Plant disease control method

Abstract

The present invention provides an excellent plant disease control method. According to the present invention, compounds represented by formula (I) or N-oxides thereof or salts of the compounds or N-oxides can be used for plant disease control. (In the formula, R1 is a C1–6 chain-type hydrocarbon group or the like, R2 is a C1–6 chain-type hydrocarbon group or the like, n and R3 are either a combination of n being 0, 1, or 2 and R3 being a C2–6 chain-type hydrocarbon group or the like or a combination of n being 2 and R3 being NR8R9, R4, R5, R6, and R7 are the same or different and are a C1–6 chain-type hydrocarbon group or the like, R8 is a C1–6 chain-type hydrocarbon group or the like, R9 is a C1–6 chain-type hydrocarbon group or the like, and Z1 is a phenyl group or the like.)

Description

Methods for controlling plant diseases

[0001] This application claims priority and benefits thereof to Japanese Patent Application No. 2024-190368, filed on 30 October 2024, the entire contents of which are incorporated herein by reference. The present invention relates to a method for controlling plant diseases.

[0002] Patent Document 1 describes sulfonyl compounds.

[0003] International Publication No. 02 / 40431

[0004] The objective of this invention is to provide an excellent method for controlling plant diseases.

[0005] The present inventors, in an effort to find an excellent method for controlling plant diseases, have discovered that the compound represented by the following formula (I) has excellent control efficacy against plant diseases. That is, the present invention is as follows.

[0006] [1] Equation (I) [In the formula, R 1 R represents a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group (the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group A), a C1-C6 alkoxy group, a C1-C6 haloalkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, an amino group, a hydroxyl group, a halogen atom, or a hydrogen atom, and R 2 n and R represent a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a 3-8 membered non-aromatic heterocyclic group (the C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group A), a halogen atom, or a hydrogen atom, and n and R 3 The combinations are when n is 0, 1, or 2, and R 3is a C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group C {the C3-C6 alicyclic hydrocarbon group and the 3-6 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group F}; or, n is 2, and R 3 is NR 8 R 9 represents a combination where R 4 , R 5 R 6 and R 7 are the same or different and represent a C1-C6 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a nitro group, a halogen atom, a hydroxy group, or a hydrogen atom which may be substituted with one or more substituents selected from group A, and R 8 represents a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a C1-C6 alkoxy group, or a C1-C6 haloalkoxy group which may be substituted with one or more substituents selected from group A, and R 9 represents a C1-C6 chain hydrocarbon group or a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group A, and Z 1 represents a phenyl group, a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazol-3-yl group) {the phenyl group and the 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazol-3-yl group) may be substituted with one or more substituents selected from group D}, a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group B, a 3-8 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E, or OR 10 and R 10This represents a C3-C8 alicyclic hydrocarbon group or a 3-8 member non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}. Group A: A group consisting of a C1-C6 alkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group {the C1-C6 alkoxy group, the C1-C6 alkylamino group and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, a C3-C6 alicyclic hydrocarbon group, a 3-6 member non-aromatic heterocyclic group {the C3-C6 alicyclic hydrocarbon group and the 3-6 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group F}, a halogen atom, a cyano group, a nitro group, and a hydroxyl group. Group B: A group consisting of oxo groups, thioxo groups, C1-C6 hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups, {the C1-C6 hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, and C2-C8 dialkylamino groups may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, halogen atoms, cyano groups, nitro groups, hydroxyl groups, and sulfanyl groups. Group C: A group consisting of C1-C6 alkoxy groups, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, fluorine atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more halogen atoms. Group D: A group consisting of C1-C6 chain hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups {the C1-C6 chain hydrocarbon groups, the C1-C6 alkoxy groups, the C1-C6 alkylamino groups, and the C2-C8 dialkylamino groups may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups {the C3-C6 alicyclic hydrocarbon groups and the 3-6 membered non-aromatic heterocyclic groups may be substituted with one or more substituents selected from Group F}, halogen atoms, cyano groups, and nitro groups.Group E: A group consisting of oxo groups, thioxo groups, C1-C6 chain hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups (the C1-C6 alkoxy groups, C1-C6 alkylamino groups, and C2-C8 dialkylamino groups may be substituted with one or more halogen atoms), C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, halogen atoms, cyano groups, nitro groups, hydroxyl groups, and sulfanyl groups. Group F: A group consisting of oxo groups, halogen atoms, C1-C4 alkyl groups, C1-C4 alkoxy groups, C1-C4 haloalkyl groups, C1-C4 haloalkoxy groups, and cyano groups. A method for controlling plant diseases, comprising treating plants or soil on which plants are cultivated with a compound represented by ] (hereinafter referred to as Compound N), its N oxide, or a salt thereof (hereinafter referred to as Compound N, its N oxide, or a salt thereof). [2] Formula (II). [In the formula, na represents 0, 1, or 2, and R 1a Group A a A C1-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group E. a {may be substituted with one or more substituents selected from}, representing a C1-C6 alkoxy group, a C1-C6 haloalkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, an amino group, a hydroxyl group, a halogen atom, or a hydrogen atom, R 2a Group A a A C1-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group E. a R represents a halogen atom or a hydrogen atom, which may be substituted with one or more more selected substituents. 3a is group C aA C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group which may be substituted with one, two, three, four, or five more selected substituents {the C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a This represents {may be substituted with one or more more selected substituents}, R 4a Group A a R represents a C1-C4 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a halogen atom, or a hydroxyl group, which may be substituted with one or more more selected substituents. 5a Group A a Z represents a C1-C4 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a halogen atom, a hydroxyl group, or a hydrogen atom, which may be substituted with one or more more selected substituents. 1a This includes a phenyl group and a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D a Group B a C5-C6 alicyclic hydrocarbon groups, group B, which may be substituted with one or more more selected substituents. a A C3-C4 cycloalkyl group, or OR, which may be substituted with one or more more selected substituents. 10a Represents R 10a This refers to a C3-C8 alicyclic hydrocarbon group or a 3-8 membered non-aromatic heterocyclic group {The C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group belong to group E a This represents {may be substituted with one or more more selected substituents}. Group A a: C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group {The C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a Group B: A group consisting of halogen atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more more selected substituents. a : Oxo group, thioxo group, C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group, {The C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a A group consisting of halogen atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more more selected substituents. Group C a : A group consisting of C1-C6 alkoxy groups, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, fluorine atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more halogen atoms. Group D a : C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group {The C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a A group consisting of halogen atoms, cyano groups, and nitro groups, which may be substituted with one or more more selected substituents. Group E a[2] A group consisting of an oxo group, a halogen atom, a C1-C4 alkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkyl group, a C1-C4 haloalkoxy group, and a cyano group. A compound represented by [2] (hereinafter referred to as "Inventive Compound N") or its N oxide or a salt thereof (hereinafter referred to as "Inventive Compound N", its N oxide or a salt thereof). [3] A composition containing the compound described in [2] or its N oxide or a salt thereof and an inert carrier. [4] A composition containing one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound described in [2] or its N oxide or a salt thereof: Group (a): A group consisting of insecticidal components, acaricidal components, and nematicidal components; Group (b): Bactericidal components; Group (c): Plant growth regulating components; Group (d): Repellent components. [5] A method for controlling plant diseases, comprising treating a plant or soil on which a plant is cultivated with an effective amount of the compound described in [2], its N oxide, or a salt thereof, or an effective amount of the composition described in [4]. [6] Use of the compound described in [2], its N oxide, or a salt thereof, or the composition described in [4], for controlling plant diseases. [7] Seeds or vegetative reproductive organs containing an effective amount of the compound described in [2], its N oxide, or a salt thereof, or an effective amount of the composition described in [4].

[0007] This invention makes it possible to control plant diseases.

[0008] The substituents in this invention will now be described. A halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom. When a substituent is substituted with two or more halogen atoms or substituents, those halogen atoms or substituents may be the same or different. In this specification, "may be substituted with one or more substituents selected from group X" (where X is A, B, C, D, D N E, F, A a , B a , C a , D a , D Na , E a and E NaThe notation (meaning any one of the above) means that if there are two or more substituents selected from group X, those substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 to 6. A chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, butyl, sec-butyl, tert-butyl, pentyl, and hexyl groups. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl groups. Examples of alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl groups. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy groups. Examples of haloalkoxy groups include trifluoromethyl, difluoromethyl, monofluoromethyl, trichloromethyl, CH2CHF2, CH2CF3, CH2CH2CF3, CH2CH2CH2CF3, CH2CH2CH2CH2CF3, and CH2CH2CH2CH2CH2CF3. Examples of C1-C6 alkylamino groups include methylamino group, ethylamino group, propylamino group, isopropylamino group, butylamino group, sec-butylamino group, tert-butylamino group, pentylamino group, and hexylamino group.Examples of C2-C8 dialkylamino groups include dimethylamino group, diethylamino group, dipropylamino group, diisopropylamino group, dibutylamino group, ethylmethylamino group, methylpropylamino group, isopropylmethylamino group, butylmethylamino group, ethylpropylamino group, ethylisopropylamino group, butylethylamino group, isopropylpropylamino group, butylpropylamino group, and butylisopropylamino group. Examples of alicyclic hydrocarbon groups include cycloalkyl groups and cycloalkenyl groups. Examples of cycloalkyl groups include cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, and cyclooctyl group. Examples of cycloalkenyl groups include cyclopentenyl group, cyclohexenyl group, cycloheptenyl group, and cyclooctenyl group. Examples of non-aromatic heterocyclic groups include azilidinyl group, oxyranyl group, thyranyl group, azetidinyl group, oxetanyl group, thietanyl group, pyrrolidinyl group, tetrahydrofuranyl group, tetrahydrothienyl group, pyrazolinyl group, pyrazolidinyl group, imidazolinyl group, imidazolidinyl group, oxazolinyl group, thiazolinyl group, oxazolidinyl group, thiazolidinyl group, isoxazolidinyl group, isoxazolidinyl group, isothiazolidinyl group, isothiazolidinyl group, dioxolanyl group, dioxanyl group, piperidyl group, piperazinyl group, morpholinyl group, thiomorpholinyl group, pyranyl group, dihydropyranyl group, tetrahydropyranyl group, tetrahydrothiopyranyl group, azepanyl group, oxepanyl group, thiepanyl group, and azokanyl group. Examples of aromatic heterocyclic groups include five-membered aromatic heterocyclic groups such as pyrrolyl, furanyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, and thiadiazolyl groups; and six-membered aromatic heterocyclic groups such as pyridyl, pyridadinyl, pyrimidinyl, pyrazinyl, triazinyl, and tetradinyl groups.

[0009] The N oxide of a compound represented by formula (I) or formula (II) refers to a structure in which at least one nitrogen atom in the compound represented by formula (I) or formula (II) is substituted with an oxo group.

[0010] The compound in question or the compound of the present invention may have one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, atropisomers, and geometric isomers. The present invention includes each stereoisomer and mixtures of stereoisomers in any ratio.

[0011] Compounds represented by formula (I) or formula (II), or their N oxides, may form acid addition salts such as hydrochloride, sulfate, nitrate, phosphate, acetate, and benzoate when mixed with acids such as hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, acetic acid, and benzoic acid.

[0012] Examples of the compound N include the following compounds.

[0013] [Aspect 1] In compound N, Z 1 However, a phenyl group, a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) may be substituted with one or more substituents selected from group D}, a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group B, or OR 10 And R 10 However, it is a compound that has a C3-C8 alicyclic hydrocarbon group. [Aspect 2] In compound N, Z 1 A compound having a phenyl group or a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) may be substituted with one or more substituents selected from group D}. [Aspect 3] In the compound N, Z 1 However, a compound which is a phenyl group that may be substituted with one or more substituents selected from group D. [Aspect 4] In the compound N, Z 1However, the compound is a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) which may be substituted with one or more substituents selected from group D. [Aspect 5] In the compound N, Z 1 However, a compound which is a C3-C8 alicyclic hydrocarbon group that may be substituted with one or more substituents selected from group B. [Aspect 6] In this compound N, Z 1 However, OR 10 And R 10 However, it is a compound that has a C3-C8 alicyclic hydrocarbon group. [Aspect 7] In this compound N, Z 1 However, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more halogen atoms}, a C3-C6 alicyclic hydrocarbon group, or OR 10 And R 10 However, it is a compound that has a C3-C6 alicyclic hydrocarbon group. [Aspect 8] In this compound N, Z 1 However, a phenyl group, a six-membered aromatic heterocyclic group {the phenyl group and the six-membered aromatic heterocyclic group may be substituted with one or more halogen atoms}, a C3-C6 alicyclic hydrocarbon group, or OR 10 And R 10 However, it is a compound that has a C3-C6 alicyclic hydrocarbon group. [Aspect 9] In this compound N, Z 1 However, the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D N Group D N A C3-C6 alicyclic hydrocarbon group, or OR, which may be substituted with one or more more selected substituents. 10 And R 10 However, group D N A compound that is a C3-C8 alicyclic hydrocarbon group, which may be substituted with one or more more selected substituents. Group D N : A group consisting of halogen atoms, methyl groups, methoxy groups, CF3 groups, CF2H groups, and cyclopropyl groups. [Aspect 10] In compound N, Z 1 However, group D NA compound which is a phenyl group optionally substituted with one or more substituents selected from the group consisting of 1 is a compound in which Z N is a 5- to 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D (excluding the 1,2,4-oxadiazol-3-yl group). [Aspect 12] In this compound N, Z 1 is a compound in which Z N is a C3-C6 alicyclic hydrocarbon group optionally substituted with one or more substituents selected from Group D. [Aspect 13] In Aspect 1, R 1 , and R 2 are hydrogen atoms, and R 4 , R 5 , R 6 , and R 7 are the same or different and are a halogen atom or a hydrogen atom. [Aspect 14] In Aspect 2, R 1 , and R 2 are hydrogen atoms, and R 4 , R 5 , R 6 , and R 7 are the same or different and are a halogen atom or a hydrogen atom. [Aspect 15] In Aspect 3, R 1 , and R 2 are hydrogen atoms, and R 4 , R 5 , R 6 , and R 7 are the same or different and are a halogen atom or a hydrogen atom. [Aspect 16] In Aspect 4, R 1 , and R 2 are hydrogen atoms, and R 4 , R 5 , R 6 , and R 7 are the same or different and are a halogen atom or a hydrogen atom. [Aspect 17] In Aspect 5, R 1 , and R 2 are hydrogen atoms, and R 4 , R 5 , R 6 , and R 7 are the same or different and are a halogen atom or a hydrogen atom. [Aspect 18] In Aspect 6, R1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 19] In aspect 7, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 20] In aspect 8, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 21] In aspect 9, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 22] In aspect 10, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 23] In aspect 11, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 24] In aspect 12, R 1 , and R 2 is a hydrogen atom, R 4 , R 5 , R 6 , and R 7However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 25] In Aspect 1, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 26] In aspect 2, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 27] In aspect 3, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 28] In aspect 4, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 29] In Aspect 5, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 30] In aspect 6, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 31] In aspect 7, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 32] In aspect 8, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 33] In aspect 9, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 34] In aspect 10, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 35] In aspect 11, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 36] In aspect 12, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 However, a compound which is the same or different in phase, and is a halogen atom or a hydrogen atom. [Aspect 37] In Aspect 1, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 38] In aspect 2, R 1 , R 2 , R 6 , and R 7is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 39] In aspect 3, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 40] In aspect 4, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 41] In aspect 5, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 42] In aspect 6, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 43] In aspect 7, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 44] In aspect 8, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 45] In aspect 9, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 46] In aspect 10, R 1 , R2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 47] In aspect 11, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 48] In aspect 12, R 1 , R 2 , R 6 , and R 7 is a hydrogen atom, R 4 , and R 5 A compound in which is a halogen atom. [Aspect 49] In the present compound N, or any of aspects 1 to 48, n is 0, 1, or 2, and R 3 A compound in which a C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group C {the C3-C6 alicyclic hydrocarbon group and the 3-6 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group F}. [Aspect 50] In the present compound N, or any of aspects 1 to 48, n is 2, and R 3 However, NR 8 R 9 A compound that is a combination of the following. [Aspect 51] Compound N of this invention, or any of the embodiments 1 to 48, in which n is 1 or 2. [Aspect 52] Compound N of this invention, or any of the embodiments 1 to 48, in which n is 2. [Aspect 53] Compound N of this invention, or any of the embodiments 1 to 48, in which n is 0, 1, or 2, and R 3 However, the compound is a C2-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, or a C3-C6 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group F. [Aspect 54] In the present compound N, or any of aspects 1 to 48, n is 0, 1, or 2, and R 3However, a compound which is a C2-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C. [Aspect 55] In the present compound N, or any of aspects 1 to 48, n is 0, 1, or 2, and R 3 However, the compound is a C2-C6 chain hydrocarbon group or a C3-C6 alicyclic hydrocarbon group. [Aspect 56] In the present compound N, or any of aspects 1 to 48, n is 0, 1, or 2, and R 3 A compound in which is a C3-C6 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group F. [Aspect 57] In the present compound N, or any of aspects 1 to 48, n is 0, 1, or 2, and R 3 A compound in which the group is a C3-C6 alicyclic hydrocarbon group.

[0014] Examples of the compound N of the present invention include the following compounds.

[0015] [Aspect A1] In compound N of the present invention, Z 1a However, the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D a Group B a C5-C6 alicyclic hydrocarbon groups, group B, which may be substituted with one or more more selected substituents. a A C3-C4 cycloalkyl group, or OR, which may be substituted with one or more more selected substituents. 10a And R 10a However, it is a compound that is a C3-C8 cycloalkyl group. [Aspect A2] In compound N of the present invention, Z 1a However, a phenyl group or a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D a A compound which may be substituted with one or more more selected substituents. [Aspect A3] In compound N of the present invention, Z 1a However, group D aA compound which is a phenyl group that may be substituted with one or more more selected substituents. [Aspect A4] In compound N of the present invention, Z 1a However, group D a A compound which is a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) which may be substituted with one or more substituents selected from the above. [Aspect A5] In compound N of the present invention, Z 1a However, Group B a A C5-C6 alicyclic hydrocarbon group, or group B, which may be substituted with one or more more selected substituents. a A compound which is a C3-C4 cycloalkyl group that may be substituted with one or more more selected substituents. [Aspect A6] In compound N of the present invention, Z 1a However, OR 10a And R 10a A compound in which is a C3-C6 cycloalkyl group. [Aspect A7] In compound N of the present invention, Z 1a However, a phenyl group, a 5-6 membered aromatic heterocyclic group {the phenyl group and the 5-6 membered aromatic heterocyclic group may be substituted with one or more halogen atoms}, a C5-C6 alicyclic hydrocarbon group, or OR 10a And R 10a However, it is a compound that is a C3-C6 cycloalkyl group. [Aspect A8] In compound N of the present invention, Z 1a However, a phenyl group, a six-membered aromatic heterocyclic group {the phenyl group and the six-membered aromatic heterocyclic group may be substituted with one or more halogen atoms}, a C5-C6 alicyclic hydrocarbon group, or OR 10a And R 10a However, it is a compound that is a C3-C6 cycloalkyl group. [Aspect A9] In compound N of the present invention, Z 1a However, the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D Na Group D Na C5-C6 alicyclic hydrocarbon groups, group D, which may be substituted with one or more more selected substituents. NaA cyclopropyl group which may be substituted with one or more more selected substituents, OR 10a And R 10a However, group E Na A compound that is a C3-C8 alicyclic hydrocarbon group, which may be substituted with one or more more selected substituents. Group D Na : A group consisting of halogen atoms, methyl groups, methoxy groups, CF3 groups, CF2H groups, and cyclopropyl groups. Group E Na : A group consisting of halogen atoms, methyl groups, methoxy groups, CF3 groups, and CF2H groups. [Aspect A10] In compound N of the present invention, Z 1a However, group D Na A compound which is a phenyl group that may be substituted with one or more more selected substituents. [Aspect A11] In compound N of the present invention, Z 1a However, group D Na A compound which is a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) which may be substituted with one or more more selected substituents. [Aspect A12] In compound N of the present invention, Z 1a However, group D Na A C5-C6 alicyclic hydrocarbon group which may be substituted with one or more more selected substituents, or group D Na A compound which is a cyclopropyl group that may be substituted with one or more more selected substituents. [Aspect A13] In aspect A1, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A14] In aspect A2, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A15] In aspect A3, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A16] In aspect A4, R 1a , and R 2ais a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A17] In aspect A5, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A18] In aspect A6, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A19] In aspect A7, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A20] In aspect A8, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A21] In aspect A9, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A22] In aspect A10, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A23] In aspect A11, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5a However, a compound which is a halogen atom or a hydrogen atom. [Aspect A24] In aspect A12, R 1a , and R 2a is a hydrogen atom, R 4a is a halogen atom, R 5aHowever, a compound which is a halogen atom or a hydrogen atom. [Aspect A25] In aspect A1, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A26] In Aspect A2, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A27] In aspect A3, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A28] In Aspect A4, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A29] In Aspect A5, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A30] In aspect A6, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A31] In aspect A7, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A32] In Aspect A8, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A33] In Aspect A9, R 1a , and R 2a is a hydrogen atom, R4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A34] In aspect A10, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A35] In aspect A11, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A36] In aspect A12, R 1a , and R 2a is a hydrogen atom, R 4a is a fluorine atom, R 5a A compound in which is a fluorine atom or a hydrogen atom. [Aspect A37] In aspect A1, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A38] In aspect A2, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A39] In aspect A3, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A40] In aspect A4, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A41] In aspect A5, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A42] In aspect A6, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5aA compound in which is a halogen atom. [Aspect A43] In Aspect A7, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A44] In Aspect A8, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A45] In aspect A9, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A46] In aspect A10, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A47] In aspect A11, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A48] In aspect A12, R 1a , and R 2a is a hydrogen atom, R 4a , and R 5a A compound in which is a halogen atom. [Aspect A49] Compound N of the present invention, or any of aspects A1 to A48, R 3a However, group C a A C2-C6 chain hydrocarbon group, which may be substituted with one, two, three, four, or five more selected substituents, or group E a A compound that is a C3-C6 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from the above. [Aspect A50] Compound N of the present invention, or any of aspects A1 to A48, in which na is 1 or 2. [Aspect A51] Compound N of the present invention, or any of aspects A1 to A48, in which na is 2. [Aspect A52] Compound N of the present invention, or any of aspects A1 to A48, R 3a However, group C aA compound which is a C2-C6 chain hydrocarbon group which may be substituted with one, two, three, four, or five more selected substituents. [Aspect A53] Compound N of the present invention, or any of aspects A1 to A48, R 3a However, the compound is a C2-C6 chain hydrocarbon group or a C3-C6 alicyclic hydrocarbon group. [Aspect A54] In compound N of the present invention, or any of aspects A1 to A48, R 3a Group E a A compound which is a C3-C6 alicyclic hydrocarbon group that may be substituted with one or more substituents selected from among them. [Aspect A55] In compound N of the present invention, or in any of aspects A1 to A48, R 3a A compound in which is a C3-C6 alicyclic hydrocarbon group. [Aspect A56] Compound N of the present invention, or any of aspects A1 to A48, in which na is 2, and R 3a However, group C a A C2-C6 chain hydrocarbon group, which may be substituted with one, two, three, four, or five more selected substituents, or group E a A compound which is a C3-C6 alicyclic hydrocarbon group that may be substituted with one or more substituents selected from the others. [Aspect A57] In compound N of the present invention, or any of aspects A1 to A48, na is 1 or 2, and R 3a However, group C a A C2-C6 chain hydrocarbon group, which may be substituted with one, two, three, four, or five more selected substituents, or group E a A compound which is a C3-C6 alicyclic hydrocarbon group that may be substituted with one or more substituents selected from the others. [Aspect A58] Compound N of the present invention, or any of aspects A1 to A48, wherein na is 2, and R 3a However, the compound is a C2-C6 chain hydrocarbon group or a C3-C6 alicyclic hydrocarbon group. [Aspect A59] In compound N of the present invention, or any of aspects A1 to A48, na is 1 or 2, and R 3a However, the compound is a C2-C6 chain hydrocarbon group or a C3-C6 alicyclic hydrocarbon group.

