Molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin as well as preparation and application thereof

Through hydrothermal synthesis and surface functional group modification technology, modified urea formaldehyde/melamine resin was prepared, which solved the problem of fast curing speed and low compressive strength of existing resin sand-sand solidifying agents at high temperatures, achieved higher temperature resistance and compressive strength, and significantly improved the sand-solidization effect and permeability retention rate.

CN119684614AActive Publication Date: 2025-03-25PETROCHINA CO LTD
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Patent Information

Application Number
CN202311230204.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-09-22
Publication Date
2025-03-25
Estimated Expiration
2043-09-22

AI Technical Summary

Technical Problem

The existing resin sand solidifiers have problems such as too fast curing speed, low compressive strength, poor tolerance to formation fluids and low permeability retention at high temperatures, which are difficult to meet the needs of medium and high liquid yields in petroleum mining.

Method used

Molybdenum disulfide nanosheets were prepared by hydrothermal synthesis, and the surface functional group modification and copolymerization reaction were carried out by copolymerization of aldehydes and polyamine compounds with the modified molybdenum disulfide nanosheets to form a modified urea formaldehyde/melamine resin, which increased its stability and compressive strength at high temperatures.

Benefits of technology

The temperature resistance and compressive strength of the resin are improved, the dispersion of nanosheets in the resin is improved, the binding ability with sand and gravel is enhanced, and the sand solidification effect and permeability retention rate are significantly improved.

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Abstract

The invention discloses molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin as well as preparation and application thereof. A preparation method of the molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin comprises the following steps: (1) preparing molybdenum disulfide nanosheets from a sulfur source and a molybdenum source by adopting a hydrothermal synthesis method; (2) carrying out surface functional group modification on the molybdenum disulfide nanosheet by using a surface functional group modifier; (3) carrying out copolymerization reaction on aldehydes, a compound containing polyamido and the molybdenum disulfide nanosheet modified by the surface functional group in the step (2) to obtain molybdenum disulfide nanosheet urea formaldehyde / melamine resin; and (4) modifying the molybdenum disulfide nanosheet urea formaldehyde / melamine resin by using a silane coupling agent to obtain the molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin. According to the method disclosed by the invention, the polymer is copolymerized and grafted onto the molybdenum disulfide nanosheet, so that the problems that urea formaldehyde / melamine resin is insufficient in temperature resistance and poor in pressure resistance after being solidified with a rock core are effectively solved.
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