Battery System

Abstract

To accurately diagnose deterioration of a battery pack.SOLUTION: A battery system 200 includes a monitoring unit 4 that detects a voltage Vp between batteries 3 included in a battery pack 2, a current IB, and a temperature Tb of the battery 3. An ECU 8 uses detection results of the monitoring unit 4 to increment a count value when SOC variations between the batteries 3 exceed a threshold. The ECU 8 uses detection results of the monitoring unit 4 to increment the count value when positive electrode potential of the battery 3 falls below the threshold. When an amount of change in any of the count values becomes equal to or greater than a predetermined value, the ECU 8 diagnoses that the battery pack 2 is deteriorated.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a battery system. [Background technology]

[0002] Japanese Patent Laid-Open Publication No. 2022-111574 (Patent Document 1) discloses a battery system that diagnoses the deterioration of a battery pack including multiple blocks connected in parallel using the SOC (State Of Charge) variation between each block and the positive electrode potential of each block. The battery system described in Patent Document 1 diagnoses whether the battery pack is prone to deterioration based on the number of times (frequency) that a block with an SOC variation greater than a predetermined amount occurs within a specified time and the number of times (frequency) that a block with a positive electrode potential equal to or lower than a specified potential occurs within a specified time. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2022-111574 A Summary of the Invention [Problem to be solved by the invention]

[0004] When the temperature variation between the cells constituting the battery pack is large, the SOC variation between the cells fluctuates, and even if the battery pack is not deteriorated, the SOC variation between the cells may become larger than a predetermined amount. Also, depending on the usage of the battery pack, even if the battery pack is not deteriorated, the positive electrode potential of the battery may become equal to or lower than a specified potential. Therefore, when diagnosing deterioration of the battery pack based on the number of times that the SOC variation between the cells occurs or the number of times that the positive electrode potential of the battery becomes equal to or lower than a specified potential, there is a possibility of misdiagnosis.

[0005] An object of the present disclosure is to accurately diagnose the deterioration of a battery pack. [Means for solving the problem]

[0006] (1) A battery system according to the present disclosure includes an assembled battery having multiple batteries connected thereto, and a control device that diagnoses a degraded state of the assembled battery. The control device of the battery system includes a parameter calculation unit that repeatedly calculates a parameter indicative of degradation of the assembled battery, a comparison unit that compares the parameter with a threshold, a count unit that adds a count value based on a comparison result between the parameter and the threshold, a change amount calculation unit that calculates an amount of change in the count value, and a diagnosis unit that determines that the assembled battery is degraded when the amount of change is equal to or greater than a predetermined value.

[0007] According to this configuration, the parameter calculation unit repeatedly calculates a parameter representing battery deterioration. The parameter representing battery deterioration may be, for example, an SOC variation between batteries or a positive electrode potential of the battery. The parameter representing battery deterioration is compared with a threshold value by the comparison unit. The count unit adds the count value by incrementing the count value based on a comparison result between the parameter and the threshold value.

[0008] The change amount calculation unit calculates the amount of change in the count value. The amount of change in the count value is an amount that represents the slope of the count value, and is an amount that represents the slope of the trajectory of the count value. For example, it may be a value obtained by dividing the count value by the accumulated usage time (accumulated operation time) of the battery pack, or may be an increase in the count value per predetermined usage time (per predetermined operation time). Furthermore, if the battery pack is mounted on a vehicle, it may be a value obtained by dividing the count value by the accumulated mileage, or may be an increase in the count value per predetermined mileage.

[0009] The diagnosis unit determines that the battery pack has deteriorated when the change in the count value reaches or exceeds a predetermined value. As deterioration of the battery pack progresses, the count value is continuously incremented, and the battery pack is diagnosed as deteriorated when the change in the count value reaches or exceeds a predetermined value. This makes it possible to suppress erroneous diagnosis due to large temperature variations between the batteries constituting the battery pack and erroneous diagnosis due to the usage pattern of the battery pack, and makes it possible to accurately diagnose deterioration of the battery pack.

[0010] (2) The parameter representing deterioration of the battery pack may be SOC variation among the plurality of batteries, and the counting unit may increment the count value by one when the SOC variation is greater than a threshold value.

[0011] According to this configuration, when the SOC variation between the batteries, for example the difference between the maximum SOC and the minimum SOC of each battery in the battery pack, is greater than a threshold value, the count value is incremented by 1. As the battery pack deteriorates, the SOC variation between the batteries increases, so the SOC variation between the batteries can be used as a parameter representing the deterioration of the battery pack.

