Polyimide film main body material with high light transmittance, film coating, composite film material and preparation and application thereof

By introducing aromatic phosphorus-containing diamine and alicyclic dianhydride monomers into polyimide films, and combining them with fillers and additives, a composite film structure is formed, which solves the problem of balancing optical transparency and antigenic oxygen properties, improves the light transmittance and corrosion resistance of the film, and is suitable for aerospace and flexible optoelectronic fields.

CN122080403AActive Publication Date: 2026-05-26CHINA UNIV OF GEOSCIENCES (BEIJING)
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Patent Information

Application Number
CN202610010183.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-01-06
Publication Date
2026-05-26
Estimated Expiration
2046-01-06

AI Technical Summary

Technical Problem

Existing polyimide films present a conflict between optical transparency and antigenic oxygen properties, and the long-term effectiveness and stability of the antigenic oxygen protective layer are insufficient, making it prone to "drilling" phenomena.

Method used

Aromatic phosphorus-containing diamine and alicyclic dianhydride monomers are mixed with organic solvents, and fillers and additives are added to form a polyimide film substrate through polymerization reaction. The substrate is then coated onto a polyimide base film to form a composite film structure.

Benefits of technology

It improves the light transmittance and interfacial adhesion of the thin film, while enhancing its resistance to atomic oxygen erosion, maintaining the optical transparency and mechanical properties of the thin film, making it suitable for the field of space exploration.

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Abstract

The invention discloses a high-light-transmittance polyimide film main body material, a film coating, a composite film material and preparation and application thereof, and belongs to the technical field of materials. The invention provides a polyimide film with high optical transparency and strong atomic oxygen corrosion resistance aiming at the problems that the surface of a transparent atomic oxygen resistant polyimide film in the prior art is easy to crack and the optical performance is obviously reduced after radiation. According to the technical scheme, the high-light-transmittance polyimide film main body material is characterized by comprising aromatic phosphorus-containing diamine, an alicyclic dianhydride monomer and an organic solvent, the aromatic phosphorus-containing diamine is 2, 5-bis [(4-aminophenoxy) phenyl] diphenyl phosphine oxide; the alicyclic dianhydride monomer is selected from at least one of 1, 2, 3, 4-cyclobutane tetracarboxylic acid dianhydride, 1, 3-dimethyl-cyclobutane-1, 2, 3, 4-tetracarboxylic acid dianhydride and 1, 2, 3, 4-tetramethyl-1, 2, 3, 4-cyclobutane tetracarboxylic acid dianhydride.
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