Cosmetic premix composition and methods for makeup removal
A two-step cosmetic premix composition and method efficiently removes long-wear makeup by using a hydrophobic polymer in the first anhydrous composition to dissolve makeup, followed by a second composition that solidifies it for easy removal, addressing the inefficiencies of existing products.
Patent Information
- Application Number
- PCT/US2024/060692
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2024-02-27
- Filing Date
- 2024-12-18
- Publication Date
- 2025-06-26
AI Technical Summary
Existing makeup removal products are often messy, difficult to use, and leave behind a greasy residue, making them inefficient for removing long-wear makeup without disrupting the skin's barrier.
A two-step cosmetic premix composition and method for makeup removal, where a first anhydrous composition with a hydrophobic polymer is applied to dissolve and dislodge makeup, followed by a second anhydrous composition that causes the makeup and polymer to solidify and coagulate for easy removal.
The method effectively dissolves and removes long-wear makeup without leaving a residue, providing a gentle and efficient cleansing experience for the skin.
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Abstract
Description
[0001] Attorney Docket No.085137-824799 TITLE COSMETIC PREMIX COMPOSITION AND METHODS FOR MAKEUP REMOVAL CROSS-REFERENCE TO RELATED APPLICATIONS This application claims benefit of U.S. Serial No.18 / 544,330 filed December 18, 2023, U.S. Serial No.18 / 543,619, filed December 18, 2023, and benefit of French Application No. FR 2401688, filed on February 21, 2024, and French Application No. FR 2401884, filed on February 27, 2024, which are incorporated herein by reference in their entirety. FIELD OF THE DISCLOSURE The instant disclosure is drawn to a cosmetic premix composition, a cosmetic compositions comprising the cosmetic premix composition, and methods of use, including a method for cleansing skin using a two-step cleansing procedure. A first anhydrous composition is comprising a unique hydrophobic polymer is initially applied to skin, upon which makeup is present, followed by application of a second anhydrous composition. BACKGROUND This section is intended to introduce the reader to various aspects of art, which may be related to various aspects of the present invention that are described and / or claimed below. This discussion is believed to be helpful in providing the reader with background information to facilitate a better understanding of the various aspects of the present invention. Accordingly, it should be understood that these statements are to be read in this light, and not as admissions of prior art. Cosmetic chemists often experiment with new materials, or materials not typically utilized in the cosmetic industry. One such material is a reaction product of an acrylate and a natural or food-derived oil (such as linseed oil). However, such a material can be difficult to incorporate due to a high viscosity. As such, cosmetic grade solvents are identified for ease of processing to incorporate the reaction product into various cosmetic formulations. Many cosmetic compositions, including pigmented cosmetics such as foundations, mascaras, lipsticks, and eye shadows, have been formulated to have long-wear and transfer-resistance properties. Such properties are typically obtained Attorney Docket No.085137-824799 by incorporating one or more film-forming agents into the compositions, such as oil- soluble film formers (or waxes), water-soluble film-formers, or resins (e.g., silicone resins like MQ resins). After application, the film-forming agents form a film that provides long-wear and transfer-resistance properties. However, these compositions and films can be difficult to remove, particularly if different types of film forming agents are included in the compositions. Stubborn makeup may cause consumers to scrub, rub, and tug at sthe kin, which can disrupt skin’s protective barrier, especially around delicate areas around the eyes. In addition, sleeping without removing makeup from the skin can cause a build-up and clog pores, leading to acne, inflammation, and skin irritation. Therefore, makeup removing products and procedures are needed. Makeup removing products are formulated to break down and remove makeup, excess oil, and dirt from the skin. Several types of skin cleansing and makeup removing products have been developed, for example, rinsible anhydrous oils and gels, foaming creams, and lotions. Rinsible, anhydrous oils and gels have impart cleansing or makeup removing actions by virtue of the oils included in these formulations. The oils dissolve fatty residues and disperse make-up pigments. Although they are effective for dissolving certain elements of makeup compositions, they tend to be messy and difficult to use. Also, anhydrous makeup removing compositions tend to leave behind a greasy or oily residue, which can require additional effort to remove. Therefore, a need for improved makeup removing compositions and methods that are simple, effective, and gentle to the skin are needed. SUMMARY OF THE DISCLOSURE A cosmetic premix composition is disclosed, which is useful in the preparation of cosmetic products including products for removing makeup from the skin. The instant disclosure is also drawn to a method for removing makeup from skin, including long-wear makeup. The method relies on a unique two-step process, wherein a first anhydrous composition is initially applied to the skin to dissolve and dislodge makeup present on the skin. A second anhydrous composition is subsequently used. The second anhydrous composition is applied without removing the first anhydrous composition from the skin. The second anhydrous composition is Attorney Docket No.085137-824799 applied to the first anhydrous composition with which the makeup is dissolved or dislodged. Application of the second anhydrous composition results in the first anhydrous composition and the makeup dissolved within the first anhydrous composition, and the makeup dislodged by the first anhydrous composition, to solidify or coagulate for easy removal, for example, by peeling the material from the skin or by wiping or rinsing away the solidified or coagulated material. The process is surprisingly effective and provides the consumer with a unique cleansing experience. The first anhydrous composition has a strong affinity for fatty materials, pigments, and other components of makeup, and efficiently solubilizes and dislodges the makeup, especially long-wear makeup. The first anhydrous composition and the solubilized or dislodged makeup is not appreciably soluble in the second anhydrous composition. Therefore, application of the second anhydrous composition causes precipitation, aggregation, and solidification of the first anhydrous composition and makeup that has been absorbed or dislodged from the skin. The cosmetic premix composition may include a solvent for the reaction product, the solvent having Hansen Solubility Parameters within a designated range, where the distance (Ra) between Hansen parameters in Hansen space must satisfyparticular requirements. Specifically, the parameters must satisfy ^^^^ ≤√4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra = 13.4 MPa0.5, D1= 16.8 MPa0.5, P1 bonding component (D), the polar component (P), and the dispersion component (H) may be defined by the selected solvent with units of MPa0.5. The one or more solvents may include, e.g., caprylic / capric triglyceride, isopropyl myristate, citronellyl acetate, acetone, triglycerides, or a combination thereof. In some embodiments, at least some of the triglycerides may be provided by a vegetable oil. The reaction product may be present in an amount of 10-80% by weight of the cosmetic premix composition. The natural or food-derived oil may be linseed oil. In various aspects, a method of manufacturing a cosmetic composition may be provided. The method may include providing a reaction product of an acrylate and a natural or food-derived oil. The method may include providing one or moresolvents. Each solvent may have Hansen Solubility Parameters that satisfy ^^^^ ≤√4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra = 13.4 MPa0.5, D1 = 16.8 MPa0.5, P1 Attorney Docket No.085137-824799 = 4.8 MPa0.5, and H1 = 13.0 MPa0.5. The method may include combining the reaction product and the one or more solvents to form a premix consisting of the reaction product and the one or more solvents. The one or more solvents may include, e.g., caprylic / capric triglyceride, isopropyl myristate, citronellol acetate, acetone, triglycerides, or a combination thereof. In some embodiments, at least some of the triglycerides provided by a vegetable oil. The reaction product may be present in an amount of 10-80% by weight of the cosmetic premix composition. The natural or food-derived oil may be linseed oil. In various aspects, a cosmetic composition may be provided. The cosmetic composition may include a premix as well as one or more additional materials. The premix may include a reaction product of an acrylate and a natural or food-derived oil as disclosed herein. The premix may include one or more solvents of the reaction product, , and one or more additional materials. Each solvent may have HansenSolubility Parameters that satisfy ^^^^ ≤ √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, whereRa = 13.4 MPa0.5, D1 = 16.8 The one or more additional materials may include one or more additionalsolvents having Hansen Solubility Parameters that satisfy ^^^^ >√4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra = 13.4 MPa0.5, D1 = 16.8 MPa0.5, P1 more additional materials includes one or more pigments, a filler, a polyol, a polyester of polyglycerol having 2 to 10 glycerol units, a glyceryl ester of a fatty acid, or a combination thereof. The first anhydrous composition typically includes: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (a); and (c) optionally, one or more alkanes. The second anhydrous composition includes one or more nonpolar oils in which the hydrophobic polymer of (a) is not soluble. The second anhydrous composition can optionally include one or more additional components, for example, one or more oil thickening agents, solid fatty compounds, for example, solid waxes, Attorney Docket No.085137-824799 and miscellaneous ingredients. The additional components, however, are often solubilized in the second anhydrous composition. The hydrophobic polymer is a reaction product of a natural or food-derived oil and an acrylate or methacrylate polymer. According to certain embodiments, the hydrophobic polymer is a reaction product of a natural or food-derived oil and a methacrylate polymer. The natural or food-derived oil may be a drying oil or a semi- drying oil. Nonlimiting examples include linseed oil, sunflower oil, tung oil, fish oil, cottonseed oil, soybean oil, or combinations thereof. The methacrylate polymer may be formed from methacrylate monomers, for example, monomers selected from isobutyl methacrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, and combinations thereof. In a preferred embodiment, the hydrophobic polymer is formed from a natural or food-derived oil and an isobutyl methacrylate polymer. In various embodiments, the hydrophobic polymer is the reaction product of about 50 to about 85 parts by weight of the natural or food-derived oil and about 15 to about 50 parts by weight of the methacrylate or acrylate polymer. More specifically, the hydrophobic polymer may be the reaction product of about 72 to about 77 parts by weight of the natural or food-derived oil and about 23 to about 28 parts by weight of a methacrylate polymer. For example, the hydrophobic polymer may be the reaction product of linseed oil and poly(isobutyl methacrylate) in a suitable solvent, such as, for example, 2,2,4-trimethyl-1, 3-pentanediol monoisobutyrate. Preferably, the reaction product is formed from about 72 to about 77% of linseed oil and about 23 to about 28 parts by weight of isobutyl methacrylate polymer in a suitable solvent, such as 2,2,4-trimethyl-1, 3-pentanediol monoisobutyrate. The hydrophobic polymer of (a) is solubilized in one or more solvents capable of solubilizing the hydrophobic polymer. A single solvent may be used or a combination of solvents, wherein the combination of solvents can solubilize the hydrophobic polymer. In various embodiments, the one or more solvents capable of solubilizing the hydrophobic polymer have a dispersion component (D), a polar component (P), a hydrogen bonding component (H), and a distance (Ra) per Hansen Solubility Parameters pf less than or equal to 13.4 MPa0.5, wherein the distance (Ra) is defined by formula (I): Attorney Docket No.085137-824799 ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2 (I) D1 is 16.8 MPa0.5, P1 is 4.8 MPa0.5, and H1 is 13.0 MPa0.5. Nonlimiting examples of solvents capable of solubilizing the hydrophobic polymer of (a) include polycitronellol acetate, caprylic / capric triglyceride, isododecane, isohexadecane, tetradecane, isopropyl myristate, isopropyl alcohol, octyldodecanol, ethanol, phenoxyethanol, castor oil, and mixtures thereof. Polycitronellol acetate, caprylic / capric triglyceride, isododecane, and mixtures thereof, are particularly useful. The first anhydrous composition may optionally include one or more alkanes. Nonlimiting examples of alkanes include C6-C16 alkanes, for example, one or more alkanes selected from isododecane, isodecane, isohexadecane, n-heptane, n- octane, n-nonane, n-decane, n-undecane, n-dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof. The second anhydrous composition includes one or more nonpolar oils in which the hydrophobic polymer of (a) is not soluble. Nonlimiting examples include squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof. The second anhydrous composition optionally includes one or more oil thickening agents that thicken the second anhydrous composition. Nonlimiting examples of oil thickening agents include polymers, gums, organoclays, polyethylenes, silica, or mixtures thereof. More specific but nonlimiting examples include acrylate copolymers, hectorite gel, silica, silica dimethyl silylate, behenate, glyceryl dibehenate, behenyl behenate, or mixtures thereof. The second anhydrous composition optionally includes one or more solid fatty compounds. Nonlimiting examples of solid fatty compounds include solid fatty acids, solid fatty alcohol, solid waxes, and the like. The solid fatty compounds are solid at 25oC and atmospheric pressure. Nonetheless, the solid fatty compounds are Attorney Docket No.085137-824799 typically solubilized in the second anhydrous composition, i.e., they do not exist as solids when formulated in the second anhydrous composition. Nonlimiting examples of solid fatty compounds include candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, cetyl alcohol, stearyl alcohol, cetearyl alcohol, lanolin alcohol, or mixtures thereof. The first anhydrous composition, the second anhydrous composition, or both the first and second anhydrous composition may be transparent. The first anhydrous composition and the second anhydrous composition may be provided as a kit. Such kits include: (i) first anhydrous comprising: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) optionally, one or more alkanes; and (ii) a second anhydrous composition comprising: (a) one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble; (b) optionally, one or more thickening agent capable of thickening the second anhydrous composition; and (c) optionally, one or more solid fatty compounds that are soluble in the second anhydrous composition; wherein the first anhydrous composition and the second anhydrous composition are separately contained. The methods of the disclosure include methods for cleansing the skin and methods for removing makeup from skin, in particular, long-wear makeup. Nonlimiting examples of makeup that can be removed include mascara, lipstick, rouge, eyeliner, eye shadow, foundation, blush, and the like. Attorney Docket No.085137-824799 DETAILED DESCRIPTION OF THE DISCLOSURE The present disclosure is drawn cosmetic premix compositions and to use of the compositions, for example, in methods and compositions for cleansing the skin and removing makeup from the skin, including long-wear makeup. For example, in a preferred embodiment, a first anhydrous composition and a second anhydrous composition are used together in a method that effectively and efficiently cleanses the skin and removes makeup from the skin. The first anhydrous composition is initially applied to the skin to dissolve and dislodge makeup present on the skin. A second anhydrous composition is