Method for preparing cyclic olefin copolymer composite insulating dielectric film

By grafting polyimide in cycloolefin copolymer, changing the chain conformation and local arrangement, the cycloolefin copolymer composite insulating dielectric film is solved, and the insulation performance deterioration and energy storage efficiency of polymer dielectric films under high temperature or high electric field is achieved, achieving efficient breakdown performance and energy storage performance improvement.

CN119081183BActive Publication Date: 2025-08-29HARBIN UNIV OF SCI & TECH
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Patent Information

Application Number
CN202411209219.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-08-30
Publication Date
2025-08-29
Estimated Expiration
2044-08-30

AI Technical Summary

Technical Problem

The existing polymer dielectric film capacitors have deteriorated insulation performance and reduced energy storage efficiency under high temperature or high electric field conditions.

Method used

By grafting polyimide in the cycloolefin copolymer, a large number of fluorine atoms and large pendant groups of benzene rings are introduced, the conformation and local arrangement of the polymer chain are changed, and trap sites are introduced to prepare a cycloolefin copolymer composite insulating dielectric film.

Benefits of technology

It significantly improves the dielectric breakdown field strength, discharge energy density and charge and discharge efficiency, solves the problems of deterioration of insulation performance and reduction of energy storage efficiency under high temperature or high electric field conditions, and is simple and environmentally friendly, suitable for industrial production.

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Abstract

A method for preparing a cyclic olefin copolymer composite insulating dielectric film, belonging to the field of capacitors. This invention addresses the problem of deteriorating insulation properties and reduced energy storage efficiency in existing polymer dielectric film capacitors under high temperature or high electric field conditions. The method includes the following steps: 1. Preparing a cyclic olefin copolymer solution; 2. Preparing an anhydride-grafted cyclic olefin copolymer solution; 3. Adding a high-polarity diamine monomer to the anhydride-grafted cyclic olefin copolymer solution for reaction, followed by coating and gradient-heating thermal imidization treatment. This method is used to prepare a cyclic olefin copolymer composite insulating dielectric film.
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