A multi-stage rolled fine-grain pressure vessel steel sheet and a method of manufacturing the same

Abstract

The application discloses a multi-stage rolling fine-grain pressure vessel steel plate and a manufacturing method thereof. The composition of the steel plate is as follows in terms of percentage by weight: C: 0.20-0.30%, Si: 0.15-0.40%, Mn: 0.90-1.50%, P: 0.015% or less, S: 0.005% or less, Cr: 0.20-0.30%, Ni: 0.30-0.40%, Mo: 1.0-2.0%, Nb: 0.01-0.02%, Ti: 0.02-0.03%, Cu: 0.15-0.25%, V: 0.02-0.03%, B: 0.001-0.002%, Als: 0.025-0.035%, N: 0.06-0.08%, and the balance of Fe and inevitable impurities. The steel plate has not only high room temperature strength, but also good room temperature plasticity and relatively high hardness.

Description

TECHNICAL FIELD

[0001] The present application relates to a multi-stage rolling fine-grain pressure vessel steel plate and a manufacturing method thereof, and belongs to the technical field of steel. BACKGROUND

[0002] Traditional medium carbon steel is suitable for the production of tool steel and die steel with low toughness requirement due to its high hardness and high strength, but it cannot be used for the production of structural materials such as pressure vessels due to its brittleness. With the continuous development of the industry, the development direction of equipment tends to be large-scale, high-performance and long-term service, which puts higher requirements on the raw materials for equipment manufacturing. The strength and toughness of traditional low-carbon alloy container steel plate cannot meet the manufacturing requirements of high-end pressure vessel equipment. As known, the performance of a material depends on the type of organization, and the uniform refinement of the organization will greatly improve the comprehensive mechanical properties of the material and achieve a high matching degree of strength and toughness. At present, the organization refinement of low-carbon steel has been successfully realized, but the organization refinement of medium and high carbon steel is still under research.

[0003] CN201911106651.8 discloses a method for refining the solidification structure of steel continuous casting billet based on target equiaxed crystal size and proportion. In the steelmaking process, a specified amount of one or more modification elements is added at one or more nodes in the smelting, refining and continuous casting process according to the target equiaxed crystal proportion and size under the corresponding working condition parameters. The molten steel containing the modification elements is poured into the billet to realize the refinement of the solidification structure. CN201510900912.9 discloses a method for refining and purifying the solidification structure of thick-walled cast steel parts. On the basis of pre-deoxidation of ferrosilicon and ferromanganese and silicon-calcium-barium alloy in the furnace, the final deoxidization and solidification structure refinement process are combined together and carried out in the ladle, thereby realizing the refinement and purification of the solidification structure of thick-walled cast steel parts. CN201510112841.6 discloses a method for refining the structure of steel and improving its mechanical properties by adding nano-particles. After mixing and uniformly dispersing the nano-particles and alloy nano-powder, they are filled into an elongated steel pipe and compacted and sealed. Under a fixed continuous casting speed, the steel pipe is slowly stretched into the steel flow below the crystallizer at a certain speed, relying on the continuous impact force of the molten steel flowing from the tundish and the turbulent flow field inside the crystallizer, so that the nano-particles enter the molten steel and quickly disperse. However, the above-mentioned organization refinement method has a limited degree of grain refinement, so the performance improvement is also limited. CN201610841911.6 discloses a fine-grain modification agent prepared by mixing powders obtained by atomization of ferrotitanium, ferrovanadium and ferro-niobium in a set ratio and then mixing them with rare earth ferrosilicon particles in a set ratio. Although the refinement effect is improved, the by-products AlCl3, HCl and chlorine will cause serious damage to the human body, environment and equipment. SUMMARY

[0004] The present application aims to overcome the above problems and deficiencies, and provides a multi-stage rolling fine-grained pressure vessel steel plate and a manufacturing method thereof.

[0005] The present application adopts micro-alloying + high-temperature short-time homogenization treatment + multi-stage rolling + intercritical quenching organization refining technology to realize the refinement of micro composite organization, so that the medium carbon steel not only has high room temperature strength, but also has good room temperature plasticity and higher hardness.