[0016] The following compounds are also examples of the compound N of the present invention. [Aspect AX1] In the compound N of the present invention, R 1a and R 2ais a hydrogen atom, R 3a is a C2-C6 chain hydrocarbon group or a C3-C6 alicyclic hydrocarbon group, R 4a and R 5a is a fluorine atom, Z 1a is a phenyl group, a 6-membered aromatic heterocyclic group {the phenyl group and the 6-membered aromatic heterocyclic group may be substituted with one or more halogen atoms}, a C5-C6 alicyclic hydrocarbon group, or OR 10a And R 10a However, it is a compound that is a C3-C6 cycloalkyl group. [Aspect AX2] In compound N of the present invention, R 1a and R 2a is a hydrogen atom, R 3a is a C2-C4 chain hydrocarbon group or a cyclopropyl group, R 4a and R 5a is a fluorine atom, Z 1a is a phenyl group, a pyridyl group {the phenyl group and the pyridyl group may be substituted with one or more halogen atoms}, a C5-C6 alicyclic hydrocarbon group, or OR 10a And R 10a However, a compound that is a C3-C6 cycloalkyl group. [Aspect AX3] A compound in which na is 1 or 2 in Aspect AX1 or AX2. [Aspect AX4] A compound in which na is 2 in Aspect AX1 or AX2.

[0017] Next, a method for producing the present compound (including the compound of the present invention) will be described.

[0018] Manufacturing Method A The compound represented by formula (I-X1) (hereinafter referred to as compound (I-X1)) can be produced by reacting the compound represented by formula (A1) (hereinafter referred to as compound (A1)) and the compound represented by formula (M1) (hereinafter referred to as compound (M1)) in the presence of a palladium catalyst. [In the formula, X 1x represents a chlorine atom, a bromine atom, an iodine atom, or a trifuryloxy group, M 1x represents B(OH)2,4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, tributylstannyl group, ZnBr, MgBr, or MgCl, Z 1xThis represents a phenyl group, a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {the phenyl group and the 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) may be substituted with one or more substituents selected from group D}, a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group B, or a 3-8 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E (however, Z 1x In M 1xOr, the atom bonded to the benzene ring shown in compound (I-X1) is a carbon atom), and other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include hydrocarbons such as hexane, toluene, and xylene (hereinafter referred to as hydrocarbons); ethers such as methyl tert-butyl ether (hereinafter referred to as MTBE), tetrahydrofuran (hereinafter referred to as THF), and 1,2-dimethoxyethane (hereinafter referred to as DME) (hereinafter referred to as ethers); halogenated hydrocarbons such as dichloromethane, chloroform, and chlorobenzene (hereinafter referred to as halogenated hydrocarbons); amides such as dimethylformamide (hereinafter referred to as DMF) and N-methylpyrrolidone (hereinafter referred to as NMP) (hereinafter referred to as amides); esters such as methyl acetate and ethyl acetate (hereinafter referred to as esters); nitriles such as acetonitrile and propionitrile (hereinafter referred to as nitriles); dimethyl sulfoxide (hereinafter referred to as DMSO); water; and mixtures of two or more of these. Examples of palladium catalysts used in the reaction include palladium(II) acetate and [1,1'-bis(diphenylphosphin)ferrocene]palladium(II) dichloride. In the reaction, compound (M1) is usually used in a ratio of 0.5 to 2 moles and palladium catalyst in a ratio of 0.01 to 0.3 moles per mole of compound (A1). A base may be added to the reaction as needed. Examples of bases that may be used in the reaction as needed include organic bases such as triethylamine and pyridine (hereinafter referred to as organic bases); alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); alkali metal bicarbonates such as sodium bicarbonate and potassium bicarbonate (hereinafter referred to as alkali metal bicarbonates); sodium fluoride; and tripotassium phosphate. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (A1). The reaction temperature is usually in the range of 0°C to 150°C. The reaction time is typically in the range of 0.1 to 120 hours. After the reaction is complete, the compound (I-X1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the resulting organic layer.Compound (M1) is either publicly known or can be produced according to known methods.

[0019] Manufacturing Method B Compound (I-X1) can also be produced by reacting the compound represented by formula (A2) (hereinafter referred to as compound (A2)) with the compound represented by formula (M2) (hereinafter referred to as compound (M2)) in the presence of a palladium catalyst. [In the formula, the symbols have the same meaning as above (however, Z 1x In X 1x (or the atom bonded to the benzene ring shown in compound (I-X1) is a carbon atom.) The reaction can be carried out in accordance with manufacturing method A, using compound (M2) instead of compound (A1) and compound (A2) instead of compound (M1). Compound (M2) is known or can be manufactured in accordance with known methods.

[0020] Manufacturing Method C The compound represented by formula (I-X2) (hereinafter referred to as compound (I-X2)) can be produced by reacting compound (A1) and the compound represented by formula (M3) (hereinafter referred to as compound (M3)) in the presence of a copper catalyst and a base. [In the ceremony, Z 2x This represents a 3-8 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, or a 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {the 5-6 member aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group)}, or a 3-8 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E (however, Z 2xIn this example, the hydrogen atom shown in compound (M3), or the atom bonded to the benzene ring in compound (I-X2), is a nitrogen atom), and other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Solvents used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, DMSO, water, and mixtures of two or more of these. Copper catalysts used in the reaction include, for example, copper(I) iodide and copper(I) bromide. Bases used in the reaction include, for example, organic bases, alkali metal carbonates, alkali metal bicarbonates, and tripotassium phosphate. In the reaction, compound (M3) is usually used in a ratio of 0.5 to 2 moles, copper catalyst in a ratio of 0.01 to 0.5 moles, and base in a ratio of 1 to 10 moles per mole of compound (A1). Ligands may be added to the reaction as needed. Ligands that may be used in the reaction as needed include diamines such as N,N'-dimethylethylenediamine and trans-N,N'-dimethylcyclohexane-1,2-diamine (hereinafter referred to as diamines), and amino acid derivatives such as N-methylglycine. When ligands are used in the reaction, the ligand is usually used in a ratio of 0.01 moles to 4.0 moles per mole of compound (A1). The reaction temperature is usually in the range of 0°C to 150°C. The reaction time is usually in the range of 0.1 hours to 120 hours. After the reaction is complete, compound (I-X2) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the resulting organic layer. Compound (M3) is known or can be produced according to known methods.

[0021] Manufacturing Method D The compound represented by formula (I-X3) (hereinafter referred to as compound (I-X3)) can be produced by reacting the compound represented by formula (A3) (hereinafter referred to as compound (A3)) and the compound represented by formula (M4) (hereinafter referred to as compound (M4)) in the presence of a base. [In the formula, X 2xThe symbols represent a chlorine atom, a bromine atom, an iodine atom, a mesyloxy group, or a trifuryloxy group, and the other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include nitriles, ethers, hydrocarbons, amides, DMSO, water, and mixtures of two or more of these. Examples of bases used in the reaction include alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides), alkali metal carbonates, organic bases, and tripotassium phosphate. 2xIf is a bromine atom, an iodine atom, or a trifuryloxy group, the reaction may be carried out by adding a metal catalyst and ligand as needed. Examples of metal catalysts that can be used in the reaction as needed include palladium catalysts such as palladium(II) acetate and [1,1'-bis(diphenylphosphin)ferrocene]palladium(II) dichloride; nickel catalysts such as bis(cyclooctadiene)nickel(O) and nickel(II) chloride; and copper catalysts such as copper(I) iodide and copper(I) chloride. When a metal catalyst is used in the reaction, the metal catalyst is usually used in a ratio of 0.01 moles to 1 mole per mole of compound (A3). Ligands that may be used in the reaction as needed include triphenylphosphine, xanthophos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. When ligands are used in the reaction, the ligand is usually used in a ratio of 0.01 moles to 1 mole per mole of compound (A3). In the reaction, compound (M4) is usually used in a ratio of 1 mole to 10 moles and the base in a ratio of 1 mole to 1 mole of compound (A3). The reaction temperature is typically in the range of -20°C to 200°C. The reaction time is typically in the range of 0.1 hours to 72 hours. After the reaction is complete, compound (I-X3) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, drying the resulting organic layer, and concentrating it. Compound (M4) is either known or can be produced according to known methods.

[0022] Intermediate preparation method A: Compound (A2) can be prepared by reacting compound (A1) with bis(pinacolato)diborone in the presence of a base and a palladium catalyst. [In the formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with manufacturing method A, using bis(pinacolato)diborone instead of compound (M1).

[0023] Intermediate preparation method B: Compound (A3) can be prepared by reacting compound (A2) with an oxidizing agent, followed by hydrolysis of the product. [The symbols in the formula have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, and mixtures of two or more of these. Examples of oxidizing agents used in the reaction include sodium periodate, m-chloroperbenzoic acid (hereinafter referred to as mCPBA), and hydrogen peroxide. In the reaction, the oxidizing agent is usually used in a ratio of 1 mole to 1.2 moles per mole of compound (A2). The reaction temperature is usually in the range of -20°C to 80°C. The reaction time is usually in the range of 0.1 hours to 12 hours. After the oxidation reaction is complete, the hydrolysis reaction of the product proceeds by adding water or an aqueous solution of a base such as sodium bicarbonate to the reaction mixture. The reaction temperature for the hydrolysis reaction is usually in the range of -20°C to 80°C. The reaction time for the hydrolysis reaction is usually in the range of 0.1 hours to 12 hours. After the hydrolysis reaction is complete, the mixture is extracted with an organic solvent, and the resulting organic layer is washed with an aqueous solution of a reducing agent (e.g., sodium sulfite, sodium thiosulfate) and an aqueous solution of a base (e.g., sodium bicarbonate) as needed. Compound (A3) can be obtained by drying and concentrating the organic layer.

[0024] Intermediate production method C The compound represented by formula (A1-1) (hereinafter referred to as compound (A1-1)) can be produced by reacting compound (B1) and the compound represented by formula (M5) (hereinafter referred to as compound (M5)) in the presence of a base. [In the formula, R 3xrepresents a C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-5 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group C {the C3-C6 alicyclic hydrocarbon group and the 3-5 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group F}, and the other symbols have the same meaning as above. The reaction can be carried out in accordance with production method D, using compound (B1) instead of compound (M4) and compound (M5) instead of compound (A3). Compounds (B1) and (M5) are known or can be produced in accordance with known methods.

[0025] Intermediate manufacturing method D: The compound represented by formula (B3) (hereinafter referred to as compound (B3)) can be manufactured from compound (B2). [In the formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with, for example, the method described in Tetrahedron Letters, 2017, 58, 2244-2247. Compound (B2) is known or can be prepared in accordance with known methods.

[0026] Intermediate production method E The compound represented by formula (A1-2) (hereinafter referred to as compound (A1-2)) can be produced by reacting compound (B3) and the compound represented by formula (M6) (hereinafter referred to as compound (M6)) in the presence of a base. [In the formula, the symbols have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include hydrocarbons, ethers, halogenated hydrocarbons, amides, esters, nitriles, and mixtures of two or more of these. Examples of bases used in the reaction include organic bases, alkali metal carbonates, alkali metal bicarbonates, sodium hydride, and tripotassium phosphate. In the reaction, compound (M6) is usually used in a ratio of 1 mole to 10 moles per mole of compound (B3), and the base is usually used in a ratio of 1 mole to 10 moles. The reaction temperature is usually in the range of 0°C to 150°C. The reaction time is usually in the range of 0.1 hours to 48 hours. After the reaction is complete, compound (A1-2) can be isolated by post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying the organic layer, and concentrating it. Compound (M6) is known or can be produced according to known methods.

[0027] Intermediate production method F The compound represented by formula (A1-3) (hereinafter referred to as compound (A1-3)) can be produced by reacting compound (A1-1) with an oxidizing agent, and the compound represented by formula (A1-4) (hereinafter referred to as compound (A1-4)) can be produced by reacting compound (A1-3) with an oxidizing agent. [In the formula, the symbols have the same meaning as above.] First, a method for producing compound (A1-3) from compound (A1-1) will be described. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include halogenated hydrocarbons such as dichloromethane, chloroform, and chlorobenzene (hereinafter referred to as halogenated hydrocarbons); nitriles such as acetonitrile and propionitrile (hereinafter referred to as nitriles); alcohols such as methanol and ethanol (hereinafter referred to as alcohols); acetic acid; water and mixtures of two or more of these. Examples of oxidizing agents used in the reaction include sodium periodate, m-chloroperbenzoic acid (hereinafter referred to as mCPBA), and hydrogen peroxide. When hydrogen peroxide is used as an oxidizing agent, an acid, base, or catalyst may be added as needed. An example of an acid that may be used in the reaction as needed is trifluoroacetic acid. When an acid is used in the reaction, the acid is usually used in a ratio of 0.01 to 1 mole per mole of compound (A1-1). A suitable base to be used in the reaction, if necessary, is sodium carbonate. When a base is used in the reaction, it is usually used in a ratio of 0.01 to 1 mole of base per mole of compound (A1-1). A suitable catalyst to be used in the reaction, if necessary, is sodium tungstate. When a catalyst is used in the reaction, it is usually used in a ratio of 0.01 to 0.5 moles of catalyst per mole of compound (A1-1). An oxidizing agent is usually used in a ratio of 1 to 1.2 moles per mole of compound (A1-1). The reaction temperature is usually in the range of -20°C to 80°C. The reaction time is usually in the range of 0.1 to 12 hours. After the reaction is complete, water is added to the reaction mixture, extracted with an organic solvent, and the organic layer is washed with an aqueous solution of a reducing agent such as sodium sulfite or sodium thiosulfate, and an aqueous solution of a base such as sodium bicarbonate, if necessary. Compound (A1-3) can be obtained by drying and concentrating the organic layer.

[0028] Next, a method for producing compound (A1-4) from compound (A1-3) is described. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, and mixtures of two or more of these. Examples of oxidizing agents used in the reaction include mCPBA and hydrogen peroxide. When hydrogen peroxide is used as the oxidizing agent, a base or catalyst may be added as needed. An example of a base used in the reaction is sodium carbonate. When a base is used in the reaction, it is usually used in a ratio of 0.01 moles to 1 mole of the base per mole of compound (A1-3). An example of a catalyst used in the reaction is sodium tungstate. When a catalyst is used in the reaction, it is usually used in a ratio of 0.01 moles to 0.5 moles of the catalyst per mole of compound (A1-3). In the reaction, an oxidizing agent is usually used in a ratio of 1 mole to 2 moles per mole of compound (A1-3). The reaction temperature is usually in the range of -20°C to 120°C. The reaction time is typically in the range of 0.1 to 12 hours. After the reaction is complete, water is added to the reaction mixture, and it is extracted with an organic solvent. The organic layer is then washed with an aqueous solution of a reducing agent such as sodium sulfite or sodium thiosulfate, and an aqueous solution of a base such as sodium bicarbonate, as needed. By drying and concentrating this organic layer, compound (A1-4) can be obtained.

[0029] Furthermore, compound (A1-4) can also be produced in a single step by reacting compound (A1-1) with an oxidizing agent. The reaction can be carried out in accordance with the method for producing compound (A1-3) from compound (A1-1), using an oxidizing agent in a ratio of typically 2 to 5 moles per mole of compound (A1-1).

[0030] The compound of the present invention can be mixed with or used in combination with one or more components selected from the group consisting of (a), (b), (c), and (d) below (hereinafter referred to as "the component"). Mixing or used in combination means using the compound of the present invention and the component simultaneously, separately, or at intervals of time. When the compound of the present invention and the component are used simultaneously, the compound of the present invention and the component may be contained in separate formulations or in a single formulation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of (a), (b), (c), and (d) (i.e., the component), and the compound of the present invention.

[0031] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, string organ TRPV channel modulators, mite growth inhibitors, microbial insect midgut membrane disruptors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncoupling agents, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complexes I and II, This group consists of inhibitors of III and IV, voltage-gated sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chord-sound organ modulators, microbial insecticides, and other insecticidal, acaricidal, and nematicidal components. These are described in the IRAC classification based on the mechanism of action.

[0032] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acyl amino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signaling inhibitors, lipid and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., triazole-based DMI fungicides), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-point contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the FRAC classification based on mechanism of action.

[0033] Group (c) is a group of plant growth regulating components (including mycorrhizal fungi and rhizobia).

[0034] Group (d) is the group of repellent components.

[0035] Examples of combinations of this component and the compounds of the present invention are described below. For example, alanycarb + SX means a combination of alanycarb and SX. The abbreviation SX refers to any one of the compounds of the present invention selected from compound group SX1 to SX73. Furthermore, all of the components described below are known components and can be obtained from commercially available formulations or manufactured by known methods. If the component is a microorganism, it can also be obtained from a microbial depositary. The numbers in parentheses represent CAS RN (registered trademark).

[0036] Combinations of the above group (a) components with the compounds of the present invention: abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acynonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, Amitraz + SX, Azadirachtin + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bark of Celastrus angulatus + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Bentioflumin + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX,Bioallethrin + SX, Bioresmethrin + SX, Bistrifluron + SX, Bisulflufen + SX, Borax + SX, Boric acid + SX, Broflanilide + SX, Bromopropylate + SX, Buprofezin + SX, Butocarboxim + SX, Butoxycarboxim + SX, Cadusafos + SX, Calcium phosphide + SX, Carbaryl + SX, Carbofuran + SX, Carbosulfan + SX, Cartap hydrochloride + SX, Cartap + SX, Chinomethionate + SX, Chlorantraniliprole + SX, Chlordane + SX, Chlorethoxyfos + SX, Chlorfenapyr + SX, Chlorfenvinphos + SX, Chlorfluazuron + SX, Chlormephos + SX, Chloropicrin + SX, Chlorpyrifos + SX, Chlorpyrifos-methyl + SX, Chromafenozide + SX, Clofentezine + SX, Clothianidin + SX, Concanamycin A + SX, Coumaphos + SX, Cryolite + SX,Cyanophos + SX, Cyantraniliprole + SX, Cybenzoxasulfyl + SX, Cyclaniliprole + SX, Cyclobutrifluram + SX, Cycloprothrin + SX, Cycloxaprid + SX, Cyenopyrafen + SX, Cyetpyrafen + SX, Cyflumetofen + SX, Cyfluthrin + SX, Cyhalodiamide + SX, Cyhalothrin + SX, Cyhexatin + SX, Cypermethrin + SX, Cyphenothrin + SX, Cyproflanilide + SX, Cyromazine + SX, Dazomet + SX, Deltamethrin + SX, Demeton-S-methyl + SX, Diafenthiuron + SX, Diazinon + SX, Dichlorvos + SX, Dichloromezotiaz + SX, Dicofol + SX, Diclotophos + SX, Diflovidazin + SX, Diflubenzuron + SX, Dimefluthrin + SX, Dimethoate + SX, Dimethylvinphos + SX, Dimpropyridaz + SX, Dinotefuran + SX, Disodium octaborate + SX,Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, dried leaves of Dryopteris filix-mas + SX, emamectin-benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, Ethiprole + SX, Ethoprophos + SX, Etofenprox + SX, Ethoxazole + SX, Artemisia absinthium extract + SX, Azadirachta indica extract + SX, Cassia nigricans extract + SX, Clitoria ternatea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract + SX, Tansy extract + SX, Urtica dioica extract + SX Mistletoe extract (extract of Viscum album) + SX,Fanflu + SX, Fenamiphos + SX, Fenazaquin + SX, Fenbutatin oxide + SX, Fenitrothion + SX, Fenmezoditiaz + SX, Fenobucarb + SX, Fenoxycarb + SX, Fenpropathrin + SX, Fenpyroximate + SX, Fenthion + SX, Fenvalerate + SX, Fipronil + SX, Flometoquin + SX, Flonicamid + SX, Fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenoprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flumetnicam + SX, flupentiofenox + SX, Flupyradifurone + SX, Flupyrimin + SX, Flupyroxystrobin + SX, Fluralaner + SX, Fluvalinate + SX,Fluxametamide + SX, Formetanate + SX, Fosthiazate + SX, Furamethrin + SX, Furathiocarb + SX, Gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, Halfenprox + SX, Halofenozide + SX, Heptafluthrin + SX, Heptenophos + SX, Hexaflumuron + SX, Hexythiazox + SX, Potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imicyafos + SX, imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoflualanam + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate salicylate) + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappatefluthrin + SX,Kappa-bifenthrin + SX, Kinoprene + SX, Lambda-cyhalothrin + SX, Ledprona + SX, Lenoremycin + SX, Lepimectin + SX, Lime sulfur + SX, Lotilaner + SX, Lufenuron + SX, Machine oil + SX, Malathion + SX, Mecarbam + SX, Meperfluthrin + SX, Metaflumizone + SX, Metam + SX, Methamidophos + SX, Methidathion + SX, Methiocarb + SX, Methomyl + SX, Methoprene + SX, Methoxychlor + SX, Methoxyfenozide + SX, Methyl bromide + SX, Metofluthrin + SX, Metolcarb + SX, Methoxadiazone + SX, Mevinphos + SX, Milbemectin + SX, Milbemycin oxime + SX, Mivorilaner + SX, Modoflaner + SX, Momfluorothrin + SX, Monocrotophos + SX, Moxidectin + SX, Naled + SX, Nicofluprole + SX, Nicotine + SX,Nicotine sulfate + SX, nitenpyram + SX, novaluron + SX, nobiflumulon + SX, oil of the seeds of Chenopodium anthelminticum + SX, omethoate + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pioxaniliprole + SX, piperflanilide + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, Pyflubumide + SX, Pymetrozine + SX, Pyraclofos + SX,Pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spinosad + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfiflumin + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfoxamyl + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tau-fluvalinate + SX,Tebufenozide + SX, Tebufenpyrad + SX, Tebupirimfos + SX, Teflubenzuron + SX, Tefluthrin + SX, Temephos + SX, Terbufos + SX, Terpene constituents of the extract of chenopodium ambrosioides near ambrosioides + SX, Tetrachlorantraniliprole + SX, Tetrachlorvinphos + SX, Tetradifon + SX, Tetramethrin + SX, Tetramethylfluthrin + SX, Tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap-disodium + SX, thiosultap-monosodium + SX, tiapyrachlor + SX, tigolaner + SX, tiorantraniliprole + SX, tioxazafen + SX, Tolfenpyrad + SX, Tralomethrin + SX, Transfluthrin + SX,Triazamate + SX, Triazophos + SX, Trichlorfon + SX, Trifluenfuronate + SX, Triflumezopyrim + SX, Triflumuron + SX, Trimethacarb + SX, Trioxyflanilide + SX, Tyclopyrazoflor + SX, Umifoxolaner + SX, Vadescana + SX, Vamidothion + SX, Wood extract of Quassia amara + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX,N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX, Cry1Ab protein from Bacillus thuringiensis + SX, Cry1Ac protein from Bacillus thuringiensis + SX, Cry1Fa protein from Bacillus thuringiensis + SX, Cry1A.105 protein from Bacillus thuringiensis + SX, Cry2Ab protein from Bacillus thuringiensis SX, Bacillus thuringiensis Vip3A protein + SX, Bacillus thuringiensis mCry3A protein + SX, Bacillus thuringiensis Cry3Ab protein + SX, Bacillus thuringiensis Cry3Ab protein + SX, Bacillus thuringiensis Cry3Bb protein + SX, Bacillus thuringiensis Cry34Ab1 / Cry35Ab1 protein + SX,Adoxophyes orana GV (granulovirus) strain BV-0001 + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Cryptophlebia leucotreta GV + SX, Dendrolimus punctatus cytoplasmic polyhedron virus + SX, Helicoverpa armigera NPV (nucleopolyhedrovirus) strain BV-0003 + SX, Helicoverpa zea NPV + SX, Lymantria dispar NPV + SX, Mamestra brassicae NPV + SX, Mamestra configurata NPV + SX, Neodiprion abietis NPV + SX, Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Nosema locustae + SX,Orgyia pseudotsugata NPV + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Spodoptera exigua MNPV + SX, Spodoptera littoralis MNPV + SX, Spodoptera litura NPV + SX, Arthrobotrys dactyloides + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus megaterium + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52 + SX, Bacillus thuringiensis subsp. Aizawai strain GC-91 + SX,Bacillus thuringiensis subsp. Aizawai strain NB200 + SX, Bacillus thuringiensis subsp. Aizawai Serotype strain H-7 + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176 + SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002 + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis var. colmeri + SX,Bacillus thuringiensis var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis var. dendrolimus + SX, Bacillus thuringiensis var. galleriae + SX, Bacillus thuringiensis var. israelensis strain BMP144 + SX, Bacillus thuringiensis var. israelensis serotype strain H-14 + SX, Bacillus thuringiensis var. japonensis strain buibui + SX, Bacillus thuringiensis var. san diego strain M-7 + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. aegypti + SX, Bacillus thuringiensis var. T36 + SX, Beauveria bassiana strain ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain GHA + SX, Beauveria brongniartii + SX, Burkholderia rinogensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Dactyllela ellipsospora + SX, Dactylaria thaumasia + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Lagenidium giganteum + SX, Lecanicillium lecanii strain KV01 + SX,Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX, Lecanicillium muscarium strain Ve6 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae var. acridum + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae + SX, Pasteuria thornei + SX, Serratia entomophila + SX, Verticillium chlamydosporium + SX, Verticillium lecani strain NCIM1312 + SX, Wolbachia pipientis + SX。,

