An externally-applied skin pasting film is composed of a water-soluble polymer material, a function additive and distilled water, and concretely comprises sodium polyacrylate, cross-linked polyacrylate, polyvinyl alcohol, sodium alginate, sorbitol, citric acid, glycerin, the function additive and distilled water, wherein the function additive is anyone of or a mixture comprising several of a skin humectants, a skin whitening agent, a cutin softener, a skin anti-wrinkling agent and a skin reparing agent; the skin humectant is anyone of or a mixture comprising several of chondroitin sulfate, allantoin, elastin, lactic acid, hyaluronic acid, sodium alginate, chitosan, chitin, casein, soybean protein, wheat gluten protein and lactalbumin; and the function additive is processed to prepare a water-soluble polymer system, has the characteristics of large drug loading, good biocompatibility with skins, no excitation, no allergy, comfortable application and the like, simultaneously enhances the hydration of the skins and the percutaneous absorption of functional substances, and improves the percutaneous absorption effect.