Iridium complex and iridium complex / natural polymer composite material as well as preparation method and application of iridium complex / natural polymer composite material

By modifying iridium complexes with long alkyl chains and combining them with natural polymers, the problems of aggregation quenching and hydrophobicity of iridium complexes are solved, achieving high efficiency and stable optical performance, which is suitable for flexible OLED devices and biocompatible optical sensors.

CN120817985AActive Publication Date: 2025-10-21ANHUI SCI & TECH UNIV
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Patent Information

Application Number
CN202511319413.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-09-16
Publication Date
2025-10-21
Estimated Expiration
2045-09-16

AI Technical Summary

Technical Problem

Traditional iridium complexes are prone to aggregation and quenching in the solid state or at high concentrations, have poor hydrophobicity, and are prone to phase separation or luminescence quenching when complexed with natural polymers. Existing technologies have failed to effectively synergize their optical advantages and film-forming properties.

Method used

Iridium complexes were designed and synthesized by modifying the ligands of iridium complexes with long alkyl chains, and then combined with natural polymer materials such as chitosan or sodium alginate to regulate their photophysical properties, thus preparing iridium complex/natural polymer composite materials.

Benefits of technology

The problem of aggregation fluorescence quenching in iridium complexes has been solved, improving the hydrophobicity, film uniformity, and photophysical properties of the composite material. This results in high-intensity, tunable, and stable luminescence, making it suitable for flexible OLED devices and biocompatible optical sensors.

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Abstract

The invention discloses an iridium complex, an iridium complex / natural polymer composite material as well as a preparation method and application of the iridium complex / natural polymer composite material, and relates to the technical field of organic photoelectric functional materials. According to the present invention, the problem of aggregation fluorescence quenching of the traditional iridium complex under the high concentration or the solid state is solved, the aggregation-induced emission effect is significantly improved, the hydrophobicity, the film forming uniformity and the photophysical property of the composite material can be optimized, and the adjustable (yellow light to orange light) high-intensity stable light emission can be achieved under the 365 nm ultraviolet excitation.
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