[0012] (3) In the above (2), the control device may calculate temperature variations among the multiple batteries and set the threshold value based on the temperature variations.

[0013] According to this configuration, the threshold value is set based on the temperature variation between the batteries. The temperature variation may be, for example, the difference between the maximum and minimum temperatures of each battery in the battery pack. When the temperature variation between the batteries is large, the SOC variation between the batteries tends to be large even if the battery pack is not deteriorated. By setting the threshold value based on the temperature variation between the batteries, it is possible to diagnose deterioration of the battery pack with greater accuracy.

[0014] (4) In the above (2) and (3), the diagnosing unit may be configured not to diagnose deterioration of the battery pack when the amount of change is decreasing.

[0015] According to this configuration, when the amount of change in the count value is decreasing, the deterioration of the battery pack is not diagnosed. In particular, when the batteries are nickel-metal hydride batteries or nickel-cadmium batteries, a memory effect occurs. When the memory effect occurs, variations occur in the OCV (Open Circuit Voltage) characteristics between the batteries. For this reason, even if the battery pack is not deteriorated, the amount of change in the count value using the SOC variation between the batteries may become large.

[0016] The memory effect saturates after the battery has been used for some time and has been repeatedly charged and discharged (the decrease in the battery's OCV due to the memory effect saturates). Therefore, the amount of change in the count value shows a decreasing trend from when the memory effect appears until it saturates. When the amount of change in the count value is decreasing, the deterioration diagnosis of the battery pack is not performed, so that erroneous diagnosis due to the memory effect can be suppressed.

[0017] (5) The parameter representing deterioration of the battery pack may be the positive electrode potential of the battery, and the counting unit may increment the count value by one when the positive electrode potential is lower than a threshold value.

[0018] According to this configuration, when the positive electrode potential of the battery is lower than the threshold value, the count value is incremented by 1. In particular, when the battery is a nickel-metal hydride battery, the positive electrode potential of the battery decreases as the battery pack deteriorates, and therefore the positive electrode potential of the battery can be used as a parameter representing deterioration of the battery pack. Effect of the Invention

[0019] According to the present disclosure, deterioration of a battery pack can be diagnosed with high accuracy. [Brief description of the drawings]

[0020] [Figure 1] 1 is a block diagram illustrating a schematic overall configuration of an electric vehicle equipped with a battery system according to an embodiment of the present disclosure. [Diagram 2] 5 is a flowchart showing a procedure of degradation diagnosis processing in the present embodiment. [Diagram 3] 10 is a flowchart showing a procedure for a ΔSOC degradation level determination process. [Figure 4] 13A, 13B, and 13C are diagrams illustrating a method for setting a threshold value Rft. [Diagram 5] 10 is a flowchart showing a procedure for a process of determining a deterioration level of a positive electrode potential. [Figure 6]13A, 13B, and 13C are diagrams illustrating the deterioration diagnosis of the assembled battery based on the count values ​​CTN1, CTN2 and the deterioration diagnosis of the assembled battery based on the amounts of change dCNT1, dCNT. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0021] Hereinafter, embodiments of the present disclosure will be described in detail with reference to the drawings. In the drawings, the same or corresponding parts are denoted by the same reference characters, and the description thereof will not be repeated.

[0022] In the following, a configuration in which a battery system according to an embodiment of the present disclosure is mounted on an electric vehicle will be described as an example. The electric vehicle may be a hybrid vehicle (including a plug-in hybrid vehicle), an electric vehicle, or a fuel cell vehicle. In addition, the use of the battery system is not limited to vehicle use, and may be stationary.

[0023] FIG. 1 is a block diagram showing a schematic overall configuration of an electric vehicle equipped with a battery system according to an embodiment of the present disclosure. The vehicle 100 includes a battery system 200. The battery system 200 includes a battery pack 1. The battery pack 1 includes a plurality of assembled batteries 2 connected in parallel to each other. Each of the assembled batteries 2 includes a plurality of batteries (battery cells: single cells) 3 connected in series. Each of the assembled batteries 2 is provided with a monitoring unit 4. The battery system 200 further includes a system main relay (SMR) 7 and a control device (ECU: Electronic Control Unit) 8. The vehicle 100 further includes a power control unit (PCU: Power Control Unit) 91, a motor generator 92, a power transmission gear 93, and drive wheels 94.

