formula, R ｊ２７ are each independently a hydroxyl group or a hydrolyzable group, R ｊ２８ are each independently a monovalent organic group, and m3 is 1 to 3. A silane compound can be obtained by reacting a compound represented by the formula:

[0033] . The monovalent organic group does not contain a hydrolyzable group.

[0301] Examples of carbinols include carbinols having one or more Si atoms at one end that are not directly bonded to a hydroxyl group or a hydrolyzable group. Examples of carbinols having one or more Si atoms at one end that are not directly bonded to a hydroxyl group or a hydrolyzable group include compounds having a hydroxyl group at one end of polydimethylsiloxane (e.g., Silaplane (trademark) FM-0411, Silaplane (trademark) FM-0421, Silaplane (trademark) FM-0425, Silaplane (trademark) FM-DA11, Silaplane (trademark) FM-DA21, and Silaplane (trademark) FM-DA26, all manufactured by JNC Corporation).

[0302] Examples of olefin compounds having a halogen atom at the terminal include those represented by formula (1b): Hal-R Ｘ１ -CH=CH ２ (1b) wherein: Hal is a halogen, such as fluorine, chlorine, bromine, or iodine, preferably bromine; R Ｘ１ is a single bond or a divalent group.

[0303] Examples of the formula (1b) include the following formulas (1b1), (1b2), (1b3), and (1b4): Hal-R Ｘ -CONR ８１ - (CH ２ ) ｚａ -CH=CH ２ (1b1) Hal-R Ｘ -CON [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1b2) Hal-R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -CR ８２ [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1b3) Hal-R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -C[-(CH２ ) ｚａ -CH=CH ２ ] ３ (1b4) wherein: Hal is halogen; R Ｘ is a single bond or a divalent group, R ８１ is a hydrogen atom or a monovalent organic group, R ８２ represents a hydrogen atom or a monovalent organic group, za represents an integer of 0 to 30, and zb represents an integer of 0 to 30.] or a compound represented by formula (1d1), (1d2), or (1d3): Hal-R Ｘ - (CH ２ ) ｚａ -CH=CH ２ (1d1) Hal-R Ｘ -SiR ８３ [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1d2) Hal-R Ｘ -Si[-(CH ２ ) ｚａ -CH=CH ２ ] ３ (1d3) wherein: Hal is halogen; Ｘ is a single bond or a divalent group, R ８３ represents a hydrogen atom or a monovalent organic group, and za represents an integer of 0 to 30.

[0304] In one embodiment, examples of the olefin compound having a halogen atom at the terminal include allyl bromide, 4-bromo-1-butene, 5-bromo-1-pentene, 6-bromo-1-hexene, 7-bromo-1-heptene, 8-bromo-1-octene, 9-bromo-1-nonene, 10-bromo-1-decene, 11-bromo-1-undecene, 12-bromo-1-dodecene, 13-bromo-1-tridecene, 14-bromo-1-tetradecene, 15-bromo-1-pentadecene, 16-bromo-1-hexadecene, and 17-bromo-1-heptane. Decene, 18-bromo-1-octadecene, 19-bromo-1-nonadecene, 20-bromo-1-icosene, 21-bromo-1-heneicosene, 24-bromo-1-tetracosene, 30-bromo-1-triacontene, allyl chloride, 4-chloro-1-butene, 5-chloro-1-pentene, 6-chloro-1-hexene, 7-chloro-1-heptene, 8-chloro-1-octene, 9-chloro-1-nonene, 10-chloro-1-decene, 11-chloro-1-undecene, 12-chloro-1-dodecene, 13-chloro-1-tridecene, 14-chloro-1-trimethylsilyl methyl acrylate, 15-chloro-1-trimethylsilyl methyl acrylate, 16-chloro-1-trimethylsilyl methyl acrylate, 17-chloro-1-trimethylsilyl methyl acrylate, 18-bromo-1-octadecene, 19-bromo-1-nonadecene, 20-bromo-1-icosene, 21-bromo-1-heneicosene, 24-bromo-1-tetracosene, 30-bromo-1-triacontene, allyl chloride, 4-chloro-1-butene, 5-chloro-1-pentene, 6-chloro-1-hexene, 7-chloro-1-heptene, 8-chloro-1-octene, 9-chloro-1-nonene, 10-chloro-1-decene, 11-chloro-1-undecene, 12-chloro-1-dodecene, 13-chloro-1-trimethylsilyl methyl acrylate Decene, 14-chloro-1-tetradecene, 15-chloro-1-pentadecene, 16-chloro-1-hexadecene, 17-chloro-1-heptadecene, 18-chloro-1-octadecene, 19-chloro-1-nonadecene, 20-chloro-1-icosene, 21-chloro-1-heneicosene, 24-chloro-1-tetracosene, 30-chloro-1-triacontene, allyl iodide, 4-iodo-1-butene, 5-iodo-1-pentene, 6-iodo-1-hexene, 7-iodo-1-heptene, 8-iodo-1-octene, 9- Examples of the iodo-1-nonene include 10-iodo-1-decene, 11-iodo-1-undecene, 12-iodo-1-dodecene, 13-iodo-1-tridecene, 14-iodo-1-tetradecene, 15-iodo-1-pentadecene, 16-iodo-1-hexadecene, 17-iodo-1-heptadecene, 18-iodo-1-octadecene, 19-iodo-1-nonadecene, 20-iodo-1-icosene, 21-iodo-1-heneicosene, 24-iodo-1-tetracosene, and 30-iodo-1-triacontene.

[0305] The reaction of a single-terminated carbinol containing one or more silicon atoms to which no hydroxyl or hydrolyzable group is directly bonded with an olefin compound having a halogen at the terminal is carried out in the presence of a base. The base can be either an organic or inorganic base. Examples of organic bases include triethylamine, diisopropylethylamine, and diethylamine. Examples of inorganic bases include sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate.

[0306] The reaction can be carried out in an organic solvent, which is not particularly limited as long as it does not react with the base.

[0307] In one embodiment, examples of the solvent include aliphatic hydrocarbons such as hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, and mineral spirits; aromatic hydrocarbons such as benzene, toluene, xylene, naphthalene, and solvent naphtha; glycol ethers such as dipropylene glycol dimethyl ether; cyclic ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; ethers such as diethyl ether and cyclopentyl methyl ether; and siloxanes such as hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and tetradecamethylhexasiloxane. Alternatively, a mixed solvent of two or more of these solvents may be used.

[0308] (Production Method 2) In this production method, an aromatic compound having a siloxane group and an olefin-containing group is produced by reacting an aromatic compound having a halogen atom and a terminal olefin-containing group with a silane compound, and the olefin group of this aromatic compound is converted into a siloxane group represented by the following formula: ｊ２７ ｍ３ R ｊ２８ ３－ｍ３ [In the formula, R ｊ２７ are each independently a hydroxyl group or a hydrolyzable group, R ｊ２８are each independently a monovalent organic group, and m3 is 1 to 3. A silane compound can be obtained by reacting a compound represented by the formula:

[0033] . The monovalent organic group does not contain a hydrolyzable group.

[0309] Examples of aromatic compounds having a halogen atom and a terminal olefin-containing group include those represented by the formula (1b): Hal-R Ａｒ -R Ｘ１ -CH=CH ２ (1b) wherein: Hal is a halogen, such as fluorine, chlorine, bromine, or iodine, preferably bromine; R Ａｒ is a divalent aromatic group and has the same meaning as in formula (1); R Ｘ１ is a divalent to decavalent group containing two or more ether bonds.]

[0310] Examples of the formula (1b) include the following formulas (1b1), (1b2), (1b3), and (1b4): Hal-R Ａｒ -R Ｘ -CONR ８１ - (CH ２ ) ｚａ -CH=CH ２ (1b1) Hal-R Ａｒ -R Ｘ -CON [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1b2) Hal-R Ａｒ -R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -CR ８２ [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1b3) Hal-R Ａｒ -R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -C[-(CH ２ ) ｚａ -CH=CH ２ ]３ (1b4) wherein: Hal is halogen; Ａｒ is a divalent aromatic group, R Ｘ is a divalent group containing two or more ether bonds, and R ８１ is a hydrogen atom or a monovalent organic group, R ８２ represents a hydrogen atom or a monovalent organic group, za represents an integer of 0 to 30, and zb represents an integer of 0 to 30.] or a compound represented by formula (1d1), (1d2), or (1d3): Hal-R Ａｒ -R Ｘ - (CH ２ ) ｚａ -CH=CH ２ (1d1) Hal-R Ａｒ -R Ｘ -SiR ８３ [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1d2) Hal-R Ａｒ -R Ｘ -Si[-(CH ２ ) ｚａ -CH=CH ２ ] ３ (1d3) wherein: Hal is halogen; Ａｒ is a divalent aromatic group, R Ｘ is a divalent group containing two or more ether bonds, and R ８３ represents a hydrogen atom or a monovalent organic group, and za represents an integer of 0 to 30.