subsequently applied, without first removing the first anhydrous composition from the skin. Application of the second anhydrous composition results in the first anhydrous composition, and the makeup, to solidify and coagulate for easy removal from the skin, for example, by peeling the material from the skin or by wiping or rinsing away the solidified or coagulated residue. The process is surprisingly effective and provides the consumer with a unique cleansing experience. The method for removing makeup from skin comprises: (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) optionally, one or more alkanes; (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising: (a) one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble; (b) optionally, one or more thickening agents capable of thickening the second anhydrous composition; Attorney Docket No.085137-824799 (c) optionally, one or more solid fatty compounds, wherein the one or more solid fatty compounds is soluble in the second anhydrous composition. The first anhydrous composition, the second anhydrous composition, or both the first and second anhydrous composition can be transparent or translucent. The first anhydrous composition is applied to skin upon which makeup is present. It can be rubbed over the skin and makeup, for example, with an individual’s hand or with a cloth or other substrate. A rubbing action helps dissolve and dislodge makeup adhered to the skin. The first anhydrous composition is typically applied to the skin, upon which makeup is present, and optionally rubbed or mixed with makeup on the skin. The first anhydrous composition can remain on the skin with the makeup for a period of time, for example, for about 10 seconds to about 10 minutes. The first anhydrous composition is effective for dissolving and dislodging the makeup and therefore a long period of time is not needed. The first anhydrous composition immediately begins dissolving and dislodging makeup adhered to the skin upon application and the process is expedited by rubbing or mixing the first anhydrous composition with the makeup on the skin. The second anhydrous composition is typically applied immediately or shortly after application of the first anhydrous composition. For example, the second anhydrous composition may be applied within about 10 minutes, with 5 minutes, or within 1 minute after application of the first anhydrous composition. (i) First Anhydrous Composition A primary role of the first anhydrous composition is to solubilize, dislodge, and to adhere to makeup and ingredients of the makeup present on the skin. This is achieved, at least in part, with a hydrophobic polymer that is as a reaction product of a natural or food- derived oil and a methacrylate or acrylate polymer. The first anhydrous composition is typically a solution comprising the hydrophobic polymer. The one or more solvents capable of solubilizing the hydrophobic polymer also assist in dissolving and removing makeup from the skin. (i)(a) Hydrophobic Polymer The hydrophobic polymer is a reaction product of a natural or food-derived oil (oil component) and an acrylate component. In particular, the natural or food-derived Attorney Docket No.085137-824799 oil may be a drying oil, preferably linseed oil. The reaction product may include an isobutyl methacrylate backbone with a plurality of linseed oil side chains. Preferably, the reaction product is a product sold under the MYCELX® brand from MYCELX Technologies Corporation of Gainesville, Georgia. See U.S. Pat. No.5,698,139 for a description of MYCELX materials, which is incorporated herein by reference in its entirety. The hydrophobic polymer is comprised of an oil component and a polymer component, typically reacted in a solvent. In a preferred embodiment, the hydrophobic polymer is a reaction product of linseed oil and poly(isobutyl methacrylate), in a solvent such as 2,2,4-trimethyl-1,3-pentanediol-monoisobutyrate as a solvent. The oil component is derived from glycerin and carboxylic acids, such as linseed fatty acid to form monoglycerides, diglycerides, and triglycerides. The oil component is preferably derived from plant / vegetable or natural origin. Vegetable oils are obtained by cold pressing the seeds of a plant to obtain the oil contained therein. Of the vegetable oils, drying oils such as linseed and tung oil, semi-drying oils such as soybean and cotton seed oil, and non-drying oils such as coconut oil may be used as the oil component. The oil component typically forms about 72% to 77%, or most preferably, 74.62%, of the hydrophobic polymer (e.g., linseed oil / isobutyl methacrylate). The polymer component may be derived from α and β-unsaturated carbonyl compounds. The polymer component is the resultant product of a monomer which is an ester of an acrylic acid, crotonic acid, isocrotonic acid, methacrylic acid, sorbic acid, cinnamic acid, maleic acid, fumaric acid, and methyl methacrylic acid. Nonlimiting examples of useful polymers which cover any number of reaction possibilities between the esters of such compounds include acrylate polymers, methyl methacrylate polymers, methyl / n-butyl methacrylate polymers, methacrylate copolymers, ethyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, n- butyl / isobutyl methacrylate copolymers, or combinations thereof. Preferably the polymer is poly(isobutyl methacrylate). The hydrophobic polymer is a reaction product typically formed in a liquid solvent able to dissolve or dilute the polymer component (poly(oil / polymer)) and the Attorney Docket No.085137-824799 hydrophobic polymer. The solvent, or diluent should generally comprise any liquid or mixture of liquids that is able to dissolve or dilute hydrophobic polymer product. The solvent / diluent can control the evaporation, desired flow, and coalescing of the hydrophobic polymer. The solvent may be, for example, an aliphatic hydrocarbon, aromatic hydrocarbon, alcohols, ketones, ethers, aldehydes, phenols, carboxylic acids, carboxylates, synthetic chemicals and naturally occurring substances. Preferably the solvent is 2,2,4-trimethyl-1,3-pentanediol-monoisobutyrate. Hydrophobic polymers according to the instant disclosure and methods for making them are described, for example, in U.S. Pat. Nos.5,437,793, 5,698,139, 5,837,146, 5,961,823, 6,180,010, 6,475,393, and 6,805,727, which are incorporated herein by reference in their entireties. The preferred hydrophobic polymer may be designated as poly(linseed oil / isobutyl methacrylate). The amount of hydrophobic polymer in the first anhydrous composition will vary. Nonetheless, the total amount of the hydrophobic polymer in the first anhydrous composition is typically from about 1 to about 40 wt.%, based on the total weight of the first anhydrous composition. In further embodiment, the total amount of the hydrophobic polymer is from about 1 to about 35 wt.%, about 1 to about 30 wt.%, about 5 to about 40 wt.%, about 5 to about 35 wt.%, about 5 to about 30 wt.%, about 5 to about 26 wt.%, about 10 to about 40 wt.%, about 10 to about 35 wt.%, about 10 to about 30 wt.%, about 10 to about 26 wt.%, about 15 to about 40 wt.%, about 15 to about 35 wt.%, about 15 to about 30 wt.%, about 15 to about 26 wt.%, about 20 to about 40 wt.%, about 20 to about 35 wt.%, about 20 to about 30 wt.%, about 20 to about 26 wt.%, about 25 to about 40 wt.%, about 25 to about 35 wt.%, about 25 to about 30 wt.%, or about 25 to about 28 wt.%, based on the total weight of the first anhydrous composition. (i)(b) Solvent Capable of Solubilizing (i)(a) The hydrophobic polymer of (i)(a) is typically dissolved in one or more solvents capable of solubilizing the hydrophobic polymer. The solvent may include one or more solvents used to generate the hydrophobic polymer of (i)(a), i.e., used in generating the reaction product (hydrophobic polymer), such as, 2,2,4-trimethyl-1,3- pentanediol-monoisobutyrate. The solvent may be a single solvent or a plurality of solvents. For example, in various embodiments, solvents capable of solubilizing the hydrophobic polymer have a dispersion component (D), a polar component (P), a Attorney Docket No.085137-824799 hydrogen bonding component (H), and a distance (Ra) of less than or equal to 13.4 MPa0.5per the Hansen Solubility Parameters, wherein the distance (Ra) is defined by formula (I): ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2(I) D1 is 16.8 MPa0.5, P1 is 4.8 MPa0.5, and H1 is 13.0 MPa0.5. In a preferred embodiment, the one or more solvents have a dispersion component (D), a polar component (P), a hydrogen bonding component (H), and a distance (Ra) of less than or equal to 9.9 MPa0.5per Hansen Solubility Parameters, wherein the distance (Ra) is defined by formula (I): ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2 (I) D1is 16.4 MPa0.5, P1 is 5.0 MPa0.5, and H1 is 11.7 MPa0.5. The solvent may be an oil. The term “oil” is intended to mean a non-aqueous compound that is non-miscible in water and liquid at 25° C and atmospheric pressure (760 mmHg; 1.013x105Pa). The solvent may be a non-silicone oil (e.g., an oil that does not contain silicon atoms, and in particular does not contain Si-O groups). Nonlimiting examples of useful solvents include caprylic / capric triglyceride, isopropyl myristate, polycitronellol acetate, and mixtures thereof. The solvents may include acetone. The solvents may include oleic acid. The solvents may include an oleic acid containing oil (such as a vegetable oil). Table 1 below, shows values of D, P, and H, as well as Ra values for the allowable range as well as the preferred range, for several preferred solvents. Attorney Docket No.085137-824799 Table 1 Solvent (b) D P H Ra Ra (All bl R ) (P f d R e) d may be provided by a vegetable oil. The vegetable oil may be a seed or nut oil. The vegetable oil may have an oleic acid content of at least 20% by weight of the vegetable oil. The vegetable oil may include sunflower oil, soybean oil, macadamia nut oil, and / or avocado oil. In some embodiments, the composition may include macadamia nut oil, and may be free, or substantially free, of other vegetable oils. For purposes of the instant disclosure, the one or more of the solvents capable of solubilizing the hydrophobic polymer of (i)(a) may not individually solubilize the hydrophobic polymer. However, when combined with other solvents, the combination solubilizes the hydrophobic polymer. Thus, when referring to a total amount of one or more solvents capable of solubilizing the hydrophobic polymer, the inclusion of all solvents that in combination solubilize the hydrophobic polymer is intended, even if one or more solvents in the combination do not individually solubilize the hydrophobic polymer. Nonlimiting examples of solvents useful for solubilizing the hydrophobic polymer of (i)(a), individually, or in combination with other solvents, include polycitronellol acetate, caprylic / capric triglyceride, isododecane, isohexadecane, tetradecane, isopropyl myristate, octyldodecanol, ethanol, phenoxyethanol, castor oil, and mixtures thereof. In a preferred embodiment, at least one of the one or more solvents capable of solubilizing the hydrophobic polymer are selected from caprylic / capric triglyceride, polycitronellol acetate, isododecane, and mixtures thereof. In another preferred embodiment, at least one of the one or more solvents Attorney Docket No.085137-824799 capable of solubilizing the hydrophobic polymer is polycitronellol acetate, caprylic / capric triglyceride, isododecane, or mixtures thereof. Further nonlimiting solvents that individually or in combination with other solvents are useful for solubilizing the hydrophobic polymer of (a) include dioctylcyclohexane, mineral oil, isocetyl palmitate, isocetyl palmitate, cyclopentasiloxane, dicaprylyl carbonate, octyl isostearate, trimethylhexyl isononanoate, 2-ethylhexyl isononanoate, dicaprylyl ether, dihexyl carbonate, polydecene, octyl cocoate, isodecyl neopentanoate, isohexy decanoate, isodecyl octanoate, dihexyl ether, isododecane, isodecyl 3,5,5 trimethyl hexanoate, oleyl erucate, passiflora incarnata oil, jojoba oil, octyl palmitate, macadamia nut oil, isopropyl stearate, rapeseed oil, hexyl decanol, isotridecyl 3,5,5 trimethylhexanonanoate, polycitronellol acetate, mixed decanoyl and octanoyl glycerides, 2-ethylhexanoic acid, 3,5,5 trimethyl ester, cetystearyl octanoate, dimethicone, isopropyl palmitate, octyldodecanol, dioctyl adipate, isopropyl myristate, octyl palmitate (2-ethylhexyl palmitate), octyldodeceyl myristate, butyl octanoic acid, isopropyl stearate, caprylic / capric triglyceride, isopropyl isostearate, Jojoba oil, cyclomethicone, groundnut oil, almond oil, sunflower oil, decyl oleate, avocado oil, olive oil, dibutyl adipate, castor oil, calendula oil, wheatgerm oil, decyl oleate, avocado oil, calendula oil, propylene glycol monoisostearate, cocoglycerides, butylene glycol caprylate / caprate, C12-15 alkyl benzoate, caprylic / capric diglyceryl succinate, caprylic / capric triglyceride, cetearyl isonoanoate, cetearyl octanoate, cetyl dimethicone, coco-caprylate / caprate, cocoglycerides, Di-C12-13 alkyl tartrate, dibutyl adipate, dicaprylyl carbonate, dicaprylyl ether, hexyl decanol, hydrogenated polyisobutene, isoeicosane, isohexadecane, isopropyl palmitate, isopropyl stearate, octyl cocoate, octyl isostearate, octyl octanoate, octyl palmitate, octyl stearate, octyl dodecanol, octyldodecyl myristate, isopropyl stearate, pentaerythrityl tetraisostearate, phenyl trimethicone, polydecene, propylene glycol dicaprylate / dicaprate, stearyl heptanoate, tricaprylin, tridecyl stearate, tridecyl trimellitate, triisostearin, or combinations thereof. In various embodiments, the one or more oils capable of solubilizing the hydrophobic polymer of (i)(a) are selected from polar oils and medium polar oils. The polarity of an oil is defined as the polarity index (interfacial tension) of the oil with respect to water. The polarity may be determined using a ring tensiometer (e.g., Attorney Docket No.085137-824799 Krüss K 10), which measures the interfacial tension in mN / m in analogy to the ASTM method D971-99a (2004). Interfacial tension is the force which acts on an imaginary line one meter in length in the interface between two phases. The physical unit for this interfacial tension is conventionally calculated from the force / length relationship and is usually expressed in mN / m (millinewtons divided by meters). For the purposes of the present disclosure, medium polar oils (or mid-polar oils) have an interfacial tension (Polarity Index) of 23 mN / m to 37 mN / m, and polar oils have an interfacial tension (Polarity Index) less than 23 mN / m. Nonlimiting examples of medium polar oils (or mid-polar oils) and polar oils are set forth below in Table A. TABLE A il TFA N Polarity Index Attorney Docket No.085137-824799 Mixed decanoyl and octanoyl glycerides (Myritol® 312) 25.3 2 Eth lh i A i T i th l The total amount of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) are often the predominant component of the first anhydrous composition. Therefore, the one or more solvents may constitute from about 35 to about 99 wt.% of the first anhydrous composition. In further embodiments, the first anhydrous composition includes from about 35 to about 95 wt.%, about 35 to about 90 wt.%, about 35 to about 85 wt.%, about 35 to about 80 Attorney Docket No.085137-824799 wt.%, about 35 to about 75 wt.%, about 35 to about 70 wt.%, about 35 to about 65 wt.%, about 35 to about 60 wt.%, about 45 to about 99 wt.%, about 45 to about 95 wt.%, about 45 to about 90 wt.%, about 45 to about 85 wt.%, about 45 to about 80 wt.%, about 45 to about 75 wt.%, about 45 to about 70 wt.%, about 45 to about 65 wt.%, about 45 to about 60 wt.%, about 55 to about 99 wt.%, about 55 to about 95 wt.%, about 55 to about 90 wt.%, about 55 to about 85 wt.%, about 55 to about 80 wt.%, about 55 to about 75 wt.%, about 55 to about 70 wt.%, about 55 to about 65 wt.%, about 55 to about 60 wt.