[0006] In order to achieve the above-mentioned purpose, the technical scheme of the present application is as follows:

[0007] In one aspect, the present application provides a fine-grained pressure vessel steel plate, the composition of the steel plate is as follows in terms of percentage by weight: C: 0.20-0.30%, Si: 0.15-0.40%, Mn: 0.90-1.50%, P≤0.015%, S≤0.005%, Cr: 0.20-0.30%, Ni: 0.30%-0.40%, Mo: 1.0%-2.0%, Nb: 0.01-0.02%, Ti: 0.02-0.03%, Cu: 0.15-0.25%, V: 0.02-0.03%, B: 0.001-0.002%, Als: 0.025-0.035%, N: 0.06-0.08%, and the balance is Fe and unavoidable impurities.

[0008] The mechanism of each alloying element in the steel plate of the present application is as follows:

[0009] (1) C: C is the main component element of the steel, the strength of the steel mainly depends on the content of C element in the steel, too high C element content will result in poor toughness, plasticity and welding performance of the steel; low C element content will result in low strength and performance after simulated stress relief treatment of the steel. In order to ensure that the steel plate has good matching of low temperature impact toughness, strength and welding performance during use, therefore, the C content in the steel plate of the present application should be controlled in the range of 0.20-0.30%.

[0010] (2) Si: adding Si in the medium carbon steel has influence on the thermodynamics of iron-carbon system and the kinetics of carbide formation and dissolution. Silicon as a ferrite stabilizing element will increase the Ac1 point of the steel. The addition of silicon results in the decrease of carbon content of the eutectoid composition, thereby increasing the number of pro-eutectoid carbides, so that the volume fraction of carbides for pinning grain boundaries in the gamma + theta two-phase region is increased. In this way, the growth of ferrite and austenite grains is inhibited. Silicon is insoluble in carbides, when carbides precipitate, silicon is distributed around the carbides, forming a high concentration area of silicon. Silicon is also an element that increases the activity of carbon. In the high concentration area of silicon, the activity of carbon also increases accordingly, which reduces the diffusion flux of carbon to carbides, so that the coarsening of carbides can be inhibited, therefore, the Si content in the steel plate of the present application is controlled in the range of 0.15-0.40%.

[0011] (3) Mn: Mn element can strengthen ferrite in steel grade through solid solution strengthening, C-Mn strengthening is also the main way to improve the strength of low carbon steel, but if Mn content is too high, it increases the production cost, and Mn element is easy to combine with S element to generate MnS, which reduces the material's resistance to hydrogen-induced cracking, therefore, Mn content in the steel plate of the present application is controlled at 0.90-1.50%.

[0012] (4) P: P is a harmful element in steel, which increases the cold brittleness of steel, makes the welding performance worse, reduces the plasticity, makes the cold bending performance worse, and P is particularly sensitive to irradiation embrittlement. Therefore, the lower the P content in steel, the better, and the P content in the steel plate of the present application is less than 0.015%.

[0013] (5) S: S is a harmful element under normal circumstances. S is easy to form brittle sulfide with alloying elements in steel, which makes the steel produce thermal brittleness, reduces the ductility and toughness of the steel, and S also has the tendency to accelerate irradiation embrittlement. Therefore, the S content in the steel plate of the present application is controlled at 0.005% or less.

[0014] (6) Als: Aluminum alloying can also increase the Ac1 point of steel, refine and uniformly distribute proeutectoid cementite, and inhibit the formation of network carbide. After adding aluminum, the grain boundary carbide and widmanstatten carbide disappear, and a refined complete pearlite structure is obtained. Therefore, the Al content in the steel plate of the present application is controlled at 0.025-0.035%.

[0015] (7) V: V is a micro-alloying element, and V micro-alloying in steel can form fine second phase particles, play the role of pinning grain boundaries and precipitation strengthening, effectively refine the grain, and greatly improve the comprehensive mechanical properties of the steel such as strength, toughness, ductility and thermal fatigue resistance, therefore, the V content in the steel plate of the present application is controlled at 0.02-0.03%.

[0016] (8) Ni: Ni is a solid solution strengthening element in steel which can improve the strength of steel. Ni reduces the resistance to dislocation movement of the steel grade, relaxes the stress, and thus changes the substructure of the matrix structure, thereby improving the toughness of the steel, especially the low temperature toughness. Therefore, the Ni content in the steel plate of the present application is controlled at 0.30-0.40%.