[0024] The battery pack 1 is a rechargeable DC power source. The number of assembled batteries 2 included in the battery pack 1 is three in FIG. 1, but this number is not particularly limited. The number of batteries 3 included in the assembled battery 2 is arbitrary and may be, for example, 54. The battery pack 1 may be composed of a single assembled battery 2 rather than a plurality of assembled batteries 2 connected in parallel. In this case, the number of batteries 3 included in the assembled battery 2 may be, for example, 168.

[0025] In this embodiment, the battery 3 is a single cell (cell) made of a nickel-metal hydride battery. The battery 3 is, for example, a rectangular sealed cell, and includes an electrode body and an electrolyte solution housed in a case. The electrode body includes a positive electrode, a negative electrode, and a separator. Various conventionally known materials can be used as the materials for the electrode body and the electrolyte solution. As an example, the positive electrode includes a positive electrode active material layer including nickel hydroxide (Ni(OH)2 or NiOOH) and an active material support such as foamed nickel. The negative electrode includes a hydrogen storage alloy. The separator is made of a nonwoven fabric made of synthetic fibers that have been hydrophilically treated. The electrolyte solution is an alkaline aqueous solution including potassium hydroxide (KOH) or sodium hydroxide (NaOH), etc.

[0026] The monitoring unit 4 detects the voltage Vb of each battery 3 , the current IB flowing through the battery pack 2 (through each battery 3 ), and the temperature Tb of each battery 3 .

[0027] The SMR 7 is electrically connected to a power line connecting the battery pack 1 and the PCU 91. The SMR 7 is opened and closed in response to a control command from the ECU 8. When the SMR 7 is closed, power can be exchanged between the battery pack 1 and the PCU 91.

[0028] The ECU 8 includes a processor 81 such as a CPU (Central Processing Unit), a memory 82 such as a ROM (Read Only Memory) and a RAM (Random Access Memory), and an input / output port (not shown). The processor 81 controls each device based on signals received from each sensor and maps and programs stored in the memory 82 so that the vehicle 100 and the battery system 200 are in a desired state. In this embodiment, a main process executed by the ECU 8 is a "deterioration diagnosis process" for the battery pack 2.

[0029] The PCU 91 includes an inverter and a converter. When the battery pack 1 is discharged, the converter boosts the voltage supplied from the battery pack 1 and supplies it to the inverter. The inverter converts the DC power supplied from the converter into AC power to drive the motor generator 92. On the other hand, when the battery pack 1 is charged, the inverter converts the AC power generated by the motor generator 92 into DC power and supplies it to the converter. The converter reduces the voltage supplied from the inverter and supplies it to the battery pack 1.

[0030] The motor generator 92 is, for example, a three-phase AC rotating electric machine. The output torque of the motor generator 92 is transmitted to drive wheels 94 via a power transmission gear 93. The motor generator 92 is also capable of generating electricity using the rotational force of the drive wheels 94 during regenerative braking of the vehicle 100.

[0031] 2 is a flowchart showing the procedure of the degradation diagnosis process in this embodiment. This flowchart is executed, for example, when a predetermined condition is satisfied. Each process is realized by software processing by the ECU 8, which is a control device, but may also be realized by hardware (electrical circuitry) arranged in the ECU 8.

[0032] The degradation diagnosis process in this embodiment is a process for diagnosing degradation of the battery pack 2 from the viewpoint of SOC variations among the batteries 3 and from the viewpoint of the amount of decrease in the positive electrode potential of the batteries 3. The degradation diagnosis process is executed for each battery pack 2. First, in step (hereinafter, step will be abbreviated as "S") 10, a ΔSOC degradation level is acquired. The ΔSOC degradation level is the degradation level of the battery pack 2 diagnosed based on the SOC variations among the batteries 3 included in the battery pack 2.

[0033] 3 is a flowchart showing the procedure of the ΔSOC deterioration level determination process, which is called from the main routine and executed at predetermined intervals, for example.

[0034] 3, first, in S30, the SOC variation (ΔSOC) between the batteries 3 is calculated. In this embodiment, the SOC of each battery 3 is calculated from the SOC-OCV characteristics using the voltage Vb of the battery 3 detected by the monitoring unit 4. Note that the SOC may be calculated by also using a coulomb counting method using the current IB. Then, the difference between the maximum SOCmax of the SOC of the batteries 3 included in the battery pack 2 and the minimum SOCmin of the SOC of the batteries 3 included in the battery pack 2 is calculated as ΔSOC (ΔSOC=SOCmax-SOCmin). Next, in S31, the maximum ΔSOC (ΔSOCmax) is stored. For example, if the ΔSOC calculated in the current routine is greater than the stored ΔSOCmax, ΔSOCmax is rewritten (updated) to the ΔSOC calculated in the current routine and stored.

