Frame on carrier for automotive interior cover glass applications

By using carrier materials and adhesives with thermal expansion coefficient matching, combined with cold forming process, the problems of high cost and optical distortion of curved glass substrates in vehicle interior systems are solved, and the application of low-cost, distortion-free curved glass substrates is achieved, improving the durability of glass materials and the user experience of the display.

CN114040856BActive Publication Date: 2025-08-22CORNING INC
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Patent Information

Application Number
CN202080047723.0
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2019-06-07
Filing Date
2020-06-01
Publication Date
2025-08-22
Estimated Expiration
2040-06-01

AI Technical Summary

Technical Problem

The prior art has problems of high cost and optical distortion when forming a curved glass substrate, especially when using a curved glass substrate in a vehicle interior system, it is difficult to effectively introduce a curved glass substrate without surface markings.

Method used

The glass sheet is adhered to the carrier by using a carrier material with a thermal expansion coefficient matching the glass sheet, combined with an adhesive, the curved shape of the glass sheet is maintained using a cold forming process, and the stable connection between the glass sheet and the carrier is achieved by optimizing the stress distribution to reduce shear stress.

Benefits of technology

It realizes the introduction of curved glass substrates in the vehicle interior system at a low cost, avoids optical distortion and surface marking, and improves the durability of glass materials and the user experience of the display.

✦ Generated by Eureka AI based on patent content.

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Abstract

Disclosed herein are embodiments of curved glass articles. The curved glass article comprises a glass sheet having a first major surface and a second major surface. The second major surface is opposite the first major surface, and the first major surface and the second major surface define a thickness therebetween. The curved glass article further comprises a carrier having a curvature, and the carrier is made of a carrier material. The coefficient of thermal expansion (CTE) of the carrier material is from 8 (10 ‑6 ) / ℃ to 40(10 ‑6 ) / ° C. The glass sheet is adhered to the carrier such that the glass sheet conforms to the curvature of the carrier.
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Description

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS

[0002] This application claims the benefit of priority to U.S. Provisional Application No. 62 / 858,664, filed on June 7, 2019, the contents of which are relied upon and incorporated herein by reference in their entirety. Background Art

[0003] The present disclosure relates to glass articles and methods of forming the same, and more particularly, to vehicle interior systems including glass articles having a carrier having a coefficient of thermal expansion that closely matches that of a glass sheet.

[0004] Vehicle interiors include curved surfaces, and displays may be incorporated into these curved surfaces. The materials used to form these curved surfaces are typically limited to polymers, which do not exhibit the durability and optical performance of glass. Therefore, curved glass substrates are desirable, especially when used as covers for displays. Existing methods for forming such curved glass substrates, such as thermoforming, have disadvantages including high cost, optical distortion, and surface marking. Therefore, applicants have identified a need for a vehicle interior system that can incorporate curved glass substrates in a cost-effective manner and without the problems typically associated with glass thermoforming processes. Summary of the Invention

[0005] According to one aspect, embodiments of the present disclosure relate to a curved glass article. The curved glass article comprises a glass sheet having a first major surface and a second major surface. The second major surface is opposite the first major surface, and the first major surface and the second major surface define a thickness therebetween. The curved glass article further comprises a carrier having a curvature, and the carrier is made of a carrier material. The coefficient of thermal expansion (CTE) of the carrier material is 8 (10 -6 ) / ℃ to 40(10 -6 ) / ° C. The glass sheet is adhered to the carrier such that the glass sheet conforms to the curvature of the carrier.

[0006] According to another aspect, embodiments of the present disclosure relate to a curved glass article. The curved glass article comprises a glass sheet having a first major surface and a second major surface, the second major surface being opposite the first major surface. The first and second major surfaces define a thickness therebetween. The curved glass article also comprises a carrier having a curvature and an adhesive that bonds the second major surface of the glass sheet to the carrier so that the glass sheet conforms to the curvature of the carrier. The adhesive has a bond strength. A combined stress comprises a bending stress that causes the glass sheet to conform to the curvature and a shear stress caused by the differential expansion of the glass sheet and the carrier when heated from room temperature to 75°C. The combined stress is less than the bond strength.

[0007] Additional features and advantages will be set forth in the detailed description that follows, and in part will be apparent to those skilled in the art from the following description, or will be recognized by practicing the embodiments as described herein, including the subsequent detailed description, claims, and drawings.

[0008] It is to be understood that both the foregoing general description and the following detailed description are merely exemplary and are intended to provide an overview or framework for understanding the nature and character of the claims. The accompanying drawings are included to provide a further understanding, and are incorporated into and constitute a part of this specification. BRIEF DESCRIPTION OF THE DRAWINGS

[0009] The accompanying drawings, which are incorporated into and constitute a part of the specification, illustrate several aspects of the present invention and, together with the description, serve to explain the principles of the present invention. In the drawings:

[0010] Figure 1 is a perspective view of a vehicle interior having a vehicle interior system according to an exemplary embodiment;

[0011] Figure 2A and 2B showing a side view and a rear view, respectively, of a V-shaped glass article according to an exemplary embodiment;

[0012] Figure 3A and 3B showing a side view and a rear view, respectively, of a C-shaped glass article according to an exemplary embodiment;

[0013] Figure 4 A graph showing shear stress in an adhesive as a function of the coefficient of thermal expansion (CTE) of the carrier according to an exemplary embodiment;

[0014] Figure 5 A graph showing the CTE of a composite material compared to the CTE of glass according to an exemplary embodiment;

[0015] Figure 6 Graph showing tensile stress and shear stress in an adhesive as a function of the CTE of a carrier material according to an exemplary embodiment;

[0016] Figure 7 Schematically shows a Figure 6 stresses in the adhesive shown;

[0017] Figure 8 A graph showing deflection of stainless steel and composite carriers as a function of carrier height according to exemplary embodiments;

[0018] Figure 9 and Figure 10 A prototype of a carrier according to an exemplary embodiment is shown;

[0019] Figures 11A to 11C shows an embodiment of a segmented tape carrier according to an exemplary embodiment;

[0020] 12A to 12C Another embodiment of a segmented tape carrier according to an exemplary embodiment is shown;

[0021] 13A to 13C An embodiment of a carrier disposed on a V-shaped glass article according to an exemplary embodiment is shown;

[0022] Figure 14A and Figure 14B An embodiment of a carrier disposed on a C-shaped glass article according to an exemplary embodiment is shown;

[0023] Figure 15A and Figure 15B Depicts a vehicle interior system mounted on a frame according to an exemplary embodiment. Figure 14A and Figure 14B carriers; and

[0024] Figure 16 A glass sheet suitable for cold forming on a carrier to produce a glass article is shown according to an exemplary embodiment. DETAILED DESCRIPTION

[0025] Reference will now be made in detail to various embodiments, examples of which are illustrated in the accompanying drawings. Generally, various embodiments relate to vehicle interior systems having curved glass surfaces. In the embodiments discussed herein, the curved glass surface comprises a glass sheet bonded to a carrier that holds the glass in its curved shape. Furthermore, the carrier is configured to mount to the frame of the vehicle interior system. Advantageously, the carrier defines a border (i.e., a non-display area) having a width of at most approximately 10 mm, more particularly, a width of at most approximately 2 mm, thereby allowing the majority of the glass surface to be used for viewing a display mounted thereon. The carrier can be so small and have such a small border width because the stress between the cold-bent glass and the carrier is optimized, significantly reducing the likelihood of the glass sheet peeling from the carrier. In particular, the coefficient of thermal expansion (CTE) of the carrier matches the CTE of the glass, so that the thermal stress component of the total stress between the glass sheet and the carrier does not cause the glass sheet to shear the adhesive bonding the glass sheet to the carrier. Various embodiments of the carrier and various configurations for mounting the carrier to a vehicle frame are disclosed herein. These embodiments are provided by way of illustration only and are not intended to be limiting.

[0026] Typically, vehicle interior systems may include a variety of different curved surfaces designed to be transparent, such as curved display surfaces and curved non-display glass covers. Forming curved vehicle surfaces from glass materials offers numerous advantages over the typical curved plastic panels commonly found in vehicle interiors. For example, glass is generally considered to provide enhanced functionality and user experience in many curved cover material applications, such as display applications and touchscreen applications, compared to plastic cover materials.

[0027] Figure 1 An exemplary vehicle interior 1000 is shown, including three different embodiments 100, 200, and 300 of vehicle interior systems. Vehicle interior system 100 includes a frame, shown as a center console base 110, having a curved surface 120 containing an optically bonded display 130. Vehicle interior system 200 includes a frame, shown as an instrument panel base 210, having a curved surface 220 containing an optically bonded display 230. Instrument panel base 210 typically includes an instrument panel 215, which may also include an optically bonded display. Vehicle interior system 300 includes a frame, shown as a steering wheel base 310, having a curved surface 320 and an optically bonded display 330. In one or more embodiments, the vehicle interior system includes a frame that is an armrest, pillar, seat back, floor, headrest, door panel, or any portion of the vehicle interior that includes a curved surface. In other embodiments, the frame is part of a housing for a freestanding display (i.e., a display that is not permanently attached to a part of the vehicle). In an embodiment, the optically bonded display 130, 230, 330 is at least one of a light emitting diode (LED) display, an organic LED (OLED) display, a liquid crystal display (LCD), or a plasma display.

[0028] Embodiments of the glass articles described herein can be used in each of the vehicle interior systems 100 , 200 , and 300 . Furthermore, the glass articles discussed herein can be used as curved cover glass for any of the display embodiments discussed herein, including displays used in the vehicle interior systems 100 , 200 , and / or 300 . Furthermore, in various embodiments, various non-display components of the vehicle interior systems 100 , 200 , and 300 can be formed from the glass articles discussed herein. In some such embodiments, the glass articles discussed herein can be used as non-display cover surfaces for instrument panels, center consoles, door panels, and the like. In these embodiments, the glass material can be selected based on its weight, aesthetic appearance, and the like, and can be provided with a coating (e.g., an ink or pigment coating) having a pattern (e.g., a brushed metal look, a wood grain look, a leather look, a tinted look, etc.) to visually match the glass component with adjacent non-glass components. In certain embodiments, these ink or pigment coatings can have a level of transparency that provides a deadfront or color-matching function.

