The invention relates to a method for synthesizing trifluoromethyl-containing carbamate by using carbon dioxide. The method comprises the steps of sequentially adding an organic solvent, alkyne, amine and a Togni reagent into a high-pressure reaction kettle, and then adding copper salt serving as a catalyst and an organic compound containing nitrogen or phosphor serving as a ligand; after that, replenishing the high-pressure reaction kettle with carbon dioxide, and stirring for carrying out a reaction for 5-24h at the temperature of 40-80 DEG C; after the reaction is finished, cooling to the room temperature, slowly discharging carbon dioxide to normal pressure, washing reaction liquid with water, extracting by using ethyl acetate, drying by using anhydrous magnesium sulfate, and then carrying out reduced pressure distillation and concentration to obtain a crude product; then, purifying by means of column chromatography to obtain a trifluoromethyl-containing carbamate compound. The method for synthesizing the trifluoromethyl-containing carbamate has the advantages of being easy in obtaining of raw materials, safe and simple in operation, mild in reaction conditions, good in functional group compatibility, wide in substrate applicability, high in yield of target product, and the like, is beneficial to industrial production, and has potential application prospect in synthesis of pesticides and medicines.