[0035] In S32, it is determined whether or not the ΔSOC calculated in S30 is equal to or greater than a threshold value Rft. The threshold value Rft is set based on the temperature variation among the batteries 3 included in the battery pack 2.

[0036] 4 is a diagram for explaining a method for setting the threshold value Rft. When there is a large temperature variation among the batteries 3, the ΔSOC between the batteries 3 tends to become large even if the assembled battery 2 is not deteriorated. By setting the threshold value Rft based on the temperature variation among the batteries 3, deterioration of the assembled battery 2 can be diagnosed with greater accuracy.

[0037] FIG. 4(A) shows the temperature Tb of the battery 3 during a trip of the vehicle 100. A trip is the period from when the power switch (ignition switch) is turned ON to start traveling until when the power switch is turned OFF to end traveling. FIG. 4(A) shows the transition of the temperature Tbh of the battery 3 with the highest temperature and the temperature Tbl of the battery 3 with the lowest temperature among the batteries 3 included in the battery pack 2. In this embodiment, each time a trip ends, the temperature at which the temperature Tbh became the highest is stored as the current maximum temperature (Tbmax). In addition, the difference between the temperature Tbh and the temperature Tbl at that time is stored as the current temperature variation (ΔTbmax).

[0038] Fig. 4(B) shows the transition of the cumulative average of Tbmax (Tbmave) and the cumulative average of ΔTbmax (ΔTbmave). As shown in Fig. 4(B), each time a trip of the vehicle 100 ends, the arithmetic mean (arithmetic average) of the stored Tbmax is calculated and stored as Tbmave. In addition, each time a trip of the vehicle 100 ends, the arithmetic mean of the stored ΔTbmax is calculated and stored as ΔTbmave.

[0039] Fig. 4C shows a calculation map of the threshold Rtf. In Fig. 4C, the vertical axis is ΔTbmave and the horizontal axis is Tbmave. The threshold Rtf is set to a larger value as ΔTbmave increases and as Tbmave increases. The threshold Rtf is calculated from the current ΔTbmave and the current Tbmave using the calculation map shown in Fig. 4C every time S32 is processed.

[0040] 3, in S32, ΔSOC is compared with a threshold value Rtf set based on the temperature variation (ΔTbmax) between the batteries 3. If ΔSOC is equal to or greater than the threshold value Rtf, a positive determination is made and the process proceeds to S33. If ΔSOC is smaller than the threshold value Rtf, a negative determination is made and the process proceeds to S34.

[0041] In S33, the count value CNT1 is incremented, and the process proceeds to S34. The initial value of the count value CNT1 is 0, and the count value CNT1 is incremented every time S33 is executed. When the battery pack 2 is replaced, the count value CNT1 is reset to 0.

[0042] In S34, a change amount dCNT1 of the count value CNT1 is calculated. The change amount dCNT1 is an amount that represents the slope of the count value CNT1. In this embodiment, the change amount dCNT1 is calculated by dividing the count value CNT1 by the accumulated travel distance Mc of the vehicle 100 (dCNT1=CNT1 / Mc). The change amount dCNT1 may be an increase amount of the count value CNT1 per predetermined travel distance. For example, when the count value CNT1 at a certain travel distance Mo before the present (this time) is CNT1o, it may be calculated from "dCNT1=(CNT1-CNT1o) / Mo". The change amount dCNT1 may be a value obtained by dividing the count value CNT1 by the accumulated usage time Tc of the battery pack 2 (dCNT1=CNT1 / Tc). The change amount dCNT1 may be an increase amount of the count value CNT1 per predetermined usage time. For example, when the count value CNT1 from the present (current) time before a certain period of use To is taken as CNT1to, the calculation may be made as follows: dCNT1=(CNT1-CNT1to) / To.

[0043] In the next S35, it is determined whether the amount of change dCNT1 is greater than the previous value. The previous value is the value of the amount of change dCNT1 when this routine was processed last time. If the amount of change dCNT1 is greater than the previous value, a positive determination is made and the routine proceeds to S36. If the amount of change dCNT1 is equal to or less than the previous value, a negative determination is made and the current routine is terminated.

