Composite comprising a platinum-alkaline earth metal alloy, fuel cell comprising the composite, and water electrolysis cell and methods for their production

By preparing a platinum-alkaline earth metal binary alloy on a carbon support, the problem of insufficient activity and durability of platinum-based catalysts in fuel cells and water electrolysis cells was solved, and the economy and stability of the catalyst were improved, making it suitable for oxygen reduction reaction and hydrogen evolution reaction.

CN116529427BActive Publication Date: 2026-05-12DAEGU GYEONGBUK INSTITUTE OF SCIENCE AND TECHNOLOGY
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Patent Information

Application Number
CN202280007850.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2021-11-01
Filing Date
2022-11-01
Publication Date
2026-05-12
Estimated Expiration
2042-11-01

AI Technical Summary

Technical Problem

In the existing technology, platinum-based catalysts have shortcomings in terms of activity, durability and economy in fuel cells and water electrolysis batteries. In particular, the synthesis of platinum-alkaline earth metal alloys is difficult to achieve, which limits the improvement of catalyst performance.

Method used

By preparing platinum-alkaline earth metal binary alloys on carbon supports and controlling the E1/E2 ratio in the Pt4f XPS energy spectrum to be ≤0.85, granular PtSr, Pt2Ca, Pt3Mg alloys are formed. Combined with solvothermal synthesis and heat treatment methods, dealloying and poisoning phenomena are suppressed, and the stability of the catalyst is improved.

Benefits of technology

Significant improvements have been made in the economy, activity, and stability of the catalyst, making it suitable for oxygen reduction and hydrogen evolution reactions, and enhancing the performance of fuel cells and water electrolysis cells.

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Abstract

The present invention relates to a composite having the advantages of economy, excellent catalyst activity, and significantly improved stability compared to conventional pure platinum catalysts, and specifically, the composite according to the present invention includes: a carbon support; and a binary alloy loaded on the carbon support and containing platinum (Pt) and an alkaline earth metal, wherein, in a Pt 4f XPS spectrum of the binary alloy based on X-ray photoelectron spectroscopy (XPS), E1 and E2 defined by the following Formula 1 and Formula 2 satisfy the following Formula 3. (Formula 1) E1 = E0 - E0(ref) (Formula 2) E2 = EII - EII(ref) (Formula 3) E1 / E2 ≤ 0.85, in Formula 1 and Formula 2, E0(ref) and EII(ref) are binding energies (centers) of a Pt(0) peak and a Pt(II) peak, respectively, in a Pt 4f XPS spectrum of pure platinum (Pt), and E0 and EII are binding energies (centers) of a Pt(0) peak and a Pt(II) peak, respectively, in a Pt 4f XPS spectrum of the binary alloy.
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