Method and system for the demilitarization of conventional ammunition of all types and calibers as well as chemical and biological weapons with integrated artificial intelligence (AI)

Abstract

Method and system for the demilitarization of conventional ammunition of all types and calibers as well as chemical and biological weapons in which takes place the automated detection of each type via an Artificial Intelligence (AI) system, their instantaneous destruction and the immediate separation of the chemical-biological agent, the explosive material and the metallic mass within a co-rotating pulsed vortex environment under controlled electromagnetic field, which is applied by entering into a specialized feeding apparatus (1), a bipolar rotational vortex chamber (2), a metal parts separator (3), a metal mass processing unit (4), a configured annular drainage and separation apparatus (5), an electric arc unit (6), an off gases treatment unit originating from the electric arc unit, a gaseous pollutants treatment unit (8), a closed-loop type A and B emulsion supply-recycling system and a emulsion treatment system via E / M pulse application (111), while the whole operation is controlled by a control and operation unit (9).

Description

[0001] DESCRIPTION

[0002] Method and system for the demilitarization of conventional ammunition of all types and calibers as well as chemical and biological weapons with integrated Artificial Intelligence (Al)

[0003] The invention relates to a method and a system for the demilitarization of conventional ammunition of all types and calibers as well as chemical and biological weapons in which is it takes place the automated detection of each type via an Artificial Intelligence (Al) system, their instantaneous destruction and the immediate separation of the chemical-biological agent, the explosive material and the metallic mass within a co-rotating pulsed vortex environment under a controlled electromagnetic field. The process is completed with the production of stable final products in an environment of aqueous alkaline solution of specific qualitative and quantitative composition under the influence of high power microwave radiation. The method is fully automated and the system achieves the destruction of high-volume ammunition at a very high rate, meeting with all hygiene and safety as well as environmental protection standards.

[0004] The applied method is in full compliance with the term "demilitarization", as the ammunition and biological / chemical weapons undergo irreversible disassembly in such manner that their reconstruction is impossible. Specifically, at the end of the process, clean metallic parts are produced along with the following basic chemical products: gases (such as carbon dioxide, water and nitrogen), as well as various salts (such as phosphates, chlorides, sulphates, carbonates and fluorides of calcium, sodium or potassium) depending on the specific agent.

[0005] To date, there is no appropriate method and system for the demilitarization of different materials-chemical and biological weapons that covers their full spectrum. The two most commonly verified technologies that are acceptable under legislative standards are incineration and chemical inactivation, which however involve issues that must be considered such as the high costs of destruction and safety, as well as environmental, legal and political factors.

[0006] Specifically, some studies have identified incineration as the preferred CWA destruction method due to the perceived low cost and relative simplicity of the technology. However, it becomes clear that the incineration of chemical agents involves both short and long-term nature risks, which may not be acceptable to the population. The integrity of public health and ecosystem is threatened by the emission of materials that can escape during the combustion process, resulting in the dispersion of uncharacterized products of incomplete combustion into the atmosphere. The obvious problems of incineration forced US government authorities to consider alternative methods, including CWA chemical treatment which leads to environmentally neutral products. However, this idea was rejected in the United States after research publications stated that, compared to incineration, chemical neutralization processes "are slow, complex, produce excessive amounts of waste that cannot be certified as precursor-free”, and require higher capital and operating costs.

[0007] A promising alternative method that destroys or neutralizes chemical agents is the process of hydrolysis. However, there are several significant problems in the hydrolysis of chemical weapons agents. One problem is the caustic, pungent and toxic nature of the resulting hydrolysate. In addition, the hydrolysates contain precursors of the chemical agent, which present additional problems in relation to legal compliance. The terms of chemical weapons treatment clarify that in order to take place the complete destruction of a chemical agent, any precursors that may react to recreate the chemical agent must be also destroyed.

[0008] The present invention constitutes an automated method for the demilitarization of conventional munitions of all types and calibers as well as chemical and biological weapons. Prior art techniques such as US2004 / 7442848B2, US2000 / 6017750A and US2002 / 649828B1 also describe methods and systems mainly for the hydrolysis of chemical weapons that aim to solve the same technical problems as the present invention, but present technical disadvantages. Specifically, they require a combination of processes such as UV radiati on / oxidation without however, being able to fully destroy precursor substances, in contrast to the present invention which accomplishes this under the influence of high power microwave radiation, in combination with the subsequent exposure of hazardous and toxic gases and elements to plasma conditions. The system described in the present invention constitutes a method, based on which the demilitarization is completed rapidly and instantaneously without the emission of polluting liquids, solid or gaseous by-products and additionally offers the possibility of recycling the produced materials. Also, the speed at which they are destroyed is such that it prevents a potential initiation of the explosive chain (high order explosion).

[0009] By the application of the present invention, the complete demilitarization of various materials-chemical and conventional ammunition of all types and calibers takes place, on site at their storage locations, as it involves mobile units, with the capability for ecological, massive and rapid destruction of obsolete chemical and conventional ammunition and the separation of explosive material from the output metallic mass of the destructed ammunition as well as the complete inactivation of the energetic materials (explosive or propellant charge). A key design principle of the system is to limit exposure of the minimum number of people for the shortest duration, to the minimum possible amount of ammunition and explosives.

[0010] The invention focuses on an upgraded and fully ergonomic system which includes a bipolar rotational vortex chamber (2), whose operation consists of the coordinated effect of a magnetic field on materials of different granulometry (surface-volume) and the creation of a pulsed rotational vortex, resulting in the selective and rapid destruction of them. Furthermore, the use of an electromagnetic wave radiation device in order to uniformly excite the molecules in a frequency range of 300MHz- 300GHz completes the total inactivation of the chemical agents. Through the aforementioned process, the destruction / demilitarization of ammunition is carried out due to the significant increase in the width of the pulse-field path along and across the chamber and also due to the use of electromagnetic waves, which minimizes the time of demilitarization and allows the processing of large caliber ammunition.

[0011] The present invention also provides a specific method for processing chemical agents hydrolysates. Specifically, the present invention enables the successful treatment of chemical agent hydrolysates by means of an aqueous emulsion of specific qualitative and quantitative composition which reduces the toxicity of the hydrolysate while simultaneously rendering the component chemical precursors unsuitable for reaction during the reformation of the hydrolyzed agent.

[0012] The invention also consists of a method that introduces new additional steps, not obvious to the expert, which ensure the automated process through the use of robotic systems without human intervention, the use of artificial intelligence for type-specific detection, the continuous operation without lengthy preparation intervals, the reintroduction of the resulting materials into the economic cycle (via recycling or in a useful or harmless form), the minimization of the quantities of accumulated energetic materials, the treatment of all process waste, and the possibility of processing and utilizing ammunition at their storage location.

[0013] Furthermore, the method, due to its uniqueness and effectiveness, achieves integrated management and recirculation of the emulsion as well as of the gaseous and solid pollutants resulting from the destruction of the explosive materials, leading to minimal release of gaseous pollutants into the atmosphere and minimal generation of hazardous solids and liquid waste. Therefore, it ensures the complete demilitarization of all types and calibers of ammunition as well as chemical / biological weapons, by destroying the deactivated explosive substance, with minimal environmental impact, and also fully separates and purifies recyclable materials (brass, steel, copper), making full utilization of the materials which, due to their high purity, present significant commercial value for recycling.

[0014] A brief disclosure of the method steps and the machinery system that implements it follows. The method includes, in summary, the following steps:

[0015] Step 1: Entry into a specialized feeding apparatus (1) with integrated Artificial Intelligence (Al) by which ammunition is led to destruction Step 2: Entry into a bipolar rotational vortex chamber (2) for ammunition destruction

[0016] Step 3: Entry into a metal parts separator (3)

[0017] Step 4: Entry into a metal mass processing unit (4)

[0018] Step 5: Entry into a semi-solid waste configured annular drainage and separation apparatus (5)

[0019] Step 6: Entry into an electric arc unit (6) Step 7 : Entry into an off gases treatment unit originating from the electric arc unit

[0020] Step 8: Entry into a gaseous pollutants treatment unit (8)

[0021] Step 9: Entry into a closed-loop type A emulsion supply -recycling system Step 10: Entry into a type B emulsion recirculation closed-loop system Step 11 : Entry into an emulsion treatment system via E / M Pulse application (111)

[0022] In order to understand figures and the description of operation, it should be noted that electromechanical equipment that implements the stages of the present method is housed in five shipping -containers-type units. These containers are numbered according to the operational sequence of the machinery implementing the present method. Specifically:

[0023] - Container 1 (100) which includes the specialized feeding apparatus (1), the bipolar rotational vortex chamber (2) and the metal parts separator (3)

[0024] - Container 2 which includes the metal mass processing unit (4)

[0025] - Container 3 (101) which includes the configured annular drainage and separation device (5), the electric arc unit (6) and the off gases treatment unit originating from the electric arc unit

[0026] - Container 4 which includes the gaseous pollutants treatment unit (8)

[0027] - Container 5 which includes the control and operation unit (9)

[0028] The method and the machinery system that implements it, concern a continuous operation system, in the sense that the product (in this case ammunition of all types and calibers), enters in its original state and exits directly in its final one, without time-consuming procedures and in minimal time.

[0029] The entire operation of the system is controlled by a control and operation unit (9), from which the operator(s) can supervise and control every phase of the process and each subsystem. The Control and Operation Unit is equipped with LCD screens, electronic operation and display systems, computers with remote control application (SCADA), control and operation panels for manual and automatic operation, PLC units for automatic programming and process control, UPS, DVR for virtual data logging, necessary counters and emergency stop provisions. The operator can automatically or manually control the entire installation through the installed remote control application (SCADA), but also supervise the operation of the system through the monitors to intervene if it is necessary.

[0030] Where power supply from the grid is not available, the system can be powered via a generator unit.

[0031] The present method concerns a highly advanced technology system, whose advantages lie in the fact that:

[0032] The present invention achieves the massive and rapid destruction of chemical and conventional ammunition, regardless of their initial state and the order of input. Since the ammunition do not undergo any pretreatment before feeding, in the present invention, their destruction occurs instantaneously.

[0033] One of the main advantages of the artificial intelligence system for detection by type is the minimization of human error, since Al system decisions are based on data and algorithms, leading to increased accuracy and reduced errors. Furthermore, the Al system cooperates with various technologies that help machines make faster decisions, resulting in quicker actions, as it can detect patterns from data analysis, resulting in predictions.

[0034] Additionally, the present invention achieves the processing of a wide range of ammunition, of all types and calibers, many of which currently lack a recommended destruction method or where such methods exist involve high risk both for the persons life involved in this process and for the environment, since no assurance is taken, or it is impossible to take for its protection.

[0035] An advantage of the present invention is also that no hazardous byproducts are produced, as well as no explosions are carried out and no nuclear energy is used to destroy the ammunition.