[0311] The compound represented by the above formula (1b1), (1b2), (1b3), or (1b4), or the compound represented by the formula (1d1), (1d2), or (1d3), is reacted with a silane compound to produce a compound represented by the following formula (1a1), (1a2), (1a3), or (1a4), respectively: Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -CONR ８１- (CH ２ ) ｚａ -CH=CH ２ (1a1) R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -CON [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1a2) R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -CR ８２ [-(CH ２ ) ｚａ -CH=CH ２ ] ２ (1a3) R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -CONR ８１ - (CH ２ ) ｚｂ -C[-(CH ２ ) ｚａ -CH=CH ２ ] ３ (1a4) or the following (1c1), (1c2), or (1c3): R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ - (CH ２ ) ｚａ -CH=CH ２ (1c1) R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -SiR ８３ [-(CH ２ ) ｚａ -CH=CH２ ] ２ (1c2) R Ａ -R Ｓ -SiR ６ ２ -R Ａｒ -R Ｘ -Si[-(CH ２ ) ｚａ -CH=CH ２ ] ３ (1c3) [wherein: R Ａ is a hydrocarbon group or a monovalent group containing one or more Si atoms to which a hydroxyl group or a hydrolyzable group is not directly bonded, and R Ｓ is the following formula: (In the formula: R ７３ are each independently a single bond, C １－１２ alkylene group, -R ７６ -O-R ７６ -, -R ７８ -R ７７ -R ７８ -, -R ７８ -R ７７ -R ７９ -R ７７ -R ７８ -, -R ７８ -R ７７ -R ７９ -R ７６ -R ７９ -R ７７ -R ７８ - or -R ７９ -R ７６ -R ７９ -R ７７ -R ７９ -R ７６ -R ７９ - and R ７４ are each independently C １－１２ alkylene group, -R ７６ -O-R ７６ -, -R ７８ -R ７７ -R ７８ -, -R ７８ -R ７７ -R ７９ -R ７７ -R ７８ -, -R ７８ -R ７７ -R ７９ -R７６ -R ７９ -R ７７ -R ７８ - or -R ７９ -R ７６ -R ７９ -R ７７ -R ７９ -R ７６ -R ７９ - and R ７６ are each independently C １－６ is an alkylene group, R ７７ are each independently an optionally substituted phenylene group or naphthylene group, and R ７８ are each independently a single bond or C １－６ is an alkylene group, R ７９ are each independently a single bond or an oxygen atom, ７５ are each independently a hydrocarbon group, x is an integer of 0 to 500, y is an integer of 0 to 500, z is an integer of 0 to 500, x + y + z is 1 or more, and the order of occurrence of the respective repeating units enclosed in parentheses with x, y, or z is arbitrary in the formula, ６ are each independently a hydrocarbon group; R Ａｒ is a divalent aromatic group, R Ｘ is a divalent group containing two or more ether bonds, and R ８１ is a hydrogen atom or a monovalent organic group, R ８３ represents a hydrogen atom or a monovalent organic group, za represents an integer of 0 to 30, and zb represents an integer of 0 to 30.

[0312] In formulae (1a1) to (1a4), (1b1) to (1b4), (1c1) to (1c3) and (1d1) to (1d3), R Ａ , R Ｓ , R ６ , and R Ａｒ is R in formula (1). Ａ , R Ｓ , R ６ , and R Ａｒ and may have the same meaning as above.

[0313] In formulae (1b1) to (1b4) and (1d1) to (1d3), Hal is a halogen, specifically a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, preferably a chlorine atom or a bromine atom, more preferably a bromine atom.

[0314] In formulae (1a1) to (1a4), (1b1) to (1b4), (1c1) to (1c3) and (1d1) to (1d3), R Ｘ is a divalent group containing two or more ether bonds.

[0315] In one embodiment, the divalent group has the following formula: １１’ -X １２’ -X １３’ - [In the formula: X １１’ is a single bond or a divalent group, １２’ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1), １３’ is a single bond or a divalent group. １１’ , X １２’ , and X １３’ is X in formula (1). １１ , X １２ , and X １３ and may have the same meaning as above.

[0316] R ８１ is a hydrogen atom or a monovalent organic group.

[0317] R ８２ is a hydrogen atom, a hydroxyl group, or a monovalent organic group.

[0318] R ８３ is a hydrogen atom, a hydroxyl group, or a monovalent organic group.

[0319] R ８１ , R ８２ and R ８３The monovalent organic groups in the formula (I) may each independently be a hydrocarbon group or a hydrocarbon group having an oxygen atom at the end or in the main chain.

[0320] The monovalent organic group is preferably C １－２０ an alkyl group, or -(C ｓ H ２ｓ ) ｔ１ -(O-C ｓ H ２ｓ ) ｔ２ H (wherein s is an integer of 1 to 6, preferably an integer of 2 to 4; t1 is 1 or 0, preferably 0; t2 is an integer of 1 to 20, preferably an integer of 2 to 10, more preferably an integer of 2 to 6), and more preferably C １－２０ alkyl group, more preferably C １－６ An alkyl group, particularly preferably a methyl group.

[0321] In formulas (1a1) to (1a4), (1b1) to (1b4), (1c1) to (1c3), and (1d1) to (1d3), za is an integer of 0 to 30.

[0322] In one embodiment, za is 0.

[0323] In another embodiment, za is an integer from 1 to 30, for example, 4 to 30, 8 to 28, 10 to 26, or 14 to 22.

[0324] In formulas (1a1) to (1a4), (1b1) to (1b4), (1c1) to (1c3), and (1d1) to (1d3), zb is an integer of 0 to 30.

[0325] In one embodiment, zb is 0.

[0326] In another embodiment, zb is an integer from 1 to 30, for example, 4 to 30, 8 to 28, 10 to 26, or 14 to 22.

[0327] Examples of the silane compound include the following compounds: ClSiR ８５ ３ , ClSiR ８５ (SiR ８５ ３ ) ２ , [wherein, R８５ are each independently a hydrocarbon group, preferably C １－６ alkyl group, more preferably C １－３ It is preferably an alkyl group, and more preferably a methyl group. [In the formula, n is 0 to 500, preferably 0 to 200 (in one embodiment, n is 0; in another embodiment, n is 1 to 200, preferably 10 to 100, more preferably 10 to 50; in yet another embodiment, n is preferably 1 to 10, more preferably 1 to 6).]

[0328] The silane compound can be cyclic siloxane.Cyclic siloxane can be hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetradecamethylcycloheptasiloxane, hexadecamethylcyclooctasiloxane, octadecamethylcyclononasiloxane, eicosamethylcyclodecasiloxane, etc.From the viewpoint of reactivity, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane are preferred, and hexamethylcyclotrisiloxane and octamethylcyclotetrasiloxane are more preferred.

[0329] By reacting the silane with the cyclic siloxane and then reacting it with a capping agent, a silane compound represented by (1a1), (1a2), (1a3), or (1a4), or (1c1), (1c2), or (1c3), can be obtained. Chlorosilanes can be used as capping agents. Specific examples of chlorosilanes include chlorotrimethylsilane, chlorotriethylsilane, chlorotripropylsilane, chlorotributylsilane, chlorocyclohexyldimethylsilane, chlorodimethylphenylsilane, chloromethyldiphenylsilane, chlorotriphenylsilane, and chlorosilanes represented by the following formulas:

[0330] The present disclosure provides intermediates for use in the preparation of the disclosed silane compounds. The disclosed intermediate compounds have the formula: Ｓ-X １ａ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ａ is a divalent group containing two or more ether bonds.

[0331] In a preferred embodiment, the intermediate compound of the present disclosure has the formula: Ｓ -X １ａ -CONR ５１ - (CH ２ ) ｘ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which no hydroxyl group or hydrolyzable group is directly bonded, and X １ａ is a divalent group containing two or more ether bonds, and R ５１ is a hydrogen atom or a monovalent hydrocarbon group, and x is an integer of 0 to 30.

[0332] Next, the surface treatment agent of the present invention will be described.

[0333] The surface treatment agent of the present disclosure contains at least one silane compound represented by formula (1). That is, the surface treatment agent of the present disclosure may contain two silane compounds represented by formula (1).

[0334] The silane compound represented by formula (1) may include a silane compound having one Si atom bonded to a hydrolyzable group, and a silane compound having two or more, for example, two or three, Si atoms bonded to water-decomposable groups.

[0335] The ratio by mass of the silane compound having one Si atom bonded to a hydrolyzable group and the silane compound having two or more Si atoms bonded to water-decomposable groups may be 10:90 to 90:10, preferably 20:80 to 80:20, for example 30 to 70 to 70:30.

[0336] In one embodiment, the surface treatment agent of the present disclosure is at least one compound represented by formula (1) itself.

[0337] In one embodiment, the content of the compound represented by formula (1) above may be preferably 0.1 to 50.0 mass%, more preferably 1.0 to 30.0 mass%, even more preferably 5.0 to 25.0 mass%, and particularly preferably 10.0 to 20.0 mass%, based on the total mass of the surface treatment agent.

[0338] In another embodiment, the content of the compound represented by the above formula (1) may be preferably 0.001 to 30 mass%, more preferably 0.01 to 10 mass%, even more preferably 0.05 to 5 mass%, and particularly preferably 0.05 to 2 mass%, based on the total mass of the surface treatment agent.

[0339] In one embodiment, the surface treatment agent of the present disclosure may contain a compound represented by formula (1) and a condensate in which at least a portion of the compound represented by formula (1) is condensed.

[0340] In the above aspect, the content of the condensate may be preferably 40% by mass or less, more preferably 30% by mass or less, based on the total of the compound represented by formula (1) and the condensate. Here, the content of the condensate can be determined, for example, from the abundance ratio of peak position and area in GPC (gel permeation chromatography).

[0341] The surface treatment agent of the present disclosure may further comprise a compound represented by formula (3): R ５１ -R ５２ -CONR ５４ -R ５３ -SiR １１ ｎ１ R １２ ３－ｎ１ (3) [In the formula: R ５１ is CH ３ CH ２ CH ２ -, CH ３ CH═CH—, or R １２ ３－ｎ１ R １１ ｎ１ Si—, and R ５２ is C ０－３０ is an alkylene group, R ５３ is C １－１０ is an alkylene group, R ５４ is a hydrogen atom, C１－６ an alkyl group or a phenyl group, R １１ are each independently a hydroxyl group or a hydrolyzable group, R １２ are each independently a hydrogen atom or a monovalent organic group, and n1 is an integer of 1 to 3. By including the compound represented by formula (3), the surface treatment agent of the present disclosure further improves friction durability.

[0342] In one embodiment, R ５１ is CH ３ CH ２ CH ２ - and CH ３ It can be CH=CH-.

[0343] In one embodiment, R ５２ is C ０ An alkylene group, i.e., a single bond.

[0344] In another embodiment, R ５２ is C １－３０ Alkylene groups, such as C １－１０ Alkylene group, C ３－６ Alkylene group, C ６－２７ Alkylene group, C ７－２３ Alkylene group, C ８－２１ Alkylene group, C ９－１９ It may be an alkylene group.

[0345] R ５３ is C １－１０ Alkylene group, preferably C ２－６ Alkylene group, more preferably C ２－４ an alkylene group,

[0346] In one embodiment, R ５４ is a hydrogen atom.

[0347] In another embodiment, R ５４ is C １－６ It is an alkyl group or a phenyl group.

[0348] R ５４ C in １－６ The alkyl group may be linear or branched. １－６The alkyl group is linear. １－６ The alkyl group is a branched chain. １－６ The alkyl group is preferably C １－４ It is an alkyl group.