[0029] In an embodiment, the curved surface 120, 220, 320 is generally as follows Figures 2A-2B V-shaped as shown or Figures 3A-3B First refer to the C type shown. Figure 2A , which shows a side view of an embodiment of a V-shaped glass article 10. The V-shaped glass article 10 includes a glass sheet 12. The glass sheet 12 has a first major surface 14 and a second major surface 16. In a vehicle, the first major surface 14 faces the vehicle's occupants, and the second major surface 16 is the rear surface of the V-shaped glass article 10, to which a display (e.g., an LED display, an OLED display, an LCD display, or a plasma display) can be mounted (e.g., using an optically clear adhesive). The second major surface 16 is opposite the first major surface 14, and the first and second major surfaces 14, 16 define a thickness T of the glass sheet 12. The first and second major surfaces 14, 16 are joined by a minor surface 18.

[0030] As in Figure 2A As can be seen in FIG, the glass sheet 12 has a curved region 20 disposed between the first flat portion 22a and the second flat portion 22b. In an embodiment, the curved region 20 has a radius of curvature R ranging from 20 mm to 10 m. Figure 2A As shown, the curved region 20 defines a concave curve, but in other embodiments, the curved region 20 is an alternative convex curve. Figure 2A In the V-shaped article 10, adhesive 24 is applied to the second major surface 16 in the bend region 20. The adhesive 24 connects the carrier 26 to the glass sheet 12.

[0031] In an embodiment, adhesive 24 comprises a pressure sensitive adhesive. Exemplary pressure sensitive adhesives suitable for adhesive 24 include 3M TM VHB TM (available from 3M Company, St. Paul, Minnesota) or tesa (available from tesa SE, Norderstedt, Germany). In an embodiment, the adhesive 24 comprises a liquid adhesive. Exemplary liquid adhesives include toughened epoxies, flexible epoxies, acrylics, silicones, urethanes, polyurethanes, and silane-modified polymers. In a particular embodiment, the liquid adhesive comprises one or more toughened epoxies, such as EP21TDCHT-LO (available from Masterbond, Hackensack, New Jersey), 3M TM Scotch-Weld TM Epoxy DP460 off-white (available from 3M Company, St. Paul, Minnesota). In other embodiments, the liquid adhesive comprises one or more flexible epoxy resins, such as Masterbond EP21TDC-2LO (available from Masterbond, Hackensack, New Jersey), 3M TM cotch-Weld TM Epoxy Resin 2216B / A Gray (available from 3M Company, St. Paul, Minnesota) and 3M TM Scotch-Weld TM Epoxy Resin DP125. In yet other embodiments, the liquid adhesive comprises one or more acrylics, such as LOAD Adhesive 410 / Accelerator 19w / LOAD AP134 Primer, LOAD Adhesive 852 / LOAD Accelerator 25GB (both available from LOAD Corporation of Cary, North Carolina), DELO PUR SJ9356 (available from DELO Industrial Adhesives of Windach, Germany), Loctite AA4800, Loctite HF8000, TEROSON MS9399, and TEROSON MS647-2C (the latter four available from Henkel AG of Düsseldorf, Germany). In other embodiments, the liquid adhesive comprises one or more urethanes, such as 3M TM Scotch-Weld TM UrethaneDP640 Brown and 3M TM Scotch-Weld TM Urethane DP604. And in yet other embodiments, the liquid adhesive comprises one or more silicones, such as Dow Corning 995 (available from Dow Corning Corporation, Midland, Michigan).

[0032] Additionally, in embodiments, a primer may be applied to prepare the surfaces of the glass sheet 12 and the carrier 26 for better adhesion. In embodiments, in addition to or in lieu of applying a primer, the carrier 26 may be roughened to provide better adhesion between the adhesive 24 and the carrier 26. Additionally, in embodiments, an ink primer may be used in addition to or in lieu of primers for metal and glass surfaces. The ink primer helps provide better adhesion between the adhesive 24 and ink-covered surfaces (e.g., the pigment design described above for blank front applications). An example of a primer is 3M TM Scotch-Weld TM Metal Primer 3901 (available from 3M Company, St. Paul, Minnesota), and other commercially available primers are also suitable for use in the present disclosure and may be selected based on the surfaces involved in bonding and the adhesive used to create the bond.

[0033] The carrier 26 holds the glass sheet 12 in a curved shape with the aid of the adhesive 24 and a cold forming process (described below). The carrier 26 is also configured to be attached to a frame of a vehicle interior system, such as a Figure 1 Vehicle interior systems 100, 200, 300. Figure 2B As shown, the height H of the carrier 26 corresponds to the distance that the carrier 26 extends from the adhesive 24. In an embodiment, the height H is from 5 mm to 20 mm, more particularly from 8 mm to 12 mm.

[0034] Figure 2B The rear surface, i.e., the second major surface 16, of the V-shaped glass article 10 is shown. Figure 2B As shown, the carrier 26 includes a first strip 28 on a first side 30 of the glass sheet 12 and a second strip 32 on a second side 34 of the glass sheet 12. In an embodiment, the strips 28, 32 of the carrier are applied across the entire width of the bend region 20, and in an embodiment, the carrier 26 may extend as far as Figure 2A The flat portions 22a, 22b are shown. Figure 2B As can be seen in FIG, glass sheet 12 is substantially unencumbered by carrier 26. In certain embodiments, carrier 26 defines a border 36 over a portion of glass sheet 12. As used herein, "border" refers to the amount of glass sheet 12 that is not available for viewing a display (e.g., a display mounted to second major surface 16). In embodiments, the width W of border 36 is b At most 10 mm, more particularly at most 5 mm, and most particularly at most 2 mm.

[0035] Figure 3A An embodiment of a C-shaped glass article 40 is shown. The C-shaped glass article 40 also includes a glass sheet 12. Figure 2A and Figure 2B V-shaped glass products 10, Figure 3A The glass sheet 12 of the C-shaped glazing 40 has a first major surface 14 and a second major surface 16 defining a thickness T and connected by a minor surface 18. The C-shaped glazing 40 also has a curved region 20 and flat portions 22a, 22b. Compared to the V-shaped glazing 10, the C-shaped glazing 40 has a much larger curved region 20 and much smaller flat portions 22a, 22b. Figure 3A As can be seen in FIG, carrier 26 is connected to second major surface 16 by adhesive 24. Because bending area 20 is much larger than in the previously discussed embodiments, carrier 26 extends substantially along the entire side of each side 30, 34, as shown in FIG. Figure 3B However, the border 36 defined by the strips 28 , 32 of the carrier 26 remains at most 10 mm, more particularly at most 5 mm, and most particularly at most 2 mm.

[0036] As described above, carrier 26 of both V-shaped glazing 10 and C-shaped glazing 40 is made of a material having a CTE that matches the CTE of glass sheet 12. The matched CTE reduces thermal stresses in adhesive 24 due to differences in thermal expansion between glass sheet 12 and carrier 26. Figure 4 A graph depicts the shear stress generated in the adhesive 24 as a function of the CTE of the carrier 26. The CTE of the glass sheet 12 is approximately 8 (10 -6 ) / °C. Therefore, in an embodiment, the carrier 26 is selected to have a -6 ) / ℃ and about 40(10 -6 ) / °C, more particularly about 8(10 -6 ) / ℃ and about 22(10 -6 ) / °C, and even more particularly about 8(10 -6 ) / ℃ and about 15(10 -6 ) / °C, most particularly about 8(10 -6 ) / ℃ and about 15(10 -6 ) / ℃.

[0037] like Figure 4 As shown, the shear stress in the adhesive increases as the CTE increases further from the glass CTE. For example, the CTE of the carrier 26 of aluminum or magnesium is 23 (10 -6 ) / ℃ or 26(10 -6 ) / °C, and the shear stress generated at a temperature change of 75°C is approximately 1 MPa and 1.2 MPa. The CTE of the steel carrier 26 is approximately 10(10 -6) / °C, and the shear stress generated at a temperature change of 75°C is approximately 0.2 MPa. A temperature change of 75°C is used because the lowest temperature for thermal reliability testing in the automotive industry is typically 95°C, which has a temperature change of 75°C from room temperature (20°C). Based on the selected carrier material, the adhesive is selected to be able to withstand the combined shear stress and bending stress. Therefore, in embodiments, the adhesive 24 used with an aluminum or magnesium carrier 26 will need to have a higher bond strength than the adhesive used with a steel carrier 26.

[0038] Table 1 below considers various carrier materials used in combination with an adhesive having a bond strength of 0.6 MPa.