[0036] Another advantage of the present method is that the system machinery that applies it, i.e. the mechanical equipment, along with the required electrical and electronic equipment, can be manufactured in such dimensions as to allow installation within containers, such as standard shipping containers. These containers, (which may also have cooling systems), can be transported for example by train, ship, truck and deployed immediately to any location worldwide where destruction of ammunition is required, allowing this to occur on-site at military units, without the need to transport the stored munitions off-site. The ability to install the system machinery of the invention inside transportable containers makes the invention flexible, mobile and applicable anywhere.

[0037] An advantage is the fact that the design of the bipolar rotational vortex chamber (2) allows the continuous feeding of ammunition, since the time required to fragment incoming ammunition is significantly shorter than that of any other technology. Simultaneously, the continuous spraying of emulsion inside the chamber prevents explosions and ensures immediate inactivation of the explosive substance.

[0038] The advantages also of ammunition segmentation into separate streams are positive and multiple. Firstly, the process is being greatly simplified because the material streams are directed to distinct processes for their treatment, which are better controlled and increase process safety. The applied technologies for each stream are adapted to the needs of the materials, instead of using technology for mixed waste streams which in any case is complex and expensive.

[0039] A major advantage also is the fact that the design of the configured annular drainage and separation (5) apparatus of the explosive material and generally of solid particulates from the emulsion enables the maximum possible surface collection of the emulsion. At the same time, the ergonomic design of the smooth transition of the hydro to air transport process, leads to the gradual and massive removal and concentration of solid particulates, with a high degree of efficiency compared to any other technology.

[0040] Also the innovative design of the systems of the thermal oxidizer (68) and of the electrical emission control unit (131) where the primary and secondary off gases oxidation-afterburning from the electric arc unit (6) takes place, leads to a maximization of combustion efficiency, with a significant reduction in the percentage of harmful substances to off gases, causing less environmental damage.

[0041] An advantage of this method is also the fact that the microbial load is in a liquid phase, which according to literature is better absorber of microwave energy than the gas phase. Therefore, the transfer of thermal energy to the material takes place almost instantaneously and the speed of heating can be accomplished within seconds or minutes, which could take several minutes, several hours, even days using conventional heating and sterilization methods. Therefore, the method has the advantage that the application time of E / M energy is at low levels compared to the time required to kill the same population of biological organisms in the air phase. This fact leads to the simplification of the process to a great extent.

[0042] An advantage is also the fact that the electromagnetic microwave pulses interact uniformly to all material causing total (spatial) heating. The incident energy is bound directly by the material and is not transferred to other points. This leads to significant energy savings as well as to a significant reduction in process operation costs.

[0043] Another major advantage of the mentioned system is the fact that the demilitarization process output can be separated into its basic components (explosive material, chemical agent and metal mass of the destroyed ammunitions) for their commercial exploitation. In particular, takes place the separation and recovery of materials (brass, steel, copper) and their re-introduction into the production cycle with a significant commercial sale value.

[0044] Each subsystem and chamber comprising this invention can be isolated from its adjacent subsystems. The entire installation is easily decomposable into its individual parts with parallel potential of connection with additional subsystems for future use.

[0045] All subsystems of the present invention are resistant to explosions and high temperatures.

[0046] Its operation can be characterized as ecological since the advanced treatment of gaseous and solid residues, as well as the integrated management and recirculation of the emulsion, minimizes the release of gaseous pollutants into the atmosphere and the generation of solid and liquid hazardous waste. Additionally, automation systems, alarm systems, and temperature and pressure detectors are installed in all individual subsystems that are activated if the process functions fail to operate. They also permit early detection of malfunction when there is insufficient temperature and exposure time.

[0047] The method and system of the present invention will be better understood from the following description and with the help of the attached figures, specifically:

[0048] Figure 1 presents a perspective view of all the electromechanical equipment that implements the present method, showing the operational sequence of the machinery which implement the present method within Container 1 (100), Container 2 which includes the metal mass processing unit (4), Container 3 (101), Container 4 which includes the gaseous pollutants treatment unit (8) and Container 5 which includes the control and operation unit (9).

[0049] Some of the machines that perform the steps of the present method are depicted, in the order shown in figure:

[0050] Specialized feeding apparatus (1)

[0051] Conveyor belt (14)

[0052] Type A emulsion concentrate tank (112).

[0053] Type A Emulsion Tanks (56)

[0054] Type B Emulsion Tanks (85)

[0055] Type B Emulsion Concentrate Tanks (119)

[0056] Figure 2 presents a perspective view of Container 1 (100) and a side view of the specialized feeding apparatus (1) by which ammunition is led to destruction.

[0057] Figure 3 presents a perspective view of Container 1 (100), showing the two rotating airlocks of parallel connection (10) and (11) and the piping (15) between them, the pump array (110) which transfers the emulsion from drainage tank of the metal parts separator (3) and the pumps (113) that transfer the emulsion to the emulsion treatment system via E / M Pulse Application (111). Figure 4 presents a front view of Container 1 (100) emphasizing the two hydraulic motors (12) and (13) and the piping (15) between the airlocks (10), (11), the pressure relief valves (114) , the activated carbon filters (52), the vacuum system of air regulator (33), the maintenance ports (24), the custom length conical parts (30) and the pump array (110), (113).

[0058] Figure 5 presents a developed view of the main parts of Container 1 (100), showing the electromagnetic pulse system (111), the two parallel connection rotating air locks (10) and (11), the bipolar rotational vortex chamber (2) and the metal parts separator (3).

[0059] Figure 6 presents a front view of the bipolar rotational vortex chamber (2), focusing on the cylindrical cross section drum (28), showing in side section the multiaxial eccentric reciprocating loads (141), the metal members (142) of anti-friction steel and the narrow area (143) between them.

[0060] Figure 7 presents a vertical section of the bipolar rotational vortex chamber (2) with detailed construction features.

[0061] Figure 8 presents the complete development of parts of the bipolar rotational vortex chamber (2) with detailed construction features.

[0062] Figure 9 presents a front cross section of Container 1 (100) showing the appropriate outlets (35) for connection with pipes of corresponding diameter (36) creating a recirculation loop, as well as the separator of metal pieces (3) with its internal provisions in detailed illustration.

[0063] Figure 10 presents a perspective view of Container 2 (4), showing all its internal systems in detail.

[0064] Figure 11 presents a front view and a vertical cross section of Container 2 (4), showing the inclined chain conveyor (39), the chain conveyor (47), which enters the entire electric incandescence chamber (48), the multiple induction heaters elements (49), the second chain conveyor of special type (51) and the emulsion tank (56) of type A. Figure 12 presents a perspective view of Container 3 (101), detailing the semi-solid waste configured annular drainage and separation apparatus (5), the electric arc unit (6), the B-type emulsion concentrate tanks (119) with the analog level indication servos (116), the analog ph measurement servos (117), the emulsion filling servos (118) and the condenser array (81).

[0065] Figure 13 presents a side view of the electric arc unit (6) as well as its internal details.

[0066] Figure 14 presents a perspective view of the semi-solid waste configured annular drainage and separation apparatus (5) with its internal subsystems in detail.

[0067] Figure 15 presents a front view of Container 3 (101) detailing the electrical emission control device (131), the thermal oxidizer (68), the catalytic converter (78), the condenser array (81), the activated carbon filters (52) as well as various auxiliary systems.

[0068] Figure 16 presents in detail the internal arrangements of the thermal oxidizer (68).

[0069] Figure 17 presents in detail the internal arrangements of the electrical emission control device (131).

[0070] Figure 18 presents a horizontal cross section of the internal layout (133) of the electrical emission control device (131), emphasizing the sequence (139) of the cylindrical porous rods (70).

[0071] Figure 19 presents a horizontal cross section view of Container 3 (101) showing the electrical emission control device (131), the thermal oxidizer (68), the electric arc unit (6), the shaped annular drainage and separation apparatus (5), the catalytic converter (78), the condensers (81) and the moisture absorption device (128) with the wire meshes (129).

[0072] Figure 20 presents a perspective view of Container 4 (8), detailing the gas-gas exchanger (87), the liquid-gas exchanger (97), the B-type emulsion tanks (85) with the analog level indicator servos (116) and the analog ph measuring servos (117) and the water concentrate tank (98) with the pumping systems (99), (102).

[0073] Figure 21 presents in detail the internal arrangements of the gas-to-gas exchanger (87).

[0074] Figure 22 presents in detail the internal arrangements of the liquid-gas exchanger (97).

[0075] Figure 23 presents a horizontal section of Container 4 (8), showing the gas-gas exchanger (87), the liquid-gas exchanger (97), the suction and filtration system (104) with the centrifugal absorber (109) and the gas to atmosphere pump (106), the type B emulsion tanks (85), the water concentrate tank (98), the cooler (103), the liquid-gas exchanger (97) and the twin series exchangers (140).

[0076] Figure 24 presents a perspective view of the suction and filtration system (104) with its sub-systems.

[0077] Figure 25 presents a front view of Containers 1 (100) and 2 (4) detailing the type A emulsion supply -recycling loop.

[0078] Figure 26 presents a front view of Containers 3 (101) and 4 (8) detailing the type B emulsion supply -recirculation loop.

[0079] Figure 27 presents a perspective view of Container 1 (100) detailing the emulsion treatment system via E / M Pulse Application (111).

[0080] A non-restrictive application of the method and the system that applies it is described below with reference to the attached figures.

[0081] Step 1: Entry into a specialized feeding apparatus (1) with integrated Artificial Intelligence (Al) by which ammunition is led to destruction

[0082] For proper and safe operation of the Unit, ammunition is first introduced into the specialized feeding apparatus (1), which consists of two rotating airlocks of parallel connection (10) and (11) which airlocks are placed in Container 1 (100) (see Figure 3). Motion transmission of the two supply airlocks is achieved by means of two corresponding hydraulic motors (12) and (13). The ammunition to be destroyed is safely placed on a conveyor belt (14) and first enters the first airlock (10). The speed of movement and the special design of the conveyor belt ensure the desired feeding rate (pieces / hour).

[0083] The pipes (15) between the airlocks (10) and (11) are hermetically sealed, so that there is no entry of atmospheric air and no escape of dangerous toxic fumes. The layout of the two airlocks (10) (11) is connected in a closed loop in which vacuum conditions prevail, created by the installed vacuum system.

[0084] The vacuum system consists of two lobe pumps (15) connected in parallel (see Container 2 (4), Figure 10), which are suitable for vacuum application with high efficiency but also low air consumption. Vacuum conditions within the loop ensure the direction of fumes trapped within the loop (containing chemical or biological agents) to the arc unit (6) (Step 6).

[0085] This closed loop is additionally equipped with multiple electric valves in suitable positions, thus allowing the continuous suction and transfer of the fumes, even in a failure of one lobe pump (15). All of the above are necessary in order to avoid leakage of toxic fumes to the atmosphere and the surrounding workplace.

