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High impact recycled PET/ABS alloy composition and preparation method thereof

A composition and high-impact technology, applied in the field of polymer materials, can solve the problems of low technical value, physical property level, cost price, etc., and achieve the effects of increasing molecular weight, good batch stability, and increasing compatibility

Active Publication Date: 2013-07-31
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 2011, the recycling rate of PET was about 28% in the United States, 50% in Europe, and about 15% to 20% in China, and most of them were in the primary recycling stage, with low technical value
Although there are some examples in the market at present, their physical properties or cost price are difficult to meet the requirements. Therefore, there has been a great call and demand for PET / ABS alloy materials with high impact and low cost.

Method used

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  • High impact recycled PET/ABS alloy composition and preparation method thereof
  • High impact recycled PET/ABS alloy composition and preparation method thereof
  • High impact recycled PET/ABS alloy composition and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] This embodiment relates to a PET / ABS alloy with excellent impact properties and a preparation method thereof, the method comprising the following steps:

[0066] (1) Weigh each component by weight: regenerated PET is 17.5Kg, PBT is 8Kg, PET transesterification masterbatch-1# is 5Kg, ABS8391 is 50Kg, P / D150 is 20Kg, compatibilizer XIRAN SZ231101Kg, anti- Oxygen 245 is 0.1Kg, antioxidant 168 is 0.1Kg, lubricant PETS is 0.3Kg, silicone powder is 0.2Kg, and nucleating agent nano-montmorillonite is 2Kg.

[0067] (2) Put the material in a medium-speed mixer and mix for 5 to 30 minutes to obtain the mixed material;

[0068] (3) Put the mixed material into a twin-screw extruder, control the screw speed to 300-600rpm, melt and extrude, and granulate to obtain the product. The twin-screw extruder includes 10 temperature control zones, the temperature of temperature control zone 1-2 is 100~260℃, the temperature of temperature control zone 3-4 is 140~260℃, the temperature of tempe...

Embodiment 2

[0070] This embodiment relates to a PET / ABS alloy with excellent impact properties and a preparation method thereof, the method comprising the following steps:

[0071] (1) Weigh each component by weight: regenerated PET is 25.5Kg, PBT is 12.5Kg, PET transesterification masterbatch-1# is 10Kg, ABS3513 is 30Kg, P / D190 is 30Kg, compatibilizer XIRAN SZ231102Kg, The antioxidant 245 is 0.1Kg, the antioxidant 168 is 0.1Kg, the lubricant PETS is 0.3Kg, the silicone powder is 0.2Kg, and the nucleating agent nano-montmorillonite is 3Kg.

[0072] (2) Put the material in a medium-speed mixer and mix for 5 to 30 minutes to obtain the mixed material;

[0073] (3) Put the mixed material into a twin-screw extruder, control the screw speed to 300-600rpm, melt and extrude, and granulate to obtain the product. The twin-screw extruder includes 10 temperature control zones, the temperature of temperature control zone 1-2 is 100~260℃, the temperature of temperature control zone 3-4 is 140~260℃, t...

Embodiment 3

[0075] This embodiment relates to a PET / ABS alloy with excellent impact properties and a preparation method thereof, the method comprising the following steps:

[0076] (1) Weigh each component by weight: regenerated PET is 45Kg, ABS8434 is 30Kg, P / D150 is 20Kg, PET transesterification masterbatch-2# is 5Kg, compatibilizer XIRAN SZ231103Kg, antioxidant 245 is 0.1 Kg, antioxidant 168 is 0.1Kg, lubricant PETS is 0.3Kg, silicone powder is 0.2g, and nucleating agent nano talcum powder is 3Kg.

[0077] (2) Put the material in a medium-speed mixer and mix for 5 to 30 minutes to obtain the mixed material;

[0078] (3) Put the mixed material into a twin-screw extruder, control the screw speed to 300-600 rpm, melt and extrude, and granulate to obtain the product. The twin-screw extruder includes 10 temperature control zones, the temperature of temperature control zone 1-2 is 100~260℃, the temperature of temperature control zone 3-4 is 140~260℃, the temperature of temperature control z...

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Abstract

The present invention discloses a high impact recycled PET / ABS alloy composition and a preparation method thereof. The alloy comprises the following components, by weight, 20-50 parts of recycled PET, 5-30 parts of ABS powder, 10-70 parts of ABS, 0-20 parts of PBT, 0.5-10 parts of PET ester exchange master batch, 0.5-5 parts of a compatilizer, 0.1-1 part of an antioxidant, 0.1-1 part of a lubricant, and 0.1-3 parts of a nucleating agent. The preparation method comprises: preparing the materials according to the ratio, placing the materials into a medium speed mixer to mix for 5-30 min to obtain a mixed material, pouring the mixed material into a twin-screw extruder, and carrying out melt extrusion and granulation to obtain the product, wherein a screw rotation speed is controlled to 300-600 rpm. Compared with the high impact recycled PET / ABS alloy composition in the prior art, the PET / ABS alloy material of the present invention has the following characteristics that: the specific ABS content and the self-made ester exchange master batch are adopted so as to improve an impact performance of the PET / ABS alloy.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a high-impact recycled PET / ABS alloy composition and a preparation method thereof. Background technique [0002] Problems such as white pollution, climate warming, and resource shortages have prompted calls for environmentally friendly materials to grow louder and louder. Green and renewable, reducing material carbon emissions has become the development policy of many companies and even many countries. Now there are many requirements and standards for the environmental protection and renewability of materials in the industry, such as RoHS, WEEE, EuP, EPEAT and so on. Based on the above background, the use of green renewable materials will become a future trend. [0003] According to reports, the global PET packaging consumption in 2015 will exceed 14.5 million tons. And the average annual compound growth rate in the Asia-Pacific region is expected to reach 7.4%, while the aver...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L25/14C08L55/02C08J3/22B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 高磊李强罗明华辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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