[0039]

[0040] In preparing Table 1, several assumptions were made. The total stress on the adhesive was estimated as the sum of the bending stress required to keep the glass sheet bent in line with the carrier and the shear stress caused by the CTE mismatch between the glass sheet 12 and the carrier 26. Regarding the bending stress, the bending stress of the C-shaped glazing 40 is greater due to its larger bending area 20. The maximum bending stress of the C-shaped glazing 40 was estimated as the maximum glass bending force divided by the area of ​​the 1 mm frame 36. The maximum bending force was calculated to be 200 N, and the area was 1000 mm. 2 , so the maximum bending stress is 0.2 MPa. Since the bending area 20 of the V-bend article 10 is small, it can be assumed that its maximum bending stress is less than 0.2 MPa. The shear stress is calculated for a temperature change of 75°C and is shown in column 4 of Table 1. Therefore, for each material in Table 1, its total stress is estimated to be the bending stress of 0.2 MPa plus the shear stress. Column 5 of Table 1 considers whether the total stress (Stress) is less than the strength of the adhesive (Strength). For the purposes of Table 1, it is assumed that the adhesive has a strength of 0.6 MPa (which corresponds to a polyurethane structural adhesive such as BETASEAL TM X2500Plus, available from The Dow Chemical Company, Midland, Michigan). Based on the fifth column (stress < strength), suitable materials for the carrier 26 include Kovar (Fe-Ni-Co alloy) and the two stainless steels tested. When combined with the maximum bending stress, the aluminum, magnesium, and plastic carrier materials all produced shear stresses that exceeded the long-term strength of the adhesive 24. Therefore, in order to use aluminum or magnesium as a carrier, a stronger adhesive would have to be used. Column 6 of Table 1 takes into account the cost of the materials used for the frame. As can be seen, the cost of stainless steel is within the range of commonly used aluminum and magnesium alloys, indicating that switching to a stainless steel carrier material is also economically feasible.

[0041] In an embodiment, when the adhesive is selected to have a bond strength greater than the combined shear stress and bending stress, the carrier 26 can be made of a material having a CTE between 8 (10 -6 ) / ℃ and 40(10 -6 ) / °C. Thus, a variety of metallic materials can be used, including steel (especially stainless steel, galvanized steel, and other corrosion-resistant steels), iron-nickel alloys, aluminum and its alloys, and magnesium and its alloys. Furthermore, the carrier material can be plastic or a composite material as described below. In this way, the carrier material and binder can be selected from a wide variety of materials, allowing for design and economic flexibility.

[0042] In another embodiment, the carrier material may be a fiber reinforced plastic composite. For example, the carrier material may include a composite material having glass fibers embedded in an epoxy resin. The glass fibers have a Young's modulus of 720 GPa and a CTE of 5 (10 -6 ) / ℃. The Young's modulus of epoxy resin is 35GPa and CTE is 57.5(10 -6 ) / °C. The CTE of the composite will depend on the relative amounts of glass fiber and epoxy resin. Figure 5 A graph depicts the longitudinal CTE of composites with various glass fiber fractions. As expected for composites, the longitudinal CTE decreases with increasing fiber fraction (assuming there is more low CTE material). Figure 5 Describes a region where the -6 ) / °C, the CTE mismatch of the composite material is acceptable when used with glass sheets having a CTE of about 0.38 to about 0.52. In an embodiment, the acceptable fiber volume fraction is about 0.38 to about 0.52. In an embodiment, the fiber component of the composite material comprises at least one of glass fiber, carbon fiber, aramid fiber, or graphite fiber. In an embodiment, the plastic component of the composite material comprises at least one of epoxy, polycarbonate, acrylic, polyester, polyetherketoneketone (PEKK), polycarbonate / acrylonitrile butadiene styrene (PC / ABS), polypropylene, or phenolic resin. Furthermore, in an embodiment, the fibers can be aligned along the longitudinal axis of the carrier 26, which can be along the sides 30, 34 of the glass sheet 12.

[0043] Figure 6 A graph showing stress as a function of the CTE of the carrier material is shown. In particular, Figure 6 The specific stress of the adhesive 24 is shown in FIG. Figure 7 As shown in Figure 7The tensile component can be considered as the opening stress, i.e., pulling the glass sheet away from the carrier, which exerts tension on the adhesive 24. The shear component is associated with the CTE mismatch between the glass sheet 12 and the carrier 26, which causes shear in the adhesive 24. Back Figure 6 , the graph shows that the magnitude of both the tensile and shear components increases as the CTE of the carrier material increases. Figure 6 The diagram of considers the stresses associated with a glass sheet 12 having a length of 750 mm, a width of 150 mm, a radius of curvature of 2300 mm and a carrier 26 having a height H of 10 mm.

[0044] Figure 8 A graph shows the deflection of a glass sheet 12 bonded to a carrier 26 as a function of the carrier height H. The deflection is related to the CTE mismatch between the glass sheet 12 and the carrier 26, which is a result of the uneven expansion of the glass sheet 12 and the carrier 26 when heated. Due to the uneven expansion, the carrier 26 will (usually) expand more than the glass sheet 12, causing the assembly of components to deflect toward the glass sheet 12. Figure 8 , the deflection is modeled as a function of the carrier height H. It can be seen that the deflection decreases as the carrier height H increases for both the stainless steel and composite carriers.

[0045] Figure 9-1 5 depicts various embodiments of the carrier 26 mounted to the glass sheet 12. Figure 9 and Figure 10 A prototype V-shaped glass article 10 is depicted. Figure 9 It can be seen that the V-shaped glass product 10 and Figure 2A and 2B . That is, the carrier 26 comprises a first strip 28 on a first side 30 of the glass sheet 12 and a second strip 32 on a second side 34 of the glass sheet 12. In the illustrated embodiment, the V-shaped glazing 10 comprises an adhesive 24 that would typically be applied to the glass sheet 12 to attach the conventional carrier 26 to the glass sheet 12. As can be seen, the adhesive 24 defines a conventional frame width W. c , which is larger than the required size of the carrier 26 according to the present disclosure. In fact, according to embodiments of the present disclosure, all adhesive not provided under the strips 28, 32 of the carrier 26 can be removed, thereby substantially increasing the display area of ​​the glass sheet.

[0046] Figure 10Another embodiment of the carrier 26 is shown. The carrier 26 includes the first strip 28 and the second strip 32, but also includes a third strip 42 located between the first strip 28 and the second strip 32. The carrier 26 also includes a plurality of reinforcing strips 44 that extend from the first strip 28 through the third strip 42 and to the second strip 32. Figure 10 In the embodiment shown in FIG. 4 , there are three reinforcing strips 44. However, in other embodiments, there may be more or fewer reinforcing strips 44, such as from one to twenty reinforcing strips 44 (e.g., positioned periodically throughout the curved region 20 of the C-shaped glazing 40). Figure 10 Also depicted are a plurality of holes 46 formed in the first strap 28 and the second strap 32. These holes 46 are configured to receive push-type fasteners, for example, to attach the carrier 26 to a frame of a vehicle interior trim system.

[0047] Figures 11A-11C Another embodiment of the carrier 26 is depicted. The carrier 26 includes a segmented strip 48 that can be used as the first strip 28 or the second strip 32 or both the first strip 28 and the second strip 32 (e.g., Figure 11C ). The segmented strip 48 defines a plurality of detents 50 along the length of the segmented strip 48. The segmented strip 48 also defines a plurality of bonding surfaces 52 for adhering the segmented strip 48 to the glass sheet 12. Figure 11B As shown, the segmented strip 48 has a zigzag configuration that allows for differential expansion on the side with the detents 50 and the side with the bonding surface 52. Thus, expansion of the frame of the vehicle interior trim system is not transferred to the glass sheet 12 and vice versa.

[0048] Figures 12A-12C Another embodiment of a segmented ribbon 48 that can be used as one or both of the first ribbon 28 and the second ribbon 32 of the carrier 26 is depicted. The segmented ribbon 48 includes a bonding surface 52 for attaching the segmented ribbon 48 to the glass sheet 12. However, Figures 12A-12C The segmented strip 48 also includes hooks 54 configured to engage with corresponding structures of the frame of the vehicle interior trim system. The segmented strip 48 includes a plurality of slots 56 that allow for differential expansion of the hook 54 side and the bonding surface 52 side.

[0049] Figures 13A-13C Another embodiment of a carrier 26 is depicted on a V-shaped glazing 10 (although the carrier 26 can also be used with a C-shaped glazing 40). Figure 13AAs can be seen in FIG, carrier 26 extends substantially around the perimeter of glass sheet 12. Carrier 26 includes an adhesive strip 58 connected to mounting strip 60. In the embodiment shown, adhesive strip 58 is arranged substantially perpendicular (e.g., within 10°) to mounting strip 60. Adhesive strip 58 is configured to be connected to glass sheet 12 using adhesive 24. Figures 13A-13C In the embodiment of FIG. 5 , the mounting strip 60 includes a plurality of holes 62 through which fasteners 64 may be inserted to connect the carrier 26 to the frame of the vehicle interior trim system.

[0050] Figure 14A and Figure 14B Another embodiment of the carrier 26 is depicted on a C-shaped glazing 40 (although the carrier 26 can also be used with a V-shaped glazing 10). Figure 14A As shown, the carrier 26 includes a first strip 28 and a second strip 32 located at the sides 30, 34 of the glass sheet 12. Figure 14B As can be seen in FIG. 2 , edge 66 of strip 28 is adhered to second major surface 16 of glass sheet 12 . Figure 14B It is also shown that the height H of the strip 28 far exceeds the thickness T of the strip 28. S As described above, a larger height H (e.g., at least 10 mm) reduces the amount of deflection due to CTE mismatch, and a smaller thickness (e.g., less than 2 mm) reduces the size of the C-shaped glass frame 36. The strip 28 includes a plurality of holes 62 through which fasteners 64 can be inserted to connect the carrier 26 to the frame of the vehicle interior system. Figure 15A and 15B Depicts Figure 14A and 14B The carrier 26 is mounted on the frame 68 of the vehicle interior system. Figure 14B As shown, fasteners 64 inserted through holes 62 of strap 28 engage corresponding mating holes 70 located in frame 68 .

[0051] As briefly mentioned above, the glass sheet 12 is attached to the carrier 26 via a cold forming process. Cold forming refers to introducing the curved region 20 into the glass sheet 12 at a temperature below the softening temperature of the glass. More specifically, cold forming is performed at temperatures below 200°C, below 100°C, or even at room temperature. During cold forming, pressure is applied to the glass sheet 12 to conform the glass sheet 12 to the shape of the carrier 26. Pressure can be applied in a variety of ways, such as vacuum pressure, mechanical pressing, rollers, and the like. In embodiments, pressure is maintained on the glass sheet 12 until the adhesive 24 cures (at least sufficiently to prevent the glass sheet 12 from delaminating from the carrier 26). Thereafter, the glass sheet 12 is bonded to the carrier 26, and the glass article can be shipped and / or installed as part of a vehicle interior system.

