Invert emulsion comprising pullulan, an apolar hydrocarbon-based oil, a lipophilic mineral thickener and a dyestuff, and makeup process using same

A water-in-oil emulsion cosmetic composition with pullulan, apolar hydrocarbon-based oil, lipophilic mineral thickener, and dyestuff addresses the challenges of matte finish compositions by providing comfort, long-lasting results, and environmental sustainability without silicone polymers.

WO2025132141A1PCT designated stage expired Publication Date: 2025-06-26LOREAL SA
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Patent Information

Application Number
PCT/EP2024/086441
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2023-12-20
Filing Date
2024-12-16
Publication Date
2025-06-26

AI Technical Summary

Technical Problem

Existing cosmetic makeup compositions that provide a matte finish often contain high levels of volatile oils and fillers, leading to discomfort, dryness, and poor staying power, while also relying on silicone film-forming polymers that consumers are increasingly looking to avoid.

Method used

A cosmetic composition in the form of a water-in-oil emulsion comprising at least 5% pullulan, 20% apolar hydrocarbon-based oil, a lipophilic mineral thickener, and a dyestuff, which provides a stable, comfortable, and long-lasting matte to satiny finish without the need for silicone polymers.

Benefits of technology

The composition achieves a stable, comfortable, and long-lasting matte to satiny finish with good staying power, without causing dryness or discomfort, and does not migrate into fine lines, while also being environmentally friendly and using more natural ingredients.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention relates to a cosmetic composition for making up human keratin materials, in particular the skin and / or the lips, preferably the lips, in the form of a water-in-oil emulsion comprising: - at least 5% by weight of pullulan; - at least 20% by weight of at least a first apolar hydrocarbon-based oil comprising from 8 to 16 carbon atoms; - at least one lipophilic mineral thickener, - at least one dyestuff. The invention also relates to a makeup process in which this composition is applied to said keratin materials.
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Description