[0017] (9) Cr: Chromium is an element that stabilizes carbides. Adding chromium reduces the dissolution rate of carbides. Therefore, when using thermal deformation organization refinement process, even if the heating temperature is increased or the heating time is prolonged, the eutectoid transformation can still be avoided to obtain a refined structure. Chromium can also inhibit the graphitization of silicon and aluminum containing ultra-high carbon steel. Therefore, the Cr content in the steel plate of the present application is controlled at 0.20-0.30%.

[0018] (10) Cu: The outstanding role of Cu in the steel is to improve the corrosion resistance of plain low alloy steel, and also to improve the strength and yield ratio of the steel, but it has no adverse effect on the welding performance, but when the content is high, it leads to copper brittleness during hot deformation processing. Therefore, the Cu content in the steel is controlled to be 0.15-0.25%.

[0019] (11) Nb: Nb as a strong carbide forming element forms NbC phase with large dispersion and good high temperature stability in the steel, which plays a role of precipitation strengthening, and through multi-stage rolling, the grain can be effectively refined, the toughness reduction caused by precipitation strengthening is improved, so that the steel plate obtains high strength and high toughness. In addition, in the steel with Nb-Mo composite addition, Mo can also be segregated on the interface of NbC matrix, preventing the coarsening of NbC particles, thereby greatly improving the high temperature strength of the steel, therefore the Nb content in the steel plate is controlled to be 0.01-0.02%.

[0020] (12) Mo: Mo mainly relies on solid solution strengthening and grain boundary strengthening to improve the strength of the steel; secondly, Mo increases the stability of undercooled austenite, and moves the austenite to ferrite transformation curve to the right, and after phase transition, more fine ferrite structure is obtained; in addition, Ti and Mo combine to precipitate a large amount of nanometer-sized Ti-Mo(CN) carbide in the steel, which pins dislocations, greatly improving the strength and toughness of the steel, therefore the Mo content in the steel plate is controlled to be 1.0-2.0%

[0021] (13) Ti: Adding appropriate amount of Ti can form a large number of fine TiN or Ti2O3 particles which are dispersedly distributed, they can act as heterogeneous nucleation core of acicular ferrite during organization solidification, thereby refining the organization. Ti also has the effect of deoxidation, which ensures that B is not oxidized and nitrided. B can reduce the transformation temperature of austenite to ferrite, promote the formation of intragranular acicular ferrite, and play a role in refining the grain. However, when w(Ti)≥0.09%, the content of acicular ferrite is reduced, which deteriorates the low temperature toughness of the steel plate, therefore the Ti content in the steel plate is controlled to be 0.02-0.03%.

[0022] (14) B: B can reduce the transformation temperature of austenite to ferrite, promote the formation of intragranular acicular ferrite, and play a role in refining the grain. Therefore, the B content in the steel plate is controlled to be 0.001-0.002%.

[0023] (15) N: N can combine with Ti to form a large number of fine TiN which are dispersedly distributed, they can act as heterogeneous nucleation core of acicular ferrite during organization solidification, thereby refining the organization. Therefore, the N content in the steel plate is controlled to be 0.06-0.08%.

[0024] In the technical solution, further, the microstructure of the steel plate is composed of ferrite and pearlite, wherein the grain size of the pearlite is 0.5-2.0 μm, and the ferrite grain size is 1-3.0 μm.

[0025] In the technical solution, further, the steel plate has a tensile strength of 650-790 MPa, a yield strength of 410-550 MPa, an elongation of 30-40%, an impact energy at-20 ℃ of 410-550 J, a surface Brinell hardness of 340-410 HBW, and a high-temperature tensile yield strength at 450 ℃ of 315-455 MPa.

[0026] In the technical solution, further, the thickness of the steel plate is 15-95 mm.