[0052] In the following paragraphs, various geometrical characteristics of the glass sheet 12 are provided as well as the composition of the glass sheet. Figure 16 , glass sheet 12 has a substantially constant thickness T1, with thickness T1 being defined as the distance between first major surface 14 and second major surface 16. In various embodiments, T1 may refer to the average thickness or maximum thickness of the glass sheet. Furthermore, glass sheet 12 includes a width W1, defined as a first maximum dimension of one of first major surface 14 or second major surface 16 that is orthogonal to thickness T1, and a length L1, defined as a second maximum dimension of one of first major surface 14 or second major surface 16 that is orthogonal to both the thickness and width. In other embodiments, W1 and L1 may be the average width and average length, respectively, of glass sheet 12. In other embodiments (e.g., for glass sheet 14 of variable width or length), W1 and L1 may be the maximum width and maximum length, respectively, of glass sheet 12.

[0053] In various embodiments, the thickness T1 is 2 mm or less, and specifically 0.3 mm to 1.1 mm. For example, the thickness T1 can range from about 0.1 mm to about 1.5 mm, from about 0.15 mm to about 1.5 mm, from about 0.2 mm to about 1.5 mm, from about 0.25 mm to about 1.5 mm, from about 0.3 mm to about 1.5 mm, from about 0.35 mm to about 1.5 mm, from about 0.4 mm to about 1.5 mm, from about 0.45 mm to about 1.5 mm, from about 0.5 mm to about 1.5 mm, from about 0.55 mm to about 1.5 mm, from about 0.6 mm to about 1.5 mm, from about 0.65 mm to about 1.5 mm, from about 0.7 mm to about 1.5 mm, from about 0.1 mm to about 1.4 mm, from about 0.1 mm to about 1.3 mm , from about 0.1mm to about 1.2mm, from about 0.1mm to about 1.1mm, from about 0.1mm to about 1.05mm, from about 0.1mm to about 1mm, from about 0.1mm to about 0.95mm, from about 0.1mm to about 0.9mm, from about 0.1mm to about 0.85mm, from about 0.1mm to about 0.8mm, from about 0.1mm to about 0.75mm, from about 0.1mm to about 0.7mm, from about 0.1mm to about 0.65mm, from about 0.1mm to about 0.6mm, from about 0.1mm to about 0.55mm, from about 0.1mm to about 0.5mm, from about 0.1mm to about 0.4mm, or from about 0.3mm to about 0.7mm. In other embodiments, T1 falls within any one of the exact numerical ranges set forth in this paragraph.

[0054] In various embodiments, the width W1 may range from 5 cm to 250 cm, from about 10 cm to about 250 cm, from about 15 cm to about 250 cm, from about 20 cm to about 250 cm, from about 25 cm to about 250 cm, from about 30 cm to about 250 cm, from about 35 cm to about 250 cm, from about 40 cm to about 250 cm, from about 45 cm to about 250 cm, from about 50 cm to about 250 cm, from about 55 cm to about 250 cm, from about 60 cm to about 250 cm, from about 65 cm to about 250 cm, from about 70 cm to about 250 cm, from about 75 cm to about 250 cm, from about 80 cm to about 250 cm, from about 85 cm to about 250 cm, from about 90 cm to about 250 cm, from about 95 cm to about 250 cm, from about 100 cm to about 250 cm, from about 110 cm to about 250 cm, From about 5 cm to about 190 cm, from about 5 cm to about 180 cm, from about 5 cm to about 170 cm, from about 5 cm to about 160 cm, from about 5 cm to about 150 cm, from about 5 cm to about 140 cm, from about 5 cm to about 130 cm, from about 5 cm to about 120 cm, from about 5 cm to about 110 cm, from about 5 cm to about 110 cm, from about 5 cm to about 100 cm, from about 5 cm to about 90 cm, from about 5 cm to about 80 cm, or from about 5 cm to about 75 cm. In other embodiments, W1 falls within any of the explicit numerical ranges in this paragraph.

[0055] In various embodiments, the length L1 can be in the range of from about 5 cm to about 1500 cm, from about 50 cm to about 1500 cm, from about 100 cm to about 1500 cm, from about 150 cm to about 1500 cm, from about 200 cm to about 1500 cm, from about 250 cm to about 1500 cm, from about 300 cm to about 1500 cm, from about 350 cm to about 1500 cm, from about 400 cm to about 1500 cm, from about 450 cm to about 1500 cm, from about 500 cm to about 1500 cm, from about 550 cm to about 1500 cm, from about 600 cm to about 1500 cm, from about 650 cm to about 1500 cm, from about 70 In another embodiment, L1 can be from about 1500cm to about 1500cm, from about 750cm to about 1500cm, from about 800cm to about 1500cm, from about 850cm to about 1500cm, from about 900cm to about 1500cm, from about 950cm to about 1500cm, from about 1000cm to about 1500cm, from about 1050cm to about 1500cm, from about 1100cm to about 1500cm, from about 1150cm to about 1500cm, from about 1200cm to about 1500cm, from about 1250cm to about 1500cm, from about 1300cm to about 1500cm, from about 1350cm to about 1500cm, from about 1400cm to about 1500cm, or from about 1450cm to about 1500cm. In other embodiments, L1 falls within any one of the exact numerical ranges set forth in this paragraph.

[0056] In various embodiments, one or more radii of curvature (e.g., Figure 2A and 3AFor example, R may range from about 20 mm to about 10,000 mm, from about 30 mm to about 10,000 mm, from about 40 mm to about 10,000 mm, from about 50 mm to about 10,000 mm, from about 60 mm to about 10,000 mm, from about 70 mm to about 10,000 mm, from about 80 mm to about 10,000 mm, from about 90 mm to about 10,000 mm, from about 100 mm to about 10,000 mm, from about 120 mm to about 10,000 mm, from about 140 mm to about 10,000 mm, from about 150 mm to about 10,000 mm, from about 160 mm to about 10,000 mm, from about 170 mm to about 10,000 mm, from about 180 mm to about 10,000 mm, from about 190 mm to about 10,000 mm, from about 200 mm to about 10,000 mm, from about 210 mm to about 10,000 mm, from about 220 mm to about 10,000 mm, from about 230 mm to about 10,000 mm, from about 240 mm to about 10,000 mm, from about 250 mm to about 10,000 mm, from about from about 180 mm to about 10,000 mm, from about 200 mm to about 10,000 mm, from about 220 mm to about 10,000 mm, from about 240 mm to about 10,000 mm, from about 250 mm to about 10,000 mm, from about 260 mm to about 10,000 mm, from about 270 mm to about 10,000 mm, from about 280 mm to about 10,000 mm, from about 290 mm to about 10,000 mm, from about 300 mm to about 10,000 mm, from about 350 mm to about 10,000 mm, from about 400 mm to about 10,000 mm, from about 450 mm to about 10,000 mm, from about 500 mm to about 10,000mm, from about 550mm to about 10,000mm, from about 600mm to about 10,000mm, from about 650mm to about 10,000mm, from about 700mm to about 10,000mm, from about 750mm to about 10,000mm, from about 800mm to about 10,000mm, from about 900mm to about 10,000mm, from about 950mm to about 10,000mm, from about 1000mm to about 10,000mm, from about 1250mm to about 10,000mm, from about 20mm to about 1400mm, from about 20mm to about 1300mm, from about 20mm to about 1200mm, from about 1 From about 20 mm to about 1100 mm, from about 20 mm to about 1000 mm, from about 20 mm to about 950 mm, from about 20 mm to about 900 mm, from about 20 mm to about 850 mm, from about 20 mm to about 800 mm, from about 20 mm to about 750 mm, from about 20 mm to about 700 mm, from about 20 mm to about 650 mm, from about 20 mm to about 600 mm, from about 20 mm to about 550 mm, from about 20 mm to about 500 mm, from about 20 mm to about 450 mm, from about 20 mm to about 400 mm, from about 20 mm to about 350 mm, from about 20 mm to about 300 mm, or from about 20 mm to about 250 mm.In other embodiments, R1 falls within any of the exact numerical ranges recited in this paragraph.

[0057] Various embodiments of the vehicle interior system can be incorporated into vehicles such as trains, automobiles (e.g., cars, trucks, buses, etc.), marine vehicles (ships, ships, submarines, etc.), and aircraft (e.g., drones, airliners, jet fighters, helicopters, etc.).

[0058] Strengthened glass performance

[0059] As described above, the glass sheet 12 can be strengthened. In one or more embodiments, the glass sheet 12 can be strengthened to contain compressive stress extending from the surface to the depth of compression (DOC). This compressive stress region is balanced by a central portion exhibiting tensile stress. At the DOC, the stress transitions from positive (compressive) stress to negative (tensile) stress.

[0060] In various embodiments, the glass sheet 12 can be mechanically strengthened by exploiting the mismatch in thermal expansion coefficients between portions of the article to create regions of compressive stress and a central region exhibiting tensile stress. In some embodiments, the glass sheet can be thermally strengthened by heating the glass to a temperature above its glass transition point and then rapidly quenching it.

[0061] In various embodiments, the glass sheet 12 can be chemically strengthened by ion exchange. During ion exchange, ions at or near the surface of the glass sheet are replaced with or exchanged for larger ions of the same valence or oxidation state. In those embodiments in which the glass sheet comprises an alkali aluminosilicate glass, the ions and larger ions in the surface layer of the article are monovalent alkali metal cations, such as Li + 、Na + , K + , Rb + , and Cs + Alternatively, the monovalent cations in the surface layer may be replaced by monovalent cations other than alkali metal cations, such as Ag + Etc. In these embodiments, the monovalent ions (or cations) exchanged into the glass sheet generate stress.