% of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a), based on the total weight of the first anhydrous composition. (i)(c) Alkanes The first anhydrous composition may optionally include one or more alkanes. The one or more alkanes may be considered part of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) or may be accounted for separately considering the hydrophobic polymer of (i)(a) is not necessarily soluble in alkanes but can be solubilized when one or more alkanes are combined with other solvents capable of solubilizing the hydrophobic polymer of (i)(a). Alkanes are a series of compounds that contain carbon and hydrogen atoms with single covalent bonds. Squalane is an example of an alkane. Alkanes are nonpolar because they contain nonpolar carbon-carbon and carbon-hydrogen bonds. They are therefore not soluble in water, and since they are generally less dense than water, they typically float on water. Due to their lack of polarity, they are individually not capable of solubilizing the hydrophobic polymers of (i)(a). Nonetheless, having an amount of an alkane in the first anhydrous composition, in combination with solvents that are individually capable of solubilizing the hydrophobic polymer of (i)(a), results in the first anhydrous composition being able to solubilize the hydrophobic polymer of (i)(a) and contributes to makeup removing properties, as isododecane readily dissolves long-wear makeup. However, it also helps the second anhydrous composition expeditiously solidify or coagulate the hydrophobic polymer of (i)(a) when the second anhydrous composition is applied. A smaller amount of the second anhydrous composition is needed to transform the hydrophobic polymer because the first anhydrous composition already includes an amount of alkane in which the hydrophobic polymer of (i)(a) is not individually soluble, and therefore includes lower Attorney Docket No.085137-824799 amounts of individual solvents capable of solubilizing the hydrophobic polymer of (i)(a). Nonlimiting examples of alkanes include linear and branches alkanes having from 6 to 16 carbon atoms. Nonlimiting examples include isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n-decane, n-undecane, n- dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof. The total amount of the one or more alkanes in the first anhydrous composition, if present, will vary. Nonetheless, in various embodiments, the first anhydrous composition includes from about 1 to about 30 wt.% of one or more alkanes. In further embodiments, the first anhydrous composition includes from about 1 to about 25 wt.%, about 1 to about 20 wt.%, about 1 to about 15 wt.%, about 1 to about 10 wt.%, about 2 to about 30 wt.%, about 2 to 25 wt.%, about 2 to about 20 wt.%, about 2 to about 15 wt.%, about 2 to about 10 wt.%, about 5 to about 30 wt.%, about 5 to about 25 wt.%, about 5 to about 20 wt.%, about 5 to about 15 wt.%, about 5 to about 10 wt.%, about 8 to about 30 wt.%, about 8 to about 25 wt.%, about 8 to about 20 wt.%, about 8 to about 15 wt.%, about 10 to about 30 wt.%, about 10 to about 25 wt.%, about 10 to about 20 wt.%, or about 10 to about 15 wt.%, based on the total weight of the first anhydrous composition. Oil Thickening Agents The first anhydrous composition may include one or more oil thickening agents. An “oil thickening agent” is a material which when combined with the solvents of the first anhydrous composition results in a thickening of the first anhydrous composition. Nonlimiting examples of oil thickening agents include polymers, gums, organoclays, polyethylenes, silica, or combinations thereof. More specific but nonlimiting examples include acrylate copolymer, hectorite gel, guar gum, cellulose gum, Caesalpinia Spinosa gum, gum Arabic, starch, silica, silica dimethyl silylate, behenate, glyceryl dibehenate, behenyl behenate, or mixtures thereof. In various embodiments, polyalcohol acrylates may be useful, for examples, poly C10-30 alkyl acrylate. The oil thickening agents can be selected from semi- crystalline or crystalline polymers and / or semi-crystalline or crystalline waxes. Attorney Docket No.085137-824799 In one embodiment, one or more oil thickening agent are selected from polymeric thickening agents and inorganic thickening agents. In one embodiment, the at least one polymeric thickening agent can be an amorphous polymer formed by polymerization of an olefin. In a further embodiment, the olefin can be an ethylenically unsaturated elastomer monomer. Examples of olefins include, but are not limited to, ethylenic carbide monomers, for example those comprising one or two ethylenic unsaturations, comprising from 2 to 5 carbon atoms, such as ethylene, propylene, butadiene, or isoprene. In at least one embodiment, the at least one polymeric thickening agent of oils is capable of thickening or gelling the organic phase of the composition. As used herein, “amorphous polymer” means a polymer which does not have a crystalline form. In another embodiment, the oil thickening agents may be polycondensation products of the polyamide type resulting from condensation between (α) at least one acid chosen from dicarboxylic acids comprising at least 32 carbon atoms, such as the dimeric fatty acids and (β) alkylenediamines, such as ethylenediamine, wherein the polymeric polyamide comprises at least one terminal carboxylic acid group esterified or amidated with at least one monoalcoholor one monoamine comprising from 12 to 30 linear and saturated carbon atoms, for example ethylenediamine / stearyl dilinoleate copolymers such as that marketed under the name Uniclear 100 VG® by Arizona Chemical. The oil thickening agent may be selected from inorganic thickening agents of oils, such as organophilic clay or at least one pyrogenic silica. As used herein, “organophilic clays” mean clays modified with chemical compounds rendering the clay capable of swelling in oily media. The clays are products already well known in themselves, which are for example described in the book “Mineralogy of clays, S. Caillère, S. Hénin, M. Rautureau, 2nd edition 1982, Masson”, the teaching of which is incorporated herein by reference in its entirety. In one embodiment, the at least one clay is a silicate comprising a cation which may be chosen from the cations of calcium, magnesium, aluminium, sodium, potassium, and lithium. Examples of such clays include, but are not limited to, the clays of the smectite family such as montmorillonites, hectorites, bentonites, beidellites, saponites, and the vermiculite family, stevensite, and chlorites. These clays can be of natural or synthetic origin. Attorney Docket No.085137-824799 The total amount of the one or more oil thickening agents, if present, will vary. Nonetheless, in certain embodiments, the first anhydrous composition includes from about 0.1 to about 10 wt.% of one or more oil thickening agents, based on the total weight of the second anhydrous composition. In further embodiment, the total amount of the one or more oil thickening agents is from about 0.1 to about 5 wt.%, about 0.1 to about 3 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 5 wt.%, about 0.5 to about 3 wt.%, about 1 to about 10 wt.%, about 1 to about 5 wt.%, or about 1 to about 3 wt.%, based on the total weight of the first anhydrous composition. Miscellaneous Ingredients The first anhydrous composition may optionally include one or more miscellaneous ingredients. Miscellaneous ingredients are ingredients that are compatible with the first anhydrous composition and do not disrupt or materially affect the basic and novel properties of the first anhydrous composition. Nonlimiting examples of ingredients include preservatives, fragrances, pH adjusters, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, etc. In various embodiments, the miscellaneous ingredients are chosen from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, composition colorants, and mixtures thereof. In the context of the instant disclosure, a “composition colorant” is a compound that colors the composition but does not have an appreciable coloring effect on hair. In other words, the composition colorant is included to provide a coloring to the composition for aesthetic appeal but is not intended to impart coloring properties to hair. Styling gels, for example, can be found in a variety of different colors (e.g., light blue, light pink, etc.) yet application of the styling gel to hair does not visibly change the color of the hair. The total amount of the one or more miscellaneous ingredients in the first anhydrous composition, if present, will vary. Nonetheless, the first anhydrous composition may include from about 0.1 to about 15 wt.% of the one or more miscellaneous ingredients, based on the total weight of the first anhydrous composition. In further embodiments, the first anhydrous composition includes from Attorney Docket No.085137-824799 about 0.1 to about 12 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 15 wt.%, about 0.5 to about 12 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 5 wt.%, about 1 to about 15 wt.%, about 1 to about 12 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 5 wt.%, about 2 to about 15 wt.%, about 2 to about 12 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, or about 2 to about 5 wt.% of one or more miscellaneous ingredients, based on the total weight of the first anhydrous composition. (ii) Second Anhydrous Composition A primary role of the second anhydrous composition is to solidify, congeal, and precipitate the hydrophobic polymer (i)(a) of the first anhydrous composition and the makeup that interacts with the hydrophobic polymer. The hydrophobic polymer has an affinity for makeup or elements in the makeup and therefore sequesters or attaches to the makeup and the elements of the makeup. Upon application of the second anhydrous composition and the congealing, hardening, or precipitation of the hydrophobic polymer (and the makeup and elements of makeup with which it interacts), the solidified or agglomerated material can be easily removed from the skin, for example, with rinsing, wiping, or rubbing. A significant amount of the second anhydrous composition is one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble. (ii)(a) Nonpolar Oils Nonlimiting examples of nonpolar oils include squalane, isoparaffin (C12- C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof. In various embodiments, the nonpolar oil may be a nonpolar oil having a polarity index (interfacial tension) of at greater than 37 mN / m. The polarity of an oil is defined as the polarity index (interfacial tension) of the oil with respect to water. The polarity may be determined using a ring tensiometer (e.g., Krüss K 10), which measures the interfacial tension in mN / m in analogy to the ASTM method D971-99a (2004). Attorney Docket No.085137-824799 Interfacial tension is the force which acts on an imaginary line one meter in length in the interface between two phases. The physical unit for this interfacial tension is conventionally calculated from the force / length relationship and is usually expressed in mN / m (millinewtons divided by meters). For the purposes of the present disclosure, nonpolar oils have an interfacial tension (Polarity Index) of greater than 37 mN / m. Nonlimiting examples of nonpolar oils are provided below in Table B. TABLE B Oil (CTFA Name) Polarity Index nding on polymer length. The total amount of the one or more nonpolar oils in the second anhydrous composition will vary depending on amounts of other ingredients in the second anhydrous composition. Nonetheless, the total amount of the one or more nonpolar oils can be from about 50 wt.% to about 99.9 wt.%, based on the total weight of the second anhydrous composition. In further embodiments, the total amount of the one or more nonpolar oils is from about 50 to about 99 wt.%, about 50 to about 95 wt.%, about 50 to about 90 wt.%, about 50 to about 80 wt.%, about 50 to about 70 wt.%, about 50 to about 60 wt.%, about 60 to about 99.9 wt.%, about 60 to about 99 wt.%, about 60 to about 95 wt.%, about 60 to about 90 wt.%, about 60 to about 80 wt.%, about 60 to about 70 wt.%, about 70 to about 99.9 wt.%, about 70 to about 99 wt.%, about 70 to about 95 wt.%, about 70 to about 90 wt.%, about 70 to about 80 wt.%, about 80 to about 99.9 wt.%, about 80 to about 99 wt.%, about 80 to about 95 wt.%, Attorney Docket No.085137-824799 or about 80 to about 90 wt.%, based on the total weight of the second anhydrous composition. (ii)(b) Oil Thickening Agents The term “oil thickening agent” means a material which when combined with the nonpolar oil of the second anhydrous composition results in a thickening of the second anhydrous composition. Nonlimiting examples of oil thickening agents include polymers, gums, organoclays, polyethylenes, silica, or combinations thereof. More specific but nonlimiting examples include acrylate copolymer, hectorite gel, guar gum, cellulose gum, Caesalpinia Spinosa gum, gum Arabic, starch, silica, silica dimethyl silylate, behenate, glyceryl dibehenate, behenyl behenate, or mixtures thereof. In various embodiments, polyalcohol acrylates may be useful, for examples, poly C10-30 alkyl acrylate. The oil thickening agents can be selected from semi- crystalline or crystalline polymers and / or semi-crystalline or crystalline waxes. In one embodiment, one or more oil thickening agent are selected from polymeric thickening agents and inorganic thickening agents. In one embodiment, the at least one polymeric thickening agent can be an amorphous polymer formed by polymerization of an olefin. In a further embodiment, the olefin can be an ethylenically unsaturated elastomer monomer. Examples of olefins include, but are not limited to, ethylenic carbide monomers, for example those comprising one or two ethylenic unsaturations, comprising from 2 to 5 carbon atoms, such as ethylene, propylene, butadiene, or isoprene. In at least one embodiment, the at least one polymeric thickening agent of oils is capable of thickening or gelling the organic phase of the composition. As used herein, “amorphous polymer” means a polymer which does not have a crystalline form. In another embodiment, the oil thickening agents may be polycondensation products of the polyamide type resulting from condensation between (α) at least one acid chosen from dicarboxylic acids comprising at least 32 carbon atoms, such as the dimeric fatty acids and (β) alkylenediamines, such as ethylenediamine, wherein the polymeric polyamide comprises at least one terminal carboxylic acid group esterified or amidated with at least one monoalcoholor one monoamine comprising Attorney Docket No.085137-824799 from 12 to 30 linear and saturated carbon atoms, for example ethylenediamine / stearyl dilinoleate copolymers such as that marketed under the name Uniclear 100 VG® by Arizona Chemical. The oil thickening agent may be selected from inorganic thickening agents of oils, such as organophilic clay or at least one pyrogenic silica. As used herein, “organophilic clays” mean clays modified with chemical compounds rendering the clay capable of swelling in oily media. The clays are products already well known in themselves, which are for example described in the book “Mineralogy of clays, S. Caillère, S. Hénin, M. Rautureau, 2nd edition 1982, Masson”, the teaching of which is incorporated herein by reference in its entirety. In one embodiment, the at least one clay is a silicate comprising a cation which may be chosen from the cations of calcium, magnesium, aluminium, sodium, potassium, and lithium. Examples of such clays include, but are not limited to, the clays of the smectite family such as montmorillonites, hectorites, bentonites, beidellites, saponites, and the vermiculite family, stevensite, and chlorites. These clays can be of natural or synthetic origin. The total amount of the one or more oil thickening agents, if present, will vary. Nonetheless, in certain embodiments, the second anhydrous composition includes from about 0.1 to about 10 wt.% of one or more oil thickening agents, based on the total weight of the second anhydrous composition. In further embodiment, the total amount of the one or more oil thickening agents is from about 0.1 to about 5 wt.%, about 0.1 to about 3 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 5 wt.%, about 0.5 to about 3 wt.%, about 1 to about 10 wt.%, about 1 to about 5 wt.%, or about 1 to about 3 wt.