[0027] Another aspect of the present application provides a method for manufacturing the fine-grained pressure vessel steel plate, which comprises the following steps:

[0028] (1) Smelting: the thickness of the continuously cast billet after smelting is 150-350 mm;

[0029] (2) Homogenization treatment: after the continuously cast billet is smelted, the continuously cast billet is directly hot-charged into a heating furnace for homogenization treatment; homogenization annealing is performed in a single-phase austenite zone to fully dissolve carbon elements;

[0030] (3) Rough rolling and finish rolling: after the homogenization treatment, the continuously cast billet is hot sent to a rolling mill for rolling; first, the continuously cast billet is roughed and broken down, and after the rough rolling, the intermediate billet roller bed reciprocates and swings to be air-cooled; when the temperature is reduced to 600-650 ℃, the continuously cast billet is continuously finish-rolled in multiple passes; the thermal deformation in this process helps to break the pro-eutectoid cementite precipitated from the austenite, and avoids the formation of network carbide;

[0031] (4) Isothermal rolling: after the finish rolling, the steel plate is isothermally rolled at a temperature of 550-600 ℃ to break the pearlite structure formed by phase transition; the total deformation rate of the isothermal rolling is 1-2%.

[0032] (5) Subcritical quenching: after the isothermal rolling is completed, the steel plate is directly sent from the holding furnace to a heat treatment furnace for subcritical quenching treatment, and is cooled to room temperature by ACC water after being discharged.

[0033] In the technical solution, further, in the step (2), the homogenization temperature treatment is: the temperature is kept at 1140-1160 ℃ for 1-2 h.

[0034] In the technical scheme, further, in the step (3), the rough rolling opening rolling temperature is 1080-1110 DEG C, the finish rolling temperature is 810-840 DEG C, the guaranteeing of each pass reduction rate is 15-25%, and the intermediate blank thickness is 2-3 times of the finished steel plate thickness; the finish rolling guarantees the each pass reduction rate of 5-15%, and 1.0-2.0% deformation rate is reserved after the finish rolling to the final finished steel plate thickness.

[0035] In the technical scheme, further, in the step (4), the isothermal rolling is carried out in two stages, the first stage is the initial rolling of 0.5-1% deformation rate, the initial rolling is kept at 550-600 DEG C for 5-10 min, and the second stage is the finish rolling of 0.5-1% deformation rate, and the finish rolling is kept at 550-600 DEG C for 5-10 min.

[0036] In the technical scheme, further, in the step (5), the intercritical quenching temperature is 500-550 DEG C, and the net keeping time is 3-4 min / mm.

[0037] The beneficial effects of the present application are as follows:

[0038] 1. The high-temperature short-time homogenization treatment of the present application carries out the single-phase austenite zone homogenization annealing, fully dissolves the carbon element, and after the rough rolling, the finish rolling is helpful to break the pro-eutectoid cementite precipitated from the austenite, avoids the formation of network carbide; the isothermal rolling breaks the pearlite organization formed through the phase transition; the intercritical quenching obtains the completely spheroidized microstructure, the grain size of the pearlite reaches 0.5-2.0 μm, and the grain size of the ferrite reaches 1-3.0 μm; the present application realizes the refinement of the micro composite organization, so that the medium carbon steel not only has high room temperature strength, but also has good room temperature plasticity and higher hardness.

[0039] 2. The finished steel plate of the present application has the tensile strength of 650-790 MPa, the yield strength of 410-550 MPa, the elongation after fracture of 30-40%, the impact energy at-20 DEG C of 410-550 J, the surface Brinell hardness of 340-410 HBW, and the high-temperature tensile yield strength at 450 DEG C of 315-455 MPa; the good process performance and mechanical properties make it expected to be widely used in the field of pressure vessel equipment manufacturing. BRIEF DESCRIPTION OF DRAWINGS

[0040] Figure 1 The figure is the metallographic structure photo of the steel plate of example 1. DETAILED DESCRIPTION

[0041] The following examples are used to specifically illustrate the content of the present application, and these examples are only the general description of the content of the present application, and do not limit the content of the present application.

[0042] The components of the steel plates in examples 1-6 of the present application are shown in table 1.

[0043] Table 1 Composition of steel plates of Examples 1-6 (wt%)

[0044] Example C Si Mn P S N Cr Ni Mo Cu V Nb Ti Als B 1 0.26 0.31 1.29 0.010 0.003 0.071 0.26 0.36 1.6 0.20 0.025 0.016 0.027 0.031 0.0017 2 0.22 0.19 1.07 0.013 0.004 0.064 0.22 0.32 1.2 0.16 0.021 0.011 0.022 0.027 0.0013 3 0.24 0.24 1.14 0.011 0.003 0.068 0.24 0.34 1.4 0.18 0.023 0.013 0.025 0.030 0.0015 4 0.28 0.34 1.44 0.008 0.002 0.076 0.28 0.38 1.8 0.24 0.029 0.018 0.028 0.034 0.0019 5 0.20 0.15 0.90 0.015 0.005 0.060 0.20 0.30 1.0 0.15 0.02 0.010 0.020 0.025 0.001 6 0.30 0.40 1.50 0.005 0.001 0.080 0.30 0.40 2.0 0.25 0.030 0.020 0.030 0.035 0.002