[0044] In S36, it is determined whether the amount of change dCNT1 is greater than the threshold value Th1. If the amount of change dCNT1 is greater than the threshold value Th1, an affirmative determination is made and the program proceeds to S37. If the amount of change dCNT1 is equal to or less than the threshold value Th1, a negative determination is made and the current routine is terminated.

[0045] In S37, it is determined whether the amount of change dCNT1 is greater than a threshold value Th2. The threshold value Th2 is set to be greater than the threshold value Th1 (Th2>Th1). If the amount of change dCNT1 is greater than the threshold value Th2, a positive determination is made, and the routine proceeds to S38, where the ΔSOC deterioration level of the battery pack 2 is set to "2", and this routine ends. If the amount of change dCNT1 is equal to or less than the threshold value Th2, a negative determination is made, and the routine proceeds to S39.

[0046] In S39, it is determined whether ΔSOCmax is greater than a predetermined value α. If ΔSOCmax is greater than the predetermined value α, a positive determination is made and the process proceeds to S38, where the degradation level of the battery pack 2 is set to "ΔSOC degradation level 2," and the current routine is terminated. If ΔSOCmax is equal to or less than the predetermined value α, the process proceeds to S40, where the ΔSOC degradation level of the battery pack 2 is set to "1," and the current routine is terminated.

[0047] 2, in S11, the positive electrode potential deterioration level is acquired. The positive electrode potential deterioration level is the deterioration level of the battery pack 2 diagnosed based on the decrease in the positive electrode potential of the batteries 3 included in the battery pack 2.

[0048] 5 is a flowchart showing the procedure of a process for determining the deterioration level of the positive electrode potential. This process is called from the main routine and executed at predetermined intervals, for example.

[0049] In FIG. 5, first, in S50, a calculation process of the positive electrode potential Vp of the battery 3 is performed. The positive electrode potential Vp of the battery 3 is calculated using the voltage Vb, current IB, and temperature Tb of the battery 3 detected by the monitoring unit 4, as described in, for example, JP 2018-6029 A. The cell resistance (battery resistance) R is calculated from the voltage Vb and current IB, and the positive electrode resistance Rp is calculated from a correspondence map between the temperature Tb and the positive electrode resistance Rp. The negative electrode resistance Rn is calculated from the difference between the cell resistance R and the positive electrode resistance Rp (Rn=R-Rp). The negative electrode potential Vn is calculated by adding the product of the current IB and the negative electrode resistance Rn to the negative electrode open circuit potential OCVn (Vn=OCVn+Rn×IB). Then, the positive electrode potential Vp is calculated by adding the voltage Vb to the negative electrode potential Vn (Vp=Vn+Vb). The negative electrode open circuit potential OCVn is previously obtained by an experiment or the like. The calculation process of the positive electrode potential Vp is performed for each battery 3 included in the battery pack 2, and the subsequent processes from S51 onwards are executed for each battery 3 positive electrode potential Vp.

[0050] In S51, it is determined whether the positive electrode potential Vp is lower than a specified potential V0. The specified potential V0 is an example of a "threshold value" in the present disclosure, and may be a positive electrode protection potential that is set in advance in consideration of a potential at which positive electrode deterioration (dissolution of the conductive material in the positive electrode active material layer) may occur. When the positive electrode potential Vp is lower than the specified potential V0, a ​​positive determination is made and the process proceeds to S52, and when the positive electrode potential Vp is equal to or higher than the specified potential V0, a ​​negative determination is made and the process proceeds to S53.

[0051] In S52, the count value CNT2 is incremented, and the process proceeds to S53. The initial value of the count value CNT2 is 0, and the count value CNT2 is incremented every time S52 is executed. When the battery pack 2 is replaced, the count value CNT2 is reset to 0.

[0052] In S53, a change amount dCNT2 of the count value CNT2 is calculated. The change amount dCNT2 is an amount that represents the slope of the count value CNT2. In this embodiment, the change amount dCNT2 is calculated by dividing the count value CNT2 by the accumulated travel distance Mc of the vehicle 100 (dCNT2=CNT2 / Mc). The change amount dCNT2 may be an increase amount of the count value CNT2 per predetermined travel distance. For example, when the count value CNT2 from the present (present) to a certain travel distance Mo before is CNT2o, the change amount dCNT2 may be calculated as "dCNT2=(CNT2-CNT2o) / Mo". The change amount dCNT2 may be a value obtained by dividing the count value CNT2 by the accumulated usage time Tc of the battery pack 2 (dCNT2=CNT2 / Tc). The change amount dCNT2 may be an increase amount of the count value CNT2 per predetermined usage time. For example, when the count value CNT2 from the present (current time) a certain period of use To is taken as CNT2to, the calculation may be made as "dCNT2=(CNT2-CNT2to) / To".

