A non-vacuum preparation method of copper-chromium-zirconium alloy and copper-chromium-zirconium alloy
CN116656984BActive Publication Date: 2026-08-28KUNMING METALLURGY INST
Patent Information
- Application Number
- CN202310949108.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-07-31
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2043-07-31
AI Technical Summary
Technical Problem
真空熔炼的环境虽然能有效的隔绝Zr与O2接触,确保Zr的收得率,但真空环境不利于工业化的推广、批量生产和生产成本的控制,而且不能生产大规格用于轧板用的铸锭
Benefits of technology
1、本发明采用高纯阴极铜和铜铬中间合金、铜锆中间合金材料在还原性条件下加热熔化,并通过综合控制合金熔体温度,铜铬中间合金与铜锆中间合金的加料顺序及比例、加料工具与入炉方法等多方面因素,有效的克服了铬元素难溶,以及锆元素高熔点、在加热时大量吸收氧,易与氧结合导致的锆元素收得率低的缺点,明显降低了铜铬锆合金中的氧含量和锆元素的氧化损失。
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Abstract
The application discloses a non-vacuum preparation method of copper-chromium-zirconium alloy and the copper-chromium-zirconium alloy. The preparation method comprises the following steps: taking high-purity negative plate copper, copper-chromium intermediate alloy and copper-zirconium intermediate alloy according to proportions and preparing high-purity graphite; the graphite crucible of the intermediate frequency induction furnace is heated to 1150-1300 DEG C, the high-purity negative plate copper and the copper-chromium intermediate alloy are added, and the alloy melt with a temperature of 1210+ / -15 DEG C is formed; the copper-zirconium intermediate alloy is inserted into the melt liquid surface under 50-150 mm by using a feeding tool, the tool is taken out after 3-5 min of heat preservation and stirring; the high-purity graphite is covered on the alloy melt liquid surface and / or inert gas is continuously introduced above; the copper-chromium-zirconium alloy melt is sampled and detected by using a sampling spoon; the copper-chromium-zirconium alloy melt is discharged from the furnace and cast, and the casting temperature is 1200+ / -10 DEG C. The copper-chromium-zirconium alloy is prepared by using the preparation method. The application has the characteristics of low oxygen content, uniform zirconium distribution, small burning loss and low preparation cost.
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Citation Information
Patent Citations
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