A high-temperature conductive silver paste for a microcrystalline glass thick-film heating plate, its preparation method and sintering process

By using composite glass powder with a low coefficient of thermal expansion and a rapid sintering process, a high-temperature conductive silver paste suitable for microcrystalline glass thick film heating plates was prepared. This solved the problem of thermal expansion mismatch in the high-temperature preparation and multiple sintering processes of microcrystalline glass thick film heating plates, and achieved high-performance conductivity and resistance to current surges.

CN117198588BActive Publication Date: 2026-05-26HUNAN TEFA NEW MATERIAL CO LTD
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Patent Information

Application Number
CN202210808740.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-07-11
Publication Date
2026-05-26
Estimated Expiration
2042-07-11

AI Technical Summary

Technical Problem

Microcrystalline glass thick film heating plates are prone to appearance defects such as cracking, blistering, and peeling under high-temperature preparation conditions. In addition, they may experience problems such as open circuits, breakage at the overlap between the conductive and resistive layers, and decreased solderability and adhesion during multiple sintering cycles, making them difficult to match with microcrystalline glass substrates.

Method used

By using composite glass powder with a low coefficient of thermal expansion and a rapid sintering process, combined with a specific ratio of silver powder and organic carrier, a high-temperature conductive silver paste for a microcrystalline glass thick film heating plate is prepared. A dense conductive layer is formed through solid-phase diffusion reaction, which matches the thermal expansion characteristics of the microcrystalline glass substrate.

Benefits of technology

It achieves good thermal expansion matching between conductive silver paste and microcrystalline glass substrate, improves high temperature creep resistance and current surge resistance, ensures that the conductive paste does not fail during multiple sintering cycles, has strong adhesion, excellent conductivity, and the maximum operating temperature can reach over 450℃.

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Abstract

This invention provides a high-temperature conductive silver paste for a microcrystalline glass thick-film heating plate, its preparation method, and sintering process. The high-temperature conductive silver paste for the microcrystalline glass thick-film heating plate, by mass percentage, comprises: silver powder: 75-85%; composite glass powder: 1-5%; organic carrier: 10-24%. The composite glass powder comprises component A and component B in a mass ratio of 1-3:1. Component B is silicon micropowder. Component A, by mass percentage, comprises: silicon oxide: 35-50%; boric acid: 20-30%; magnesium oxide: 10-15%; aluminum oxide: 5-10%; titanium oxide: 3-5%; and zirconium oxide: 1-2%. The high-temperature conductive silver paste for the microcrystalline glass thick-film heating plate prepared by this invention has high solderability, strong adhesion, a maximum operating temperature exceeding 450℃, strong resistance to high current impact, high re-firing stability, and excellent overall performance.
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