[0037] Combinations of the main component from group (b) above with the compounds of the present invention: acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, Benzovindiflupyr + SX, Bifemetstrobin + SX, Binapacryl + SX, Biphenyl + SX, Bitertanol + SX, Bixafen + SX, Blastoicidin-S + SX, Bordeaux mixture + SX, Boscalid + SX, Bromothalonil + SX, Bromuconazole + SX, Bupirimate + SX, Captafol + SX, Captan + SX, Carbendazim + SX, Carboxin + SX, Carpropamid + SX, Chinomethionate + SX, Chitin + SX, Chloroinconazide + SX,Chloroneb + ​​SX, chlorothalonil + SX, chlozolinate + SX, colletochlorin B + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, basic copper chloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, Diclobentiazox + SX, Dichlofluanid + SX, Diclocymet + SX, Diclomezine + SX, Dichloran + SX, Dietofencarb + SX, Difenoconazole + SX, Diflumetorim + SX, Dimethachlone + SX, Dimethirimol + SX, Dimethomorph + SX, Dimoxystrobin + SX, Diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogen phosphite + SX, Dipymetitrone + SX, Dithianon + SX,Dodecylbenzenesulfonic acid bisethylenediamine copper(II) complex salt + SX, Dodemorph + SX, Dodine + SX, Edifenphos + SX, Enoxastrobin + SX, Epoxiconazole + SX, Etaconazole + SX, Ethaboxam + SX, Ethirimol + SX, Etridiazole + SX, Garlic extract (Allium sativum) + SX, Extract of the cotyledons of lupine plantlets ("BLAD") + SX, Horsetail extract (Equisetum arvense) + SX, Tea tree extract (extract of Melaleuca alternifolia) + SX, Japanese knotweed extract (extract of Reynoutria sachalinensis) + SX, Nasturtium extract (extract of Tropaeolum majus) + SX, Famoxadone + SX, Fenamidone + SX, Fenaminstrobin + SX, Fenarimol + SX, Fenbuconazole + SX, Feneptamidoquin + SX, Fenfuram + SX, Fenhexamide + SX, Fenopyramid + SX, Fenoxanil + SX, Fenpiclonil + SX, Fenpicoxamide + SX,Fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX, flubeneteram + SX, fludioxonil + SX, flufenoxadiazam + SX, flufenoxystrobin + SX, fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, fluquinometoate + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, Flutriafol + SX, Fluxapyroxad + SX, Folpet + SX, Fosetyl + SX,Fosetyl-aluminium + SX, Fuberidazole + SX, Furalaxyl + SX, Furametpyr + SX, Galquin + SX, Guazatine + SX, Hexaconazole + SX, Hymexazole + SX, Imazalil + SX, Imibenconazole + SX, Iminoctadine + SX, Iminoctadine triacetate + SX, Inpyrfluxam + SX, Iodocarb + SX, Ipconazole + SX, Ipfentrifluconazole + SX, Ipflufenoquin + SX, Iprobenfos + SX, Iprodione + SX, Iprovalicarb + SX, Isofetamide + SX, Isoflucypram + SX, Isoprothiolane + SX, Isopyrazam + SX, Isothianil + SX, Kasugamycin + SX, Kresoxim-methyl + SX, Laminarin + SX, Leaves and bark of Quercus + SX, Mancozeb + SX, Mandestrobin + SX, Mandipropamid + SX, Maneb + ​​SX, Mefentrifluconazole + SX, Mepanipyrim + SX,Mepronil + SX, Meptyldinocap + SX, Metalaxyl + SX, Metalaxyl-M + SX, Metarylpicoxamide + SX, Metconazole + SX, Methasulfocarb + SX, Methylam + SX, Metominostrobin + SX, Metrafenone + SX, Methyltetraprole + SX, Myclobutanil + SX, Naftifine + SX, Nuarimol + SX, Octilinone + SX, Ofurace + SX, Orysastrobin + SX, Oxadixyl + SX, Oxathiapiprolin + SX, Oxine-copper + SX, Oxolinic acid + SX, Oxpoconazole + SX, Oxpoconazole fumarate + SX, Oxcarboxin + SX, Oxtetracycline + SX, Pefurazoate + SX, Penconazole + SX, Pencycuron + SX, Penflufen + SX, Penthiopyrad + SX, Phenamacril + SX, Phosphorous acid + SX, Phthalide + SX, Picarbutrazox + SX, Picoxystrobin + SX,Piperalin + SX, Polyoxins + SX, Potassium hydrogencarbonate + SX, Potassium dihydrogenphosphite + SX, Probenazole + SX, Prochloraz + SX, Procymidone + SX, Propamidine + SX, Propamocarb + SX, Propiconazole + SX, Propineb + ​​SX, Proquinazid + SX, Prothiocarb + SX, Prothioconazole + SX, Pydiflumetofen + SX, Pyraclostrobin + SX, Pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, Quinconazole + SX, Quinofumelin + SX, Quinoxyfen + SX, Quintozene + SX,Quinoa saponins (Saponins of Chenopodium quinoa) + SX, Seboctylamine + SX, Sedaxane + SX, Silthiofam + SX, Simeconazole + SX, Sodium hydrogencarbonate + SX, Spiroxamine + SX, Streptomycin + SX, Sulfur + SX, Tebuconazole + SX, Tebufloquin + SX, Teclofthalam + SX, Tecnazene + SX, Terbinafine + SX, Tetraconazole + SX, Thiabendazole + SX, tifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, thymol + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, Tridemorph + SX, Trifloxystrobin + SX, Triflumizole + SX, Triforine + SX,トリチコナゾール(triticonazole) + SX, バリダマイシン(validamycin) + SX, バリフェナレート(valifenalate) + SX, ビンクロゾリン(vinclozolin) + SX, マスタードパウダー(yellow mustard powder) + SX, zinc thiazole + SX, ジネブ(zineb) + SX, ジラム(ziram) + SX, ゾキサミド(zoxamide) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-d ichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX,N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, [4-(difluoromethoxy)phenyl]methyl 4-[(N-ethyl-N-methylamino)methylidene]amino-2,5-dimethylbenzoate + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R, 2S, 5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S, 2R, 5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-carboxylate (1791398-02-1) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX, 3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX,3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX,4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + SX, methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, ethyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, methyl 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX,1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-met hylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyprop-2-enoate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX, Agrobacterium radiobactor strain K1026 + SX, Agrobacterium radiobactor strain K84 + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo(trademark) EZ Nematicide) + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX,Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX,Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus subtilis strain Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX, Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-8 + SX, cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Fusarium oxysporum strain Fo47 + SX, Gliocladium catenulatum strain J1446 + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Pantoea agglomerans strain E325 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas fluorescens strain 1629RS + SX,Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain MA-4 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum SKT-1 + SX, Trichoderma asperellum strain T25 + SX, Trichoderma asperellum strain T34 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain SC1 + SX,Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harzianum strain 21 + SX, Trichoderma harzianum strain DB104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain kd + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma polysporum strain IMI206039 + SX, trichoderma stromaticum + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus strain CGF4526 + SX, Harpin protein + SX。,

[0038] Combinations of the main component from group (c) above with the compound of the present invention: 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, Cyclanilide + SX,Daminozide + SX, Decan-1-ol + SX, Dichlorprop + SX, Dikegulac + SX, Dimethipin + SX, Diquat + SX, Ethephon + SX, Ethychlozate + SX, Flumetralin + SX, Flurprimidol + SX, Forchlorfenuron + SX, Formononetin + SX, Gibberellin A + SX, Gibberellin A3 + SX, Inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintofen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate + SX, Thidiazuron + SX, Tripenthenol + SX, Tribufos + SX, Trinexapac-ethyl + SX,Uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate methyl + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Claroideoglomus etunicatum + SX, Claroideoglomus claroideum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregularis DAOM 197198 + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH + SX, Azospirillum brasilense Ab-V5 + SX, Azospirillum brasilense Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 + SX, Bradyrhizobium elkanii SEMIA 5019 + SX, Bradyrhizobium japonicum TA-11 + SX,Bradyrhizobium japonicum USDA 110 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Zucchini Yellow Mosaik Virus weak strain + SX. ,

[0039] Combinations of the above group (d) components with the compounds of the present invention: anthraquinone + SX, DEET + SX, icaridin + SX.

[0040] The ratio of the compound of the present invention to the component of this invention is not particularly limited, but examples of weight ratios (compound of the present invention:component of this invention) include 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, etc.

[0041] This compound, the compound of the present invention, or composition A can control plant diseases caused by plant pathogenic microorganisms such as fungi, oomycetes, phytomyxea, and bacteria. Examples of fungi include Ascomycota, Basidiomycota, Blastocoladiomycota, Chytridiomycota, Mucoromycota, and Olpidiomycota. Specifically, examples include the following. The names in parentheses indicate the scientific names of the plant pathogenic microorganisms that cause each disease.

[0042] Diseases of rice: blast (Pyricularia oryzae), sesame leaf blight (Cochliobolus miyabeanus), sheath blight (Rhizoctonia solani), bakanae disease (Gibberella fujikuroi), yellowing and withering disease (Sclerophthora macrospora), false blast and ear blight (Epicoccum nigrum), seedling blight (Trichoderma viride, Rhizopus oryzae), suspected sheath blight (red sclerotium pathogen (Waitea circinata), brown sclerotium pathogen (Ceratobasidium setariae), brown sheath blight pathogen (Thanatephorus cucumeris)), false smut (Ustilaginoidea virens), black kernel smut (Tilletia horrida, Tilletia barclayana);Wheat diseases: Powdery mildew (Blumeria graminis), Fusarium graminearum, Fusarium avenaceum, Fusarium culmorum, Microdochium nivale, Yellow rust (Puccinia striiformis), Black rust (Puccinia graminis), Red rust (Puccinia recondita), Red snow mold (Microdochium nivale, Microdochium majus), Snow mold (Typhula incarnata, Typhula ishikariensis), Snow mold (Sclerotinia borealis), Brown snow mold (Pythium spp.), Naked smut (Ustilago tritici), Smut (Tilletia caries, Tilletia controversa), Eye spot disease (Pseudocercosporella herpotrichoides), Leaf blight (Septoria tritici), rotten blight (Stagonospora nodorum), yellow spot (Pyrenophora tritici-repentis), seedling damping off caused by Rhizoctonia fungi (Rhizoctonia solani), damping off (Gaeumannomyces graminis), rice blast (Pyricularia graminis-tritici);Barley diseases: powdery mildew (Blumeria graminis), Fusarium graminearum, Fusarium avenaceum, Fusarium culmorum, Microdochium nivale, yellow rust (Puccinia striiformis), black rust (Puccinia graminis), small rust (Puccinia hordei), bare smut (Ustilago nuda), cloudy smut (Rhynchosporium secalis), net-like spot (Pyrenophora teres), leaf spot (Cochliobolus sativus), leaf spot (Pyrenophora graminea), Ramularia leaf spot (Ramularia collo-cygni), seedling blight caused by Rhizoctonia fungi (Rhizoctonia solani); maize diseases: rust (Puccinia sorghi), southern rust (Puccinia Polysora, sooty mold (Setosphaeria turcica), tropical rust (Physopella zeae), sesame leaf spot (Cochliobolus heterostrophus), anthracnose (Colletotrichum graminicola), gray leaf spot (Cercospora zeae-maydis), brown spot (Kabatiella zeae), Phaeosphaeria maydis, Diplodia disease (Stenocarpella maydis, Stenocarpella macrospora), Stoke's disease (Fusarium graminearum, Fusarium verticilioides, Colletotrichum graminicola), smut (Ustilago maydis), Physoderma disease (Physoderma maydis), tar spot disease (Phyllachora maydis);Cotton diseases: anthracnose (Colletotrichum gossypii), white mold (Ramularia areola), black spot (Alternaria macrospora, Alternaria gossypii), black root rot (Thielaviopsis basicola); coffee diseases: coffee rust (Hemileia vastatrix), leaf spot (Cercospora coffeicola); rapeseed diseases: sclerotinia sclerotiorum, black spot (Alternaria brassicae), root rot (Phoma lingam), light leaf spot (Pyrenopeziza brassicae); sugarcane diseases: rust (Puccinia melanocephela, Puccinia kuehnii), smut (Ustilago scitaminea); sunflower diseases: rust (Puccinia helianthi), downy mildew (Plasmopara halstedii); Citrus diseases: black spot (Diaporthe citri), scab (Elsinoe fawcetti), green mold (Penicillium digitatum), blue mold (Penicillium italicum), late blight (Phytophthora parasitica, Phytophthora citrophthora), aspergillus niger, white mold (Geotrichum candidum var. citri-aurantii), sooty mold (Cladosporium cladosporioides);Apple diseases: Monilinia mali, canker (Valsa ceratosperma), powdery mildew (Podosphaera leucotricha), apple leaf spot (Alternaria alternata apple pathotype), black spot (Venturia inaequalis), anthracnose (Glomerella cingulata, Colletotrichum acutatum), brown spot (Diplocarpon mali), ring spot (Botryosphaeria berengeriana), late blight (Phytophtora cactorum), cedar-apple rust (Gymnosporangium juniperi-virginianae, Gymnosporangium yamadae); Pear diseases: Black spot (Venturia nashicola, Venturia pirina), black spot (Alternaria alternata Japanese pear pathotype), cedar-apple rust (Gymnosporangium haraeanum); Peach diseases: Gray mold (Monilinia fructicola), black spot (Cladosporium carpophilum), Phomopsis rot (Phomopsis sp.), leaf curl (Taphrina deformans), powdery mildew (Podosphaera leucotricha); Grape diseases: Black rot (Elsinoe ampelina), late blight (Glomerella cingulata, Colletotrichum acutatum), powdery mildew (Uncinula necator), rust (Neophysopella sp.), black rot (Guignardia bidwellii), downy mildew (Plasmopara viticola), brown spot (Pseudocercospora vitis), white rot (Coniella castaneicola); Persimmon diseases: Anthracnose (Gloeosporium kaki, Colletotrichum acutatum), leaf spot (Cercospora kaki, Mycosphaerella Nawae, powdery mildew (Phyllactinia kakicola);Fig diseases: rust (Phakopsora nishidana); Cucurbit diseases: anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca fuliginea), vine blight (Didymella bryoniae), brown spot (Corynespora cassiicola), vine wilt (Fusarium oxysporum), downy mildew (Pseudoperonospora cubensis), late blight (Phytophthora capsici), seedling blight (Pythium sp.), Phomopsis root rot (Phomopsis sp.); Tomato diseases: ring spot (Alternaria solani), leaf mold (Cladosporium fulvum), sooty mold (Pseudocercospora fuligena), late blight (Phytophthora infestans), powdery mildew (Leveillula taurica); Eggplant diseases: brown spot (Phomopsis vexans), powdery mildew (Erysiphe cichoracearum), black blight (Corynespora melongenae), sooty mold (Mycovellosiella nattrassii), brown spot (Thanatephorus cucumeris); Brassicaceae vegetable diseases: black spot (Alternaria japonica), white spot (Cercosporella brassicae), clubroot (Plasmodiophora brassicae), downy mildew (Peronospora parasitica), white rust (Albugo candida), black sooty mold (Alternaria brassicola); Onion diseases: rust (Puccinia allii), black spot (Alternaria porri), black rot (Sclerotium cepivorum), small sclerotium rot (Botrytis squamosa), leaf blight (Stemphylium) vesicarium, Stempphylium botryosum), white silk disease (Sclerotium rolfsii), white spot leaf blight (Botrytis squamosa);Soybean diseases: Purple spot (Cercospora kikuchii), black rot (Elsinoe glycines), black spot (Diaporthe phaseolorum var. sojae), rust (Phakopsora pachyrhizi), brown ring spot (Corynespora cassiicola), anthracnose (Colletotrichum glycines, Colletotrichum truncatum), leaf blight (Rhizoctonia solani), brown spot (Septoria glycines), leaf spot (Cercospora sojina), sclerotinia rot (Sclerotinia sclerotiorum), powdery mildew (Microsphaera diffusa), stem blight (Phytophthora sojae), downy mildew (Peronospora manshurica), sudden death disease (Fusarium virguliforme), black root rot (Calonectria ilicicola), Diaporthe / Phomopsis Soybean pod abnormalities caused by various causative fungi (Diaporthe longicolla, Diaporthe phaseolorum, Phomopsis longicolla): pod anomalies; Bean diseases: Sclerotinia sclerotiorum, rust (Uromyces appendiculatus), horn spot disease (Phaeoisariopsis griseola), anthracnose (Colletotrichum lindemuthianum), root rot (Fusarium solani); Peanut diseases: Black spot disease (Cercospora personata), brown spot disease (Cercospora arachidicola), white mold disease (Sclerotium rolfsii), black root rot (Calonectria ilicicola); Pea diseases: Powdery mildew (Erysiphe pisi), root rot (Fusarium solani);Potato diseases: Late blight (Alternaria solani), late blight (Phytophthora infestans), scarlet rot (Phytophthora erythroseptica), powdery scab (Spongospora subterranea f. sp. subterranea), Verticillium albo-atrum, Verticillium dahliae, Verticillium nigrescens, dry rot (Fusarium solani), crown gall (Synchytrium endobioticum); Strawberry diseases: Powdery mildew (Sphaerotheca humuli), anthracnose (Glomerella cingulata, Colletotrichum acutatum); Tea diseases: Net blight (Exobasidium reticulatum), white spot (Elsinoe leucospila), ring spot (Pestalotiopsis) Diseases of tobacco plants: red rust (Alternaria longipes), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), blight (Phytophthora nicotianae); Diseases of sugar beets: brown spot (Cercospora beticola), leaf blight (Thanatephorus cucumeris), root rot (Thanatephorus cucumeris), black root disease (Aphanomyces cochlioides), rust (Uromyces betae); Diseases of roses: black spot (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosa); Diseases of chrysanthemums: brown spot (Septoria chrysanthemi-indici), white rust (Puccinia horiana); Onion diseases: White spot leaf blight (Botrytis cinerea, Botrytis byssoidea, Botrytis squamosa), gray rot (Botrytis allii), small sclerotinia rot (Botrytis squamosa);Diseases of various crops: gray mold (Botrytis cinerea), sclerotinia sclerotiorum, black rot (Sclerotium cepivorum), white mold (Sclerotium rolfsii), seedling blight (Pythium aphanidermatum, Pythium irregulare, Pythium ultimum); diseases of radishes: black spot (Alternaria brassicicola); diseases of sweet potatoes: vine wilt (Fusarium oxysporum f. sp. batatas), basal rot (Diaporthe destruens), black spot (Ceratocystis fimbriata); diseases of turfgrass: dollar spot (Sclerotinia homoeocarpa), brown patch, large patch (Rhizoctonia solani), red blight (Pythium aphanidermatum), anthracnose (Colletotrichum). caudatum); Banana diseases: Sigatoka disease (Mycosphaerella fijiensis, Mycosphaerella musicola); Lentil diseases: Ascochyta disease (Ascochyta lentis); Chickpea diseases: Ascochyta disease (Ascochyta rabiei); Bell pepper diseases: Anthracnose (Colletotrichum scovillei), powdery mildew (Leveillula taurica), white mold (Sclerotium rolfsii); Mango diseases: Anthracnose (Colletotrichum acutatum); Cacao diseases: Witches' broom disease (Moniliophthora perniciosa), Frosty pod rot (Moniliophthora roreri); Pecan diseases: Black spot disease (Venturia effusa); Lychee diseases: Downy mildew (Peronophythora litchii), Anthracnose (Colletotrichum siemense); Fruit tree diseases: White root rot (Rosellinia necatrix), Purple root rot (Helicobasidium mompa);Diseases of fruits such as apples and pears after harvest: Mucor piriformis; seed diseases or diseases of the early growth stage caused by genera such as Aspergillus, Penicillium, Fusarium, Gibberella, Tricoderma, Thielaviopsis, Rhizopus, Mucor, Corticium, Phoma, Rhizoctonia, and Diplodia; Viral diseases: Big vein disease of lettuce transmitted by Olpidium brassicae, viral diseases of various crops transmitted by the genus Polymyxa (e.g., Polymyxa betae and Polymyxa graminis); Diseases caused by bacteria: Bacterial blight of rice (Burkholderia plantarii), blotch of rice (Pantoea ananatis), bacterial leaf blight of rice (Xanthomonas oryzae pv. Oryzae, bacterial leaf spot of cucumber (Pseudomonas syringae pv. Lachrymans), bacterial wilt of eggplant (Ralstonia solanacearum), citrus canker (Xanthomonas citri), soft rot of Chinese cabbage (Erwinia carotovora), potato scab (Streptomyces scabiei), potato blackfoot (Pectobacterium carotovorum, Dickeya sp.), bacterial spot of peach (Pseudomona syringae, Erwinia nigrifluens, Xanthomonas campestris), citrus canker of plum (Pseudomonas syringae pv. Morsprunorum, Erwinia sp.), Goss's wilt of corn (Clavibacter michiganensis), piercing disease of grapes, olives, peaches, etc. (Xylella Agrobacterium tumefaciens (also known as fastidiosa), a crown gall disease affecting rose family plants such as apples, peaches, and cherries.

[0043] Soybean rust fungus with the F129L amino acid substitution in the mitochondrial cytochrome b protein is a soybean rust fungus (scientific name: Phakopsora pachyrhizi) that has a mutation in the mitochondrial cytochrome b gene that codes for the mitochondrial cytochrome protein, and as a result of this mutation, the F129L amino acid substitution occurs, making it resistant to the QoI fungicide.

[0044] The plant disease control method of the present invention is carried out by treating a plant or the soil in which the plant is cultivated with an effective amount of the present compound, the compound of the present invention, or composition A. Examples of treatment methods include treatment of stems and leaves, soil treatment, and seed treatment.

[0045] The present compound, the compound of the present invention, or composition A is typically used by mixing an inert carrier such as a solid carrier or liquid carrier with a surfactant, and adding formulation aids such as binders, dispersants, and stabilizers as needed, to formulate it into aqueous suspensions, oily suspensions, oils, emulsions, microemulsions, microcapsules, wettable powders, wettable granules, powders, granules, etc. It is not limited to these formulations, but can also be used in formulations described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517. These formulations typically contain the present compound, the compound of the present invention, or composition A in an amount of 0.0001% to 99% by weight.