%, based on the total weight of the second anhydrous composition. (ii)(c) Solid Fatty Compounds The second anhydrous composition may optionally include one or more solid fatty compounds. A solid fatty compound has a melting point above 25oC at atmospheric pressure, i.e., they are solid at 25oC and atmospheric pressure. Although the second anhydrous composition may include one or more fatty compounds, the one or more fatty compounds is typically not solid when incorporated into the second anhydrous composition. The one or more solid fatty Attorney Docket No.085137-824799 compounds is usually dissolved by the other components of the second anhydrous composition, for example, by the one or more nonpolar oils. Nonlimiting examples of solid fatty compounds include solid animal and solid vegetable oils and fats, fully hydrogenated or partially hydrogenated vegetable and animal oils and fats, saturated fatty acids, partially hydrogenated or fully hydrogenated fatty acids, fatty acid esters, saturated, partially hydrogenated or fully hydrogenated monoglycerides, diglycerides and triglycerides, phospholipids, lecithins, partially hydrogenated or completely hydrogenated phospholipids and lecithins, lysolecithins and lysophosphatidylcholine, animal waxes, plant waxes, mineral waxes, synthetic waxes, wax esters, saturated and unsaturated fatty alcohols, fatty alcohol ethers / esters; solid saturated and unsaturated hydrocarbons (paraffins); solid silicones and silicone ethers / esters; polyol ethers / esters: glycerol ethers / esters, sorbitan, sorbitan stearate, glyceryl ricinoleate; polyglycerols and their ethers / esters, hydrophobic gelling agents: silicon dioxide, polyethylenes, or mixtures thereof. In various embodiments, one or more of the solid fatty compounds is a wax, for example, a vegetable wax, an animal wax, a mineral, a synthetic wax and / or petroleum derived wax. Nonlimiting examples include Bayberry wax, candelilla wax, carnauba wax, castor wax, esparto wax, japan wax, ouricury wax, rice bran wax, soy wax, tallow tree wax, beeswax, Chinese wax, lanolin wax (wool wax), shellac wax, spermaceti wax, and mixtures thereof, paraffin wax, microcrystalline wax, ceresin wax, montan wax, ozocerite wax, polyethylene wax, peat wax. In further embodiments, one or more of the solid fatty compounds may be a resin, for example, plant and / or animal and / or petroleum derived resin and / or a synthetic resin. Nonlimiting examples include asphaltite, Utah resin (petroleum bitumens), shellac, copals, dammars, mastic, sandarac, frankincense, elemi, turpentine, copaiba, gum resins, Aleppo pine resin, bisphenol A diglycidyl ether and silicone resins. Solid fatty alcohols include those represented by: R-OH, wherein R denotes a linear alkyl group, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40 carbon atoms, preferably 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, and even more preferably 14 to 22 carbon atoms. Attorney Docket No.085137-824799 Nonlimiting examples include cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures thereof, preferably cetyl alcohol, behenyl alcohol, cetearyl alcohol, and mixtures thereof. Nonlimiting examples of solid fatty acids include decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid or behenic acid. Solid fatty alcohols may be linear, unsaturated 1-alkanols with at least 12 carbon atoms. Examples of solid fatty alcohols are lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, or mixtures thereof. In certain embodiments, the one or more solid fatty compounds are selected from waxes, fatty alcohols, solid fatty acids, or combinations thereof. Nonlimiting examples include candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, cetyl alcohol, stearyl alcohol, cetearyl alcohol, lanolin alcohol, or mixtures thereof. The total amount of the one or more solid fatty compounds, if present, will vary. Nonetheless, the second anhydrous composition may optionally include from about 0.01 to about 20 wt.% of one or more solid fatty compounds. In further embodiments, the second anhydrous composition comprises from about 0.01 to about 15 wt.%, about 0.01 to about 10 wt.%, about 0.01 to about 5 wt.%, about 0.01 to about 3 wt.%, of one or more solid fatty compounds. In other embodiments, the second anhydrous composition comprises from about 0.1 to about 20 wt.%, about 0.1 to about 15 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 5 wt.%, about 1 to about 20 wt.%, about 1 to about 15 wt.%, about 1 to about 10 wt.%, about 1 to about 5 wt.%, about 2 to about 20 wt.%, about 2 to about 15 wt.%, about 2 to about 10 wt.%, about 2 to about 5 wt.%, about 5 to about 20 wt.%, about 5 to about 15 wt.%, or about 5 to about 10 wt.% of one or more solid fatty compounds based on the total weight of the second anhydrous composition. Miscellaneous Ingredients The second anhydrous composition optionally includes one or more miscellaneous ingredients. Miscellaneous ingredients are ingredients that are compatible with the compositions and do not disrupt or materially affect the basic and novel properties of the compositions. Nonlimiting examples of ingredients include preservatives, fragrances, pH adjusters, chelating agents, buffers, Attorney Docket No.085137-824799 antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, etc. In various embodiments, the miscellaneous ingredients are chosen from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, composition colorants, and mixtures thereof. In the context of the instant disclosure, a “composition colorant” is a compound that colors the composition but does not have an appreciable coloring effect on hair. In other words, the composition colorant is included to provide a coloring to the composition for aesthetic appeal but is not intended to impart coloring properties to hair. Styling gels, for example, can be found in a variety of different colors (e.g., light blue, light pink, etc.) yet application of the styling gel to hair does not visibly change the color of the hair. The total amount of the one or more miscellaneous ingredients in the second anhydrous composition, if present, will vary. Nonetheless, the second anhydrous composition may include from about 0.1 to about 15 wt.% of the one or more miscellaneous ingredients, based on the total weight of the second anhydrous composition. In further embodiments, the first anhydrous composition includes from about 0.1 to about 12 wt.%, about 0.1 to about 10 wt.%, about 0.1 to about 5 wt.%, about 0.5 to about 15 wt.%, about 0.5 to about 12 wt.%, about 0.5 to about 10 wt.%, about 0.5 to about 8 wt.%, about 0.5 to about 5 wt.%, about 1 to about 15 wt.%, about 1 to about 12 wt.%, about 1 to about 10 wt.%, about 1 to about 8 wt.%, about 1 to about 5 wt.%, about 2 to about 15 wt.%, about 2 to about 12 wt.%, about 2 to about 10 wt.%, about 2 to about 8 wt.%, or about 2 to about 5 wt.% of one or more miscellaneous ingredients, based on the total weight of the second anhydrous composition. Cosmetic Premix Composition As mentioned above, the instant disclosure also relates to a cosmetic premix composition, which can be used in preparing cosmetic compositions. The cosmetic compositions are not limited and therefore include compositions for removing makeup from the skin but also include unrelated cosmetic compositions, including makeup compositions. Attorney Docket No.085137-824799 The cosmetic composition may exist any appropriate form, such as an emulsion (including a water-in-oil emulsion or an oil-in water emulsion), an anhydrous solution, etc., and may be a gel, lotion, crème, stick, etc. The cosmetic composition may include an embodiment of a cosmetic premix composition as disclosed herein, and one or more additional materials. As such, the premix may include a reaction product of an acrylate and a natural or food-derived oil as disclosed herein. The premix may include one or more solvents of the reaction product. Each of the one or more solvents may, as disclosed herein, have Hansen Solubility Parameters that satisfy Eq.1, where Ra = 13.4 MPa0.5, D1= 16.8 MPa0.5, P1 = 4.8 MPa0.5, and H1 = 13.0 MPa0.5. The reaction product may be present in a total amount of no more than 20% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 19% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 18% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 17% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 16% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 15% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 14% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 13% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 12% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 11% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 10% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 9% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 8% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 7% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 6% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 5% by weight of the cosmetic composition. The reaction product may be present in Attorney Docket No.085137-824799 a total amount of no more than 4% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 3% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 2.5% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 2% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 1.5% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 1% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 0.75% by weight of the cosmetic composition. The reaction product may be present in a total amount of no more than 0.5% by weight of the cosmetic composition. The reaction product may be present in a total amount of at least 0.1% by weight of the cosmetic composition. The reaction product may be present in a total amount of at least 0.5% by weight of the cosmetic composition. The reaction product may be present in a total amount of at least 1% by weight of the cosmetic composition. Additional Materials The one or more additional materials may include one or more additional solvents having Hansen Solubility Parameters that around outside the range for solvents of the reaction product. That is, the one or more additional solvent(S) may have Hansen Solubility Parameters that satisfy ^^^^ > √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2where Ra = and H1 = 13.0 MPa0.5. The table below shows values of D, P, and H, as well as calculated Ra values for the allowable range as well as the preferred range, for several solvents that fall outside the allowable range. The D, P, and H were determined based on compatibility at 55°C Attorney Docket No.085137-824799 Material D P H Ra (Allowable Ra (Preferred Range) Range) It should be noted that these additional solvents may not be soluble with the reaction product by itself. Non-limiting examples of such components include water, glycerin, and propanediol. Additional examples may include various alkanes, such as C10-C18 alkanes, which may be branched alkanes such as isohexadecane, isododecane, or squalane, or linear (non-branched) alkanes such as decane, undecane, or tridecane. As seen in the table below, when 10% of the reaction product was mixed with 90% of the additional solvent material at 55°C, various instabilities were detected during stability testing. Visible Stability Results Material Visible Stability Result The additional solvent(s) may be present in a total amount of at least 1% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 3% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 5% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 10% by weight of the cosmetic composition. The additional solvent(s) may be Attorney Docket No.085137-824799 present in a total amount of at least 15% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 20% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 25% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of at least 30% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 99% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 90% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 80% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 70% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 60% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 50% by weight of the cosmetic composition. The additional solvent(s) may be present in a total amount of no more than 40% by weight of the cosmetic composition. Polyol The additional solvent(s) may include at least one polyol. The polyol(s) may be present in a total amount of at least 1% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of at least 2% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of at least 3% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of at least 5% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 30% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 25% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 20% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 15% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 10% by weight of the cosmetic composition. The polyol(s) may be present in a total amount of no more than 5% by weight of the cosmetic composition. The cosmetic composition may be free, or substantially free, of a polyol. The cosmetic premix composition may be free, or substantially free, of a polyol. Attorney Docket No.085137-824799 The polyol may include a non-sugar alcohol. The non-sugar alcohol mayinclude at least one polyol between 2 to 20 carbon atoms, such as between 2 to 10carbon atoms, such as between 2 to 6 carbon atoms. Non-limiting examples of a polyol include glycerol and glycols, such as propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, glycol ethers, preferably mono-, di- or tripropylene glycol of alkyl(C1-C4)ether or mono-, di- or triethylene glycol of alkyl(C1-C4)ether, or mixtures thereof. The non-sugar alcohol(s) may be present in a total amount of at least 1% by weight of the cosmetic composition. The non-sugar alcohol (s) may be present in a total amount of at least 2% by weight of the cosmetic composition. The non-sugar alcohol (s) may be present in a total amount of at least 3% by weight of the cosmetic composition. The non-sugar alcohol (s) may be present in a total amount of no more than 15% by weight of the cosmetic composition. The non-sugar alcohol (s) may be present in a total amount of no more than 10% by weight of the cosmetic composition. The non-sugar alcohol (s) may be present in a total amount of no more than 5% by weight of the cosmetic composition. The cosmetic composition may be free, or substantially free, of a non-sugar alcohol. The cosmetic premix composition may be free, or substantially free, of a non-sugar alcohol. The polyol may include a sugar alcohol. The sugar alcohol may include a monosaccharide-polyol. The monosaccharide-polyol may be, e.g., mannitol, erythritol, xylitol, sorbitol, or a mixture thereof. The sugar alcohol(s) may be present in a total amount of at least 1% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of at least 2% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of at least 3% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of at least 4% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of at least 5% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 15% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 10% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 9% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 8% by weight Attorney Docket No.085137-824799 of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 7% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 6% by weight of the cosmetic composition. The sugar alcohol(s) may be present in a total amount of no more than 5% by weight of the cosmetic composition. The cosmetic composition may be free, or substantially free, of a sugar alcohol. The cosmetic premix composition may be free, or substantially free, of a sugar alcohol. Silicone Oil The additional solvent(s) may include a silicone oil. As used herein, the term “silicone oil” refers to an oil containing at least one silicon atom, and in particular containing Si—O groups. The silicone oil may be present in a total amount of at least 0.1% by weight of the cosmetic composition. The silicone oil may be present in a total amount of at least 0.5% by weight of the cosmetic composition. The silicone oil may be present in a total amount of at least 1% by weight of the cosmetic composition. The silicone oil may be present in a total amount of no more than 5% by weight of the cosmetic composition. The silicone oil may be present in a total amount of no more than 2% by weight of the cosmetic composition. The silicone oil may be present in a total amount of no more than 1% by weight of the cosmetic composition. The cosmetic composition may be free, or substantially free, of a silicone oil. The cosmetic premix composition may be free, or substantially free, of a silicone oil. The silicone oil may be present in a total amount (by weight % of the composition) less than the amount of the solvent of the reaction product. The silicone oil may be present in a total amount (by weight % of the composition) less than the amount of the reaction product. The silicone oil(s) may include a non-volatile silicone oil. Non-limitingexamples of non-volatile silicone oils include non-volatile polydimethylsiloxanes(PDMS); phenyl silicones such as phenyl trimethicones, phenyl dimethicones, diphenyl dimethicones, tri methyl penta phenyltrisiloxanes, tetra methyltetra phenyltrisiloxanes, trimethylsiloxyphenyl dimethicones, diphenylsiloxyphenyl trimethicones, or combinations thereof. The cometic composition may be free, or Attorney Docket No.085137-824799 substantially free, of non-volatile silicone oils. The cometic premix composition may be