[0086] Above the conveyor belt (14), prior to entry into the specialized feeding apparatus (1), the Artificial Intelligence (Al) type-detection system is positioned, where via computer vision takes place the detection type of each ammunition and movement monitoring. The integrated automated (Al) detection system by type uses non-destructive detection methods in combination with standards recognition.

[0087] Specifically, the system applies supervised machine learning methods. The system algorithm accepts exemplary inputs and the desired results in order to match the inputs with the results through feedback. This achieves high system performance through visual identification of the ammunition (type, size, etc.), automatic classification (weight, materials of manufacture, processing time) and non-linear statistical modeling of the data. The system's central computer in this way, through pattern recognition and modeling, adapts the time and method of processing ammunition rapidly, even if it is a new type of ammunition, without human intervention.

[0088] Finally, special pressure measuring instruments are placed along the pipes of the closed loop, ensuring that their pressure will not exceed 0.8bar throughout the operation of the system. Retention of fumes is a necessary stage of the process in order to protect the workers in the area, but also to avoid air pollution.

[0089] Step 2: Entry into a bipolar rotational vortex chamber (2) for ammunition destruction

[0090] Under the influence of gravity, ammunition exits the second airlock (11) and enters the bipolar rotational vortex chamber (2) of Container 1 (100) in a controlled way. The operation of the chamber is continuous, while its feeding is achieved at a specified rate of "piece of ammunition per unit of time", which is ensured by the appropriate adjustment of the operating speed of the hydraulic motors connected to the airlocks. The chamber has suitable measuring and control instruments for the precise adjustment of all critical and non-critical parameters of the process.

[0091] Both ammunition transport pipes and the bipolar rotational vortex chamber (2) are hermetically sealed to prevent the release of toxic gases and liquids into the surrounding area.

[0092] The bipolar rotational vortex chamber (2) as presented in Figure 8, is equipped with two mirror poles (16) which respectively, each one contain one exciting sliding machine (17) with which the resonance of the alternating frequency of the magnetic field is achieved and each one contain one cylindrical cross-section container (18) in which is contained a cylindrical cross-section drum (28) (see Figure 6,8) containing the main inductor (19) and the axial rotor (20) carrying the polyaxial eccentric reciprocating loads (141). The main inductor (19) is fed by the corresponding adjustable exciter sliding machine (17) and creates a magnetic field which by induction creates currents in the rotor (20), which together with the field that created them cause forces and consequently electromagnetic torque , under the influence of which the axis of the rotor (20) rotates, giving motion to the multi axial eccentric reciprocating loads (141) (see Figure 6) which, in an environment of same direction pulsed rotary vortex under a controlled electromagnetic field, ensure the instantaneous destruction of the ammunition.

[0093] Specifically, inside the chamber (2), takes place the following:

[0094] • the immediate fragmentation of incoming ammunition

[0095] • the separation of the chemical agent (if chemical weapons are involved), in liquid form or in gel form in the case of mustard

[0096] • the separation of the biological agent (if they enter)

[0097] • the separation of the contained energetic material from the casing of the ammunition (such as shell, projectile, firing tube)

[0098] The chamber operation is the most important stage of the whole process, because it divides the incoming ammunition into four main material streams, depending on the type of ammunition, which then follow separate treatment processes. The incoming ammunition mass is simultaneously put into forced rotation with planetary motion due to the coordinated effect of the magnetic field on materials of different granulometry (surface-volume) and the creation of a pulsed rotational vortex that entails their selective and rapid destruction.

[0099] The existence of a two-pole chamber leads to a significant increase in the width of the pulse-field path alongside the chamber, which minimizes the demilitarization time and allows the processing of a wide range of ammunition diameters. In addition, the existence of an external circular ring (21) around the mirror poles (16) (see Figure 6), ensures on the one hand the sealing of the process through the retention and removal of toxic fumes and on the other hand it helps to maintain the smooth process, since the selected diameter of the circumference of the outer circular ring (21) ensures an increase in the moment of inertia of the system with respect to the axis of rotation with the result that the angular speed of rotation is reduced and therefore the ability to stabilize position in any disturbances of the balance during demilitarization is increased.

[0100] The production of a magnetic field in a limited space changes the energy in that space, resulting in a force being produced. This force is found in the acceleration of a moving electric charge in the field or by the torque on a magnetic dipole or even by the reorientation of the electron spins in specific types of atoms. When the particles under voltage are close to each other then the magnetic field formed by one interacts with the other and vice versa resulting in forces being exerted between them. For same direction currents the force between them is attractive while for counter currents it is repulsive.

[0101] By applying an alternating magnetic field, local inductive electric loads are created, causing the affected particles to move at an angle to the magnetic field, performing helical motion. With appropriate coordination of the frequency of rotation of the magnetic field, a same direction pulsating rotational vortex can be achieved, which results in the synchronized suspension of the particles, under the influence of velocities that gradually lead to the reduction of their surface area (disintegration) and to their instantaneous dispersion in space by size.

[0102] Particles of the same load but different mass are separated because of the different tracks they follow. The smaller diameter particles, due to the smaller surface area they have in space, receive a smaller effect of the magnetic force and as a result, through the rotational movement and under the influence of gravity, they are separated and collected. The larger diameters particles through the recirculation system are put in continuous rotary motion until they get the appropriate diameter to be separated.

[0103] The whole demilitarization process takes place as follows: In the upper part of the bipolar rotational vortex chamber (2), there is an inlet hopper (22) of rectangular cross-section for the smooth feeding of the ammunition. Throughout the demilitarization process, ammunition is sprayed by the special type A emulsion (detailed description of the closed-loop type A emulsion supply-recycling system, see Step 9).

[0104] The cylindrical cross-section container (18) of the bipolar rotational vortex chamber (2) into which the ammunition enters, is made of high hardness and strength armor steel plates 30mm thick. The chamber (2) can dampen a shock wave from an inadvertent explosion of the active material (explosive and propellant). In the event of self-ignition of the active material due to failure or overheating, the effects of any explosion are not even noticeable (due to the small amount of explosive material) and are suppressed within the shielded destruction chamber.

[0105] As presented in Figures 6 and 8, the main part of the bipolar rotational vortex chamber (2) is seated on a cylindrical cross-section container (18), which is installed in a symmetrical position with respect to the mirror poles (16). It has high-strength joints (23) along its length and width, suitable for resistance to mechanical stress and high temperatures. In its front part there are maintenance ports (24) consisting of stiffening ribs (25), while on the side walls of the inlet hopper (22) there are pipes of circular cross-section (27) that serve the feedback with the type A emulsion.

[0106] Inside the cylindrical cross-section container (18), the fixed part of the system, the main inductor (19) is installed which is seated on a cylindrical cross-section drum (28) made of sheets of steel laminations having notches (29) on its inner circumference, in which it is mounted metal rods (142) of anti-friction steel. The mobile part of the system, the axial runner (20) is made of smooth solid forged cylindrical steel, is connected to drive systems (86) and has around its perimeter the multiaxial eccentric reciprocating loads (141) which are made of anti-friction steel plates with excellent structural properties and high resistance to deformation resulting in effective impact resistance.

[0107] By applying a three-phase current from the adjustable sliding exciter machines (17) mounted on the two mirror poles (16) a rotating magnetic field is created in the center of the main inductor (19), which drives the axial rotor (20) which rotates so as to align its magnetic field with the field of the main inductor (19). This magnetic field is converted into motion in the multiaxial eccentric reciprocating loads (141), which in an environment of same direction pulsed rotational vortex under a controlled electromagnetic field, ensure the instantaneous destruction of the ammunition, by trapping and fragmenting them in the narrow area (143) widthwise created between the multiaxial eccentric reciprocating loads (141) and the metal rods (142) of anti -friction steel. On either side of the cylindrical cross-section container (18) are based via suitable connectors (34) and sealing material (26) the mirror poles (16), each of which has a track-like shape and which end in conical sections of adjusted length (30), while in the their circumference have cylindrical pipes of increased rectangular cross-section of suitable dimensions (31) in which the active carbon filters (52) are placed for the purification of toxic fumes. The variation of dimensions and the alternation of the shape of the two poles regulate the type of forced movement of the ammunition particulates and the maximum increase of their velocity inside the bipolar rotational vortex chamber (2).

[0108] Circular rings (21) are placed around the perimeter of each mirror pole (16) where the vacuum system under pressure takes place in their clearance space, the regulation of which is carried out through appropriate regulators (33).

[0109] In the upper part of the poles there are suitable outlets (35) for connection with pipes of corresponding diameter (36). Pipes connected to the outlets curved at an angle of 90° are connected to the inlet hopper (22) creating a recirculation loop that ensures the continuous rotational movement of the larger diameter particulates until they have the appropriate diameter and being separated.

[0110] In addition, the bipolar rotational vortex chamber (2) has suitable holes (37) which allow the exit of the metal elements of the ammunition only when they are of the desired granulometry size.

[0111] For further increase of safety degree, the whole process takes place in the presence of an aqueous alkaline emulsion type A, which ensures the immediate inactivation of the accumulated active material, while prevents its ignition due to the prevailing conditions of friction of heterogeneous materials. Thus, throughout the operation of the chamber (2), it is internally sprayed with an excess of a Type A emulsion, aiming at the prevalence of safe operating conditions, without ignitions and explosions.

[0112] Type A emulsion plays two (2) important roles within the destruction chamber:

[0113] • The instantaneous inactivation of energetic material • The immediate chemical neutralization of the chemical agent, aiming to its decomposition - destruction

[0114] This emulsion is soaked in the mass of energetic material, which has been released inside the chamber from the dismemberment of the ammunition, while at the same time it sprays under pressure the open casings of the ammunition to facilitate the release of the energetic material which, due to age, is stuck to the walls of the casing. The contact of the energetic material with the emulsion (as an aqueous element) ensures its instantaneous inactivation, which means preventing a voluntary ignition, while at the same time micro particles (dust) are bound.

[0115] At the same time, the alkaline emulsion solution entrains the chemical agent during its rapid flow inside the bipolar rotational vortex chamber (2). The mixing of these two liquid elements (emulsion, agent) in combination with the prevailing suitable conditions of temperatures and pH, allow the immediate chemical neutralization of the chemical agent at a rate of over 85% of the initial amount. The alkaline nature of the Type A emulsion (pH 11-12) combined with the temperature at which it is fed into the chamber, which varies between 40-50°C, allows the immediate decomposition of the chemical agents within a few minutes.