[0349] R １１ , R １２ and n are defined as in formula (1).

[0350] The surface treatment agent according to the present disclosure may contain the compound represented by formula (3) in an amount of preferably 0.1% by mass to 30% by mass, more preferably 0.5% by mass to 20% by mass, and even more preferably 1.0% by mass to 20% by mass, based on the total amount of the compound represented by formula (1) and the compound represented by formula (3).

[0351] In one embodiment, the surface treatment agent of the present disclosure is R ５４ is C １－６ The compound represented by formula (3), which is an alkyl group or a phenyl group, may be contained in an amount of, for example, 0.5% by mass to 99.5% by mass, preferably 0.5% by mass to 30% by mass, more preferably 1.0% by mass to 20% by mass, or 30% by mass to 70% by mass, or 70% by mass to 99.5% by mass, based on the total amount of the compound represented by formula (1) and the compound represented by formula (3).

[0352] In one embodiment, the surface treatment agent of the present disclosure is R ５４ is R １２ ３－ｎ１ R １１ ｎ１ The compound represented by formula (3) which is Si- may be contained in an amount of, for example, 0.1% by mass to 99.5% by mass, preferably 0.1% by mass to 3.0% by mass, more preferably 0.1% by mass to 1.0% by mass, alternatively 3.0% by mass to 50% by mass, 50% by mass to 99.5% by mass, 30% by mass to 70% by mass, or 70% by mass to 99.5% by mass, based on the total amount of the compound represented by formula (1) and the compound represented by formula (3).

[0353] The composition of the present disclosure may contain a solvent, a (non-reactive) silicone compound that can be understood as silicone oil (hereinafter referred to as "silicone oil"), an amine compound, an alcohol, a catalyst, a surfactant, a polymerization inhibitor, a sensitizer, etc.

[0354] In one embodiment, the surface treatment agent of the present disclosure is R ９０ This includes compounds represented by —OH. ９０ is a monovalent organic group, preferably C １－２０ Alkyl group or C ３－２０ The alkylene group may be substituted with one or more substituents. Examples of the substituents include a hydroxyl group, -OR ９１ (where R ９１ is C １－１０ Alkyl group, preferably C １－３ alkyl groups, such as methyl groups.

[0355] In one embodiment, the surface treatment agent of the present disclosure is R ８１ OR ８２ , R ８３ ｎ８ C ６ H ６－ｎ８ , R ８４ R ８５ R ８６ Si—(O—SiR ８７ R ８８ ) ｍ８ -R ８９ , and (OSiR ８７ R ８８ ) ｍ９ [In the formula R ８１ ~R ８９ are each independently a monovalent organic group having 1 to 10 carbon atoms, m8 is an integer of 1 to 6, m9 is an integer of 3 to 8, and n8 is an integer of 0 to 6.

[0356] The monovalent organic group having 1 to 10 carbon atoms may be linear or branched, and may further contain a cyclic structure.

[0357] In one embodiment, the monovalent organic group having 1 to 10 carbon atoms may contain an oxygen atom, a nitrogen atom, or a halogen atom.

[0358] In another embodiment, the monovalent organic group having 1 to 10 carbon atoms does not contain a halogen atom.

[0359] In a preferred embodiment, the monovalent organic group having 1 to 10 carbon atoms is a hydrocarbon group which may be substituted with a halogen, preferably a hydrocarbon group which is not substituted with a halogen.

[0360] In one embodiment, the hydrocarbon group is linear.

[0361] In another embodiment, the hydrocarbon group is branched.

[0362] In another embodiment, the hydrocarbon group comprises a cyclic structure.

[0363] In one embodiment, the solvent is R ８１ OR ８２ is.

[0364] R ８１ and R ８２ are each independently preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably C １－６ or an alkyl group of C ５－８ It can be a cycloalkyl group of the formula:

[0365] In one embodiment, the solvent is R ８３ ｎ８ C ６ H ６－ｎ８ is.

[0366] C ６ H ６－ｎ８ is an n-octavalent benzene ring. That is, R ８３ ｎ８ C ６ H ６－ｎ８ is n8 R ８３ is benzene substituted with

[0367] R ８３ are each independently a halogen or a C optionally substituted by a halogen. １－６ The alkyl group may be:

[0368] n8 is preferably an integer of 1 to 3.

[0369] In one embodiment, the solvent is R ８４ R ８５ R ８６ Si—(O—SiR ８７ R ８８) ｍ８ -R ８９ is.

[0370] In one embodiment, the solvent is (OSiR ８７ R ８８ ) ｍ９ (OSiR ８７ R ８８ ) ｍ９ is a set of multiple OSiRs ８７ R ８８ It is a cyclic siloxane formed by bonding units in a ring.

[0371] R ８４ ~R ８９ are each independently a hydrogen atom or C １－６ alkyl group, preferably C １－６ alkyl groups of the formula C １－３ The alkyl group is preferably a methyl group.

[0372] m8 is preferably an integer of 1 to 6, more preferably an integer of 1 to 5, and even more preferably 1 or 2.

[0373] m9 is preferably an integer of 3 to 6, more preferably an integer of 3 to 5.

[0374] In one embodiment, the solvent may be, for example, an aliphatic hydrocarbon such as hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, or mineral spirit; an aromatic hydrocarbon such as benzene, toluene, xylene, naphthalene, or solvent naphtha; or an alkyl ester such as methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, cellosolve acetate, propylene glycol methyl ether acetate, carbitol acetate, diethyl oxalate, ethyl pyruvate, or ethyl-2-hydroxybutyl acetate. esters such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 2-hexanone, cyclohexanone, methyl amino ketone, 2-heptanone; ethyl cellosolve, methyl cellosolve, methyl cellosolve acetate, ethyl cellosolve acetate, propylene glycol monomethyl ether ... glycol ethers such as glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, dipropylene glycol dimethyl ether, and ethylene glycol monoalkyl ether; alcohols such as methanol, ethanol, iso-propanol, n-butanol, isobutanol, tert-butanol, sec-butanol, 3-pentanol, octyl alcohol, 3-methyl-3-methoxybutanol, and tert-amyl alcohol; glycols such as ethylene glycol and propylene glycol; cyclic ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; amides such as N,N-dimethylformamide, N,N-dimethylacetamide, and N-methylpyrrolidone; ether alcohols such as methyl cellosolve, cellosolve, isopropyl cellosolve, butyl cellosolve, and diethylene glycol monomethyl ether; diethylene glycol monoethyl ether acetate;Polyfluoroaromatic hydrocarbons (e.g., 1,3-bis(trifluoromethyl)benzene); polyfluoroaliphatic hydrocarbons (e.g., C; ６ F １３ CH ２ CH ３ (For example, Asahiklin (registered trademark) AC-6000 manufactured by Asahi Glass Co., Ltd.), C ６ F １３ H (for example, Asahiklin (registered trademark) AC-2000 manufactured by Asahi Glass Co., Ltd.), 1,1,2,2,3,3,4-heptafluorocyclopentane (for example, Zeorora (registered trademark) H manufactured by Zeon Corporation); fluorine-containing hydrocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane (HCFC225), and 1,3-bis(trifluoromethyl)benzene; CF ３ CH ２ OH, CF ３ CF ２ CH ２ OH, (CF ３ ) ２ fluorine-containing alcohols such as CHOH; hydrofluoroethers (HFEs) (for example, perfluoropropyl methyl ether (C ３ F ７ OCH ３ ) (e.g., Novec (trademark) 7000 manufactured by Sumitomo 3M Limited), perfluorobutyl methyl ether (C ４ F ９ OCH ３ ) (e.g., Novec (trademark) 7100 manufactured by Sumitomo 3M Limited), perfluorobutyl ethyl ether (C ４ F ９ O.C. ２ H ５ ) (e.g., Novec (trademark) 7200 manufactured by Sumitomo 3M Limited), perfluorohexyl methyl ether (C ２ F ５ CF (OCH ３ ) C ３ F ７) (e.g., Novec™ 7300 manufactured by Sumitomo 3M Limited) (the perfluoroalkyl group and the alkyl group may be linear or branched), or CF ３ CH ２ OCF ２ CHF ２ (e.g., Asahiklin (registered trademark) AE-3000 manufactured by Asahi Glass Co., Ltd.), hydrofluoroolefins; CF ３ CH═CHCl (e.g., CELEFIN® 1233Z manufactured by Central Glass Co., Ltd.), CHF ２ Examples of suitable solvents include ethers such as CF═CHCl (for example, AMOLEA (registered trademark) AS-300 manufactured by Asahi Glass Co., Ltd.) and cyclopentyl methyl ether; siloxanes such as hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and tetradecamethylhexasiloxane; and dimethyl sulfoxide. Alternatively, examples include mixed solvents of two or more of these. Among these, aliphatic hydrocarbons, esters, glycol ethers, alcohols, ether alcohols, and siloxanes are preferred. For example, hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, mineral spirits, methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, methanol, ethanol, isopropanol, n-butanol, isobutanol, tert-butanol, sec-butanol, diethylene glycol monomethyl ether, hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane are preferred.

[0375] The silicone oil is not particularly limited, but examples thereof include silicone oils represented by the following general formula (3a): １ａ -(SiR ３ａ ２ -O) ａ１ -SiR ３ａ ２ -R １ａ ...(3a) [wherein: R １ａ are each independently a hydrogen atom or a hydrocarbon group, ３ａ are each independently a hydrogen atom or a hydrocarbon group, and a1 is 2 to 3,000.

[0376] The above R ３ａ are each independently a hydrogen atom or a hydrocarbon group. Such hydrocarbon groups may be substituted.

[0377] R ３ａ are each independently preferably an unsubstituted hydrocarbon group or a hydrocarbon group substituted with a halogen atom. Such a halogen atom is preferably a fluorine atom.

[0378] R ３ａ are each independently preferably C optionally substituted by a halogen atom. １－６ an alkyl group or an aryl group, more preferably C １－６ It is an alkyl group or an aryl group.

[0379] Above C １－６ The alkyl group may be a straight chain or a branched chain, but is preferably a straight chain. １－６ The alkyl group is preferably C １－３ It is preferably an alkyl group, more preferably a methyl group.

[0380] The aryl group is preferably a phenyl group.

