The invention belongs to a synergistic insecticidal composition, a preparation method and an application thereof. The synergistic insecticidal composition is a mixture comprising a compound (A) and a compound (B). The insecticidal composition can be used for preventing and treating various pests, such as armyworms (subtropical armyworms, fall armyworms, yellowstriped armyworms and western yellowstriped armyworms), cotton bollworms, tomato pinworms, tomato fruit borer, sphinges, garden webworms, potato moths, cabbage moths, cabbage loopers, nocturnal insects, asparagus caterpillars, codling moths, peach fruitborers, oriental fruit moths, rose leaf roller stripes, codling olethreutids, plaque screen leafminer, apple leaf miners, rice stem borers, yellow rice borers, pink rice borers, rice leaf rollers, cabbage worms, ostrinia nubilalis, ostrinia furnacalis, melon worms, diaphania indica, pickleworms, oriental tobacco budworms and the like. The preventing effect is higher than that of using the compound (A) or the compound (B) singly.