[0116] The decomposition of the chemical agent is achieved by the method of alkaline hydrolysis, i.e. its reaction with water to form products of reduced toxicity. Because this reaction leads to the formation of acids, the hydrolysis takes place in the presence of a strong base such as sodium hydroxide (NaOH), which neutralizes the acidic products of the reaction. Additionally, the presence of the base adjusts the pH solution to the 11- 12 range (with a limit of 10) and catalyzes the hydrolysis reaction, achieving higher reaction rates. Additionally, alkaline hydrolysis takes place in the presence of sodium lauryl sulfate (CH3(CH2)l lSO4Na). It concerns a surfactant, the properties of which allow the dissolution of sufficient amounts of water-soluble and fat-soluble chemical agents in the aqueous phase, acting in this way as a means of accelerating the hydrolysis reaction.

[0117] The used Type A emulsion contains:

[0118] - 1 % by weight sodium hydroxide, - 1 % by weight sodium lauryl sulfate and

[0119] - 98% by weight water.

[0120] It is an alkaline aqueous solution with a pH betweenl 1-12

[0121] Based on research results, it appears that these hydrolysis reactions take place rapidly within the chamber (2). Based on this data, the chamber (2) must be fed with an appropriate rate of ammunition per time (min), so that the complete disintegration of the introduced amount of chemical agent is possible in this time, before the introduction of new ammunition. In this way, the highest degree of decomposition of the chemical agent is achieved, ensuring a degree of decomposition of at least 85%.

[0122] Finally, chemical neutralization leads to the formation of hydrolysis derivatives, most of which are readily soluble in water. For this reason, they are entrained by the liquid emulsion as they exit the metal pieces separator (3). This liquid stream is a mixture of emulsion, hydrolysis derivatives, energetic material, metal shavings and also a chemical agent that has not been broken down. It is expected that this mixture will contain 10-15% wt. of the initial amount of chemical agent. Then, this mixture is led to the closed loop of emulsion recycling and re-feeding.

[0123] Step 3: Entry into a metal parts separator (3)

[0124] A heterogeneous mixture of solid and liquid elements emerges from the bottom of the bipolar rotational vortex chamber (2). The mixture includes the metal parts together with a large amount of emulsion, energetic material and dangerous agent (if chemical and biological weapons are included).

[0125] This mixed stream is led to the metal parts separator (3) for the mechanical separation of the metal pieces from the liquid fraction of the mixture. The metal parts separator (3) is manufactured for heavy industrial use.

[0126] As shown in Figure 9, the separator (3) consists of the array of two chain conveyors (38), (39) of special design and a drainage tank (40). The first chain conveyor (38) is horizontal and is located above the drainage tank (40), while the second one (39) is inclined and is located at the outlet of the first chain conveyor in such a way that it exits the drainage tank (40). The second one aims to the exit of the metal pieces from the separator (3) in order to advance them to the next stage of the process.

[0127] In the present method and system applied, each chain conveyor (38), (39) is of metal durable construction and variable speed and consists of at least one chain (41), the sliding supports of the chain (42), and at least one cylindrical shaft (43) bearing perpendicularly thereon and concentrically suitable toothed discs (44). Each shaft (43) is located at both ends of the chain conveyor and they transfer motion to the chain (41). The toothed discs (44) of each axle (43) are numerically equal to the number of chains (41) while they have suitable diameter. The shaft (43) is axially connected to an electric motor (45) and transmits adjustable motion to the chain (41) of the chain conveyor (38), (39). Other modes of transmission are possible, such as a belt and pulley or chain and gear layout.

[0128] During the fall of the mixed stream on the horizontal moving chain conveyor (38), the metal parts are held on the perforated surface, while they are sprayed simultaneously with the Type A emulsion. On the contrary, the emulsion containing the hydrolysis derivatives, the active substances and the hazardous agent escapes from the clearance spaces, forming a semi-solid waste. With the movement of the chain conveyors (38) (39), the separated metals are pushed towards the outlet.

[0129] The additional spraying of the metal parts by the alkaline emulsion reduces the degree of their contamination by foreign elements (such as active material, chemical agent), making them safe for the next stage where they are subjected to heat treatment in the metal mass processing unit (4)

[0130] The emulsion is dispersed under high pressure for the following reasons:

[0131] 1. For releasing remaining traces of energetic material, stuck to the surface of metals due to age.

[0132] 2. For detaching gel -type Mustard quantities from the surface of metals due to age.

[0133] 3. In addition, for washing the metals with clear emulsion in order to remove the chemical and / or biological agent. Finally, the outgoing metal parts exit and are transported to the metal mass processing unit (4).

[0134] Step 4: Entry into a metal mass processing unit (4)

[0135] The purpose of the unit is the complete elimination of explosive residues, as well as traces of toxic chemical compounds and biological agents that may be attached to the surfaces of the metal pieces, as they result from the breakdown of the ammunition inside the bipolar rotational vortex chamber (2).

[0136] The metal pieces exit the metal parts separator (3) and go directly to the metal mass processing unit (4) (Figure 10).

[0137] The process to which the metal parts are subjected is extremely necessary, so that they become clean and disinfected before they leave the metal mass processing unit (4) for their safe collection and recycling.

[0138] All stages inside the unit are performed automatically through electronic programming. In detail, the stages are as follows:

[0139] • Stage of feeding

[0140] • Stage of thermal exposure of metallic elements

[0141] • Stage of rapid cooling of metal elements via an air stream

[0142] • Stage of hot air extraction and recirculation

[0143] • Stage of unloading

[0144] All stages of the process take place in air-tight chambers of horizontal layout (46) with automated controls for loading and unloading of metal elements, monitoring of process temperature and other parameters (chamber pressure, exhaust gas temperature, exposure time). In appropriate points, gas discharge nozzles (54) are provided, which are connected in a closed loop for the discharge and recirculation of hot gas masses.

[0145] Initially as presented in Figure 11, the metal parts are received from the outlet of the Metal Parts Separator (3) and transported via the inclined chain conveyor (39) to the metal mass processing unit (4). From there they are automatically unloaded onto a chain conveyor (47), which enters whole into the electric glow chamber (48). The design of the entry port of the metals in the glow chamber allows keeping the user away from the heated surface that follows.

[0146] Here the electrical ignition of the incoming metals at temperatures of 600°C takes place. For this reason, the chamber is thermally insulated. The surface of the horizontal chain conveyor (47) is heated by means of multiple inductive heating elements (49) placed symmetrically along it, as well as on the upper side of the chamber, allowing a uniformity of temperature to be maintained.

[0147] The maximum temperatures reached are at 600°C and are suitable for the complete destruction of explosive elements as well as chemical and biological agents on metal surfaces while retaining the metals in their natural state. The operating parameters of the chamber have been calculated during its design and relate to specific exposure times, atmospheric pressure and room temperature conditions. The movement speed of the chain conveyor is determined by the Control and operation unit (9).

[0148] Externally the chamber is made of durable steel and various alloys thereof, forming a double wall to ensure a low external temperature and its durability in extreme environments subject to pressure and temperature. Proper parameter setting should provide a smooth stream of uniform hot air, which will not drop below 600 °C during the total residence time of the material in the chamber. In normal operation, the exposure time of the materials to a temperature of 600 °C must be at least 15 minutes.

[0149] Temperature sensors (50) are located along the chain conveyors and determine their speed of movement so that the temperature profile is controlled. Through the use of a serial interface, thermocouple data is recorded at predetermined time intervals for evaluation. Over temperature protection devices determine the accuracy and efficiency of the process.

[0150] Then the hot charge (metals) exits the glow chamber (48) and is transferred to a second chain conveyor of a special type (51), which is non-heated and is at ambient temperature conditions. Its purpose is to receive and simultaneously cool them before they leave the unit. The materials are cooled externally by transporting atmospheric air in a natural flow over the chain conveyor. Metals coming out of the unit are temperature checked before being sent for collection.

[0151] The glow chamber (48) is equipped with a closed loop for suction and recirculation of produced off gases. As the heat treatment off gases pass through the recirculation loop, they go through an activated carbon filter (52) before returning to the chamber.

[0152] The loop includes an off gases suction turbine (53) and an activated carbon filter (52). The turbine (53) ensures the sufficient flow of hot off gases in the loop, while the active carbon filter absorbs and neutralizes all harmful gaseous pollutants (such as chlorine, suspended particles, organic compounds).

[0153] Step 5: Entry into a semi-solid waste configured annular drainage and separation apparatus (5)

[0154] The separated semi-solid waste resulting from Step 3 concerns the heterogeneous mixture of liquid and solid impurities which exits the Separator of metal parts (3) and includes the Type A emulsion, the hydrolysis derivatives, the hazardous agent and the solid impurities (active materials, metal shavings).

[0155] Through the pump array (55) of Container 2 (4) (see Figure 10), the semisolid waste (contaminated emulsion) is pumped from the drainage tank (40) (see Figure 9) and directed to the configured annular drainage and separation apparatus (5) which is placed within a robust cylindrical crosssection construction in Container 3 (101). In this way, an ever-increasing high-speed centrifugal force is imposed on the incoming semi-solid waste under conditions of specific rotational speed, centrifugation time and rotor radius.

[0156] Regarding the solid impurities in the waste, these conditions allow the easy separation of the heavier phase (the solid impurities) and their settlement by weight to the bottom of the rotating container. These elements that go to the bottom constitute the sediment.

[0157] Regarding the liquid impurities, in a balanced state of operation of the Unit, the semi-solid waste is in a supersaturated state, because it contains the hydrolysis derivatives and the chemical agent in larger quantities than those that make the solution saturated. In this supersaturated state, liquid impurities are easily separated by centrifugation where they are removed by overflow. This current is called supernatant.

[0158] The supernatant is removed by overflow, producing a now 'clear' emulsion, which may however contain a small amount of undissolved chemical agent. In this way, sediment and supernatant are completely separated. The 'clean' emulsion (from the overflow) is transferred through the pumping system (88) and the leachate tank (89) (see Figure 15) to the emulsion tank type A (56) (see Container 2 (4)).

[0159] At the bottom of the configured annular drainage and separation apparatus (5) the sediment has settled, which is a thick mass with high viscosity (sludge layer), which contains a dangerous and explosive load. This is led directly to the arc unit (6) see Step 6, for its complete destruction.

[0160] The process that takes place is as follows: As presented in Figure 14, the separated semi-solid waste flows by gravity into the square cross-section inlet chamber (57), the bottom of which is cylindrical in shape. The chamber internally and perpendicularly to its cross-section has a helical water transport surface (58) for continuous transportation of the suspension to the configured annular drainage and separation apparatus (5). The shape of the bottom of the inlet chamber (57) ensures the tangential contact of the helical water transport surface (58) with the bottom walls for maximum transport efficiency and for achieving continuous mechanical balance during operation.

[0161] The suspension is then led inside the apparatus (5). The configured annular drainage and separation apparatus (5) consists of two parts, from the upper semi-cylindrical part (59) which terminates in the lower conical part of rectangular cross-section (60). Internally in the upper part there is a fixed cylindrical pipe (61) made of perforated sheet metal with peripheral holes (62). The pipe has a structured wall for optimal flow speed.