[0062] The ion exchange process is typically performed by immersing the glass sheet in a molten salt bath (or two or more molten salt baths) containing larger ions to be exchanged with smaller ions in the glass sheet. It should be noted that salt water baths may also be utilized. In addition, the composition of the bath(s) may include more than one type of larger ion (e.g., Na + and K +) or a single larger ion. Those skilled in the art will appreciate that the parameters of the ion exchange process (including but not limited to bath composition and temperature, immersion time, number of immersions of the glass sheet in the salt bath(s), use of multiple salt baths, additional steps such as annealing, washing, etc.) are generally determined by the composition of the glass sheet (including the structure of the article and any crystalline phases present) and the desired DOC and CS of the glass sheet resulting from strengthening. Exemplary molten salt bath compositions may include nitrates, sulfates, and chlorides of larger alkali metal ions. Typical nitrates include KNO3, NaNO3, LiNO3, NaSO4, and combinations thereof. The temperature of the molten salt bath typically ranges from about 380°C up to about 450°C, while the immersion time ranges from about 15 minutes up to about 100 hours, depending on the thickness of the glass sheet, bath temperature, glass (or monovalent ion) diffusivity. However, temperatures and immersion times different from those described above may also be used.

[0063] In one or more embodiments, the glass sheet may be immersed in a molten salt bath of 100% NaNO, 100% KNO, or a combination of NaNO and KNO at a temperature of from about 370° C. to about 480° C. In some embodiments, the glass sheet may be immersed in a molten mixed salt bath comprising from about 5% to about 90% KNO and from about 10% to about 95% NaNO. In one or more embodiments, the glass sheet may be immersed in a second bath after being immersed in the first bath. The first and second baths may have different compositions and / or temperatures. The immersion times in the first and second baths may vary. For example, the immersion in the first bath may be longer than the immersion in the second bath.

[0064] In one or more embodiments, the glass sheet may be immersed in a molten mixed salt bath comprising NaNO3 and KNO3 (e.g., 49% / 51%, 50% / 50%, 51% / 49%) at a temperature of less than about 420°C (e.g., about 400°C or about 380°C) for less than about 5 hours, or even about 4 hours or less.

[0065] Ion exchange conditions can be adjusted to provide a "peak" in the stress profile at or near the surface of the resulting glass sheet, or to increase the slope of the stress profile. The peak can result in a greater surface CS value. Due to the unique properties of the glass compositions used in the glass sheets described herein, this peak can be achieved using a single bath or multiple baths, where the bath(s) have a single composition or a mixed composition.

[0066] In one or more embodiments, when more than one monovalent ion is exchanged into the glass sheet, the different monovalent ions may be exchanged to different depths within the glass sheet (and generate different amounts of stress at different depths within the glass sheet). The relative depths of the resulting stress-generating ions may be determined, resulting in different characteristics of the stress distribution.

[0067] CS is measured using means known in the art, such as a surface stress meter (FSM) utilizing a commercially available instrument, such as the FSM-6000 manufactured by Orihara Industrial Co., Ltd. (Japan). Surface stress measurement relies on accurate measurement of the stress-optical coefficient (SOC), which is related to the birefringence of the glass. The SOC is, in turn, measured using methods known in the art, such as the fiber bend method and the four-point bend method (both described in ASTM Standard C770-98 (2013), entitled "Standard Test Method for Measurement of Glass Stress-Optical Coefficient," the contents of which are incorporated herein by reference in their entirety), as well as the bulk cylinder method. As used herein, CS may be the "maximum compressive stress," which is the highest compressive stress value measured within the compressive stress layer. In some embodiments, the maximum compressive stress is located at the surface of the glass sheet. In other embodiments, the maximum compressive stress may occur at a depth below the surface, resulting in a "buried peak" in the compression profile.

[0068] DOC can be measured by FSM or by a scattered light polariscope (SCALP) (such as the SCALP-04 scattered light polariscope available from Glasstress Ltd., located in Tallinn, Estonia), depending on the strengthening method and conditions. When the glass sheet is chemically strengthened by an ion exchange process, either FSM or SCALP can be used, depending on which ions are exchanged into the glass sheet. In the case where stress is induced in the glass sheet by exchanging potassium ions into the glass sheet, DOC is measured using FSM. In the case where stress is induced in the glass sheet by exchanging sodium ions into the glass sheet, DOC is measured using SCALP. In the case where stress is induced in the glass sheet by exchanging both potassium and sodium ions into the glass sheet, DOC is measured using SCALP, because it is believed that the exchange depth of sodium indicates DOC, and the exchange depth of potassium ions indicates the change in the magnitude of compressive stress (but not the change from compressive stress to tensile stress); the exchange depth of potassium ions in such glass sheets is measured by FSM. Central tension, or CT, is the maximum tensile stress and is measured by SCALP.

[0069] In one or more embodiments, the glass sheet can be strengthened to exhibit a DOC (as described herein) described as a fraction of the thickness T1 of the glass sheet 12. For example, in one or more embodiments, the DOC can be equal to or greater than about 0.05T1, equal to or greater than about 0.1T1, equal to or greater than about 0.11T1, equal to or greater than about 0.12T1, equal to or greater than about 0.13T1, equal to or greater than about 0.14T1, equal to or greater than about 0.15T1, equal to or greater than about 0.16T1, equal to or greater than about 0.17T1, equal to or greater than about 0.18T1, equal to or greater than about 0.19T1, equal to or greater than about 0.2T1, or equal to or greater than about 0.21T1. In some embodiments, the DOC may be in the range of from about 0.08T1 to about 0.25T1, from about 0.09T1 to about 0.25T1, from about 0.18T1 to about 0.25T1, from about 0.11T1 to about 0.25T1, from about 0.12T1 to about 0.25T1, from about 0.13T1 to about 0.25T1, from about 0.14T1 to about 0.25T1, from about 0.15T1 to about 0.25T1, from about 0.08 T1 to about 0.24T1, from about 0.08T1 to about 0.23T1, from about 0.08T1 to about 0.22T1, from about 0.08T1 to about 0.21T1, from about 0.08T1 to about 0.2T1, from about 0.08T1 to about 0.19T1, from about 0.08T1 to about 0.18T1, from about 0.08T1 to about 0.17T1, from about 0.08T1 to about 0.16T1, or from about 0.08T1 to about 0.15T1. In some cases, the DOC may be about 20 μm or less.In one or more embodiments, the DOC may be about 40 μm or greater (e.g., from about 40 μm to about 300 μm, from about 50 μm to about 300 μm, from about 60 μm to about 300 μm, from about 70 μm to about 300 μm, from about 80 μm to about 300 μm, from about 90 μm to about 300 μm, from about 100 μm to about 300 μm, from about 110 μm to about 300 μm, from about 120 μm to about 300 μm, from about 140 μm to about 300 μm, from about 150 μm to about 300 μm, from about 40 μm to about 290 μm, from about 40 μm to about 280 μm). In some embodiments, the DOC is from about 40 μm to about 200 μm, from about 40 μm to about 180 μm, from about 40 μm to about 160 μm, from about 40 μm to about 150 μm, from about 40 μm to about 140 μm, from about 40 μm to about 130 μm, from about 40 μm to about 120 μm, from about 40 μm to about 110 μm, or from about 40 μm to about 100 μm. In other embodiments, the DOC falls within any of the specific numerical ranges set forth in this paragraph.

[0070] In one or more embodiments, the strengthened glass sheet may have a CS (which may be seen at the surface or at depth within the glass sheet) of about 200 MPa or greater, 300 MPa or greater, 400 MPa or greater, about 500 MPa or greater, about 600 MPa or greater, about 700 MPa or greater, about 800 MPa or greater, about 900 MPa or greater, about 930 MPa or greater, about 1000 MPa or greater, or about 1050 MPa or greater.

[0071] In one or more embodiments, the strengthened glass sheet may have a maximum tensile stress or central tension (CT) of about 20 MPa or greater, about 30 MPa or greater, about 40 MPa or greater, about 45 MPa or greater, about 50 MPa or greater, about 60 MPa or greater, about 70 MPa or greater, about 75 MPa or greater, about 80 MPa or greater, or about 85 MPa or greater. In some embodiments, the maximum tensile stress or central tension (CT) may be in the range of from about 40 MPa to about 100 MPa. In other embodiments, the CT falls within the exact numerical ranges recited in this paragraph.

[0072] Glass composition

[0073] Suitable glass compositions for the glass sheet 12 include soda-lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.

[0074] Unless otherwise indicated, the glass compositions disclosed herein are described in terms of mole percent (mol %) as based on oxide analysis.

[0075] In one or more embodiments, the glass composition may include SiO2 in an amount ranging from about 66 mol% to about 80 mol%, from about 67 mol% to about 80 mol%, from about 68 mol% to about 80 mol%, from about 69 mol% to about 80 mol%, from about 70 mol% to about 80 mol%, from about 72 mol% to about 80 mol%, from about 65 mol% to about 78 mol%, from about 65 mol% to about 76 mol%, from about 65 mol% to about 75 mol%, from about 65 mol% to about 74 mol%, from about 65 mol% to about 72 mol%, or from about 65 mol% to about 70 mol%, and all ranges and subranges therebetween.