INVERT EMULSION COMPRISING PULLULAN, AN APOLAR HYDROCARBON-BASED OIL, A LIPOPHILIC MINERAL THICKENER AND A DYESTUFF, AND MAKEUP PROCESS USING SAMEThe present invention relates to a cosmetic makeup composition, notably for the skin and / or the lips, preferably the lips, in the form of an invert emulsion (i.e. a water-in-oil emulsion) comprising at least 5% by weight of pullulan, at least one particular hydrocarbon-based oil, at least one lipophilic mineral thickener and at least one dyestuff. The invention also relates to a makeup process using such a composition.Compositions intended for application to the skin or the lips, and which provide a matte finish after application, are well known in the cosmetics field and mostly have the feature of comprising high contents of volatile oils and / or fillers. The high content of volatile oil(s) makes it possible to further increase the content of solid particles in the deposit, such as fillers and pigments, once the composition has been applied and dried. As regards the fillers used in compositions providing a matte finish, organic particles are often found, notably polymeric particles such as nylon, polytetrafluoroethylene, polyethylene, silicone resins or elastomers, or else mineral particles such as kaolin or silica for example. These fillers enable,inter alia, part of the remaining oily compounds to be absorbed, whether they originate from the composition or from the support to which it is applied (sebum). With the high contents of volatile oils and of solid particles in compositions with a matte rendering, the content of nonvolatile oils is consequently greatly reduced in the deposit after application and drying of the composition. For this reason, matte compositions are generally considered by users to be sparingly or totally uncomfortable, once they have been applied, and also to cause a more or less pronounced sensation of dryness.In addition to the color effect provided on the skin and / or the lips, it is also sought to improve the staying power and the transfer-resistance properties of the compositions. Specifically, poor staying power leads to visible premature removal of the deposit (for example, fading of the color), thus obliging the user to reapply makeup more often than desired in order to maintain appropriate coloring. It is also sought to limit the transfer of the composition onto another support (clothes, cups, etc.), which limits staining problems and contributes in the majority of cases toward maintaining good staying power of the deposit.Improving the staying power of compositions is obtained by means of compositions which form a film after application. Such compositions generally contain volatile solvents which evaporate on contact with the skin or the lips, leaving behind a layer comprising waxes and / or film-forming polymers, pigments and fillers. Film-forming polymers are synthetic polymers, usually silicone or acrylic polymers. Thus, mention may be made of the use of silicone resins, for instance trimethyl siloxysilicate (INCI name) or polypropylsilsesquioxane (INCI name) resins, or resins which comprise silicone polymers such as silicone acrylate dendrimer copolymers (acrylates / polytrimethyl siloxymethacrylate copolymer - INCI name). Acrylic polymers such as acrylic acid / isobutyl acrylate / isobornyl acrylate copolymers are also used. However, these compositions are, themselves also, very often considered not very comfortable, or even sometimes uncomfortable, from a sensory point of view for consumers.Furthermore, for some years, consumers have been becoming more demanding with regard to the compositions of their cosmetic products and are looking in particular to minimize the content of silicone compounds, or indeed even to do without them. In return, they are looking to use products comprising a greater content of natural ingredients or ingredients of natural origin, or ingredients whose environmental impact is minimized and / or ingredients which are compatible with numerous packagings.The difficulty lies, however, in reconciling the latter trends with the fact that consumers do not wish, for all that, to relinquish the very high performance qualities to which they have been accustomed with the products which they already use, which comprise in particular silicone film-forming polymers.There is thus still a search for effective makeup compositions which are more comfortable, which also exhibit good staying power, without it being necessary to use the film-forming polymers conventionally used, in particular silicone polymers, and which are more environmentally friendly, by employing, for example, more natural compounds or compounds of natural origin.These and other problems are solved by the present invention, one subject of which is a cosmetic composition for making up human keratin materials, in particular the skin and / or the lips, preferably the lips, in the form of a water-in-oil emulsion, comprising:- at least 5% by weight of pullulan relative to the total weight of the composition;- at least 20% by weight, relative to the total weight of the composition, of at least a first apolar hydrocarbon-based oil comprising from 8 to 16 carbon atoms;- at least one lipophilic mineral thickener,- at least one dyestuff.The present invention also relates to a makeup process in which the abovementioned cosmetic composition is applied to human keratin materials, in particular the skin and / or the lips, preferably the lips.The composition according to the invention has the advantage of being stable over time and of being easy to apply, without dewetting on application or on blotting. Moreover, the deposit obtained is precise, homogeneous, not runny and sparingly or not at all tacky.The deposit does not migrate either into the wrinkles and fine lines, in particular around the lips.Furthermore, the resulting deposit is matte to satiny, with good staying power. It is also comfortable, without leaving a feeling of dryness or tautness.The composition according to the invention is thus in the form of a water-in-oil emulsion, or invert emulsion. In other words, the composition comprises an aqueous phase dispersed within the lipophilic phase, which constitutes the continuous phase of the emulsion.The composition according to the invention is advantageously in the form of a liquid composition.The term “liquid composition” means any composition which has one or more of the following features:i) it flows under its own weight at room temperature (20°C) and at atmospheric pressure (1.013 x 105Pa);ii) it is not solid at room temperature and at atmospheric pressure and a viscosity or consistency characterized by its hardness may be measured for same;iii) it does not have any particular shape such as that which can be obtained by hot casting in a mold or container of a given shape.Such compositions may thus be found notably in fluid, creamy, pasty or gel form.Protocol for measuring the viscosityThe viscosity measurement is generally performed with a sample of composition at 25°C, at least 24 hours after its manufacture (storage at room temperature), using a Rheomat RM180 viscometer equipped with a No. 2, 3 or 4 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the composition (after which time stabilization of the viscosity and of the spin speed of the spindle are observed), at a shear rate of 200 rpm.According to one embodiment, the composition according to the invention may have, at 25°C, a viscosity of between 0.1 and 5 Pa.s, preferably between 0.5 and 4 Pa.s.PULLULANAs indicated previously, the composition comprises pullulan.Pullulan is a polysaccharide formed from maltotriose units, known under the name α(1,4)-α(1,6)-glucan. Three glucose units in maltotriose are connected via an α(1,4) glycoside bond, whereas the consecutive maltotriose units are connected to each other via an α(1,6) glycoside bond. It is produced from starch by the fungusAureobasidium pullulans.Pullulan is produced, for example, under the trade name Pullulan PF 20® by the Hayashibara Group in Japan, or under the trade name Aqua Beta® by the company Daiso, Co., Ltd, like the product sold under the name Pullulan Cosmetic Grade® by the company Hayashibara.The composition according to the invention comprises at least 5% by weight of pullulan, expressed as active material, relative to the total weight of the composition. More particularly, the pullulan content is between 5% and 15% by weight, more particularly between 5% and 10% by weight, relative to the total weight of the composition.FIRST HYDROCARBON-BASED OILThe composition also comprises at least a first apolar hydrocarbon-based oil comprising from 8 to 16 carbon atoms.The term “oil” means any water-immiscible compound that is in liquid form at room temperature and at atmospheric pressure.The term “water-immiscible” means that the mixing of the same amount of water and oil, after stirring, does not result in a stable solution comprising only a single phase, at room temperature and atmospheric pressure. Observation is made by eye or using a phase-contrast microscope, if necessary, on 100 g of mixture obtained after sufficient stirring with a Rayneri blender to produce a vortex within the mixture (as a guide, 200 to 1000 rpm), the resulting mixture being left to stand, in a closed flask, for 24 hours at room temperature before observation.The term “apolar hydrocarbon-based oil” means an oil chosen from hydrocarbons, that is to say from compounds comprising only carbon and hydrogen atoms.The apolar hydrocarbon-based first oils that may be used in the context of the invention are more particularly chosen from linear or branched, preferably saturated, oils containing from 8 to 16 carbon atoms, and mixtures thereof.Advantageously, these oils are volatile.The term “volatile oil” means an oil with a nonzero vapor pressure, at room temperature and atmospheric pressure, ranging in particular from 2.66 Pa to 40 000 Pa, in particular ranging up to 13 000 Pa and more particularly ranging up to 1300 Pa (standard OCDE 104).The apolar hydrocarbon-based oils may thus be chosen from linear alkanes comprising from 8 to 14 carbon atoms.As examples of linear alkanes, in particular C8-C14 alkanes, mention may be made of n-octane (C8), n-nonane (C9), n-decane (C10), n-undecane (C11), n-dodecane (C12) and n-tridecane (C13), and mixtures thereof. Mention may notably be made of n-dodecane (C12) and n-tetradecane (C14) sold by Sasol under the references, respectively, Parafol 12-97® and Parafol 14-97®, and also mixtures thereof. According to another embodiment, use may be made of a mixture of n-dodecane and n-tetradecane, and in particular the dodecane / tetradecane mixture sold by the company Biosynthis under the reference Vegelight 1214®. According to yet another embodiment, use may also be made of a mixture of volatile linear C9-C12 alkanes of INCI name: C9-12 Alkane, such as the product sold by the company Biosynthis under the reference Vegelight Silk®. According to yet another embodiment, use may be made of a mixture of n-undecane (C11) and of n-tridecane (C13) as obtained in Examples 1 and 2 of patent application WO 2008 / 155 059 (mixtures of different alkanes differing by at least one carbon) from the company Cognis and the product sold under the trade name Cetiol Ultimate® by the company BASF.Mention may also be made of the alkanes described in the Cognis patent applications WO 2007 / 068 371. These alkanes are obtained from fatty alcohols, which are themselves obtained from coconut kernel oil or palm oil.The hydrocarbon-based oils that may be used in the compositions according to the invention may be chosen from branched C8-C16 alkanes. Mention may notably be made of C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), such as isododecane (also known as 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane and, for example, the oils sold under the Isopar® or Permethyl® trade names.According to a particularly preferred embodiment, the first is chosen from isododecane, the mixture of linear C9-C12 alkanes, and the mixture of n-undecane (C11) and n-tridecane (C13), and mixtures thereof.Preferably, the content of apolar hydrocarbon-based first oil(s) represents from 20% to 50% by weight and preferably from 20% to 40% by weight relative to the total weight of the composition.LIPOPHILIC MINERAL THICKENERThe composition according to the invention comprises at least one lipophilic mineral thickener, in particular chosen from lipophilic clays.The term “lipophilic clay” refers to any clay that is liposoluble or lipodispersible in the oily phase of the composition.Clay denotes a material based on hydrated silicates and / or aluminosilicates, of lamellar structure.The clays may be natural or synthetic, and they are made lipophilic by treatment with an alkylammonium salt such as a C10 to C22 ammonium chloride, in particular stearalkonium chloride or distearyldimethylammonium chloride.They may be chosen from bentonites, in particular bentonites, hectorites and montmorillonites, beidellites, saponites, nontronites, sepiolites, biotites, attapulgites, vermiculites and zeolites.They are preferably chosen from hectorites and bentonites.For example, use may be made of a lipophilic clay chosen from hydrophobically modified bentonites and hydrophobically modified hectorites, notably modified with a C10 to C22 quaternary ammonium chloride, such as:- a bentonite modified with stearalkonium chloride, such as the commercial products sold under the name Claytone AF®, Garamite VT®, Tixogel® LG-M, Tixogel® MP 250 Tixogel® VZ and Tixogel® VZ-V XR, by the company BYK Additives Inc; or the commercial products sold under the name Viscogel® B3, Viscogel® B4, Viscogel® B7, Viscogel® B8, Viscogel® ED, Viscogel® GM, Viscogel® S4 and Viscogel® SD by the company Bentec S.P.A;- a bentonite modified with stearalkonium chloride in the presence of at least propylene carbonate and at least one oil, such as the commercial products Dub Velvet Gum® from the company Stéarinerie Dubois Fils, Miglyol Gel T® from the company Cremer Oleo, Tixogel® CGT 6030, Tixogel® DBA 6060, Tixogel® FTN, TIXOGEL® FTN 1564, Tixogel® IPM, Tixogel® LAN, Tixogel® LAN 1563 from the company BYK Additives Inc.;- a hectorite modified with distearyldimethylammonium chloride (INCI name: Disteardimonium Hectorite), for instance the product sold under the name Bentone® 38VCG Rheological Additive by the company Elementis Specialties;- a hectorite modified with distearyldimethylammonium chloride in the presence of at least propylene carbonate or triethyl citrate and of at least one oil, such as the commercial products sold under the name Bentone® Gel DOA V, Bentone® Gel EUG V, Bentone® Gel IHD V, Bentone® Gel ISD V, Bentone® Gel MIO V, Bentone® Gel PTM V, Bentone® SS-71 V, Bentone® VS-5 PC V or Bentone® VS-5 by the company Elementis Specialities; the commercial products sold under the name Creagel Bentone CPS / Hectone CPS or Creagel Bentone ID / Hectone ID by the company Créations Couleurs; the commercial products sold under the name NS Gel DM1®, NS Gel PTIS® or NS MGel 1152® by the company Next Step Laboratories Stop.More particularly, if the composition comprises any, the content of lipophilic thickener represents from 0.5% to 4% by weight, preferably from 0.75% to 3% by weight, relative to the total weight of the composition.SECOND OILThe composition according to the invention may optionally comprise at least one second oil, different from the first oil(s), chosen from nonvolatile, polar or apolar hydrocarbon-based oils, from volatile or nonvolatile silicone oils, and also mixtures thereof.The term “hydrocarbon-based oil” refers to an oil mainly containing carbon and hydrogen atoms and possibly one or more functions chosen from hydroxyl, ester, ether and carboxylic functions. These oils are thus different from silicone oils.The term “polar hydrocarbon-based oil” means that said oils comprise, in addition to carbon and hydrogen atoms, at least one oxygen atom. Thus, said hydrocarbon-based oil comprises at least one hydroxyl, ester, ether and / or carboxylic function.The term “silicone oil” refers to an oil comprising at least one silicon atom, and notably at least one Si-O group, and more particularly an organopolysiloxane.The term “nonvolatile oil" means an oil whose vapor pressure at 20°C and atmospheric pressure is nonzero and is less than 2.66 Pa and preferably less than or equal to 0.13 Pa. By way of example, the vapor pressure may be measured according to the static method or via the effusion method by isothermal thermogravimetry, depending on the vapor pressure of the oil (standard OCDE 104).Polar nonvolatile hydrocarbon-based oilsThe composition according to the invention may thus comprise at least one nonvolatile polar hydrocarbon-based oil, more particularly chosen from:* saturated or unsaturated, linear or branched, C10-C26fatty alcohols, preferably monoalcohols, which are preferably branched when they comprise at least 16 carbon atoms. More particularly, the fatty alcohol comprises from 10 to 24 carbon atoms and more preferentially from 12 to 22 carbon atoms;* ethers of formula ROR’ or carbonates of formula RO(CO)OR', in which formulae the groups R and R’, which may be identical or different, represent a saturated or unsaturated, branched or unbranched, hydrocarbon-based group comprising not more than 16 carbon atoms, preferably a C3-C16group;* hydroxylated or non-hydroxylated plant oils;* ester oils comprising one or more ester functions, preferably one to four ester functions, and comprising at least one linear or branched, saturated, unsaturated or aromatic hydrocarbon-based group comprising at least 6 carbon atoms, preferably at least 8 carbon atoms; the ester oil may optionally comprise one or more ether or hydroxyl functions;* liquid polyesters derived from the reaction of a monounsaturated or polyunsaturated acid dimer; the fatty acid comprising from 16 to 22 carbon atoms;* and mixtures thereof.Preferably, the second oil is chosen from:- lauryl alcohol, isostearyl alcohol, oleyl alcohol, 2-butyloctanol, 2-undecylpentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol and octyldodecanol, and mixtures thereof; preferably octyldodecanol;- dicaprylyl ether;- dipropyl carbonate, diethylhexyl carbonate, dicaprylyl carbonate, and C14-C15dialkyl carbonate;- castor oil, olive oil, jojoba oil, ximenia oil, pracaxi oil, wheat germ oil, corn oil, sunflower oil, sweet almond oil, macadamia oil, apricot kernel oil, soybean oil, rapeseed oil, groundnut oil, cottonseed oil, alfalfa oil, poppy oil, pumpkin oil, sesame oil, marrow oil, avocado oil, hazelnut oil, grape seed oil, blackcurrant oil, argan oil, evening primrose oil, millet oil, barley oil, linseed oil, quinoa oil, rye oil, safflower oil, candlenut oil, passionflower oil, musk rose oil, the liquid fraction of shea butter and the liquid fraction of cocoa butter, and mixtures thereof;- 2-ethylhexyl palmitate, 2-octyldecyl palmitate, octyldodecyl neopentanoate, 2-octyldodecyl stearate, butyl stearate, 2-octyldodecyl erucate, C12to C15alkyl benzoates, 2-octyldodecyl benzoate, isocetyl isostearate, isostearyl isostearate, isononyl isononanoate, isopropyl palmitate, hexyl laurate, 2-hexyldecyl laurate, isopropyl myristate, 2-octyldodecyl myristate, diisostearyl malate, neopentyl glycol dicaprate, glyceryl tris(2-decyltetradecanoate), capric acid triglyceride, alone or as a mixture, such as capric / caprylic acid triglycerides, C18-36acid triglycerides, glyceryl triheptanoate, glyceryl trioctanoate, glyceryl tris(2-decyltetradecanoate), triisostearyl citrate, tridecyl stearate, tridecyl trimellitate, pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetraisononanoate, pentaerythrityl tetrakis(2-decyltetradecanoate); polyglycerol-2 tetraisostearate; Pentaerythrityl Isostearate / Caprate / Caprylate / Adipate (INCI name, for example the Supermol L products from the company Croda); isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate;- the polyesters having the following INCI names: Dilinoleic Acid / Butanediol Copolymer, Dilinoleic Acid / Propanediol Copolymer, sold, for example, under the names: Viscoplast, by the company Biosynthis; Dimer Dilinoleyl Dilinoleate, notably sold under the name Lusplan by the company Nippon Fine Chemical;- and also mixtures thereof.Apolar nonvolatile hydrocarbon-based oilsThe apolar, nonvolatile hydrocarbon-based oil may be chosen from linear or branched hydrocarbons of mineral, plant or synthetic origin, for instance:- liquid paraffin,- squalane, in particular of plant origin,- isoeicosane,- mixtures of saturated linear hydrocarbons, more particularly of C15-C28, such as the mixtures of which the INCI names are, for example, the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, for instance the products Gemseal 40, Gemseal 60 and Gemseal 120 sold by Total, and Emogreen L15 and L19 