[0162] Inside the cylindrical pipe (61) rotates a horizontal stirrer (63), coaxial with the helical water transport surface (58) of the inlet chamber (57). The stirrer (63) covers the entire surface of the cylindrical pipe (61) and has fixed rectangular-shaped fins (64) around its perimeter which, as they rotate, achieve a homogeneous dispersion of the explosive material on its metal walls. The length of the cylindrical pipe (61) and the stirrer (63), as well as the configuration of the annular space between them, are determined in such a way as to achieve the maximum possible collection surface, the drainage and the separation of the suspension in the conical lower part of the device (60). The configured annular drainage apparatus (5) is essentially a concentric duct filtration system, the efficiency of which is proportional to the rotation rate of the stirrer (63).

[0163] Specifically, through continuous stirring, gravity separates the suspension from the explosive and solid particulates, which are then propelled by the stirrer in the front part of the device, towards a horizontal finned aerator (65).

[0164] The horizontal finned aerator (65) is an extension of the stirrer (63) and is a pipe of rectangular cross-section bearing square-shaped fins (66) with a cylindrical outlet for the isomeric, continuous and gradual advancement of the mass of drained material towards the electric arc unit (6).

[0165] Step 6: Entry into an electric arc unit (6)

[0166] Unit (6) is fed with two (2) waste streams: a) the sediment from the configured annular drainage and separation apparatus (5) and b) the off gases and fumes transported through the lobe pumps (15) of Container 2 (4) which concerns the toxic gases and dusts which are suction flows from the ammunition feeding stage, from inside the bipolar rotational vortex chamber (3) and also from the metal mass processing unit (4). The electric arc unit (6) concerns a gasification installation with plasma arc gasification technology. A gas becomes plasma when the addition of heat or other energy causes a significant number of atoms to release some or all of their electrons. The remaining parts of those atoms are left with a positive charge, and the detached negative electrons are free to move. The mixture of positively charged nuclei and negatively charged electrons is plasma. The movement of free electrons is the one responsible for the electric arc phenomenon.

[0167] Inside the electric plasma arc unit (6) takes place the conversion of the incoming fumes, as well as the semi-solid stream (sludge) into synthesis gas (mixture of carbon monoxide CO and hydrogen H2) and off gases. In other words, Unit (6) includes at least one plasma torch (130), which transmits electric current or gaseous medium, through electrical discharges due to the potential difference of two anode-cathode electrodes. The plasma arc is thus produced and the gas is converted into plasma. Then a spark is created between their ends, which is being stabilized since a suitable potential difference is maintained at the ends of the electrodes. The gas between the electrodes ensures the continuation of the electric current circulation in this space, i.e. it acts as a bridge.

[0168] Each plasma torch (130) as presented in Figure 13 uses a copper alloy nozzle (32) to restrict the stream of ionized gas and focus its energy into a very small area where it is launched at high speed. Each nozzle (32) is polygonal shaped for better pouring of the gas, while for design purpose the use of eight (8) torches (130) with nozzles (32) has been preferred, with the ability to operate only the necessary ones each time for maximum efficiency.

[0169] All gaseous flows in the feeding and outlet of the electric arc unit (6) are controlled by the PLC unit of the control and operation unit (9). Automatic control of gaseous flows is essential to achieve the best possible destruction without sacrificing chamber capacity and vice versa. The on / off procedures of the electric arc are also performed automatically by the PLC.

[0170] The destruction efficiency (DRE) of the torch reaches 99.99%. The system includes an autonomous control unit (PLC), which ensures its automatic operation, keeping all the necessary safety precautions. The controller is connected to all the sensors of the system (thermocouples, pressure switches, thermostats, etc.) ensuring that the system works under normal operating conditions.

[0171] A suitable cooling system including ambient air inlet piping (67) is installed to prevent overheating of the torch and to ensure stable arc operation.

[0172] Step 7: Entry into an off gases treatment unit originating from the electric arc unit

[0173] Subsequently, the produced off-gases and any vitreous inert material residues from the electric arc unit (6) are led to treatment in the next sequential treatment stages.

[0174] Specifically, the hot off-gases are initially channeled into the thermal oxidizer (68) of Container 3 (101), where their primary oxidation takes place. The thermal oxidizer (68) is a conically shaped metallic structure, appropriately configured for the smooth inlet and outlet of the gases.

[0175] The mixture of the produced off-gases and any residual inert vitreous material enters the square-shaped internal layout (69) of the thermal oxidizer (68) (see Drawing 16), where the purification of the solid residues (vitreous inert material) takes place via a suitable horizontal screw conveyor (132).

[0176] Subsequently, the primary oxidation of the purified fraction of the offgases takes place at a temperature exceeding 1000°C. Through parallel cylindrical holes (73) they are channeled into the perimetric (peripheral) oxidation chamber (74), which encloses the square-shaped internal layout (69) of the thermal oxidizer (68). The perimeter oxidation chamber (74) is continuously supplied with atmospheric air via an air intake subsystem including a pumping system (75) to supply an excess amount of oxygen to the oxidation process. Also as shown in Figure 16, between the perimeter oxidation chamber (74) and the square shaped internal layout (69) of the thermal oxidizer (68) there is a temperature maintaining insulating layer (72) so that combustion efficiency is maximized. The feeding off gas enters from the bottom of the chamber (76), while the atmospheric air is blown vertically into the flow of the off gas inlet (77) under high pressure and in large excess. The high velocity of the air inlet has the result that the rate of performance of the intended process is multiplied. Due to these high temperatures >1000°C, simple gaseous compounds (such as volatile organic compounds, VOCs) are ignited, which results to the conversion of CO2 and water (H2O) in the outlet pipe of thermal oxidizer (68). More complex organic compounds are broken down into simpler compounds through complex electron shedding processes.

[0177] To increase the efficiency of the chamber, it is filled with basalt elements (7) which, due to the high concentration of iron, retain the heat for a longer period of time, as a result of which they are ignited by the hot off gases from the outlet of the Thermal Oxidizer (68) and accelerate the oxidation process.

[0178] Basalt is an igneous rock formed by the rapid cooling of basaltic lava. Its silica content is below 50%, with quartz content by weight below 20%. Basalt is usually gray or black in color, almost always has a fine-grained texture because the rapid cooling of the fluid rock does not allow the formation of large mineral crystals.

[0179] Full oxidation of off gases is very difficult to be achieved, and almost always even a minimal amount of hazardous compounds remains unburned. For this reason, off gases are channeled into a cylindrical shaped emission control electrical device (131), where their secondary oxidation-afterburning takes place.

[0180] As shown in Figure 17, the cylindrical shaped emission control electrical device (131) includes an internal assembly (133) which encloses parallel cylindrical porous rods (70) of refractory construction and large surface area, in the form of a truncated cone, which have teeth (71) which are formations of successive recesses and projections on the circumference of each rod (70) for better distribution of developing temperature. The teeth (71) have various profiles, such as that of the advanced one where it is the curve that traces a point of straight rolling without sliding on a circle. The parallel cylindrical porous rods (70) are placed next to each other, creating parallel sequences of rods (139) (see Figure 18), which are supported on the internal assembly (133) via stainless steel cylindrical shafts (135).

[0181] The basic function of the emission control electrical device (131) is to neutralize dangerous chemical reactions by converting harmful substances into less dangerous ones, providing space and conditions for the chemical reactions to take place, resulting in the appearance of carbon dioxide and water vapors. Due to the high temperatures the percentage of harmful substances in the off gases is significantly reduced causing less environmental damage.

[0182] To achieve appropriate temperatures (>900°C), so that off gases are oxidized, special electrical resistances (134) have been placed along the parallel cylindrical porous rods (70), inside the teeth (71), so as to create a complex structure of a small "cell" - like channels that run through them lengthwise, in the direction of gaseous flow.

[0183] At the same time to achieve insulation, perlite grains (138) have been placed inside the emission control electrical device (131). Perlite is an amorphous volcanic glass with relatively high-water content and expands when exposed at quite high temperature.

[0184] Above conditions result in off gases oxidation entering from inlet (136), while at the same time are cooled from 900 °C (inlet temperature) to 150°C (exit temperature). All the above process is controlled by thermocouples and gas pressure gauges.

[0185] From the upper part (137) of the emission control electrical device (131) off gases exit at 150°C and are led to the next stage, where they are led into the catalytic converter (78) of Container 3 (101) (see Figure 19). Inside it, the following are achieved: a) Purification of gaseous pollutants, mainly sulfur dioxide SO2 and hydrogen chloride HC1 b) Removal of particulates with high moisture content c) Clean gas stream outlet At this stage, produced off gases is fed to the catalytic converter (78) at a temperature of 150°C. It concerns a special chamber of cylindrical configuration, in which the purification of off gases is achieved through the use of a liquid phase (aqueous emulsion Type B). Harmful contaminants are removed from the gas stream by diffusion and absorption by emulsion B.

[0186] As presented in Figure 15, the gas stream enters at high pressure from the bottom of the chamber (79) in an upward direction. Instead, the special Type B emulsion is injected from the top (80) of the catalytic converter (78) in the form of small diameter droplets. The emulsion is introduced in such a way as to create a uniform jet spray of the emulsion inside the chamber under countercurrent conditions to entrain the particles to the bottom (base).

[0187] Type B emulsion concerns an aqueous solution of calcium hydroxide Ca(OH)i at a rate of 5% by weight. The supply of the emulsion and the manner of its distribution within the catalytic converter (78) do not allow the release of polluting gases at its outlet, especially of the acidic compounds. The main reason for the sparging process is to remove sulfur oxides (SOx), nitrogen oxides (NOx), HF, HC1, HNO3 gases and particulates from off gases.

[0188] The temperature inside the chamber is relatively low, because it favors the reaction of the polluting gases with the emulsion droplets. This reaction ultimately leads to the adsorption of certain gaseous compounds by the droplets, to the formation of salts, but also to the removal of particulates and heavy metals from the gas stream.

[0189] Through the process inside the catalytic converter (78), two (2) waste streams result:

[0190] 1. A semi-liquid sediment (sludgy waste) at the bottom of the catalytic converter (78), which is led to the condenser array (81)

[0191] 2. A clean gas stream with very high humidity

[0192] Here it should be noted that inside Container 3 (101), to the gas piping there are installed activated carbon filters (52) for the absorption and neutralization of all harmful gaseous pollutants. Before the clean gaseous stream with very high humidity is directed to the gaseous pollutants final treatment unit (see Step 8), it passes through the moisture absorption device (128) (see Figure 19), which is a cylindrical cross-section device used to remove of entrained liquid droplets from the gas stream. The device includes wire meshes (129) of small diameter, stainless steel, of highly elastic that can cover the entire internal surface of the device. In addition, the high quality material of the meshes, make it have excellent corrosion and rust resistance, temperature resistance and long service life.

