Method for full resource utilization of soda ash plant waste residue wastewater

By using mixed heating dissociation and gas carbonization precipitation technology, the problems of incomplete component extraction and material balance in the treatment of waste residue and wastewater in soda ash plants have been solved. This has enabled the preparation of high-value products and full resource utilization, reduced energy consumption and environmental pollution, and is suitable for industrial applications.

CN122403475APending Publication Date: 2026-07-17CARBON SILVER (HEBEI XIONGAN) NEW ENERGY TECHNOLOGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CARBON SILVER (HEBEI XIONGAN) NEW ENERGY TECHNOLOGY CO LTD
Filing Date
2026-05-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for treating waste residue and wastewater from soda ash plants suffer from problems such as incomplete component extraction, low product added value, high energy consumption, and difficulty in balancing system materials. These issues make it difficult to achieve full disposal and closed-loop recycling, and traditional disposal methods lead to environmental pollution.

Method used

By mixing waste residue, wastewater, and circulating mother liquor with ammonium salt and heating to dissociate them, ammonia and carbon dioxide are recovered. Magnesium hydroxide is extracted by adding calcium source to the filtrate and carbonization is carried out. Light calcium carbonate is prepared by carbonization using the recovered gas. The calcium extraction filtrate is purified by NaCl to generate sodium carbonate, realizing a closed-loop cycle of the extractant and mother liquor, and preparing a variety of high-value products.

Benefits of technology

It achieves efficient extraction of all components from waste residue and wastewater, significantly increases the added value of resource-based products, reduces the consumption of chemical reagents and water resources, reduces environmental pollution, and has mild process conditions that are easy to implement industrially.

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Abstract

本发明公开了一种纯碱厂废渣废水全量资源化的方法。将废渣、废水、循环母液与铵盐混合加热离解,回收氨气与二氧化碳;滤液加钙源沉淀提取氢氧化镁;利用回收气体碳化制备轻质碳酸钙;提钙滤液经NaCl精制后,通过定向补加氯化铵和碳酸钙原位生成补充气源,联合回收气体碳化制备碳酸钠,初级母液返回循环;最后用部分碳酸钠中和废水制取碳酸钙并回收NaCl溶液。本发明突破了系统碳化气源不守恒的技术瓶颈,实现了提取剂与母液的高度闭环循环,将废弃物全组分转化为多种高值产品,全程无二次污染。
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