free, or substantially free, of non-volatile silicone oils. The silicone oil(s) may include volatile silicone oil. The volatile silicone oilmay include a linear volatile silicone oil and / or a cyclic volatile silicone oil. Non-limiting examples of linear volatile silicone oils include octamethyltrisiloxane,decamethyltetrasiloxane, dodecamethylpentasiloxane, or combinations thereof.Non-limiting examples of cyclic volatile silicone oils includeoctamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, or combinations thereof. The cosmetic composition may be free, or substantially free, of volatile silicone oils. The cosmetic premix composition may be free, or substantially free, of volatile silicone oils. Colorants The one or more additional materials may include at least one cosmetically acceptable colorant, such as a pigment or dyestuff. The term “pigment” means any pigment that gives color to keratin materials. Their solubility in water at 25° C. and atmospheric pressure (760 mmHg) is less than 0.05% by weight, preferably less than 0.01%. Examples of suitable pigments include, but are not limited to, inorganic pigments, organic pigments, lakes, pearlescent pigments, iridescent or optically variable pigments, and mixtures thereof. The pigments may be chosen from the organic and / or mineral pigments known in the art. The pigments may be in the form of powder or of pigmentary paste. They may be coated or uncoated. Said pigments may optionally be surface-treated within the scope of the present invention but are not limited to treatments such as silicones, perfluorinated compounds, lecithin, and amino acids. The pigments may be chosen, for example, from inorganic pigments, organic pigments, lakes, pigments with special effects such as nacres or glitter flakes, and mixtures thereof. Non-limiting examples of inorganic pigments include those selected from the group consisting of rutile or anatase titanium dioxide, coded in the Color Index under the reference CI 77,891; black, yellow, red and brown iron oxides, coded under references CI 77,499, 77, 492 and, 77,491; manganese violet (CI Attorney Docket No.085137-824799 77,742); ultramarine blue (CI 77,007); chromium oxide (CI 77,288); chromium hydrate (CI 77,289); and ferric blue (CI 77,510) and mixtures thereof. The pigment may be an inorganic pigment. The term “inorganic pigment” refers to any pigment that satisfies the definition in Ullmann's encyclopedia in the chapter on inorganic pigments. Non-limiting examples include iron oxides, chromium oxides, manganese violet, ultramarine blue, chromium hydrate, ferric blue and titanium oxide. The pigment may be an organic pigment. The term “organic pigment” refers to any pigment that satisfies the definition in Ullmann's encyclopedia in the chapter on organic pigments. Non-limiting examples include nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanin, metal-complex, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane and quinophthalone compounds. In particular, the white or colored organic pigments may be chosen from carmine, carbon black, aniline black, azo yellow, quinacridone, phthalocyanin blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100 and 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000 and 47005, the green pigments codified in the Color Index under the references CI 61565, 61570 and 74260, the orange pigments codified in the Color Index under the references CI 11725, 15510, 45370 and 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915 and 75470, and pigments obtained by oxidative polymerization of indole or phenolic derivatives. Non-limiting examples of organic pigments and lakes include, but are not limited to, D&C Red No.19 (CI 45,170), D&C Red No.9 (CI 15,585), D&C Red No.21 (CI 45,380), D&C Orange No. 4 (CI 15,510), D&C Orange No.5 (CI 45,370), D&C Red No.27 (CI 45,410), D&C Red No.13 (CI 15,630), D&C Red No.7 (CI 15,850), D&C Red No.6 (CI 15,850), D&C Yellow No.5 (CI 19,140), D&C Red No.36 (CI 12,085), D&C Orange No.10 (CI 45,425), D&C Yellow No.6 (CI 15,985), D&C Red No.30 (CI 73,360), D&C Red No.3 (CI 45,430) and the dye or lakes based on cochineal carmine (CI 75,570) and mixtures thereof. Attorney Docket No.085137-824799 The pigments in accordance with the invention may also be in the form of composite pigments. These composite pigments may be compounds especially of particles comprising a inorganic core, at least one binder for ensuring the binding of the organic pigments to the core, and at least one organic pigment at least partially covering the core. The organic pigment may also be a lake. The term “lake” refers dyes adsorbed onto insoluble particles, the assembly thus obtained remaining insoluble during use. The inorganic substrates onto which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum. Among the dyes, mention may be made of cochineal carmine. Non-limiting examples of dyes include: D&C Red 21 (CI 45380), D&C Orange 5 (CI 45370), D&C Red 27 (CI 45410), D&C Orange 10 (CI 45425), D&C Red 3 (CI 45430), D&C Red 4 (CI 15510), D&C Red 33 (CI 17200), D&C Yellow 5 (CI 19140), D&C Yellow 6 (CI 15985), D&C Green (CI 61570), D&C Yellow 10 (CI 77002), D&C Green 3 (CI 42053), D&C Blue 1 (CI 42090). An example of a lake is D&C Red 7 (CI 15850:1). The pigment may also be a pigment with special effects. The term “pigments with special effects” refers pigments that generally create a non-uniform colored appearance (characterized by a certain shade, a certain vivacity and a certain lightness) that changes as a function of the conditions of observation (light, temperature, observation angles, etc.). They thus contrast with colored pigments that afford a standard uniform opaque, semi-transparent or transparent shade. Several types of pigment with special effects exist: those with a low refractive index, such as fluorescent, photochromic or thermochromic pigments, and those with a higher refractive index, such as nacres or glitter flakes. Examples of pigments with special effects that may be mentioned include nacreous pigments such as titanium mica coated with an iron oxide, mica coated with an iron oxide, mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye especially of the abovementioned type, and also nacreous pigments based on bismuth oxychloride. Attorney Docket No.085137-824799 They may also be mica particles at the surface of which are superposed at least two successive layers of metal oxides and / or of organic dyestuffs. The nacres may more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or coppery color or tint. Non-limiting examples of nacres include gold-colored nacres sold especially by the company Engelhard under the name Gold 222C (a CLOISONNÉ® pigment), Sparkle gold (a TIMICA® pigment), Gold 4504 (a CHROMA-LITE® pigment) and Monarch gold 233X (a CLOISONNÉ® pigment); the bronze nacres sold especially by the company Merck under the name Bronze fine (17384) (a COLORONA® pigment) and Bronze (17353) (a COLORONA® pigment), by the company Eckart under the name PRESTIGE™ Bronze pigment and by the company Engelhard under the name Super bronze (a CLOISONNÉ® pigment); the orange nacres sold especially by the company Engelhard under the name Orange 363C (a CLOISONNE® pigment) and Orange MCR 101 and by the company Merck under the name Passion orange (a COLORONA® pigment) and Matte orange (17449); the brown nacres sold especially by the company Engelhard under the name Nu-antique copper 340XB (a CLOISONNE® pigment) and Brown CL4509 (a CHROMA-LITE® pigment); the nacres with a copper tint sold especially by the company Engelhard under the name Copper 340A (a TIMICA® pigment) and by the company Eckart under the name Prestige Copper; the nacres with a red tint sold especially by the company Merck under the name Sienna fine (17386) (a COLORONA® pigment); the nacres with a yellow tint sold especially by the company Engelhard under the name Yellow (4502) (a CHROMA-LITE® pigment); the red nacres with a gold tint sold especially by the company Engelhard under the name Sunstone G012 (a GEMTONE® pigment); the black nacres with a gold tint sold especially by the company Engelhard under the name Nu antique bronze 240 AB (a TIMICA® pigment), the blue nacres sold especially by the company Merck under the name Matte blue (17433), Dark Blue (117324) (a COLORONA® pigment), the white nacres with a silvery tint sold especially by the company Merck under the name XIRONA® Silver pigment, and the golden-green pink-orange nacres sold especially by the company Merck under the name Indian summer (a XIRONA® pigment), and mixtures thereof. Attorney Docket No.085137-824799 In addition to nacres on a mica support, multilayer pigments based on synthetic substrates such as alumina, silica, sodium calcium borosilicate or calcium aluminum borosilicate, and aluminum, may be envisaged. Non-limiting examples of pearlescent pigments include those selected from the group consisting of the white pearlescent pigments such as mica coated with titanium oxide, mica coated with titanium dioxide, bismuth oxychloride, titanium oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the above-mentioned type as well as those based on bismuth oxychloride and mixtures thereof. Mention may also be made of pigments with an interference effect that are not fixed onto a substrate, for instance liquid crystals or holographic interference glitter flakes. Pigments with special effects also comprise fluorescent pigments, whether these are substances that are fluorescent in daylight or that produce an ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments and quantum dots. The variety of pigments that may be used in the present invention makes it possible to obtain a wide range of colors, and also particular optical effects such as metallic effects or interference effects. The effective diameter of the pigment particles may generally be between 10 nm and 200 μm, such as between 20 nm and 80 μm, such as between 30 nm and 50 μm. The pigment may be present in a total amount of no more than 20% by weight of the cosmetic composition. The pigment may be present in a total amount of no more than 15% by weight of the cosmetic composition. The pigment may be present in a total amount of no more than 10% by weight of the cosmetic composition. The pigment may be present in a total amount of no more than 8% by weight of the cosmetic composition. The pigment may be present in a total amount of no more than 6% by weight of the cosmetic composition. The pigment may be present in a total amount of no more than 5% by weight of the cosmetic composition. The pigment may be present in a total amount of at least 0.1% by weight of the cosmetic composition. The pigment may be present in a total amount of at least 1% by weight Attorney Docket No.085137-824799 of the cosmetic composition. The pigment may be present in a total amount of at least 2% by weight of the cosmetic composition. The pigment may be present in a total amount of at least 3% by weight of the cosmetic composition. The pigment may be present in a total amount of at least 4% by weight of the cosmetic composition. The pigment may be present in a total amount of at least 5% by weight of the cosmetic composition. The colorant may comprise or consist of a pigment. The pigment may be a single pigment. The pigment may be a plurality of pigments. In some embodiments, titanium dioxide may be a primary component of the pigment(s). For example, in some embodiments, the pigments may be comprised by titanium dioxide, where the titanium dioxide may be present in an amount of at least 55% by weight of the pigment. The titanium dioxide is present in an amount of at least 75% by weight of the pigment. The titanium dioxide is present in an amount of at least 80% by weight of the pigment. The titanium dioxide is present in an amount of at least 85% by weight of the pigment. The titanium dioxide is present in an amount of at least 90% by weight of the pigment. Filler The one or more additional materials may include one or more fillers. Non- limiting examples of fillers include silica powder; talc; polyamide particles and especially those sold under the name ORGASOL® powders by the company Atochem; polyethylene powders; microspheres based on acrylic copolymers, such as those based on ethylene glycol dimethacrylate / lauryl methacrylate copolymer sold by the company Dow Corning under the name POLYTRAP® systems; expanded powders such as hollow microspheres and especially the microspheres sold under the name EXPANCEL® thermoplastic microspheres by the company Kemanord Plast or under the name MICROSPHERE® F 80 ED microcapsules by the company Matsumoto; powders of natural organic materials such as crosslinked or noncrosslinked corn starch, wheat starch or rice starch, such as the powders of starch crosslinked with octenyl succinate anhydride, sold under the name DRY- FLO® starch by the company National Starch; silicone resin microbeads such as those sold under the name TOSPEARL® microspheres by the company Toshiba Silicone; clays (bentone, laponite, saponite, etc.); and mixtures thereof. Attorney Docket No.085137-824799 The filler may include a clay (such as kaolin, disteardimonium hectorite, or a combination thereof), which may include a swellable clay. By "swellable clay" it is meant a clay material that is capable of swelling in water. An example of a swellable clay are smectite clays. The crystal structure of the smectite group, is an octahedral alumina sheet between two tetrahedral silica sheets. In one notable embodiment, the swellable clay is bentonite. Bentonite is a rock formed of highly colloidal and plastic clays composed mainly of montmorillonite, a clay mineral of the smectite group, and is produced by in situ devitrification of volcanic ash. In addition to montmorillonite, bentonite may contain feldspar, cristobalite, and crystalline quartz. Bentonite has an ability to form thixotrophic gels with water, an ability to absorb large quantities of water. Variations in interstitial water and exchangeable cations in the interlayer space affect the properties of bentonite and thus the commercial uses of the different types of bentonite. One notable swellable clay suitable for use in the cosmetic composition is BENTONE GEL® ISD V dispersion, commercially available from Elementis Specialties, East Windsor, New Jersey. BENTONE GEL® GTCC V dispersion is a dispersion of organically (disterammonium) modified hectorite in isododecane with added propylene carbonate. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 1% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 1.5% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 2% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 2.5% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 3% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of no more than 10% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of no more than 10% by weight. The fillers may be present in the cosmetic compositions of the present invention in a total amount of at least 1% by weight. Attorney Docket No.085137-824799 A carbonate, such as propylene carbonate or calcium carbonate, may be present. If present, the carbonate may be present in an amount such that the ratio by weight of swellable clay to propylene carbonate is about 2:1 to about 5:1. While in certain embodiments, certain fillers such as hydrophobic silica aerogels may be included. In certain other embodiments, the cosmetic compositions may be substantially free of hydrophobic silica aerogels. The cosmetic premix compositions may free or substantially free of hydrophobic silica aerogels. Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air. They are generally synthesized via a sol-gel process in liquid medium and then dried, usually by extraction of a supercritical fluid, the one most commonly used being supercritical CO2. This type of drying makes it possible to avoid shrinkage of the pores and of the material. The sol-gel process and the various drying processes are described in detail in Brinker CJ., and Scherer G.W., Sol-Gel Science: New York: Academic Press, 1990. Silica aerogels, in general, have been disclosed in U.S. Pat. No.9,320,689, the entire content of which is hereby incorporated by reference. As hydrophobic silica aerogels that may be used in the invention, examples that may be mentioned include the aerogel sold under the name VM-2260 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m2 / g. Mention may also be made of the aerogels sold by the company Cabot under the references Aerogel TLD 201, Aerogel OGD 201, Aerogel TLD 203, ENOVA® Aerogel MT 1100 silica aerogel, ENOVA® Aerogel MT 1200 silica aerogel. Use will be made more particularly of the aerogel sold under the name VM- 2270 (INCI name: Silica silylate), by the company Dow Corning, the particles of which have a mean size ranging from 5-15 microns and a specific surface area per unit of mass ranging from 600 to 800 m2 / g. The silica aerogel particles if used can be used in the cosmetic compositions from 0.1% to about 8% by weight, preferably from about 0.1%, 0.2%. or 0.5% to about 0.5%, 1% 2% or 5% by weight, all weights based on the weight of the cosmetic composition. Attorney Docket No.085137-824799 Emulsifiers The one or more additional materials may include one or more emulsifiers. As used herein. the term "emulsifier" refers to any substance or agent that aids in the formation of an emulsion. As used herein, the term "emulsion" refers to a generally stable and homogeneous mixture of two liquids that do not normally mix (i.e., they are immiscible between themselves), such as vegetable oil and water. Emulsions can be true colloids or less stable mixtures, which tend to separate in a short time. An emulsion can often be broken down (i.e. the liquids separated) by factors such as mechanical manipulation, chemical effects and / or time. The emulsifier may be a surfactant. As used herein, the term “surfactant” refers to an amphiphilic molecule, i.e. a molecule that has two parts of different polarity, one generally being lipophilic (soluble or dispersible in an oily phase), and the other being hydrophilic (soluble or dispersible in water), and which is preferably capable of reducing the surface tension of water. Surfactants are characterized by their HLB (hydrophilic-lipophilic balance) value, the HLB being the ratio between the hydrophilic part and the lipophilic part in the molecule. The term “HLB” is well known to those skilled in the art and is described, for example, in “The HLB system. A time- saving guide to Emulsifier Selection” (published by ICI Americas Inc., 1984). For the emulsifying surfactants, the HLB generally ranges from 3 to 8 for the preparation of W / O emulsions and from 8 to 18 for the preparation of O / W emulsions. The HLB of the surfactant(s) used according to the invention may be determined via the Griffin method or the Davies method. The emulsifier may comprise or consist of a polyester of polyglycerol having 2 to 10 glycerol units (such as polyglyceryl-6 polyricinoleate). The emulsifier(s) may be present in a total amount of no more than 15% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of no more than 10% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of no more than 8% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of no more than 7% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of no more than 6% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of at least 1% by weight of the Attorney Docket No.085137-824799 cosmetic composition. The emulsifier(s) may be present in a total amount of at least 2% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of at least 3% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of at least 4% by weight of the cosmetic composition. The emulsifier(s) may be present in a total amount of at least 5% by weight of the cosmetic composition. The cosmetic composition may be free, or substantially free, of an emulsifier. The cosmetic composition may be free, or substantially free, of a surfactant. The cosmetic premix composition may be free, or substantially free, of an emulsifier. The cosmetic premix composition may be free, or substantially free, of a surfactant. Thickening agent The one or more additional materials may include at least one thickening agent. Non-limiting examples include those conventionally used in cosmetics, such as polymers of natural origin and synthetic polymers. For example, nonionic, anionic, cationic, amphiphilic, and amphoteric polymers, and other known rheology modifiers, such as cellulose or a cellulose-based thickener, may be used. According to certain embodiments, the thickening agent may include a cellulose-based thickener. Suitable cellulose-based compounds include, but are not limited to, cellulose polymers, such as, for example, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, and ethylhydroxyethylcellulose. Certain notable cellulose derivatives include hydroxyl-modified cellulose polymers such as Hydroxyethylcellulose, e.g., those having a molecular weight over 500,000 daltons such as NATROSOL® 250 HHR hydroxethylcellulose and Hydroxypropyl cellulose, e.g., KLUCEL® MF hydroxypropyl cellulose —both available from Ashland of Covington, Ky. According to other embodiments, the thickening agent may include a polysaccharide. In general, polysaccharides may be divided into several categories. Polysaccharides that are suitable for use in the invention may be homopolysaccharides such as fructans, glucans, galactans and mannans or heteropolysaccharides such as hemicellulose. Attorney Docket No.085137-824799 The polysaccharides may include linear polysaccharides such as pullulan or branched polysaccharides such as gum arabic and amylopectin, or mixed polysaccharides such as starch. Suitable polysaccharides may be starchy polysaccharides. Starchy polysaccharides include, but are not limited to, native starches, modified starches and particulate starches. According to other embodiments, the thickening agent may include an acrylic thickening agent (acrylic thickener) or an acrylamide thickening agent (acrylamide thickener). “Acrylic thickening agent” or “acrylic thickener” as used herein refers to polymers based upon one or more (meth)acrylic acid (and corresponding (meth)acrylate) monomers or similar monomers. “Acrylamide thickening agent” or “acrylamide thickener” as used herein refers to polymers based upon one or more acrylamide monomers or similar monomers. According to other embodiments, the thickening agent may include at least one monomer performing a weak acid function such as, for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid and / or fumaric acid. According to other embodiments, the thickening agent may include at least one monomer performing a strong acid function such as, for example, monomers having a function of the sulfonic acid type or phosphonic acid type, such as 2- acrylamido-2-methylpropane sulfonic acid (AMPS). According to other embodiments, the thickening agent may be crosslinked (or branched). Non-limiting examples of acceptable crosslinking agents include methylene bisacrylamide (MBA), ethylene glycol diacrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethacrylate, vinyloxyethacrylate or methacrylate, formaldehyde, glyoxal, and compositions of the glycidylether type such as ethyleneglycol diglycidylether, or epoxides. Specific non-limiting examples of suitable thickening agents include homopolymers or copolymers of acrylic or methacrylic acids or the salts thereof and the esters thereof, polyacrylates and polymethacrylates, polyacrylic acids, polyacrylamides, copolymers of acrylic acid and of acrylamide sold in the form of the sodium salt thereof, sodium polymethacrylate, and the sodium salts of polyhydroxycarboxylic acids, optionally crosslinked and / or neutralized 2-acrylamido- Attorney Docket No.085137-824799 2-methylpropanesulphonic acid polymers and copolymers, for instance poly(2- acrylamido-2-methylpropanesulphonic acid), crosslinked anionic copolymers of acrylamide and of AMPS, e.g. in the form of a water-in-oil emulsion, such as those sold under the name SEPIGEL® 305 (CTFA name: Polyacrylamide / C13-14 lsoparaffin / Laureth-7) and under the name SIMULGEL® 600 (INCI name: Acrylamide / Sodium acryloyldimethyltaurate copolymer / Isohexa-decane / Polysorbate 80) by SEPPIC, polyacrylic acid / alkyl acrylate copolymers of PEMULEN® copolymer type, sodium acrylate / sodium acryloyldimethyl taurate such as that sold under the INCI name Sodium Acrylate / Sodium Acryloyldimethyl Taurate Copolymer & Hydrogenated Polydecene & Sorbitan Laurate & Trideceth-6 which is marketed by Lonza, Allendale, N.J., USA under the tradename ViscUp®EZ. Certain especially notable acrylic thickeners are selected from the group of: Acrylamide / Sodium Acryloyldimethyl Taurate Copolymer such as those provided in Isohexadecane & Polysorbate 80 as SIMULGEL™ 600 and SIMULGEL™ 800 (Seppic, Inc.); Polyacrylamide provided with C13-14 isoparaffin and laureth-7 available as SEPIGEL 305™ (Seppic, Inc.); and Polyacrylate Crosspolymer-6 available as SEPIMAX ZEN (Seppic, Inc.). In certain embodiments, the thickening agent is selected from polyacrylamides and water-soluble cellulose polymers (such as hydroxypropylmethylcellulose, ethylcellulose, and / or hydroxypropylcellulose), and combinations thereof. While clays and silicas may be considered thickening agents, for the purposes of this disclosure, the thickening agent may be free of clays and / or silicas, and the cosmetic composition may only contain clays or silicas as fillers. The thickening agent(s) may be present in a total amount at least 0.05% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 0.1% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 0.5% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 1% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 1.5% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 2% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount at least 2.5% by weight of the cosmetic composition. The thickening agent(s) may be present in a Attorney Docket No.085137-824799 total amount at least 3% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 15% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 10% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 8% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 6% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 5% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 4% by weight of the cosmetic composition. The thickening agent(s) may be present in a total amount no more than 3% by weight of the cosmetic composition. Film Former The one or more additional materials may include a film former. As used herein, the term “film former” refers to a polymer or resin that leaves a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, absorbed into and / or dissipated on the substrate. Non-limiting examples of a film former include acrylic acid / isobutyl acrylates / isobornyl acrylate copolymer, trimethylsiloxysilicate, acrylates / isobornyl acrylate copolymer, norbornene / tris(trimethylsiloxy)silylnorbornene copolymer, acrylate / polytrimethyl siloxymethacrylate copolymer, C30-45 alkyldimethylsilylpolypropylsilsequioxane, trimethylsilsesquioxane, polypropylsilsesquioxane, acrylates / dimethicone copolymer, octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer, VA / butyl maleate / isobornyl acrylate copolymer, acrylates / t-butylacrylamide copolymer, polyvinylpyrrolidone / vinyl acetate copolymer, triacontanyl PVP copolymer, acrylates / dimethylaminoethyl methacrylate copolymer, or a combination thereof. The film former(s) may be present in a total amount of at least 0.5% by weight of the cosmetic composition. The film former(s) may be present in a total amount of at least 1% by weight of the cosmetic composition. The film former(s) may be present in a total amount of no more than 5% by weight of the cosmetic composition. The film former(s) may be present in a total amount of no more than 3% by weight of the cosmetic composition. The cosmetic composition may be free or substantially Attorney Docket No.085137-824799 free of a film former. The cosmetic premix composition may be free or substantially free of a film former. Other Materials The one or more additional materials may include one or more other materials, such as materials known to be used in cosmetics, such as a preservative, antioxidant, a chelating agent, a fragrance, a coating material, or a combination thereof. The cosmetic composition may include other materials in a total amount of no more than 5% by weight of the cosmetic composition. The cosmetic composition may include no more than 4% by weight of other materials. The cosmetic composition may include no more than 3% by weight of other materials. The cosmetic composition may include no more than 2% by weight of other materials. The cosmetic composition may be free or substantially free of other materials. Preferred Embodiments In a preferred embodiment, the method for removing makeup from skin comprises, consists essentially of, or consists of (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising, consisting essentially of, or consisting of: (i)(a) about 1 to about 40 wt.%, preferably about 10 to about 35 wt.%, more preferably about 20 to about 35 wt.% a hydrophobic polymer that is a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer, wherein preferably the hydrophobic polymer is a reaction product of: (i) a natural or food-derived oil selected from linseed oil, sunflower oil, tung oil, fish oil, cottonseed oil, soybean oil, or combinations thereof, preferably linseed oil; and(ii) a polymer derived from monomers selected from isobutyl methacrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, and combinations thereof, preferably isobutyl methacrylate polymer, wherein even more preferably, Attorney Docket No.085137-824799 the hydrophobic polymer is the reaction product of linseed oil and poly(isobutyl methacrylate); (i)(b) about 30 to about 80 wt.%, preferably from about 40 to about 75 wt.%, more preferably from about 45 to about 70 wt.% of one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a), wherein preferably, the one or more solvents capable of solubilizing the reaction product of (i)(a) have a dispersion component (D), a polar component (P), and a hydrogen bonding component (H), and a distance (Ra) of less than or equal to 13.4 MPa0.5per Hansen Solubility Parameters, wherein the distance (Ra) is defined by formula (I): ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2(I) wherein D1 is 16.8 MPa0.5, P1 is 4.8 MPa0.5, and H1 is 13.0 MPa0.5, wherein more preferably, the one or more solvents capable of solubilizing the reaction product of (i)(a) have a dispersion component (D), a polar component (P), and a hydrogen bonding component (H), and a distance (Ra) of less than or equal to 9.9 MPa0.5per Hansen Solubility Parameters, wherein the distance (Ra) is defined by formula (I): ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2 (I)wherein D1 is 16.4 MPa0.5, P1 is 5.0 MPa0.5, and H1 is 11.7 MPa0.5, wherein even more preferably, Attorney Docket No.085137-824799 at least one of the one or more solvents capable of dissolving the hydrophobic polymer of (i)(a) are selected from dioctylcyclohexane, isocetyl palmitate, isocetyl palmitate, cyclopentasiloxane, dicaprylyl carbonate, octyl isostearate, trimethylhexyl isononanoate, 2-ethylhexyl isononanoate, dicaprylyl ether, dihexyl carbonate, polydecene, octyl cocoate, isodecyl neopentanoate, isohexy decanoate, isodecyl octanoate, dihexyl ether, isododecane, isodecyl 3,5,5 trimethyl hexanoate, oleyl erucate, passiflora incarnata oil, jojoba oil, octyl palmitate, macadamia nut oil, isopropyl stearate, rapeseed oil, hexyl decanol, isotridecyl 3,5,5 trimethylhexanonanoate, polycitronellol acetate, mixed decanoyl and octanoyl glycerides, 2-ethylhexanoic acid, 3,5,5 trimethyl ester, cetystearyl octanoate, dimethicone, isopropyl palmitate, octyldodecanol, dioctyl adipate, isopropyl myristate, octyl palmitate (2-ethylhexyl palmitate), octyldodeceyl myristate, butyl octanoic acid, isopropyl stearate, caprylic / capric triglyceride, isopropyl isostearate, Jojoba oil, cyclomethicone, groundnut oil, almond oil, sunflower oil, decyl oleate, avocado oil, olive oil, dibutyl adipate, castor oil, calendula oil, wheatgerm oil, decyl oleate, avocado oil, calendula oil, propylene glycol monoisostearate, cocoglycerides, butylene glycol caprylate / caprate, C12-15 alkyl benzoate, caprylic / capric diglyceryl succinate, caprylic / capric triglyceride, cetearyl isonoanoate, cetearyl octanoate, cetyl dimethicone, coco- caprylate / caprate, cocoglycerides, Di-C12-13 alkyl tartrate, dibutyl adipate, dicaprylyl carbonate, dicaprylyl ether, hexyl decanol, hydrogenated polyisobutene, isoeicosane, isohexadecane, isopropyl palmitate, isopropyl stearate, octyl cocoate, octyl isostearate, octyl octanoate, octyl palmitate, octyl stearate, octyl dodecanol, octyldodecyl myristate, isopropyl stearate, pentaerythrityl tetraisostearate, phenyl trimethicone, polydecene, propylene glycol dicaprylate / dicaprate, stearyl Attorney Docket No.085137-824799 heptanoate, tricaprylin, tridecyl stearate, tridecyl trimellitate, triisostearin, or combinations thereof; and (i)(c) optionally, about 1 to about 30 wt.%, preferably about 5 to about 25 wt.%, more preferably about 10 to about 20 wt.