[0046] Examples of solid carriers include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powders and granules of chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0047] Examples of liquid carriers include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0048] Examples of surfactants include nonionic surfactants (polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers, polyethylene glycol fatty acid esters, etc.) and anionic surfactants (alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, etc.).

[0049] Other pharmaceutical additives include, for example, binders, dispersants, colorants, and stabilizers. Specifically, examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), acidic isopropyl phosphate, and dibutylhydroxytoluene.

[0050] Furthermore, adjuvants can be used as components to enhance or assist the efficacy of this compound, the compound of the present invention, or composition A. Specifically, these include AgriDex®, Induce®, Gramin S®, Genamin T 200BM®, Silwet L77®, Nimbus®, Assist®, Aureo®, Iharol Gold®, BreakThru®, Sundance II®, Lutensol A8®, NP-7®, Triton®, Nufilm®, Emulgator NP7®, Emulad®, TRITON X 45®, AGRAL 90®, AGROTIN®, ARPON®, EnSpray N®, BANOLE®, Ochima®, Agris®, AMS (Ammonium Sulfate), UAN (Urea Ammonium) Examples include Nitrate (ammonium urea nitrate), AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), and Penetrator.

[0051] In the present invention, "plant" includes the whole plant and specific parts of the plant. Examples of specific parts of a plant include stems and leaves, flowers, spikes, fruits, trunks, branches, canopies, seeds, vegetative reproductive organs, and seedlings.

[0052] Vegetative reproductive organs refer to parts of a plant, such as roots, stems, and leaves, that have the ability to grow when separated from the main plant and placed in the soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and cane cuttings are also called bulbils, and are divided into broad buds and bulbils. Vines refer to shoots (a general term for leaves and stems) of plants such as sweet potatoes and yams. Bulbs, corms, tubers, rhizomes, cane cuttings, propagules, or tubers are collectively called bulbs. Potato cultivation begins with planting tubers in the soil, and the tubers used are generally called seed potatoes.

[0053] Seedlings include seedlings and saplings.

[0054] A method for controlling plant diseases by applying an effective amount of this compound, the compound of the present invention, or composition A to the soil includes, for example, applying an effective amount of this compound, the compound of the present invention, or composition A to the soil before or after planting plants. More specifically, for example, planting hole treatment (spraying in planting holes, mixing in planting hole treatment soil), base treatment (spraying around the base of the plant, mixing around the base of the plant, drenching around the base of the plant, base treatment in the latter half of the seedling stage), furrow treatment (spraying in planting furrows, mixing in planting furrow soil), furrow treatment (spraying in furrows, mixing in furrow soil, spraying in furrows during the growing season), furrow treatment at sowing (spraying in furrows at sowing, mixing in furrow soil at sowing), overall treatment (spraying in all areas of soil, mixing in all areas of soil), side-dressing treatment, water surface treatment (application to the water surface, application to the water surface after flooding), other soil application treatments (foliar application of granular fertilizer during the growing season, application under the tree canopy or around the main trunk, application to the soil surface, mixing to the soil surface, spraying in planting holes, application to the soil surface on ridges, application between plants), and so on. Other drenching treatments include soil drenching, seedling stage drenching, chemical injection treatment, drenching at the base of the plant, chemical drip irrigation, and chemigation. Seedling tray treatments include seedling tray spraying, seedling tray drenching, and seedling tray watering. Seedling tray treatments include seedling tray spraying, seedling tray drenching, and seedling tray watering. Seedbed treatments include seedbed spraying, seedbed drenching, watered seedbed spraying, and seedling soaking. Seedbed soil mixing treatments include seedbed soil mixing, seedbed soil mixing before sowing, spraying before covering with soil at sowing, spraying after covering with soil at sowing, and soil mixing with covering soil. Other treatments include growing soil mixing, tilling, topsoil mixing, soil mixing at the rainwater drainage area, planting location treatment, granular flower cluster spraying, and paste fertilizer mixing.

[0055] Seed treatments include, for example, treatment of seeds or vegetative reproductive organs with the present compound, the compound of the present invention, or composition A. More specifically, these include, for example, a spray treatment in which a suspension of the present compound, the compound of the present invention, or composition A is sprayed in a mist onto the surface of the seed or vegetative reproductive organ; a coating treatment in which the present compound, the compound of the present invention, or composition A is applied to the seed or vegetative reproductive organ; an immersion treatment in which the seed or vegetative reproductive organ is immersed in a solution of the present compound, the compound of the present invention, or composition A for a certain period of time; and a method of coating the seed or vegetative reproductive organ with a carrier containing the present compound, the compound of the present invention, or composition A (film coating treatment, pellet coating treatment, etc.). Seed potatoes are a particularly good example of the vegetative reproductive organs mentioned above. In the present invention, a seed or vegetative reproductive organ holding the present compound, the compound of the present invention, or composition A means a seed or vegetative reproductive organ in which the present compound, the compound of the present invention, or composition A is attached to its surface. The above seed or vegetative reproductive organ holding the present compound, the compound of the present invention, or composition A may have other materials attached to it before or after the present compound, the compound of the present invention, or composition A is attached to it. Furthermore, when composition A adheres to the surface of a seed or vegetative reproductive organ in a layer, the layer consists of one or more layers. If it consists of multiple layers, each layer either contains one or more active ingredients, or consists of a layer containing one or more active ingredients and a layer not containing any active ingredients. Seeds or vegetative reproductive organs holding this compound, the compound of the present invention, or composition A can be obtained, for example, by applying a formulation containing this compound, the compound of the present invention, or composition A to the seed or vegetative reproductive organ using the seed treatment method described above.

[0056] The application rate of this compound, the compound of the present invention, or composition A varies depending on weather conditions, formulation form, application timing, application method, application location, target disease, target crop, etc. However, in the case of foliar treatment or soil treatment, the application rate is 1000 m² of plant cultivation area. 2The amount is usually 1g to 500g per unit. In the case of seed treatment, the amount of this compound, the compound of the present invention, or composition A per 1kg of seeds is usually 0.001g to 100g. When this compound, the compound of the present invention, or composition A is formulated as an emulsion, wettable powder, flowable formulation, etc., it is usually diluted with water to an active ingredient concentration of 0.01ppm to 10000ppm before application, while powders, granules, etc., are usually applied as is.

[0057] This compound, the compound of the present invention, or composition A can be used as a control agent for plant diseases in agricultural land such as fields, paddy fields, lawns, and orchards. Examples of plants include the following:

[0058] Corn (Horsetail, hard-grain, soft-grain, popping, glutinous, sweet, field corn), rice (long-grain, short-grain, medium-grain, Japonica, tropical Japonica, Indica, Javanica, paddy rice, upland rice, floating rice, direct seeding, transplanting, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat, club wheat, each with winter wheat type and spring wheat type), barley (two-row barley (= malting barley), six-row barley, hulless barley, glutinous barley, each with winter barley type and spring barley type), rye (winter rye type, spring rye) (Types), Triticare (winter Triticare type, spring Triticare type), oats (winter oat type, spring oat type), sorghum, cotton (Upland variety, Pima variety), soybeans (full-seed harvest varieties, edamame varieties, green-harvested varieties, each with infinite growth type, finite growth type, and semi-finite growth type), peanuts, potatoes (tetraploid, diploid, true seed varieties), buckwheat, sugar beets (for sugar production, for animal feed, root vegetables, leafy vegetables, fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflowers (for oil extraction, food, ornamental), sugarcane, tobacco, tea plants, mulberry, eggplant Vegetables from the genus Aceraceae (eggplant, tomato, bell pepper, chili pepper, etc.), Cucurbitaceae (cucumber, pumpkin, zucchini, watermelon, melon, etc.), Brassicaceae (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard greens, broccoli, cauliflower, etc.), Asteraceae (burdock, garland chrysanthemum, artichoke, lettuce, etc.), Liliaceae (leek, onion, garlic, asparagus, etc.), Apiaceae (carrot, parsley, celery, angelica tree, etc.), Chenopodiaceae (spinach, Swiss chard, etc.), Lamiaceae (perilla, mint, basil, etc.), strawberry Sweet potatoes, Japanese yams, taro, pomelo (apples, European pears, Japanese pears, Chinese pears, quince, marzipan, etc.), drupes (peaches, plums, nectarines, apricots, cherries, prunes, etc.), citrus fruits (Unshu mandarins, oranges, lemons, limes, grapefruit, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates,Coconut palms, ornamental plants, forest plants, grasses, and pasture grasses.

[0059] The plants listed above are not limited to any commonly cultivated varieties. These include plants that can be produced through natural cross-pollination, plants that can arise from spontaneous mutation, F1 hybrid plants, and genetically modified crops. Examples of genetically modified crops include plants conferred with resistance to HPPD (4-hydroxyphenylpyruvate dioxygenase enzyme) inhibitors such as isoxaflutol, ALS (acetolactate synthase) inhibitors such as imazetapyr and thifensulfuron-methyl, EPSP (5-enolpyruvirshikimate-3-phosphate synthase) inhibitors, glutamine synthase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil, or herbicides such as dicamba; plants capable of synthesizing selective toxins known from the Bacillus genus, such as Bacillus thuringiensis; and plants that can be conferred with specific insecticidal activity by synthesizing gene fragments that partially match endogenous genes derived from harmful insects and inducing gene silencing (RNAi; RNA interference) within the target harmful insect.

[0060] The present invention will be described in more detail below with reference manufacturing examples, formulation examples, and test examples, but the present invention is not limited to these examples.

[0061] In this specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, iPr represents an isopropyl group, cPr represents a cyclopropyl group, Bu represents a butyl group, cBu represents a cyclobutyl group, iBu represents an isobutyl group, sBu represents a sec-butyl group, tBu represents a tert-butyl group, Ph represents a phenyl group, cPen represents a cyclopentyl group, cHex represents a cyclohexyl group, and pyridin-3-yl represents a pyridine-3-yl group. If these groups have substituents, the substituents are indicated before the symbols of these groups along with their substitution positions. For example, 4-OMe-Ph represents a 4-methoxyphenyl group, and 3,5-Me2-Ph represents a 3,5-dimethylphenyl group.

[0062] When the physical properties of a compound are measured by liquid chromatography / mass spectrometry (hereinafter referred to as LC / MS), the measured molecular ion value [M + H] + or [M-H] - The retention time (hereinafter referred to as RT) is also noted. The conditions for liquid chromatography (hereinafter referred to as LC) and mass spectrometry (hereinafter referred to as MS) are as follows: [LC conditions] Column: L-column2 ODS, inner diameter 4.6 mm, length 30 mm, particle size 3 μm (manufactured by the Chemicals Evaluation and Research Institute) UV measurement wavelength: 254 nm Mobile phase: Solution A: 0.1% formic acid aqueous solution, Solution B: 0.1% formic acid acetonitrile Flow rate: 2.0 mL / min Pump: LC-20AD (manufactured by Shimadzu Corporation) 2 units (high pressure gradient) Gradient conditions: The solution is delivered with the concentration gradient described in [Table LC1].

[0063]

[0064] [MS conditions] Detector: LCMS-2020 (manufactured by Shimadzu Corporation) Ionization method: DUIS (ESI, APCI)

[0065] First, we will show an example of the preparation of this compound (including the compound of the present invention). Preparation Example 1 A mixture of 0.18 g, 0.30 g of intermediate 1 (1-cyclopentenylboronic acid), 0.04 g of {1,1'-bis(diphenylphosphino)ferrocene}dichloropalladium(II)), 0.43 g of tripotassium phosphate, 5.0 mL of DME, and 0.5 mL of water was stirred at 80°C for 4 hours. After cooling to room temperature, the resulting mixture was concentrated under reduced pressure, and the resulting residue was subjected to silica gel column chromatography to obtain 0.17 g of compound 1, shown by the following formula. This compound 1: 1 H-NMR (CDCl3) δ: 7.04-7.00 (2H, m), 6.29-6.28 (1H, m), 4.34 (2H, s), 3.00 (2H, q), 2.67-2.62 (2H, m), 2.59-2.53 (2H, m), 2.08-2.00 (2H, m), 1.42 (3H, t).

[0066] Manufacturing Example 1-1 The compound manufactured according to Manufacturing Example 1 and its physical properties are shown below. Formula (I-1P) In the compound represented by (hereinafter referred to as compound (I-1P)), R 3p , R 4p , R 5p , R 6p , R 7p , and Z 1p A compound whose combination is one of the combinations listed in [Table A-1].

[0067] This compound 2: 1 H-NMR (CDCl3) δ: 7.62-7.58 (2H, m), 7.50-7.47 (2H, m), 7.46-7.42 (1H, m), 7.37-7.32 (1H, m), 7.25-7.21 (1H, m), 7.19-7.14 (1H, m), 4.26 (2H, s), 2.89-2.83 (2H, m), 1.93-1.85 (2H, m), 1.06 (3H, t). Compound 3: 1 H-NMR (CDCl3) δ: 7.57-7.53 (2H, m), 7.50-7.40 (3H, m), 7.25-7.19 (2H, m), 4.40 (2H, s), 3.05 (2H, q), 1.45 (3H, t). Compound 4: 1 H-NMR (CDCl3) δ: 7.45-7.36 (2H, m), 7.28-7.15 (4H, m), 4.41 (2H, s), 3.06 (2H, q), 1.46 (3H, t). Compound 5: 1 H-NMR (CDCl3) δ: 7.99-7.96 (1H, m), 7.59-7.56 (2H, m), 7.52-7.51 (2H, m), 6.95 (1H, dd), 4.26 (2H, s), 2.89-2.85 (2H, m), 1.92-1.88 (2H, m), 1.07 (3H, t). Compound 6: 1 H-NMR (CDCl3) δ: 7.99-7.96 (1H, m), 7.21-7.19 (2H, m), 6.99-6.97 (1H, m), 4.40 (2H, s), 3.09-3.03 (2H, m), 1.46 (3H, t).

[0068] Preparation Example 2 Under a nitrogen atmosphere, 0.30 g of intermediate 4 and 3 mL of ethanol were mixed together, and 0.17 g of sodium cyclopropanesulfinate was added at room temperature. The mixture was stirred at 70°C for 3 hours. Water was added to the resulting mixture, and the precipitated solid was filtered off. The obtained solid was subjected to silica gel column chromatography to obtain 0.20 g of the compound 7 shown by the following formula. This compound 7: 1 H-NMR (CDCl3) δ: 7.45-7.37 (2H, m), 7.27-7.25 (1H, m), 7.24-7.16 (3H, m), 4.48 (2H, s), 2.48-2.44 (1H, m), 1.22-1.18 (2H, m), 1.07-1.02 (2H, m).

[0069] Preparation Example 3 Under a nitrogen atmosphere, 0.60 g of intermediate 4, 0.55 g of potassium carbonate, and 4 mL of DMF were mixed together, and 0.21 mL of propanethol was added at room temperature and the mixture was stirred for 6 hours at room temperature. Water was added to the resulting mixture and extracted with ethyl acetate. The resulting organic layer was washed with saturated brine and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.47 g of compound 8, represented by the following formula. This compound 8: 1 H-NMR (CDCl3) δ: 7.44-7.33 (2H, m), 7.25-7.08 (4H, m), 3.79 (2H, s), 2.54 (2H, t), 1.71-1.61 (2H, m), 0.99 (3H, t).

[0070] Manufacturing Example 3-1 The compound manufactured in accordance with Manufacturing Example 3 and its physical properties are shown below. This compound 9: 1 H-NMR (CDCl3) δ: 7.43-7.39 (1H, m), 7.38-7.33 (1H, m), 7.24-7.21 (1H, m), 7.19-7.14 (1H, m), 7.13-7.09 (2H, m), 3.79 (2H, s), 2.56 (2H, t), 1.64-1.58 (2H, m), 1.44-1.37 (2H, m), 0.91 (3H, t).

[0071] Preparation Example 4 A mixture of 0.35 g of Compound 8 and 10 mL of chloroform was mixed with 0.44 g of mCPBA (75% by weight purity, 25% by weight water content) at 0°C and stirred at room temperature for 1.5 hours. 10 mL of saturated sodium thiosulfate aqueous solution and 10 mL of saturated sodium bicarbonate aqueous solution were sequentially added to the resulting mixture and stirred for 1 hour, after which it was extracted with chloroform. The resulting organic layer was sequentially washed with saturated sodium bicarbonate aqueous solution and saturated brine, and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.16 g of Compound 10 and 0.20 g of Compound 11, which are shown in the following formula. This compound 10: 1 H-NMR (CDCl3) δ: 7.44-7.38 (2H, m), 7.27-7.16 (4H, m), 4.40 (2H, s), 3.03-2.99 (2H, m), 1.98-1.91 (2H, m), 1.10 (3H, t).

[0072] This compound 11: 1 H-NMR (CDCl3) δ: 7.44-7.36 (2H, m), 7.26-7.23 (1H, m), 7.21-7.16 (3H, m), 4.17 (1H, d), 4.11 (1H, d), 2.80-2.73 (1H, m), 2.70-2.62 (1H, m), 1.94-1.79 (2H, m), 1.09 (3H, t).

[0073] Manufacturing Example 4-1 The compound manufactured in accordance with Manufacturing Example 4 and its physical properties are shown below. This compound 12: 1 H-NMR (CDCl3) δ: 7.43-7.38 (2H, m), 7.27-7.17 (4H, m), 4.40 (2H, s), 3.05-3.01 (2H, m), 1.92-1.85 (2H, m), 1.53-1.46 (2H, m), 0.97 (3H, t).

[0074] This compound 13: 1H-NMR (CDCl3) δ: 7.43-7.36 (2H, m), 7.26-7.22 (1H, m), 7.21-7.15 (3H, m), 4.17 (1H, d), 4.11 (1H, d), 2.80-2.68 (2H, m), 1.88-1.74 (2H, m), 1.58-1.42 (2H, m), 0.96 (3H, t).

[0075] Preparation Example 5 Under a nitrogen atmosphere, a mixture of 0.14 g of intermediate 5, 0.24 g of potassium carbonate, 0.10 mL of bromocyclopentane, and 4 mL of DMF was stirred at 70°C for 6 hours. After cooling to room temperature, water was added to the resulting mixture and extracted with ethyl acetate. The resulting organic layer was washed with saturated brine and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.04 g of compound 14, shown by the following formula. This compound 14: 1 H-NMR (CDCl3) δ: 6.50-6.46 (2H, m), 4.71-4.67 (1H, m), 4.25 (2H, s), 2.98 (2H, q), 1.96-1.72 (6H, m), 1.64-1.60 (2H, m), 1.40 (3H, t).

[0076] Intermediate Production Example 1 The compound produced in accordance with Production Example 2 and its physical properties are shown below. Intermediate 1: 1 H-NMR (CDCl3) δ: 7.23-7.18 (2H, m), 4.31 (2H, s), 3.02 (2H, q), 1.44 (3H, t).

[0077] Intermediate 2: 1 H-NMR (CDCl3) δ: 7.56-7.52 (2H, m), 7.31-7.27 (2H, m), 4.16 (2H, s), 2.83-2.81 (2H, m), 1.90-1.81 (2H, m), 1.05 (3H, t).

[0078] Intermediate Preparation Example 2 A mixture of 8.16 g of 2-fluorophenylboronic acid, 10.0 g of (4-bromo-2,6-difluorophenyl)methanol, 1.0 g of {1,1'-bis(diphenylphosphino)ferrocene}dichloropalladium(II), 19.0 g of tripotassium phosphate, 100 mL of DME, and 10 mL of water was stirred at 82°C for 8 hours. After cooling to room temperature, the resulting mixture was concentrated under reduced pressure, and the resulting residue was subjected to silica gel column chromatography to obtain 10.4 g of intermediate 3, shown by the following formula. Intermediate 3: 1 H-NMR (CDCl3) δ: 7.42-7.35 (2H, m), 7.25-7.21 (1H, m), 7.20-7.10 (3H, m), 4.83 (2H, d), 1.97-1.89 (1H, m).

[0079] Intermediate Preparation Example 3 Under a nitrogen atmosphere, 4.5 mL of phosphorus tribromide was added dropwise to a mixture of 7.5 g of intermediate 3 and 80 mL of chloroform at 0°C, and the mixture was stirred at room temperature for 2 hours. At the same temperature, the resulting mixture was added dropwise to saturated sodium bicarbonate solution. The resulting mixture was extracted with chloroform, the resulting organic layer was washed with saturated brine, and concentrated under reduced pressure to obtain 3.42 g of intermediate 4, which is shown by the following formula. Intermediate 4: 1 H-NMR (CDCl3) δ: 7.45-7.34 (2H, m), 7.25-7.10 (4H, m), 4.57 (2H, s).

[0080] Intermediate Preparation Example 4 A mixture of 0.18 g of bis(pinacolato)diborone, 0.18 g of intermediate 1, 0.03 g of {1,1'-bis(diphenylphosphino)ferrocene}dichloropalladium(II), 0.13 g of potassium acetate, and 4.0 mL of DMSO was stirred at 80°C for 7 hours. After cooling to room temperature, water was added to the resulting mixture and extracted with ethyl acetate. The resulting organic layer was washed with saturated brine and concentrated under reduced pressure. To the resulting residue, 2.0 mL of acetonitrile, 1.0 mL of ethanol, and 2.0 mL of water were added at room temperature. 0.13 g of mCPBA (75% by weight purity, 25% by weight water content) was added to the resulting mixture at 0°C and stirred at room temperature for 1.5 hours. Sodium thiosulfate aqueous solution and sodium bicarbonate aqueous solution were sequentially added to the resulting mixture and stirred at room temperature for 2 hours. The resulting mixture was extracted with ethyl acetate. The obtained organic layer was sequentially washed with saturated sodium bicarbonate aqueous solution and saturated brine, dried over anhydrous sodium sulfate, and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.14 g of intermediate 5, shown by the following formula. Intermediate 5: LC / MS: 235[MH] - , RT = 1.213 minutes

[0081] The compound of the present invention and an example of the compound produced in accordance with the above manufacturing method and example are shown below. Formula (A-1) [In the ceremony, Z 1x This represents one of formulas L1 to L39. (However, ● represents R) 4x (This represents the bonding site with the benzene ring that has been substituted.)

[0082]

[0083]

[0084] In the compound represented by ] (hereinafter referred to as compound (A-1)), R 3x However, it is an ethyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 1xThe base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in Combination A (hereinafter referred to as Compound Group SX1).