[0053] In S54, it is determined whether the change amount dCNT2 is greater than the threshold value Th3. If the change amount dCNT2 is greater than the threshold value Th3, an affirmative determination is made and the routine proceeds to S55. If the change amount dCNT2 is equal to or less than the threshold value Th3, a negative determination is made and the current routine is terminated.

[0054] In S55, it is determined whether the amount of change dCNT2 is greater than a threshold value Th4. The threshold value Th4 is set to be greater than the threshold value Th3 (Th4>Th3). If the amount of change dCNT2 is greater than the threshold value Th4, an affirmative determination is made, the process proceeds to S56, the positive electrode potential deterioration level of the battery pack 2 is set to "2", and the current routine is terminated. If the amount of change dCNT2 is equal to or less than the threshold value Th4, a negative determination is made, the process proceeds to S57, the positive electrode potential deterioration level of the battery pack 2 is set to "1", and the current routine is terminated.

[0055] Returning to FIG. 2 again, in S12, it is determined whether the ΔSOC degradation level acquired in S10 is equal to or greater than 1. If the ΔSOC degradation level is less than 1 (if the ΔSOC degradation level has not been set), a negative determination is made and the process proceeds to S13. If the ΔSOC degradation level is equal to or greater than 1, a positive determination is made and the process proceeds to S15.

[0056] In S13, it is determined whether the positive electrode potential deterioration level acquired in S11 is equal to or greater than 1. If the positive electrode potential deterioration level is less than 1 (if the positive electrode potential deterioration level has not been set), a negative determination is made and the process proceeds to S14, where it is determined that no deterioration has occurred in the battery pack 2 and the current routine is terminated. If the positive electrode potential deterioration level is equal to or greater than 1, a positive determination is made and the process proceeds to S15.

[0057] In S15, it is determined whether the ΔSOC degradation level is 2. If the ΔSOC degradation level is not 2, the process proceeds to S16, where the degradation state of the battery pack 2 is determined to be "degradation level 1," and the current routine is terminated. If the ΔSOC degradation level is 2, a positive determination is made, and the process proceeds to S17.

[0058] In S17, it is determined whether the positive electrode potential deterioration level is 2. If the positive electrode potential deterioration level is not 2, the process proceeds to S16, where it is determined that the deterioration state of the battery pack 2 is "deterioration level 1", and the current routine is terminated. If the positive electrode potential deterioration level is 2, an affirmative determination is made and the process proceeds to S18, where it is determined that the deterioration state of the battery pack 2 is "deterioration level 2", and the current routine is terminated.

[0059] According to this embodiment, in FIG. 3, ΔSOC (SOC variation between batteries 3) is calculated in S30, ΔSOC is compared with a threshold value Rft in S32, and if ΔSOC≧Rft, the count value CNT1 is incremented in S33. In S34, the amount of change dCNT1 in the count value CNT1 is calculated. If the amount of change dCNT1 is equal to or greater than the threshold value Th2, the ΔSOC degradation level is set to "2" and Th1 <dCNT1< Th2 If so, the ΔSOC deterioration level is set to "1" (S36 to S40).

[0060] Also, in FIG. 4, the positive electrode potential Vp of the battery 3 is calculated at S50, and at S51, the positive electrode potential Vp is compared with the specified potential V0. When Vp < V0, the count value CTN2 is incremented at S52. At S53, the change amount dCNT2 of the count value CNT2 is calculated. When the change amount dCNT2 is equal to or greater than the threshold value Th4, the positive electrode potential degradation level is set to "2", and " Th3 < dCNT2 < Th4 ", when it is, the positive electrode potential degradation level is set to "1" (from S54 to S57).

[0061] Then, in S12 to S16 of FIG. 2, when at least one of the ΔSOC degradation level or the positive electrode potential degradation level is "1", it is diagnosed that the degradation state of the assembled battery 2 is "degradation level 1", and when the ΔSOC degradation level and the positive electrode potential degradation level are "2", it is diagnosed that the degradation state of the assembled battery is "degradation level 2".