% of one or more alkanes, wherein preferably the one or more alkanes are selected from selected from C6-C16 alkanes, wherein even more preferably, the one or more alkanes are selected from isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n- decane, n-undecane, n-dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof; (i)(d) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (i)(e) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%; wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition; (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising, consisting essentially of, or consisting of: Attorney Docket No.085137-824799 (ii)(a) about 50 to about 100 wt.%, preferably from about 60 to about 99 wt.%, more preferably from about 75 to about 95 wt.% of one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble, wherein preferably, the one or more nonpolar oils have a polarity index (interfacial tension) of at greater than 37 mN / m, wherein more preferably, the one or more nonpolar oils are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof; (ii)(b) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (ii)(c) optionally, one or more solid fatty compounds, wherein if present, may be in an amount of from about 0.01 to about 20 wt.%, preferably about 0.1 to about 15 wt.%, more preferably about 1 to about 10 wt.%, wherein preferably, at least one of the one or more solid fatty compounds is a wax, for example, one or more waxes selected from candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, or mixtures thereof; (ii)(d) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an Attorney Docket No.085137-824799 amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%. wherein all weight percentages of (ii) are based on the total weight of the second anhydrous composition. The first anhydrous composition, the second anhydrous composition, or both the first anhydrous composition and the second anhydrous may be transparent or translucent. In another preferred embodiment, the method for removing makeup from skin comprises, consists essentially of, or consists of (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising, consisting essentially of, or consisting of: (i)(a) about 1 to about 40 wt.%, preferably about 10 to about 35 wt.%, more preferably about 20 to about 35 wt.% a hydrophobic polymer that is a reaction product of linseed oil and poly(isobutyl methacrylate), wherein preferably, the hydrophobic polymer is the reaction product of about 50 to about 85 parts by weight of the linseed oil and about 15 to about 50 parts by weight of the poly(isobutyl methacrylate), wherein more preferably, the hydrophobic polymer is the reaction product of about 72 to about 77 parts by weight of the linseed oil and about 23 to about 28 parts by weight of the poly(isobutyl methacrylate); (i)(b) about 30 to about 80 wt.%, preferably from about 40 to about 75 wt.%, more preferably from about 45 to about 70 wt.% of one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a), wherein preferably, the one or more solvents capable of solubilizing the reaction product of (i)(a) are selected from dioctylcyclohexane, mineral oil, isocetyl palmitate, isocetyl palmitate, cyclopentasiloxane, dicaprylyl carbonate, octyl isostearate, trimethylhexyl isononanoate, 2-ethylhexyl isononanoate, dicaprylyl ether, dihexyl carbonate, polydecene, octyl cocoate, Attorney Docket No.085137-824799 isodecyl neopentanoate, isohexy decanoate, isodecyl octanoate, dihexyl ether, isododecane, isodecyl 3,5,5 trimethyl hexanoate, oleyl erucate, passiflora incarnata oil, jojoba oil, octyl palmitate, macadamia nut oil, isopropyl stearate, rapeseed oil, hexyl decanol, isotridecyl 3,5,5 trimethylhexanonanoate, polycitronellol acetate, mixed decanoyl and octanoyl glycerides, 2- ethylhexanoic acid, 3,5,5 trimethyl ester, cetystearyl octanoate, dimethicone, isopropyl palmitate, octyldodecanol, dioctyl adipate, isopropyl myristate, octyl palmitate (2-ethylhexyl palmitate), octyldodeceyl myristate, butyl octanoic acid, isopropyl stearate, caprylic / capric triglycerides, isopropyl isostearate, Jojoba oil, cyclomethicone, groundnut oil, almond oil, sunflower oil, decyl oleate, avocado oil, olive oil, dibutyl adipate, castor oil, calendula oil, wheatgerm oil, decyl oleate, avocado oil, calendula oil, propylene glycol monoisostearate, cocoglycerides, butylene glycol caprylate / caprate, C12-15 alkyl benzoate, caprylic / capric diglyceryl succinate, caprylic / capric triglyceride, cetearyl isonoanoate, cetearyl octanoate, cetyl dimethicone, coco-caprylate / caprate, cocoglycerides, Di-C12-13 alkyl tartrate, dibutyl adipate, dicaprylyl carbonate, dicaprylyl ether, hexyl decanol, hydrogenated polyisobutene, isoeicosane, isohexadecane, isopropyl palmitate, isopropyl stearate, octyl cocoate, octyl isostearate, octyl octanoate, octyl palmitate, octyl stearate, octyl dodecanol, octyldodecyl myristate, isopropyl stearate, pentaerythrityl tetraisostearate, phenyl trimethicone, polydecene, propylene glycol dicaprylate / dicaprate, stearyl heptanoate, tricaprylin, tridecyl stearate, tridecyl trimellitate, triisostearin, or combinations thereof, wherein more preferably, the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) are selected from polar oils and medium polar oils having a Polarity Index (interfacial tension) of 37 mN / m or below, wherein even more preferably, Attorney Docket No.085137-824799 the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) are selected from polar oils having a Polarity Index (interfacial tension) of 23 to 37 mN / m; (i)(c) optionally, about 1 to about 30 wt.%, preferably about 5 to about 25 wt.%, more preferably about 10 to about 20 wt.% of one or more alkanes, wherein preferably the one or more alkanes are selected from selected from C6-C16 alkanes, wherein even more preferably, the one or more alkanes are selected from isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n- decane, n-undecane, n-dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof, and even more preferably, at least one of the one or more alkanes is isododecane; (i)(d) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (i)(e) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%; wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition; Attorney Docket No.085137-824799 (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising, consisting essentially of, or consisting of: (ii)(a) about 50 to about 100 wt.%, preferably from about 60 to about 99 wt.%, more preferably from about 75 to about 95 wt.% of one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble, wherein preferably, the one or more nonpolar oils have a polarity index (interfacial tension) of at greater than 37 mN / m, wherein more preferably, the one or more nonpolar oils are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof, wherein even more preferably, at least one of the one or more nonpolar oils is squalane; (ii)(b) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (ii)(c) optionally, one or more solid fatty compounds, wherein if present, may be in an amount of from about 0.01 to about 20 wt.%, preferably about 0.1 to about 15 wt.%, more preferably about 1 to about 10 wt.%, wherein preferably, at least one of the one or more solid fatty compounds is a wax, for example, one or more waxes selected from candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, or mixtures thereof; (ii)(d) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, Attorney Docket No.085137-824799 chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%. wherein all weight percentages of (ii) are based on the total weight of the second anhydrous composition. The first anhydrous composition, the second anhydrous composition, or both the first anhydrous composition and the second anhydrous may be transparent or translucent. In another preferred embodiment, the method for removing makeup from skin comprises, consists essentially of, or consists of (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising, consisting essentially of, or consisting of: (i)(a) about 1 to about 40 wt.%, preferably about 10 to about 35 wt.%, more preferably about 20 to about 35 wt.% of a reaction product of about 72 to about 77 parts by weight of the linseed oil and about 23 to about 28 parts by weight of the poly(isobutyl methacrylate); (i)(b) about 30 to about 80 wt.%, preferably from about 40 to about 75 wt.%, more preferably from about 45 to about 70 wt.% of one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a), wherein preferably, at least one of the one or more solvents is polycitronellol acetate, caprylic capric triglycerine, isopropyl myristate, or combinations thereof; (i)(c) optionally, about 1 to about 30 wt.%, preferably about 5 to about 25 wt.%, more preferably about 10 to about 20 wt.% of one or more alkanes selected from isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n-decane, n- undecane, n-dodecane, n-tetradecane, n-tridecane, n- Attorney Docket No.085137-824799 tetradecane, n-pentadecane, or mixtures thereof, and even more preferably, at least one of the one or more alkanes is isododecane; (i)(d) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (i)(e) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%; wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition; (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising, consisting essentially of, or consisting of: (ii)(a) about 50 to about 100 wt.%, preferably from about 60 to about 99 wt.%, more preferably from about 75 to about 95 wt.% of one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble, wherein preferably, the one or more nonpolar oils are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures Attorney Docket No.085137-824799 thereof, wherein even more preferably, at least one of the one or more nonpolar oils is squalane; (ii)(b) optionally, one or more oil thickening agents, wherein if present, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, if present, may be in an amount of from about 0.01 to about 10 wt.%, preferably about 0.1 to about 5 wt.%, more preferably about 0.5 to about 4 wt.%, (ii)(c) optionally, one or more solid fatty compounds, wherein if present, may be in an amount of from about 0.01 to about 20 wt.%, preferably about 0.1 to about 15 wt.%, more preferably about 1 to about 10 wt.%, wherein preferably, at least one of the one or more solid fatty compounds is a wax, for example, one or more waxes selected from candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, or mixtures thereof; (ii)(d) optionally, one or more miscellaneous ingredients, preferably wherein the one or more miscellaneous ingredients, if present, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if present, are preferably in an amount of about 0.1 to about 15 wt.%, more preferably about 0.5 to about 10 wt.%, more preferably about 1 to about 6 wt.%. wherein all weight percentages of (ii) are based on the total weight of the second anhydrous composition. The first anhydrous composition, the second anhydrous composition, or both the first anhydrous composition and the second anhydrous may be transparent or translucent. Attorney Docket No.085137-824799 EXAMPLES Implementation of the present disclosure is provided by way of the following examples. The examples serve to illustrate the technology without being limiting in nature. Example 1 Solubility Testing Testing was carried out to ascertain the solubility of MycelX® in various solvent mixtures of polycitronellol acetate and squalane. To determine how the solvent mixtures influence solubility of MycelX®, the MycelX® was initially dissolved in polycitronellol acetate to form a transparent solution. Squalane was subsequently added to the solution in various amounts to assess how the addition of a nonpolar oil influences the solubility of the MycelX®. When polycitronellol acetate and squalane were combined in a weight ratio of 80 / 20 (MycelX®:squalane), the MycelX® was soluble in all amounts tested, i.e., 30 wt.%, 40 wt.%, 50 wt.%, and 60 wt.%. When polycitronellol acetate and squalane were combined in a weight ratio of 65:35 (polycitronellol acetate:squalane), the combination solubilized 10 wt.% of the MycelX® but only partially solubilized 20 wt.% of the MycelX®. At 20 wt.% MycelX®, the mixture became hazy (lost transparency) indicating a degree of precipitation. At 30 and 40 wt.% MycelX®, the MycelX® precipitated resulting in hazy mixture with a yellow color, which contained particles of the MycelX®. The results are summarized in the table below. Solubility of MycelX® Ratio of MycelX® / Squalane (wt %)e e ee Attorney Docket No.085137-824799 Example 2 Peeling Studies Various compositions were prepared and studied to determine their peel properties in comparison to a commercial-peeling facial cleanser, used as a benchmark. The compositions are shown in the following table. First Anhydrous Composition Inventive Comparative Benchmark * The commercial benchmark product reports the following ingredients list: Aqua / Water, Glycerin, Dicocodimonium Chloride, Carbomer, Steartrimonium Bromide, Isopropyl Alcohol, Dipotassium Glycyrrhizate, Allantoin, Citric Acid, Malic Acid, Lactic Acid, Sodium Hyaluronate, Aloe Barbadensis Leaf Extract, Punica Granatum Pericarp Extract, Soluble Collagen, Placental Protein, Fucus Vesiculosus Extract, Clematis Vitalba Leaf Extract, Spiraea Ulmaria Flower Extract, Equisetum Arvense (Horsetail) Extract, Hedera Helix (Ivy) Extract, Butylene Glycol, Phenoxyethanol, Fragrance; Parfum; Aroma, CI 16255; ACID RED 18. About 2 µL of matte ink long-wear makeup (red) was uniformly applied onto white supplare substrates (2x2 inch) and dried in a 37oC chamber for about 1 hour, or until dry. After drying, about 2 µL of inventive composition A, comparative composition B, comparative composition C (control), and the commercial benchmark were applied with pipette to separate dried makeup samples and rubbed with a finger over the makeup in a circular motion ten times. After waiting about 10 seconds, about 2 µL of squalane (second anhydrous composition) was subsequently applied with pipette to the makeup samples and rubbed with a fiber over the makeup in a circular motion ten times. Upon application of the squalane to the makeup sample treated with inventive composition A, the makeup coagulated and peeled Attorney Docket No.085137-824799 from the supplare substrate. The makeup samples treated with comparative compositions B, comparative composition C, and the commercial benchmark E did not coagulate and peel from the supplare substrate upon application of the squalane. Additionally, water was added on top of benchmark E, but there is very minimal peeling. Example 3 Makeup Removing Studies Various compositions were prepared and studied to determine their ability to remove makeup in comparison to a commercial benchmark makeup removing product. The compositions are shown in the following table. Inventive composition A, comparative compositions B and C, and the commercial benchmark product E are identical to those tested in Example 2. First Anhydrous Composition Inventive Comparative Benchmark * The commercial benchmark product reports the following ingredients list: Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium-15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol. About 20 µL of matte ink long-wear makeup (red) was uniformly applied onto a black supplare substrates (1.25x1.25 inch) and dried in a 37oC chamber for about 1 hour or until dry. After drying, about 20 µL of inventive composition A, comparative composition B, comparative composition C (control), comparative composition D, and the commercial benchmark product E were applied by pipette to separate dried Attorney Docket No.085137-824799 makeup samples and rubbed over the makeup in a circular motion ten times. After waiting about 10 seconds, about 20 µL of squalane (second anhydrous composition) was subsequently applied by pipette to the makeup samples and rubbed with a finger over the makeup in a circular motion ten times. For the sample treated with the commercial benchmark product, instead of squalane, an additional about 20 µL of the commercial benchmark product was reapplied in the second step. The samples were then wiped with a cotton pad under controlled pressure using a pressure sensor control the pressure at around 500 gram force L*a*b* values were measured using a Datacolor 600TMSpectraflash spectrometer. The percent removal of makeup was calculated according to the following formula. Each sample was run in triplicate and the results averaged. % Removal = (a*(after) – a*(before)) / (a*(before) – a*(substrate)) % Removal (L*a*b*) Inventive Comparative Benchmark The results show that inventive composition A removed the highest percentage of the long wear makeup, even more than the commercial benchmark standard.