sold by SEPPIC,- hydrogenated or non-hydrogenated polybutenes, for instance products of the Indopol range sold by the company Ineos Oligomers,- hydrogenated or non-hydrogenated polyisobutenes, for instance the nonvolatile compounds of the Parleam® range sold by the company Nippon Oil & Fats,- hydrogenated or non-hydrogenated polydecenes, for instance nonvolatile compounds of the Silkflo range sold by the company Ineos, and Dekanex by the company IMCD,- and mixtures thereof;Nonvolatile silicone oilsThe composition according to the invention may comprise at least one nonvolatile phenyl silicone oil, optionally comprising at least one dimethicone fragment, or comprising at least one nonvolatile non-phenyl silicone oil, or mixtures thereof.The term “phenyl(ated)” specifies that said oil includes, in its structure, at least one phenyl radical.The term “dimethicone fragment” denotes a divalent siloxane group, the silicon atom of which bears two methyl radicals, this group not being located at one or both ends of the molecule. It may be represented by the following formula:-(Si(CH3)2-O)-.Preferably, the silicones do not contain a C2-C3alkylene oxide group or a glycerolated group.As nonvolatile phenylated oil comprising at least one dimethicone fragment, mention may be made of the oils having the following INCI names: Trimethylsiloxyphenyl Dimethicone, Diphenyl Dimethicone, Tetramethyl Tetraphenyl Trisiloxane and also mixtures thereof, preferably Trimethylsiloxyphenyl Dimethicone. The Diphenyl Dimethicones are notably sold by the company Shin-Etsu under the names KF-54, KF54HV, KF-50-300CS, KF-53 d and KF-50-100CS. The Trimethylsiloxy Phenyl Dimethicones are sold, for example, by the company Wacker Chemie under the names Belsil PDM 1000 and Belsil PDM 20.Among the nonvolatile phenyl silicone oils not containing a dimethicone fragment, mention may be made of the compounds having the following INCI names: Phenyltrimethicone, Trimethyl Pentaphenyl Trisiloxanes, alone or as mixtures. As nonvolatile, non-phenyl silicone oils that are suitable for performing the invention, mention may be made of those sold by the company Wacker under the Belsil DM range, by the company Dow Corning with the Xiameter PMX 200 Silicone Fluid range, and by the company Shin-Etsu with the KF-96 A range.Representative examples of the nonvolatile non-phenyl silicone oils include polydimethylsiloxanes and alkyl dimethicones. It should be noted that the term “dimethicone” (INCI name) corresponds to a polydimethylsiloxane (chemical name). Preferably, these nonvolatile, non-phenyl silicone oils are chosen from polydimethylsiloxanes and alkyl dimethicones comprising at least one C2-C24alkyl group, and also mixtures thereof. Thus, these oils may be chosen from dimethicone, cetyl dimethicone and stearyl dimethicone, alone or as mixtures. As nonvolatile, non-phenyl silicone oils that are suitable for use, mention may be made of those sold by the company Wacker under the Belsil DM range, by the company Dow Corning with the Xiameter PMX 200 Silicone Fluid range, and by the company Shin-Etsu with the KF-96 A range. The alkyldimethicones may be sold, for example, under the trade names Abil Wax 9800 and Abil Wax 9801 from Evonik Goldschmidt, or Dowsil 2502 Cosmetic Fluid, Dowsil 2503 Cosmetic Wax, from Dow Corning; and mixtures thereof.Volatile silicone oilsThe volatile silicone oils may be chosen from linear, branched or cyclic silicone oils, such as polydimethylsiloxanes containing from 3 to 7 silicon atoms.As examples of such oils, mention may be made of the oils having the following INCI names: Cyclopentasiloxane, Cyclotetrasiloxane, Cyclohexasiloxane, Caprylyl Methicone, Disiloxane, Trisiloxane, Dimethicones notably with a viscosity of less than 5 cSt, such as those sold under the reference Xiameter PMX-200 Silicone Fluid, sold by the company Dow Corning, with viscosities notably of 1 cSt, 1.5 cSt, 3 cSt, or also KF 96 L 2 cs from Shin-Etsu, alone or as mixtures.Preferably, the second oil, if the composition according to the invention comprises one, is at least chosen from nonvolatile, preferably polar, hydrocarbon-based oils, alone or as mixtures.Preferably, the second oil is chosen from polar nonvolatile hydrocarbon-based oils.Preferably, the second oil(s) are chosen from ether oils and ester oils. In accordance with an even more preferred embodiment, if the composition comprises them, the second oil(s) are chosen from plant oils; optionally hydroxylated ester oils comprising 1 to 4 ester functions, comprising at least one linear or branched, saturated, unsaturated or aromatic group, comprising at least 6 carbon atoms, preferably at least 8 carbon atoms; ether oils of formula ROR’ where R and R’, which may be identical or different, represent a saturated or unsaturated, branched or unbranched hydrocarbon-based group comprising not more than 16 carbon atoms; and also mixtures thereof.According to a preferred embodiment, the second oil is chosen from triglycerides of fatty acids containing from 8 to 24 carbon atoms, and more particularly a caprylic / capric acid triglyceride (INCI name: Caprylic / Capric Triglyceride), plant oils, dicaprylyl ether, and also mixtures thereof.If the composition comprises any, the content of second oil(s) does not exceed 15% by weight, more particularly ranges from 0.1% to 10% by weight, relative to the total weight of the composition.Preferably, if the composition comprises at least one volatile or nonvolatile silicone oil, then their content does not exceed 5% by weight, more particularly does not exceed 3% by weight, even more preferentially does not exceed 1% by weight, relative to the total weight of the composition. Preferably, the composition according to the invention does not contain any.WATERThe composition according to the invention also comprises water.A water that is suitable for use in the invention may be a demineralized water, a floral water such as cornflower water and / or a mineral water such as Vittel water, Lucas water or La Roche Posay water and / or a spring water.According to a particular embodiment of the invention, the water content is at least 20% by weight, preferably between 20% and 50% by weight and preferably between 20% and 40% by weight relative to the total weight of the composition.C2-C6 MONOALCOHOLThe composition according to the invention may optionally comprise at least one saturated or unsaturated, preferably saturated, C2-C6 and more particularly C2-C4 monoalcohol. The monoalcohol(s) may be represented, for example, by the formula RaOH, in which Ra represents a linear or branched alkyl group comprising from 2 to 6 carbon atoms, preferably comprising from 2 to 4 carbon atoms. Monoalcohols that may be mentioned include include ethanol, isopropanol, tert-butanol or butanol, or mixtures thereof. Preferably, said monoalcohol comprises at least ethanol, and even more preferentially the monoalcohol is ethanol.According to an advantageous embodiment of the invention, the monoalcohol content represents from 3% to 20% by weight, preferably from 5% to 15% by weight, relative to the total weight of the composition.LIQUID POLYOLThe composition according to the invention may optionally comprise at least one saturated or unsaturated, linear or branched C2-C8 and preferably C3-C6 polyol that is liquid at room temperature, comprising from 2 to 6 hydroxyl groups. More particularly, the liquid polyol is chosen from glycerol, diglycerol, and linear or branched, saturated C3-C8 glycols or alkanediols. Propylene glycol, propanediol, butylene glycol, pentanediol, pentylene glycol, caprylyl glycol, dipropylene glycol and also mixtures thereof, and preferably glycerol, are notably suitable for use.According to an advantageous embodiment of the invention, the content of liquid polyol ranges from 3% to 20% by weight, in particular from 4% to 15% by weight, relative to the total weight of the composition.NONIONIC SURFACTANTThe composition according to the invention comprises at least one nonionic hydrocarbon-based or silicone surfactant with an HLB of less than or equal to 8.For the purposes of the present invention, the term “surfactant” refers to an amphiphilic compound, i.e. a compound containing two parts of different polarities. Generally, one is lipophilic (soluble or dispersible in an oily phase), the other is hydrophilic (soluble or dispersible in water). Nonionic surfactants are characterized by the value of their HLB (Hydrophilic Lipophilic Balance), the HLB being the ratio of the hydrophilic part to the lipophilic part in the molecule. The term “HLB” is well known to those skilled in the art and is described, for example, in “The HLB System. A Time-Saving Guide to Emulsifier Selection” (published by ICI Americas Inc.; 1984). For the surfactants used in the context of the present invention, their HLB value is less than or equal to 8 and more particularly ranges from 3 to 8. The HLB value may be determined via the Griffin method or the Davies method.More particularly, the nonionic surfactant(s) are chosen from optionally (poly)oxyethylenated, (poly)oxypropylenated or (poly)glycerolated compounds.Nonionic hydrocarbon-based surfactantAmong the hydrocarbon-based nonionic surfactants that may be used in the context of the invention, mention may be made of (poly)oxyethylenated and / or (poly)oxypropylenated C8-C30alcohols; (poly)oxyethylenated or (poly)oxypropylenated C8-C30esters; preferably polyhydroxylated, polyoxyalkylenated C12-C20fatty acid polyesters containing from 4 to 50 ethylene oxide units; (C8-C30)alkyl and (C8-C30)polyalkyl esters of sorbitan; (C8-C30)alkyl and (C8-C30)polyalkyl esters of (poly)glycerol; alone or as mixtures.Examples of such surfactants that are notably suitable for use include:(poly)oxyethylenated or (poly)oxypropylenated, preferably (poly)oxyethylenated, C8-C30alcohols, more particularly comprising a number of ethylene oxide (EO) units ranging from 2 to 4. Examples that may notably be mentioned include laureth-2; steareth-2; oleth-2; oleth-3; ceteth-2 and ceteareth-3;(poly)oxyethylenated or (poly)oxypropylenated, preferably (poly)oxyethylenated, (C8-C30)alkyl and (C8-C30)polyalkyl esters, more particularly comprising a number of ethylene oxide (EO) units ranging from 1 to 5, with for example glycol distearate, glycol stearate, PEG-2 oleate; PEG-3 oleate; PEG-4 dilaurate (HLB 6), propylene glycol isostearate; PEG-2.5 castor oil; PEG-3 castor oil;3) polyoxyalkylenated C12-C20fatty acid polyesters, which are preferably polyhydroxylated, containing from 4 to 50 ethylene oxide units. In particular, these polymers are block polymers, preferably of ABA structure, including poly(hydroxylated ester) blocks and polyethylene glycol blocks. The fatty acid of said surfactant polymer as defined above preferably contains from 14 to 18 carbon atoms. The esters may notably be chosen from oleates, palmitates or stearates. The polyethylene glycol blocks of said surfactant polymer as defined above preferably include from 20 to 40 ethylene oxide units. A polymeric surfactant that is particularly suitable for preparing the compositions of the invention is polyethylene glycol dipolyhydroxystearate containing 30 EO, sold under the trade name Arlacel P 135 by the company Croda.4) (C8-C30)alkyl and (C8-C30)polyalkyl esters of sorbitan, for instance sorbitan trioleate, sorbitan sesquioleate, sorbitan oleate, sorbitan palmitate, sorbitan stearate, sorbitan isostearate, (Span 120 from the company Croda), sorbitan sesquiisostearate (Cosmol 182V from the company Nisshin Oillio), mixtures of sorbitan stearate and sucrose cocoate (Arlacel 2121 sold by the company Croda), sorbitan isostearate mixed with hydrogenated castor oil, stearic acid and white wax (Arlacel 986 sold by the company Croda), and mixtures thereof.5) (C8-C30)alkyl and poly(C8-C30)alkyl esters of (poly)glycerol more particularly comprising a number of glycerol units ranging from 1 to 10.Mention may be made, for example, of glyceryl isostearate, glyceryl stearate and glyceryl laurate, alone or as mixtures.Among the polyglycerolated nonionic surfactants, mention may be made notably of:- esters of isostearic acid and of polyglycerol containing from 2 to 10 mol of glycerol units, for instance Polyglyceryl-4 Isostearate sold under the name Isolan GI34® by the company Evonik Nutrition & Care GmbH, Polyglyceryl-2 sesquiisostearate sold under the name Hostacerin® DGI by the company Clariant, Polyglyceryl-3 Diisostearate sold under the name Lameform TGI® by the company Cognis; Polyglyceryl-2 Diisostearate sold under the name Emalex PGSA® by the company Nihon Emulsion; Polyglyceryl-10 Isostearate sold under the name Nikkol Decaglyn 1-IS® by the company Nihon Surfactant; Polyglyceryl-4 Diisostearate / Polyhydroxystearate Sebacate sold under the name ISOLAN GPS® by Evonik Nutrition & Care GmbH; Polyglyceryl-2 Triisostearate sold under the name Cithrol PG23IS® by Croda Europe, Ltd;- stearic acid esters of polyglycerol containing from 2 to 3 mol of glycerol units, such as Polyglyceryl-2 Sesquistearate sold under the name Sunsoft Q-18B® by the company Taiyo Kagaku Company, Polyglyceryl-3 Distearate sold under the name Cremophor GS 32® by the company BASF, and Polyglyceryl-2 Stearate sold under the name Hostacerin DGMS® by Clariant International Ltd;- oleic acid esters of polyglycerol containing 2 or 3 mol of glycerol units, such as Polyglyceryl-2 Oleate sold under the name Nikkol DGMO-CV® by Nikko Chemicals, Polyglyceryl-3 Oleate sold under the name Isolan GO 33® by Evonik Nutrition & Care GmbH, Polyglyceryl-2 Dioleate; Polyglyceryl-3 Dioleate sold under the name Plurol Oleique CC 497® by Gattefosse;- polyglyceryl polyricinoleate(s) containing from 3 to 6 mol of glycerol units, such as Polyglyceryl-3 Polyricinoleate, notably sold by the company Karlshamns under the name Akoline PGPR® or by the company Stéarinerie Dubois Fils under the name DUB PGPR or by the company Dr. Straetmans under the name Dermofeel®, or by the company Croda under the name Crester PR® or else by the company Sasol under the name Imwitor 600®; Polygyceryl-5 Polyricinoleate sold by the company Taiyo Kagaku Co. Ltd under the name Sunsoft NO.818R®; Polyglyceryl-6 Polyricinoleate sold by the company Nikko Chemicals Co. Ltd under the name Hexaglyn PR-15® or by the company Sakamoto Yakuhin Kogyo Co. Ltd under the name SY-Glyster CRS-75®. According to one embodiment, mixtures of these compounds may be used.More particularly, the nonionic polyglycerolated surfactant is chosen from polyglyceryl polyricinoleate(s) containing from 3 to 6 mol of glycerol units, and more particularly Polyglyceryl-6 Polyricinoleate sold by the company Nikko Chemicals Co. Ltd under the name Hexaglyn PR-15® or by the company Sakamoto Yakuhin Kogyo Co. Ltd under the name SY-Glyster CRS-75®.Nonionic silicone surfactantThe nonionic surfactant may also be chosen from nonionic silicone surfactants, in particular linear oxyalkylenated (C3-C4) polydimethylmethylsiloxanes with an HLB of less than or equal to 8, preferably linear oxypropylenated and / or oxyethylenated, notably having the formula (I) below:[Chem 12](I)in which: R1, R2and R3, independently of each other, represent a C1-C6 alkyl radical or a radical -(CH2)x-(OCH2CH2)y-(OCH2CH2CH2)z-OR4, at least one radical R1, R2or R3not being an alkyl radical; R4being a hydrogen atom, a C1-C3 alkyl radical or a C2-C4 acyl radical;A is a mean integer ranging from 0 to 200;B is a mean integer ranging from 0 to 50; on condition that A and B are not simultaneously equal to zero;x is a mean integer ranging from 0 to 6;y is a mean integer ranging from 1 to 30;z is a mean integer ranging from 0 to 30.According to a particular embodiment, the linear oxyalkylenated polydimethylmethylsiloxane surfactant of HLB ≤ 8 is chosen from those of formula (I) in which R1and R3denote methyl, R2is -(CH2)x-(OCH2CH2)y-(OCH2CH2CH2)z-OR4and R4is a hydrogen atom.More particularly, among these compounds, the linear oxyalkylenated polydimethylmethylsiloxane surfactant of HLB ≤ 8 is chosen from those of formula (I) in which x is equal to 0.More particularly, the linear oxyalkylenated polydimethylmethylsiloxane surfactant of HLB ≤ 8 is chosen from those of formula (I) in which R1and R3denote methyl, R2is-(CH2)x-(OCH2CH2)y-(OCH2CH2CH2)z-OR4, R4is a hydrogen atom and z is equal to 0.According to a particular embodiment, the linear oxyalkylenated polydimethylmethylsiloxane surfactant of HLB ≤ 8 is chosen from those of formula (I) in which R1and R3denote -(CH2)x-(OCH2CH2)y-(OCH2CH2CH2)z-OR4, R2is methyl and R4is a hydrogen atom.As examples of silicone surfactants, mention may be made of the surfactants having the following INCI names: PEG / PPG-8 / 8 Dimethicone, Bis-PEG / PPG-14 / 14 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG-3 Dimethicone, PEG-10 Dimethicone, and also mixtures thereof.The following products are notably suitable for use:- PEG / PPG-8 / 8 dimethicone, such as the products sold under the trade names Silube J208-4I®, Silube J208-6I®, Silube J208-8I® and Silsurf J-1013-V-CG® by the company Siltech LLC; Andisil SP 1818® by the company AB Specialty Silicones; Jeesilc DMC 19® by the company Jeen International Corporation; Xiameter OFX-0190 Fluid® by the company Dow Chemical;- the Bis-PEG / PPG-14 / 14 dimethicone (and) dimethicone mixture sold under the trade name Abil EM 97 S® by the company Evonik Goldschmidt;- the cyclopentasiloxane and PEG / PPG-18 / 18 dimethicone mixture, such as the products sold under the trade names Dowsil 5225C Formulation Aid® by the company Dow Chemical; Emusil WO-5115® by the company Innospec Performance Chemicals; Gransurf 10C® by the company Grant Industries, Inc.; Jeesilc DMC522® by the company Jeen International Corporation; Silsurf 400R® by the company Siltech LLC;- the cyclotetrasiloxane and cyclopentasiloxane and PEG / PPG-18 / 18 dimethicone mixture, such as the commercial products sold under the name Dowsil 3225C Formulation AID® by Dow Chemical; Emulsil WO-3115® by Innospec Performance Chemicals; Jeesilc DMC252® and Jeesilc DMC322® by Jeen International Corporation;- the dimethicone and PEG / PPG-18 / 18 dimethicone mixture, such as the commercial products Dowsil ES-5226 DM Formulation AID® and Dowsil ES-5227 DM Formulations AID® from Dow Chemical; Gransurf 50C® and Gransurf 50C-HM® from Grant Industries, Inc. and X-22-6711D from Shin-Etsu.- the PEG / PPG-19 / 19 dimethicone and C13-C16 isoparaffin and C10-C13 isoparaffin mixture, such as the commercial product Dow Corning® BY 25-337 from Dow Chemical;- PEG-3 dimethicone, such as the commercial product KF-6015® from Shin-Etsu Chemical Co, Ltd;- PEG-10 dimethicone, such as the commercial products KF-6017® from Shin-Etsu Chemical Co. Ltd; Serasol SC 86® and Serasol SC 86A® from KCC Corporation);- mixtures thereof.Preferably, the composition according to the invention comprises, as nonionic surfactant(s), at least one hydrocarbon-based surfactant with an HLB of less than or equal to 8 and even more preferably, at least one polyglycerolated hydrocarbon-based surfactant as described previously.A composition of the invention preferably comprises from 2% to 10% by weight and in particular from 2% to 7% by weight of nonionic hydrocarbon-based or silicone surfactant(s) relative to the total weight of the composition.DYESTUFFThe composition according to the invention comprises at least one dyestuff.According to a particular form of the invention, the dyestuff may be chosen from pulverulent dyestuffs, liposoluble dyes, water-soluble dyes and mixtures thereof.Pulverulent dyestuffThe pulverulent dyestuffs may be chosen from mineral pigments, organic pigments, nacres and mixtures thereof.The term “pigments” means white or colored, mineral or organic particles, which are insoluble in an aqueous medium, and which are intended to color and / or opacify the resulting composition and / or deposit. These pigments may be white or colored, and mineral and / or organic.According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments.The term “mineral pigment” refers to any pigment that satisfies the definition in Ullmann’s encyclopedia in the chapter on inorganic pigments. Among the mineral pigments that are useful in the present invention, mention may be made of zirconium oxide or cerium oxide, and also zinc oxide, iron oxide (black, yellow or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, and metal powders, for instance aluminum powder and copper powder. The following mineral pigments may also be used: Ta2O5, Ti3O5, Ti2O3, TiO, ZrO2as a mixture with TiO2, ZrO2, Nb2O5, CeO2, ZnS.The size of the pigment that is useful in the context of the present invention is generally greater than 100 nm and may range up to 10 µm, preferably from 200 nm to 5 µm and more preferentially from 300 nm to 1 µm.According to a particular form of the invention, the pigments have a size characterized by a D