[0085] Combination A consists of substituent numbers A1 to A1283. Substituents A1 to A1283 are the Z substituents in compound (A-1). 1x The relationship and Z 1x substituent R corresponding to the structure X8 , R X9 , R X10 and R X11 This represents a combination of [substituent number; Z], and is described below as follows: 1x ;R X8 , R X9 , R X10 , R X11 ] is written as. For example, substituent number A2 is Z 1x L1 is R X8 is a methyl group, R X9 , R X10 and R X11means a combination in which it is a hydrogen atom. Combination A: [A1;L1;H,H,H,H],[A2;L1;Me,H,H,H],[A3;L1;Et,H,H,H],[A4;L1;Pr,H,H,H],[A5;L1;iPr,H,H,H],[A6;L1;tBu,H,H,H],[A7;L1;OMe,H,H,H],[A8;L1;OEt,H,H,H],[A9;L1;OPr,H,H,H],[A10;L1;OiPr,H,H,H],[A11;L1;CF3,H,H,H],[A12;L1;CF2H,H,H,H],[A13;L1;CFH2,H,H,H],[A14;L1;F,H,H,H],[A15;L1;Cl,H,H,H],[A16;L1;Br,H,H,H],[A17;L1;CN,H,H,H],[A18;L1;cPr,H,H,H],[A19;L1;H,Me,H,H],[A20;L1;H,Et,H,H],[A21;L1;H,Pr,H,H],[A22;L1;H,iPr,H,H],[A23;L1;H,tBu,H,H],[A24;L1;H,OMe,H,H],[A25;L1;H,OEt,H,H],[A26;L1;H,OPr,H,H],[A27;L1;H,OiPr,H,H],[A28;L1;H,CF3,H,H],[A29;L1;H,CF2H,H,H],[A30;L1;H,CFH2,H,H],[A31;L1;H,F,H,H],[A32;L1;H,Cl,H,H],[A33;L1;H,Br,H,H],[A34;L1;H,CN,H,H],[A35;L1;H,cPr,H,H],[A36;L1;H,H,Me,H],[A37;L1;H,H,Et,H],[A38;L1;H,H,Pr,H],[A39;L1;H,H,iPr,H],[A40;L1;H,H,tBu,H],[A41;L1;H,H,OMe,H],[A42;L1;H,H,OEt,H],[A43;L1;H,H,OPr,H],[A44;L1;H,H,OiPr,H],[A45;L1;H,H,CF3,H],[A46;L1;H,H,CF2H,H],[A47;L1;H,H,CFH2,H],[A48;L1;H,H,F,H],[A49;L1;H,H,Cl,H],[A50;L1;H,H,Br,H],[A51;L1;H,H,CN,H], [A52;L1;H,H,cPr,H],[A53;L1;H,H,H,Me],[A54;L1;H,H,H,Et],[A55;L1;H,H,H,Pr],[A56;L1;H,H,H,iPr],[A57;L1;H,H,H,tBu],[A58;L1;H,H,H,OMe],[A59;L1;H,H,H,OEt],[A60;L1;H,H,H,OPr],[A61;L1;H,H,H,OiPr],[A62;L1;H,H,H,CF3],[A63;L1;H,H,H,CF2H],[A64;L1;H,H,H,CFH2],[A65;L1;H,H,H,F],[A66;L1;H,H,H,Cl],[A67;L1;H,H,H,Br],[A68;L1;H,H,H,CN],[A69;L1;H,H,H,cPr],[A70;L1;F,F,H,H],[A71;L1;F,H,F,H],[A72;L1;F,H,H,F],[A73;L1;H,F,F,H],[A74;L1;H,F,H,F],[A75;L1;H,H,F,F],[A76;L1;Cl,Cl,H,H],[A77;L1;Cl,H,Cl,H],[A78;L1;Cl,H,H,Cl],[A79;L1;H,Cl,Cl,H],[A80;L1;H,Cl,H,Cl],[A81;L1;H,H,Cl,Cl],[A82;L2;H,H,H,H],[A83;L2;Me,H,H,H],[A84;L2;Et,H,H,H],[A85;L2;Pr,H,H,H],[A86;L2;iPr,H,H,H],[A87;L2;tBu,H,H,H],[A88;L2;OMe,H,H,H],[A89;L2;OEt,H,H,H],[A90;L2;OPr,H,H,H],[A91;L2;OiPr,H,H,H],[A92;L2;CF3,H,H,H],[A93;L2;CF2H,H,H,H],[A94;L2;CFH2,H,H,H],[A95;L2;F,H,H,H],[A96;L2;Cl,H,H,H],[A97;L2;Br,H,H,H],[A98;L2;CN,H,H,H],[A99;L2;cPr,H,H,H],[A100;L2;H,Me,H,H],[A101;L2;H,Et,H,H],[A102;L2;H,Pr,H,H],[A103;L2;H,iPr,H,H],[A104;L2;H,tBu,H,H],[A105;L2;H,OMe,H,H],[A106;L2;H,OEt,H,H],[A107;L2;H,OPr,H,H],[A108;L2;H,OiPr,H,H],[A109;L2;H,CF3,H,H],[A110;L2;H,CF2H,H,H],[A111;L2;H,CFH2,H,H],[A112;L2;H,F,H,H],[A113;L2;H,Cl,H,H],[A114;L2;H,Br,H,H],[A115;L2;H,CN,H,H],[A116;L2;H,cPr,H,H],[A117;L2;H,H,Me,H],[A118;L2;H,H,Et,H],[A119;L2;H,H,Pr,H],[A120;L2;H,H,iPr,H],[A121;L2;H,H,tBu,H],[A122;L2;H,H,OMe,H],[A123;L2;H,H,OEt,H],[A124;L2;H,H,OPr,H],[A125;L2;H,H,OiPr,H],[A126;L2;H,H,CF3,H],[A127;L2;H,H,CF2H,H],[A128;L2;H,H,CFH2,H],[A129;L2;H,H,F,H],[A130;L2;H,H,Cl,H],[A131;L2;H,H,Br,H],[A132;L2;H,H,CN,H],[A133;L2;H,H,cPr,H],[A134;L2;H,H,H,Me],[A135;L2;H,H,H,Et],[A136;L2;H,H,H,Pr],[A137;L2;H,H,H,iPr],[A138;L2;H,H,H,tBu],[A139;L2;H,H,H,OMe],[A140;L2;H,H,H,OEt],[A141;L2;H,H,H,OPr],[A142;L2;H,H,H,OiPr],[A143;L2;H,H,H,CF3],[A144;L2;H,H,H,CF2H],[A145;L2;H,H,H,CFH2],[A146;L2;H,H,H,F],[A147;L2;H,H,H,Cl],[A148;L2;H,H,H,Br],[A149;L2;H,H,H,CN],[A150;L2;H,H,H,cPr],[A151;L2;F,F,H,H],[A152;L2;F,H,F,H],[A153;L2;F,H,H,F],[A154;L2;H,F,F,H],[A155;L2;H,F,H,F],[A156;L2;H,H,F,F],[A157;L2;Cl,Cl,H,H],[A158;L2;Cl,H,Cl,H],[A159;L2;Cl,H,H,Cl],[A160;L2;H,Cl,Cl,H],[A161;L2;H,Cl,H,Cl],[A162;L2;H,H,Cl,Cl],[A163;L3 ;H,H,H,H, H,H,H],[A170;L3;OEt,H,H,H],[A171;L3;OPr,H,H,H],[A172;L3;OiPr,H,H,H],[A173;L3;CF3,H,H,H],[A174;L3;CF2H,H,H,H],[A175;L3;CFH2,H,H,H],[A176;L3;F,H,H,H],[A177;L3;Cl,H,H,H],[A178;L3;Br,H,H,H],[A179;L3;CN,H,H,H],[A180;L3;cPr,H,H,H],[A181;L3;H,Me, H,H],[A182;L3;H,Et,H,H],[A183;L3;H,Pr,H,H],[A184;L3;H,iPr,H,H],[A185;L3;H,tBu,H,H],[A186;L3;H,OMe,H,H],[A187;L3;H,OEt,H,H],[A188;L3;H,OPr,H,H],[A189;L3;H,OiPr,H,H],[A190;L3;H,CF3,H,H],[A191;L3;H,CF2H,H,H],[A192;L3;H,CFH2,H,H],[A193;L3;H,F, H,H]. . [A206;L3;H,H,OiPr,H],[A207;L3;H,H,CF3,H],[A208;L3;H,H,CF2H,H],[A209;L3;H,H,CFH2,H],[A210;L3;H,H,F,H],[A211;L3;H,H,Cl,H],[A212;L3;H,H,Br,H],[A213;L3;H,H,CN,H],[A214;L3;H,H,cPr,H],[A215;L3;H,H,H,Me],[A216;L3;H,H,H,Et],[A217;L3;H,H,H,Pr],[A218;L3;H,H,H,iPr],[A219;L3;H,H,H,tBu],[A 220;L3;H,H,H,OMe],[A221;L3;H,H,H,OEt],[A222;L3;H,H,H,OPr],[A223;L3;H,H,H,OiPr],[A224;L3;H,H,H,CF3],[A225;L3;H,H,H,CF2H],[A226;L3;H,H,H,CFH2],[A227;L3;H,H,H,F],[A228;L3;H,H,H,Cl],[A229;L3;H,H,H,Br],[A230;L3;H,H,H,CN],[A231;L3;H,H,H,cPr],[A232;L3;F, [F,H,H],[A233;L3;F,H,F,H],[A234;L3;F,H,H,F],[A235;L3;H,F,F,H],[A236;L3;H,F,H,F],[A237;L3;H,H,F,F],[A238;L3;Cl,Cl,H,H],[A239;L3;Cl,H,Cl,H],[A240;L3;Cl,H,H,Cl],[A241;L3;H,Cl,Cl,H],[A242;L3;H,Cl,H,Cl],[A243;L3;H,H,Cl,Cl],[A244;L4;H,H,H,-],[A245;L4;Me, H,H,-],[A246;L4;Et,H,H,-],[A247;L4;Pr,H,H,-],[A248;L4;iPr,H,H,-],[A249;L4;OMe,H,H,-],[A250;L4;CF3,H,H,-],[A251;L4;F,H,H,-], [A252;L4;Cl,H,H,-],[A253;L4;Br,H,H,-],[A254;L4;CN,H,H,-],[A255;L4;cPr,H,H,-],[A256;L4;H,Me,H,-],[A257;L4;H,Et,H,-],[A258;L4;H,Pr,H,-],[A259;L4;H,iPr,H,-],[A260;L4;H,OMe,H,-],[A261;L4;H,CF3,H,-],[A262;L4;H,F,H,-],[A263;L4;H,Cl,H,-],[A264;L4;H,Br,H,-],[A265;L4;H,CN,H,-],[A266;L4;H,cPr,H,-],[A267;L4;H,H,Me,-],[A268;L4;H,H,Et,-],[A269;L4;H,H,Pr,-],[A270;L4;H,H,iPr,-],[A271;L4;H,H,OMe,-],[A272;L4;H,H,CF3,-],[A273;L4;H,H,F,-],[A274;L4;H,H,Cl,-],[A275;L4;H,H,Br,-],[A276;L4;H,H,CN,-],[A277;L4;H,H,cPr,-],[A278;L5;H,H,H,-],[A279;L5;Me,H,H,-],[A280;L5;Et,H,H,-],[A281;L5;Pr,H,H,-],[A282;L5;iPr,H,H,-],[A283;L5;OMe,H,H,-],[A284;L5;CF3,H,H,-],[A285;L5;F,H,H,-],[A286;L5;Cl,H,H,-],[A287;L5;Br,H,H,-],[A288;L5;CN,H,H,-],[A289;L5;cPr,H,H,-],[A290;L5;H,Me,H,-],[A291;L5;H,Et,H,-],[A292;L5;H,Pr,H,-],[A293;L5;H,iPr,H,-],[A294;L5;H,OMe,H,-],[A295;L5;H,CF3,H,-],[A296;L5;H,F,H,-],[A297;L5;H,Cl,H,-],[A298;L5;H,Br,H,-],[A299;L5;H,CN,H,-],[A300;L5;H,cPr,H,-],[A301;L5;H,H,Me,-],[A302;L5;H,H,Et,-],[A303;L5;H,H,Pr,-],[A304;L5;H,H,iPr,-],[A305;L5;H,H,OMe,-],[A306;L5;H,H,CF3,-],[A307;L5;H,H,F,-],[A308;L5;H,H,Cl,-],[A309;L5;H,H,Br,-],[A310;L5;H,H,CN,-],[A311;L5;H,H,cPr,-],[A312;L6;H,H,H,-],[A313;L6;Me,H,H,-],[A314;L6;Et,H,H,-],[A315;L6;Pr,H,H,-],[A316;L6;iPr,H,H,-],[A317;L6;OMe,H,H,-],[A318;L6;CF3,H,H,-],[A319;L6;F,H,H,-],[A320;L6;Cl,H,H,-],[A321;L6;Br,H,H,-],[A322;L6;CN,H,H,-],[A323;L6;c 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. [A913;L23;CN,H,-,-],[A914;L23;cPr,H,-,-],[A915;L23,CF2H,H,-,-],[A916;L23;H,Me,-,-],[A917;L23;H,Et,-,-],[A918;L23;H,Pr,-,-],[A919;L23;H,iPr,-,-],[A920;L23;H,Bu,-,-],[A921;L23,H,tBu,-,-],[A922;L23,H,CH2(iPr),-,-],[A923;L23;H,OMe,-,-],[A924 ;L23;H,CF3,-,-],[A925;L23;H,F,-,-],[A926;L23;H,Cl,-,-],[A927;L23;H,Br,-,-],[A928;L23;H,CN,-,-],[A929;L23;H,cPr,-,-],[A930; L23,H,cBu,-,-],[A931;L23,H,CF2H,-,-],[A932;L23,Me,Me,-,-],[A933;L23,Me,Et,-,-],[A934;L23,Me,iPr,-,-],[A935;L23,Me,cPr,-,-], [A936;L23,Me,cHex,-,-],[A937;L23,Me,CF2H,-,-],[A938;L23,Me,CF3,-,-],[A939;L23,Me,F,-,-],[A940;L23,Me,Cl,-,-],[A941;L23,Me, [A947;L23,Cl,CF2H,-,-],[A948;L23,Cl,CF3,-,-],[A949;L23,Cl,F,-,-],[A950;L23,Cl,Cl,-,-],[A951;L23,Cl,Br,-,-],[A952;L23,F,Me,-,-],[A953;L23,F,Et,-,-],[A954;L23,F,iPr,-,-],[A955;L23,F,cPr,-,-],[A956;L23,F,cHex,-,-],[A957;L23,F,CF2H,-,-],[A958;L23,F,CF3,-,-],[A959;L23,F,F,-,-],[A960;L23,F,Cl,-,-],[A961;L23,F,Br,-,-],[A962;L24;H,H,-,-],[A963;L24;Me,H,-,-],[A964;L24;Et,H,-,-],[A965;L24;Pr,H,-,-],[A966;L24;iPr,H,-,-],[A967;L24;OMe,H,-,-],[A968;L24;CF3,H,-,-],[A969;L24;F,H,-,-],[A970;L24;Cl,H,-,-],[A971;L24;Br,H,-,-],[A972;L24;CN,H,-,-],[A973;L24;cPr,H,-,-],[A974;L24;H,Me,-,-],[A975;L24;H,Et,-,-],[A976;L24;H,Pr,-,-],[A977;L24;H,iPr,-,-],[A978;L24;H,OMe,-,-],[A979;L24;H,CF3,-,-],[A980;L24;H,F,-,-],[A981;L24;H,Cl,-,-],[A982;L24;H,Br,-,-],[A983;L24;H,CN,-,-],[A984;L24;H,cPr,-,-],[A985;L25;H,H,H,-],[A986;L25;Me,H,H,-],[A987;L25;Et,H,H,-],[A988;L25;Pr,H,H,-],[A989;L25;iPr,H,H,-],[A990;L25;OMe,H,H,-],[A991;L25;CF3,H,H,-],[A992;L25;F,H,H,-],[A993;L25;Cl,H,H,-],[A994;L25;Br,H,H,-],[A995;L25;CN,H,H,-],[A996;L25;cPr,H,H,-],[A997;L25;H,Me,H,-],[A998;L25;H,Et,H,-],[A999;L25;H,Pr,H,-],[A1000;L25;H,iPr,H,-],[A1001;L25;H,OMe,H,-],[A1002;L25;H,CF3,H,-],[A1003;L25;H,F,H,-],[A1004;L25;H,Cl,H,-],[A1005;L25;H,Br,H,-],[A1006;L25;H,CN,H,-],[A1007;L25;H,cPr,H,-],[A1008;L25;H,H,Me,-],[A1009;L25;H,H,Et,-],[A1010;L25;H,H,Pr,-],[A1011;L25;H,H,iPr,-],[A1012;L25;H,H,OMe,-],[A1013;L25;H,H,CF3,-],[A1014;L25;H,H,F,-],[A1015;L25;H,H,Cl,-],[A1016;L25;H,H,Br,-],[A1017;L25;H,H,CN,-],[A1018;L25;H,H,cPr,-],[A1019;L26;H,H,-,-],[A1020;L26;Me,H,-,-],[A1021;L26;Et,H,-,-],[A1022;L26;Pr,H,-,-],[A1023;L26;iPr,H,-,-],[A1024;L26;OMe,H,-,-],[A1025;L26;CF3,H,-,-],[A1026;L26;F,H,-,-],[A1027;L26;Cl,H,-,-],[A1028;L26;Br,H,-,-],[A1029;L26;CN,H,-,-],[A1030;L26;cPr,H,-,-],[A1031;L26;H,Me,-,-],[A1032;L26;H,Et,-,-], [A1033;L26;H,Pr,-,-],[A1034;L26;H,iPr,-,-],[A1035;L26;H,OMe,-,-],[A1036;L26;H,CF3,-,-],[A1037;L26;H,F,-,-],[A1038;L26;H,Cl,-,-],[A1039;L26;H,Br,-,-],[A1040;L26;H,CN,-,-],[A1041;L26;H,cPr,-,-],[A1042;L27;H,H,H,-],[A1043;L27;Me,H,H,-],[A1044;L27;Et,H,H,-],[A1045;L27;Pr,H,H,-],[A1046;L27;iPr,H,H,-],[A1047;L27;CF3,H,H,-],[A1048;L27;cPr,H,H,-],[A1049;L27;Me,Me,H,-],[A1050;L27;Me,Et,H,-],[A1051;L27;Me,Pr,H,-],[A1052;L27;Me,iPr,H,-],[A1053;L27;Me,OMe,H,-],[A1054;L27;Me,CF3,H,-],[A1055;L27;Me,F,H,-],[A1056;L27;Me,Cl,H,-],[A1057;L27;Me,CN,H,-],[A1058;L27;Me,cPr,H,-],[A1059;L27;Me,H,Me,-],[A1060;L27;Me,H,Et,-],[A1061;L27;Me,H,Pr,-],[A1062;L27;Me,H,iPr,-],[A1063;L27;Me,H,OMe,-],[A1064;L27;Me,H,CF3,-],[A1065;L27;Me,H,F,-],[A1066;L27;Me,H,Cl,-],[A1067;L27;Me,H,CN,-],[A1068;L27;Me,H,cPr,-],[A1069;L28;H,H,H,-],[A1070;L28;Me,H,H,-],[A1071;L28;Et,H,H,-],[A1072;L28;Pr,H,H,-],[A1073;L28;iPr,H,H,-],[A1074;L28;CF3,H,H,-],[A1075;L28;cPr,H,H,-],[A1076;L28;Me,Me,H,-],[A1077;L28;Me,Et,H,-],[A1078;L28;Me,Pr,H,-],[A1079;L28;Me,iPr,H,-],[A1080;L28;Me,OMe,H,-],[A1081;L28;Me,CF3,H,-],[A1082;L28;Me,F,H,-],[A1083;L28;Me,Cl,H,-],[A1084;L28;Me,CN,H,-],[A1085;L28;Me,cPr,H,-],[A1086;L28;Me,H,Me,-],[A1087;L28;Me,H,Et,-],[A1088;L28;Me,H,Pr,-],[A1089;L28;Me,H,iPr,-],[A1090;L28;Me,H,OMe,-],[A1091;L28;Me,H,CF3,-],[A1092;L28;Me,H,F,-],[A1093;L28;Me,H,Cl,-],[A1094;L28;Me,H,CN,-],[A1095;L28;Me,H,cPr,-],[A1096;L29;H,H,H,-],[A1097;L29;Me,H,H,-],[A1098;L29;Et,H,H,-],[A1099;L29;Pr,H,H,-],[A1100;L29;iPr,H,H,-],[A1101;L29;OMe,H,H,-],[A1102;L29;CF3,H,H,-],[A1103;L29;F,H,H,-],[A1104;L29;Cl,H,H,-],[A1105;L29;CN,H,H,-],[A1106;L29;cPr,H,H,-],[A1107;L29;H,Me,H,-],[A1108;L29;H,Et,H,-],[A1109;L29;H,Pr,H,-],[A1110;L29;H,iPr,H,-],[A1111;L29;H,OMe,H,-],[A1112;L29;H,CF3,H,-],[A1113;L29;H,F,H,-],[A1114;L29;H,Cl,H,-],[A1115;L29;H,CN,H,-],[A1116;L29;H,cPr,H,-],[A1117;L29;H,H,Me,-],[A1118;L29;H,H,Et,-],[A1119;L29;H,H,Pr,-],[A1120;L29;H,H,iPr,-],[A1121;L29;H,H,OMe,-],[A1122;L29;H,H,CF3,-],[A1123;L29;H,H,F,-],[A1124;L29;H,H,Cl,-],[A1125;L29;H,H,CN,-],[A1126;L29;H,H,cPr,-],[A1127;L30;H,H,-,-],[A1128;L30;Me,H,-,-],[A1129;L30;Et,H,-,-],[A1130;L30;Pr,H,-,-],[A1131;L30;iPr,H,-,-],[A1132;L30;OMe,H,-,-],[A1133;L30;CF3,H,-,-],[A1134;L30;F,H,-,-],[A1135;L30;Cl,H,-,-],[A1136;L30;CN,H,-,-],[A1137;L30;cPr,H,-,-],[A1138;L30;H,Me,-,-],[A1139;L30;H,Et,-,-],[A1140;L30;H,Pr,-,-],[A1141;L30;H,iPr,-,-],[A1142;L30;H,OMe,-,-],[A1143;L30;H,CF3,-,-],[A1144;L30;H,F,-,-],[A1145;L30;H,Cl,-,-],[A1146;L30;H,CN,-,-],[A1147;L30;H,Ph,-,-],[A1148;L30;H,cPr,-,-],[A1149;L31;H,H,H,-],[A1150;L31;Me,H,H,-],[A1151;L31;Et,H,H,-],[A1152;L31;Pr,H,H,-],[A1153;L31;iPr,H,H,-],[A1154;L31;CF3,H,H,-],[A1155;L31;cPr,H,H,-],[A1156;L31;Me,Me,H,-],[A1157;L31;Me,Et,H,-],[A1158;L31;Me,Pr,H,-],[A1159;L31;Me,iPr,H,-],[A1160;L31;Me,OMe,H,-],[A1161;L31;Me,CF3,H,-],[A1162;L31;Me,F,H,-],[A1163;L31;Me,Cl,H,-],[A1164;L31;Me,CN,H,-],[A1165;L31;Me,cPr,H,-],[A1166;L31;Me,H,Me,-],[A1167;L31;Me,H,Et,-],[A1168;L31;Me,H,Pr,-],[A1169;L31;Me,H,iPr,-],[A1170;L31;Me,H,OMe,-],[A1171;L31;Me,H,CF3,-],[A1172;L31;Me,H,F,-],[A1173;L31;Me,H,Cl,-],[A1174;L31;Me,H,CN,-],[A1175;L31;Me,H,cPr,-],[A1176;L32;H,-,-,-],[A1177;L32;Me,-,-,-],[A1178;L32;Et,-,-,-],[A1179;L32;Pr,-,-,-],[A1180;L32;iPr,-,-,-],[A1181;L32;OMe,-,-,-],[A1182;L32;CF3,-,-,-],[A1183;L32;F,-,-,-],[A1184;L32;Cl,-,-,-],[A1185;L32;Br,-,-,-],[A1186;L32;CN,-,-,-],[A1187;L32;cPr,-,-,-],[A1188;L33;H,-,-,-],[A1189;L33;Me,-,-,-],[A1190;L33;Et,-,-,-],[A1191;L33;Pr,-,-,-],[A1192;L33;iPr,-,-,-],[A1193;L33;OMe,-,-,-],[A1194;L33;CF3,-,-,-],[A1195;L33;F,-,-,-],[A1196;L33;Cl,-,-,-],[A1197;L33;Br,-,-,-],[A1198;L33;CN,-,-,-],[A1199;L33;cPr,-,-,-],[A1200;L34;H,-,-,-],[A1201;L34;Me,-,-,-],[A1202;L34;Et,-,-,-],[A1203;L34;Pr,-,-,-],[A1204;L34;iPr,-,-,-],[A1205;L34;OMe,-,-,-],[A1206;L34;CF3,-,-,-],[A1207;L34;F,-,-,-],[A1208;L34;Cl,-,-,-],[A1209;L34;Br,-,-,-],[A1210;L34;CN,-,-,-],[A1211;L34;cPr,-,-,-],[A1212;L35;H,-,-,-],[A1213;L35;Me,-,-,-],[A1214;L35;Et,-,-,-],[A1215;L35;Pr,-,-,-],[A1216;L35;iPr,-,-,-],[A1217;L35;OMe,-,-,-],[A1218;L35;CF3,-,-,-],[A1219;L35;F,-,-,-],[A1220;L35;Cl,-,-,-],[A1221;L35;Br,-,-,-],[A1222;L35;CN,-,-,-],[A1223;L35;cPr,-,-,-],[A1224;L36,H,H,-,-],[A1225;L36,Me,H,-,-], [A1226;L36,Et,H,-,-],[A1227;L36,Pr,H,-,-],[A1228;L36,Bu,H,-,-],[A1229;L36,iPr,H,-,-],[A1230;L36,CF2H,H,-,-],[A1231;L36,CF3,H,-,-],[A1232;L36,cPr,H,-,-],[A1233;L36,F,H,-,-],[A1234;L36,Cl,H,-,-],[A1235;L36,Br,H,-,-],[A1236;L36,Me,Me,-,-],[A1237;L37,H,H,-,-],[A1238;L37,Me,H,-,- [A1239;L37,Et,H,-,-],[A1240;L37,Pr,H,-,-],[A1241;L37,iPr,H,-,-],[A1242;L37,OMe,H,-,-],[A1244;L37,F,H,-,-],[A1245;L37,Cl,H,-,-],[A1246;L37,Br,H,-,-],[A1247;L37,CN,H,-,-],[A1248;L37,cPr,H,-,-],[A1249;L38;H,-,-,-],[A1250;L38;Me,-,-,-],[A1251;L38;Et, [A1252;L38;Pr,-,-,-], [A1253;L38;iPr,-,-,-], [A1254;L38;OMe,-,-,-], [A1256;L38;F,-,-,-], [A1257;L38;Cl,-,-,-], [A1258;L38;Br,-,-,-], [A1259;L38;CN,-,-,-], [A1260;L38;cPr,-,-,-], [A1261;L39;H,H,H,-], [A1262;L39;Me,H,H,-], [A1263;L39;Et,H,H,-], [A1264;L3 9: 0;L39;cPr,H,H,-],[A1271;L39;H,H,Me,-],[A1272;L39;H,H,Et,-],[A1 273;L39;H,H,Pr,-],[A1274;L39;H,H,iPr,-],[A1275;L39;H,H,OMe,-], [A1276;L39;H,H,Cl,-],[A1277;L39;H,H,Br,-],[A1278;L39;H,H,CN,-],[A1279;L39;H,H,cPr,-],[A1280 ;L39;Me,Me,H,-],[A1281;L39;Cl,Cl,H,-],[A1282;L39;Me,H,Me,-],[A1283;L39;Me,Me,Me,-].;