[0076] In one or more embodiments, the glass composition includes Al2O3 in an amount greater than about 4 mol%, or greater than about 5 mol%. In one or more embodiments, the glass composition includes Al2O3 in an amount ranging from greater than about 7 mol% to about 15 mol%, from greater than about 7 mol% to about 14 mol%, from about 7 mol% to about 13 mol%, from about 4 mol% to about 12 mol%, from about 7 mol% to about 11 mol%, from about 8 mol% to about 15 mol%, from about 9 mol% to about 15 mol%, from about 10 mol% to about 15 mol%, from about 11 mol% to about 15 mol%, or from about 12 mol% to about 15 mol%, and all ranges and sub-ranges therebetween. In one or more embodiments, the upper limit of Al2O3 may be about 14 mol%, 14.2 mol%, 14.4 mol%, 14.6 mol%, or 14.8 mol%.

[0077] In one or more embodiments, a glass article is described as an aluminosilicate glass article or includes an aluminosilicate glass composition. In these embodiments, the glass composition or article formed therefrom includes SiO2 and Al2O3 and is not a soda-lime silicate glass. In this regard, the glass composition or article formed therefrom includes Al2O3 in an amount of about 2 mol% or greater, 2.25 mol% or greater, 2.5 mol% or greater, about 2.75 mol% or greater, or about 3 mol% or greater.

[0078] In one or more embodiments, the glass composition includes B2O3 (e.g., about 0.01 mol% or greater). In one or more embodiments, the glass composition has a B2O3 content ranging from about 0 mol% to about 5 mol%, from about 0 mol% to about 4 mol%, from about 0 mol% to about 3 mol%, from about 0 mol% to about 2 mol%, from about 0 mol% to about 1 mol%, from about 0 mol% to about 0.5 mol%, from about 0.1 mol% to about 5 mol%, from about 0.1 mol% to about 4 mol%, from about 0.1 mol% to about 3 mol%, from about 0.1 mol% to about 2 mol%, from about 0.1 mol% to about 1 mol%, from about 0.1 mol% to about 0.5 mol%, and all ranges and sub-ranges therebetween. In one or more embodiments, the glass composition is substantially free of B2O3.

[0079] As used herein, the phrase "substantially free" with respect to a component of a composition means that the component is not actively or intentionally added to the composition during initial compounding, but may be present as an impurity in an amount of less than about 0.001 mol%.

[0080] In one or more embodiments, the glass composition optionally includes PO (e.g., about 0.01 mol% or greater). In one or more embodiments, the glass composition includes a non-zero amount of PO up to and including 2 mol%, 1.5 mol%, 1 mol%, or 0.5 mol%. In one or more embodiments, the glass composition is substantially free of PO.

[0081] In one or more embodiments, the glass composition may include a total amount of RO (which is the total amount of alkali metal oxides such as Li2O, Na2O, KO, Rb2O, and Cs2O) of greater than or equal to about 8 mol%, greater than or equal to about 10 mol%, or greater than or equal to about 12 mol%. In some embodiments, the glass composition includes a total amount of RO in a range from about 8 mol% to about 20 mol%, from about 8 mol% to about 18 mol%, from about 8 mol% to about 16 mol%, from about 8 mol% to about 14 mol%, from about 8 mol% to about 12 mol%, from about 9 mol% to about 20 mol%, from about 10 mol% to about 20 mol%, from about 11 mol% to about 20 mol%, from about 12 mol% to about 20 mol%, from about 13 mol% to about 20 mol%, from about 10 mol% to about 14 mol%, or from 11 mol% to about 13 mol%, and all ranges and subranges therebetween. In one or more embodiments, the glass composition may be substantially free of Rb2O, Cs2O, or both Rb2O and Cs2O. In one or more embodiments, R2O may comprise only the total amount of Li2O, Na2O, and KO. In one or more embodiments, the glass composition may include at least one alkali metal oxide selected from Li2O, Na2O, and KO, wherein the alkali metal oxide is present in an amount greater than about 8 mol% or more.

[0082] In one or more embodiments, the glass composition includes Na2O in an amount greater than or equal to about 8 mol%, greater than or equal to about 10 mol%, or greater than or equal to about 12 mol%. In one or more embodiments, the composition includes Na2O in an amount in the range from about 8 mol% to about 20 mol%, from about 8 mol% to about 18 mol%, from about 8 mol% to about 16 mol%, from about 8 mol% to about 14 mol%, from about 8 mol% to about 12 mol%, from about 9 mol% to about 20 mol%, from about 10 mol% to about 20 mol%, from about 11 mol% to about 20 mol%, from about 12 mol% to about 20 mol%, from about 13 mol% to about 20 mol%, about 10 mol% to about 14 mol%, or from 11 mol% to about 16 mol%, and all ranges and subranges therebetween.

[0083] In one or more embodiments, the glass composition includes less than about 4 mol% K2O, less than about 3 mol% K2O, or less than about 1 mol% K2O. In some cases, the glass composition can include KO in an amount ranging from about 0 mol% to about 4 mol%, from about 0 mol% to about 3.5 mol%, from about 0 mol% to about 3 mol%, from about 0 mol% to about 2.5 mol%, from about 0 mol% to about 2 mol%, from about 0 mol% to about 1.5 mol%, from about 0 mol% to about 1 mol%, from about 0 mol% to about 0.5 mol%, from about 0 mol% to about 0.2 mol%, from about 0 mol% to about 0.1 mol%, from about 0.5 mol% to about 4 mol%, from about 0.5 mol% to about 3.5 mol%, from about 0.5 mol% to about 3 mol%, from about 0.5 mol% to about 2.5 mol%, from about 0.5 mol% to about 2 mol%, from about 0.5 mol% to about 1.5 mol%, or from about 0.5 mol% to about 1 mol%, and all ranges and sub-ranges therebetween. In one or more embodiments, the glass composition can be substantially free of KO.

[0084] In one or more embodiments, the glass composition is substantially free of Li2O.

[0085] In one or more embodiments, the amount of Na2O in the composition may be greater than the amount of Li2O. In some cases, the amount of Na2O may be greater than the combined amount of Li2O and KO. In one or more alternative embodiments, the amount of Li2O in the composition may be greater than the amount of Na2O or the combined amount of Na2O and KO.

[0086] In one or more embodiments, the glass composition may include a total amount of RO (which is the total amount of alkaline earth metal oxides such as CaO, MgO, BaO, ZnO, and SrO) in the range of from about 0 mol% to about 2 mol%. In some embodiments, the glass composition includes a non-zero amount of RO up to about 2 mol%. In one or more embodiments, the glass composition includes RO in an amount ranging from about 0 mol% to about 1.8 mol%, from about 0 mol% to about 1.6 mol%, from about 0 mol% to about 1.5 mol%, from about 0 mol% to about 1.4 mol%, from about 0 mol% to about 1.2 mol%, from about 0 mol% to about 1 mol%, from about 0 mol% to about 0.8 mol%, from about 0 mol% to about 0.5 mol%, and all ranges and sub-ranges therebetween.

[0087] In one or more embodiments, the glass composition includes CaO in an amount of less than about 1 mol%, less than about 0.8 mol%, or less than about 0.5 mol%. In one or more embodiments, the glass composition is substantially free of CaO.

[0088] In some embodiments, the glass composition includes MgO in an amount ranging from about 0 mol% to about 7 mol%, from about 0 mol% to about 6 mol%, from about 0 mol% to about 5 mol%, from about 0 mol% to about 4 mol%, from about 0.1 mol% to about 7 mol%, from about 0.1 mol% to about 6 mol%, from about 0.1 mol% to about 5 mol%, from about 0.1 mol% to about 4 mol%, from about 1 mol% to about 7 mol%, from about 2 mol% to about 6 mol%, or from about 3 mol% to about 6 mol%, and all ranges and sub-ranges therebetween.

[0089] In one or more embodiments, the glass composition includes ZrO2 in an amount equal to or less than about 0.2 mol%, less than about 0.18 mol%, less than about 0.16 mol%, less than about 0.15 mol%, less than about 0.14 mol%, less than about 0.12 mol%. In one or more embodiments, the glass composition includes ZrO2 in an amount ranging from about 0.01 mol% to about 0.2 mol%, from about 0.01 mol% to about 0.18 mol%, from about 0.01 mol% to about 0.16 mol%, from about 0.01 mol% to about 0.15 mol%, from about 0.01 mol% to about 0.14 mol%, from about 0.01 mol% to about 0.12 mol%, or from about 0.01 mol% to about 0.10 mol%, and all ranges and subranges therebetween.

[0090] In one or more embodiments, the glass composition includes SnO2 in an amount equal to or less than about 0.2 mol%, less than about 0.18 mol%, less than about 0.16 mol%, less than about 0.15 mol%, less than about 0.14 mol%, less than about 0.12 mol%. In one or more embodiments, the glass composition includes SnO2 in an amount ranging from about 0.01 mol% to about 0.2 mol%, from about 0.01 mol% to about 0.18 mol%, from about 0.01 mol% to about 0.16 mol%, from about 0.01 mol% to about 0.15 mol%, from about 0.01 mol% to about 0.14 mol%, from about 0.01 mol% to about 0.12 mol%, or about 0.01 mol% to about 0.10 mol%, and all ranges and subranges therebetween.

[0091] In one or more embodiments, the glass composition may include an oxide that imparts color or tint to the glass article. In some embodiments, the glass composition includes an oxide that prevents discoloration of the glass article when the glass article is exposed to ultraviolet radiation. Examples of such oxides include, without limitation, oxides of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Ce, W, and Mo.

[0092] In one or more embodiments, the glass composition includes Fe expressed as Fe2O3, wherein Fe is present in an amount up to and including about 1 mol%. In some embodiments, the glass composition is substantially free of Fe. In one or more embodiments, the glass composition includes Fe2O3 in an amount equal to or less than about 0.2 mol%, less than about 0.18 mol%, less than about 0.16 mol%, less than about 0.15 mol%, less than about 0.14 mol%, or less than about 0.12 mol%. In one or more embodiments, the glass composition includes Fe2O3 in an amount ranging from about 0.01 mol% to about 0.2 mol%, from about 0.01 mol% to about 0.18 mol%, from about 0.01 mol% to about 0.16 mol%, from about 0.01 mol% to about 0.15 mol%, from about 0.01 mol% to about 0.14 mol%, from about 0.01 mol% to about 0.12 mol%, or from about 0.01 mol% to about 0.10 mol%, and all ranges and sub-ranges therebetween.