[0193] When the gas, enriched with liquid droplets, rises at a constant speed and passes through the wire meshes (129), the rising moisture will collide with their surface and adhere due to inertia. The liquid droplets will spread on the surface of the wire meshes (129), grow and separate when the gravity of the droplets exceeds the surface tension of the liquid. Separation of droplets from the gas stream can improve operation, optimize process indicators, reduce equipment corrosion and extend equipment life.

[0194] As mentioned above, the spraying of Type B emulsion creates a semiliquid waste at the bottom of the catalytic converter (78), which is removed via the transfer pump array (82). The semi-liquid consists of approximately 60% Type B emulsion and 40% insoluble solids (calcium salts, dust and rust particles).

[0195] Then, as shown in Figure 15, the semi -liquid waste is conveyed to the condensers array (81), where the separation of the suspended insoluble solid residue (calcium salts) from the liquid part of the emulsion is achieved. The separation capacity reaches 99% due to the greater specific gravity of the salts from the wet part (water). To increase the separation efficiency, the volume of the semi-fluid is divided into two condensers (81) of equal feeding.

[0196] The condenser is a separation device that, based on the principle of inertia, achieves the removal of particulate materials. Condenser type separators use for their operation the centrifuge with a continuous flow of fluids. The inside of the chamber creates a spiral vortex. Lighter components have less inertia, so it is easier for them to be affected by the vortex and be swept away. In contrast, larger particle components have greater inertia and are not as easily affected by vortex.

[0197] Each condenser (81) has an inverted cone shape to promote the collection of these particulates at its bottom. Therefore, the concentrated sediment settles at the bottom of the collection cone (83) from where it is removed with the help of flow control systems (84). The condenser will be made of seamless copper tubes, expanded on aluminum fins.

[0198] The separated liquid fraction (emulsion) is returned to the Type B emulsion tanks (85), via the pumps (99), of the gaseous pollutants treatment unit of Container 4 (8) (see Step 8).

[0199] Step 8: Entry into a gaseous pollutants final treatment unit (8)

[0200] In the Unit, the gaseous pollutants of the off gas treatment unit coming from Container 3 (101) are processed, aiming to their complete destruction in order to reduce the environmental risk. Their control and treatment are necessary to avoid pollution of the ambient air of the area and to maintain a good air quality, in accordance with the current environmental legislation.

[0201] Specifically, the outgoing gas stream from the catalytic converter (78) of Step 7, is transferred to the inlet (95) (see Figure 21) of the gas-gas exchanger (87) in order to be dehumidified and cooled from 100°C to 60°C. The cooling process leads to the condensation of the contained water vapor (H2O). In this way, a large percentage of moisture is separated from the gas stream, which water concentrate is collected in the water concentrate tank (98) (see Figure 20).

[0202] As shown in Figure 21, the gas-gas exchanger (87) consists of a casing (90), a bundle of heat transfer tubes (91), a shell sheet (92) and flow reflectors (93) for high heat exchange efficiency. The housing (90) is mostly cylindrical and a bundle of heat transfer tubes (91) is installed inside it and both ends of the bundle are fixed to the shell sheet (92). The flow of material between the bonds of the shells creates an exchange of heat and cold. The two types of hot and cold fluids for heat exchange, one flowing in the tube is called tube flow fluid and the other flowing outside the tube is called shell side fluid. The flow deflectors (93) increase the fluid process thermal coefficient and the shell side fluid velocity by causing the fluid to pass laterally through the bundle of passages (91) multiple times over a specific path, enhancing fluid turbulence, with resulting in the liquid being extremely turbulent and the heat transfer coefficient being large. The gas-to-gas exchanger (87) is also coated with sealing material (94) to prevent leaks.

[0203] Finally, the gas stream from the outlet (96) of the gas-gas exchanger (87) is directed to an active carbon filter array (52) of Container 4 (8) to remove chemical and organic pollutants, chlorine and solid particles (dust) before its release into the atmosphere.

[0204] In the next phase of the process, the outgoing gas stream of 60 °C from the gas-gas exchanger (87) is fed to the second liquid-gas exchanger (97) to be further cooled to 5°C. These low temperatures also cause the water vapor to condense into water (concentrate), which is collected in the water concentrate tank (98). The water concentrate tank (98) via a pump array (102) continuously supplies the type B emulsion tanks (85) with water concentrate, thus closing this loop.

[0205] The cold gaseous stream of 5°C returns to the first gas-gas exchanger (87), where it is now used as a coolant medium. In contrast, the second liquid-gas exchanger (97) uses cold water as a coolant for its operation. As shown in Figure 23, the cold water supply is ensured by a closed network returning the hot water to the cooler (103), passing through two twin simple series exchangers (140) and re-feeding colder water to the liquid-gas exchanger (97).

[0206] As presented in Figure 22, the liquid-gas exchanger (97) is a plate heat exchanger and it is a cylindrical configuration device equipped with robustly constructed metal sheets (125) and provides a large heat exchange surface for a specific installation volume. The two fluids flow counter currently through small gaps between the plates. Each fluid alternately moves up and down in turbulent flow, achieving high heat transfer coefficients. The plates (124) are tightly connected to each other, supported on a special frame plate (126) and compressed in a manner analogous to filter presses. The plates (124) have wavy grooves through which strong turbulent flow and high heat transfer rates are achieved. The overall heat transfer coefficients are approximately double to the corresponding coefficients of tubular exchangers and range between 5000-10000W / m2K. Also, the liquid-gas exchanger (97) is equipped with a single-suction ventilator (127) of direct movement, in order to optimally transport the gas from the outlet. The fan has been selected to provide optimal operation in terms of flow, noise level and lifetime.

[0207] Plate heat exchangers are particularly suitable for heating perishable products, due to their high heat transfer rate and short residence time. Due to the composition of stainless steel (plate) with copper welds they are particularly resistant to corrosion.

[0208] The entire cooling and dehumidification process is necessary because the clean gas stream, exiting the catalytic converter (78), has a very high humidity and is at a temperature between 90 - 100°C. Under these conditions, this gaseous stream cannot pass through the active carbon filter (52), because auto-ignition conditions are created due to high relative humidity.

[0209] Activated carbon is always used in the final stage of filtering gaseous mixtures. It is installed to clean gaseous mixtures from chemical compounds and microparticles (fine dust particles) before their release into the atmosphere. This proves that the design of the processes was carried out with environmental protection and compliance with anti- pollution legislation. The concentration of activated carbon inside the filter is selected in such a way that the filter offers high protection and resistance over time.

[0210] Throughout the filtration process, the temperature and pressure of the gaseous stream is continuously monitored before entering the active carbon filter (52). It is estimated that the gas at the entry point will have 15% relative humidity.

[0211] Finally, before the exit of the gas into the atmosphere, the suction and filtration system (104) is installed, which is equipped with an exhaust gas monitoring system (105) (see Figure 24), for continuous control of the air quality. By means of a pump (106), the outgoing gaseous stream from the suction and filtration system (104) is released into the atmosphere.

[0212] The suction and filtration system (104) is a cylindrical cross-section device comprising the multilayer filter arrangement (107). The cylindrical cross-section device has a special opening-closing system

[0213] (108) for easy access.

[0214] The gas is transferred into the device through a centrifugal absorber

[0215] (109), single suction with Siroco type impeller dynamically balanced. The gas is then introduced into the multilayer arrangement for its final filtration.

[0216] In particular, a carbon filter layer is used which acts as a pre-filter. In such a setup, the first stage of the filtration process consists of a pre-filter that removes most of the larger dust particles, PM10 from the air. Then the high-quality second-stage HEPA filter is used to remove the fine particles that escape the pre-filter.

[0217] HEPA filters consist of a layer of randomly arranged fibers. The fibers usually consist of fiberglass between 0.5 and 2.0 micrometers in diameter. Key factors that affect its functions are the diameter of the fibers and the thickness of the filter. Unlike sieves or membrane filters, where particles smaller than openings or pores can pass through, HEPA filters are designed to target a range of particle sizes.

[0218] The exhaust gas monitoring system (105) includes state-of-the-art automated instruments with multiple capabilities for measuring and recording concentrations of nitrogen oxides (NO and NO2), sulfur dioxide (SO2), hydrogen sulfide (H2S), carbon monoxide (CO), total hydrocarbons, hydrocarbons except methane (CH4), benzene and PM10 and PM2.5 particulate matter.

[0219] Exhaust gases are also checked via continuous measurement analyzers, which monitor parameters such as temperature, pressure, flow, concentrations of oxygen, nitrogen oxides, sulfur dioxide and particulate matter. It is important to emphasize the fact that all continuous measuring analyzers can be connected to the control and operation unit (9) which provides the possibility of continuous and full control of the process.

[0220] Step 9: Entry into a closed-loop type A emulsion supply- recycling system

[0221] Key factor in the present process is ensuring sufficient amounts of Type A emulsion for the safe operation of the bipolar rotational vortex chamber (2). This is achieved by connecting an emulsion recycling and re-feeding closed-loop. The closed-loop, as shown in Figure 25, consists of three different emulsion recirculation networks, which are:

[0222] Network 1 :

[0223] The semi- solid waste (contaminated emulsion) from the drainage tank of metal parts separator (3) via the pump array (55) of Container 2(4), is led directly to the configured annular drainage and separation apparatus (5) of Container 3(101) where via centrifugation process of the energetic material, the separation of hydrolysis derivatives and chemical agent from the heterogeneous emulsion mixture is achieved. The remaining emulsion (supernatant) is led through the pumps (88) of Container 3 (101) to the emulsion tank type A (56) of Container 2 (4). At the same time, the remaining sediment is led directly to the electric arc unit (6), see Step 6, for its complete destruction.

[0224] Network 2:

[0225] The semi-solid waste (contaminated emulsion) from the drain tank of metal parts separator (3) through the pump array (110) of Container 1 (100) is directed in parallel to:

[0226] - Inside emulsion type A filling tanks (56) of Container 2(4) and

[0227] - Inside emulsion treatment system via E / M pulse (111) where at the same time the secondary destruction of any present small amounts of chemical and / or biological agent takes place

[0228] Finally, the now pure emulsion returns to be used in the bipolar rotational vortex chamber (2) through the pressure relief valves (114), where after the end of the process it returns to the metal parts separator (3). At this point it should be underlined that emulsion type A filling tanks (56) are directly connected to each other in such a way as to form communicating containers and are directly fed with Type A emulsion concentrate from the tank (112) of Container 2 which includes the metal mass processing unit (4). As a result, the emulsion levels within the tanks are always the same.

[0229] The tank (112) is the heart of the closed-loop because it contains Type A emulsion concentrate and supplies the tanks (56) with it whenever it is necessary.