[0086] In compound (A-1), R 3x However, it is an ethyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX2). In compound (A-1), R 3x However, it is an ethyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX3). In compound (A-1), R 3x However, it is an ethyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8, R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX4). In compound (A-1), R 3x However, it is a propyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX5). In compound (A-1), R 3x However, it is a propyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX6). In compound (A-1), R 3x However, it is a propyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX7). In compound (A-1), R3x However, it is a propyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX8). In compound (A-1), R 3x However, it is an isopropyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX9). In compound (A-1), R 3x However, it is an isopropyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX10). In compound (A-1), R 3x However, it is an isopropyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX11). In compound (A-1), R 3x However, it is an isopropyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX12). In compound (A-1), R 3x However, it is a butyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX13). In compound (A-1), R 3x However, it is a butyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , RX9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX14). In compound (A-1), R 3x However, it is a butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX15). In compound (A-1), R 3x However, it is a butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX16). In compound (A-1), R 3x However, it is an isobutyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX17). In compound (A-1), R3x However, it is an isobutyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX18). In compound (A-1), R 3x However, it is an isobutyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX19). In compound (A-1), R 3x However, it is an isobutyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX20). In compound (A-1), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 4x , R 5x , R6x , and R 7x This is a hydrogen atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX21). In compound (A-1), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX22). In compound (A-1), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX23). In compound (A-1), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented byX8 , R X9 , R X10 , and R X11 's combination is a compound (hereinafter referred to as compound group SX24) that is any of the combinations described in combination A. In compound (A-1), R 3x is a propyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x are hydrogen atoms, and the substituents R 1x represented by Z 1x and the substituents R X8 , R X9 , R X10 , and R X11 's combination is a compound (hereinafter referred to as compound group SX25) that is any of the combinations described in combination A. In compound (A-1), R 3x is a propyl group, R 1x , and R 2x are methyl groups, R 5x , R 6x , and R 7x are hydrogen atoms, R 4x is a fluorine atom, and the substituents R 1x represented by Z 1x and the substituents R X8 , R X9 , R X10 , and R X11 's combination is a compound (hereinafter referred to as compound group SX26) that is any of the combinations described in combination A. In compound (A-1), R 3x is a propyl group, R 1x , and R 2x are methyl groups, R 6x , and R 7x are hydrogen atoms, R 4x and R 5x are fluorine atoms, and the substituents R 1x represented by Z 1x and the substituents R X8 , R X9 , R X10 , and R X11The combination is a compound that is any of the combinations described in combination A (hereinafter referred to as compound group SX27). In compound (A-1), R 3x is a propyl group, R 1x , and R 2x [[ID=Q6]]are methyl groups, R 6x , and R 7x are hydrogen atoms, R 4x and R 5x are chlorine atoms, the groups represented by Z 1x and the groups represented by Z 1x in the substituents R X8 , R X9 , R X10 , and R X11 is a compound that is any of the combinations described in combination A (hereinafter referred to as compound group SX28). In compound (A-1), R 3x is an ethyl group, R 1x , and R 2x are methyl groups, R 4x , R 5x , R 6x , and R 7x are hydrogen atoms, the groups represented by Z 1x and the groups represented by Z 1x in the substituents R X8 , R X9 , R X10 , and R X11 is a compound that is any of the combinations described in combination A (hereinafter referred to as compound group SX29). In compound (A-1), R 3x is an ethyl group, R 1x , and R 2x are methyl groups, R 5x , R 6x , and R 7x are hydrogen atoms, R 4x is a fluorine atom, the groups represented by Z 1x and the groups represented by Z 1x in the substituents R X8 , R X9 , R X10 , and R X11 is a compound that is any of the combinations described in combination A (hereinafter referred to as compound group SX30). In compound (A-1), R 3xHowever, it is an ethyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in combination A (hereinafter referred to as compound group SX31). In compound (A-1), R 3x However, it is an ethyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 1x The base and Z that represent 1x substituent R in the group represented by X8 , R X9 , R X10 , and R X11 A compound whose combination is one of the combinations listed in Combination A (hereinafter referred to as Compound Group SX32).

[0087] Formula (A-2) [In the ceremony, Z 2x This represents one of the formulas L44 to L51. (However, ● represents R) 4x (This represents the bonding site with the benzene ring that has been substituted.) In the compound represented by ] (hereinafter referred to as compound (A-2)), R 3x However, it is an ethyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , RY5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in Combination B (hereinafter referred to as Compound Group SX33).

[0088] Combination B consists of substituent numbers B1 to B143. Substituents B1 to B143 are Z in compound (A-2). 2x The relationship and Z 2x substituent R corresponding to the structure Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 This represents a combination of [substituent number; Z], and is described below as follows: 2x ;R Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , R Y10 ] is written as. For example, substituent number B2 is Z 2x L44 and R Y1 is a methyl group, R Y2 , R Y3 , R Y4 , R Y5 , and R Y6 This refers to a combination where the atom is a hydrogen atom.

[0089] Combination B: [B1; L44; H, H, H, H, H, H, -, -, -, -], [B2; L44; Me, H, H, H, H, H, -, -, -, -], [B3; L44; F, H, H, H, H, H, -, -, -, -], [B4; L44; Cl, H, H, H, H, H, -, -, -, -], [B5; L44; F, F, H, H, H, H, -, -, -, -], [B6; L44; Cl, Cl, H, H, H, H, -, -, -, -], [B7; L44; Me, Me, H, H, H, H, -, -, -, -], [B8; L44; H, H, F, H, H, H, -, -, -, -], [B9; L44; H, H, Cl, H, H, H, -, -, -, -], [B10; L44; H, H, Me, H, H, H, -, -, -, -], [B11; L44; H, H, F, F, H, H, -, -, -, -], [B12; L44; H, H, Cl, Cl, H, H, -, -, -, -], [B13; L44; H, H, Me, Me, H, H, -, -, -, -], [B14; L44; H, H, H, H, F, H, -, -, -, -], [B15; L44; H, H, H, H, Cl, H, -, -, -, -], [B16; L44; H, H, H, H, Me, H, -, -, -, -], [B17; L44; H, H, H, H, F, F, -, -, -, -], [B18; L44; H, H, H, H, Cl, Cl, -, -, -, -], [B19; L44; H, H, H, H, Me, Me, -, -, -, -], [B20; L44; Me, H, Me, H, H, H, -, -, -, -], [B21; L44; Me, Et, H, H, H, H, -, -, -, -], [B22; L44; H, H, H, H, Me, Et, -, -, -, -], [B23; L44; H, H, H, H, Et, H, -, -, -, -], [B24; L44; H, H, H, H, cPr, H, -, -, -, -], [B25; L44; H, H, Et, H, H, H, -, -, -, -], [B26; L44; H, H, cPr, H, H, H, -, -, -, -], [BH,F,F,H,H,H,H,H,-,-],[B34;L45;H,Cl,Cl,H,H,H,H,H,-,-],[B35;L45;H,Me,Me,H,H,H,H,H,-,-],[B36;L45;H,H,H,F,F,H,H,H,-,-],[B37;L45;H,H,H,Cl,Cl,H,H,H,-,-],[B38;L45;H,H,H,Me,Me,H,H,H,-,-],[B39;L45;H,H,H,H,H,F,F,H,-,-],[B40;L45;H,H,H,H,H,Cl,Cl,H,-,-],[B41;L45;H,H,H,H,H,Me,Me,H,-,-],[B42;L45;F,H,H,H,H,H,H,F,-,-],[B43;L45;Cl,H,H,H,H,H,H,Cl,-,-],[B44;L45;Me,H,H,H,H,H,H,Me,-,-],[B45;L46;H,H,H,H,H,H,H,-,-,-],[B46;L46;Me,H,H,H,H,H,H,-,-,-],[B47;L46;F,H,H,H,H,H,H,-,-,-],[B48;L46;Cl,H,H,H,H,H,H,-,-,-],[B49;L46;H,F,F,H,H,H,H,-,-,-],[B50;L46;H,Cl,Cl,H,H,H,H,-,-,-],[B51;L46;H,H,H,H,H,H,H,-,-,-],[B52;L46;H,H,H,F,F,H,H,-,-,-],[B53;L46;H,H,H,Me,Me,H,H,-,-,-],[B54;L46;H,H,H,Cl,Cl,H,H,-,-,-],[B55;L46;H,H,H,H,H,Me,Me,-,-,-],[B56;L46;H,H,H,H,H,Cl,Cl,-,-,-],[B57;L46;H,H,H,H,H,F,F,-,-,-],[B58;L47;H,H,H,H,H,H,H,H,H,-],[B59;L47;Me,H,H,H,H,H,H,H,H,-],[B60;L47;F,H,H,H,H,H,H,H,H,-],[B61;L47;Cl,H,H,H,H,H,H,H,H,-],[B62;L47;H,F,F,H,H,H,H,H,H,-],[B63;L47;H,Cl,Cl,H,H,H,H,H,H,-],[B64;L47;H,Me,Me,H,H,H,H,H,H,-],[B65;L47;H,H,H,F,F,H,H,H,H,-],[B66;L47;H,H,H,Cl,Cl,H,H,H,H,-],[B67;L47;H,H,H,Me,Me,H,H,H,H,-],[B68;L47;H,H,H,H,H,F,F,H,H,-],[B69;L47;H,H,H,H,H,Cl,Cl,H,H,-],[B70;L47;H,H,H,H,H,Me,Me,H,H,-],[B71;L47;H,H,H,H,H,H,H,F,F,-],[B72;L47;H,H,H,H,H,H,H,Cl,Cl,-],[B73;L47;H,H,H,H,H,H,H,Me,Me,-],[B74;L48;H,H,H,H,H,H,H,H,-,-],[B75;L48;Me,H,H,H,H,H,H,H,-,-],[B76;L48;F,H,H,H,H,H,H,H,-,-],[B77;L48;Cl,H,H,H,H,H,H,H,-,-],[B78;L48;H,F,F,H,H,H,H,H,-,-],[B79;L48;H,Cl,Cl,H,H,H,H,H,-,-],[B80;L48;H,Me,Me,H,H,H,H,H,-,-],[B81;L48;H,H,H,F,F,H,H,H,-,-],[B82;L48;H,H,H,Cl,Cl,H,H,H,-,-],[B83;L48;H,H,H,Me,Me,H,H,H,-,-],[B84;L48;H,H,H,H,H,F,F,H,-,-],[B85;L48;H,H,H,H,H,Cl,Cl,H,-,-],[B86;L48;H,H,H,H,H,Me,Me,H,-,-],[B87;L48;F,H,H,H,H,H,H,F,-,-],[B88;L48;Cl,H,H,H,H,H,H,Cl,-,-],[B89;L48;Me,H,H,H,H,H,H,Me,-,-],[B90;L49;H,H,H,H,H,H,H,H,H,H],[B91;L49;Me,H,H,H,H,H,H,H,H,H],[B92;L49;F,H,H,H,H,H,H,H,H,H],[B93;L49;Cl,H,H,H,H,H,H,H,H,H],[B94;L49;H,F,F,H,H,H,H,H,H,H],[B95;L49;H,Cl,Cl,H,H,H,H,H,H,H],[B96;L49;H,Me,Me,H,H,H,H,H,H,H],[B97;L49;H,H,H,F,F,H,H,H,H,H],[B98;L49;H,H,H,Cl,Cl,H,H,H,H,H],[B99;L49;H,H,H,Me,Me,H,H,H,H,H],[B100;L49;H,H,H,H,H,F,F,H,H,H],[B101;L49;H,H,H,H,H,Cl,Cl,H,H,H],[B102;L49;H,H,H,H,H,Me,Me,H,H,H],[B103;L49;H,H,H,H,H,H,H,F,F,H],[B104;L49;H,H,H,H,H,H,H,Cl,Cl,H],[B105;L49;H,H,H,H,H,H,H,Me,Me,H],[B106;L49;F,H,H,H,H,H,H,H,H,F],[B107;L49;Cl,H,H,H,H,H,H,Me,Me,Cl],[B108;L49;Me,H,H,H,H,H,H,Me,Me,Me],[B109;L50;H,H,H,H,H,H,H,H,-,-],[B110;L50;Me,H,H,H,H,H,H,H,-,-],[B111;L50;F,H,H,H,H,H,H,H,-,-],[B112;L50;Cl,H,H,H,H,H,H,H,-,-],[B113;L50;H,F,F,H,H,H,H,H,-,-],[B114;L50;H,Cl,Cl,H,H,H,H,H,-,-],[B115;L50;H,Me,Me,H,H,H,H,H,-,-],[B116;L50;H,H,H,F,F,H,H,H,-,-],[B117;L50;H,H,H,Cl,Cl,H,H,H,-,-],[B118;L50;H,H,H,Me,Me,H,H,H,-,-],[B119;L50;H,H,H,H,H,F,F,H,-,-],[B120;L50;H,H,H,H,H,Cl,Cl,H,-,-],[B121;L50;H,H,H,H,H,Me,Me,H,-,-],[B122;L50;F,H,H,H,H,H,H,F,-,-],[B123;L50;Cl,H,H,H,H,H,H,Cl,-,-],[B124;L50;Me,H,H,H,H,H,H,Me,-,-],[B125;L51;H,H,H,H,H,H,H,H,H,H],[B126;L51;Me,H,H,H,H,H,H,H,H,H],[B127;L51;F,H,H,H,H,H,H,H,H,H],[B128;L51;Cl,H,H,H,H,H,H,H,H,H],[B129;L51;H,F,F,H,H,H,H,H,H,H],[B130;L51; H,Cl,Cl,H,H,H,H,H,H,H],[B131;L51;H,Me,Me,H,H,H,H,H,H,H],[B132;L5 1;H,H,H,F,F,H,H,H,H,H],[B133;L51;H,H,H,Cl,Cl,H,H,H,H,H],[B134;L5 1;H,H,H,Me,Me,H,H,H,H,H],[B135;L51;H,H,H,H,H,F,F,H,H,H],[B136;L5 1;H,H,H,H,H,Cl,Cl,H,H,H],[B137;L51;H,H,H,H,H,Me,Me,H,H,H],[B138; L51;H,H,H,H,H,H,H,F,F,H],[B139;L51;H,H,H,H,H,H,H,Cl,Cl,H],[B140; L51;H,H,H,H,H,H,H,Me,Me,H],[B141;L51;F,H,H,H,H,H,H,H,H,F],[B142; L51;Cl,H,H,H,H,H,H,Me,Me,Cl],[B143;L51;Me,H,H,H,H,H,H,Me,Me,Me]. In compound (A-2), R; 3x However, it is an ethyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX34). In compound (A-2), R 3x However, it is an ethyl group, R 1x , R 2x , R 6x , and R 7xis a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX35). In compound (A-2), R 3x However, it is an ethyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX36). In compound (A-2), R 3x However, it is a propyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9, and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX37). In compound (A-2), R 3x However, it is a propyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX38). In compound (A-2), R 3x However, it is a propyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX39). In compound (A-2), R 3x However, it is a propyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX40). In compound (A-2), R 3x However, it is an isopropyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX41). In compound (A-2), R 3x However, it is an isopropyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX42). In compound (A-2), R 3x However, it is an isopropyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX43). In compound (A-2), R 3x However, it is an isopropyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX44). In compound (A-2), R 3x However, it is a butyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX45). In compound (A-2), R 3x However, it is a butyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX46). In compound (A-2), R 3x However, it is a butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX47). In compound (A-2), R 3x However, it is a butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX48). In compound (A-2), R 3x However, it is an isobutyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX49). In compound (A-2), R 3x However, it is an isobutyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2xsubstituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX50). In compound (A-2), R 3x However, it is an isobutyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX51). In compound (A-2), R 3x However, it is an isobutyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX52). In compound (A-2), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX53). In compound (A-2), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX54). In compound (A-2), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX55). In compound (A-2), R 3x However, it is a sec-butyl group, R 1x , R 2x , R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX56). In compound (A-2), R 3x However, it is a propyl group, R 1x , R 2x , R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX57). In compound (A-2), R 3x However, it is a propyl group, R 1x , and R 2x is a methyl group, R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX58). In compound (A-2), R 3x However, it is a propyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX59). In compound (A-2), R 3x However, it is a propyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5xThis is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX60). In compound (A-2), R 3x However, it is an ethyl group, R 1x , and R 2x is a methyl group, R 4x , R 5x , R 6x , and R 7x This is a hydrogen atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX61). In compound (A-2), R 3x However, it is an ethyl group, R 1x , and R 2x is a methyl group, R 5x , R 6x , and R 7x is a hydrogen atom, R 4x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX62). In compound (A-2), R 3x However, it is an ethyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5x is a fluorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in combination B (hereinafter referred to as compound group SX63). In compound (A-2), R 3x However, it is an ethyl group, R 1x , and R 2x is a methyl group, R 6x , and R 7x is a hydrogen atom, R 4x and R 5x This is a chlorine atom, Z 2x The base and Z that represent 2x substituent R in the group represented by Y1 , R Y2 , R Y3 , R Y4 , R Y5 , R Y6 , R Y7 , R Y8 , R Y9 , and R Y10 A compound whose combination is one of the combinations listed in Combination B (hereinafter referred to as Compound Group SX64).

[0090] Formula (A-3) In the compound shown (hereinafter referred to as compound (A-3)), n x R is 0, 1x and R 2x is a hydrogen atom, R 3x , R4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX65).

[0091] Combination C consists of substituent numbers C1 to C456. Substituents C1 to C456 are R in compound (A-3). 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x This represents a combination of [substituent number; R], and below [substituent number; R] represents a combination of [substituent number; R]. 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , R 12x ] is written as. For example, substituent number C2 is R 3x is an ethyl group, R 4x , R 5x , R 6x , R 7x , R 9x , R 10x , R 11x , and R 12x is a hydrogen atom, R 8x This refers to a combination in which the atom is a fluorine atom.