[0093] Where the glass composition includes TiO2, TiO2 may be present in an amount of about 5 mol% or less, about 2.5 mol% or less, about 2 mol% or less, or about 1 mol% or less. In one or more embodiments, the glass composition may be substantially free of TiO2.

[0094] Exemplary glass compositions include SiO2 in an amount ranging from about 65 mol% to about 75 mol%, Al2O3 in an amount ranging from about 8 mol% to about 14 mol%, Na2O in an amount ranging from about 12 mol% to about 17 mol%, KO in an amount ranging from about 0 mol% to about 0.2 mol%, and MgO in an amount ranging from about 1.5 mol% to about 6 mol%. Optionally, SnO2 may be included in an amount as otherwise disclosed herein. It should be understood that while the foregoing glass composition paragraphs express approximate ranges, in other embodiments, the glass sheet 12 may be made of any glass composition that falls within any of the precise numerical ranges discussed above.

[0095] Aspect (1) of the present disclosure relates to a curved glass article comprising: a glass sheet comprising a first major surface and a second major surface, the second major surface being opposite the first major surface, wherein the first major surface and the second major surface define a thickness therebetween; a carrier comprising a curvature and comprising a carrier material having a coefficient of thermal expansion (CTE) of 8 (10 -6 ) / ℃ to 40(10 -6 ) / °C; wherein the glass sheet is adhered to the carrier so that the glass sheet conforms to the curvature of the carrier.

[0096] Aspect (2) of the present disclosure relates to the curved glass article of aspect (1), wherein the carrier comprises a first strip along a first side edge of the glass sheet and a second strip along a second side edge of the glass sheet.

[0097] Aspect (3) of the present disclosure relates to the curved glass article of aspect (2), wherein the carrier further comprises at least one reinforcing strip extending from the first strip to the second strip.

[0098] Aspect (4) of the present disclosure relates to the curved glass article of any one of aspects (1) to (3), wherein the carrier material is a steel alloy.

[0099] Aspect (5) of the present disclosure relates to the curved glass article of aspect (4), wherein the steel alloy is a stainless steel alloy or a galvanized steel alloy.

[0100] Aspect (6) of the present disclosure relates to the curved glass article of one of aspects (1) to (3), wherein the carrier material is a fiber-reinforced composite material.

[0101] Aspect (7) of the present disclosure relates to the curved glass article of aspect (6), wherein the fiber-reinforced composite material comprises at least one of carbon fibers, glass fibers, aramid fibers, or graphite fibers, and wherein the fiber-reinforced composite material comprises at least one of epoxy resin, polycarbonate, acrylic, polyester, polyetherketoneketone, polycarbonate / acrylonitrile butadiene styrene, polypropylene, or phenolic resin.

[0102] Aspect (8) of the present disclosure relates to the curved glass article of aspect (7), wherein the fiber-reinforced composite material comprises glass fibers and an epoxy resin, and wherein the glass fibers comprise 0.38 to 0.52 of the volume fraction of the reinforced composite material.

[0103] Aspect (9) of the present disclosure relates to the curved glass article of any one of aspects (1) to (8), wherein the curved glass article is V-shaped.

[0104] Aspect (10) of the present disclosure relates to the curved glass article of any one of aspects (1) to (8), wherein the curved glass article is C-shaped.

[0105] Aspect (11) of the present disclosure relates to the curved glass article of any one of aspects (1) to (10), wherein the curvature has a radius of curvature of 20 mm to 10,000 mm.

[0106] Aspect (12) of the present disclosure relates to the curved glass article of any one of aspects (1) to (11), wherein the glass sheet comprises at least one of soda-lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.

[0107] Aspect (13) of the present disclosure relates to the curved glass article of any one of aspects (1) to (12), wherein the thickness of the glass sheet is 0.4 mm to 2.0 mm.

[0108] Aspect (14) of the present disclosure relates to the curved glass article of any one of aspects (1) to (13), wherein at least one of the first major surface or the second major surface comprises a surface treatment.

[0109] Aspect (15) of the present disclosure relates to the curved glass article of aspect (14), wherein the surface treatment is at least one of a tinted film, a pigment design, an anti-glare treatment, an anti-reflective coating, and an easy-to-clean coating.

[0110] Aspect (16) of the present disclosure relates to the curved glass article of any one of aspects (1) to (15), wherein the carrier comprises a segmented strip adhered to at least one side edge of the glass sheet.

[0111] Aspect (17) of the present disclosure relates to the curved glass article of aspect (16), wherein the segmented strip comprises a plurality of detents and a plurality of bonding surfaces, the detents being configured to connect the carrier to a frame of a vehicle interior system, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet, and wherein the segmented strip defines a zigzag structure along its length.

[0112] Aspect (18) of the present disclosure relates to the curved glass article of aspect (16), wherein the segmented strip comprises hooks, a plurality of bonding surfaces, and a plurality of grooves, the hooks being configured to connect the carrier to a frame of a vehicle interior system, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet, and the plurality of grooves being periodically spaced along the length of the segmented strip.

[0113] Aspect (19) of the present disclosure relates to the curved glass article of any one of aspects (1) to (15), wherein the carrier comprises at least one strip having a bonding surface and a mounting surface, the bonding surface being adhered to the second major surface of the glass sheet, the mounting surface comprising a plurality of holes configured to receive fasteners that connect the carrier to a frame of a vehicle interior system, and wherein the mounting surface is arranged substantially perpendicular to the bonding surface.

[0114] Aspect (20) of the present disclosure relates to the curved glass article of any one of aspects (1) to (19), further comprising at least one display mounted to the second major surface of the glass sheet.

[0115] Aspect (21) of the present disclosure relates to the curved glass article of aspect (20), wherein at least one display comprises at least one of a light emitting diode display, an organic light emitting diode display, a liquid crystal display, or a plasma display.

[0116] Aspect (22) of the present disclosure relates to a curved glass article comprising:

[0117] A glass sheet comprising a first major surface and a second major surface, the second major surface opposite the first major surface, wherein the first major surface and the second major surface define a thickness therebetween; a carrier comprising a curvature; an adhesive bonding the second major surface of the glass sheet to the carrier such that the glass sheet conforms to the curvature of the carrier; wherein the adhesive has a bond strength; and wherein a combined stress comprises a bending stress that causes the glass sheet to conform to the curvature and a shear stress caused by the differential expansion of the glass sheet and the carrier when heated from room temperature to 75° C.; and wherein the combined stress is less than the bond strength.

[0118] Aspect (23) relates to the curved glass article of aspect (22), wherein the combined stress does not exceed 1.4 MPa.

[0119] Aspect (24) relates to the curved glass article of aspect (22) or aspect (23), wherein the bonding strength is at most 0.6 MPa.

[0120] Aspect (25) of the present disclosure relates to the curved glass article of any one of aspects (22) to (24), wherein the carrier comprises a glass having a thermal expansion coefficient of 8 (10 -6 ) / ℃ to 40(10 -6 ) / ℃ carrier material.

[0121] Aspect (26) of the present disclosure relates to the curved glass article of aspect (25), wherein the carrier material is a steel alloy.

[0122] Aspect (27) of the present disclosure relates to the curved glass article of aspect (25), wherein the carrier material is one of an iron-nickel alloy, aluminum and its alloys, or magnesium and its alloys.

[0123] Aspect (28) of the present disclosure relates to the curved glass article of aspect (25), wherein the steel alloy is a stainless steel alloy or a galvanized steel alloy.

[0124] Aspect (29) of the present disclosure relates to the curved glass article of aspect (25), wherein the carrier material is a fiber-reinforced composite material.

[0125] Aspect (30) of the present disclosure relates to the curved glass article of aspect (29), wherein the fiber-reinforced composite material comprises at least one of carbon fibers, glass fibers, aramid fibers, or graphite fibers, and wherein the fiber-reinforced composite material comprises at least one of epoxy, polycarbonate, acrylic, polyester, polyetherketoneketone, polycarbonate / acrylonitrile butadiene styrene, polypropylene, or phenolic resin.

[0126] Aspect (31) of the present disclosure relates to the curved glass article of aspect (30), wherein the fiber-reinforced composite material comprises glass fibers and an epoxy resin, and wherein the glass fibers comprise 0.38 to 0.52 of the volume fraction of the fiber-reinforced composite material.

[0127] Aspect (32) of the present disclosure relates to the curved glass article of any one of aspects (22) to (31), wherein the curved glass article is V-shaped.

[0128] Aspect (33) of the present disclosure relates to the curved glass article of any one of aspects (22) to (31), wherein the curved glass article is C-shaped.

[0129] Aspect (34) of the present disclosure relates to the curved glass article of any one of aspects (22) to (33), wherein the curvature has a radius of curvature of 20 mm to 10,000 mm.

[0130] Aspect (35) of the present disclosure relates to the curved glass article of any one of aspects (22) to (34), wherein the glass sheet comprises at least one of soda-lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.

[0131] Aspect (36) of the present disclosure relates to the curved glass article of any one of aspects (22) to (35), wherein the thickness of the glass sheet is from 0.4 mm to 2.0 mm.

[0132] Aspect (37) of the present disclosure relates to the curved glass article of any one of aspects (22) to (36), wherein at least one of the first major surface or the second major surface comprises a surface treatment.

[0133] Aspect (38) of the present disclosure relates to the curved glass article of aspect (37), wherein the surface treatment is at least one of a tinted film, a pigment design, an anti-glare treatment, an anti-reflective coating, and an easy-to-clean coating.