[0230] The composition of type A emulsion concentrate is: Sodium hydroxide NaOH: 35% Sodium lauryl sulfate (SLS) 043(041)1 lSO4Na: 35% Water H2O: 30%

[0231] Network 3:

[0232] The qualitative reconstruction of the emulsion is achieved inside the type A emulsion filling tanks (56) and then through the pumps (113) of Container 1 (100), the emulsion is transported to the emulsion treatment system via E / M Pulse (111), to be dispersed inside the chamber of the bipolar rotational vortex chamber (2) through the pressure relief valves (114) where after the end of the process it returns to the metal parts separator (3).

[0233] The entire closed network of emulsion tanks and piping is controlled by analog flow metering servos (115) and pressure relief valves (114) that ensure continuous emulsion flow throughout the destruction process. Also, on tanks (56) and (112) are mounted analog level indicator servos (116), analog ph measuring servos (117) and emulsion filling servos (118) for continuous control.

[0234] The correct connection and adjustment of the measuring and control instruments, along with the uninterrupted supply of an appropriate quality and quantity of emulsion, provide conditions for the safe operation of the destruction chamber aiming the complete destroying of incoming ammunition. The emulsion recirculation technique is used to reduce emulsion consumption in the process, contributing to a better environmental footprint of the method applied. We note from the beginning that the environmental footprint is an important factor in enhancing the competitiveness of a method and plays an important role in the effort to establish processes with reduced operating costs through the recycling of raw materials.

[0235] Step 10: Entry to type B emulsion recirculation closed loop

[0236] Type B emulsion (cleaning agent) moves in a closed loop for continuous reuse. As shown in Figure 26, the emulsion from the emulsion Type B filling tanks (85) of Container 4 (8) is led through the pumps (99), to the catalytic converter (78) of Container 3 (101), then exits from its bottom together with the sediment, is removed through the transfer pump array (82) and finally is separated in the condensers (81) until it finally returns back to Container 4 (8) where it is collected in emulsion type B filling tanks (85).

[0237] The closed loop includes the tanks (119) of Container 3 (101), which feed the emulsion Type B filling tanks (85) with emulsion Type B concentrate. The emulsion Type B concentrate is an alkaline solution with a content of 80% by weight Ca(OH)2in water.

[0238] It is important to mention that the emulsion filling tanks (85) are communicating vessels, which are connected to each other via a pipe. Inside them there is always the same emulsion and liquid levels are always at the same level. This requires continuous monitoring of emulsion Type B filling tanks (85) in terms of pH, level and tank filling (117), (116), (118).

[0239] As the process is repeated, the chemical reaction between Ca(OH)2and the acid gases, depletes the stores of Ca2+cations in the emulsion. For this reason, the emulsion Type B filling tanks (85) are continuously filled with emulsion Type B concentrate (from tanks (119)) and with condensed water (from tank (98) of Container 4) so that a emulsion Type B is reformed and the pH is continuously maintained at appropriate levels within the Catalytic Converter (78). Step 11: Entry to emulsion treatment system via E / M Pulse

[0240] Application (111)

[0241] The recycling Type A and B emulsion closed loop is additionally equipped with emulsion treatment systems via E / M Pulse Application (111) which are installed in Container 1 (100).

[0242] Each system (111), as depicted in Figure 27, consists of the following main parts:

[0243] • one (1) hermetically sealed chamber (120) lined with metal armor walls and with a layer of thermal insulation

[0244] • generators for producing E / M pulses (121) of specific frequency and amplitude,

[0245] • special anti-interference channels for the passage of the cables (122) coming from the peripheral devices to avoid effects from external electromagnetic fields,

[0246] • safety valve (114) which allows limiting the maximum pressure in the system to an acceptable level,

[0247] • control thermocouples (123) of temperature conditions.

[0248] The purpose of these systems is to eliminate any chemical and microbial agent residues that may still be present in the emulsion flow.

[0249] At this point it should be noted that a small percentage of chemical and biological agent is expected to be at this stage (inside System (111)). However, since the emulsion is reused in the same process, it is necessary to completely eliminate both the microbial population and the load of toxic chemical agents before returning back to the bipolar rotational vortex chamber (2), thereby minimizing the risks of overloading the networks from continuous accumulation of toxic elements. In addition, by this way, the risk of workers being exposed to a dangerous environment during the maintenance and supervision of the unit is also reduced.

[0250] The applied process is considered preventive and takes place using natural means and not chemicals. The use of chemical agents (such as chlorine, alcohols, phenolic compounds, etc.) is avoided, because they lead to the formation of by-products, which would require additional processes for their removal.

[0251] As a natural means of disinfecting biological organisms and simultaneously destroying dangerous chemical elements, electromagnetic pulses are used, which are produced by the built-in E / M pulse generators (121) with which each System (111) is equipped. Electromagnetic pulses are essentially high-power electromagnetic microwave pulses in the 300 MHz and 300 GHz Band frequencies, capable of neutralizing dangerous loads within the emulsion at the appropriate intensity, without causing damage to the equipment itself and peripheral electronic devices. By this method, the substrate of hazardous cargo within the emulsion will be completely destroyed, without affecting the quality of the emulsion Type A.

[0252] System (111) is positively a high-tech "converter", which converts 50 or 60Hz alternating current into high frequency electromagnetic radiation. These pulses impinge on the dangerous chemical load of the emulsion and interact with it, leading their atoms, molecules or ions to be transferred to a higher energy level. The incident electromagnetic radiation leads to the excitation of all elements through the absorption of energy, resulting in a rapid increase in their temperature.

[0253] Each molecule at normal temperatures is in its ground state, that is, the positions of the atoms (molecules or ions) are fixed and the strength of the bonds between them is very high. By absorbing high-power E / M energy, matter is offered such a large amount of thermal energy that it causes a large number of collisions and energy transfer. As a result, due to the high temperature, the atoms perform chaotic movements in space, they collide with each other and the bonds between the atoms (molecules or ions) are completely broken. The chemical material breaks down into simpler harmless compounds.

[0254] Under the mentioned conditions, secondary reactions also occur in parallel, which affect the microbial organisms contained in the emulsion. In this case, the incident energy is absorbed either directly by the existing microorganisms or by the aqueous emulsion (substrate) and transferred to the microorganisms by conduction. In both cases, the increase in their temperature is achieved. For every microorganism there is an upper growth temperature limit, while exceeding this limit gradually causes their cell death. The rate of micro-organism killing therefore occurs faster and faster as the temperature increases, following an exponential rate.

[0255] The thermo resistance of microorganisms (time required to kill a certain percentage of cells) at a certain temperature is independent of the concentration of cells in the given volume. Given these conditions, the necrosis of the microbial population can be achieved at a constant residence time of the emulsion inside the chamber, without being important to take in mind their concentration. The process kills 99.9% of microorganisms.

[0256] In the case where the material to be processed is fluid, such as the emulsion, the handling of the fluid plays an important role. Here the agitation of the fluid is imposed, so that its geometry changes and the entire volume of the material come into contact with the incident radiation in a reasonable time. The design of the System eliminates the possibility of E / M pulses escaping into the environment for the complete safety of the workers in the area.

Claims

AMENDED CLAIMS received by the International Bureau on 29 January 2026 (29.01.2026)1. Method and system for the demilitarization of conventional ammunition of all types and calibers as well as chemical and biological weapons, which is characterized by the automated detection of each type5 via an Artificial Intelligence (Al) system, their instantaneous destruction and the immediate separation of the chemical-biological agent, the explosive material and the metallic mass within a co-rotating pulsed vortex environment under a controlled electromagnetic field, while the process is completed with the production of stable final products in an10 environment of an aqueous alkaline solution of a specific qualitative and quantitative composition under the influence of high power microwave radiation, performing the following basic steps:- Step 1: Entry into a specialized feeding apparatus (1) with integrated Artificial Intelligence (Al) by which ammunition is led15 to destruction- Step 2: Entry into a bipolar rotational vortex chamber (2) for ammunition destruction- Step 3: Entry into a metal parts separator (3)- Step 4: Entry into a metal mass processing unit (4)20 - Step 5: Entry into a semi-solid waste configured annular drainage and separation apparatus (5)- Step 6: Entry into an electric arc unit (6)- Step 7 : Entry into an off gases treatment unit originating from the electric arc unit25 - Step 8: Entry into a gaseous pollutants treatment unit (8)- Step 9: Entry into a closed-loop type A emulsion supply-recycling system- Step 10: Entry into a type B emulsion recirculation closed-loop system30 - Step 11 : Entry into an emulsion treatment system via E / M Pulse application (111) while the entire operation of the system is controlled by a control and operation unit (9), from where the operator(s) can monitor and control each phase of the process and each subsystem.

