The invention relates to a preparation method of a polydimethylsiloxane porous adsorption material. The method comprises the steps that organo-siloxane is used as a preformed polymer, and a curing agent, a thinning agent, a pore-forming agent and a foaming agent are added; the porous adsorption material is prepared from, by weight, 10-20% of the siloxane preformed polymer, 1-5% of the curing agent, 10-30% of the thinning agent, 10-30% of the pore-forming agent and 30-50% of the foaming agent, uniform stirring is performed, the mixture is dropped into a foaming solution drop by drop, and the porous adsorption material is obtained through specific treatment. The obtained porous material can adsorb various oils and organic solvents such as petroleum ether, carbon tetrachloride, tetrahydrofuran, trichloromethane, normal octane, cyclohexane, normal octane, kerosene and ethyl acetate. The experimental method is novel, simple and easy to implement and low in cost, the material can be recycled, the material is environmentally friendly, and therefore the porous material has the excellent application prospect.