[0381] In one embodiment, R ３ａ are each independently C １－６ Alkyl group, preferably C １－３ It is preferably an alkyl group, more preferably a methyl group.

[0382] In another embodiment, R３ａ is a phenyl group.

[0383] In another embodiment, R ３ａ is a methyl group or a phenyl group, preferably a methyl group.

[0384] The above R １ａ are each independently a hydrogen atom or a hydrocarbon group, and ３ａ It has the same meaning as:

[0385] R １ａ are each independently preferably C optionally substituted by a halogen atom. １－６ an alkyl group or an aryl group, more preferably C １－６ It is an alkyl group or an aryl group.

[0386] In one embodiment, R １ａ are each independently C １－６ Alkyl group, preferably C １－３ It is preferably an alkyl group, more preferably a methyl group.

[0387] In another embodiment, R １ａ is a phenyl group.

[0388] In another embodiment, R １ａ is a methyl group or a phenyl group, preferably a methyl group.

[0389] The above a1 is 2 to 1500. a1 is preferably 5 or more, more preferably 10 or more, even more preferably 15 or more, for example, 30 or more, or 50 or more. a1 is preferably 1000 or less, more preferably 500 or less, even more preferably 200 or less, even more preferably 150 or less, for example, 100 or less, or 80 or less.

[0390] a1 may be preferably 5 to 1000, more preferably 10 to 500, even more preferably 15 to 200, and even more preferably 15 to 150.

[0391] Another silicone oil is the following (3b): １ａ -R ＳＯ２ -R ３ａ ...(3b) [wherein: R １ａare each independently a hydrocarbon group; R ３ａ are each independently a hydrocarbon group; R ＳＯ２ is -R Ｓ -SiR ５ ２ - and R Ｓ and R ５ has the same meaning as above.]

[0392] The silicone oil may have an average molecular weight of 500 to 1,000,000, preferably 1,000 to 100,000. The molecular weight of the silicone oil can be measured using GPC.

[0393] Examples of the silicone oil include -(SiR ３ａ ２ -O) ａ１ Linear or cyclic silicone oils in which a1 is 30 or less can be used. The linear silicone oils may be so-called straight silicone oils or modified silicone oils. Examples of straight silicone oils include dimethyl silicone oil, methylphenyl silicone oil, and methylhydrogen silicone oil. Examples of modified silicone oils include straight silicone oils modified with alkyl, aralkyl, polyether, higher fatty acid ester, fluoroalkyl, amino, epoxy, carboxyl, alcohol, etc. Examples of cyclic silicone oils include cyclic dimethylsiloxane oil.

[0394] The silicone oil may be contained in an amount of, for example, 0 to 50% by mass, preferably 0.001 to 30% by mass, and more preferably 0.1 to 5% by mass, relative to the composition of the present disclosure.

[0395] In the composition of the present disclosure, such silicone oil may be contained in an amount of, for example, 0 to 300 parts by mass, preferably 0 to 100 parts by mass, more preferably 0 to 50 parts by mass, and even more preferably 0 to 10 parts by mass, relative to a total of 100 parts by mass of the compounds of the present disclosure (if there are two or more types, the total of these, the same applies hereinafter).

[0396] The silicone oil contributes to improving the surface slipperiness of the surface treatment layer.

[0397] Examples of the alcohols include methanol, ethanol, isopropanol, n-butanol, isobutanol, tert-butanol, sec-butanol, 3-pentanol, octyl alcohol, 3-methyl-3-methoxybutanol, and tert-amyl alcohol. Addition of these alcohols to the composition improves the stability of the composition.

[0398] Examples of the catalyst include acids (e.g., acetic acid, hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, sulfonic acid, p-toluenesulfonic acid, trifluoroacetic acid, etc.), bases (e.g., sodium hydroxide, potassium hydroxide, ammonia, triethylamine, diethylamine, etc.), transition metals (e.g., Ti, Ni, Sn, Zr, Al, B, Si, Ta, Nb, Mo, W, Cr, Hf, V, etc.), sulfur-containing compounds having an unshared electron pair in the molecular structure, or nitrogen-containing compounds (e.g., sulfoxide compounds, aliphatic amine compounds, aromatic amine compounds, phosphoric acid amide compounds, amide compounds, urea compounds), etc.

[0399] Examples of the aliphatic amine compounds include diethylamine, triethylamine, etc. Examples of the aromatic amine compounds include aniline, pyridine, etc.

[0400] In a preferred embodiment, the transition metal is contained as a transition metal compound represented by M-R (wherein M is a transition metal atom and R is a hydrolyzable group). By using a transition metal compound in which a transition metal is bonded to a hydrolyzable group, the transition metal atom can be contained more efficiently in the surface treatment layer, and the friction durability and chemical resistance of the surface treatment layer can be further improved.

[0401] The hydrolyzable group means a group that can undergo a hydrolysis reaction, similar to the hydrolyzable group in the above-mentioned compound, that is, a group that can be separated from a transition metal atom by a hydrolysis reaction. Examples of the hydrolyzable group include -OR ｍ , -OCOR ｍ, —O—N═CR ｍ ２ , -NR ｍ ２ , -NHR ｍ , —NCO, halogen (wherein R ｍ is a substituted or unsubstituted C １－４ (representing an alkyl group) and the like.

[0402] In a preferred embodiment, the hydrolyzable group is —OR ｍ By using an alkoxy group as the hydrolyzable group, transition metal atoms can be more efficiently incorporated into the surface treatment layer, and the friction durability and chemical resistance of the surface treatment layer can be further improved.

[0403] In one embodiment, the hydrolyzable group may be the same as the hydrolyzable group contained in the compound described above. By using the same hydrolyzable group in the compound and the transition metal compound, even if the hydrolyzable groups are exchanged with each other, the effect can be reduced.

[0404] In another embodiment, the hydrolyzable group may be different from the hydrolyzable group contained in the compound. By making the hydrolyzable groups in the compound and the transition metal compound different, the hydrolysis reactivity can be controlled.

[0405] In one embodiment, the hydrolyzable group and the hydrolyzable group contained in the compound may be interchangeable in the composition.

[0406] In a preferred embodiment, the transition metal compound is Ta(OR ｍ ) ５ (In the formula, R ｍ is a substituted or unsubstituted C １－４ is an alkyl group.), and preferably Ta(OCH ２ CH ３ ) ５ , or Si(OR ｍ ) １－ｍ１ R ｍ’ ｍ１ (In the formula, R ｍ is a substituted or unsubstituted C １－４is an alkyl group, and R ｍ’ is C １－４ is an alkyl group, and m1 is 0 or 1.), and preferably tetraethoxysilane, methyltrimethoxysilane, methyltriethoxysilane, tetraisopropoxysilane, dimethyldiethoxysilane, or dimethyldimethoxysilane.

[0407] The catalyst may be contained in an amount of, for example, 0.0002% by mass or more relative to the total composition. The catalyst is preferably contained in an amount of 0.02% by mass or more, more preferably 0.04% by mass or more, relative to the total composition. The catalyst may be contained in an amount of, for example, 10% by mass or less, particularly 1% by mass or less, relative to the total composition. The composition of the present disclosure may contribute to the formation of a surface treatment layer with better durability by containing the catalyst at the above-mentioned concentration.

[0408] The content of the catalyst is preferably 0 to 10% by mass, more preferably 0 to 5% by mass, and particularly preferably 0 to 1% by mass, based on the compound of the present disclosure.

[0409] The catalyst promotes the hydrolysis and dehydration condensation of the compounds of the present disclosure, and promotes the formation of the layer formed by the composition of the present disclosure.

[0410] In addition to the above, other components include, for example, tetraethoxysilane, methyltrimethoxysilane, 3-aminopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, methyltriacetoxysilane, and the like.

[0411] In addition to the components described above, the composition of the present disclosure may contain trace amounts of impurities such as Pt, Rh, Ru, 1,3-divinyltetramethyldisiloxane, triphenylphosphine, NaCl, KCl, and silane condensates.

[0412] In one embodiment, the compositions of the present disclosure are for dry coating processes, preferably vacuum deposition.

[0413] In one embodiment, the compositions of the present disclosure are for use in wet coating methods, preferably dip coating.

[0414] The compositions of the present disclosure can be impregnated into porous materials, such as porous ceramic materials, metal fibers, such as steel wool, and formed into pellets, which can be used, for example, in vacuum deposition.

[0415] The composition of the present disclosure is preferably used as a surface treatment agent or as a component of a surface treatment agent.

[0416] The articles of the present disclosure are described below.

[0417] The article of the present disclosure includes a substrate and a layer (surface treatment layer) formed on the surface of the substrate from the surface treatment agent of the present disclosure.

[0418] Substrates that can be used in the present disclosure may be made of any suitable material, such as glass, resin (which may be a natural or synthetic resin, for example, a common plastic material), metal, ceramics, semiconductors (silicon, germanium, etc.), fibers (woven fabrics, nonwoven fabrics, etc.), fur, leather, wood, ceramics, stone, etc., building materials, etc., sanitary products, etc.

[0419] For example, when the article to be manufactured is an optical component, the material constituting the surface of the substrate may be a material for optical components, such as glass or transparent plastic. When the article to be manufactured is an optical component, some layer (or film), such as a hard coat layer or an anti-reflection layer, may be formed on the surface (outermost layer) of the substrate. The anti-reflection layer may be either a single-layer anti-reflection layer or a multi-layer anti-reflection layer. Examples of inorganic materials that can be used for the anti-reflection layer include SiO ２ , SiO, ZrO ２ , TiO ２ , TiO, Ti ２ O ３ , Ti ２ O ５ , Al ２ O ３ , Ta ２ O ５ , Ta ３ O ５ , Nb ２ O ５ , HfO ２ , Si ３ N ４ , CeO ２, MgO, Y ２ O ３ , SnO ２ , MgF ２ , W.O. ３ These inorganic substances may be used alone or in combination of two or more (for example, as a mixture). In the case of a multi-layer antireflection layer, the outermost layer may contain SiO ２ and / or SiO is preferably used. When the article to be manufactured is an optical glass component for a touch panel, a transparent electrode, for example, a thin film using indium tin oxide (ITO) or indium zinc oxide, may be provided on a portion of the surface of the substrate (glass). Furthermore, the substrate may have an insulating layer, an adhesive layer, a protective layer, a decorative frame layer (I-CON), an atomization film layer, a hard coating film layer, a polarizing film, a phase difference film, a liquid crystal display module, or the like, depending on its specific specifications.