[0050] of greater than 100 nm and possibly ranging up to 10 µm, preferably from 200 nm to 5 µm and more preferentially from 300 nm to 1 µm.The sizes are measured by static light scattering using a commercial MasterSizer 3000® particle size analyzer from Malvern, which makes it possible to determine the particle size distribution of all of the particles over a wide range which may extend from 0.01 µm to 1000 µm. The data are processed on the basis of the standard Mie scattering theory. This theory is the most suitable for size distributions ranging from submicronic to multimicronic; it makes it possible to determine an “effective” particle diameter. This theory is notably described in the publication by Van de Hulst, H.C.,Light Scattering by Small Particles, Chapters 9 and 10, Wiley, New York, 1957.D

[0050] represents the maximum size exhibited by 50% by volume of the particles.According to a particular form of the invention, the mineral pigment comprises a lipophilic or hydrophobic coating, said coating preferably being present in the oily phase of the composition according to the invention.According to a particular embodiment of the invention, the pigments may be coated according to the invention with at least one compound chosen from metal soaps; N-acylamino acids or salts thereof; lecithin and derivatives thereof; isopropyl triisostearyl titanate; isostearyl sebacate; natural plant or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof.According to a preferential embodiment, the pigments may be coated according to the invention with an N-acylamino acid or a salt thereof, which may comprise an acyl group containing from 8 to 22 carbon atoms, for instance a 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group.The amino acid may be, for example, lysine, glutamic acid or alanine. The salts of these compounds may be the aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. Thus, according to a particularly preferred embodiment, the pigments may be coated with an N-acylamino acid derivative which may notably be a glutamic acid derivative and / or a salt thereof, and more particularly a stearoyl glutamate, for instance aluminum stearoyl glutamate. As examples of pigments treated with aluminum stearoyl glutamate, mention may be made of titanium dioxide pigments and black, red and yellow iron oxide pigments sold under the trade name NAI® by the company Miyoshi Kasei.According to a preferential embodiment, the pigments may be coated according to the invention with isopropyl triisostearyl titanate. As examples of isopropyl titanium triisostearate (ITT)-treated pigments, mention may be made of titanium dioxide pigments and the black, red and yellow iron oxide pigments sold under the trade names BWBO-I2® (iron oxide CI77499 and isopropyl titanium triisostearate), BWYO-I2® (iron oxide CI77492 and isopropyl titanium triisostearate) and BWRO-I2® (iron oxide CI77491 and isopropyl titanium triisostearate) by the company Kobo.The pigments that may be used according to the invention may also be organic pigments.The term “organic pigment” refers to any pigment that satisfies the definition in Ullmann’s Encyclopedia in the chapter on organic pigments. The organic pigment may notably be chosen from nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal-complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane or quinophthalone compounds.The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100 and 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000 and 47005, the green pigments codified in the Color Index under the references CI 61565, 61570 and 74260, the orange pigments codified in the Color Index under the references CI 11725, 15510, 45370 and 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915 and 75470, and the pigments obtained by oxidative polymerization of indole or phenol derivatives as described in patent FR 2 679 771.These pigments may also be in the form of composite pigments as described in patent EP 1 184 426. These composite pigments may notably be composed of particles including a mineral core at least partially covered with an organic pigment and at least one binder for fixing the organic pigments to the core.The pigment may also be a lake. The term “lake” means insolubilized dyes adsorbed onto insoluble particles, the assembly thus obtained remaining insoluble during use.The inorganic substrates onto which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum.Mention may be made, among the organic dyes, of cochineal carmine. Mention may also be made of the products known under the following names: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15 510), D&C Red 33 (CI 17 200), D&C Yellow 5 (CI 19 140), D&C Yellow 6 (CI 15 985), D&C Green 5 (CI 61 570), D&C Yellow 10 (CI 47 005), D&C Green 3 (CI 42 053), D&C Blue 10 (CI 42 090).An example of a lake that may be mentioned is the product known under the name D&C Red 7 (CI 15 850:1).Preferably, the composition according to the invention comprises at least one pulverulent dyestuff of mineral pigment type, in particular chosen from metal oxides, and more particularly chosen from coated or uncoated titanium dioxides or iron oxides and mixtures thereof.The nacres may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, colored nacreous pigments such as titanium mica with iron oxides, titanium mica notably with ferric blue or chromium oxide, titanium mica with an organic pigment of the abovementioned type, and also nacreous pigments based on bismuth oxychloride.Preferably, the pulverulent dyestuff(s) are present in the composition in a content ranging from 3% to 25% by weight, preferably from 5% to 20% by weight, more particularly from 5% to 15% by weight, relative to the total weight of the composition.Liposoluble or water-soluble dyestuffA composition according to the invention may comprise at least one water-soluble or liposoluble dyestuff, preferably in a proportion of at least 0.01% by weight relative to the total weight of the composition.For obvious reasons, this amount is liable to vary significantly with regard to the intensity of the desired color effect and of the color intensity afforded by the dyestuffs under consideration, and its adjustment clearly falls within the competence of a person skilled in the art.The additional dyestuffs that are suitable for use in the invention may be liposoluble.For the purposes of the invention, the term “liposoluble dyestuff” means any natural or synthetic, generally organic compound, which is soluble in an oily phase or in solvents that are miscible with a fatty substance, and which is capable of imparting color.As liposoluble dyes that are suitable for use in the invention, mention may notably be made of synthetic or natural liposoluble dyes, for instance DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red, carotenes (β-carotene, lycopene), xanthophylls (capsanthin, capsorubin, lutein), palm oil, Sudan brown, quinoline yellow, annatto and curcumin.The additional dyestuffs that are suitable for use in the invention may be water-soluble.For the purposes of the invention, the term “water-soluble dyestuff” means any natural or synthetic, generally organic compound, which is soluble in an aqueous phase or water-miscible solvents and which is capable of imparting color.As water-soluble dyes that are suitable for use in the invention, mention may be made notably of synthetic or natural water-soluble dyes, for instance FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5, FDC Blue 1, betanine (beetroot), carmine, copper chlorophyllin, methylene blue, anthocyanins (enocianin, black carrot, hibiscus, elder), caramel and riboflavin.The water-soluble or liposoluble dye(s), if the composition comprises any, are preferably present in contents of less than 4% by weight, or even less than 2% by weight, more preferentially ranging from 0.01% to 2% by weight and better still from 0.02% to 1.5% by weight, relative to the total weight of the composition.FILLERThe composition according to the invention preferably comprises at least one mineral filler, other than the mineral thickener described previously, or an organic filler, and also mixtures thereof.The term “filler” denotes a particle of organic or mineral nature which is colorless or white, which is solid, which has any shape and which is insoluble in the medium of the composition at room temperature and atmospheric pressure. These fillers are advantageously dispersed in the composition.Mineral fillerThe term “mineral filler” refers to any compound in which the chemical structure does not comprise a carbon atom, independently of the presence of a coating of said filler.The fillers are in the form of particles and are different from the dyestuffs described previously.The fillers used in the compositions according to the present invention may be particles in lamellar, globular or spherical form, in the form of fibers or in any other form intermediate between these defined forms. The fillers may be spherical, i.e. they may comprise at least a rounded general portion, notably defining at least a sphere portion, preferably internally defining a concavity or a hollow (sphere, globules, bowls, horseshoe, and the like), or lamellar.In accordance with a particular embodiment of the invention, the fillers more particularly have a mean particle size (expressed as volume-mean diameter - D[0.5]) of at least 1 µm, preferably of at least 2 µm, advantageously of between 2 and 15 µm. The size of the particles can be measured by laser diffraction using a commercial Mastersizer 3000 particle size analyzer from the company Malvern (see also the standard ISO 13320).The fillers used in the composition according to the invention may or may not be surface coated, and in particular they may be coated with a hydrophobic treatment agent, in particular promoting the dispersion and compatibility of the filler in the composition. The hydrophobic treatment agent may be chosen from silicones, in particular silanes; fluorinated derivatives, fatty acids such as stearic acid; metal soaps such as aluminum dimyristate, the aluminum salt of hydrogenated tallow glutamate; amino acids; N-acylamino acids or salts thereof; lecithin, isopropyl triisostearyl titanate, and mixtures thereof. The N-acylamino acids may comprise an acyl group containing from 8 to 22 carbon atoms, for instance a 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl group. The salts of these compounds may be the aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. The amino acid may be, for example, lysine, glutamic acid or alanine. The term “alkyl” mentioned in the compounds cited previously notably denotes an alkyl group containing from 1 to 30 carbon atoms and preferably containing from 5 to 16 carbon atoms.Such fillers are advantageously chosen from:-Silica(INCI name: Silica), such as the porous silica microspheres sold under the name Silica Beads SB-700 by the company Myoshi; Sunsphere H51, Sunsphere H33, SA Sunsphere H53, Sunsphere H121 by the company AGC SI-TECH; MSS-500 / 20N and Silica Shells by the company Kobo; Perluccia 14M by the company JGC Catalysts & Chemicals; hollow silica microspheres, for example BA4 silicas, by the company JGC Catalysts & Chemicals; amorphous silica microspheres coated with polydimethylsiloxane. Also suitable for use are the following products: Resifa FB-82 by the company AGC SI-TECH (INCI: Silica (and) Sodium Chloride); Aerova 5 Microns by the company JIOS Aerogel; Sunsil-Oleo 150H by the company Sunjin Beauty Science (INCI name: Silica (and) Cetyl Alcohol); Sensibeads SI 175 by the company Sensient; Miyofeel SXI-L by the company Myoshi (INCI name: Mica (and) Silica (and) Hydrogenated Lecithin (and) Calcium Chloride);-Perlitesuch as those sold by the company World Minerals under the trade name Perlite P1430, Perlite P2550, Perlite P2040 or OpTiMatTM1430 OR or 2550 OR. Europerl EMP-2 and Europerl 1 by the company Imerys; Perlite-MSZ12 by the company Myoshi;-Zeolitessuch as the products sold by the company Zeochem under the names Zeoflair 300, Zeoflair 200, Zeoflair 100, X-Mol and X-Mol MT;- Carbonate or hydrogen carbonate particles of alkaline-earth metals such as calcium or magnesium, or hydroxyapatite. Mention may be made, for example, of calcium magnesium carbonate particles such as those sold by the company Imerys under the name Calcidol. Also suitable for use is calcium carbonate, for example the products sold by the company Omya under the names Omyacare Extra 35-OG, Omyacare S 60-AV; by the company Sensient under the name Carbomat. Mention may also be made of magnesium carbonate and magnesium hydrogen carbonate particles.-Kaolin and talc particles, for example sold under the Imercare, Imercare Pharma and Luzenac Pharma ranges by the company Imerys; Rose Talc by the company Nippon Talc, Hallopure Ultra by the company I-minerals (INCI name: Halloysite (and) Kaolin);-Natural or synthetic mica, such as the product under the INCI name Synthetic Fluorphlogopite, sold under the names RonaFlair Silk Mica by the company Merck, Sericite PHN by the company Presperse, NHS-100 and NHS-150 by the company Myoshi Kasei, those sold under the names PDM-NSO or FNK-100 by the company Topy, Mearlmica DD by the company BASF.-Boron nitride, for example the products Ronaflair Boroneige SQ-6 sold by the company Merck, Softouch Boron Nitride Powder CC6058 by the company Momentive Performances, Boron Nitride SHP 3 by the company Mizushima Ferroalloy; silica and titanium dioxide composites, such as the TSG® series sold by Nippon Sheet Glass; bismuth oxychloride.-Glass or ceramic microcapsules; for instance borosilicate particles.-Barium sulfates, for instance the products Flake Shaped Barium Sulfate H by the company Sakai Chemical, LLD-5 BASO4 (PL) by the company Daito Kasei (NCI name: Barium sulfate (and) lauroyl lysine);-diatomaceous earths, for instance the Imercare references by the company Imerys;- mixtures thereof.Preferably, the composition according to the invention comprises, as mineral fillers, kaolin, mica, calcium carbonate and silica, and also mixtures thereof.In accordance with a particularly advantageous embodiment of the invention, the content of mineral filler represents from 2% to 20% by weight, preferentially from 3% to 15% by weight, relative to the total weight of the composition.Organic fillerFor the purposes of the invention, the term "organic filler" refers to solid particles of at least one hydrocarbon-based or silicone compound, or combinations thereof, independently of their coating.The fillers are in the form of particles which may or may not be surface-treated by means of compounds such as those described above in the context of the mineral fillers.The fillers used in the compositions according to the present invention may be in lamellar, globular or spherical form, in the form of fibers or in any other intermediate form between these defined forms. The fillers may be spherical, i.e. they may comprise at least a rounded general portion, notably defining at least a sphere portion, preferably internally defining a concavity or a hollow (sphere, globules, bowls, horseshoe, and the like), or lamellar.Among the suitable fillers, mention may be made of:-Natural or synthetic micronized waxes.-Metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate.-Natural organic materialssuch as polysaccharide powders and in particular starch powders, notably crosslinked or non-crosslinked corn, wheat or rice starch powders, powders of starch crosslinked with octenylsuccinic anhydride sold under the name Dry-Flo® by the company National Starch or powders of waxy corn starch, such as those which are sold under the names C* Gel 04201 by the company Cargill, Corn Starch B by the company Roquette and Organic Corn Starch by the company Draco Natural Products, Amaze Nordic Barley by the company Nouryon, and Celus Bi Feel by the company Roelm;-Cellulose, notably in the form of spherical particles, such as the products in the Cellulobeads range from Daito Kasei (for example Cellulobeads D-10, Cellulobeads D-5 and Cellulobeads USF). Tego Feel C10 cellulose by the company Evonik may also be used, or even microcrystalline celluloses, for example from the Vivapur range by the company Rettenmaier, or from the Avicel range by the company DuPont.-N-(C8-C22 acyl)amino acids; the amino acid may be, for example, lysine, glutamic acid or alanine, preferably lysine. Mention may be made, for example, of lauroyl lysine notably sold under the names Amihope LL by the company Ajinomoto or Corum 5105 by the company Corum;-Polyhdyroxyalkanoates, such as polyhydroxybutyrate particles (sold under the name Biosoft 915 by the company Micro Powders);-Acrylic (co)polymers particlesand derivatives thereof, in particular:* polymethyl methacrylate (INCI name Methyl Methacrylate Crosspolymer), sold under the name Covabead LH85 by the company Sensient, or Polymethyl Methacrylate, under the names Sepimat P by the company SEPPIC, Microsphere M-100® by the company Matsumoto Yushi-Seiyaku;* polymethyl methacrylate / ethylene glycol dimethacrylate (INCI name Methyl Methacrylate / Glycol Dimethacrylate Crosspolymer) sold under the name Dow Corning 5640 Microsponge Skin Oil Adsorber by the company Dow Corning;* crosslinked acrylate (INCI name: Acrylates Crosspolymer) sold, for example, under the name Ganzpearl GMP-0820 by the company Ganz Chemical,* the polyallyl methacrylate / ethylene glycol dimethacrylate powder sold under the name Poly-Pore L200 or Poly-Pore E200 by the company Amcol Health and Beauty Solutions Inc.;* ethylene glycol dimethacrylate / lauryl methacrylate copolymer (INCI name: Lauryl Methacrylate / Glycol Dimethacrylate Crosspolymer) sold under the name Polytrap 6603 Adsorber by the company Amcol Health and Beauty Solutions Inc.;* crosslinked acrylate / alkyl acrylate copolymer (INCI name: Acrylates / Ethylhexyl Acrylate Crosspolymer) sold under the name Techpolymer ACP-8C by the company Sekisui Plastics;* ethylene / acrylate copolymer, such as the product sold under the name Flobeads® by the company Sumitomo Seika Chemicals;*Acrylonitrile (co)polymer particles, in particular the expanded hollow particles sold under the name Expancel by the company AkzoNobel or the microspheres sold under the name Micropearl F 80 ED® by the company Matsumoto;-Polyurethane particles, for example sold under the names D-400, D-800 (INCI name: HDI / Trimethylol Hexyllactone Crosspolymer (and) Silica), CS-400 (INCI name: HDI / PPG / Polycaprolactone Crosspolymer(and) Silica), by the company Toshiki;-Silicone polymer particles,advantageously chosen from:* silicone resin particles such as those sold under the INCI name Polymethylsilsesquioxane, notably sold under the name Tospearl, notably Tospearl 145 A, by the company Momentive Performance Materials,* silicone elastomer powders coated with silicone resin, notably with silsesquioxane resin, such as the products sold under the name KSP-100, KSP-101, KSP-102, KSP-103, KSP-104 or KSP-105 (INCI name: Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer), or KSP-300 (INCI name: Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer) by the company Shin-Etsu;* silicone elastomer particles, such as the products sold under the name Dowsil 9506 Cosmetic Powder by the company Dow Corning (INCI name: Dimethicone / Vinyl Dimethicone Crosspolymer);* Methylsilanol / Silicate Crosspolymer particles, for example in the form of bowls such as those sold notably under the name TAK-110 by the company Takemoto Oil & Fat;-Polyamide particles, such as Nylon®, in particular Nylon 12, Nylon 6 / 12; such as the nylon powders sold under the names Orgasol 2002 EXS NAT COS, Orgasol 4000 EXD NAT COS Caresse, by the company Arkema;-Tetrafluoroethylene polymer (Teflonâ) particles.Preferably, if the composition comprises any, the organic filler may be chosen from cellulose particles, particles of N-(C8-C22 acyl)amino acids, such as lauroyl lysine, and also mixtures thereof.In accordance with a particular embodiment of the invention, the content of organic filler ranges from 2% to 10% by weight, more particularly from 3% to 8% by weight, relative to the total weight of the composition.According to a particularly advantageous embodiment of the present invention, it may be that the composition does not comprise polymeric organic fillers, considered to be microplastics. It will be recalled that, for the purposes of the invention, the term “microplastics” means solid particles, having a stable form, of polymer comprising carbon atoms in the polymer chain (backbone), of synthetic origin or of chemically modified natural origin, insoluble in water (i.e.: less than 2 g / l; OECD Directive 105), with a size less than 5 mm (and with a size less than 15 mm for fibers). The term "stable form" denotes particles remaining solid in the composition and after its use. For example, polymer particles forming a film in the composition or when said composition is used are not considered to be of stable form. Thus, preferably, it may be that the composition according to the invention does not comprise particles of acrylic polymers or copolymers, acrylonitriles, polyurethanes, polyamides, tetrafluoroethylene polymers, silicone polymers, as described previously. If, however, the composition were to comprise any, their content would preferably be less than 5% by weight, more particularly less than 2% by weight and advantageously less than 1% by weight, relative to the total weight of the composition. Preferably, if the composition comprises them, the content of organic fillers of the abovementioned microplastic type is less than or equal to 0.01% by weight, relative to the total weight of the composition, and very advantageously, the composition is devoid organic fillers.Preferably, the composition may comprise at least one mineral filler chosen from kaolin, mica, calcium carbonate, silica, and mixtures thereof. The composition may also comprise at least one organic filler, particularly cellulose, N-(C8-C22 acyl)amino acids, lauroyl lysine, and mixtures thereof.The total filler content advantageously represents from 2% to 30% by weight, and more particularly from 3% to 25% by weight, relative to the total weight of the composition.COSMETIC ADDITIVESThe compositions according to the invention may include additives commonly used in care and / or makeup products, such as active agents such as vitamins, for example vitamins A, E, C and B3, adenosine, hyaluronic acid and salts thereof; UV-screening agents; waxes; pasty compounds; hydrophilic thickeners; hydrophobic thickeners other than the clays described previously, for instance hydrophobic silicas, such as the compounds having the following INCI names: Silica Silylate, Silica Dimethyl Silylate; surfactants other than the abovementioned nonionic surfactants with an HLB of less than or equal to 8; film-forming agents; dextrin esters; fragrances; preserving agents; and mixtures thereof. Preferably, the composition does not comprise any compound of polyphenol type. The term “polyphenol” denotes any compound having in its chemical structure at least two benzene groups, in free or fused form, each benzene group comprising at least one hydroxyl (OH) group, preferably at least 2 hydroxyl groups, or even at least 3 (OH) groups. In particular, the composition does not comprise any tannic acid, or if it does, its content does not exceed 0.5% by weight, relative to the total weight of the composition.Although this does not correspond to a preferred variant of the invention, the composition may optionally comprise one or more silicone film-forming polymers, for instance silicone resins, silicone acrylate copolymers, silicone polyamides, or combinations thereof.Among the non-glycerolated silicone resins, mention may be made, for example, of the resins having the following INCI names: Trimethylsiloxysilicate, Phenylpropyldimethylsiloxysilicate, Polymethylsilsesquioxane, Polypropylsilsesquioxane, MQT-propyl resins, notably described and prepared in application WO2005 / 075542. Mention may also be made of C30-45 Alkyldimethylsilyl Polypropylsilsesquioxane (INCI name).Among the glycerolated resins, mention may be made of those described in the application US20200332065.Among the silicone acrylate dendrimer or non-dendrimer copolymers, mention may be made, for example, of the copolymers having the INCI name Acrylates / Polytrimethylsiloxymethacrylate Copolymer; Acrylates / Dimethicone Copolymer.As regards the silicone acrylamide copolymers, mention may notably be made of the copolymer having the INCI name Nylon-611 / Dimethicone Copolymer.If the composition comprises it / them, the content of silicone film-forming polymer(s) is less than 2% by weight, more particularly does not exceed 1% by weight, preferably does not exceed 0.5% by weight, relative to the total weight of the composition. Preferably, the composition according to the invention is devoid thereof.It is a matter of routine practice to adjust the nature and amount of the additives present in the compositions in accordance with the invention such that the desired cosmetic properties thereof are not thereby affected.Needless to say, a person skilled in the art will take care to select the optional additional additives and / or the amount thereof such that the advantageous properties of the compositions according to the invention are not, or are not substantially, adversely affected by the envisaged addition.WaxThe composition according to the invention may comprise at least one polar or apolar hydrocarbon-based wax, a silicone wax, or mixtures thereof.For the purposes of the present invention, the term “wax” means a lipophilic compound, which is solid at room temperature, with a reversible solid / liquid change of state, which has a melting point of greater than or equal to 30°C that may be up to 120°C.For the purposes of the invention, the melting point corresponds to the temperature of the most endothermic peak observed on thermal analysis (DSC) as described in the standard ISO 11357-3; 1999. The melting point of the wax may be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name DSC Q2000 by the company TA Instruments with the TA Universal Analysis software.The measuring protocol is as follows:A sample of 5 mg of wax is placed in a crucible and subjected to a first temperature rise ranging from -20°C to 120°C, at a heating rate of 10°C / minute, is then cooled from 120°C to -20°C at a cooling rate of 10°C / minute and is lastly subjected to a second temperature rise ranging from -20°C to 120°C at a heating rate of 5°C / minute.During the second temperature rise, the melting point of the solid fatty substance is measured, which corresponds to the temperature of the most endothermic peak observed on the melting curve, representing the variation in the difference in power absorbed as a function of the temperature.The enthalpy of fusion of the wax (∆Hf), corresponding to the integral of the entire melting curve obtained, may also be measured. This enthalpy of fusion of the wax is the amount of energy required to cause the compound to change from the solid state to the liquid state. It is expressed in J / g.Hydrocarbon-based waxThe waxes may be of plant, mineral, animal and / or synthetic origin.In particular, the waxes have a melting point preferably greater than or equal to 35°C and better still greater than or equal to 40°C.Apolar hydrocarbon-based waxFor the purposes of the present invention, the term “apolar hydrocarbon-based wax” means a wax constituted solely of carbon and hydrogen atoms and free of heteroatoms, for instance N, O, Si, P, etc.As examples of apolar waxes that are suitable for use in the invention, mention may notably be made of hydrocarbon-based waxes, for instance microcrystalline waxes, paraffin waxes, ozokerite, polymethylene waxes, polyethylene waxes and microwaxes, notably polyethylene waxes.Polar hydrocarbon-based waxThe polar waxes may notably be hydrocarbon-based or silicone waxes.For the purposes of the present invention, the term “polar hydrocarbon-based wax” means a wax of which the chemical structure is formed essentially of, or even constituted of, carbon and hydrogen atoms, and which comprises at least one heteroatom more particularly chosen from oxygen, optionally nitrogen, or mixtures thereof. It may thus contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.The term “silicone wax” means an oil comprising at least one silicon atom and notably comprising Si-O groups.According to a first preferred embodiment, the polar wax is a hydrocarbon-based wax.A wax chosen from ester waxes and alcohol waxes is preferred as polar hydrocarbon-based wax.According to the invention, the term “ester wax” means a wax comprising at least one ester function. The ester waxes may also be hydroxylated.According to the invention, the term “alcohol wax” means a wax comprising at least one alcohol function, i.e. comprising at least one free hydroxyl (OH) group.Use may notably be made, as ester wax, alone or as mixtures, of:i) waxes of formula R1COOR2in which R1and R2represent linear, branched or cyclic aliphatic chains, the number of atoms of which ranges from 6 to 50, notably from 10 to 50, which may contain a heteroatom, for instance O or N, and the melting point of which ranges more particularly from 30°C to 120°C. In particular, use may be made, as ester wax, of a C20-C40alkyl (hydroxystearyloxy)stearate (the alkyl group comprising from 20 to 40 carbon atoms), alone or as a mixture, or a C20-C40alkyl stearate. Such waxes are notably sold under the names Kester Wax K 82 P®, Hydroxypolyester K 82 P®, Kester Wax K 80 P®or Kester Wax K82H by the company Koster Keunen. Use may also be made of stearyl heptanoate and stearyl caprylate and mixtures thereof;ii) bis(1,1,1-trimethylolpropane) tetrastearate,iii) diester waxes of a dicarboxylic acid of general formula R3-(-OCO-R4-COO-R5), in which R3and R5are identical or different, preferably identical, and