[0045] The method for manufacturing the fine-grained pressure vessel steel plate described above comprises the following steps:

[0046] (1) Smelting: the molten steel is smelted into a continuous casting billet;

[0047] (2) Homogenization treatment: after the smelting of the continuous casting billet is completed, the continuous casting billet is directly hot-charged into a heating furnace to perform homogenization treatment; homogenization annealing in a single-phase austenite zone is performed to fully dissolve carbon elements; the main process parameters of smelting and homogenization treatment of Examples 1-6 are shown in Table 2;

[0048] Table 2 Main process parameters of smelting and homogenization treatment of Examples 1-6

[0049] Example Casting slab thickness / mm Finished steel plate thickness / mm Temperature holding temperature / °C Temperature holding time / h 1 150 15 1145 1.2 2 200 24 1157 1.5 3 230 32 1148 1.6 4 250 54 1156 1.9 5 300 77 1152 1.1 6 350 95 1146 1.5

[0050] (3) Rough rolling and finish rolling: after the homogenization treatment, the continuous casting billet is hot sent to a double-stand rolling mill for rolling; first, the continuous casting billet is roughed and broken down, and after the rough rolling, the intermediate billet roller bed reciprocates and swings to air cool, and after cooling, continuous multi-pass finish rolling is performed; the thermal deformation in this process helps to break the pro-eutectoid cementite precipitated from the austenite, thereby avoiding the formation of network carbides; the main process parameters of rough rolling and finish rolling treatment of Examples 1-6 are shown in Table 3;

[0051] Table 3 Main process parameters of rough rolling and finish rolling treatment of Examples 1-6

[0052]

[0053] (4) Isothermal rolling: after the finish rolling is completed, the steel plate is subjected to isothermal rolling to break the pearlite structure formed by phase transformation; the isothermal rolling is performed in two stages; the main process parameters of isothermal rolling of Examples 1-6 are shown in Table 4;

[0054] Table 4 Main process parameters of isothermal rolling of steel plates of Examples 1-6

[0055]

[0056] (5) Subcritical quenching: the steel plate after the isothermal rolling is directly sent out of the holding furnace and into a continuous heat treatment furnace for online subcritical quenching heat treatment, and the furnace is cooled to room temperature by ACC water; the main process parameters of subcritical quenching of Examples 1-6 are shown in Table 5;

[0057] Table 5 Main process parameters of subcritical quenching of steel plates of Examples 1-6

[0058] Example Temperature °C Net temperature holding time min / mm 1 549 3.9 2 502 4.0 3 509 3.0 4 517 3.1 5 537 3.4 6 522 3.7

[0059] AsFigure 1 As shown, the microstructure of the steel plate of Example 1 is composed of ferrite and pearlite, the performance of the fine-grained pressure vessel steel plate is tested, and the grain size and comprehensive mechanical properties of the steel plate are shown in Table 6.

[0060] Table 6 Grain size and comprehensive mechanical properties of steel plates of Examples 1-6

[0061]

[0062]

[0063] In order to describe the present application, the above-mentioned embodiments are appropriately and sufficiently described by examples, the above embodiments are only used to illustrate the present application, and are not limited to the present application. Those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present application. Any modification, equivalent replacement, improvement, etc. shall be included in the protection scope of the present application, and the patent protection scope of the present application shall be defined by the claims.