[0420] The shape of the substrate is not particularly limited and may be, for example, a plate, a film, or other form. The surface region of the substrate on which the surface treatment layer is to be formed may be at least a part of the substrate surface, and may be appropriately determined depending on the use and specific specifications of the product to be manufactured.

[0421] In one embodiment, at least the surface portion of such a substrate may be made of a material that originally contains hydroxyl groups. Examples of such materials include glass, metals (especially base metals), ceramics, semiconductors, and the like, on whose surfaces native oxide or thermal oxide films form. Alternatively, in cases where the presence of hydroxyl groups is insufficient, such as in resins, or in cases where hydroxyl groups are not originally present, some kind of pretreatment can be performed on the substrate to introduce or increase the number of hydroxyl groups on the substrate surface. Examples of such pretreatments include plasma treatment (e.g., corona discharge) and ion beam irradiation. Plasma treatment can introduce or increase hydroxyl groups on the substrate surface, and can also be suitably used to clean the substrate surface (remove foreign matter, etc.). Another example of such pretreatment is a method in which an interfacial adsorbent having carbon-carbon unsaturated bond groups is preliminarily formed in the form of a monomolecular film on the substrate surface by the Langmuir-Blodgett method (LB method) or chemical adsorption method, and then the unsaturated bonds are cleaved in an atmosphere containing oxygen, nitrogen, or the like.

[0422] In another embodiment, at least the surface portion of such a substrate may be made of a material containing another reactive group, such as a silicone compound having one or more Si—H groups, or an alkoxysilane.

[0423] In a preferred embodiment, the substrate is glass, such as sapphire glass, soda-lime glass, alkali aluminosilicate glass, borosilicate glass, alkali-free glass, crystal glass, quartz glass, and crystallized glass, with chemically strengthened soda-lime glass, chemically strengthened alkali aluminosilicate glass, and chemically bonded borosilicate glass being particularly preferred.

[0424] In one embodiment, the article of the present disclosure may include an intermediate layer containing silicon oxide between the glass and the surface treatment layer. By providing such an intermediate layer, adhesion between the glass and the surface treatment layer is improved, and durability is improved.

[0425] In a preferred embodiment, the intermediate layer may contain an alkali metal in addition to silicon oxide.

[0426] Examples of the alkali metal include lithium, sodium, potassium, etc. The alkali metal is preferably sodium.

[0427] The thickness of the intermediate layer is not particularly limited, but is preferably 1 to 200 nm, and particularly preferably 1 to 20 nm. By making the thickness of the intermediate layer equal to or greater than the lower limit of the above range, the effect of the intermediate layer in improving adhesiveness becomes greater.

[0428] The alkali metal atom concentration in the intermediate layer can be measured by various surface analysis devices, such as TOF-SIMS, XPS, and XRF.

[0429] The proportion of alkali metal atoms in the total atoms of the entire intermediate layer can be obtained by XPS depth profile analysis using ion sputtering, which is performed by alternately repeating XPS measurement and surface etching by ion sputtering using an ion gun built into the XPS apparatus.

[0430] The average alkali metal concentration in the intermediate layer in a region 1 nm or less deep from the surface in contact with the surface treatment layer is determined by obtaining a depth profile of the alkali metal atom concentration by TOF-SIMS (time-of-flight secondary ion mass spectrometry) depth profile analysis using ion sputtering, and then calculating the average alkali metal atom concentration in the profile. The TOF-SIMS depth profile analysis using ion sputtering is performed by alternately repeating TOF-SIMS measurement and surface etching by ion sputtering using an ion gun built into the TOF-SIMS device.

[0431] The article of the present disclosure can be produced by forming a layer of the surface treatment agent of the present disclosure on the surface of the substrate, and then post-treating this layer as necessary, thereby forming a layer from the surface treatment agent of the present disclosure.

[0432] The layer formation of the surface treatment agent of the present disclosure can be carried out by applying the surface treatment agent to the surface of a substrate so as to coat the surface. The coating method is not particularly limited. For example, a wet coating method or a dry coating method can be used.

[0433] Examples of wet coating methods include dip coating, spin coating, flow coating, spray coating, roll coating, gravure coating, wipe coating, squeegee coating, die coating, ink jet, casting, Langmuir-Blodgett coating, and similar methods.

[0434] Examples of dry coating methods include vapor deposition (usually vacuum deposition), sputtering, CVD, and similar methods. Specific examples of vapor deposition methods (usually vacuum deposition) include resistance heating, electron beam, high frequency heating using microwaves, etc., ion beam, and similar methods. Specific examples of CVD methods include plasma-CVD, optical CVD, thermal CVD, and similar methods.

[0435] Furthermore, coating by atmospheric pressure plasma method is also possible.

[0436] When using the wet coating method, the surface treatment agent of the present disclosure can be diluted with a solvent and then applied to the surface of a substrate. From the viewpoint of the stability of the composition of the present disclosure and the volatility of the solvent, the following solvents are preferably used: aliphatic hydrocarbons such as hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, mineral spirits, etc.; aromatic hydrocarbons such as benzene, toluene, xylene, naphthalene, solvent naphtha, etc.; methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, cellosolve acetate, propylene glycol methyl ether acetate, carbohydrate acetate, etc. Esters such as ethanol, diethyl oxalate, ethyl pyruvate, ethyl 2-hydroxybutyrate, ethyl acetoacetate, amyl acetate, methyl lactate, ethyl lactate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 2-hydroxyisobutyrate, and ethyl 2-hydroxyisobutyrate; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, 2-hexanone, cyclohexanone, methyl amino ketone, and 2-heptanone; ethyl cellosolve, methyl cellosol glycol ethers such as propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monobutyl ether acetate, dipropylene glycol dimethyl ether, and ethylene glycol monoalkyl ethers; alcohols such as methanol, ethanol, iso-propanol, n-butanol, isobutanol, tert-butanol, sec-butanol, 3-pentanol, octyl alcohol, 3-methyl-3-methoxybutanol, and tert-amyl alcohol; glycols such as ethylene glycol and propylene glycol; cyclic ethers such as tetrahydrofuran, tetrahydropyran, and dioxane; amides such as N,N-dimethylformamide, N,N-dimethylacetamide, and N-methylpyrrolidone;Ether alcohols such as methyl cellosolve, cellosolve, isopropyl cellosolve, butyl cellosolve, and diethylene glycol monomethyl ether; diethylene glycol monoethyl ether acetate; polyfluoroaromatic hydrocarbons (e.g., 1,3-bis(trifluoromethyl)benzene); polyfluoroaliphatic hydrocarbons (e.g., C; ６ F １３ CH ２ CH ３ (For example, Asahiklin (registered trademark) AC-6000 manufactured by Asahi Glass Co., Ltd.), C ６ F １３ H (for example, Asahiklin (registered trademark) AC-2000 manufactured by Asahi Glass Co., Ltd.), 1,1,2,2,3,3,4-heptafluorocyclopentane (for example, Zeorora (registered trademark) H manufactured by Zeon Corporation); fluorine-containing hydrocarbons such as 1,1,2-trichloro-1,2,2-trifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane (HCFC225), and 1,3-bis(trifluoromethyl)benzene; CF ３ CH ２ OH, CF ３ CF ２ CH ２ OH, (CF ３ ) ２ fluorine-containing alcohols such as CHOH; hydrofluoroethers (HFEs) (for example, perfluoropropyl methyl ether (C ３ F ７ OCH ３ ) (e.g., Novec (trademark) 7000 manufactured by Sumitomo 3M Limited), perfluorobutyl methyl ether (C ４ F ９ OCH ３ ) (e.g., Novec (trademark) 7100 manufactured by Sumitomo 3M Limited), perfluorobutyl ethyl ether (C ４ F ９ O.C. ２ H ５ ) (e.g., Novec (trademark) 7200 manufactured by Sumitomo 3M Limited), perfluorohexyl methyl ether (C ２ F ５ CF (OCH３ ) C ３ F ７ ) (e.g., Novec™ 7300 manufactured by Sumitomo 3M Limited) (the perfluoroalkyl group and the alkyl group may be linear or branched), or CF ３ CH ２ OCF ２ CHF ２ (e.g., Asahiklin (registered trademark) AE-3000 manufactured by Asahi Glass Co., Ltd.), hydrofluoroolefins; CF ３ CH═CHCl (e.g., CELEFIN® 1233Z manufactured by Central Glass Co., Ltd.), CHF ２ethers such as CF═CHCl (for example, AMOLEA (registered trademark) AS-300 manufactured by Asahi Glass Co., Ltd.) and cyclopentyl methyl ether; siloxanes such as hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclopentasiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and tetradecamethylhexasiloxane; and dimethyl sulfoxide. These solvents can be used alone or as a mixture of two or more. Of these, aliphatic hydrocarbons, esters, glycol ethers, alcohols, ether alcohols, and siloxanes are preferred. For example, hexane, cyclohexane, heptane, octane, nonane, decane, undecane, dodecane, mineral spirits, methyl acetate, ethyl acetate, propyl acetate, n-butyl acetate, isopropyl acetate, isobutyl acetate, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, methanol, ethanol, isopropanol, n-butanol, isobutanol, tert-butanol, sec-butanol, diethylene glycol monomethyl ether, hexamethyldisiloxane, hexaethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, tetradecamethylhexasiloxane, octamethylcyclotetrasiloxane, and octamethylcyclopentasiloxane are particularly preferred.

[0437] In one embodiment, when using the wet coating method, the solvent is, for example, R ９０ A compound represented by —OH can be used. ９０ is a monovalent organic group, preferably C １－２０ Alkyl group or C ３－２０ The alkylene group may be substituted with one or more substituents. Examples of the substituents include a hydroxyl group, -OR ９１ (where R ９１ is C １－１０ Alkyl group, preferably C １－３alkyl groups, such as methyl groups.

[0438] When the dry coating method is used, the surface treatment agent of the present disclosure may be subjected to the dry coating method as it is, or may be subjected to the dry coating method after being diluted with the above-mentioned solvent.