represent a C4-C30alkyl group and R4represents a linear or branched C4-C30aliphatic group which may or may not contain one or more unsaturations. Preferably, the C4-C30aliphatic group is linear and unsaturated;iv) mention may also be made of the waxes obtained by catalytic hydrogenation of animal or plant oils notably containing linear or branched C8-C32fatty chains, for instance hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil or hydrogenated coconut kernel oil, and also the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, such as those sold in the Phytowax Castor range, for example Phytowax Castor 22L73®, or else the waxes obtained by hydrogenation of olive oil esterified with stearyl alcohol, such as those of the Phytowax Olive range, for example Phytowax Olive 18L57, sold by the company Sophim. Such waxes are notably described in patent application FR2792190;v) waxes corresponding to the partial or total esters, preferably total esters, of a saturated, optionally hydroxylated, C16-C30carboxylic acid with glycerol. The term “total esters” means that all the hydroxyl functions of glycerol are esterified. Examples that may be mentioned include trihydroxystearine (or glyceryl trihydroxystearate), tristearine (or glyceryl tristearate) and tribehenine (or glyceryl tribehenate), alone or as a mixture. Among the suitable compounds, mention may be made of triesters of glycerol and of 12-hydroxystearic acid, or hydrogenated castor oil, for instance Thixcin R and Thixcin E sold by Elementis Specialties,vi) Mention may also be made of waxes of animal or plant origin, such as beeswax, synthetic beeswax, carnauba wax, candelilla wax, rice bran wax, ouricury wax, esparto grass wax, cork fiber wax, sugar cane wax, Japan wax, sumac wax, montan wax, orange wax, laurel wax, or sunflower wax, in particular in refined form;vii) mention may also be made of natural or synthetic polyalkylenated or polyglycerolated hydrocarbon-based waxes, of animal or plant origin; the number of (C2-C4) oxyalkylene units may range from 2 to 100, the number of glycerol units may range from 1 to 20. Examples that may be mentioned include polyoxyethylenated beeswaxes, such as PEG-6 beeswax or PEG-8 beeswax; polyoxyethylenated carnauba waxes, such as PEG-12 carnauba; polyoxyethylenated or polyoxypropylenated and hydrogenated or non-hydrogenated lanolin waxes, such as PEG-30 lanolin or PEG-75 lanolin; PPG-5 lanolin wax glyceride; polyglycerolated beeswaxes, notably polyglyceryl-3 beeswax, the Acacia Decurrens / Jojoba / Sunflower Seed Wax / Polyglyceryl-3 Esters mixture, polyglycerolated plant waxes, such as mimosa, jojoba or sunflower waxes, and mixtures thereof (Acacia Decurrens / Jojoba / Sunflower Seed Wax Polyglyceryl-3 Esters).According to another embodiment, the polar wax may be an alcohol wax. As alcohol waxes, mention may be made of mixtures of saturated linear C30-C50alcohols, for instance the wax Performacol 550 Alcohol from New Phase Technologies, stearyl alcohol and cetyl alcohol, or mixtures thereof.Preferably, if the composition comprises any, the wax is chosen from hydrocarbon-based waxes. More particularly, it is chosen from polar hydrocarbon-based waxes such as animal or plant waxes, animal or plant waxes obtained by catalytic hydrogenation of animal or plant oils; ester waxes such as waxes corresponding to the partial or total, preferably total, esters of a saturated, optionally hydroxylated, C16-C30carboxylic acid with glycerol; and also mixtures thereof.Silicone waxThe term “silicone wax” means an oil comprising at least one silicon atom and notably comprising Si-O groups.As silicone wax, examples that may be mentioned include siliconized beeswax, mixtures comprising a compound of C30-45 Alkyldimethylsilyl Polypropylsilsesquioxane (INCI name) type, for example the product Dow Corning SW-8005 C30 Resin Wax sold by the company Dow Corning. Mention may also made of mixtures comprising a compound of the C30-45 Alkyl Methicone (INCI name) type, for instance the product Dow Corning® AMS-C30 Cosmetic Wax. Preferably, the silicone wax is C30-45 alkyldimethylsilyl polypropylsilsesquioxane. It should be noted that this wax is not considered as a film-forming polymer of the silicone resin type.The wax content, if the composition comprises any, advantageously ranges from 0.1% to 3% by weight, in particular from 0.2% to 2% by weight, relative to the total weight of the composition.According to one embodiment, the composition comprises at least one wax chosen from total esters of a saturated, optionally hydroxylated C16-C30carboxylic acid with glycerol. The term “total esters” means that all the hydroxyl functions of glycerol are esterified. By way of example, mention may be made of glyceryl trihydroxystearate (or trihydroxystearine), glyceryl tristearate (or tristearin), glyceryl tribehenate (or tribehenin), alone or as mixtures, preferably glyceryl tribehenate.If the composition comprises any, the content of total ester of an optionally hydroxylated, saturated C16-C30 carboxylic acid with glycerol represents from 0.1% to 3% by weight and more particularly from 0.2% to 2% by weight, relative to the total weight of the composition.Preferably, if the composition comprises any, the silicone wax content does not exceed 3% by weight relative to the total weight of the composition. Preferably, if the composition comprises any, the silicone wax content is between 0.2% and 2% by weight relative to the total weight of the composition; preferably, it does not comprise any.Pasty compoundThe composition according to the invention may also comprise at least one compound which is pasty at room temperature and atmospheric pressure.For the purposes of the present invention, the term “pasty” refers to a lipophilic compound with a reversible solid / liquid change of state, notably having in the solid state an anisotropic crystal organization, and including at room temperature a liquid fraction and a solid fraction.In other words, the starting melting point of the pasty compound may be lower than room temperature. The liquid fraction of the pasty compound, measured at room temperature, may represent 9% to 97% by weight of the pasty compound. This fraction that is liquid at room temperature preferably represents between 15% and 85%, more preferably between 40% and 85%, by weight.The melting point of the pasty fatty substance is determined according to the same principle as that described in detail previously for the waxes.In the case of a pasty compound,the measurement protocol is, however, as follows:A sample of 5 mg of pasty fatty substance placed in a crucible is subjected to a first temperature rise ranging from -20°C to 100°C, at a heating rate of 10°C / minute, is then cooled from 100°C to -20°C at a cooling rate of 10°C / minute and is finally subjected to a second temperature rise ranging from -20°C to 100°C at a heating rate of 5°C / minute.The melting point of the pasty fatty substance is the value of the temperature corresponding to the top of the peak on the curve representing the variation in the difference in power absorbed as a function of the temperature.It should be noted that the liquid fraction by weight of the pasty fatty substance at room temperature is equal to the ratio of the heat of fusion consumed at room temperature to the heat of fusion of the pasty fatty substance.The heat of fusion of the pasty fatty substance is the heat consumed by said substance in order to pass from the solid state to the liquid state. The pasty fatty substance is said to be in the solid state when all of its mass is in crystalline solid form. The pasty fatty substance is said to be in the liquid state when all of its mass is in liquid form.The heat of fusion of the pasty fatty substance is the amount of energy required to make the pasty fatty substance change from the solid state to the liquid state. It is expressed in J / g. The heat of fusion of the pasty fatty substance is equal to the area under the curve of the thermogram obtained.The pasty compound may in particular be chosen from synthetic pasty compounds and fatty substances of plant origin.The pasty compound(s) may in particular be chosen from:- lanolin and derivatives thereof, such as lanolin alcohol, oxyethylenated lanolins, acetylated lanolin, lanolin esters such as isopropyl lanolate, and oxypropylenated lanolins,- petroleum jelly (also known as petrolatum),- ethers of pentaerythritol and of C2-C4, polyalkylene glycol, for example the compounds having the following INCI names: PEG-5 Pentaerythrityl Ether, PPG-5 Pentaerythrityl Ether, and mixtures thereof. Mention may be made, for example, of the mixture sold under the name Lanolide by the company Vevy,- liposoluble polyethers resulting from polyetherification between one or more C2-C100and preferably C2-C50diols. Among the liposoluble polyethers, consideration is given in particular, to copolymers of ethylene oxide and / or of propylene oxide with long-chain C6-C30alkylene oxides, more preferably such that the weight ratio of the ethylene oxide and / or propylene oxide to alkylene oxides in the copolymer is from 5:95 to 70:30. In this family, mention will notably be made of the product having the INCI name PEG-45 / Dodecyl Glycol Copolymer sold, for example, under the brand name Elfacos ST9 by the company Akzo Nobel,- esters resulting from the condensation of a preferably saturated, linear or branched, C6-C10dicarboxylic acid and of an ester of diglycerol and of optionally hydroxylated, preferably saturated, linear or branched, C6-C20monocarboxylic acids, in particular the diester obtained by condensation of adipic acid and of a mixture of esters of diglycerol with a mixture of C6-C20fatty acids, such as caprylic acid, capric acid, stearic acid, isostearic acid and 12-hydroxystearic acid, notably sold under the reference Softisan® 649 by the company Cremer Oleo (INCI name: Bis-Diglyceryl Polyacyladipate-2),- triglycerides of fatty acids which are optionally hydrogenated (totally or partially), saturated or unsaturated, linear or branched, optionally mono- or polyhydroxylated, preferably C12-C18; for instance the glycerides of saturated C12-C18fatty acids sold under the name Softisan 100® by the company Cremer Oleo (INCI name: Hydrogenated Coco-Glycerides),- esters of diol dimer, or of polyol, and of diacid dimer, for instance:* esters of dimer of dilinoleyl alcohol and of dilinoleic acid, the hydroxyl groups of which are esterified with a mixture of phytosterols, of behenyl alcohol and of isostearyl alcohol, for example the ester sold under the name Plandool G by the company Nippon Fine Chemical (INCI name: Bis-Behenyl / Isostearyl / Phytosteryl Dimer Dilinoleyl Dimer Dilinoleate);* esters of dilinoleic acid and of a mixture of phytosterols, of isostearyl alcohol, of cetyl alcohol, of stearyl alcohol and of behenyl alcohol, for example the ester sold under the name Plandool H or Plandool S by the company Nippon Fine Chemical (INCI name: Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate);- butters of plant origin, such as mango butter, such as the product sold under the name Lipex 203 by the company Aarhuskarlshamn, shea butter, in particular the product whose INCI name is Butyrospermum Parkii Butter, such as the product sold under the reference Sheasoft®by the company Aarhuskarlshamn, cupuacu butter (Rain Forest RF3410 from the company Beraca Sabara), murumuru butter (Rain Forest RF3710 from the company Beraca Sabara), cocoa butter; and also orange wax, for instance the product sold under the reference Orange Peel Wax by the company Koster Keunen,- totally or partially hydrogenated plant oils, for instance hydrogenated soybean oil, hydrogenated coconut kernel oil, hydrogenated rapeseed oil, mixtures of hydrogenated plant oils such as the mixture of hydrogenated soybean, coconut kernel, palm and rapeseed plant oil, for example the mixture sold under the reference Akogel®by the company Aarhuskarlshamn (INCI name Hydrogenated Vegetable Oil), the trans-isomerized partially hydrogenated jojoba oil manufactured or sold by the company Desert Whale under the commercial reference Iso-Jojoba-50®, partially hydrogenated olive oil, for instance the compound sold under the reference Beurrolive by the company Soliance,- hydrogenated castor oil esters, such as hydrogenated castor oil dimer dilinoleate, for example Risocast-DA-L sold by Kokyu Alcohol Kogyo, and hydrogenated castor oil isostearate, for example Salacos HCIS (V-L) sold by Nisshin Oil,- and mixtures thereof;If the composition comprises at least one pasty compound, its / their content ranges from 0.5% to 5% by weight and preferably from 0.5% to 3% by weight, relative to the total weight of the composition.Dextrin esterThe composition may optionally comprise at least one ester of dextrin and of a fatty acid, in particular a C12 to C24, preferably C14 to C18, fatty acid, or mixtures thereof. More preferentially, the dextrin ester is an ester of dextrin and of a C12-C18 and in particular C14-C18 fatty acid. Preferably, the dextrin ester is chosen from dextrin palmitate and dextrin myristate. These dextrin esters are, for example, commercially available, notably under the name Rheopearl from the company Chiba Flour Milling Co.If the composition comprises any, their content ranges from 0.5% to 8% by weight, preferably from 0.5% to 5% by weight, relative to the total weight of the composition.The invention also relates to a process for making up and / or caring for the skin and / or the lips, in particular the lips, in which the composition according to the invention is applied.It is also pointed out that the compositions according to the invention more particularly comprise a cosmetically (or physiologically) acceptable medium, i.e. one which has a pleasant color, odor and feel and which does not give rise to any unacceptable discomfort, i.e. stinging, tautness or redness, that is liable to discourage the user from applying such compositions.Throughout the description, including the claims, the expression “comprising a” should be understood as being synonymous with “comprising at least one”, unless otherwise specified; “at least one” meaning “one or more”.The expressions “between ... and ...” and “ranging from ... to ...” should be understood as meaning limits included, unless otherwise specified.Unless otherwise indicated, the contents are expressed as the active material of the ingredient(s) under consideration.In addition, the sum of the amounts of the ingredients of the composition represents 100% by weight of the composition.The invention is illustrated in greater detail by the examples presented below.The starting materials are referred to by their chemical name or their INCI name.EXAMPLESProtocol for measuring the viscosityThe viscosity measurement is performed with a sample of composition at 25°C, at least 24 hours after its manufacture (storage at room temperature), using a Rheomat RM180 viscometer equipped with a No. 2, 3 or 4 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the formulation, at a shear rate of 200 revolutions / minute (rpm).Protocol for measuring the tackMaterials used:* White supplale strip 150 cm×25 cm (Supplier: Soudotique, reference: DFSUP15025B)* White supplale ring 38 mm diameter (Supplier: Soudotique, reference: DESUPDIAM38B)* Stable Micro Systems Texturometer (model: TA.XT. plus) and its “Exponent” software* Mobile measuring ring allowing the 38 mm diameter supplale ring to be attached.Preparation of the deposit:*Delineate the length of the deposit (10 cm) on a white supplale strip.