[0002] Attorney Docket No.085137-824799 Example 4 Makeup Removing Studies Various compositions were prepared and studied to determine their ability to remove makeup in comparison to a commercial benchmark product for removing makeup. The compositions are shown in the following table. Inventive composition A and the commercial benchmark product E are identical to those studied in Examples 2 and 3. First Anhydrous Composition Inventive Comparative Benchmark * The commercial benchmark product reports the following ingredients list: Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium-15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol. About 20 µL of matte ink long-wear makeup (red) was uniformly applied onto black supplare substrates (1.25x1.25 inch) and dried in a 37oC chamber for about 1 hour, or until dry. After drying, about 20 µL of inventive compositions A – D or the commercial benchmark product E were applied by pipette to separate dried makeup samples and rubbed over the makeup with a finger in a circular motion ten times. After waiting about 10 seconds, about 20 µL of squalane (second anhydrous composition) was subsequently applied by pipette to the makeup samples. For the sample treated with the commercial benchmark product, instead of squalane, an additional about 20 µL of the commercial benchmark product was reapplied by pipette in the second step. The samples were then wiped with a cotton pad under controlled pressure using a SWIFT Tool in the green zone. L*a*b* values were measure using a Datacolor 600TMSpectraflash spectrometer. The percent removal Attorney Docket No.085137-824799 of makeup was calculated and according to the following formula. Each composition was tested in triplicate and the results averaged. % Removal = (a*(after) – a*(before)) / (a*(before) – a*(substrate)) % Removal (L*a*b*) Inventive Benchmark T y more long wear makeup, even more than the commercial benchmark standard. Example 5 Smudge Testing Various compositions were prepared and studied to determine their performance using a smudge test in comparison to a commercial benchmark product for removing makeup. The compositions are shown in the following table. Inventive composition A, comparative composition C, and the commercial benchmark product are identical to those studied in Examples 2-4. First Anhydrous Composition Inventive Comparative Benchmark Composition A was prepared by forming a premix of the reaction product and solvent (here, polycitronellol acetate). Isododecane was subsequently mixed into the premix until homogenous, forming a clear (transparent) composition. Attorney Docket No.085137-824799 * The commercial benchmark product reports the following ingredients list: Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium- 15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol. Inventive compositions useful as the second anhydrous compounds are shown below, as compositions 1-10. Second Anhydrous Composition 1 2 3 4 5 6 7 8 9 10 00 Two different waterproof, long-wear commercially available mascaras products were used in the testing, Mascara 1 and Mascara 2. The mascara products were each applied fifteen times to eyelash samples. The eyelash samples were then placed on top of white supplar. About 4 µL of inventive composition A or the commercial benchmark product E were applied by pipette to eyelash samples treated with Mascara 1 and separately about 4 µL of inventive composition A and comparative compositions C were applied by pipette to eyelash samples treated with Mascara 2. The eyelash samples were rubbed by hand ten times from left to right followed by rubbing ten times from front to back. After rubbing, about 4 µL of squalane (Composition 1) was applied by pipette to the eyelash samples treated with inventive composition A and comparative composition C. For the eyelash samples treated with the commercial benchmark product, instead of squalane, an additional about 4 µL of the commercial benchmark product was reapplied in the second step. Again, the eyelash samples were rubbed Attorney Docket No.085137-824799 by hand ten times from left to right followed by rubbing ten times from front to back. A round cotton pad was placed underneath the attachment of a texture analyzer (Stable Micro System). A pressure of 150 g was applied over the eyelash samples and the eyelash samples were pulled over the cotton pad for a 5 second period. L*a*b* values were measured using a VeriVide DigiEye® Imaging System and L values compared. The higher the L value, the brighter / whiter the sample. Each composition was tested in triplicate and the results averaged. % Removal Mascara 1 Mascara 2 The results sh ow a nven ve compos on removed significantly more long wear makeup than the commercial benchmark and comparative composition C. Example 6 Various premix compositions may be created by mixing the reaction product with one or more solvents as disclosed herein. Examples of such premixes can be seen in the table below. Exemplary Premix Compositions (EPC), all listed values are %w / w. Material EPC1EPC2 EPC3 EPC4 EPC5om poy so uy me acryae an e nsee o . Attorney Docket No.085137-824799 The foregoing description illustrates and describes the disclosure. Additionally, the disclosure shows and describes only the preferred embodiments. However, as mentioned above, it is to be understood that it is capable to use in various other combinations, modifications, and environments and is capable of changes or modifications within the scope of the invention concepts as expressed herein, commensurate with the above teachings and / or the skill or knowledge of the relevant art. The embodiments described herein above are further intended to explain best modes known by applicant and to enable others skilled in the art to utilize the disclosure in such, or other, embodiments and with the various modifications required by the particular applications or uses thereof. Accordingly, the description is not intended to limit the invention to the form disclosed herein. Also, it is intended to the appended claims be construed to include alternative embodiments. As used herein, the terms “comprising,” “having,” and “including” are used in their open, non-limiting sense. The terms “a,” “an,” and “the” are understood to encompass the plural as well as the singular. Thus, the term “a mixture thereof” also relates to “mixtures thereof.” Throughout the disclosure, the term “a mixture thereof” is used, following a list of elements as shown in the following example where letters A-F represent the elements: “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture thereof.” The term, “a mixture thereof” does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a mixture of any two or more of A, B, C, D, E, and F can be included. In other words, it is equivalent to the phrase “one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture of any two or more of A, B, C, D, E, and F.” Likewise, the term “a salt thereof” also relates to “salts thereof.” Thus, where the disclosure refers to “an element selected from the group consisting of A, B, C, D, E, F, a salt thereof, and a mixture thereof,” it indicates that that one or more of A, B, C, D, and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included, or a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included. Attorney Docket No.085137-824799 The salts referred to throughout the disclosure may include salts having a counter-ion such as an alkali metal, alkaline earth metal, or ammonium counterion. This list of counterions, however, is non-limiting. Appropriate counterions for the components described herein are known in the art. The expression “one or more” means “at least one” and thus includes individual components as well as mixtures / combinations. The term “plurality” means “more than one” or “two or more.” The term "transparent” with respect to a transparent composition indicates that the composition has transmittance of at least 80% at a wavelength of 600 nm, for example measured using a Lambda 40 UV-visible spectrometer. The compositions may have, for example, a transmittance of at least 80%, at least 90%, or at least 95% at a wavelength of 600 nm, measured, for example, using a Lambda 40 UV-visible spectrometer. The term “clear” is interchangeable with the term “transparent” for purposes of the instant disclosure. The term “translucent” with respect to a translucent composition indicates that the composition has a transmittance of at least 50% at a wavelength of 600 nm, for example measured using a Lambda 40 UV-visible spectrometer. Other than in the operating examples, or where otherwise indicated, all amount expressing quantities of ingredients and / or reaction conditions may be modified in all instances by the term “about,” meaning within + / - 5% of the indicated number. Thus, for a range of “about 1 to about 10 wt.%,” The lower amount of “about 1 wt.%” may extend down to 0.95 wt.%, which is 5% less than 1 wt.%. The higher amount of “about 10 wt.%” may extend up to 10.5 wt.%, which is 5% higher than 10 wt.%, i.e., a range of “0.95 wt.% to 10.5 wt.%.” All percentages, parts and ratios herein are based upon the total weight of the compositions of the present invention, unless otherwise indicated. Some of the various categories of components identified may overlap. In such cases where overlap may exist and the composition includes both components (or the composition includes more than two components that overlap), an overlapping compound does not represent more than one component. For example, certain compounds may be considered both oily solvent and a surfactant. If a particular composition includes both an oily solvent and a surfactant, a single compound will Attorney Docket No.085137-824799 serve as only the oily solvent or only as the surfactant (the single compound does not simultaneously serve as both the oily solvent and the surfactant). As used herein, all ranges provided are meant to include every specific range within, and combination of sub ranges between, the given ranges. Thus, a range from 1-5, includes specifically 1, 2, 3, 4 and 5, as well as sub ranges such as 2-5, 3- 5, 2-3, 2-4, 1-4, etc. All ranges and values disclosed herein are inclusive and combinable. For examples, any value or point described herein that falls within a range described herein can serve as a minimum or maximum value to derive a sub- range, etc. The term “substantially free” or “essentially free” as used herein means that there is less than about 2% by weight of a specific material added to a composition, based on the total weight of the compositions. Nonetheless, the compositions may include less than about 1 wt.%, less than about 0.5 wt.%, less than about 0.1 wt.%, or none of the specified material. For example, if a composition is essentially free from compound X, the composition includes less that 2 wt.% of compound X, or less than 1 wt.% of compound X, or less than 0.5 wt.% of compound X, or less than 0.1 wt.% of compound X, or is free from compound X. All components that are positively set forth in the instant disclosure may be negatively excluded from the claims, e.g., a claimed composition may be “free,” “essentially free” (or “substantially free”) of one or more components that are positively set forth in the instant disclosure. All publications and patent applications cited in this specification are herein incorporated by reference in their entirety, and for any and all purposes, as if each individual publication or patent application were specifically and individually indicated to be incorporated by reference. In the event of an inconsistency between the present disclosure and any publications or patent application incorporated herein by reference, the present disclosure controls.
Claims
Attorney Docket No.085137-824799 Claims 1. A method for removing makeup from skin comprising: (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) optionally, one or more alkanes; (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising: (d) one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble.
2. The method of claim 1, wherein the first anhydrous composition is transparent.
3. The method of claim 1 or 2, the natural or food-derived oil is a drying oil or semi-drying oil selected from linseed oil, sunflower oil, tung oil, fish oil, cottonseed oil, soybean oil, or combinations thereof, and the methacrylate or acrylate polymer is derived from monomers selected from isobutyl methacrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, or combinations thereof.
4. The method of any one of the above claims, wherein the hydrophobic polymer is the reaction product of about 50 to about 85 parts by weight of the natural or food-derived oil and about 15 to about 50 parts by weight of the methacrylate or acrylate polymer.
5. The composition of any one of the above claims, wherein the methacrylate or acrylate polymer is an isobutyl methacrylate polymer.Attorney Docket No.085137-824799 6. The composition of any one of the above claims, wherein the hydrophobic polymer is a reaction product of linseed oil and poly(isobutyl methacrylate).
7. The composition of claim 6, wherein the hydrophobic polymer is the reaction product of about 72 to about 77 parts by weight of linseed oil and about 23 to about 28 parts by weight of isobutyl methacrylate polymer.
8. The method of any one of the above claims, wherein the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) have a dispersion component (D), a polar component (P), and a hydrogen bonding component (H), and a distance (Ra) less than or equal to 13.4 MPa0.5as per Hansen Solubility Parameters, wherein the distance (Ra) is defined by formula (I): ^^^^ = √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2 (I)wherein D1 is 16.8 MPa0.5, P1 is 4.8 MPa0.5, and H1 is 13.0 MPa0.
5.
9. The composition of any one of the above claims, wherein at least one of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) is selected from polycitronellol acetate, caprylic / capric triglyceride, isododecane, isohexadecane, tetradecane, isopropyl myristate, isopropyl alcohol, octyldodecanol, phenoxyethanol, castor oil, or mixtures thereof.
10. The method of any one of the above claims, wherein the first anhydrous composition comprises: (a) about 10 to about 40 wt.% of the hydrophobic polymer; (b) about 45 to about 75 wt.% of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) about 1 to about 25 wt.% of the one or more alkanes; wherein all weight percentages are based on a total weight of the first anhydrous composition.Attorney Docket No.085137-824799 11. The method of any one of the above claims, wherein the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) are selected from dioctylcyclohexane, isocetyl palmitate, cyclopentasiloxane, dicaprylyl carbonate, octyl isostearate, trimethylhexyl isononanoate, 2-ethylhexyl isononanoate, dicaprylyl ether, dihexyl carbonate, polydecene, octyl cocoate, isodecyl neopentanoate, isohexy decanoate, isodecyl octanoate, dihexyl ether isododecane, isodecyl 3,5,5 trimethyl hexanoate, oleyl erucate, passiflora incarnata oil, Jojoba oil, octyl palmitate, macadamia nut oil, isopropyl stearate, rapeseed oil, hexyl decanol, isotridecyl 3,5,5 trimethylhexanonanoate, polycitronellol acetate, mixed decanoyl and octanoyl glycerides, 2-ethylhexanoic scid 3,5,5 trimethyl ester, cetystearyl octanoate, dimethicone, isopropyl palmitate octyldodecanol, dioctyl adipate, isopropyl myristate, octyl palmitate (2-ethylhexyl palmitate), octyldodeceyl myristate, butyl octanoic acid, isopropyl stearate, caprylic / capric triglycerides, isopropyl isostearate, cyclomethicone, groundnut oil, almond oil, sunflower oil, decyl oleate, avocado oil, olive oil, dibutyl adipate, castor oil, calendula oil, wheatgerm oil, sunflower oil, decyl oleate, castor oil, calendula oil, wheatgerm oil, propylene glycol monoisostearate, cocoglycerides, or mixtures thereof.
12. The method of any one of the above claims 1, wherein the first anhydrous composition comprises the one or more alkanes and the one or more alkanes are selected from C6-C16 alkanes, preferably wherein the one or more alkanes are selected from isododecane, isodecane, isohexadecane, n-heptane, n- octane, n-nonane, n-decane, n-undecane, n-dodecane, n-tetradecane, n- tridecane, n-tetradecane, n-pentadecane, or mixtures thereof.
13. The method of any one of the above claims, wherein the first anhydrous composition comprises: (a) about 10 to about 40 wt.% of the hydrophobic polymer; (b) about 45 to about 75 wt.% of polycitronellol acetate; and (c) about 1 to about 25 wt.% of isododecane; wherein all weight percentages are based on a total weight of the first anhydrous composition.Attorney Docket No.085137-824799 14. The method of any one of the above claims, wherein the one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof.
15. The method of any one of the above claims, wherein the second anhydrous composition further comprises one or more oil thickening agents, for example, one or more oil thickening agents selected from polymers, gums, organoclays, polyethylenes, silica, or mixtures thereof, more preferably wherein the one or more oil thickening agents are selected from acrylate copolymer, hectorite gel, guar gum, cellulose gum, Caesalpinia Spinosa gum, gum Arabic, starch, silica, silica dimethyl silylate, behenate, glyceryl dibehenate, behenyl behenate, or mixtures thereof.
16. The method of any one of the above claims, wherein the second anhydrous composition further comprises one or more solid fatty compounds, wherein preferably the one or more solid fatty compounds selected from waxes and solid fatty alcohols, for example, candelilla wax, carnauba wax, castor wax, beeswax, lanolin Wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, cetyl alcohol, stearyl alcohol, cetearyl alcohol, lanolin alcohol, or mixtures thereof.
17. The method of any one of the above claims, wherein the second anhydrous composition comprises: (a) about 70 to about 99.9 wt.% of the one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble; (b) optionally, about 1 to about 15 wt.% of one or more oil thickening agents; and (c) optionally, about 1 to about 15 wt.% of one or more waxes; wherein all weight percentages are based on a total weight of the second anhydrous composition.Attorney Docket No.085137-824799 18. A method for removing makeup from skin comprising: (i) applying a first anhydrous composition to skin upon which makeup is present, the first anhydrous composition comprising: (a) about 10 to about 40 wt.% of a hydrophobic polymer that is a reaction product of linseed oil and poly(isobutyl methacrylate); (b) about 45 to about 75 wt.% of polycitronellol acetate; and (c) about 1 to about 25 wt.% of isododecane; wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition. (ii) applying a second anhydrous composition to skin upon which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising: (a) about 70 to 95 wt.% of one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble; (b) optionally, about 1 to about 15 wt.% of one or more oil thickening agents; and (c) optionally, about 1 to about 15 wt.% of one or more waxes; wherein all weight percentages of (ii) are based on a total weight of the second anhydrous composition.
19. The method of claim 18, wherein the first anhydrous composition is transparent.
20. A makeup removing kit comprising: (i) first anhydrous comprising: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) optionally, one or more alkanes; (ii) a second anhydrous composition comprising: (d) one or more nonpolar oils in which the hydrophobic polymer of (i)(a) is not soluble;Attorney Docket No.085137-824799 wherein the first anhydrous composition and the second anhydrous composition are separately contained.
21. A cosmetic premix composition, consisting of: a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; and one or more solvents, each solvent having Hansen Solubility Parameters that satisfy ^^^^ ≤ √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra = 13.4 MPa0.5, D1 = 16.8 MPa0.5.
22. The cosmetic premix composition of claim 21, wherein the one or more solvents comprises caprylic / capric triglyceride, isopropyl myristate, citronellyl acetate, acetone, triglycerides, a triglycerides-containing oil, or a combination thereof.
23. The cosmetic premix composition of claim 22, wherein at least some triglycerides are provided by a vegetable oil.
24. The cosmetic premix composition of any one of claims 21-23, wherein the reaction product is present in an amount of 10-80%by weight of the cosmetic premix composition.
25. The cosmetic makeup composition of one of claims 21-24, wherein the natural or food-derived oil is linseed oil.
26. A method of manufacturing a cosmetic composition, comprising: providing a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; providing one or more solvents, each solvent having Hansen Solubility Parameters that satisfy ^^^^ ≤ √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra= 13.4 MPa0.5, D1 = 16.8MPa0.5; and combining the reaction product and the one or more solvents to form a premix consisting of the reaction product and the one or more solvents.Attorney Docket No.085137-824799 27. The method of claim 26, wherein the one or more solvents comprises caprylic / capric triglyceride, isopropyl myristate, citronellyl acetate, acetone, triglycerides, a triglycerides-containing oil, or a combination thereof.
28. The method of claim 27, wherein at least some of the triglycerides are provided by a vegetable oil.
29. The method of claim 26 or 27, wherein the reaction product is present in an amount of 5-25% by weight of the cosmetic premix composition.
30. The method of any one of claims 26-29, wherein the natural or food-derived oil is linseed oil.
31. The method of any one of claims 26-30, further comprising combining one or more additional materials with the premix.
32. A cosmetic composition comprising: a cosmetic premix consisting of: a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; and one or more solvents, each solvent having Hansen Solubility Parameters that satisfy ^^^^ ≤ √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra= 13.4 MPa0.5, D1 = 16.8and one or more additional materials.
33. The cosmetic composition of claim 32, wherein the one or more additional materials includes one or more additional solvents having Hansen Solubility Parameters that satisfy ^^^^ > √4(^^ − ^^1)2 + (^^ − ^^1)2 + (^^ − ^^1)2, where Ra = 13.4 MPa0.5, D1 = 16.8 MPa0.5, P1 = 4.8 MPa0.5, and H1 = 13.0 MPa0.
5.
34. The cosmetic composition of claim 32 or 33, wherein the one or more additional materials includes one or more pigments, a filler, a polyol, aAttorney Docket No.085137-824799 polyester of polyglycerol having 2 to 10 glycerol units, and / or a glyceryl ester of a fatty acid.
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