[0092] Combination C: [C1; Et, H, H, H, H, H, H, H, H, H], [C2; Et, H, H, H, H, F, H, H, H, H], [C3; Et, H, H, H, H, H, F, H, H, H], [C4; Et, H, H, H, H, H, H, F, H, H], [C5; Et, H, H, H, H, Cl, H, H, H, H], [C6; Et, H, H, H, H, H, Cl, H, H, H], [C7; Et, H, H, H, H, H, H, Cl, H, H], [C8; Et, H, H, H, H, Me, H, H, H, H], [C9; Et, H, H, H, H, H, Me, H, H, H], [C10; Et, H, H, H, H, H, H, Me, H, H], [C11; Et, H, H, H, H, OMe, H, H, H, H], [C12; Et, H, H, H, H, H, OMe, H, H, H], [C13; Et, H, H, H, H, H, H, OMe, H, H], [C14; Et, H, H, H, H, F, F, H, H, H], [C15; Et, H, H, H, H, F, H, F, H, H], [C16; Et, H, H, H, H, F, H, H, F, H], [C17; Et, H, H, H, H, F, H, H, H, F], [C18; Et, H, H, H, H, F, H, F, H, F], [C19; Et, H, H, H, H, H, F, F, F, H], [C20; Pr, H, H, H, H, H, H, H, H, H], [C21; Pr, H, H, H, H, F, H, H, H, H], [C22; Pr, H, H, H, H, H, F, H, H, H], [C23; Pr, H, H, H, H, H, H, F, H, H], [C24; Pr, H, H, H, H, Cl, H, H, H, H], [C25; Pr, H, H, H, H, H, Cl, H, H, H], [C26; Pr, H, H, H, H, H, H, Cl, H, H], [C27; Pr, H, H, H, H, Me, H, H, H, H], [C28; Pr, H, H, H, H, H, Me, H, H, H], [C29; Pr, H, H, H, H, H, H, Me, H, H], [C30; Pr, H, H, H, H, OMe, H, H, H, H], [C31; Pr, H, H, H, H, H, OMe, H, H, H], [C32; Pr, H, H, H, H, H, H, OMe, H, H], [C33; Pr, H, H, H, H, F, F, H, H, H], [C34; Pr, H, H, H, H, F, H, F, H, H], [C35; Pr, H, H, H, H, F, H, H, F, H], [C36; Pr, H, H, H, H, F, H, H, H, F], [C37;Pr,H,H,H,H,F,H,F,H,F],[C38;Pr,H,H,H,H,H,F,F,F,H],[C39;iPr,H,H,H,H,H,H,H,H,H],[C40;iPr,H,H,H,H,F,H,H,H,H],[C41;iPr,H,H,H,H,H,F,H,H,H],[C42;iPr,H,H,H,H,H,H,F,H,H],[C43;iPr,H,H,H,H,Cl,H,H,H,H],[C44;iPr,H,H,H,H,H,Cl,H,H,H],[C45;iPr,H,H,H,H,H,H,Cl,H,H],[C46;iPr,H,H,H,H,Me,H,H,H,H],[C47;iPr,H,H,H,H,H,Me,H,H,H],[C48;iPr,H,H,H,H,H,H,Me,H,H],[C49;iPr,H,H,H,H,OMe,H,H,H,H],[C50;iPr,H,H,H,H,H,OMe,H,H,H],[C51;iPr,H,H,H,H,H,H,OMe,H,H],[C52;iPr,H,H,H,H,F,F,H,H,H],[C53;iPr,H,H,H,H,F,H,F,H,H],[C54;iPr,H,H,H,H,F,H,H,F,H],[C55;iPr,H,H,H,H,F,H,H,H,F],[C56;iPr,H,H,H,H,F,H,F,H,F],[C57;iPr,H,H,H,H,H,F,F,F,H],[C58;Bu,H,H,H,H,H,H,H,H,H],[C59;Bu,H,H,H,H,F,H,H,H,H],[C60;Bu,H,H,H,H,H,F,H,H,H],[C61;Bu,H,H,H,H,H,H,F,H,H],[C62;Bu,H,H,H,H,Cl,H,H,H,H],[C63;Bu,H,H,H,H,H,Cl,H,H,H],[C64;Bu,H,H,H,H,H,H,Cl,H,H],[C65;Bu,H,H,H,H,Me,H,H,H,H],[C66;Bu,H,H,H,H,H,Me,H,H,H],[C67;Bu,H,H,H,H,H,H,Me,H,H],[C68;Bu,H,H,H,H,OMe,H,H,H,H],[C69;Bu,H,H,H,H,H,OMe,H,H,H],[C70;Bu,H,H,H,H,H,H,OMe,H,H],[C71;Bu,H,H,H,H,F,F,H,H,H],[C72;Bu,H,H,H,H,F,H,F,H,H],[C73;Bu,H,H,H,H,F,H,H,F,H],[C74;Bu,H,H,H,H,F,H,H,H,F],[C75;Bu,H,H,H,H,F,H,F,H,F],[C76;Bu,H,H,H,H,H,F,F,F,H],[C77;iBu,H,H,H,H,H,H,H,H,H],[C78;iBu,H,H,H,H,F,H,H,H,H],[C79;iBu,H,H,H,H,H,F,H,H,H],[C80;iBu,H,H,H,H,H,H,F,H,H],[C81;iBu,H,H,H,H,Cl,H,H,H,H],[C82;iBu,H,H,H,H,H,Cl,H,H,H],[C83;iBu,H,H,H,H,H,H,Cl,H,H],[C84;iBu,H,H,H,H,Me,H,H,H,H],[C85;iBu,H,H,H,H,H,Me,H,H,H],[C86;iBu,H,H,H,H,H,H,Me,H,H],[C87;iBu,H,H,H,H,OMe,H,H,H,H],[C88;iBu,H,H,H,H,H,OMe,H,H,H],[C89;iBu,H,H,H,H,H,H,OMe,H,H],[C90;iBu,H,H,H,H,F,F,H,H,H],[C91;iBu,H,H,H,H,F,H,F,H,H],[C92;iBu,H,H,H,H,F,H,H,F,H],[C93;iBu,H,H,H,H,F,H,H,H,F],[C94;iBu,H,H,H,H,F,H,F,H,F],[C95;iBu,H,H,H,H,H,F,F,F,H],[C96;sBu,H,H,H,H,H,H,H,H,H], [C97;sBu,H,H,H,H,F,H,H,H,H],[C98;sBu,H,H,H,H,H,F,H,H,H],[C99;sBu,H,H,H,H,H,H,F,H,H],[C100;sBu,H,H,H,H,Cl,H,H,H,H],[C101;sBu,H,H,H,H,H,Cl,H,H,H],[C102;sBu,H,H,H,H,H,H,Cl,H,H],[C103;sBu,H,H,H,H,Me,H,H,H,H],[C104;sBu,H,H,H,H,H,Me,H,H,H],[C105;sBu,H,H,H,H,H,H,Me,H,H],[C106;sBu,H,H,H,H,OMe,H,H,H,H],[C107;sBu,H,H,H,H,H,OMe,H,H,H],[C108;sBu,H,H,H,H,H,H,OMe,H,H],[C109;sBu,H,H,H,H,F,F,H,H,H],[C110;sBu,H,H,H,H,F,H,F,H,H],[C111;sBu,H,H,H,H,F,H,H,F,H],[C112;sBu,H,H,H,H,F,H,H,H,F],[C113;sBu,H,H,H,H,F,H,F,H,F],[C114;sBu,H,H,H,H,H,F,F,F,H],[C115;Et,F,H,H,H,H,H,H,H,H],[C116;Et,F,H,H,H,F,H,H,H,H],[C117;Et,F,H,H,H,H,F,H,H,H],[C118;Et,F,H,H,H,H,H,F,H,H],[C119;Et,F,H,H,H,Cl,H,H,H,H],[C120;Et,F,H,H,H,H,Cl,H,H,H],[C121;Et,F,H,H,H,H,H,Cl,H,H],[C122;Et,F,H,H,H,Me,H,H,H,H],[C123;Et,F,H,H,H,H,Me,H,H,H],[C124;Et,F,H,H,H,H,H,Me,H,H],[C125;Et,F,H,H,H,OMe,H,H,H,H],[C126;Et,F,H,H,H,H,OMe,H,H,H],[C127;Et,F,H,H,H,H,H,OMe,H,H],[C128;Et,F,H,H,H,F,F,H,H,H],[C129;Et,F,H,H,H,F,H,F,H,H],[C130;Et,F,H,H,H,F,H,H,F,H],[C131;Et,F,H,H,H,F,H,H,H,F],[C132;Et,F,H,H,H,F,H,F,H,F],[C133;Et,F,H,H,H,H,F,F,F,H],[C134;Pr,F,H,H,H,H,H,H,H,H],[C135;Pr,F,H,H,H,F,H,H,H,H],[C136;Pr,F,H,H,H,H,F,H,H,H],[C137;Pr,F,H,H,H,H,H,F,H,H],[C138;Pr,F,H,H,H,Cl,H,H,H,H],[C139;Pr,F,H,H,H,H,Cl,H,H,H],[C140;Pr,F,H,H,H,H,H,Cl,H,H],[C141;Pr,F,H,H,H,Me,H,H,H,H],[C142;Pr,F,H,H,H,H,Me,H,H,H],[C143;Pr,F,H,H,H,H,H,Me,H,H],[C144;Pr,F,H,H,H,OMe,H,H,H,H],[C145;Pr,F,H,H,H,H,OMe,H,H,H],[C146;Pr,F,H,H,H,H,H,OMe,H,H],[C147;Pr,F,H,H,H,F,F,H,H,H],[C148;Pr,F,H,H,H,F,H,F,H,H],[C149;Pr,F,H,H,H,F,H,H,F,H],[C150;Pr,F,H,H,H,F,H,H,H,F],[C151;Pr,F,H,H,H,F,H,F,H,F],[C152;Pr,F,H,H,H,H,F,F,F,H],[C153;iPr,F,H,H,H,H,H,H,H,H],[C154;iPr,F,H,H,H,F,H,H,H,H],[C155;iPr,F,H,H,H,H,F,H,H,H],[C156;iPr,F,H,H,H,H,H,F,H,H],[C157;iPr,F,H,H,H,Cl,H,H,H,H],[C158;iPr,F,H,H,H,H,Cl,H,H,H],[C159;iPr,F,H,H,H,H,H,Cl,H,H],[C160;iPr,F,H,H,H,Me,H,H,H,H],[C161;iPr,F,H,H,H,H,Me,H,H,H],[C162;iPr,F,H,H,H,H,H,Me,H,H],[C163;iPr,F,H,H,H,OMe,H,H,H,H],[C164;iPr,F,H,H,H,H,OMe,H,H,H],[C165;iPr,F,H,H,H,H,H,OMe,H,H],[C166;iPr,F,H,H,H,F,F,H,H,H],[C167;iPr,F,H,H,H,F,H,F,H,H],[C168;iPr,F,H,H,H,F,H,H,F,H],[C169;iPr,F,H,H,H,F,H,H,H,F],[C170;iPr,F,H,H,H,F,H,F,H,F],[C171;iPr,F,H,H,H,H,F,F,F,H],[C172;Bu,F,H,H,H,H,H,H,H,H],[C173;Bu,F,H,H,H,F,H,H,H,H],[C174;Bu,F,H,H,H,H,F,H,H,H],[C175;Bu,F,H,H,H,H,H,F,H,H],[C176;Bu,F,H,H,H,Cl,H,H,H,H],[C177;Bu,F,H,H,H,H,Cl,H,H,H],[C178;Bu,F,H,H,H,H,H,Cl,H,H],[C179;Bu,F,H,H,H,Me,H,H,H,H],[C180;Bu,F,H,H,H,H,Me,H,H,H],[C181;Bu,F,H,H,H,H,H,Me,H,H],[C182;Bu,F,H,H,H,OMe,H,H,H,H],[C183;Bu,F,H,H,H,H,OMe,H,H,H],[C184;Bu,F,H,H,H,H,H,OMe,H,H],[C185;Bu,F,H,H,H,F,F,H,H,H],[C186;Bu,F,H,H,H,F,H,F,H,H],[C187;Bu,F,H,H,H,F,H,H,F,H],[C188;Bu,F,H,H,H,F,H,H,H,F],[C189;Bu,F,H,H,H,F,H,F,H,F],[C190;Bu,F,H,H,H,H,F,F,F,H], [C191;iBu,F,H,H,H,H,H,H,H,H],[C192;iBu,F,H,H,H,F,H,H,H,H],[C193;iBu,F,H,H,H,H,F,H,H,H],[C194;iBu,F,H,H,H,H,H,F,H,H],[C195;iBu,F,H,H,H,Cl,H,H,H,H],[C196;iBu,F,H,H,H,H,Cl,H,H,H],[C197;iBu,F,H,H,H,H,H,Cl,H,H],[C198;iBu,F,H,H,H,Me,H,H,H,H],[C199;iBu,F,H,H,H,H,Me,H,H,H],[C200;iBu,F,H,H,H,H,H,Me,H,H],[C201;iBu,F,H,H,H,OMe,H,H,H,H],[C202;iBu,F,H,H,H,H,OMe,H,H,H],[C203;iBu,F,H,H,H,H,H,OMe,H,H],[C204;iBu,F,H,H,H,F,F,H,H,H],[C205;iBu,F,H,H,H,F,H,F,H,H],[C206;iBu,F,H,H,H,F,H,H,F,H],[C207;iBu,F,H,H,H,F,H,H,H,F],[C208;iBu,F,H,H,H,F,H,F,H,F],[C209;iBu,F,H,H,H,H,F,F,F,H],[C210;sBu,F,H,H,H,H,H,H,H,H],[C211;sBu,F,H,H,H,F,H,H,H,H],[C212;sBu,F,H,H,H,H,F,H,H,H],[C213;sBu,F,H,H,H,H,H,F,H,H],[C214;sBu,F,H,H,H,Cl,H,H,H,H],[C215;sBu,F,H,H,H,H,Cl,H,H,H],[C216;sBu,F,H,H,H,H,H,Cl,H,H],[C217;sBu,F,H,H,H,Me,H,H,H,H],[C218;sBu,F,H,H,H,H,Me,H,H,H],[C219;sBu,F,H,H,H,H,H,Me,H,H],[C220;sBu,F,H,H,H,OMe,H,H,H,H], [C221;sBu,F,H,H,H,H,OMe,H,H,H],[C222;sBu,F,H,H,H,H,H,OMe,H,H],[C223;sBu,F,H,H,H,F,F,H,H,H],[C224;sBu,F,H,H,H,F,H,F,H,H],[C225;sBu,F,H,H,H,F,H,H,F,H],[C226;sBu,F,H,H,H,F,H,H,H,F],[C227;sBu,F,H,H,H,F,H,F,H,F],[C228;sBu,F,H,H,H,H,F,F,F,H],[C229;Et,F,F,H,H,H,H,H,H,H],[C230;Et,F,F,H,H,F,H,H,H,H],[C231;Et,F,F,H,H,H,F,H,H,H],[C232;Et,F,F,H,H,H,H,F,H,H],[C233;Et,F,F,H,H,Cl,H,H,H,H],[C234;Et,F,F,H,H,H,Cl,H,H,H],[C235;Et,F,F,H,H,H,H,Cl,H,H],[C236;Et,F,F,H,H,Me,H,H,H,H],[C237;Et,F,F,H,H,H,Me,H,H,H],[C238;Et,F,F,H,H,H,H,Me,H,H],[C239;Et,F,F,H,H,OMe,H,H,H,H],[C240;Et,F,F,H,H,H,OMe,H,H,H],[C241;Et,F,F,H,H,H,H,OMe,H,H],[C242;Et,F,F,H,H,F,F,H,H,H],[C243;Et,F,F,H,H,F,H,F,H,H],[C244;Et,F,F,H,H,F,H,H,F,H],[C245;Et,F,F,H,H,F,H,H,H,F],[C246;Et,F,F,H,H,F,H,F,H,F],[C247;Et,F,F,H,H,H,F,F,F,H],[C248;Pr,F,F,H,H,H,H,H,H,H],[C249;Pr,F,F,H,H,F,H,H,H,H],[C250;Pr,F,F,H,H,H,F,H,H,H],[C251;Pr,F,F,H,H,H,H,F,H,H],[C252;Pr,F,F,H,H,Cl,H,H,H,H],[C253;Pr,F,F,H,H,H,Cl,H,H,H],[C254;Pr,F,F,H,H,H,H,Cl,H,H],[C255;Pr,F,F,H,H,Me,H,H,H,H],[C256;Pr,F,F,H,H,H,Me,H,H,H],[C257;Pr,F,F,H,H,H,H,Me,H,H],[C258;Pr,F,F,H,H,OMe,H,H,H,H],[C259;Pr,F,F,H,H,H,OMe,H,H,H],[C260;Pr,F,F,H,H,H,H,OMe,H,H],[C261;Pr,F,F,H,H,F,F,H,H,H],[C262;Pr,F,F,H,H,F,H,F,H,H],[C263;Pr,F,F,H,H,F,H,H,F,H],[C264;Pr,F,F,H,H,F,H,H,H,F],[C265;Pr,F,F,H,H,F,H,F,H,F],[C266;Pr,F,F,H,H,H,F,F,F,H],[C267;iPr,F,F,H,H,H,H,H,H,H],[C268;iPr,F,F,H,H,F,H,H,H,H],[C269;iPr,F,F,H,H,H,F,H,H,H],[C270;iPr,F,F,H,H,H,H,F,H,H],[C271;iPr,F,F,H,H,Cl,H,H,H,H],[C272;iPr,F,F,H,H,H,Cl,H,H,H],[C273;iPr,F,F,H,H,H,H,Cl,H,H],[C274;iPr,F,F,H,H,Me,H,H,H,H],[C275;iPr,F,F,H,H,H,Me,H,H,H],[C276;iPr,F,F,H,H,H,H,Me,H,H],[C277;iPr,F,F,H,H,OMe,H,H,H,H],[C278;iPr,F,F,H,H,H,OMe,H,H,H],[C279;iPr,F,F,H,H,H,H,OMe,H,H],[C280;iPr,F,F,H,H,F,F,H,H,H],[C281;iPr,F,F,H,H,F,H,F,H,H],[C282;iPr,F,F,H,H,F,H,H,F,H],[C283;iPr,F,F,H,H,F,H,H,H,F],[C284;iPr,F,F,H,H,F,H,F,H,F],[C285;iPr,F,F,H,H,H,F,F,F,H],[C286;Bu,F,F,H,H,H,H,H,H,H],[C287;Bu,F,F,H,H,F,H,H,H,H],[C288;Bu,F,F,H,H,H,F,H,H,H],[C289;Bu,F,F,H,H,H,H,F,H,H],[C290;Bu,F,F,H,H,Cl,H,H,H,H],[C291;Bu,F,F,H,H,H,Cl,H,H,H],[C292;Bu,F,F,H,H,H,H,Cl,H,H],[C293;Bu,F,F,H,H,Me,H,H,H,H],[C294;Bu,F,F,H,H,H,Me,H,H,H],[C295;Bu,F,F,H,H,H,H,Me,H,H],[C296;Bu,F,F,H,H,OMe,H,H,H,H],[C297;Bu,F,F,H,H,H,OMe,H,H,H],[C298;Bu,F,F,H,H,H,H,OMe,H,H],[C299;Bu,F,F,H,H,F,F,H,H,H],[C300;Bu,F,F,H,H,F,H,F,H,H], [C301;Bu,F,F,H,H,F,H,H,F,H],[C302;Bu,F,F,H,H,F,H,H,H,F],[C303;Bu,F,F,H,H,F,H,F,H,F],[C304;Bu,F,F,H,H,H,F,F,F,H],[C305;iBu,F,F,H,H,H,H,H,H,H],[C306;iBu,F,F,H,H,F,H,H,H,H],[C307;iBu,F,F,H,H,H,F,H,H,H],[C308;iBu,F,F,H,H,H,H,F,H,H],[C309;iBu,F,F,H,H,Cl,H,H,H,H],[C310;iBu,F,F,H,H,H,Cl,H,H,H],[C311;iBu,F,F,H,H,H,H,Cl,H,H],[C312;iBu,F,F,H,H,Me,H,H,H,H],[C313;iBu,F,F,H,H,H,Me,H,H,H],[C314;iBu,F,F,H,H,H,H,Me,H,H],[C315;iBu,F,F,H,H,OMe,H,H,H,H],[C316;iBu,F,F,H,H,H,OMe,H,H,H],[C317;iBu,F,F,H,H,H,H,OMe,H,H],[C318;iBu,F,F,H,H,F,F,H,H,H],[C319;iBu,F,F,H,H,F,H,F,H,H],[C320;iBu,F,F,H,H,F,H,H,F,H],[C321;iBu,F,F,H,H,F,H,H,H,F],[C322;iBu,F,F,H,H,F,H,F,H,F],[C323;iBu,F,F,H,H,H,F,F,F,H],[C324;sBu,F,F,H,H,H,H,H,H,H],[C325;sBu,F,F,H,H,F,H,H,H,H],[C326;sBu,F,F,H,H,H,F,H,H,H],[C327;sBu,F,F,H,H,H,H,F,H,H],[C328;sBu,F,F,H,H,Cl,H,H,H,H],[C329;sBu,F,F,H,H,H,Cl,H,H,H],[C330;sBu,F,F,H,H,H,H,Cl,H,H],[C331;sBu,F,F,H,H,Me,H,H,H,H],[C332;sBu,F,F,H,H,H,Me,H,H,H],[C333;sBu,F,F,H,H,H,H,Me,H,H],[C334;sBu,F,F,H,H,OMe,H,H,H,H],[C335;sBu,F,F,H,H,H,OMe,H,H,H],[C336;sBu,F,F,H,H,H,H,OMe,H,H],[C337;sBu,F,F,H,H,F,F,H,H,H],[C338;sBu,F,F,H,H,F,H,F,H,H],[C339;sBu,F,F,H,H,F,H,H,F,H],[C340;sBu,F,F,H,H,F,H,H,H,F],[C341;sBu,F,F,H,H,F,H,F,H,F],[C342;sBu,F,F,H,H,H,F,F,F,H],[C343;Et,Cl,Cl,H,H,H,H,H,H,H],[C344;Et,Cl,Cl,H,H,F,H,H,H,H],[C345;Et,Cl,Cl,H,H,H,F,H,H,H],[C346;Et,Cl,Cl,H,H,H,H,F,H,H],[C347;Et,Cl,Cl,H,H,Cl,H,H,H,H],[C348;Et,Cl,Cl,H,H,H,Cl,H,H,H],[C349;Et,Cl,Cl,H,H,H,H,Cl,H,H],[C350;Et,Cl,Cl,H,H,Me,H,H,H,H],[C351;Et,Cl,Cl,H,H,H,Me,H,H,H],[C352;Et,Cl,Cl,H,H,H,H,Me,H,H],[C353;Et,Cl,Cl,H,H,OMe,H,H,H,H],[C354;Et,Cl,Cl,H,H,H,OMe,H,H,H],[C355;Et,Cl,Cl,H,H,H,H,OMe,H,H],[C356;Et,Cl,Cl,H,H,F,F,H,H,H],[C357;Et,Cl,Cl,H,H,F,H,F,H,H],[C358;Et,Cl,Cl,H,H,F,H,H,F,H],[C359;Et,Cl,Cl,H,H,F,H,H,H,F],[C360;Et,Cl,Cl,H,H,F,H,F,H,F],[C361;Et,Cl,Cl,H,H,H,F,F,F,H],[C362;Pr,Cl,Cl,H,H,H,H,H,H,H],[C363;Pr,Cl,Cl,H,H,F,H,H,H,H],[C364;Pr,Cl,Cl,H,H,H,F,H,H,H],[C365;Pr,Cl,Cl,H,H,H,H,F,H,H],[C366;Pr,Cl,Cl,H,H,Cl,H,H,H,H],[C367;Pr,Cl,Cl,H,H,H,Cl,H,H,H],[C368;Pr,Cl,Cl,H,H,H,H,Cl,H,H],[C369;Pr,Cl,Cl,H,H,Me,H,H,H,H],[C370;Pr,Cl,Cl,H,H,H,Me,H,H,H],[C371;Pr,Cl,Cl,H,H,H,H,Me,H,H],[C372;Pr,Cl,Cl,H,H,OMe,H,H,H,H],[C373;Pr,Cl,Cl,H,H,H,OMe,H,H,H],[C374;Pr,Cl,Cl,H,H,H,H,OMe,H,H],[C375;Pr,Cl,Cl,H,H,F,F,H,H,H],[C376;Pr,Cl,Cl,H,H,F,H,F,H,H],[C377;Pr,Cl,Cl,H,H,F,H,H,F,H],[C378;Pr,Cl,Cl,H,H,F,H,H,H,F],[C379;Pr,Cl,Cl,H,H,F,H,F,H,F],[C380;Pr,Cl,Cl,H,H,H,F,F,F,H],[C381;iPr,Cl,Cl,H,H,H,H,H,H,H],[C382;iPr,Cl,Cl,H,H,F,H,H,H,H],[C383;iPr,Cl,Cl,H,H,H,F,H,H,H],[C384;iPr,Cl,Cl,H,H,H,H,F,H,H],[C385;iPr,Cl,Cl,H,H,Cl,H,H,H,H],[C386;iPr,Cl,Cl,H,H,H,Cl,H,H,H],[C387;iPr,Cl,Cl,H,H,H,H,Cl,H,H],[C388;iPr,Cl,Cl,H,H,Me,H,H,H,H],[C389;iPr,Cl,Cl,H,H,H,Me,H,H,H],[C390;iPr,Cl,Cl,H,H,H,H,Me,H,H],[C391;iPr,Cl,Cl,H,H,OMe,H,H,H,H],[C392;iPr,Cl,Cl,H,H,H,OMe,H,H,H],[C393;iPr,Cl,Cl,H,H,H,H,OMe,H,H],[C394;iPr,Cl,Cl,H,H,F,F,H,H,H],[C395;iPr,Cl,Cl,H,H,F,H,F,H,H],[C396;iPr,Cl,Cl,H,H,F,H,H,F,H],[C397;iPr,Cl,Cl,H,H,F,H,H,H,F],[C398;iPr,Cl,Cl,H,H,F,H,F,H,F],[C399;iPr,Cl,Cl,H,H,H,F,F,F,H],[C400;Bu,Cl,Cl,H,H,H,H,H,H,H],[C401;Bu,Cl,Cl,H,H,F,H,H,H,H],[C402;Bu,Cl,Cl,H,H,H,F,H,H,H],[C403;Bu,Cl,Cl,H,H,H,H,F,H,H],[C404;Bu,Cl,Cl,H,H,Cl,H,H,H,H],[C405;Bu,Cl,Cl,H,H,H,Cl,H,H,H],[C406;Bu,Cl,Cl,H,H,H,H,Cl,H,H],[C407;Bu,Cl,Cl,H,H,Me,H,H,H,H],[C408;Bu,Cl,Cl,H,H,H,Me,H,H,H],[C409;Bu,Cl,Cl,H,H,H,H,Me,H,H],[C410;Bu,Cl,Cl,H,H,OMe,H,H,H,H],[C411;Bu,Cl,Cl,H,H,H,OMe,H,H,H],[C412;Bu,Cl,Cl,H,H,H,H,OMe,H,H],[C413;Bu,Cl,Cl,H,H,F,F,H,H,H],[C414;Bu,Cl,Cl,H,H,F,H,F,H,H],[C415;Bu,Cl,Cl,H,H,F,H,H,F,H],[C416;Bu,Cl,Cl,H,H,F,H,H,H,F],[C417;Bu,Cl,Cl,H,H,F,H,F,H,F],[C418;Bu,Cl,Cl,H,H,H,F,F,F,H],[C419;iBu,Cl,Cl,H,H,H,H,H,H,H],[C420;iBu,Cl,Cl,H,H,F,H,H,H,H],[C421;iBu,Cl,Cl,H,H,H,F,H,H,H],[C422;iBu,Cl,Cl,H,H,H,H,F,H,H],[C423;iBu,Cl,Cl,H,H,Cl,H,H,H,H],[C424;iBu,Cl,Cl,H,H,H,Cl,H,H,H],[C425;iBu,Cl,Cl,H,H,H,H,Cl,H,H],[C426;iBu,Cl,Cl,H,H,Me,H,H,H,H],[C427;iBu,Cl,Cl,H,H,H,Me,H,H,H],[C428;iBu,Cl,Cl,H,H,H,H,Me,H,H],[C429;iBu,Cl,Cl,H,H,OMe,H,H,H,H],[C430;iBu,Cl,Cl,H,H,H,OMe,H,H,H],[C431;iBu,Cl,Cl,H,H,H,H,OMe,H,H],[C432;iBu,Cl,Cl,H,H,F,F,H,H,H],[C433;iBu,Cl,Cl,H,H,F,H,F,H,H],[C434;iBu,Cl,Cl,H,H,F,H,H,F,H],[C435;iBu,Cl,Cl,H,H,F,H,H,H,F],[C436;iBu,Cl,Cl,H,H,F,H,F,H,F],[C437;iBu,Cl,Cl,H,H,H,F,F,F,H],[C438;sBu,Cl,Cl,H,H,H,H,H,H,H],[C439;sBu,Cl,Cl,H,H,F,H,H,H,H],[C440;sBu,Cl,Cl,H,H,H,F,H,H,H],[C441;sBu,Cl,C l,H,H,H,H,F,H,H],[C442;sBu,Cl,Cl,H,H,Cl,H,H,H,H],[C443;sBu,Cl,Cl,H,H,H, Cl,H,H,H],[C444;sBu,Cl,Cl,H,H,H,H,Cl,H,H],[C445;sBu,Cl,Cl,H,H,Me,H,H,H ,H],[C446;sBu,Cl,Cl,H,H,H,Me,H,H,H],[C447;sBu,Cl,Cl,H,H,H,H,Me,H,H],[C4 48;sBu,Cl,Cl,H,H,OMe,H,H,H,H],[C449;sBu,Cl,Cl,H,H,H,OMe,H,H,H],[C450;s Bu,Cl,Cl,H,H,H,H,OMe,H,H],[C451;sBu,Cl,Cl,H,H,F,F,H,H,H],[C452;sBu,Cl,C l,H,H,F,H,F,H,H],[C453;sBu,Cl,Cl,H,H,F,H,H,F,H],[C454;sBu,Cl,Cl,H,H,F,H,H,H,F],[C455;sBu,Cl,Cl,H,H,F,H,F,H,F],[C456;sBu,Cl,Cl,H,H,H,F,F,F,H]. In compound (A-3), n; x R is 0, 1x and R 2x is a methyl group, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX66). In compound (A-3), n x R is 0, 1x is a methyl group, R 2x is a hydrogen atom, R 3x , R 4x , R 5x , R 6x , R 7x , R8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX67). In compound (A-3), n x is 1, R 1x and R 2x is a hydrogen atom, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX68). In compound (A-3), n x is 1, R 1x and R 2x is a methyl group, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX69). In compound (A-3), n x is 1, R 1x is a methyl group, R 2x is a hydrogen atom, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX70). In compound (A-3), n x Since R is 2, 1x and R 2xis a hydrogen atom, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX71). In compound (A-3), n x Since R is 2, 1x and R 2x is a methyl group, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX72). In compound (A-3), n x Since R is 2, 1x is a methyl group, R 2x is a hydrogen atom, R 3x , R 4x , R 5x , R 6x , R 7x , R 8x , R 9x , R 10x , R 11x , and R 12x A compound whose combination is one of the combinations listed in combination C (hereinafter referred to as compound group SX73).