* Apply the composition packaged in a hot-water bottle with a dipping applicator, so as to obtain four layers, in the following manner:a) remove the applicator without wiping off the excess on the edges and, on the “leather” side of the support, apply the composition along the 10 cm length. Make as many passes as required, always in the same direction, along the entire length and without turning the applicator over, to obtain a deposit of uniform thickness. (= application 1);b) rotate the supplale strip through 180° (in such a manner that the second layer of composition is applied in the opposite direction);c) remove the applicator without wiping the excess from the edges, and apply a new layer of composition over the preceding one, along the length of the 10 cm applied, under the same conditions as in step 1 (= application 2);- repeat steps b) and c) twice;* Leave to dry for 1 hour on a hotplate at 32°C.Measure the tack with a texturometer:The test parameters are indicated below:Approach speed(or pre-speed)1 mm / sSpeed(from detection of contact)0.5 mm / sWithdrawal speed(or post-speed)40 mm / sForce(and corresponding pressure)800 gHolding time5 sTrigger Force5 gMaximum following speed5 mm / sThe tack is characterized by the disbonding work measured during discharge (tensile phase), corresponding to the peak force (expressed positively in g) and the area (expressed positively in g / sec) under the time axis.The higher the peak force value, the tackier the deposit.Three samples are prepared and two measurements are taken on the same sample: the first at the center of the sample, the second at a different point on the sample, not at the ends of the strip. A new white supplale ring is placed in the mobile for each new measurement.The result is the mean of the three sample measurements.Protocol for measuring the staying power and the transfer1. Preparation of the test:Support:Beige Supplale (2.5 x 5 cm) (sold by Soudotique).Spread composition (D) over the entire surface three times in a row in order to have a uniform deposit. Repeat the operation on two other strips.Allow the deposit to dry on a plate heated at 32°C for 45 minutes.If necessary, take a photo of each support with the deposit (made up) before stressing.2. Stresses:Preparation of a paper tissue for each stress:Fold each paper tissue twice along the long edge and then twice in the other direction to form a square.Dry resistance:Rub once with the folded tissue lengthwise against one of the three made-up supports; the force applied is that normally exerted when removing makeup from the skin or the lips.Observe the state of the rubbed support and the used surface of the tissue, in particular the remaining color and the transferred color.If necessary, take a photo.It should be noted that the transfer resistance is evaluated with this stress.If several passes are made, they should be performed with the same force and always in the same direction (i.e. after each pass, the tissue is lifted to be repositioned at the "start" of the strip so as to be reapplied on the deposit in the same way as in the previous pass). If necessary, take a photo between each step or only at the end of the evaluation. This type of process can be used to evaluate the overall resistance of the deposit.Water resistance:Insert the second made-up support, without folding it, into a centrifuge tube.Add 10 grams of demineralized water.Centrifuge for 10 minutes at 450×g.If necessary, take a photo of the support after mixing, immediately after the operation.Rub once with a tissue along the length of the support, without waiting, with the same force as that applied for the dry resistance.Observe the state of the rubbed support and also the used surface of the tissue, in particular the remaining color and the transferred color.If necessary, take a photo.The protocol for multiple passes is the same as that detailed previously for the dry resistance.Oil resistance:Perform the same protocol as for the water resistance, on the third made-up support, replacing the water with the same amount of olive oil (Refined Olive Oil - Aarhuskarlshamn).Grading:For each stress, record the result according to the table below:DepositgradeState of the depositTissuegradeSurface of the tissue in contact with the deposit- -Total or partial removal of the deposit from the rubbed area; the surface of the support appears in places5Very intense coloring - very substantial to total color transfer-Partial removal resulting in significantly and visibly less intense coloring of the deposit.4Intense coloring - substantial color transfer+Decrease in color intensity of the deposit which is noticeable but does not reveal the support3Medium coloring - moderate color transfer++No substantial change in the deposit color2Slight coloring - little color transfer+++No variation in the deposit color1No coloring or barely visible coloring - very little or no color transferExample 11. CompositionThe following compositions, the list of ingredients and the mass percentage contents of which are collated in the table below, was prepared. Composition 1 is in accordance with the invention; compositions A and B are comparative compositions since they contain no pullulan.PhasesIngredients (INCI name)Composition 1Composition AComposition BA1Polyglyceryl-6 Polyricinoleate (SY-Glyster CRS-75, Sakamoto Yakuhin)3.443.443.44A1Dicaprylyl ether (Cetiol OE, BASF)1.151.151.15A1Undecane (and) Tridecane (Cetiol UT, BASF)25.2225.2225.22A2Disteardimonium Hectorite (Bentone 38 VCG, Elementis)1.371.371.37A3Calcium carbonate Omyacare Extra 35-OG, Omya)5.755.755.75B1Water30.7638,4533,45B1Pullulan (Pullulan cosmetic grade, Hayashibara)7.69--B1Hydroxypropylguar (Jaguar HP 105 SGI, Solvay)--5B2Glycerol555B2Denatured alcohol9.629.629.62CMica (Mearlmica SV, Sun Chemicals)2.52.52.5CRed 7 (Unipure Red LC 3079, Sensient)7.57.57.52. Preparation of the compositionsPreparation of aqueous phase B: at room temperature, mix B1 at 3500 rpm for 5 minutes in a speedmixer, then introduce B2 and continue stirring for 5 minutes at 3500 rpm.Preparation of the fatty phase A: in a beaker, mix the ingredients of phase A1, with stirring using a Rayneri rotor-stator blender for 5 minutes, then add A2 and continue stirring for 10 minutes, then finally introduce A3 when the mixture is homogenized and leave stirring for a further 10 minutes.Preparation of the emulsion: produce the emulsion by slowly pouring the aqueous phase B obtained into the preceding preparation A, with stirring using a Rayneri rotor-stator blender.Leave stirring for 10 minutes at 3300 rpm.Preparation of phase C: place the ingredients of phase C in the bowl of an IKA MV20 mill and blend at maximum speed four times for 15 seconds, taking care after each 15 seconds to loosen any powder that may have adhered to the walls.Finally, add the phase C thus obtained with stirring using a Rayneri blender at 100 rpm for 10 minutes until the composition is homogeneous.3. Evaluation of the compositionsCompositionCommentsComposition 1inventionHomogeneous composition, no leaching after 24 hours at room temperature.On making up the lips, composition 1 is applied very easily with a dipping applicator, affording a uniform, intense matte color.The film obtained after drying is sparingly tacky, comfortable, does not transfer and does not migrate into the fine lines.Composition AcomparativeHomogeneous composition, no leaching after 24 hours at room temperature.On making up the lips, composition A is applied easily with a dipping applicator, affording a uniform, intense matte color.The film obtained after drying is sparingly tacky, comfortable, but transfers and migrates slightly into the fine lines.Composition BcomparativeHeterogeneous, lumpy and unstable composition which could not be evaluated.An attempt was made to prepare a comparative composition C in which the pullulan was replaced by the same content of hydroxypropylguar. The aqueous phase obtained is very compact, does not flow and does not make it possible to prepare the emulsion.An attempt was also made to prepare a comparative composition D in which the pullulan was replaced by the same content of another polysaccharide, hydroxyethylcellulose (Cellosize HEC QP 4400H Europe PCG from Dow, content 7.69% by weight) but the aqueous phase obtained did not make it possible to prepare the emulsion.The deposits of composition 1 and comparative composition A were evaluated in a test of resistance to mechanical stress and chemical attack (dry rubbing, water and oil) according to the staying power and transfer protocol detailed previously.The table below collates the results obtained:Composition 1Composition AType of attackDryWaterOilDryWaterOilGrade: state of the deposit++++++++++Grade: surface state of the tissue in contact with the deposit113224Surprisingly, an improvement in the resistances to transfer is observed in all the cases of the test, in particular good water resistance, whereas pullulan is a water-soluble polymer. Thus, the evaluation of the resistance to transfer of the aqueous phase alone of the composition 1 shows a good dry staying power and oil staying power but not a good water staying power.Example 21. CompositionThe following composition, the list of ingredients and the mass percentage contents of which are collated in the table below, was prepared:PhasesIngredients (INCI name)Composition 2A1Polyglyceryl-6 Polyricinoleate (SY-Glyster CRS-75, Sakamoto Yakuhin)3.44A1Dicaprylyl Ether (Cetiol OE, BASF)1.15A1Undecane (and) Tridecane (Cetiol UT, BASF)25.22A2Disteardimonium Hectorite (Bentone 38 VCG, Elementis)1.37A3Calcium Carbonate (Omyacare Extra 35-OG, Omya)5.75B1Water35.76B1Pullulan (Pullulan cosmetic grade, Hayashibara)7.69B2Denatured alcohol9.62CMica (Mearlmica SV, Sun Chemicals)2.5CRed 7 (Unipure Red LC 3079 Sensient)7.52. Preparation of the compositionsPreparation of aqueous phase B: at room temperature, mix B1 at 3500 rpm for 5 minutes in a speedmixer, then introduce B2 and continue stirring for 5 minutes at 3500 rpm.Preparation of the fatty phase A: in a beaker, mix the ingredients of phase A1, with stirring using a Rayneri rotor-stator blender for 5 minutes, then add A2 and continue stirring for 10 minutes, then finally introduce A3 when the mixture is homogenized and leave stirring for a further 10 minutes.Preparation of the emulsion: produce the emulsion by slowly pouring the aqueous phase B obtained into the preceding preparation A, with stirring using a Rayneri rotor-stator blender.Leave stirring for 10 minutes at 3300 rpm.Preparation of phase C: place the ingredients of phase C in the bowl of an IKA MV20 mill and blend at maximum speed four times for 15 seconds, taking care after each 15 seconds to loosen any powder that may have adhered to the walls.Finally, add the phase C thus obtained with stirring using a Rayneri blender at 100 rpm for 10 minutes until the composition is homogeneous.3. Evaluation of the compositionsThe composition is homogeneous and stable at 24 hours, i.e. it does not exhibit leaching.On making up the lips, composition 2 is applied very easily with a dipping applicator, affording a uniform, intense matte color.The film obtained after drying is sparingly tacky, comfortable, does not transfer and does not migrate into the fine lines.The deposit was evaluated in a test of resistance to mechanical stress and chemical attack (dry rubbing, water and oil) according to the staying power and transfer protocol detailed previously.The table below collates the results obtained:Composition 2Type of attackDryWaterOilGrade: state of the deposit+++++Grade: surface state of the tissue in contact with the deposit223Composition 2 has staying power properties similar to composition 1, with dry, water and oil transfer resistances which remain acceptable. Under the conditions of the invention, it is observed, surprisingly, that the presence of glycerol improves the properties of the composition.Example 31. CompositionThe following composition, the list of ingredients and mass percentage contents of which are collated in the table below, were prepared.PhasesIngredients (INCI name)Composition 3A1Polyglyceryl-6 Polyricinoleate (SY-Glyster CRS-75, Sakamoto Yakuhin)3.44A1Dicaprylyl Ether (Cetiol OE, BASF)1.15A1Isododecane (Isodecane, Ineos)22.97A2Disteardimonium Hectorite (Bentone 38 VCG, Elementis)1.37A3Calcium Carbonate (Omyacare Extra 35-OG, Omya)8B1Water30.76B1Pullulan (Pullulan cosmetic grade, Hayashibara)7.69B2Glycerol5B2Denatured alcohol9.62CMica (Mearlmica SV, Sun Chemicals)2.5CRed 7 (Unipure Red LC 3079, Sensient)7.52. Preparation of the compositionsPreparation of aqueous phase B: at room temperature, mix B1 at 3500 rpm for 5 minutes in a speedmixer, then introduce B2 and continue stirring for 5 minutes at 3500 rpm.Preparation of the fatty phase A: in a beaker, mix the ingredients of phase A1, with stirring using a Rayneri rotor-stator blender for 5 minutes, then add A2 and continue stirring for 10 minutes, then finally introduce A3 when the mixture is homogenized and leave stirring for a further 10 minutes.Preparation of the emulsion: produce the emulsion byslowly pouring the aqueous phase B obtained into the preceding preparation A, with stirring using a Rayneri rotor-stator blender.Leave stirring for 10 minutes at 3300 rpm.Preparation of phase C: place the ingredients of phase C in the bowl of an IKA MV20 mill and blend at maximum speed four times for 15 seconds, taking care after each 15 seconds to loosen any powder that may have adhered to the walls.Finally, add the phase C thus obtained with stirring using a Rayneri blender at 100 rpm for 10 minutes until the composition is homogeneous.3. Evaluation of the compositionsThe composition is homogeneous and stable at 24 hours, i.e. it does not exhibit leaching.On making up the lips, composition 3 is applied very easily with a dipping applicator, affording a uniform, intense matte color.The film obtained after drying is sparingly tacky, comfortable, does not transfer and does not migrate into the fine lines.The deposit was evaluated in a test of resistance to mechanical stress and chemical attack (dry rubbing, water and oil) according to the staying power and transfer protocol detailed previously.The table below collates the results obtained:Composition 3Type of attackDryWaterOilGrade: state of the deposit+++++Grade: surface state of the tissue in contact with the deposit122