[0134] Aspect (39) of the present disclosure relates to the curved glass article of any one of aspects (22) to (38), wherein the carrier comprises a segmented strip adhered to at least one side edge of the glass sheet.

[0135] Aspect (40) of the present disclosure relates to the curved glass article of any one of aspects (22) to (39), wherein the segmented strip comprises a plurality of detents and a plurality of bonding surfaces, the plurality of detents being configured to connect the carrier to the vehicle interior frame, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet, and wherein the segmented strip defines a zigzag structure along its length.

[0136] Aspect (41) of the present disclosure relates to the curved glass article of aspect (39), wherein the segmented strip comprises hooks, a plurality of bonding surfaces, and a plurality of grooves, the hooks being configured to connect the carrier to a frame of a vehicle interior system, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet, and the plurality of grooves being periodically spaced along the length of the segmented strip.

[0137] Aspect (42) of the present disclosure relates to the curved glass article of any one of aspects (22) to (41), wherein the carrier comprises at least one strip having a bonding surface and a mounting surface, the bonding surface being adhered to the second major surface of the glass, the mounting surface comprising a plurality of holes configured to receive fasteners, the fasteners connecting the carrier to a frame of a vehicle interior system, and wherein the mounting surface is arranged substantially perpendicular to the bonding surface.

[0138] Aspect (43) of the present disclosure relates to the curved glass article of any one of aspects (22) to (42), further comprising at least one display mounted to the second major surface of the glass sheet.

[0139] Aspect (44) of the present disclosure relates to the curved glass article of aspect (43), wherein at least one display comprises at least one of a light emitting diode display, an organic light emitting diode display, a liquid crystal display, or a plasma display.

[0140] Unless otherwise expressly stated, it is not intended that any method described herein be construed as requiring that its steps be performed in a specific order. Therefore, in the absence of a method claim stating the order in which its steps are to be followed or in the absence of other specific statements in the claims or description that the steps are to be limited to a specific order, it is not intended that any specific order be inferred. In addition, as used herein, the article "a" is intended to include one or more than one component or element and is not intended to be construed as meaning only one.

[0141] It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since those skilled in the art may make modifications, combinations, sub-combinations, and variations to the disclosed embodiments incorporating the spirit and substance of the embodiments, the disclosed embodiments should be construed to include all matters within the scope of the appended claims and their equivalents.

Claims

1. A curved glass product comprising: a glass sheet comprising a first major surface and a second major surface, the second major surface opposite the first major surface, wherein the first major surface and the second major surface define a thickness therebetween; A carrier comprising a curvature and a carrier material, wherein the coefficient of thermal expansion (CTE) of the carrier material is 8 (10 -6 ) / ℃ to 40(10 -6 ) / °C, wherein the curvature radius is 20 mm to 10,000 mm; wherein the first major surface or the second major surface of the glass sheet is adhered to the carrier so that the glass sheet conforms to the curvature of the carrier, The carrier defines a frame along the side of the glass sheet, and the width of the frame is less than or equal to 10 mm. wherein the carrier comprises a segmented strip adhered to at least one side edge of the glass sheet, and wherein the segmented strip comprises a plurality of detents and a plurality of bonding surfaces, the plurality of detents being configured to couple the carrier to a frame of a vehicle interior system, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet and wherein the segmented strip defines a zigzag structure along its length, or wherein the segmented strip comprises a hook, a plurality of bonding surfaces and a plurality of grooves, the hook being configured to couple the carrier to a frame of a vehicle interior system, the plurality of bonding surfaces being adhered to the second major surface of the glass sheet, and the plurality of grooves being periodically spaced along the length of the segmented strip.

2. The curved glass article of claim 1, wherein the carrier comprises a first strip along a first side of the glass sheet and a second strip along a second side of the glass sheet. 3 . The curved glass article of claim 2 , wherein the carrier further comprises at least one reinforcing strip extending from the first strip to the second strip.

4. The curved glass article according to any one of the preceding claims, wherein the carrier material is a steel alloy.

5. The curved glass article of claim 4, wherein the steel alloy is a stainless steel alloy or a galvanized steel alloy.

6. The curved glass article of any one of claims 1 to 3, wherein the carrier material is a fiber-reinforced composite material.

7. The curved glass article of claim 6, wherein the fiber-reinforced composite material comprises at least one of carbon fibers, glass fibers, aramid fibers, or graphite fibers, and wherein the fiber-reinforced composite material comprises at least one of epoxy, polycarbonate, acrylic, polyester, polyetherketoneketone, polycarbonate / acrylonitrile butadiene styrene, polypropylene, or phenolic resin.

8. The curved glass article of claim 7, wherein the fiber-reinforced composite material comprises glass fibers and epoxy resin, and wherein the glass fibers constitute 0.38 to 0.52 of the volume fraction of the fiber-reinforced composite material.

9. The curved glass article according to any one of claims 1 to 3, wherein the curved glass article is V-shaped.

10. The curved glass article of any one of claims 1 to 3, wherein the curved glass article is C-shaped.

11. The curved glass article according to any one of claims 1 to 3, wherein the glass sheet comprises at least one of soda-lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.

12. The curved glass article according to any one of claims 1 to 3, wherein the glass sheet has a thickness of 0.4 mm to 2.0 mm.

13. The curved glass article of any one of claims 1 to 3, wherein at least one of the first major surface or the second major surface comprises a surface treatment.

14. The curved glass article of claim 13, wherein the surface treatment is at least one of a tinted film, a pigmented design, an anti-glare treatment, an anti-reflective coating, and an easy-to-clean coating.

15. The curved glass article of any one of claims 1 to 3, wherein the carrier comprises at least one strip having a bonding surface adhered to the second major surface of the glass sheet and a mounting surface, the bonding surface comprising a plurality of holes configured to receive fasteners that connect the carrier to a frame of a vehicle interior system, and wherein the mounting surface is arranged substantially perpendicular to the bonding surface.

16. The curved glass article of any one of claims 1 to 3, further comprising at least one display mounted to the second major surface of the glass sheet.

17. The curved glass article of claim 16, wherein the at least one display comprises at least one of a light emitting diode display, an organic light emitting diode display, a liquid crystal display, or a plasma display.

18. A curved glass product comprising: a glass sheet comprising a first major surface and a second major surface, the second major surface opposite the first major surface, wherein the first major surface and the second major surface define a thickness therebetween; A carrier comprising a curvature and a carrier material, wherein the coefficient of thermal expansion (CTE) of the carrier material is 8 (10 -6 ) / ℃ to 40(10 -6 ) / °C, wherein the curvature radius is 20 mm to 10,000 mm; an adhesive that bonds the second major surface of the glass sheet to the carrier so that the glass sheet conforms to the curvature of the carrier; wherein the adhesive has cohesive strength; and wherein the combined stress comprises a bending stress causing the glass sheet to conform to the curvature and a shear stress caused by the expansion difference between the glass sheet and the carrier when the glass sheet and the carrier are heated from room temperature to 75° C.; wherein the combined stress is less than the bond strength; wherein the carrier defines a frame along the side of the glass sheet, and the width of the frame is less than or equal to 10 mm; and The carrier comprises at least one strip having a bonding surface adhered to the second major surface of the glass sheet and a mounting surface, the bonding surface comprising a plurality of holes configured to receive fasteners that connect the carrier to a frame of a vehicle interior trim system, and wherein the mounting surface is arranged substantially perpendicular to the bonding surface.

19. The curved glass article of claim 18, wherein the combined stress does not exceed 1.4 MPa.

20. The curved glass article of claim 18 or claim 19, wherein the bond strength is at most 0.6 MPa.

21. The curved glass article of claim 19, wherein the carrier material is a steel alloy.

22. The curved glass article of claim 19, wherein the carrier material is one of an iron-nickel alloy, aluminum and its alloys, or magnesium and its alloys.

23. The curved glass article of claim 21, wherein the steel alloy is a stainless steel alloy or a galvanized steel alloy.

24. The curved glass article of claim 19, wherein the carrier material is a fiber-reinforced composite material.

25. The curved glass article of claim 24, wherein the fiber-reinforced composite material comprises at least one of carbon fibers, glass fibers, aramid fibers, or graphite fibers, and wherein the fiber-reinforced composite material comprises at least one of epoxy, polycarbonate, acrylic, polyester, polyetherketoneketone, polycarbonate / acrylonitrile butadiene styrene, polypropylene, or phenolic resin.

26. The curved glass article of claim 25, wherein the fiber-reinforced composite material comprises glass fibers and epoxy resin, and wherein the glass fibers constitute 0.38 to 0.52 of the volume fraction of the fiber-reinforced composite material.

27. The curved glass article of any one of claims 18 to 19, wherein the curved glass article is V-shaped.

28. The curved glass article of any one of claims 18 to 19, wherein the curved glass article is C-shaped.

29. The curved glass article of any one of claims 18 to 19, wherein the glass sheet comprises at least one of soda-lime glass, aluminosilicate glass, borosilicate glass, boroaluminosilicate glass, alkali-containing aluminosilicate glass, alkali-containing borosilicate glass, and alkali-containing boroaluminosilicate glass.

30. The curved glass article of any one of claims 18 to 19, wherein the glass sheet has a thickness of 0.4 mm to 2.0 mm.

31. The curved glass article of any one of claims 18 to 19, wherein at least one of the first major surface or the second major surface comprises a surface treatment.

32. The curved glass article of claim 31, wherein the surface treatment is at least one of a tinted film, a pigmented design, an anti-glare treatment, an anti-reflective coating, and an easy-to-clean coating.

33. The curved glass article of any one of claims 18 to 19, further comprising at least one display mounted to the second major surface of the glass sheet.

34. The curved glass article of claim 33, wherein the at least one display comprises at least one of a light emitting diode display, an organic light emitting diode display, a liquid crystal display, or a plasma display.

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