[0439] The layer formation of the surface treatment agent is preferably carried out so that the surface treatment agent of the present disclosure is present in the layer together with a catalyst for hydrolysis and dehydration condensation. Conveniently, in the case of a wet coating method, the surface treatment agent of the present disclosure may be diluted with a solvent, and then a catalyst may be added to the diluted solution of the surface treatment agent of the present disclosure immediately before application to the substrate surface. In the case of a dry coating method, the surface treatment agent of the present disclosure to which the catalyst has been added may be directly subjected to vapor deposition (usually vacuum deposition), or a pellet-shaped material impregnated with the surface treatment agent of the present disclosure to which the catalyst has been added may be subjected to vapor deposition (usually vacuum deposition) on a porous metal such as iron or copper.

[0440] The catalyst may be any appropriate acid or base, transition metal (e.g., Ti, Ni, Sn, Zr, Al, B, etc.), sulfur-containing compound having an unshared electron pair in its molecular structure, or nitrogen-containing compound (e.g., sulfoxide compound, aliphatic amine compound, aromatic amine compound, phosphoric acid amide compound, amide compound, urea compound), etc. Examples of acid catalysts that can be used include acetic acid, formic acid, trifluoroacetic acid, hydrochloric acid, nitric acid, sulfuric acid, phosphoric acid, sulfonic acid, methanesulfonic acid, p-toluenesulfonic acid, etc. Examples of base catalysts that can be used include ammonia, sodium hydroxide, potassium hydroxide, and organic amines such as triethylamine and diethylamine. Examples of transition metals, aliphatic amine compounds, and aromatic amine compounds are the same as those described above.

[0441] The surface treatment layer included in the article of the present disclosure can have high abrasion resistance. In addition to high abrasion resistance, the surface treatment layer can have water repellency, oil repellency, antifouling properties (for example, preventing adhesion of stains such as fingerprints), waterproof properties (preventing water penetration into electronic components, etc.), surface slipperiness (or lubricity, for example, ease of wiping off stains such as fingerprints and excellent tactile feel), chemical resistance, etc., depending on the composition of the surface treatment agent used, and can be suitably used as a functional thin film.

[0442] Therefore, the present disclosure also relates to an optical material having the above-described surface treatment layer as the outermost layer.

[0443] Preferred examples of the optical material include optical materials relating to displays and the like, such as those exemplified below, as well as a wide variety of other optical materials: for example, displays such as cathode ray tubes (CRTs; for example, personal computer monitors), liquid crystal displays, plasma displays, organic EL displays, inorganic thin-film EL dot matrix displays, rear projection displays, vacuum fluorescent displays (VFDs), and field emission displays (FEDs), or protective plates for such displays, or displays whose surfaces have been treated with an anti-reflection film.

[0444] The article of the present disclosure may be, but is not particularly limited to, an optical member. Examples of optical members include lenses for eyeglasses and the like; front protective plates, anti-reflection plates, polarizing plates, and anti-glare plates for displays such as PDPs and LCDs; touch panel sheets for devices such as mobile phones and personal digital assistants; disc surfaces of optical discs such as Blu-ray (registered trademark) discs, DVD discs, CD-Rs, and MOs; optical fibers; and the display surfaces of watches and clocks.

[0445] The article of the present disclosure may also be a medical device or medical material. The article having a layer obtained by the present disclosure may also be an automobile interior or exterior component. Examples of exterior components include windows, light covers, and exterior camera covers. Examples of interior components include instrument panel covers, navigation system touch panels, and decorative interior components.

[0446] The thickness of the layer is not particularly limited. In the case of an optical member, the thickness of the layer may be, for example, in the range of 1 to 50 nm, preferably 1 to 30 nm, and more preferably 1 to 15 nm, from the viewpoints of optical performance, abrasion resistance, and antifouling properties.

[0447] An X-ray photoelectron spectroscopy (XPS) instrument, manufactured by ULVAC-PHI, Inc., PHI5000 VersaProbe II, can be used to measure the atomic composition and atomic ratios of the surface treatment layer. XPS analysis conditions include a monochromated AlKα X-ray source at 25 W, a photoelectron detection area of ​​1400 μm × 300 μm, a photoelectron detection angle in the range of 20 to 90 degrees (e.g., 20, 45, or 90 degrees), and a pass energy of 23.5 eV. Gas cluster ion beams or Ar ions can be used for sputtering. Using the above instrument and measurement conditions, the peak areas of C1s, O1s, and Si2p can be observed, and the atomic ratios of carbon, oxygen, and silicon can be calculated to determine the composition of the surface treatment layer and intermediate layer.

[0448] Depth analysis can also be performed. Measurement conditions for XPS analysis include using a monochromated AlKα ray at 25 W as the X-ray source, a photoelectron detection area of ​​1400 μm × 300 μm, a photoelectron detection angle in the range of 20 to 90 degrees (e.g., 20, 45, or 90 degrees), and a pass energy of 23.5 eV. Ar ions, gas cluster ions, or C ions can be used as sputtering ions. Sputtering can be performed by etching 1 to 100 nm, and the composition of the coating film at each etching depth can be obtained.

[0449] The detection depth can be adjusted appropriately by adjusting the photoelectron detection angle in the XPS analysis. For example, a shallow angle close to 20 degrees can achieve a detection depth of about 3 nm, while a deep angle close to 90 degrees can achieve a detection depth of about 10-odd nm.

[0450] The intermediate layer containing silicon oxide can be formed by applying a silicon oxide precursor to the surface of the substrate. When the intermediate layer contains an alkali metal, the intermediate layer can be formed by applying a composition containing a silicon oxide precursor and an alkali metal source to the surface of the substrate.

[0451] Examples of the silicon oxide precursor include silicic acid, partial condensates of silicic acid, alkali metal silicates, silane compounds having a hydrolyzable group bonded to a silicon atom, and partial hydrolysis condensates of the silane compounds. Silicic acid and its partial condensates can be converted into silicon oxide by dehydration condensation. Alkali metal silicates can be converted into silicic acid or its partial condensates by the addition of an acid or a cation exchange resin, and the resulting silicic acid or its partial condensates can then be dehydration condensed into silicon oxide. Examples of the hydrolyzable group in a silane compound having a hydrolyzable group bonded to a silicon atom include an alkoxy group and a chlorine atom. The hydrolyzable group in the silane compound can be hydrolyzed to a hydroxyl group, and the resulting silanol compound can be dehydration condensed to form silicon oxide. Examples of silane compounds having a hydrolyzable group bonded to a silicon atom include alkoxysilanes such as tetraalkoxysilanes and alkyltrialkoxysilanes, and tetrachlorosilane.

[0452] Examples of the alkali metal source include alkali metal hydroxides, water-soluble alkali metal salts, etc. Examples of the water-soluble alkali metal salts include alkali metal carbonates, alkali metal hydrogencarbonates, alkali metal hydrochlorides, alkali metal nitrates, etc. As the alkali metal source, alkali metal hydroxides and alkali metal carbonates are preferred.

[0453] Alkali metal silicates can be used as silicon oxide precursors and alkali metal sources. Alkali metal silicates can be converted to silicon oxide via silicic acid, but a small amount of alkali metal may remain in the resulting silicon oxide. Therefore, by adjusting the amount of the remaining alkali metal, silicon oxide containing a desired amount of alkali metal atoms can be obtained.

[0454] The thickness of the intermediate layer is not particularly limited, but is, for example, in the range of 1 to 50 nm, preferably 1 to 30 nm, more preferably 2 to 15 nm, and even more preferably 3 to 10 nm.

[0455] The compounds, compositions, and articles of the present disclosure have been described in detail above. However, the compounds, compositions, and articles of the present disclosure are not limited to those exemplified above.

[0456] The present disclosure will be described below with reference to examples, but the present disclosure is not limited to the following examples.

[0457] (Synthesis Example 1) CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ 3.00 g of HCl (the average number of repeating units n is 12.0), 1.00 g of potassium tert-butoxide, 3.78 mL of allyl bromide, and 4.80 mL of tetrahydrofuran were added, and the mixture was heated to 40° C. and stirred for 7 hours. Thereafter, the mixture was concentrated under reduced pressure to obtain compound (1) CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２ OCH ２ CH=CH ２ (The average value of the number of repeating units n is 12.0) 2.30 g was obtained.

[0458] 1 H NMR (CDCl3, 400 MHz) δ[ppm]: -0.106-0.223 (m), 0.414-0.541 (m), 0.866-0.894 (m), 1.123-1.319 (m), 1.554-1.639 (m), 3.375-3.441 (m), 3.594-3.602 (m), 5.166-5.299(dd), 5.874-5.968 (m)

[0459] (Synthesis Example 2) 0.50 g of compound (1), 1.00 mL of toluene, and 25 μL of a xylene solution containing 2% Pt complex of 1,3-divinyl-1,1,3,3-tetramethyldisiloxane were added, followed by stirring at room temperature for 30 minutes. Then, 13.5 μL of aniline and 177.5 μL of trimethoxysilane were added, followed by heating to 45° C. and stirring for 4 hours. Thereafter, the mixture was purified to obtain compound (2) CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２ OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (The average value of the number of repeating units n is 11.8) was obtained in an amount of 0.48 g.

[0460] 1 H NMR (CDCl3, 400 MHz) δ[ppm]: -0.098-0.231 (m), 0.523-0.563 (m), 0.652-0.693 (m), 0.872-0.907 (m), 1.290-1.327 (m), 1.581-1.734 (m), 3.388-3.466 (m), 3.569-3.581 (m)

[0461] (Surface Treatment Agent 1) The compound (2) obtained above was diluted to a concentration of 10 wt % in hexamethyldisiloxane, thereby obtaining a surface treatment agent 1.

[0462] Synthesis Example 3: 14.2 g of 14-hydroxy-3,6,9,12-tetraoxatetradecyl p-toluenesulfonate, 6.90 g of 4-bromophenol, 305 mL of acetonitrile, and 5.52 g of potassium carbonate were added to a glass flask, and the flask was then heated in an oil bath until the internal temperature reached 80°C, followed by stirring for 5 hours. After cooling to room temperature, the mixture was filtered, and the filtrate was concentrated to obtain a pale orange oil. This was purified by silica gel column chromatography (eluent: ethyl acetate, methanol) to obtain 13.9 g of compound (3) as a colorless oil.