[0062] FIG. 6 is a diagram for explaining the degradation diagnosis of the assembled battery 2 based on the count values CTN1 and CTN2, and the degradation diagnosis of the assembled battery 2 based on the change amounts dCNT1 and dCNT2. The upper part of FIG. 6(A) shows the change in ΔSCO, and the lower part of FIG. 6(A) shows the change in the positive electrode potential Vp. The upper part of FIG. 6(B) shows the transition of the count value CTN1, and the lower part of FIG. 6(B) shows the transition of the count value CTN2.

[0063] In the upper part of FIG. 6(A), the broken line is the change in ΔSOC when the variation in the temperature Tb of the battery 3 included in the assembled battery 2 is large, and the solid line is the change in ΔSOC when the variation in the temperature Tb is small. When the variation in the temperature Tb of the battery 3 is large, as shown by the broken line, even if the assembled battery 2 is not degraded, ΔSOC may exceed the threshold value (a). As shown by the broken line in the upper part of FIG. 6(B), even if the assembled battery 2 is not degraded (even if the assembled battery 2 is normal), the count value CTN1 may exceed the determination value, and as shown by the hatched line, there is a possibility of misdiagnosing the degradation of the assembled battery 2. Note that in the upper part of FIG. 6(B), the solid line shows the transition of the count value CNT1 when the variation in the temperature Tb is small.

[0064] In the lower part of FIG. 6(A), the dashed line indicates the change in the positive electrode potential Vp when the vehicle 100 is operated so that the discharge amount of the battery pack 2 is increased, and the solid line indicates the change in the positive electrode potential Vp when the vehicle 100 is operated so that the discharge amount of the battery pack 2 falls within a predetermined range. When the vehicle 100 is operated so that the discharge amount is increased, as shown by the dashed line, the positive electrode potential VpΔ may fall below the specified potential V0 even if the battery pack 2 is not deteriorated, and as shown by the dashed line in the lower part of FIG. 6(B), even if the battery pack 2 is not deteriorated (even if the battery pack 2 is normal), the count value CTN2 may exceed the judgment value, and as shown by the diagonal lines, deterioration of the battery pack 2 may be erroneously diagnosed. Note that in the lower part of FIG. 6(B), the solid line indicates the transition of the count value CNT2 when the vehicle 100 is operated so that the discharge amount of the battery pack 2 falls within a predetermined range.

[0065] FIG. 6(C) shows the transition of the amounts of change dCNT1 and dCNT2. In FIG. 6(C), the broken line shows the amount of change dCNT1 when the temperature Tb of the battery 3 varies widely, or the amount of change dCNT2 when the vehicle 100 is operated so that the discharge amount of the battery pack 2 falls within a predetermined range. In this embodiment, when the amount of change dCNT1 exceeds the threshold value Th1 or when the amount of change dCNT2 exceeds the threshold value Th3, it is determined that the battery pack 2 has deteriorated (the deterioration state is diagnosed as "deterioration level 1"), so that erroneous diagnosis can be suppressed and deterioration of the battery pack 2 can be diagnosed with high accuracy. In addition, in this embodiment, when the amount of change dCNT1 exceeds the threshold value Th2 and the amount of change dCNT2 exceeds the threshold value Th4, the deterioration state of the battery pack 2 is diagnosed as "deterioration level 2", so that it can be determined that the deterioration has progressed to the point where replacement of the battery pack 2 is necessary.

[0066] In the upper part of Fig. 6(A), the threshold (d) indicates the value of the threshold Rtf=d in Fig. 4(C). By setting the threshold Rft to a larger value as the variation in the temperature Tb of the batteries 3 included in the battery pack 2 increases, it is possible to reduce the frequency with which the ΔSOC exceeds the threshold when the battery pack 2 is normal, even if the variation in the temperature Tb of the batteries 3 is large, and it becomes possible to more accurately diagnose the deterioration of the battery pack 2.

[0067] In the above embodiment, S30 and S50 correspond to an example of a "parameter calculation unit" of the present disclosure. S32 and S51 correspond to an example of a "comparison unit" of the present disclosure. S33 and S52 correspond to an example of a "counting unit" of the present disclosure. S34 and S53 correspond to an example of a "change amount calculation unit" of the present disclosure. S12 to S18 correspond to an example of a "diagnosis unit" of the present disclosure. Moreover, thresholds Th1, Th2, Th3, and Th4 correspond to an example of a "predetermined value" of the present disclosure.