Claims

A cosmetic composition for making up human keratin materials, in particular the skin and / or the lips, preferably the lips, in the form of a water-in-oil emulsion comprising:- at least 5% by weight of pullulan relative to the total weight of the composition;- at least 20% by weight, relative to the total weight of the composition, of at least a first apolar hydrocarbon-based oil comprising from 8 to 16 carbon atoms;- at least one lipophilic mineral thickener,- at least one dyestuff.The composition as claimed in claim 1, characterized in that the pullulan content is between 5% and 15% by weight, more particularly between 5% and 10% by weight, relative to the total weight of the composition.The composition as claimed in either of the preceding claims, characterized in that the first apolar hydrocarbon-based oil is chosen from branched C8-C16 alkanes preferably such as isododecane, isodecane, isohexadecane, C8-9 isoalkane, C11-13 isoalkane, and mixtures thereof; from linear alkanes, preferably C8-C14 alkanes, and mixtures thereof, preferably such as n-dodecane, n-tetradecane, C9-12 alkane, the undecane-tridecane mixture; and also mixtures thereof; and preferably from isododecane, C9-12 alkane, undecane and tridecane, alone or as mixtures.The composition as claimed in any one of the preceding claims, characterized in that the content of apolar hydrocarbon-based first oil(s) represents from 20% to 50% by weight and preferably from 20% to 40% by weight relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that the mineral thickener is chosen from lipophilic clays, more particularly from lipophilic clays of the hectorite type comprising at least one quaternary ammonium group, bentonites comprising at least one quaternary ammonium group, or mixtures thereof, and preferably from disteardimonium hectorite, stearalkonium hectorite, Quaternium-18 hectorite, and also mixtures thereof, and even more preferentially disteardimonium hectorite.The composition as claimed in any one of the preceding claims, characterized in that the content of mineral thickener is between 0.5% and 4% by weight and preferably between 0.75% and 3% by weight relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that the water content is at least 20% by weight, preferably between 20% and 50% by weight, and more preferably between 20% and 40% by weight, relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that the composition optionally comprises at least one second oil, different from the first oil(s), chosen from nonvolatile, polar or apolar hydrocarbon-based oils, from volatile or nonvolatile silicone oils, and also mixtures thereof.The composition as claimed in the preceding claim, characterized in that the second oil is chosen from polar nonvolatile hydrocarbon-based oils such as:- C10-C26 alcohols;- ethers of formula ROR’ or carbonates of formula RO(CO)OR’, in which formulae the groups R and R’, which may be identical or different, represent a saturated or unsaturated, branched or unbranched, hydrocarbon-based group comprising not more than 16 carbon atoms;- oils comprising one or more ester functions and comprising at least one linear or branched, saturated, unsaturated or aromatic hydrocarbon-based group comprising at least 6 carbon atoms, preferably at least 8 carbon atoms; the ester oil may optionally comprise one or more ether or hydroxyl functions;- liquid polyesters derived from the reaction of a monounsaturated or polyunsaturated acid dimer, the fatty acid comprising from 16 to 22 carbon atoms;- and also mixtures thereof;and preferably from plant oils; ester oils, comprising 1 to 4 ester functions, and comprising at least one linear or branched, saturated, unsaturated or aromatic hydrocarbon-based group, comprising at least 6 carbon atoms, preferably at least 8 carbon atoms; the ester oil may optionally comprise one or more ether or hydroxyl functions; ether oils of formula ROR’ in which R and R’, which may be identical or different, represent a saturated or unsaturated, branched or unbranched hydrocarbon-based group comprising not more than 16 carbon atoms; mixtures thereof.The composition as claimed in either of claims 8 and 9, characterized in that the content of second oil(s), if the composition comprises any, does not exceed 15% by weight, and preferably ranges from 0.1% to 15% by weight relative to the total weight of the composition.The composition as claimed in claim 8, characterized in that if the composition comprises at least one volatile or nonvolatile silicone oil, then their content does not exceed 5% by weight, advantageously does not exceed 3% by weight, and preferably does not exceed 1% by weight, relative to the total weight of the composition; preferably, the composition does not contain any.The composition as claimed in any one of the preceding claims, characterized in that the dyestuff is chosen from pulverulent dyestuffs, liposoluble dyes, water-soluble dyes and mixtures thereof.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one nonionic hydrocarbon-based or silicone surfactant with an HLB of less than or equal to 8, chosen from (poly)oxyethylenated or (poly)oxypropylenated C8-C30 alcohols, (poly)oxyethylenated or (poly)oxypropylenated C8-C30 esters, preferably polyhydroxylated C12-C20 fatty acid polyesters, which are polyoxyalkylenated, containing from 4 to 50 mol ethylene oxide, (C8-C30)alkyl and poly(C8-C30)alkyl sorbitan esters, (C8-C30)alkyl and poly(C8-C30)alkyl (poly)glycerol esters, alone or as mixtures; nonionic silicone surfactants chosen from oxyalkylenated (C2-C3) polydimethylmethylsiloxanes with an HLB ≤ 8, preferably having the following INCI names: PEG / PPG-8 / 8 Dimethicone, Bis-PEG / PPG-14 / 14 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG-3 Dimethicone, PEG-10 Dimethicone, and also mixtures thereof.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one polyglycerolated nonionic hydrocarbon-based surfactant with an HLB ≤ 8, more particularly chosen from:- polyglycerol esters of isostearic acid containing from 2 to 10 mol of glycerol units, such as polyglyceryl-4 isostearate, polyglyceryl-3 diisostearate; polyglyceryl-2 diisostearate, polyglyceryl-10 isostearate, polyglyceryl-2 triisostearate;- polyglycerol esters of stearic acid containing from 2 to 3 mol of glycerol units, such as polyglyceryl-2 sesquistearate, polyglyceryl-3 distearate, polyglyceryl-2 stearate;- polyglycerol esters of oleic acid containing from 2 to 3 mol of glycerol units, such as polyglyceryl-2 oleate, polyglyceryl-3 oleate, polyglyceryl-2 dioleate; polyglyceryl-3 dioleate;- polyglyceryl polyricinoleate(s) containing from 3 to 6 mol of glycerol units, such as polyglyceryl-3 polyricinoleate; polyglyceryl-5 polyricinoleate; polyglyceryl-6 polyricinoleate;- mixtures thereof.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one polyglycerolated, nonionic hydrocarbon-based surfactant chosen from polyglyceryl polyricinoleate(s) containing from 3 to 6 mol of glycerol units, in particular polyglyceryl-6 polyricinoleate.The composition as claimed in any one of claims 13 to 15, characterized in that the content of hydrocarbon-based or silicone surfactant(s), preferably nonionic hydrocarbon-based surfactants, represents from 2% to 10% by weight and preferably from 2% to 7% by weight, relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one saturated or unsaturated, linear or branched C2-C8 and preferably C3-C6 polyol that is liquid at room temperature, comprising from 2 to 6 hydroxyl groups; more particularly chosen from glycerol, diglycerol, linear or branched, saturated C3-C8 glycols or alkanediols, in particular propylene glycol, propanediol, butylene glycol, pentanediol, pentylene glycol, caprylyl glycol or dipropylene glycol, and also mixtures thereof, and preferably glycerol.The composition as claimed in the preceding claim, characterized in that the polyol content ranges from 3% to 20% by weight and in particular from 4% to 15% by weight, relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one C2-C6, more particularly C2-C4, monoalcohol, preferably chosen from ethanol, isopropanol, tert-butanol or butanol, or mixtures thereof, and preferably at least ethanol.The composition as claimed in the preceding claim, characterized in that the monoalcohol content represents from 3% to 20% by weight and preferably from 5% to 15% by weight relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that it comprises at least one wax chosen from total esters of an optionally hydroxylated, saturated C16-C30 carboxylic acid with glycerol, preferably glyceryl trihydroxystearate, glyceryl tristearate or glyceryl tribehenate, alone or as a mixture, preferably glyceryl tribehenate.The composition as claimed in the preceding claim, characterized in that the content of waxes chosen from total esters of an optionally hydroxylated, saturated C16-C30 carboxylic acid with glycerol represents from 0.1% to 3% by weight and more particularly from 0.2% to 2% by weight, relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that it comprises:- at least one mineral filler chosen from silica, perlite, zeolites, carbonate or hydrogen carbonate of alkaline-earth metals such as calcium or magnesium, hydroxyapatite, kaolin, talc, synthetic or natural mica, boron nitride, glass or ceramic microcapsules, barium sulfate, diatomaceous earth, mixtures thereof; preferably chosen from kaolin, mica, calcium carbonate and silica, and also mixtures thereof;- organic fillers chosen from natural or synthetic micronized waxes, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, polysaccharide powders, cellulose, N-acylamino acids containing from 8 to 22 carbon atoms, polyhdyroxyalkanoates, particles of acrylic (co)polymers, acrylonitrile (co)polymers, polyurethane, silicone polymers, polyamide, tetrafluoroethylene, and mixtures thereof, preferably chosen from cellulose, C8-C22 N-acylamino acids, and mixtures thereof;- mixtures thereof.The composition as claimed in the preceding claim, characterized in that the content of mineral filler represents from 2% to 20% by weight and preferentially from 3% to 15% by weight relative to the total weight of the composition.The composition as claimed in claim 23, characterized in that the content of organic filler represents from 2% to 10% by weight and more particularly from 3% to 8% by weight relative to the total weight of the composition.The composition as claimed in any one of the preceding claims, characterized in that the composition optionally comprises at least one silicone film-forming polymer chosen more particularly from silicone resins, silicone acrylate copolymers, silicone acrylamide copolymers, or mixtures thereof, at a content of less than 2% by weight, more particularly not exceeding 1% by weight, preferably not exceeding 0.5% by weight, relative to the total weight of the composition; preferably, the composition is devoid thereof.A process for making up human keratin materials, in particular the skin and / or the lips, preferably the lips, in which the composition as claimed in any one of the preceding claims is applied.

Citation Information

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