352. Machinery system which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons, according to claim 1, which consists at least of:52AMENDED SHEET (ARTICLE 19)i) at least one conveyor belt (14) that ends in the specialized feeding apparatus (1) which consists of two rotating air locks in parallel connection (10), (11), where their motion transmission is achieved through two hydraulic motors (12) and (13), while the device is5 connected to a vacuum system consisting of two lobe pumps (15) connected in parallel, ii) ii) a (1) bipolar rotational vortex chamber (2), which is seated on a cylindrical cross-section container (18) that has suitable holes (37) which allow the exit of the metal elements of the ammunition,10 while inside it is seated within a cylindrical cross-section drum (28) the fixed part of the system the main inductor (19) which has on its inner circumference metal rods (142) of anti -friction steel and the mobile part of the system the axial runner (20) which has around its circumference the multiaxial eccentric reciprocating15 loads (141), while on either side of it are based via suitable connectors (34) and sealing material (26) the two mirror poles (16), which respectively contain an exciting machine (17), each of which has a track-like shape and which end in conical sections of adjusted length (30), while on their circumference have cylindrical20 pipes of increased rectangular cross-section of suitable dimensions (31) and circular rings (21) in the clearance space of which the vacuum system's under pressure takes place, while in their upper part there are suitable outlets (35) for connection with pipes of corresponding diameter (36), (27) which are connected to the inlet25 hopper (22) creating a recirculation loop,Hl) a metal parts separator (3) consisting of an array of two chain conveyors one horizontal and one inclined (38), (39) and a drainage tank (40), each of which consists of at least one chain (41), the chain sliding supports (42), and at least one cylindrical30 shaft (43) bearing vertically thereon and concentrically suitable toothed discs (44) and axially connected to an electric motor (45) transmitting adjustable motion to the chain (41), iv) a metal mass processing unit (4) comprising air-tight chambers of horizontal layout (46) inside which there is the electric glow35 chamber (48) equipped with a closed-loop for suction and recirculation of the produced off gases which includes an off gases suction turbine (53) and an activated carbon filter (52) and contains a chain conveyor (47) having multiple inductive heating elements53AMENDED SHEET (ARTICLE 19)(49) and a second chain conveyor of a special type (51), which is non-heated and in ambient temperature conditions, v) one (1) configured annular drainage and separation apparatus (5) comprising a square cross-section inlet chamber (57), the bottom5 of which is cylindrical in shape and has internally and perpendicularly to its cross-section a helical water transport surface (58) for continuously transportation of the suspension in the apparatus (5) consisting of two parts, from the upper semi- cylindrical part (59) which terminates in the lower conical part of10 rectangular cross-section (60), where inside the upper part there is a fixed cylindrical pipe (61) made of perforated sheet metal with peripheral holes (62), within which a horizontal stirrer (63) rotates, coaxial with the helical water transport surface (58) of the intake chamber (57) which has fixed rectangular-shaped fins (64) around15 the perimeter and from a front part containing a horizontal finned aerator (65) which is an extension of the stirrer (63) and which is a pipe of rectangular cross-section bearing square-shaped fins (66) with a cylindrical outlet,VI) one (1) electric arc unit (6) comprising at least one plasma torch20 (130) which transmits electric current or gaseous medium, through electrical discharges, which uses at least one nozzle (32) of copper alloy, polygonal shaped, while atmospheric air inlet pipes (67) are installed to avoid overheating of the torch, vii) a thermal oxidizer (68) which is a conically shaped metal structure25 which includes a square-shaped internal layout (69) containing a horizontal screw conveyor (132) while outside of it there is temperature maintaining insulating layer (72), which layout (69) has parallel cylindrical holes (73) for transferring off- gases to the perimeter oxidation chamber (74), which is continuously supplied30 with atmospheric air through an air intake subsystem that includes a pumping system (75), includes a pumping system (75), while in order to increase efficiency it is filled with basalt elements (7), viii) a cylindrical shaped emission control electrical device (131) comprising an internal assembly (133) enclosing parallel35 cylindrical porous rods (70) of refractory construction and large surface area, in the form of a truncated cone having teeth (71), which are placed next to each other, creating parallel sequences of rods (139) supported via stainless steel cylindrical shafts (135),54AMENDED SHEET (ARTICLE 19)along which special electrical resistances (134) have been placed, while perlite grains (138) have been placed inside the internal assembly (133) to achieve insulation, ix) a catalytic converter (78) of cylindrical configuration, in which the5 gas stream enters at high pressure from its bottom (79) while the special emulsion Type B is injected from the top (80) in the form of droplets of small diameter, x) a moisture absorption device (128), which is a cylindrical crosssection device comprising wire meshes (129), of small diameter,10 stainless steel, of high elasticity that can cover the entire internal surface of the device, xi) a condensers array (81), where they have an inverted cone shape to promote the collection to the bottom of the collection cone (83) from where it is removed with the help of flow control systems15 (84), xii) a gas-gas exchanger (87) consisting of a casing (90), a bundle of heat transfer ducts (91) a shell sheet (92) and flow reflectors (93) for high heat exchange efficiency and a coating of sealing material (94) to prevent leaks,20 xiii) a liquid-gas exchanger (97) which is a cylindrical configuration device equipped with robustly constructed metal sheets (125) and includes plates (124) supported on a special frame plate (126), while finally it is equipped with a single suction ventilator (127) of direct movement, in order to optimally transport the gas from the25 outlet, xiv) a cooler (103) and two twin series exchangers (140) to supply cold water to the liquid-gas exchanger (97), xv) activated carbon filters (52) installed in all gas pipelines to absorb and neutralize all harmful gaseous pollutants,30 xvi) a suction and filtration system (104) concerning a cylindrical cross-section device with a special opening-closing system (108) and a single- suction centrifugal absorber (109) with an impeller to transport the gas to the multilayer filter arrangement (107) which includes a carbon filter as a pre-filter and a high-quality HEP A35 filter, while it is equipped with an exhaust gas monitoring system (105) which includes state-of-the-art automated instruments with multiple measuring and recording capabilities,55AMENDED SHEET (ARTICLE 19)xvii) type A emulsion, which contains 1% by weight sodium hydroxide, 1% by weight sodium lauryl sulfate and 98% by weight water and is an alkaline aqueous solution with a pH between 11-12, filling (56) and concentrate tanks (112),5 xviii) type B emulsion, which concerns an aqueous solution of calcium hydroxide Ca(OH)2 at a rate of 5% by weight, filling (85) and concentrate tanks (119), xix) a leachate tank (89) and a water concentrate tank (98), xx) at least one emulsion treatment system via E / M pulse application io (111) consisting of one (1) hermetically sealed chamber (120) lined with metal armor walls and with a thermal insulation layer, by generators for producing E / M pulse (121) of specific frequency and width, by special anti -interference channels for the passage of the cables (122), by a safety valve (114) that allows limiting the15 maximum pressure in the system to an acceptable level and by control thermocouples (123) of temperature conditions.

3. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is20 characterized in that above the conveyor belt (14) prior to entry into the specialized feeding apparatus (1), the Artificial Intelligence (Al) typedetection system is positioned, where via computer vision takes place the detection type of each ammunition and the movement monitoring.25 4. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the significant increase in the width of the pulse path along the bipolar rotational vortex chamber (2) as well as the regulation of30 the type and speed of the forced rotation with planetary motion of the ammunition particulates is due to the variation of dimensions and the alteration of the shape of the two mirror poles (16) of the bipolar rotational vortex chamber (2).35 5. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is56AMENDED SHEET (ARTICLE 19)characterized by that the cylindrical cross-section container (18) of the bipolar rotational vortex chamber (2) into which the ammunition enters, is made of high-hardness and strength armor steel plates 30mm thick, while along its length and width it has high-strength joints (23) suitable5 for resistance to mechanical stress and high temperatures.

6. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is10 characterized by that in the narrow area (143) between the multiaxial eccentric reciprocating loads (141) and the metal rods (142) of antifriction steel, widthwise of the cylindrical cross-section drum (28), takes place the ammunition trapping and fragmenting.15 7. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the existence of an external circular ring (21) around the mirror poles (16) of rotational vortex chamber (2), ensures on the one20 hand the sealing of the process through the retention and removal of toxic fumes and on the other hand it helps to maintain the smooth process, since the selected diameter of the circumference of the outer circular ring (21) ensures an increase in the moment of inertia of the system with respect to the axis of rotation with the result that the angular speed of rotation is25 reduced and therefore the ability to stabilize position in any disturbances of the balance during demilitarization is increased.

8. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and30 calibers as well as chemical and biological weapons of claim 1 , which is characterized by that throughout the operation of the rotational vortex chamber (2), it is internally sprayed with an excess of a Type A emulsion, which inactivates the energetic material and simultaneously leads to immediate chemical neutralization of the chemical agent at a rate of over35 85% of the initial amount, by the method of alkaline hydrolysis thus products of reduced toxicity are formed.57AMENDED SHEET (ARTICLE 19)9. Machinery system according to claim 2 and 8, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the Type A emulsion contains:5 A) 1 % by weight sodium hydroxide which neutralizes the acidic products of alkaline hydrolysis and simultaneously adjusts the pH solution to the 11-12 range, catalyzing the hydrolysis reaction and achieving higher reaction rates,B) 1% by weight sodium lauryl sulfate which concerns a surfactant, the10 properties of which allow the dissolution of sufficient amounts of water- soluble and fat-soluble chemical agents in the aqueous phase, acting in this way as a means of accelerating the hydrolysis reaction, andC) 98% by weight water to achieve alkaline hydrolysis.15 10. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the metal parts held on the perforated surface of the horizontal chain conveyor (38) of the metal parts separator (3), are20 sprayed with the Type A emulsion, in order to the reduce the degree of their contamination by foreign elements (such as active material, chemical-biological agent).

11. Machinery system according to claim 2, which applies the25 demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the shape of the bottom of the inlet chamber of the configured annular drainage and separation apparatus (5) ensures the tangential contact of the helical water transport surface (58) with the30 bottom walls which results to-maximum transport efficiency and continuous mechanical balance during operation.

12. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and35 calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the maximum possible collection surface, the drainage and the separation of the suspension in the conical lower part (60) of configured annular drainage and separation apparatus (5) is58AMENDED SHEET (ARTICLE 19)achieved by the length of the cylindrical pipe (61) and the stirrer (63), as well as by the configuration of the annular space between them.

13. Machinery system according to claim 2, which applies the5 demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the necessary number of torches (130) and nozzles (32) of the electric arc unit (6) is adjusted by the control of gaseous flows in the feeding and at the outlet via the PLC unit of the control and10 operation unit (9).

14. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is15 characterized by that the oxidation chamber (74) is filled with basalt elements (7) which due to the high concentration of iron, retain the heat for a longer period of time, as a result of which they are ignited by the hot off gases from and the oxidation process is being accelerated.20 15. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that the teeth (71) of parallel cylindrical rods (70) of the internal assembly (133) of the emission control electrical device (131),25 are formations of successive recesses and projections manufactured with various profiles, such as that of the advanced one for better distribution of developing temperature.

16. Machinery system according to claim 2, which applies the30 demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that for the achievement of off gases purification in the catalytic converter (78), a Type B emulsion is used, that concerns an aqueous solution of calcium hydroxide Ca(OH)2at a rate of 5% by35 weight.

17. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and59AMENDED SHEET (ARTICLE 19)calibers as well as chemical and biological weapons of claim 1 , which is characterized by that emulsion type A filling tanks (56) are directly connected to each other in such a way as to form communicating containers and are directly fed with type A emulsion concentrate from the5 tank (112), the composition of which is sodium hydroxide NaOH: 35%, sodium lauryl sulfate (SLS) CH3(CH2)l lSO4Na: 35% and water H2O: 30%.

18. Machinery system according to claim 2, which applies the10 demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that emulsion type B filling tanks (85) are directly connected to each other in such a way as to form communicating containers and are fed from emulsion type B concentrate tanks (119) with15 an alkaline solution with a content of 80% by weight Ca(OH)2in water, in order to reform emulsion Type B and to maintain the pH continuously at the appropriate levels within the catalytic converter (78).

19. Machinery system according to claim 2, which applies the20 demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that emulsion treatment system via E / M pulse application (111) produces high -power electromagnetic pulses in 300 MHz and 300 GHz Band frequencies, capable of neutralizing dangerous25 loads within the emulsion at the appropriate intensity, without causing damage to the equipment itself and peripheral electronic devices, destroying completely by this way the substrate of hazardous cargo without affecting the quality of the emulsion.30 20. Machinery system according to claim 2, which applies the demilitarization method of conventional ammunition of all types and calibers as well as chemical and biological weapons of claim 1 , which is characterized by that entire closed network of emulsion tanks and piping is controlled by analog flow metering servos (115), pressure relief valves35 (114), analog level indicator servos (116), analog ph measuring servos (117) as well as emulsion filling servos (118) that ensure continuous flow and complete control of the emulsion throughout the destruction process.60AMENDED SHEET (ARTICLE 19)

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