[0463] 1H-NMR (400 MHz, Chloroform-D) δ 7.36 (d, J = 8.8 Hz, 2H), 6.80 (d, J = 8.8 Hz, 2H), 4.10 (t, J = 4.8 Hz, 2H), 3.73 (t, J = 4.8 Hz, 2H), 3.80-3.59 (m, 16H), 2.74 (brs, 1H)

[0464] Compound (3)

[0465] Synthesis Example 84: To a glass flask, 13.1 g of compound (3) and 250 mL of tetrahydrofuran were added, and the flask was placed in an ice bath to bring the internal temperature to 2°C. Then, 6.01 g of sodium hydride (60% paraffin oil dispersion) and 15.3 g of 11-bromo-1-undecene were added to the flask, and the flask was placed in an oil bath to bring the internal temperature to 70°C and stirred for 12 hours. After cooling to room temperature, water and ethyl acetate were added to the flask and stirred. The solution was transferred to a separatory funnel and the aqueous layer was removed. The remaining organic layer was washed twice with water, dried over magnesium sulfate, and concentrated under reduced pressure to obtain an orange oil. This was purified by silica gel column chromatography (eluent: heptane, ethyl acetate) to obtain 11.9 g of compound (4) as a pale yellow oil.

[0466] 1H-NMR (400 MHz, Chloroform-D) δ 7.38 (d, J = 8.8 Hz, 2H), 6.82 (d, J = 8.8 Hz, 2H),4.15 (t, J = 4.8 Hz, 2H), 3.83 (t, J = 5.0 Hz, 2H), 3.75-3.72 (m, 2H), 3.69-3.63 (m, 12H), 3.59-3.56 (m, 2H), 3.40 (t, J = 6.6 Hz, 2H), 2.00 (m, 2H), 1.60-1.55 (m, 2H), 1.41-1.19 (m, 14H)

[0467] Compound (4)

[0468] Synthesis Example 5: 1.0 g of compound (4) and 7 mL of tetrahydrofuran were added to a glass flask. The flask was then placed in a dry ice / acetone bath, and 1.23 mL of a hexane solution containing 15% n-butyllithium was added dropwise. The mixture was stirred with a magnetic stirrer for 1 hour. Subsequently, 9 mL of a tetrahydrofuran solution containing 1.55 g of hexamethylcyclotrisiloxane was added dropwise to the flask, and the mixture was stirred at room temperature for 4 hours. Subsequently, 0.59 g of 3-chloro-1,1,1,3,5,5,5-heptamethyltrisiloxane was added to the flask, and the mixture was stirred at room temperature for 18 hours. The reaction solution was concentrated under reduced pressure, and the residue was purified by silica gel column chromatography (eluent: chloroform) to obtain a pale yellow oil. This oil was washed with acetonitrile and concentrated under reduced pressure to obtain 1.80 g of compound (5) as a pale yellow oil. The average number of repeating units was 12.

[0469] 1H-NMR (400 MHz, Chloroform-D) δ 7.47 (d, J = 8.2 Hz, 2H), 6.91 (d, J = 8.7 Hz, 2H), 5.86-5.76 (m, 1H), 5.02-4.91 (m, 2H), 4.14 (t, J = 4.8 Hz, 2H), 3.86 (t, J = 5.0 Hz, 2H), 3.75-3.72 (m, 2H), 3.69-3.63 (m, 12H), 3.59-3.56 (m, 2H), 3.44 (t, J = 6.6 Hz, 2H), 2.04 (q, J = 7.0 Hz, 2H), 1.59-1.54 (m, 2H), 1.39-1.20 (m, 14H), 0.32 (s, 6H), 0.25--0.13 (m)

[0470] Compound (5)

[0471] Synthesis Example 6 A glass flask was charged with a stirrer tip, 1.80 g of compound (5), 91 μL of a xylene solution containing 2% Pt complex of 1,3-divinyl-1,1,3,3-tetramethyldisiloxane, 13 μL of pyridine, 0.46 mL of trimethoxysilane, and 10 mL of toluene, and the mixture was stirred at room temperature with a magnetic stirrer for 4 hours. The mixture was then concentrated under reduced pressure to obtain 1.83 g of compound (6) as a pale yellow oil. The average number of repeating units was 12.

[0472] 1H-NMR (400 MHz, Chloroform-D) δ 7.47 (d, J = 8.7 Hz, 2H), 6.91 (d, J = 8.7 Hz, 2H), 4.14 (t, J = 5.0 Hz, 2H), 3.86 (t, J = 5.0 Hz, 2H), 3.74-3.72 (m, 2H), 3.69-3.62 (m, 12H), 3.60-3.54 (m, 11H), 3.44 (t, J = 6.9 Hz, 2H), 1.59-1.55 (m, 2H), 1.41-1.39 (m, 2H), 1.33-1.26 (m, 14H), 0.66-0.62 (m, 2H), 0.31 (s, 6H), 0.25--0.07 (m)

[0473] Compound (6)

[0474] (Surface Treatment Agent 2) The compound (6) obtained above was diluted to a concentration of 10 wt % in hexamethyldisiloxane, thereby obtaining a surface treatment agent 2.

[0475] (Comparative Example) (Surface Treatment Agent A) CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ ] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CH ２ CONHCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (The average number of repeating units n was 10) was diluted to a 10 wt % hexamethyldisiloxane solution to obtain surface treatment agent A.

[0476] (Na-containing intermediate layer forming material) 2.2 g of sodium hydroxide (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.) was dissolved in 24 g of distilled water to obtain an 8.4 mass% sodium hydroxide aqueous solution. 24 g of this 8.4 mass% sodium hydroxide aqueous solution was mixed with 20 g of MS gel (MSGEL D-100-60A (manufactured by AGC Si-Tech Co., Ltd.)), and the sodium hydroxide aqueous solution was absorbed into the MS gel. The MS gel that had absorbed the sodium hydroxide aqueous solution was dried at 25 ° C. for 8 hours, then molded using a tablet molding machine (4 MPa for 1 minute) and baked at 1,000 ° C. for 1 hour to obtain molded body 1 (pellet).

[0477] (Formation of Surface Treatment Layer) (Example 1 and Comparative Example 1) The surface treatment agent 1 and the surface treatment agent A prepared above were vacuum-deposited on chemically strengthened glass (Gorilla Glass, manufactured by Corning Incorporated, thickness 0.7 mm). Specifically, 0.1 g of the surface treatment agent was filled into a molybdenum boat in a vacuum deposition apparatus, and the inside of the vacuum deposition apparatus was pressurized to a pressure of 3.0 × 10 －３ The chamber was evacuated to a pressure of 100 Pa or less. Thereafter, a silicon dioxide film containing Na was formed to a thickness of 7 nm by electron beam evaporation using the molded body 1, and the boat was subsequently heated by resistance heating to form a surface treatment layer. Thereafter, a heat treatment was carried out in an oven at 150°C for 2 hours, thereby obtaining a surface treatment layer.

[0478] <Evaluation> [Weather Resistance Evaluation] (Initial Evaluation) For the initial evaluation (before UV irradiation), after the formation of the surface treatment layer, the excess water on the surface was wiped off, and then the static contact angle of water was measured. The contact angle was measured in a 25°C environment using a fully automatic contact angle meter DropMaster 700 (manufactured by Kyowa Interface Science Co., Ltd.). Specifically, the substrate having the surface treatment layer to be measured was placed horizontally, water was dropped onto the surface from a microsyringe, and a still image was taken with a video microscope 1 second after the drop to measure the static contact angle. The static contact angle was measured at five different points on the surface treatment layer of the substrate, and the average value was calculated.

[0479] (Evaluation after Weathering Test) A weathering test was conducted on the formed surface treatment layer. The accelerated weathering test is a test in which UV irradiation is performed as follows. UV irradiation was performed using a 7.5 kW xenon lamp (manufactured by Suga Test Instruments, irradiance 62 W / m2 at 300 to 400 nm), with the distance between the lamp and the surface treatment layer of the substrate set to 290 mm, and the temperature of the plate on which the substrate was placed was 55°C and humidity 55%. After 300 hours of UV irradiation, the surface treatment layer was wiped with Kimwipes (trade name, manufactured by Jujo Kimberly Co., Ltd.) thoroughly soaked in ethanol and then dried. Immediately thereafter, the static contact angle of water was measured. The evaluation results are shown in Table 1 below.

[0480]

[0481] The surface treatment agent of the present disclosure can be suitably used in a wide variety of applications.

Claims

1. The following formula (1): [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which a hydroxyl group or a hydrolyzable group is not directly bonded, １ is a divalent to decavalent group containing two or more ether bonds, R Ｓｉ is a monovalent group containing a Si atom having a hydroxyl group or a hydrolyzable group bonded thereto, and α is an integer of 1 to 9.

2. R Ｓ is R １ -R Ｓ１ -(SiR ２ ２ ) ｓ - and R １ is a hydrocarbon group, or R １ａ ｎａ R １ｂ ３－ｎａ Si-(O) ｚ -: R １ａ are each independently R １ｄ -(SiR １ｄ ２ -R １ｃ ) ｍａ -, R １ｃ each independently represents an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently a hydrocarbon group or R １ａ’ And R １ａ’ is R １ａ Each ma is independently an integer of 1 to 5, １ａ Medium, R １ａ’ The number of is 20 or less, and R １ｂ are each independently a hydrocarbon group, na is an integer of 1 to 3, z is 0 or 1, and R Ｓ１ are each independently a single bond or a group represented by the following formula: (In the formula: R ３ are each independently １－１２ Alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - and R ４ are each independently １－１２ Alkylene group, -R ６ -O-R ６ -, -R ８ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ７ -R ８ -, -R ８ -R ７ -R ９ -R ６ -R ９ -R ７ -R ８ - or -R ９ -R ６ -R ９ -R ７ -R ９ -R ６ -R ９ - and R ６ are each independently １－６ is an alkylene group, R ７ each independently represents an optionally substituted arylene group; R ８ each independently represents a single bond or C １－６ is an alkylene group, R ９ are each independently a single bond or an oxygen atom; R ５ are each independently a hydrocarbon group, x is an integer from 0 to 200, y is an integer from 0 to 200, z is an integer from 0 to 200, x+y+z is 1 or more, and the order of occurrence of each repeating unit enclosed in parentheses with x, y, or z is arbitrary in the formula. ２ The compound according to claim 1 , wherein each is independently a hydrocarbon group; and s is 0 or 1.