[0093] The following are examples of formulations. Note that "parts" refers to parts by weight. Furthermore, compound S represents a compound listed in compound group SX1 to SX73.

[0094] Formulation Example 1 A formulation is obtained by mixing 35 parts of a mixture of polyoxyethylene alkyl ether sulfate ammonium salt and silica (weight ratio 1:1), 10 parts of any one of the compounds S, and 55 parts of water, and then finely grinding the mixture using a wet grinding method.

[0095] Formulation Example 2 A formulation is obtained by grinding and mixing 50 parts of any one of the compounds S, 3 parts of calcium ligninsulfonate, 2 parts of sodium lauryl sulfate, and 45 parts of silica.

[0096] Formulation Example 3 A formulation is obtained by mixing 5 parts of any one of the compounds S, 9 parts of polyoxyethylene styrylphenyl ether, 5 parts of polyoxyethylene decyl ether (ethylene oxide addition number: 5), 6 parts of calcium dodecylbenzenesulfonate, and 75 parts of xylene.

[0097] Formulation Example 4 Two parts of any one of the compounds S, one part of silica, two parts of calcium ligninsulfonate, thirty parts of bentonite, and sixty-five parts of kaolin clay are crushed and mixed, an appropriate amount of water is added and kneaded, granulated in a granulator, and then dried to obtain a formulation.

[0098] Formulation Example 5 Ten parts of any one of the compounds S are mixed with a mixture of 18 parts benzyl alcohol and 9 parts DMSO. 6.3 parts GERONOL® TE250, 2.7 parts Ethylan® NS-500LQ, and 54 parts solvent naphtha are added and mixed to obtain a formulation.

[0099] Next, we will show some test examples. In Test Example 7, "untreated leaf disc" refers to a leaf disc prepared under the same conditions as described in the test example, except that DMSO was dispensed instead of the DMSO dilution containing the compound. In Test Example 11, "untreated" means that the aqueous dilution of the formulation containing the compound was not sprayed. In Test Example 15, "untreated" refers to a test prepared under the same conditions as described in the test example, except that DMSO was dispensed instead of the DMSO dilution containing the compound.

[0100] Test Example 1: Control Test against Septoria tritici (wheat leaf blight fungus) The compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of YBG medium (Yeast bacto glycerol medium) pre-inoculated with wheat leaf blight fungus spores was dispensed into each well. This plate was cultured at 18°C ​​for 3 days to allow the wheat leaf blight fungus to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth stage of the wheat leaf blight fungus. As a result, the compound showed efficacy in controlling plant diseases.

[0101] Test Example 2: Control Test against Ustilago maydis (corn smut virus). The compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of potato decoction liquid medium (PDB medium), which had been pre-inoculated with stilago maydis spores, was dispensed into each well. This plate was incubated at 18°C ​​for 4 days to allow the stilago maydis to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth stage of the stilago maydis. As a result, the compound showed efficacy in controlling plant diseases.

[0102] Test Example 3: Control Test against Rhynchosporium secalis (barley cloud mold fungus) The compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of potato decoction liquid medium (PDB medium), which had been pre-inoculated with barley cloud mold fungus spores, was dispensed into each well. This plate was cultured at 18°C ​​for 7 days to allow the barley cloud mold fungus to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth stage of the barley cloud mold fungus. As a result, the compound showed efficacy in controlling plant diseases.

[0103] Test Example 4: Control Test against Cucumber Gray Mold (Botrytis cinerea) The compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of complete medium pre-inoculated with cucumber gray mold spores was dispensed into each well. The plate was cultured at 18°C ​​for 4 days to allow the cucumber gray mold to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth rate of the cucumber gray mold. As a result, the compound showed efficacy in controlling plant diseases.

[0104] Test Example 5: Control Test against Peach Scratch Virus (Cladosporium carpophilum) Each well of the compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of potato decoction liquid medium (PDB medium) pre-inoculated with peach scratch virus spores was dispensed into each well. This plate was cultured at 18°C ​​for 5 days to allow the peach scratch virus to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth stage of the peach scratch virus. As a result, the compound showed efficacy in controlling plant diseases.

[0105] Test Example 6: Control Test against Cochliobolus miyabeanus (rice leaf spot disease fungus) The compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 150 μL of YBA medium (Yeast bacto acetate medium) pre-inoculated with spores of Cochliobolus miyabeanus was dispensed into each well. The plate was cultured at 23°C for 3 days to allow the Cochliobolus miyabeanus to grow. After that, the absorbance at 550 nm in each well of the microtiter plate was measured, and this value was taken as the growth stage of the Cochliobolus miyabeanus. As a result, the compound showed efficacy in controlling plant diseases.

[0106] Test Example 7 Control Test for Soybean Rust Disease (Phakopsora pachyrhizi) Leaf discs were prepared by cutting the true leaves of soybeans (variety: Kurosenkoku) to a diameter of 1 cm. 1 mL of agar medium (agar concentration 1.2%) was dispensed into each well of a 24-well microplate, and one leaf disc was placed on top of the agar medium in each well. A mixture of 0.5 μL of Solpol® 1200KX, 4.5 μL of DMSO, and 5 μL of xylene was mixed with 20 μL of DMSO solution containing 10,000 ppm of the test compound. The resulting mixture was diluted with deionized water to prepare a mixture containing the test compound at a predetermined concentration. 10 μL of the resulting mixture was sprayed onto each leaf disc. One day later, an aqueous suspension of spores of the soybean rust fungus (Phakopsora pachyrhizi) having the F129L amino acid substitution in the mitochondrial cytochrome b protein was spray-inoculated onto leaf discs. After inoculation, the microplates were placed in an artificial climate chamber (6 hours on, 18 hours off, temperature 23°C, humidity 60%). One day later, the leaf discs were air-dried until all water droplets on the surface were gone, and the microplates were placed again in the artificial climate chamber for 12 days. Subsequently, the area of ​​soybean rust lesions was investigated. As a result, the lesion area of ​​leaf discs treated with any one of the test compounds 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, or 13 at a predetermined concentration of 200 ppm was 30% or less of the lesion area of ​​untreated leaf discs.

[0107] Test Example 8: Control Test for Barley Net Spot Disease (Pyrenophora teres) Soil was packed into plastic pots, and barley (variety: Nishinohoshi) was sown in them and cultivated in a greenhouse for 7 days. The compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the barley so that it adhered well to the leaves. After spraying, the barley was air-dried, and one day later, an aqueous suspension of barley net spot fungus spores was spray-inoculated. After inoculation, the barley was placed in a greenhouse at 23°C during the day and 20°C at night under high humidity for 3 days, and then cultivated in the greenhouse for 7 days, after which the area of ​​disease lesions was investigated. As a result, the compound showed efficacy in controlling plant diseases.

[0108] Test Example 9: Control Test for Wheat Rust (Puccinia recondita) Soil was packed into plastic pots, and wheat (variety: Shirogane) was sown and cultivated in a greenhouse for 9 days. The compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the wheat so that it adhered well to the foliage. After spraying, the wheat was air-dried and cultivated at 20°C under lighting for 5 to 7 days, after which wheat rust fungus spores were sprinkled on and inoculated. After inoculation, the wheat was placed at 23°C in the dark and humid for 1 day, then cultivated at 20°C under lighting for 8 days, and the area of ​​disease lesions was investigated. As a result, the compound showed efficacy in controlling plant diseases.

[0109] Test Example 10 Control Test for Wheat Leaf Blight (Septoria tritici) Soil was packed into plastic pots, and wheat (variety: Apogee) was sown and cultivated in a greenhouse for 10 days. The compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the wheat so that it adhered well to the leaves. After spraying, the wheat was air-dried, and 4 days later, an aqueous suspension containing spores of the wheat leaf blight fungus was spray-inoculated. After inoculation, the wheat was placed at 18°C ​​and high humidity for 3 days, and then cultivated under light for 14 to 18 days, after which the area of ​​lesions was investigated. As a result, the compound showed an effect in controlling plant diseases.

[0110] Test Example 11 Control Test for Soybean Rust Disease (Phakopsora pachyrhizi) Soil was packed into plastic pots, and soybeans (variety: Kurosenkoku) were sown therein and cultivated in a greenhouse for 10 to 14 days. Compound 7, 8, 10, or 11, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the soybeans so that it adhered well to the leaves. After spraying, the soybeans were air-dried, and 2 to 5 days later, an aqueous suspension of soybean rust fungal spores was spray-inoculated. After inoculation, the soybeans were placed in a greenhouse at 23°C during the day and 20°C at night under high humidity for 1 to 2 days, and then cultivated in the greenhouse for 12 days, after which the lesion area was investigated. As a result, the lesion area in soybeans treated with each of the above compounds was 30% or less of the lesion area in untreated soybeans.

[0111] Test Example 12: Control Test for Soybean Rust Disease (Phakopsora pachyrhizi) Soil was packed into plastic pots, sowed soybeans (variety: Kurosenkoku), and cultivated in a greenhouse for 10 days. The soybeans were then spray-inoculated with an aqueous suspension containing spores of the soybean rust fungus. After inoculation, the soybeans were placed in a greenhouse at 23°C during the day and 20°C at night under high humidity for one day. Next, they were cultivated in the greenhouse for two days. Then, the compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the soybeans to ensure sufficient adhesion. After spraying, the soybeans were air-dried and cultivated in a greenhouse for eight days, after which the area of ​​disease lesions was investigated. As a result, the compound showed efficacy in controlling plant diseases.

[0112] Test Example 13: Control Test for Soybean Leaf Spot Disease (Cercospora sojina) Soil was packed into plastic pots, and soybeans (variety: Tachinagaha) were sown and cultivated in a greenhouse for 13 days. The compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the soybeans so that it adhered well to the leaves. After spraying, the soybeans were air-dried, and one day later, an aqueous suspension of soybean leaf spot fungus spores was spray-inoculated. After inoculation, the soybeans were placed in a greenhouse at 23°C during the day and 20°C at night under high humidity for 3 days, and then cultivated in the greenhouse for 16 days, after which the area of ​​disease lesions was investigated. As a result, the compound showed an effect in controlling plant diseases.

[0113] Test Example 14: Control Test for Tomato Ring Spot Disease (Alternaria solani) Soil was packed into plastic pots, and tomatoes (variety: Patio) were sown and cultivated in a greenhouse for 20 days. The compound, formulated according to the method described in Formulation Example 1, was mixed with water to a concentration of 200 ppm, and the resulting mixture was sprayed onto the leaves of the tomatoes to ensure sufficient adhesion. After spraying, the tomatoes were air-dried, and one day later, an aqueous suspension of tomato ring spot fungal spores was spray-inoculated. After inoculation, the tomatoes were placed at 18°C ​​and high humidity for 6 days, and then the area of ​​lesions was examined. As a result, the compound showed efficacy in controlling plant diseases.

[0114] Test Example 15 Control Test against Soybean Rust Fungus (Phakopsora pachyrhizi) The test compound was diluted with DMSO to a concentration of 150 ppm, and 1 μL was dispensed into each well of a microtiter plate (96 wells). Then, 149 μL of an aqueous suspension of soybean rust fungus spores, in which soybean rust fungus spores had been pre-suspended, was dispensed into each well. After culturing this plate at 23°C for several hours, the number of germinated soybean rust fungus spores was counted. As a result, at a treatment concentration of 1 ppm, the number of germinated spores in wells containing any one of the test compounds 1, 2, 3, 4, 7, 8, 9, 10, 11, 12, 13, or 14 was 50% or less of the number of germinated spores in the untreated wells.

[0115] Test Example 16: Control test against soybean rust fungus (Phakopsora pachyrhizi). The test was conducted using the present compound as the test compound at a treatment concentration of 10 ppm, following the same method as in Test Example 15. The results showed that the present compound exhibits efficacy in controlling plant diseases.

[0116] Test Example 17: Control test against soybean rust fungus (Phakopsora pachyrhizi). The test was conducted using the compound in question at a treatment concentration of 0.016 ppm, following the method described in Test Example 15. The results showed that the compound exhibits efficacy in controlling plant diseases.

[0117] This compound has a control effect against plant diseases and can be used for plant disease control.

Claims

1. Formula (I) [wherein, R 1 represents a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a 3- to 8-member non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3- to 8-member non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group F}, a C1-C6 alkoxy group, a C1-C6 haloalkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, an amino group, a hydroxy group, a halogen atom, or a hydrogen atom, and R 2 represents a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a 3- to 8-member non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3- to 8-member non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group F}, a halogen atom, or a hydrogen atom, and the combination of n and R 3 is such that n is 0, 1, or 2, and R 3 represents a C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3- to 6-member non-aromatic heterocyclic group {the C3-C6 alicyclic hydrocarbon group and the 3- to 6-member non-aromatic heterocyclic group may be substituted with one or more substituents selected from Group F} which may be substituted with one or more substituents selected from Group C; or n is 2, and R 3 is NR 8 R 9 represents a combination, and R 4 , R 5 , R[[ID=2l]] 6 , and R 7 are the same or different and represent a C1-C6 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a nitro group, a halogen atom, a hydroxy group, or a hydrogen atom which may be substituted with one or more substituents selected from Group A, and R 8 represents a C1-C6 chain hydrocarbon group, a C3-C8 alicyclic hydrocarbon group, a C1-C6 alkoxy group, or a C1-C6 haloalkoxy group which may be substituted with one or more substituents selected from Group A, and R 9 This represents a C1-C6 chain hydrocarbon group or a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group A, and Z 1 is a phenyl group, a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {the phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) may be substituted with one or more substituents selected from group D}, a C3-C8 alicyclic hydrocarbon group which may be substituted with one or more substituents selected from group B, a 3-8 membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E, or OR 10 Represents R 10 This represents a C3-C8 alicyclic hydrocarbon group or a 3-8 member non-aromatic heterocyclic group {the C3-C8 alicyclic hydrocarbon group and the 3-8 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group B}. Group A: A group consisting of a C1-C6 alkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group {the C1-C6 alkoxy group, the C1-C6 alkylamino group and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, a C3-C6 alicyclic hydrocarbon group, a 3-6 member non-aromatic heterocyclic group {the C3-C6 alicyclic hydrocarbon group and the 3-6 member non-aromatic heterocyclic group may be substituted with one or more substituents selected from group F}, a halogen atom, a cyano group, a nitro group, and a hydroxyl group. Group B: A group consisting of oxo groups, thioxo groups, C1-C6 hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups, {the C1-C6 hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, and C2-C8 dialkylamino groups may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, halogen atoms, cyano groups, nitro groups, hydroxyl groups, and sulfanyl groups. Group C: A group consisting of C1-C6 alkoxy groups, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, fluorine atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more halogen atoms. Group D: A group consisting of C1-C6 chain hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups {the C1-C6 chain hydrocarbon groups, the C1-C6 alkoxy groups, the C1-C6 alkylamino groups, and the C2-C8 dialkylamino groups may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups {the C3-C6 alicyclic hydrocarbon groups and the 3-6 membered non-aromatic heterocyclic groups may be substituted with one or more substituents selected from Group F}, halogen atoms, cyano groups, and nitro groups.Group E: A group consisting of oxo groups, thioxo groups, C1-C6 chain hydrocarbon groups, C1-C6 alkoxy groups, C1-C6 alkylamino groups, C2-C8 dialkylamino groups, {the C1-C6 alkoxy groups, the C1-C6 alkylamino groups, and the C2-C8 dialkylamino groups may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, halogen atoms, cyano groups, nitro groups, hydroxyl groups, and sulfanyl groups. Group F: A group consisting of oxo groups, halogen atoms, C1-C4 alkyl groups, C1-C4 alkoxy groups, C1-C4 haloalkyl groups, C1-C4 haloalkoxy groups, and cyano groups.] A method for controlling plant diseases comprising treating plants or soil on which plants are cultivated with compounds represented in the above, or their N oxides or salts thereof.

2. Formula (II) [In the formula, na represents 0, 1, or 2, and R 1a Group A a A C1-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group E. a {may be substituted with one or more substituents selected from}, representing a C1-C6 alkoxy group, a C1-C6 haloalkoxy group, a C1-C6 alkylamino group, a C2-C8 dialkylamino group, an amino group, a hydroxyl group, a halogen atom, or a hydrogen atom, R 2a Group A a A C1-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group may be substituted with one or more substituents selected from group E. a R represents a halogen atom or a hydrogen atom, which may be substituted with one or more more selected substituents. 3a is group C a A C2-C6 chain hydrocarbon group, a C3-C6 alicyclic hydrocarbon group, or a 3-6 membered non-aromatic heterocyclic group which may be substituted with one, two, three, four, or five more selected substituents {the C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a This represents {may be substituted with one or more more selected substituents}, R 4a Group A a R represents a C1-C4 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a halogen atom, or a hydroxyl group, which may be substituted with one or more more selected substituents. 5a Group A a Z represents a C1-C4 chain hydrocarbon group, a cyclopropyl group, a C1-C3 alkoxy group, a C1-C3 haloalkoxy group, a cyano group, a halogen atom, a hydroxyl group, or a hydrogen atom, which may be substituted with one or more more selected substituents. 1a This includes a phenyl group and a 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) {The phenyl group and the 5-6 membered aromatic heterocyclic group (excluding the 1,2,4-oxadiazole-3-yl group) belong to group D a Group B a C5-C6 alicyclic hydrocarbon groups, group B, which may be substituted with one or more more selected substituents. a A C3-C4 cycloalkyl group, or OR, which may be substituted with one or more more selected substituents. 10a Represents R 10a This refers to a C3-C8 alicyclic hydrocarbon group or a 3-8 membered non-aromatic heterocyclic group {The C3-C8 alicyclic hydrocarbon group and the 3-8 membered non-aromatic heterocyclic group belong to group E a This represents {may be substituted with one or more more selected substituents}. Group A a : C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group {The C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a Group B: A group consisting of halogen atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more more selected substituents. a : Oxo group, thioxo group, C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group, {The C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a A group consisting of halogen atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more more selected substituents. Group C a : A group consisting of C1-C6 alkoxy groups, C3-C6 alicyclic hydrocarbon groups, 3-6 membered non-aromatic heterocyclic groups, fluorine atoms, cyano groups, nitro groups, and hydroxyl groups, which may be substituted with one or more halogen atoms. Group D a : C1-C6 chain hydrocarbon group, C1-C6 alkoxy group, C1-C6 alkylamino group, C2-C8 dialkylamino group {The C1-C6 chain hydrocarbon group, the C1-C6 alkoxy group, the C1-C6 alkylamino group, and the C2-C8 dialkylamino group may be substituted with one or more halogen atoms}, C3-C6 alicyclic hydrocarbon group, 3-6 membered non-aromatic heterocyclic group {The C3-C6 alicyclic hydrocarbon group and the 3-6 membered non-aromatic heterocyclic group belong to group E a A group consisting of halogen atoms, cyano groups, and nitro groups, which may be substituted with one or more more selected substituents. Group E a Compounds represented by : a group consisting of an oxo group, a halogen atom, a C1-C4 alkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkyl group, a C1-C4 haloalkoxy group, and a cyano group, or their N oxide or salts thereof.

3. A composition containing the compound described in claim 2, its N oxide, or a salt thereof, and an inert carrier.

4. A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound described in claim 2 or its N oxide or salt thereof: Group (a): A group consisting of insecticidal components, acaricidal components, and nematicidal components; Group (b): A bactericidal component; Group (c): A plant growth regulating component; Group (d): A repellent component.

5. A method for controlling plant diseases, comprising treating a plant or soil in which a plant is cultivated with an effective amount of the compound described in claim 2, its N oxide, or a salt thereof, or an effective amount of the composition described in claim 4.

6. Use of the compound according to claim 2, its N oxide, or a salt thereof, or the composition according to claim 4, for the control of plant diseases.

7. Seeds or vegetative reproductive organs containing an effective amount of the compound described in claim 2, its N oxide, or a salt thereof, or an effective amount of the composition described in claim 4.

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