The invention belongs to the field of functional
polymer membrane preparation, and in particular relates to a
polyethylene micropore diaphragm which is used for improving the use security of a
lithium ion battery and contains an organic / inorganic composite cross-linking
coating, and a preparation method of the
polyethylene micropore diaphragm. The preparation method comprises the following steps: by taking aromatic
polyester polyhydric
alcohol and aromatic
isocyanate as basic components, preparing a
coating liquid by
combing with a cross-linking agent, a
foaming agent, a catalyst and inorganic nano packing at a certain ratio,
coating at least one surface of the
polyethylene micropore diaphragm with the coating liquid, and curing at certain temperature, thereby forming an
organic polymer / inorganic
nanoparticle composite cross-linking coating of a pored foamed structure on the surface of the polyethylene micropore diaphragm. Relatively high
porosity and air permeability of the polyethylene micropore diaphragm are maintained, at the same time the
thermal shrinkage membrane breaking temperature is greatly improved, and the use security property of the battery can be remarkably improved when the polyethylene micropore diaphragm is used as a power
lithium ion battery diaphragm material.