3. R １ is R １ａ ｎａ R １ｂ ３－ｎａ Si—O—, R １ａ are each independently -(R １ｃ -SiR １ｄ ２ ) ｍａ -R １ｄ R is a group represented by １ｃ each independently represents an oxygen atom or C １－６ is an alkylene group, R １ｄ are each independently a hydrocarbon group or R １ａ’ And R １ａ’ is R １ａ Each ma is independently an integer of 1 to 5, １ａ Medium, R １ａ’ The number of is 20 or less, and R １ｂ The compound according to claim 2, wherein each of the groups is independently a hydrocarbon group, na is an integer of 1 to 3, and is a group represented by the formula:

4. R １ａ are each independently -(OSiR １ｄ ２ ) ｍａ -R １ｄ R is a group represented by １ｄ are each independently a hydrocarbon group or R １ａ’ Each ma is independently 1 or 2; R １ｂ The compound according to claim 2, wherein each of the groups is independently a hydrocarbon group, and na is an integer of 1 to 3.

5. R １ｄ is C １－４ The compound of claim 2 which is an alkyl group.

6. X １ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ The compound according to claim 1, comprising a group represented by the formula: - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 30, and z1 is 0 or 1).

7. X １ is -(O) ｚ１ - [CH ２ CH ２ O] ｎｃ The compound according to claim 1, comprising a group represented by the formula: - (wherein nc is an integer of 1 to 8, and z1 is 0 or 1).

8. X １ can further include alkylene, phenylene, -CO-, -COO-, -NR ｘ１ --, --CONR ｘ１ --, --OCONR ｘ１ --, --NR ｘ１ -CO-NR ｘ１ -, -O-, -S-, -O-(CH ２ ) ｘ１ -CONR ｘ１ -, or -O-(CH ２ ) ｘ１ is a divalent organic group containing —CO—, ｘ１ is a hydrogen atom or C １－６ The compound according to claim 1 , wherein: x1 is an alkyl group; and x1 is an integer from 1 to 20.

9. X １ is represented by the following formula: １１ -X １２ -X １３ - [In the formula: X １１ is a single bond or a divalent group, X １２ is -(O) ｚ１ - [(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 1 to 10, nc is an integer of 1 to 8, and z1 is 0 or 1), １３ is a single bond or a divalent group.

10. R Ｓｉ is represented by the following formula (S1), (S2), (S3), (S4), or (S5): [In the formula: R １１ are each independently a hydroxyl group or a hydrolyzable group; R １２ are each independently a monovalent organic group, and n1 is (SiR １１ ｎ１ R １２ ３－ｎ１ ) each independently represents an integer of 0 to 3 for each unit; １１ are each independently a single bond or a divalent organic group; R １３ are each independently a hydrogen atom or a monovalent organic group, each t is independently an integer of 2 or more, R １４ each independently represents a hydrogen atom, a halogen atom, or -X １１ -SiR １１ ｎ１ R １２ ３－ｎ１ And R １５ are each independently a single bond, an oxygen atom, an alkylene group having 1 to 6 carbon atoms, or an alkyleneoxy group having 1 to 6 carbon atoms; R ａ１ Each independently represents -Z １ -SiR ２１ ｐ１ R ２２ ｑ１ R ２３ ｒ１ and Z １ are each independently a divalent organic group; R ２１ Each independently represents -Z １’ -SiR ２１’ ｐ１’ R ２２’ ｑ１’ R ２３’ ｒ１’ and R ２２ are each independently a hydroxyl group or a hydrolyzable group; R ２３ are each independently a monovalent organic group, p1 is each independently an integer from 0 to 3, q1 is each independently an integer from 0 to 3, r1 is each independently an integer from 0 to 3, the sum of p1, q1 and r1 is 3, Z １’ are each independently a divalent organic group; R ２１’ Each independently represents -Z １” -SiR ２２” ｑ１” R ２３” ｒ１” and R ２２’ are each independently a hydroxyl group or a hydrolyzable group; R ２３’ are each independently a monovalent organic group, p1' is each independently an integer of 0 to 3, q1' is each independently an integer of 0 to 3, r1' is each independently an integer of 0 to 3, the sum of p1', q1' and r1' is 3, Z １” are each independently a divalent organic group; R ２２” are each independently a hydroxyl group or a hydrolyzable group; R ２３” are each independently a monovalent organic group, q1" is each independently an integer from 0 to 3, r1" is each independently an integer from 0 to 3, the sum of q1" and r1" is 3, R ｂ１ are each independently a hydroxyl group or a hydrolyzable group; R ｃ１ are each independently a monovalent organic group, k1 is each independently an integer of 0 to 3, l1 is each independently an integer of 0 to 3, m1 is each independently an integer of 0 to 3, the sum of k1, l1 and m1 is 3, with the proviso that in formula (S3), at least two Si atoms having a hydroxyl group or a hydrolyzable group bonded thereto are present, and R ｄ１ Each independently represents -Z ２ -CR ３１ ｐ２ R ３２ ｑ２ R ３３ ｒ２ And Z ２ are each independently a single bond, an oxygen atom, or a divalent organic group; R ３１ Each independently represents -Z ２’ -CR ３２’ ｑ２’ R ３３’ ｒ２’ And R ３２ Each independently represents -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ And R ３３ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group, p2 is each independently an integer of 0 to 3, q2 is each independently an integer of 0 to 3, r2 is each independently an integer of 0 to 3, the sum of p2, q2, and r2 is 3, Z ２’ are each independently a single bond, an oxygen atom, or a divalent organic group; R ３２’ Each independently represents -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ And R ３３’ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group, q2' are each independently an integer of 0 to 3, r2' are each independently an integer of 0 to 3, the sum of q2' and r2' is 3, Z ３ are each independently a single bond, an oxygen atom, or a divalent organic group; R ３４ are each independently a hydroxyl group or a hydrolyzable group; R ３５ are each independently a monovalent organic group; n2 is each independently an integer of 0 to 3; R ｅ１ Each independently represents -Z ３ -SiR ３４ ｎ２ R ３５ ３－ｎ２ And R ｆ１ are each independently a hydrogen atom, a hydroxyl group, or a monovalent organic group, k2 is each independently an integer of 0 to 3, l2 is each independently an integer of 0 to 3, and m2 is each independently an integer of 0 to 3. The sum of k2, l2, and m2 is 3, with the proviso that in formula (S4), there are at least two Si atoms to which a hydroxyl group or a hydrolyzable group is bonded, and R ｇ１ and R ｈ１ Each independently represents -Z ４ -SiR １１ ｎ１ R １２ ３－ｎ１ , -Z ４ -SiR ａ１ ｋ１ R ｂ１ ｌ１ R ｃ１ ｍ１ , or -Z ４ -CR ｄ１ ｋ２ R ｅ１ ｌ２ R ｆ１ ｍ２ And Z ４ are each independently a single bond, an oxygen atom, or a divalent organic group, with the proviso that in formula (S5), there are at least two Si atoms to which a hydroxyl group or a hydrolyzable group is bonded.

11. R Ｓ is represented by the following formula: １ -[Si(CH ３ ) ２ -O] ｘ -Si(CH ３ ) ２ - [wherein, R １ is an alkyl group having 1 to 6 carbon atoms or R １ａ ｎａ R １ｂ ３－ｎａ Si-(O) ｚ - and R １ａ (CH ３ ) ３ SiO-, R １ｂ is an alkyl group having 1 to 4 carbon atoms, na is 2 or 3, and x is an integer of 5 to 50. １ is represented by the following formula: １１ -X １２ -X １３ - [In the formula: X １１ is C １－６ is an alkylene group or a phenylene group; １２ is -O-[(CH ２ ) ｎｂ O] ｎｃ - (wherein nb is an integer of 2 to 4, nc is an integer of 1 to 5, and z1 is 0 or 1), １３ is C １－１２ R is an alkylene group. Ｓｉ is represented by the following formula: １１ ３ [In the formula, R １１ is -OR ｈ And R ｈ is an alkyl group having 1 to 4 carbon atoms.] and α is 1. The compound according to claim 1, 12. The compound of claim 1, which is the compound CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２ OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (Wherein, TMSO is (CH ３ ) ３ SiO-, and n is 3 to 100.

13. The compound of claim 1, which is the compound CH ３ CH ２ CH ２ CH ２ [Si(CH ３ ) ２ O] ｎ Si(CH ３ ) ２ CH ２ CH ２ CH ２ OCH ２ CH ２ OCH ２ CH ２ CH ２ Si(OCH ３ ) ３ (Wherein, TMSO is (CH ３ ) ３ SiO-, and n is 10 to 30.

14. A surface treatment agent comprising the compound according to any one of claims 1 to 13.

15. The surface treatment agent according to claim 14, further comprising a condensate of the compound according to claim 1.

16. The surface treatment agent according to claim 14, which is for vacuum deposition.

17. The surface treatment agent according to claim 14, which is for wet coating.

18. A pellet containing the surface treatment agent according to claim 14.

19. An article comprising a substrate and a layer formed on the substrate from a compound according to any one of claims 1 to 13.

20. The article of claim 19, comprising an intermediate layer between said substrate and said layer, said intermediate layer comprising silicon oxide.

21. The article of claim 20, wherein the intermediate layer comprises alkali metal atoms.

22. The article of claim 21, wherein at least a portion of the alkali metal atoms are sodium atoms.

23. The article of claim 19 which is an optical component.

24. The article of claim 19 which is a display.

25. Formula: R Ｓ -X １ａ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which a hydroxyl group or a hydrolyzable group is not directly bonded, １ａ is a divalent group containing two or more ether bonds.

26. Formula: R Ｓ -X １ａ -CONR ５１ - (CH ２ ) ｘ -CH=CH ２ [In the formula: R Ｓ is a monovalent group containing one or more Si atoms to which a hydroxyl group or a hydrolyzable group is not directly bonded, １ａ is a divalent group containing two or more ether bonds, R ５１ is a hydrogen atom or a monovalent hydrocarbon group, and x is an integer of 0 to 30.

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