[0068] (Modification) In the above embodiment, if the amount of change dCNT1 is equal to or less than the previous value in S35 of Fig. 3, the routine is terminated without setting a ΔSOC degradation level. If the battery 3 is a nickel-metal hydride battery or a nickel-cadmium battery, the amount of change dCNT1 tends to decrease when the memory effect occurs. However, if the amount of change in the count value is decreasing, it is estimated that the memory effect has not yet reached saturation since it occurred, and degradation diagnosis of the battery pack 2 is not performed by the process of S35, so that erroneous diagnosis due to the memory effect can be suppressed.

[0069] In a modified example, instead of or in addition to the process of S35, the routine may be terminated without setting a ΔSOC degradation level until the cumulative mileage Mc of the vehicle 100 reaches a predetermined distance. This prevents deterioration diagnosis of the battery pack 2 from being performed until the memory effect is saturated, thereby suppressing erroneous diagnosis due to the memory effect. Note that the routine may be terminated without setting a ΔSOC degradation level until the cumulative usage time Tc of the vehicle 100 reaches a predetermined time.

[0070] In the above embodiment and modification, the deterioration state of the battery pack 2 is diagnosed using the SOC variation (ΔSOC) between the batteries 3 included in the battery pack 2 and the positive electrode potential Vp of the batteries 3. However, there may be a configuration in which the monitoring unit 4 cannot detect the voltage Vb and temperature Tb for each battery 3. For example, when the number of batteries 3 included in the battery pack 2 is 54, the battery pack 2 may be manufactured by preparing modules each composed of six batteries 3 and connecting nine modules. The monitoring unit 4 may be configured to detect the voltage Vmb and the temperature Tmb for each module. In this case, the SOC variation between the modules included in the battery pack 2 is adopted instead of the SOC variation between the batteries 3, and the positive electrode potential of the module is adopted instead of the positive electrode potential of the battery 3, so that the deterioration of the battery pack 2 can be diagnosed in the same manner as in the above embodiment. In this case, the module corresponds to the "battery" in this disclosure.

[0071] When the voltage detectable by the monitoring unit 4 is the total voltage of the battery pack 2 and the temperature detectable by the monitoring unit 4 is the temperature of the battery pack 2, the SOC variation between the parallel connected battery packs 2 is adopted instead of the SOC variation between the batteries 3, and the positive electrode potential of the battery pack 2 is adopted instead of the positive electrode potential of the battery 3, thereby making it possible to diagnose the deterioration of the battery pack 1 as in Patent Document 1. In this case, the battery pack 1 corresponds to the "battery pack" in this disclosure, and the battery pack corresponds to the "battery" in this disclosure.

[0072] The embodiments disclosed herein should be considered to be illustrative and not restrictive in all respects. The scope of the present disclosure is defined by the claims, not by the description of the embodiments described above, and is intended to include all modifications within the meaning and scope of the claims. [Explanation of symbols]

[0073] 1 battery pack, 2 battery pack, 3 battery (battery cell), 4 monitoring unit, 7 system main relay (SMR), 8 control device (ECU), 81 processor, 82 memory, 91 power control unit (PCU), 92 motor generator, 93 power transmission gear, 94 drive wheel, 100 vehicle, 200 battery system.

Claims

1. A battery pack in which a plurality of batteries are connected; a control device that diagnoses a deterioration state of the battery pack, The control device includes: a parameter calculation unit that repeatedly calculates a parameter that indicates deterioration of the battery pack; A comparison unit that compares the parameter with a threshold value; a counting unit that adds a count value based on a comparison result between the parameter and the threshold value; a change amount calculation unit that calculates an amount of change in the count value, the amount of change representing a slope of the count value over a predetermined usage time of the battery pack, or, when the battery pack is mounted on a vehicle, an amount of change representing a slope of the count value over a predetermined traveling distance; a diagnostic unit that determines that the battery pack has deteriorated when the amount of change becomes equal to or greater than a predetermined value.

2. the parameter is an SOC variation among the plurality of batteries; The battery system according to claim 1 , wherein the counter increases the count value by one when the SOC variation is greater than the threshold value.

3. The battery system according to claim 2 , wherein the control device calculates a temperature variation among the plurality of batteries, and sets the threshold value based on the temperature variation.

4. The battery system according to claim 2 , wherein the diagnosing unit is configured not to diagnose deterioration of the battery pack when the amount of change is decreasing.

5. the parameter is a positive electrode potential of the battery; The battery system according to claim 1 , wherein the counter adds one to the count value when the positive electrode potential is lower than the threshold value.

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