Claims

1. A fine-grained pressure vessel steel plate, characterized in that, The composition of the fine-grained pressure vessel steel plate, by weight percentage, is as follows: C: 0.20~0.30%, Si: 0.15~0.40%, Mn: 0.90~1.50%, P≤0.015%, S≤0.005%, Cr: 0.20~0.30%, Ni: 0.30~0.40%, Mo: 1.0~2.0%, Nb: 0.01~0.02%, Ti: 0.02~0.03%, Cu: 0.15~0.25%, V: 0.02~0.03%, B: 0.001~0.002%, Als: 0.025~0.035%, N: 0.06~0.08%, with the balance being Fe and unavoidable impurities; The manufacturing method of the fine-grained pressure vessel steel plate includes the following steps: (1) Smelting: The thickness of the continuously cast billet is 150~350mm; (2) Homogenization treatment: After the continuous casting billet is smelted, it is directly charged into the heating furnace for homogenization treatment. (3) Rough rolling and finish rolling: After homogenization, the continuous casting billet is hotly sent to the rolling mill for rolling. First, the continuous casting billet is rough rolled to open the billet. After rough rolling, the intermediate billet is oscillated and air-cooled on the roller table. When the temperature drops to 600~650℃, it is continuously rolled in multiple passes. (4) Isothermal rolling: After finishing rolling, the steel plate is isothermal rolled at a temperature of 550~600℃, and the total deformation rate of isothermal rolling is 1~2%; (5) Sub-temperature quenching: After isothermal rolling, the steel plate is directly sent to the heat treatment furnace for sub-temperature quenching after exiting the holding furnace, and then cooled to room temperature by ACC water cooling after exiting the furnace.

2. The fine-grained pressure vessel steel plate according to claim 1, characterized in that, The microstructure of the fine-grained pressure vessel steel plate consists of ferrite and pearlite, wherein the grain size of pearlite is 0.5~2.0μm and the grain size of ferrite is 1~3.0μm.

3. The fine-grained pressure vessel steel plate according to claim 1, characterized in that, The fine-grained pressure vessel steel plate has a tensile strength of 650~790MPa, a yield strength of 410~550MPa, an elongation after fracture of 30~40%, an impact energy of 410~550J at -20℃, a surface Brinell hardness of 340~410HBW, and a high-temperature tensile yield strength of 315~455MPa at 450℃.

4. The fine-grained pressure vessel steel plate according to claim 1, characterized in that, The thickness of the fine-grained pressure vessel steel plate is 15~95mm.

5. A method for manufacturing a fine-grained pressure vessel steel plate according to any one of claims 1-4, characterized in that, The manufacturing method of the fine-grained pressure vessel steel plate includes the following steps: (1) Smelting: The thickness of the continuously cast billet is 150~350mm; (2) Homogenization treatment: After the continuous casting billet is smelted, it is directly charged into the heating furnace for homogenization treatment. (3) Rough rolling and finish rolling: After homogenization, the continuous casting billet is hotly sent to the rolling mill for rolling. First, the continuous casting billet is rough rolled to open the billet. After rough rolling, the intermediate billet is oscillated and air-cooled on the roller table. When the temperature drops to 600~650℃, it is continuously rolled in multiple passes. (4) Isothermal rolling: After finishing rolling, the steel plate is isothermal rolled at a temperature of 550~600℃, and the total deformation rate of isothermal rolling is 1~2%; (5) Sub-temperature quenching: After isothermal rolling, the steel plate is directly sent to the heat treatment furnace for sub-temperature quenching after exiting the holding furnace, and then cooled to room temperature by ACC water cooling after exiting the furnace.

6. The manufacturing method according to claim 5, characterized in that, In step (2), the homogenization temperature treatment is: heat treatment at 1140~1160℃ for 1~2 hours.

7. The manufacturing method according to claim 5, characterized in that, In step (3), the roughing rolling temperature is 1080~1110℃ and the final rolling temperature is 810~840℃, ensuring a reduction rate of 15~25% per pass and an intermediate billet thickness of 2~3 times the thickness of the finished steel plate; the finishing rolling ensures a reduction rate of 5~15% per pass and reserves 1.0~2.0% deformation rate after finishing rolling until the final finished steel plate thickness.

8. The manufacturing method according to claim 5, characterized in that, In step (4), isothermal rolling is carried out in two stages. The first stage is the initial rolling with a deformation rate of 0.5~1%, and the temperature is maintained at 550~600℃ for 5~10 min after the initial rolling. The second stage is the final rolling with a deformation rate of 0.5~1%, and the temperature is maintained at 550~600℃ for 5~10 min after the final rolling.

9. The manufacturing method according to claim 5, characterized in that, In step (5), the sub-temperature quenching temperature is 500~550℃, and the net holding time is 3~4min / mm.

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